#------------------------------------------------------------------------------
#$Date: 2016-03-21 13:48:43 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178702 $
#$URL: svn://www.crystallography.net/cod/cif/4/08/13/4081374.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4081374
loop_
_publ_author_name
'Jiang, Yi'
'Wang, Yong-Tao'
'Ma, Zheng-Gen'
'Li, Zhi-Hong'
'Wei, Qiao-Hua'
'Chen, Guo-Nan'
_publ_section_title
;
 New Luminescent Ag2Au2Heteronuclear Alkynyl--Phosphine Complexes and
 Recognition of Homocysteine and Cysteine
;
_journal_issue                   17
_journal_name_full               Organometallics
_journal_page_first              4919
_journal_paper_doi               10.1021/om400646p
_journal_volume                  32
_journal_year                    2013
_chemical_formula_sum            'C113 H99 Ag2 Au2 Cl2 N3 O12 P6'
_chemical_formula_weight         2557.35
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-I 2ya'
_symmetry_space_group_name_H-M   'I 1 2/a 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 100.79(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   26.039(5)
_cell_length_b                   15.445(3)
_cell_length_c                   26.790(5)
_cell_measurement_reflns_used    8926
_cell_measurement_temperature    193(2)
_cell_measurement_theta_max      25
_cell_measurement_theta_min      2.08
_cell_volume                     10584(4)
_computing_cell_refinement       HKL2000
_computing_data_collection       'Mar CCD'
_computing_data_reduction        HKL2000
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      193(2)
_diffrn_measured_fraction_theta_full 0.959
_diffrn_measured_fraction_theta_max 0.959
_diffrn_measurement_device_type  'Mar CCD 165 nm'
_diffrn_measurement_method       oscillation
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           synchrotron
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0163
_diffrn_reflns_av_sigmaI/netI    0.0240
_diffrn_reflns_limit_h_max       30
_diffrn_reflns_limit_h_min       -30
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       31
_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_number            17016
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.08
_diffrn_standards_decay_%        none
_diffrn_standards_interval_count none
_diffrn_standards_interval_time  none
_diffrn_standards_number         none
_exptl_absorpt_coefficient_mu    3.331
_exptl_absorpt_correction_type   sphere
_exptl_absorpt_process_details
'spherical harmonics expansion of the absorption surface (Katayama, et al. 1986)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.605
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             5080
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.18
_refine_diff_density_max         0.891
_refine_diff_density_min         -1.069
_refine_diff_density_rms         0.081
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.066
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     633
_refine_ls_number_reflns         8926
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.066
_refine_ls_R_factor_all          0.0235
_refine_ls_R_factor_gt           0.0218
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0312P)²+21.2817P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0575
_refine_ls_wR_factor_ref         0.0581
_reflns_number_gt                8370
_reflns_number_total             8926
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om400646p_si_002.cif
_cod_data_source_block           Compoumd_4
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      I2/a
_cod_database_code               4081374
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y, -z'
'x+1/2, y+1/2, z+1/2'
'-x+1, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y, z'
'-x+1/2, -y+1/2, -z+1/2'
'x, -y+1/2, z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Au1 Au 1.7500 0.559522(10) 0.0000 0.01460(5) Uani 1 2 d S
Au2 Au 1.7500 0.754964(10) 0.0000 0.01570(5) Uani 1 2 d S
Ag1 Ag 1.713439(8) 0.421068(13) 0.062699(8) 0.01431(6) Uani 1 1 d .
Cl1 Cl 1.47058(3) 0.45405(5) 0.27597(3) 0.02159(16) Uani 1 1 d .
P1 P 1.66043(3) 0.76706(5) -0.00749(3) 0.01470(15) Uani 1 1 d .
P2 P 1.74309(3) 0.28146(5) 0.09706(3) 0.01308(15) Uani 1 1 d .
P3 P 1.62063(3) 0.44290(5) 0.02967(3) 0.01513(15) Uani 1 1 d .
O1 O 1.74604(9) 0.49936(15) 0.35665(8) 0.0286(5) Uani 1 1 d .
O01 O 1.60863(10) 0.78857(15) -0.18385(9) 0.0336(6) Uani 1 1 d .
O11 O 1.45062(11) 0.5131(2) 0.23597(11) 0.0552(9) Uani 1 1 d .
O12 O 1.46270(9) 0.49030(16) 0.32324(9) 0.0321(6) Uani 1 1 d .
O13 O 1.44218(13) 0.3749(2) 0.26726(14) 0.0624(10) Uani 1 1 d .
O14 O 1.52503(9) 0.43963(16) 0.27667(9) 0.0300(5) Uani 1 1 d .
N1 N 1.62827(9) 0.60418(16) -0.00120(9) 0.0149(5) Uani 1 1 d .
N2 N 1.7500 0.2567(2) 0.0000 0.0135(7) Uani 1 2 d S
C1 C 1.76286(11) 0.55389(18) 0.07551(12) 0.0180(6) Uani 1 1 d .
C01 C 1.70147(17) 0.7833(3) -0.1715(2) 0.0558(13) Uani 1 1 d .
H01A H 1.7319 0.8085 -0.1827 0.084 Uiso 1 1 calc R
H01B H 1.7004 0.7208 -0.1780 0.084 Uiso 1 1 calc R
H01C H 1.7040 0.7937 -0.1350 0.084 Uiso 1 1 calc R
C2 C 1.76668(11) 0.54369(19) 0.12094(12) 0.0175(6) Uani 1 1 d .
C02 C 1.65239(19) 0.8245(3) -0.20019(17) 0.0496(11) Uani 1 1 d .
H02A H 1.6535 0.8877 -0.1942 0.060 Uiso 1 1 calc R
H02B H 1.6497 0.8143 -0.2371 0.060 Uiso 1 1 calc R
C3 C 1.77090(11) 0.53443(19) 0.17511(11) 0.0175(6) Uani 1 1 d .
C4 C 1.72650(12) 0.5123(2) 0.19512(12) 0.0225(7) Uani 1 1 d .
H4A H 1.6941 0.5022 0.1729 0.027 Uiso 1 1 calc R
C04 C 1.56003(18) 0.8214(3) -0.21077(15) 0.0453(11) Uani 1 1 d .
H04A H 1.5570 0.8105 -0.2476 0.054 Uiso 1 1 calc R
H04B H 1.5582 0.8847 -0.2055 0.054 Uiso 1 1 calc R
C5 C 1.72974(12) 0.5050(2) 0.24689(12) 0.0211(6) Uani 1 1 d .
H5A H 1.6996 0.4902 0.2603 0.025 Uiso 1 1 calc R
C05 C 1.51634(16) 0.7770(3) -0.19151(16) 0.0482(11) Uani 1 1 d .
H05A H 1.4827 0.7989 -0.2098 0.072 Uiso 1 1 calc R
H05B H 1.5194 0.7885 -0.1551 0.072 Uiso 1 1 calc R
H05C H 1.5184 0.7144 -0.1970 0.072 Uiso 1 1 calc R
C6 C 1.77738(12) 0.51943(19) 0.27951(11) 0.0185(6) Uani 1 1 d .
C7 C 1.82168(12) 0.5397(2) 0.25975(12) 0.0220(7) Uani 1 1 d .
H7A H 1.8542 0.5483 0.2820 0.026 Uiso 1 1 calc R
C8 C 1.81856(12) 0.5474(2) 0.20774(12) 0.0202(6) Uani 1 1 d .
H8A H 1.8488 0.5615 0.1944 0.024 Uiso 1 1 calc R
C9 C 1.78189(13) 0.5140(2) 0.33496(12) 0.0238(7) Uani 1 1 d .
H9A H 1.8155 0.5227 0.3553 0.029 Uiso 1 1 calc R
C11 C 1.62554(11) 0.66960(18) -0.03447(11) 0.0155(6) Uani 1 1 d .
C12 C 1.60324(12) 0.66180(19) -0.08569(12) 0.0195(6) Uani 1 1 d .
H12A H 1.6037 0.7087 -0.1085 0.023 Uiso 1 1 calc R
C13 C 1.58025(12) 0.5834(2) -0.10235(12) 0.0215(7) Uani 1 1 d .
H13A H 1.5640 0.5760 -0.1369 0.026 Uiso 1 1 calc R
C14 C 1.58133(11) 0.51569(19) -0.06788(11) 0.0188(6) Uani 1 1 d .
H14A H 1.5653 0.4618 -0.0783 0.023 Uiso 1 1 calc R
C15 C 1.60623(11) 0.52836(19) -0.01813(11) 0.0164(6) Uani 1 1 d .
C21 C 1.74577(11) 0.21186(19) 0.04235(11) 0.0150(6) Uani 1 1 d .
C22 C 1.74578(12) 0.1216(2) 0.04366(11) 0.0205(6) Uani 1 1 d .
H22A H 1.7430 0.0915 0.0740 0.025 Uiso 1 1 calc R
C23 C 1.7500 0.0769(3) 0.0000 0.0246(10) Uani 1 2 d S
H23A H 1.7500 0.0154 0.0000 0.030 Uiso 1 2 calc SR
C101 C 1.64500(11) 0.77961(19) 0.05533(11) 0.0178(6) Uani 1 1 d .
C102 C 1.66725(13) 0.7209(2) 0.09290(12) 0.0248(7) Uani 1 1 d .
H10A H 1.6905 0.6774 0.0854 0.030 Uiso 1 1 calc R
C103 C 1.65533(15) 0.7262(2) 0.14130(13) 0.0321(8) Uani 1 1 d .
H10B H 1.6699 0.6856 0.1667 0.038 Uiso 1 1 calc R
C104 C 1.62232(14) 0.7902(2) 0.15251(13) 0.0316(8) Uani 1 1 d .
H10C H 1.6139 0.7930 0.1855 0.038 Uiso 1 1 calc R
C105 C 1.60163(13) 0.8499(2) 0.11629(14) 0.0307(8) Uani 1 1 d .
H10D H 1.5794 0.8943 0.1245 0.037 Uiso 1 1 calc R
C106 C 1.61304(12) 0.8458(2) 0.06770(13) 0.0240(7) Uani 1 1 d .
H10E H 1.5991 0.8879 0.0430 0.029 Uiso 1 1 calc R
C111 C 1.63072(12) 0.85522(19) -0.04646(12) 0.0177(6) Uani 1 1 d .
C112 C 1.57606(12) 0.8646(2) -0.05751(12) 0.0224(7) Uani 1 1 d .
H11A H 1.5546 0.8242 -0.0443 0.027 Uiso 1 1 calc R
C113 C 1.55347(13) 0.9323(2) -0.08735(13) 0.0244(7) Uani 1 1 d .
H11B H 1.5165 0.9384 -0.0945 0.029 Uiso 1 1 calc R
C114 C 1.58448(12) 0.9914(2) -0.10695(12) 0.0234(7) Uani 1 1 d .
H11C H 1.5689 1.0381 -0.1274 0.028 Uiso 1 1 calc R
C115 C 1.63838(13) 0.9822(2) -0.09662(13) 0.0258(7) Uani 1 1 d .
H11D H 1.6597 1.0226 -0.1101 0.031 Uiso 1 1 calc R
C116 C 1.66129(12) 0.9144(2) -0.06687(12) 0.0214(7) Uani 1 1 d .
H11E H 1.6982 0.9083 -0.0603 0.026 Uiso 1 1 calc R
C201 C 1.69807(11) 0.22668(19) 0.13111(11) 0.0159(6) Uani 1 1 d .
C202 C 1.70488(12) 0.2348(2) 0.18385(12) 0.0223(7) Uani 1 1 d .
H20A H 1.7344 0.2647 0.2021 0.027 Uiso 1 1 calc R
C203 C 1.66839(13) 0.1991(2) 0.20967(13) 0.0274(7) Uani 1 1 d .
H20B H 1.6733 0.2048 0.2456 0.033 Uiso 1 1 calc R
C204 C 1.62525(13) 0.1555(2) 0.18399(14) 0.0288(8) Uani 1 1 d .
H20C H 1.6009 0.1304 0.2020 0.035 Uiso 1 1 calc R
C205 C 1.61784(13) 0.1486(2) 0.13182(14) 0.0299(8) Uani 1 1 d .
H20D H 1.5879 0.1193 0.1139 0.036 Uiso 1 1 calc R
C206 C 1.65389(12) 0.1844(2) 0.10523(13) 0.0245(7) Uani 1 1 d .
H20E H 1.6482 0.1798 0.0693 0.029 Uiso 1 1 calc R
C211 C 1.80754(11) 0.26769(19) 0.13632(11) 0.0152(6) Uani 1 1 d .
C212 C 1.84239(12) 0.33717(19) 0.14165(12) 0.0196(6) Uani 1 1 d .
H21A H 1.8314 0.3917 0.1270 0.023 Uiso 1 1 calc R
C213 C 1.89339(13) 0.3264(2) 0.16846(13) 0.0261(7) Uani 1 1 d .
H21B H 1.9170 0.3738 0.1724 0.031 Uiso 1 1 calc R
C214 C 1.90948(13) 0.2467(2) 0.18924(13) 0.0265(7) Uani 1 1 d .
H21C H 1.9445 0.2393 0.2066 0.032 Uiso 1 1 calc R
C215 C 1.87485(12) 0.1775(2) 0.18485(12) 0.0232(7) Uani 1 1 d .
H21D H 1.8861 0.1232 0.1997 0.028 Uiso 1 1 calc R
C216 C 1.82404(12) 0.1876(2) 0.15890(11) 0.0182(6) Uani 1 1 d .
H21E H 1.8002 0.1404 0.1563 0.022 Uiso 1 1 calc R
C301 C 1.58836(11) 0.4724(2) 0.08200(11) 0.0193(6) Uani 1 1 d .
C302 C 1.56777(13) 0.5538(2) 0.08735(13) 0.0264(7) Uani 1 1 d .
H30A H 1.5673 0.5959 0.0615 0.032 Uiso 1 1 calc R
C303 C 1.54765(15) 0.5740(2) 0.13064(15) 0.0352(9) Uani 1 1 d .
H30B H 1.5335 0.6299 0.1341 0.042 Uiso 1 1 calc R
C304 C 1.54814(14) 0.5134(3) 0.16827(13) 0.0341(9) Uani 1 1 d .
H30C H 1.5344 0.5275 0.1977 0.041 Uiso 1 1 calc R
C305 C 1.56851(14) 0.4322(3) 0.16338(14) 0.0343(9) Uani 1 1 d .
H30D H 1.5685 0.3903 0.1893 0.041 Uiso 1 1 calc R
C306 C 1.58911(14) 0.4112(2) 0.12069(13) 0.0288(8) Uani 1 1 d .
H30E H 1.6037 0.3554 0.1177 0.035 Uiso 1 1 calc R
C312 C 1.53289(13) 0.3347(2) -0.00108(13) 0.0248(7) Uani 1 1 d .
H31A H 1.5138 0.3729 0.0164 0.030 Uiso 1 1 calc R
C313 C 1.50834(13) 0.2643(2) -0.02744(14) 0.0308(8) Uani 1 1 d .
H31B H 1.4721 0.2549 -0.0284 0.037 Uiso 1 1 calc R
C314 C 1.53609(14) 0.2072(2) -0.05255(14) 0.0323(8) Uani 1 1 d .
H31C H 1.5190 0.1588 -0.0702 0.039 Uiso 1 1 calc R
C315 C 1.58886(13) 0.2215(2) -0.05159(13) 0.0278(7) Uani 1 1 d .
H31D H 1.6081 0.1828 -0.0687 0.033 Uiso 1 1 calc R
C316 C 1.58606(12) 0.34926(18) -0.00041(12) 0.0173(6) Uani 1 1 d .
C317 C 1.61347(12) 0.2921(2) -0.02568(12) 0.0218(7) Uani 1 1 d .
H31E H 1.6496 0.3015 -0.0252 0.026 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Au1 C1 174.99(16) 2_855 .
C1 Au1 Ag1 122.04(8) 2_855 .
C1 Au1 Ag1 53.62(8) . .
C1 Au1 Ag1 53.62(8) 2_855 2_855
C1 Au1 Ag1 122.04(8) . 2_855
Ag1 Au1 Ag1 88.41(2) . 2_855
C1 Au1 Au2 92.50(8) 2_855 .
C1 Au1 Au2 92.50(8) . .
Ag1 Au1 Au2 135.793(10) . .
Ag1 Au1 Au2 135.793(10) 2_855 .
P1 Au2 P1 170.72(4) 2_855 .
P1 Au2 Au1 94.638(19) 2_855 .
P1 Au2 Au1 94.638(19) . .
C1 Ag1 P2 125.55(8) . .
C1 Ag1 P3 113.61(7) . .
P2 Ag1 P3 119.14(3) . .
C1 Ag1 C2 26.99(10) . .
P2 Ag1 C2 108.46(7) . .
P3 Ag1 C2 119.02(7) . .
C1 Ag1 Au1 41.62(8) . .
P2 Ag1 Au1 137.90(2) . .
P3 Ag1 Au1 95.49(2) . .
C2 Ag1 Au1 68.61(7) . .
O13 Cl1 O11 108.7(2) . .
O13 Cl1 O14 110.55(18) . .
O11 Cl1 O14 109.23(15) . .
O13 Cl1 O12 108.90(16) . .
O11 Cl1 O12 108.71(18) . .
O14 Cl1 O12 110.74(15) . .
C111 P1 C101 108.16(14) . .
C111 P1 C11 105.35(14) . .
C101 P1 C11 105.90(13) . .
C111 P1 Au2 115.39(10) . .
C101 P1 Au2 108.88(10) . .
C11 P1 Au2 112.65(9) . .
C211 P2 C201 105.46(13) . .
C211 P2 C21 103.02(13) . .
C201 P2 C21 104.64(13) . .
C211 P2 Ag1 121.32(10) . .
C201 P2 Ag1 114.56(9) . .
C21 P2 Ag1 106.07(10) . .
C316 P3 C301 106.23(14) . .
C316 P3 C15 104.19(14) . .
C301 P3 C15 107.14(14) . .
C316 P3 Ag1 115.33(10) . .
C301 P3 Ag1 108.91(10) . .
C15 P3 Ag1 114.44(9) . .
C02 O01 C04 113.3(3) . .
C11 N1 C15 117.8(3) . .
C21 N2 C21 118.4(3) . 2_855
C2 C1 Au1 173.1(3) . .
C2 C1 Ag1 88.5(2) . .
Au1 C1 Ag1 84.76(11) . .
C02 C01 H01A 109.5 . .
C02 C01 H01B 109.5 . .
H01A C01 H01B 109.5 . .
C02 C01 H01C 109.5 . .
H01A C01 H01C 109.5 . .
H01B C01 H01C 109.5 . .
C1 C2 C3 178.2(3) . .
C1 C2 Ag1 64.51(18) . .
C3 C2 Ag1 116.82(19) . .
O01 C02 C01 109.5(3) . .
O01 C02 H02A 109.8 . .
C01 C02 H02A 109.8 . .
O01 C02 H02B 109.8 . .
C01 C02 H02B 109.8 . .
H02A C02 H02B 108.2 . .
C8 C3 C4 119.7(3) . .
C8 C3 C2 120.6(3) . .
C4 C3 C2 119.7(3) . .
C5 C4 C3 120.3(3) . .
C5 C4 H4A 119.9 . .
C3 C4 H4A 119.9 . .
O01 C04 C05 108.7(3) . .
O01 C04 H04A 109.9 . .
C05 C04 H04A 109.9 . .
O01 C04 H04B 109.9 . .
C05 C04 H04B 109.9 . .
H04A C04 H04B 108.3 . .
C4 C5 C6 119.8(3) . .
C4 C5 H5A 120.1 . .
C6 C5 H5A 120.1 . .
C04 C05 H05A 109.5 . .
C04 C05 H05B 109.5 . .
H05A C05 H05B 109.5 . .
C04 C05 H05C 109.5 . .
H05A C05 H05C 109.5 . .
H05B C05 H05C 109.5 . .
C7 C6 C5 120.0(3) . .
C7 C6 C9 118.8(3) . .
C5 C6 C9 121.2(3) . .
C8 C7 C6 120.3(3) . .
C8 C7 H7A 119.8 . .
C6 C7 H7A 119.8 . .
C7 C8 C3 119.8(3) . .
C7 C8 H8A 120.1 . .
C3 C8 H8A 120.1 . .
O1 C9 C6 125.0(3) . .
O1 C9 H9A 117.5 . .
C6 C9 H9A 117.5 . .
N1 C11 C12 123.4(3) . .
N1 C11 P1 113.3(2) . .
C12 C11 P1 123.0(2) . .
C13 C12 C11 117.9(3) . .
C13 C12 H12A 121.0 . .
C11 C12 H12A 121.0 . .
C12 C13 C14 119.2(3) . .
C12 C13 H13A 120.4 . .
C14 C13 H13A 120.4 . .
C15 C14 C13 118.7(3) . .
C15 C14 H14A 120.6 . .
C13 C14 H14A 120.6 . .
N1 C15 C14 122.8(3) . .
N1 C15 P3 112.0(2) . .
C14 C15 P3 124.8(2) . .
N2 C21 C22 122.2(3) . .
N2 C21 P2 113.2(2) . .
C22 C21 P2 124.5(2) . .
C23 C22 C21 118.6(3) . .
C23 C22 H22A 120.7 . .
C21 C22 H22A 120.7 . .
C22 C23 C22 120.0(4) 2_855 .
C22 C23 H23A 120.0 2_855 .
C22 C23 H23A 120.0 . .
C106 C101 C102 119.3(3) . .
C106 C101 P1 123.0(2) . .
C102 C101 P1 117.7(2) . .
C103 C102 C101 119.9(3) . .
C103 C102 H10A 120.1 . .
C101 C102 H10A 120.1 . .
C104 C103 C102 120.1(3) . .
C104 C103 H10B 119.9 . .
C102 C103 H10B 119.9 . .
C105 C104 C103 120.4(3) . .
C105 C104 H10C 119.8 . .
C103 C104 H10C 119.8 . .
C104 C105 C106 120.4(3) . .
C104 C105 H10D 119.8 . .
C106 C105 H10D 119.8 . .
C105 C106 C101 119.8(3) . .
C105 C106 H10E 120.1 . .
C101 C106 H10E 120.1 . .
C116 C111 C112 118.7(3) . .
C116 C111 P1 120.7(2) . .
C112 C111 P1 120.6(2) . .
C113 C112 C111 120.4(3) . .
C113 C112 H11A 119.8 . .
C111 C112 H11A 119.8 . .
C112 C113 C114 120.2(3) . .
C112 C113 H11B 119.9 . .
C114 C113 H11B 119.9 . .
C113 C114 C115 119.8(3) . .
C113 C114 H11C 120.1 . .
C115 C114 H11C 120.1 . .
C116 C115 C114 120.3(3) . .
C116 C115 H11D 119.8 . .
C114 C115 H11D 119.8 . .
C115 C116 C111 120.5(3) . .
C115 C116 H11E 119.7 . .
C111 C116 H11E 119.7 . .
C206 C201 C202 118.9(3) . .
C206 C201 P2 121.2(2) . .
C202 C201 P2 119.5(2) . .
C203 C202 C201 119.9(3) . .
C203 C202 H20A 120.0 . .
C201 C202 H20A 120.0 . .
C204 C203 C202 121.0(3) . .
C204 C203 H20B 119.5 . .
C202 C203 H20B 119.5 . .
C203 C204 C205 119.3(3) . .
C203 C204 H20C 120.3 . .
C205 C204 H20C 120.3 . .
C204 C205 C206 120.5(3) . .
C204 C205 H20D 119.7 . .
C206 C205 H20D 119.7 . .
C201 C206 C205 120.3(3) . .
C201 C206 H20E 119.8 . .
C205 C206 H20E 119.8 . .
C212 C211 C216 119.4(3) . .
C212 C211 P2 118.8(2) . .
C216 C211 P2 121.7(2) . .
C211 C212 C213 119.9(3) . .
C211 C212 H21A 120.0 . .
C213 C212 H21A 120.0 . .
C214 C213 C212 120.0(3) . .
C214 C213 H21B 120.0 . .
C212 C213 H21B 120.0 . .
C213 C214 C215 120.5(3) . .
C213 C214 H21C 119.7 . .
C215 C214 H21C 119.7 . .
C216 C215 C214 120.0(3) . .
C216 C215 H21D 120.0 . .
C214 C215 H21D 120.0 . .
C215 C216 C211 120.1(3) . .
C215 C216 H21E 120.0 . .
C211 C216 H21E 120.0 . .
C302 C301 C306 119.2(3) . .
C302 C301 P3 123.4(2) . .
C306 C301 P3 117.1(2) . .
C301 C302 C303 120.1(3) . .
C301 C302 H30A 119.9 . .
C303 C302 H30A 119.9 . .
C304 C303 C302 120.3(3) . .
C304 C303 H30B 119.8 . .
C302 C303 H30B 119.8 . .
C303 C304 C305 120.1(3) . .
C303 C304 H30C 120.0 . .
C305 C304 H30C 120.0 . .
C304 C305 C306 120.4(3) . .
C304 C305 H30D 119.8 . .
C306 C305 H30D 119.8 . .
C305 C306 C301 119.8(3) . .
C305 C306 H30E 120.1 . .
C301 C306 H30E 120.1 . .
C313 C312 C316 119.5(3) . .
C313 C312 H31A 120.2 . .
C316 C312 H31A 120.2 . .
C312 C313 C314 120.8(3) . .
C312 C313 H31B 119.6 . .
C314 C313 H31B 119.6 . .
C315 C314 C313 119.6(3) . .
C315 C314 H31C 120.2 . .
C313 C314 H31C 120.2 . .
C317 C315 C314 119.9(3) . .
C317 C315 H31D 120.1 . .
C314 C315 H31D 120.1 . .
C317 C316 C312 119.3(3) . .
C317 C316 P3 117.8(2) . .
C312 C316 P3 122.8(2) . .
C315 C317 C316 120.9(3) . .
C315 C317 H31E 119.5 . .
C316 C317 H31E 119.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Au1 C1 1.990(3) 2_855
Au1 C1 1.990(3) .
Au1 Ag1 2.9832(5) .
Au1 Ag1 2.9832(5) 2_855
Au1 Au2 3.0186(7) .
Au2 P1 2.3107(8) 2_855
Au2 P1 2.3107(9) .
Ag1 C1 2.412(3) .
Ag1 P2 2.4138(9) .
Ag1 P3 2.4364(10) .
Ag1 C2 2.671(3) .
Cl1 O13 1.425(3) .
Cl1 O11 1.429(3) .
Cl1 O14 1.432(2) .
Cl1 O12 1.434(2) .
P1 C111 1.800(3) .
P1 C101 1.812(3) .
P1 C11 1.835(3) .
P2 C211 1.819(3) .
P2 C201 1.823(3) .
P2 C21 1.829(3) .
P3 C316 1.811(3) .
P3 C301 1.822(3) .
P3 C15 1.828(3) .
O1 C9 1.210(4) .
O01 C02 1.409(5) .
O01 C04 1.427(5) .
N1 C11 1.340(4) .
N1 C15 1.345(4) .
N2 C21 1.351(3) .
N2 C21 1.351(3) 2_855
C1 C2 1.213(4) .
C01 C02 1.504(7) .
C01 H01A 0.9800 .
C01 H01B 0.9800 .
C01 H01C 0.9800 .
C2 C3 1.442(4) .
C02 H02A 0.9900 .
C02 H02B 0.9900 .
C3 C8 1.392(4) .
C3 C4 1.405(4) .
C4 C5 1.378(4) .
C4 H4A 0.9500 .
C04 C05 1.500(6) .
C04 H04A 0.9900 .
C04 H04B 0.9900 .
C5 C6 1.395(4) .
C5 H5A 0.9500 .
C05 H05A 0.9800 .
C05 H05B 0.9800 .
C05 H05C 0.9800 .
C6 C7 1.392(4) .
C6 C9 1.471(4) .
C7 C8 1.385(4) .
C7 H7A 0.9500 .
C8 H8A 0.9500 .
C9 H9A 0.9500 .
C11 C12 1.391(5) .
C12 C13 1.387(4) .
C12 H12A 0.9500 .
C13 C14 1.392(4) .
C13 H13A 0.9500 .
C14 C15 1.383(4) .
C14 H14A 0.9500 .
C21 C22 1.395(4) .
C22 C23 1.380(4) .
C22 H22A 0.9500 .
C23 C22 1.380(4) 2_855
C23 H23A 0.9500 .
C101 C106 1.396(4) .
C101 C102 1.398(5) .
C102 C103 1.391(5) .
C102 H10A 0.9500 .
C103 C104 1.380(5) .
C103 H10B 0.9500 .
C104 C105 1.373(5) .
C104 H10C 0.9500 .
C105 C106 1.390(5) .
C105 H10D 0.9500 .
C106 H10E 0.9500 .
C111 C116 1.390(4) .
C111 C112 1.406(4) .
C112 C113 1.379(4) .
C112 H11A 0.9500 .
C113 C114 1.386(4) .
C113 H11B 0.9500 .
C114 C115 1.386(5) .
C114 H11C 0.9500 .
C115 C116 1.381(5) .
C115 H11D 0.9500 .
C116 H11E 0.9500 .
C201 C206 1.390(4) .
C201 C202 1.396(4) .
C202 C203 1.390(4) .
C202 H20A 0.9500 .
C203 C204 1.378(5) .
C203 H20B 0.9500 .
C204 C205 1.379(5) .
C204 H20C 0.9500 .
C205 C206 1.394(5) .
C205 H20D 0.9500 .
C206 H20E 0.9500 .
C211 C212 1.395(4) .
C211 C216 1.409(4) .
C212 C213 1.396(5) .
C212 H21A 0.9500 .
C213 C214 1.383(5) .
C213 H21B 0.9500 .
C214 C215 1.390(5) .
C214 H21C 0.9500 .
C215 C216 1.383(4) .
C215 H21D 0.9500 .
C216 H21E 0.9500 .
C301 C302 1.384(5) .
C301 C306 1.400(4) .
C302 C303 1.394(5) .
C302 H30A 0.9500 .
C303 C304 1.374(5) .
C303 H30B 0.9500 .
C304 C305 1.377(5) .
C304 H30C 0.9500 .
C305 C306 1.390(5) .
C305 H30D 0.9500 .
C306 H30E 0.9500 .
C312 C313 1.387(5) .
C312 C316 1.399(4) .
C312 H31A 0.9500 .
C313 C314 1.390(5) .
C313 H31B 0.9500 .
C314 C315 1.387(5) .
C314 H31C 0.9500 .
C315 C317 1.384(5) .
C315 H31D 0.9500 .
C316 C317 1.389(4) .
C317 H31E 0.9500 .
