#------------------------------------------------------------------------------
#$Date: 2016-02-14 06:40:26 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176432 $
#$URL: svn://www.crystallography.net/cod/cif/4/08/27/4082756.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4082756
loop_
_publ_author_name
'Matsumoto, Teruyuki'
'Sasamori, Takahiro'
'Miyake, Hideaki'
'Tokitoh, Norihiro'
_publ_section_title
;
 Synthesis of a Rhodium Carbonyl Phosphaalkenyl--Phosphido Complex: A
 Phosphorus Congener of Schiff Base Type N,N′-Chelating Monoanionic
 Ligands
;
_journal_issue                   6
_journal_name_full               Organometallics
_journal_page_first              1341
_journal_paper_doi               10.1021/om500065n
_journal_volume                  33
_journal_year                    2014
_chemical_formula_moiety         'C45 H63 O2 P2 Rh, 0.5(C6 H6), 0.5(C6 H14),'
_chemical_formula_sum            'C51 H73 O2 P2 Rh'
_chemical_formula_weight         882.94
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                111.9108(12)
_cell_angle_beta                 93.5674(12)
_cell_angle_gamma                106.4291(16)
_cell_formula_units_Z            2
_cell_length_a                   9.6326(2)
_cell_length_b                   15.2660(4)
_cell_length_c                   18.9224(6)
_cell_measurement_temperature    103(2)
_cell_volume                     2431.76(12)
_computing_cell_refinement       HKL2000
_computing_data_collection       CrystalClear
_computing_data_reduction        HKL2000
_computing_molecular_graphics
'Yadokari-XG 2011 (Wakita Nemoto et al., 2011)'
_computing_publication_material
'Yadokari-XG 2011 (Wakita,Nemoto et al., 2011)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    SIR2004
_diffrn_ambient_temperature      103(2)
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  Rigaku_Mercury_CCD
_diffrn_measurement_method       'Omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0435
_diffrn_reflns_av_sigmaI/netI    0.0707
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            21712
_diffrn_reflns_theta_full        25.50
_diffrn_reflns_theta_max         25.50
_diffrn_reflns_theta_min         1.50
_exptl_absorpt_coefficient_mu    0.453
_exptl_absorpt_correction_T_max  0.9865
_exptl_absorpt_correction_T_min  0.9561
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
 MULABS - Empirical Correction for Absorption Anisotropy.
 Blessing, R. H., Acta Cryst., A51, 33-38 (1995).
;
_exptl_crystal_colour            purple
_exptl_crystal_density_diffrn    1.206
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             940
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.03
_refine_diff_density_max         0.639
_refine_diff_density_min         -0.436
_refine_diff_density_rms         0.060
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.013
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     585
_refine_ls_number_reflns         8996
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.013
_refine_ls_R_factor_all          0.0648
_refine_ls_R_factor_gt           0.0383
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0280P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0723
_refine_ls_wR_factor_ref         0.0777
_reflns_number_gt                6602
_reflns_number_total             8996
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om500065n_si_003.cif
_cod_data_source_block           compound6
_cod_original_cell_volume        2431.76(11)
_cod_original_sg_symbol_Hall     ' -P 1 '
_cod_database_code               4082756
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.23500(2) 0.166409(18) 0.249072(13) 0.02795(8) Uani 1 1 d . . .
C1 C 0.1418(3) 0.0836(2) 0.29766(19) 0.0421(8) Uani 1 1 d . . .
O1 O 0.0834(3) 0.0360(2) 0.32771(15) 0.0664(8) Uani 1 1 d . . .
C2 C 0.0851(4) 0.0955(2) 0.1570(2) 0.0496(9) Uani 1 1 d . . .
O2 O 0.0032(3) 0.05226(19) 0.10268(16) 0.0856(10) Uani 1 1 d . . .
P1 P 0.31408(8) 0.29829(5) 0.21641(4) 0.02521(17) Uani 1 1 d . . .
C3 C 0.4945(3) 0.38680(19) 0.24460(14) 0.0236(6) Uani 1 1 d . . .
C4 C 0.5297(3) 0.4577(2) 0.21118(16) 0.0303(7) Uani 1 1 d . . .
H1 H 0.4599 0.4513 0.1702 0.036 Uiso 1 1 calc R . .
C5 C 0.6602(3) 0.5350(2) 0.23588(16) 0.0335(7) Uani 1 1 d . . .
H2 H 0.6797 0.5809 0.2120 0.040 Uiso 1 1 calc R . .
C6 C 0.7648(3) 0.5468(2) 0.29573(16) 0.0343(7) Uani 1 1 d . . .
H3 H 0.8550 0.6010 0.3130 0.041 Uiso 1 1 calc R . .
C7 C 0.7379(3) 0.4807(2) 0.32965(16) 0.0283(6) Uani 1 1 d . . .
H4 H 0.8106 0.4894 0.3702 0.034 Uiso 1 1 calc R . .
C8 C 0.6035(3) 0.39886(19) 0.30595(15) 0.0245(6) Uani 1 1 d . . .
C9 C 0.5905(3) 0.33204(19) 0.34343(15) 0.0265(6) Uani 1 1 d . . .
H5 H 0.6697 0.3516 0.3846 0.032 Uiso 1 1 calc R . .
P2 P 0.45689(8) 0.22439(5) 0.32595(4) 0.02603(17) Uani 1 1 d . . .
C10 C 0.2441(3) 0.28419(19) 0.11827(15) 0.0237(6) Uani 1 1 d . . .
C11 C 0.1284(3) 0.32423(19) 0.11038(15) 0.0245(6) Uani 1 1 d . . .
C12 C 0.0694(3) 0.3088(2) 0.03662(15) 0.0261(6) Uani 1 1 d . . .
H6 H -0.0079 0.3345 0.0313 0.031 Uiso 1 1 calc R . .
C13 C 0.1152(3) 0.25845(19) -0.03022(15) 0.0243(6) Uani 1 1 d . . .
C14 C 0.2263(3) 0.2213(2) -0.02092(15) 0.0274(6) Uani 1 1 d . . .
H7 H 0.2600 0.1869 -0.0659 0.033 Uiso 1 1 calc R . .
C15 C 0.2928(3) 0.2313(2) 0.05084(15) 0.0253(6) Uani 1 1 d . A .
C16 C 0.0610(3) 0.3833(2) 0.17746(15) 0.0303(7) Uani 1 1 d . . .
C17 C 0.1770(3) 0.4751(2) 0.24192(16) 0.0372(7) Uani 1 1 d . . .
H8 H 0.2343 0.5184 0.2192 0.056 Uiso 1 1 calc R . .
H9 H 0.2431 0.4529 0.2675 0.056 Uiso 1 1 calc R . .
H10 H 0.1275 0.5123 0.2800 0.056 Uiso 1 1 calc R . .
C18 C -0.0308(3) 0.3141(2) 0.21172(17) 0.0363(7) Uani 1 1 d . . .
H11 H -0.1045 0.2564 0.1701 0.054 Uiso 1 1 calc R . .
H12 H -0.0806 0.3510 0.2499 0.054 Uiso 1 1 calc R . .
H13 H 0.0343 0.2911 0.2370 0.054 Uiso 1 1 calc R . .
C19 C -0.0473(4) 0.4263(2) 0.14890(17) 0.0449(9) Uani 1 1 d . . .
H14 H 0.0047 0.4715 0.1263 0.067 Uiso 1 1 calc R . .
H15 H -0.0866 0.4633 0.1927 0.067 Uiso 1 1 calc R . .
H16 H -0.1285 0.3714 0.1096 0.067 Uiso 1 1 calc R . .
C20 C 0.0418(3) 0.2458(2) -0.10951(15) 0.0303(7) Uani 1 1 d . . .
C21 C -0.1209(3) 0.1801(2) -0.12651(17) 0.0431(8) Uani 1 1 d . . .
H17 H -0.1698 0.2112 -0.0849 0.065 Uiso 1 1 calc R . .
H18 H -0.1263 0.1137 -0.1294 0.065 Uiso 1 1 calc R . .
H19 H -0.1702 0.1735 -0.1760 0.065 Uiso 1 1 calc R . .
C22 C 0.0469(3) 0.3480(2) -0.10808(16) 0.0397(8) Uani 1 1 d . . .
H20 H -0.0004 0.3806 -0.0662 0.059 Uiso 1 1 calc R . .
H21 H -0.0055 0.3385 -0.1579 0.059 Uiso 1 1 calc R . .
H22 H 0.1497 0.3901 -0.0992 0.059 Uiso 1 1 calc R . .
C23 C 0.1147(4) 0.1960(3) -0.17490(16) 0.0461(9) Uani 1 1 d . . .
H23 H 0.1114 0.1306 -0.1765 0.069 Uiso 1 1 calc R . .
H24 H 0.2175 0.2381 -0.1659 0.069 Uiso 1 1 calc R . .
H25 H 0.0622 0.1873 -0.2244 0.069 Uiso 1 1 calc R . .
C24 C 0.4136(3) 0.1785(2) 0.04296(16) 0.0374(8) Uani 1 1 d . . .
C25 C 0.3491(6) 0.0739(3) -0.0129(3) 0.0450(17) Uani 0.676(6) 1 d P A 1
H26 H 0.2856 0.0701 -0.0572 0.068 Uiso 0.676(6) 1 calc PR A 1
H27 H 0.2906 0.0343 0.0121 0.068 Uiso 0.676(6) 1 calc PR A 1
H28 H 0.4280 0.0475 -0.0309 0.068 Uiso 0.676(6) 1 calc PR A 1
C26 C 0.5360(5) 0.2369(4) 0.0054(3) 0.0465(17) Uani 0.676(6) 1 d P A 1
H29 H 0.5816 0.3070 0.0421 0.070 Uiso 0.676(6) 1 calc PR A 1
H30 H 0.4878 0.2338 -0.0430 0.070 Uiso 0.676(6) 1 calc PR A 1
H31 H 0.6120 0.2050 -0.0052 0.070 Uiso 0.676(6) 1 calc PR A 1
C27 C 0.5062(6) 0.1843(4) 0.1124(3) 0.0313(13) Uani 0.676(6) 1 d P A 1
H32 H 0.5492 0.2542 0.1496 0.047 Uiso 0.676(6) 1 calc PR A 1
H33 H 0.5853 0.1571 0.0961 0.047 Uiso 0.676(6) 1 calc PR A 1
H34 H 0.4446 0.1453 0.1369 0.047 Uiso 0.676(6) 1 calc PR A 1
C28 C 0.5253(3) 0.1822(2) 0.39576(15) 0.0254(6) Uani 1 1 d . . .
C29 C 0.6085(3) 0.1154(2) 0.37152(15) 0.0254(6) Uani 1 1 d . . .
C30 C 0.6896(3) 0.1036(2) 0.42821(16) 0.0288(7) Uani 1 1 d . . .
H35 H 0.7477 0.0612 0.4124 0.035 Uiso 1 1 calc R . .
C31 C 0.6911(3) 0.1501(2) 0.50683(16) 0.0305(7) Uani 1 1 d . B .
C32 C 0.6027(3) 0.2085(2) 0.52810(16) 0.0299(7) Uani 1 1 d . . .
H36 H 0.5991 0.2384 0.5816 0.036 Uiso 1 1 calc R . .
C33 C 0.5177(3) 0.22665(19) 0.47595(15) 0.0264(6) Uani 1 1 d . C .
C34 C 0.6162(3) 0.0544(2) 0.28541(16) 0.0313(7) Uani 1 1 d . . .
C35 C 0.6851(4) -0.0279(2) 0.27892(18) 0.0485(9) Uani 1 1 d . . .
H37 H 0.6258 -0.0736 0.2991 0.073 Uiso 1 1 calc R . .
H38 H 0.7858 0.0032 0.3091 0.073 Uiso 1 1 calc R . .
H39 H 0.6873 -0.0653 0.2244 0.073 Uiso 1 1 calc R . .
C36 C 0.7135(3) 0.1219(2) 0.25235(17) 0.0432(8) Uani 1 1 d . . .
H40 H 0.8107 0.1575 0.2862 0.065 Uiso 1 1 calc R . .
H41 H 0.6678 0.1705 0.2493 0.065 Uiso 1 1 calc R . .
H42 H 0.7244 0.0810 0.2003 0.065 Uiso 1 1 calc R . .
C37 C 0.4621(3) -0.0034(2) 0.23459(17) 0.0407(8) Uani 1 1 d . . .
H43 H 0.4032 -0.0461 0.2573 0.061 Uiso 1 1 calc R . .
H44 H 0.4708 -0.0451 0.1823 0.061 Uiso 1 1 calc R . .
H45 H 0.4137 0.0440 0.2317 0.061 Uiso 1 1 calc R . .
C38 C 0.7858(3) 0.1354(2) 0.56719(17) 0.0370(8) Uani 1 1 d . . .
C39 C 0.6898(7) 0.0828(6) 0.6085(4) 0.0392(19) Uani 0.494(6) 1 d P B 1
H46 H 0.6213 0.0186 0.5705 0.059 Uiso 0.494(6) 1 calc PR B 1
H47 H 0.6338 0.1244 0.6371 0.059 Uiso 0.494(6) 1 calc PR B 1
H48 H 0.7514 0.0709 0.6448 0.059 Uiso 0.494(6) 1 calc PR B 1
C40 C 0.8962(7) 0.2336(5) 0.6192(4) 0.050(3) Uani 0.494(6) 1 d P B 1
H49 H 0.9538 0.2633 0.5880 0.075 Uiso 0.494(6) 1 calc PR B 1
H50 H 0.9623 0.2238 0.6549 0.075 Uiso 0.494(6) 1 calc PR B 1
H51 H 0.8454 0.2784 0.6489 0.075 Uiso 0.494(6) 1 calc PR B 1
C41 C 0.8841(7) 0.0657(6) 0.5266(4) 0.044(2) Uani 0.494(6) 1 d P B 1
H52 H 0.8185 -0.0012 0.4916 0.067 Uiso 0.494(6) 1 calc PR B 1
H53 H 0.9468 0.0607 0.5668 0.067 Uiso 0.494(6) 1 calc PR B 1
H54 H 0.9461 0.0959 0.4970 0.067 Uiso 0.494(6) 1 calc PR B 1
C42 C 0.4261(3) 0.2945(2) 0.51524(16) 0.0334(7) Uani 1 1 d . . .
C43 C 0.5337(6) 0.3970(4) 0.5747(5) 0.0515(19) Uani 0.722(12) 1 d P C 1
H55 H 0.5990 0.4295 0.5476 0.077 Uiso 0.722(12) 1 calc PR C 1
H56 H 0.5927 0.3866 0.6130 0.077 Uiso 0.722(12) 1 calc PR C 1
H57 H 0.4772 0.4397 0.6011 0.077 Uiso 0.722(12) 1 calc PR C 1
C44 C 0.3254(7) 0.2446(5) 0.5578(5) 0.0500(18) Uani 0.722(12) 1 d P C 1
H58 H 0.3827 0.2250 0.5902 0.075 Uiso 0.722(12) 1 calc PR C 1
H59 H 0.2477 0.1852 0.5200 0.075 Uiso 0.722(12) 1 calc PR C 1
H60 H 0.2807 0.2916 0.5906 0.075 Uiso 0.722(12) 1 calc PR C 1
C45 C 0.3269(8) 0.3218(7) 0.4662(3) 0.055(2) Uani 0.722(12) 1 d P C 1
H61 H 0.3865 0.3560 0.4381 0.082 Uiso 0.722(12) 1 calc PR C 1
H62 H 0.2799 0.3662 0.5002 0.082 Uiso 0.722(12) 1 calc PR C 1
H63 H 0.2508 0.2608 0.4290 0.082 Uiso 0.722(12) 1 calc PR C 1
C46 C 0.9221(3) 0.5363(3) 0.55698(19) 0.0470(9) Uani 1 1 d . . .
H64 H 0.8682 0.5611 0.5958 0.056 Uiso 1 1 calc R . .
C47 C 0.9044(3) 0.4363(3) 0.52451(19) 0.0448(9) Uani 1 1 d . . .
H65 H 0.8391 0.3921 0.5415 0.054 Uiso 1 1 calc R . .
C48 C 0.9809(3) 0.3989(2) 0.46709(19) 0.0460(9) Uani 1 1 d . . .
H66 H 0.9670 0.3293 0.4444 0.055 Uiso 1 1 calc R . .
C49 C 0.4025(4) 0.6493(3) 0.1440(2) 0.0683(11) Uani 1 1 d . . .
H67 H 0.4501 0.6353 0.1840 0.102 Uiso 1 1 calc R . .
H68 H 0.3085 0.6576 0.1562 0.102 Uiso 1 1 calc R . .
H69 H 0.4668 0.7107 0.1423 0.102 Uiso 1 1 calc R . .
C50 C 0.3747(4) 0.5616(3) 0.0647(2) 0.0643(11) Uani 1 1 d . . .
H70 H 0.3080 0.5005 0.0670 0.077 Uiso 1 1 calc R . .
H71 H 0.3231 0.5756 0.0253 0.077 Uiso 1 1 calc R . .
C51 C 0.5115(4) 0.5409(3) 0.03826(18) 0.0542(10) Uani 1 1 d . . .
H72 H 0.5793 0.6029 0.0377 0.065 Uiso 1 1 calc R . .
H73 H 0.5616 0.5255 0.0772 0.065 Uiso 1 1 calc R . .
C52 C 0.3121(11) 0.0634(7) 0.0517(6) 0.049(3) Uani 0.324(6) 1 d P A 2
H74 H 0.2869 0.0798 0.1034 0.073 Uiso 0.324(6) 1 calc PR A 2
H75 H 0.3734 0.0204 0.0441 0.073 Uiso 0.324(6) 1 calc PR A 2
H76 H 0.2216 0.0284 0.0123 0.073 Uiso 0.324(6) 1 calc PR A 2
C53 C 0.4361(16) 0.1285(12) -0.0357(6) 0.072(5) Uani 0.324(6) 1 d P A 2
H77 H 0.3498 0.1157 -0.0730 0.108 Uiso 0.324(6) 1 calc PR A 2
H78 H 0.4498 0.0650 -0.0421 0.108 Uiso 0.324(6) 1 calc PR A 2
H79 H 0.5238 0.1714 -0.0447 0.108 Uiso 0.324(6) 1 calc PR A 2
C54 C 0.5393(15) 0.2181(9) 0.1044(8) 0.041(4) Uiso 0.324(6) 1 d P A 2
H80 H 0.5144 0.2559 0.1535 0.061 Uiso 0.324(6) 1 calc PR A 2
H81 H 0.6219 0.2624 0.0932 0.061 Uiso 0.324(6) 1 calc PR A 2
H82 H 0.5672 0.1629 0.1085 0.061 Uiso 0.324(6) 1 calc PR A 2
C55 C 0.9408(7) 0.1671(6) 0.5609(4) 0.050(2) Uani 0.506(6) 1 d P B 2
H83 H 0.9729 0.2376 0.5689 0.076 Uiso 0.506(6) 1 calc PR B 2
H84 H 0.9530 0.1261 0.5093 0.076 Uiso 0.506(6) 1 calc PR B 2
H85 H 1.0005 0.1590 0.6004 0.076 Uiso 0.506(6) 1 calc PR B 2
C56 C 0.7742(9) 0.2046(7) 0.6542(4) 0.068(3) Uani 0.506(6) 1 d P B 2
H86 H 0.6716 0.1850 0.6611 0.103 Uiso 0.506(6) 1 calc PR B 2
H87 H 0.8074 0.2750 0.6619 0.103 Uiso 0.506(6) 1 calc PR B 2
H88 H 0.8365 0.1956 0.6921 0.103 Uiso 0.506(6) 1 calc PR B 2
C57 C 0.7219(9) 0.0302(6) 0.5579(6) 0.072(3) Uani 0.506(6) 1 d P B 2
H89 H 0.6184 0.0164 0.5635 0.107 Uiso 0.506(6) 1 calc PR B 2
H90 H 0.7770 0.0198 0.5977 0.107 Uiso 0.506(6) 1 calc PR B 2
H91 H 0.7282 -0.0151 0.5064 0.107 Uiso 0.506(6) 1 calc PR B 2
C58 C 0.404(3) 0.289(2) 0.5946(10) 0.080(8) Uani 0.278(12) 1 d P C 2
H92 H 0.3474 0.2198 0.5856 0.120 Uiso 0.278(12) 1 calc PR C 2
H93 H 0.3515 0.3337 0.6211 0.120 Uiso 0.278(12) 1 calc PR C 2
H94 H 0.5009 0.3083 0.6268 0.120 Uiso 0.278(12) 1 calc PR C 2
C59 C 0.2698(15) 0.2533(16) 0.4670(8) 0.055(5) Uani 0.278(12) 1 d P C 2
H95 H 0.2238 0.1836 0.4593 0.082 Uiso 0.278(12) 1 calc PR C 2
H96 H 0.2751 0.2568 0.4165 0.082 Uiso 0.278(12) 1 calc PR C 2
H97 H 0.2109 0.2933 0.4944 0.082 Uiso 0.278(12) 1 calc PR C 2
C60 C 0.500(2) 0.3979(12) 0.5251(16) 0.079(7) Uani 0.278(12) 1 d P C 2
H98 H 0.4415 0.4398 0.5499 0.118 Uiso 0.278(12) 1 calc PR C 2
H99 H 0.5102 0.3992 0.4742 0.118 Uiso 0.278(12) 1 calc PR C 2
H100 H 0.5980 0.4238 0.5576 0.118 Uiso 0.278(12) 1 calc PR C 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Rh1 C2 93.08(13) . .
C1 Rh1 P2 94.98(9) . .
C2 Rh1 P2 159.32(11) . .
C1 Rh1 P1 161.91(10) . .
C2 Rh1 P1 90.77(9) . .
P2 Rh1 P1 87.44(3) . .
O1 C1 Rh1 177.8(3) . .
O2 C2 Rh1 176.7(4) . .
C3 P1 C10 105.69(12) . .
C3 P1 Rh1 126.40(9) . .
C10 P1 Rh1 119.15(9) . .
C4 C3 C8 117.0(2) . .
C4 C3 P1 118.8(2) . .
C8 C3 P1 123.8(2) . .
C5 C4 C3 122.3(3) . .
C5 C4 H1 118.8 . .
C3 C4 H1 118.8 . .
C4 C5 C6 120.4(3) . .
C4 C5 H2 119.8 . .
C6 C5 H2 119.8 . .
C7 C6 C5 120.0(3) . .
C7 C6 H3 120.0 . .
C5 C6 H3 120.0 . .
C6 C7 C8 121.8(3) . .
C6 C7 H4 119.1 . .
C8 C7 H4 119.1 . .
C7 C8 C9 116.7(2) . .
C7 C8 C3 118.5(2) . .
C9 C8 C3 124.8(2) . .
C8 C9 P2 129.9(2) . .
C8 C9 H5 115.0 . .
P2 C9 H5 115.0 . .
C9 P2 C28 103.07(12) . .
C9 P2 Rh1 125.89(10) . .
C28 P2 Rh1 130.27(9) . .
C15 C10 C11 119.2(2) . .
C15 C10 P1 123.29(18) . .
C11 C10 P1 117.36(19) . .
C12 C11 C10 117.8(2) . .
C12 C11 C16 116.0(2) . .
C10 C11 C16 126.2(2) . .
C11 C12 C13 124.5(2) . .
C11 C12 H6 117.8 . .
C13 C12 H6 117.8 . .
C14 C13 C12 116.5(2) . .
C14 C13 C20 123.4(2) . .
C12 C13 C20 120.1(2) . .
C13 C14 C15 123.9(2) . .
C13 C14 H7 118.0 . .
C15 C14 H7 118.0 . .
C14 C15 C10 118.1(2) . .
C14 C15 C24 112.4(2) . .
C10 C15 C24 129.5(2) . .
C17 C16 C18 110.5(2) . .
C17 C16 C19 104.6(2) . .
C18 C16 C19 105.3(2) . .
C17 C16 C11 113.3(2) . .
C18 C16 C11 110.8(2) . .
C19 C16 C11 112.0(2) . .
C16 C17 H8 109.5 . .
C16 C17 H9 109.5 . .
H8 C17 H9 109.5 . .
C16 C17 H10 109.5 . .
H8 C17 H10 109.5 . .
H9 C17 H10 109.5 . .
C16 C18 H11 109.5 . .
C16 C18 H12 109.5 . .
H11 C18 H12 109.5 . .
C16 C18 H13 109.5 . .
H11 C18 H13 109.5 . .
H12 C18 H13 109.5 . .
C16 C19 H14 109.5 . .
C16 C19 H15 109.5 . .
H14 C19 H15 109.5 . .
C16 C19 H16 109.5 . .
H14 C19 H16 109.5 . .
H15 C19 H16 109.5 . .
C23 C20 C22 108.8(2) . .
C23 C20 C13 112.4(2) . .
C22 C20 C13 110.3(2) . .
C23 C20 C21 108.4(2) . .
C22 C20 C21 108.4(2) . .
C13 C20 C21 108.5(2) . .
C20 C21 H17 109.5 . .
C20 C21 H18 109.5 . .
H17 C21 H18 109.5 . .
C20 C21 H19 109.5 . .
H17 C21 H19 109.5 . .
H18 C21 H19 109.5 . .
C20 C22 H20 109.5 . .
C20 C22 H21 109.5 . .
H20 C22 H21 109.5 . .
C20 C22 H22 109.5 . .
H20 C22 H22 109.5 . .
H21 C22 H22 109.5 . .
C20 C23 H23 109.5 . .
C20 C23 H24 109.5 . .
H23 C23 H24 109.5 . .
C20 C23 H25 109.5 . .
H23 C23 H25 109.5 . .
H24 C23 H25 109.5 . .
C54 C24 C53 116.7(8) . .
C54 C24 C25 126.0(6) . .
C53 C24 C25 49.5(6) . .
C54 C24 C27 23.5(5) . .
C53 C24 C27 121.8(5) . .
C25 C24 C27 109.7(3) . .
C54 C24 C15 120.0(6) . .
C53 C24 C15 116.0(4) . .
C25 C24 C15 109.4(3) . .
C27 C24 C15 122.1(3) . .
C54 C24 C26 80.8(5) . .
C53 C24 C26 58.6(7) . .
C25 C24 C26 107.9(4) . .
C27 C24 C26 102.4(3) . .
C15 C24 C26 104.2(3) . .
C54 C24 C52 101.0(6) . .
C53 C24 C52 95.2(7) . .
C25 C24 C52 46.8(4) . .
C27 C24 C52 77.7(4) . .
C15 C24 C52 100.8(3) . .
C26 C24 C52 149.9(4) . .
C24 C25 H26 109.5 . .
C24 C25 H27 109.5 . .
H26 C25 H27 109.5 . .
C24 C25 H28 109.5 . .
H26 C25 H28 109.5 . .
H27 C25 H28 109.5 . .
C24 C26 H29 109.5 . .
C24 C26 H30 109.5 . .
H29 C26 H30 109.5 . .
C24 C26 H31 109.5 . .
H29 C26 H31 109.5 . .
H30 C26 H31 109.5 . .
C24 C27 H32 109.5 . .
C24 C27 H33 109.5 . .
H32 C27 H33 109.5 . .
C24 C27 H34 109.5 . .
H32 C27 H34 109.5 . .
H33 C27 H34 109.5 . .
C33 C28 C29 119.4(2) . .
C33 C28 P2 121.11(19) . .
C29 C28 P2 118.70(19) . .
C30 C29 C28 118.0(2) . .
C30 C29 C34 116.8(2) . .
C28 C29 C34 125.2(2) . .
C29 C30 C31 123.7(3) . .
C29 C30 H35 118.1 . .
C31 C30 H35 118.1 . .
C32 C31 C30 117.0(2) . .
C32 C31 C38 121.7(3) . .
C30 C31 C38 121.2(3) . .
C31 C32 C33 124.1(3) . .
C31 C32 H36 118.0 . .
C33 C32 H36 118.0 . .
C32 C33 C28 117.5(2) . .
C32 C33 C42 113.6(2) . .
C28 C33 C42 128.9(2) . .
C36 C34 C37 111.8(2) . .
C36 C34 C35 106.4(2) . .
C37 C34 C35 104.2(2) . .
C36 C34 C29 111.1(2) . .
C37 C34 C29 111.8(2) . .
C35 C34 C29 111.3(2) . .
C34 C35 H37 109.5 . .
C34 C35 H38 109.5 . .
H37 C35 H38 109.5 . .
C34 C35 H39 109.5 . .
H37 C35 H39 109.5 . .
H38 C35 H39 109.5 . .
C34 C36 H40 109.5 . .
C34 C36 H41 109.5 . .
H40 C36 H41 109.5 . .
C34 C36 H42 109.5 . .
H40 C36 H42 109.5 . .
H41 C36 H42 109.5 . .
C34 C37 H43 109.5 . .
C34 C37 H44 109.5 . .
H43 C37 H44 109.5 . .
C34 C37 H45 109.5 . .
H43 C37 H45 109.5 . .
H44 C37 H45 109.5 . .
C55 C38 C57 115.7(5) . .
C55 C38 C40 55.7(4) . .
C57 C38 C40 142.5(4) . .
C55 C38 C39 139.0(4) . .
C57 C38 C39 44.2(4) . .
C40 C38 C39 114.4(5) . .
C55 C38 C31 110.1(3) . .
C57 C38 C31 107.8(3) . .
C40 C38 C31 109.1(3) . .
C39 C38 C31 110.5(3) . .
C55 C38 C56 106.8(4) . .
C57 C38 C56 106.1(5) . .
C40 C38 C56 54.5(4) . .
C39 C38 C56 63.7(4) . .
C31 C38 C56 110.2(3) . .
C55 C38 C41 51.7(4) . .
C57 C38 C41 66.8(5) . .
C40 C38 C41 104.6(4) . .
C39 C38 C41 106.5(4) . .
C31 C38 C41 111.6(3) . .
C56 C38 C41 137.6(4) . .
C38 C39 H46 109.5 . .
C38 C39 H47 109.5 . .
H46 C39 H47 109.5 . .
C38 C39 H48 109.5 . .
H46 C39 H48 109.5 . .
H47 C39 H48 109.5 . .
C38 C40 H49 109.5 . .
C38 C40 H50 109.5 . .
H49 C40 H50 109.5 . .
C38 C40 H51 109.5 . .
H49 C40 H51 109.5 . .
H50 C40 H51 109.5 . .
C38 C41 H52 109.5 . .
C38 C41 H53 109.5 . .
H52 C41 H53 109.5 . .
C38 C41 H54 109.5 . .
H52 C41 H54 109.5 . .
H53 C41 H54 109.5 . .
C60 C42 C44 135.9(8) . .
C60 C42 C45 71.4(9) . .
C44 C42 C45 105.6(4) . .
C60 C42 C59 110.7(9) . .
C44 C42 C59 73.6(7) . .
C45 C42 C59 39.6(7) . .
C60 C42 C43 37.7(9) . .
C44 C42 C43 109.1(3) . .
C45 C42 C43 104.2(4) . .
C59 C42 C43 137.5(7) . .
C60 C42 C33 110.3(7) . .
C44 C42 C33 108.5(3) . .
C45 C42 C33 120.3(3) . .
C59 C42 C33 110.3(6) . .
C43 C42 C33 108.7(3) . .
C60 C42 C58 111.6(11) . .
C44 C42 C58 34.0(9) . .
C45 C42 C58 126.4(7) . .
C59 C42 C58 105.1(10) . .
C43 C42 C58 77.4(10) . .
C33 C42 C58 108.7(6) . .
C42 C43 H55 109.5 . .
C42 C43 H56 109.5 . .
H55 C43 H56 109.5 . .
C42 C43 H57 109.5 . .
H55 C43 H57 109.5 . .
H56 C43 H57 109.5 . .
C42 C44 H58 109.5 . .
C42 C44 H59 109.5 . .
H58 C44 H59 109.5 . .
C42 C44 H60 109.5 . .
H58 C44 H60 109.5 . .
H59 C44 H60 109.5 . .
C42 C45 H61 109.5 . .
C42 C45 H62 109.5 . .
H61 C45 H62 109.5 . .
C42 C45 H63 109.5 . .
H61 C45 H63 109.5 . .
H62 C45 H63 109.5 . .
C47 C46 C48 119.6(3) . 2_766
C47 C46 H64 120.2 . .
C48 C46 H64 120.2 2_766 .
C46 C47 C48 120.8(3) . .
C46 C47 H65 119.6 . .
C48 C47 H65 119.6 . .
C47 C48 C46 119.6(3) . 2_766
C47 C48 H66 120.2 . .
C46 C48 H66 120.2 2_766 .
C50 C49 H67 109.5 . .
C50 C49 H68 109.5 . .
H67 C49 H68 109.5 . .
C50 C49 H69 109.5 . .
H67 C49 H69 109.5 . .
H68 C49 H69 109.5 . .
C51 C50 C49 115.0(3) . .
C51 C50 H70 108.5 . .
C49 C50 H70 108.5 . .
C51 C50 H71 108.5 . .
C49 C50 H71 108.5 . .
H70 C50 H71 107.5 . .
C51 C51 C50 116.2(4) 2_665 .
C51 C51 H72 108.2 2_665 .
C50 C51 H72 108.2 . .
C51 C51 H73 108.2 2_665 .
C50 C51 H73 108.2 . .
H72 C51 H73 107.4 . .
C24 C52 H74 109.5 . .
C24 C52 H75 109.5 . .
H74 C52 H75 109.5 . .
C24 C52 H76 109.5 . .
H74 C52 H76 109.5 . .
H75 C52 H76 109.5 . .
C24 C53 H77 109.5 . .
C24 C53 H78 109.5 . .
H77 C53 H78 109.5 . .
C24 C53 H79 109.5 . .
H77 C53 H79 109.5 . .
H78 C53 H79 109.5 . .
C24 C54 H80 109.5 . .
C24 C54 H81 109.5 . .
H80 C54 H81 109.5 . .
C24 C54 H82 109.5 . .
H80 C54 H82 109.5 . .
H81 C54 H82 109.5 . .
C38 C55 H83 109.5 . .
C38 C55 H84 109.5 . .
H83 C55 H84 109.5 . .
C38 C55 H85 109.5 . .
H83 C55 H85 109.5 . .
H84 C55 H85 109.5 . .
C38 C56 H86 109.5 . .
C38 C56 H87 109.5 . .
H86 C56 H87 109.5 . .
C38 C56 H88 109.5 . .
H86 C56 H88 109.5 . .
H87 C56 H88 109.5 . .
C38 C57 H89 109.5 . .
C38 C57 H90 109.5 . .
H89 C57 H90 109.5 . .
C38 C57 H91 109.5 . .
H89 C57 H91 109.5 . .
H90 C57 H91 109.5 . .
C42 C58 H92 109.5 . .
C42 C58 H93 109.5 . .
H92 C58 H93 109.5 . .
C42 C58 H94 109.5 . .
H92 C58 H94 109.5 . .
H93 C58 H94 109.5 . .
C42 C59 H95 109.5 . .
C42 C59 H96 109.5 . .
H95 C59 H96 109.5 . .
C42 C59 H97 109.5 . .
H95 C59 H97 109.5 . .
H96 C59 H97 109.5 . .
C42 C60 H98 109.5 . .
C42 C60 H99 109.5 . .
H98 C60 H99 109.5 . .
C42 C60 H100 109.5 . .
H98 C60 H100 109.5 . .
H99 C60 H100 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Rh1 C1 1.892(3) .
Rh1 C2 1.921(3) .
Rh1 P2 2.2473(7) .
Rh1 P1 2.2661(7) .
C1 O1 1.133(3) .
C2 O2 1.101(3) .
P1 C3 1.774(3) .
P1 C10 1.847(3) .
C3 C4 1.421(4) .
C3 C8 1.437(3) .
C4 C5 1.367(4) .
C4 H1 0.9500 .
C5 C6 1.390(4) .
C5 H2 0.9500 .
C6 C7 1.361(4) .
C6 H3 0.9500 .
C7 C8 1.426(4) .
C7 H4 0.9500 .
C8 C9 1.428(3) .
C9 P2 1.677(3) .
C9 H5 0.9500 .
P2 C28 1.833(3) .
C10 C15 1.421(3) .
C10 C11 1.440(3) .
C11 C12 1.381(3) .
C11 C16 1.557(4) .
C12 C13 1.386(3) .
C12 H6 0.9500 .
C13 C14 1.376(3) .
C13 C20 1.537(3) .
C14 C15 1.400(3) .
C14 H7 0.9500 .
C15 C24 1.578(3) .
C16 C17 1.539(4) .
C16 C18 1.540(4) .
C16 C19 1.547(4) .
C17 H8 0.9800 .
C17 H9 0.9800 .
C17 H10 0.9800 .
C18 H11 0.9800 .
C18 H12 0.9800 .
C18 H13 0.9800 .
C19 H14 0.9800 .
C19 H15 0.9800 .
C19 H16 0.9800 .
C20 C23 1.520(4) .
C20 C22 1.537(4) .
C20 C21 1.541(4) .
C21 H17 0.9800 .
C21 H18 0.9800 .
C21 H19 0.9800 .
C22 H20 0.9800 .
C22 H21 0.9800 .
C22 H22 0.9800 .
C23 H23 0.9800 .
C23 H24 0.9800 .
C23 H25 0.9800 .
C24 C54 1.439(14) .
C24 C53 1.459(11) .
C24 C25 1.466(5) .
C24 C27 1.501(5) .
C24 C26 1.634(5) .
C24 C52 1.825(11) .
C25 H26 0.9800 .
C25 H27 0.9800 .
C25 H28 0.9800 .
C26 H29 0.9800 .
C26 H30 0.9800 .
C26 H31 0.9800 .
C27 H32 0.9800 .
C27 H33 0.9800 .
C27 H34 0.9800 .
C28 C33 1.429(4) .
C28 C29 1.433(3) .
C29 C30 1.383(3) .
C29 C34 1.565(4) .
C30 C31 1.386(4) .
C30 H35 0.9500 .
C31 C32 1.373(4) .
C31 C38 1.538(4) .
C32 C33 1.397(3) .
C32 H36 0.9500 .
C33 C42 1.558(4) .
C34 C36 1.530(4) .
C34 C37 1.535(4) .
C34 C35 1.549(4) .
C35 H37 0.9800 .
C35 H38 0.9800 .
C35 H39 0.9800 .
C36 H40 0.9800 .
C36 H41 0.9800 .
C36 H42 0.9800 .
C37 H43 0.9800 .
C37 H44 0.9800 .
C37 H45 0.9800 .
C38 C55 1.461(7) .
C38 C57 1.485(8) .
C38 C40 1.488(6) .
C38 C39 1.500(7) .
C38 C56 1.621(7) .
C38 C41 1.634(7) .
C39 H46 0.9800 .
C39 H47 0.9800 .
C39 H48 0.9800 .
C40 H49 0.9800 .
C40 H50 0.9800 .
C40 H51 0.9800 .
C41 H52 0.9800 .
C41 H53 0.9800 .
C41 H54 0.9800 .
C42 C60 1.471(18) .
C42 C44 1.518(6) .
C42 C45 1.534(6) .
C42 C59 1.536(13) .
C42 C43 1.554(6) .
C42 C58 1.560(16) .
C43 H55 0.9800 .
C43 H56 0.9800 .
C43 H57 0.9800 .
C44 H58 0.9800 .
C44 H59 0.9800 .
C44 H60 0.9800 .
C45 H61 0.9800 .
C45 H62 0.9800 .
C45 H63 0.9800 .
C46 C47 1.370(4) .
C46 C48 1.388(4) 2_766
C46 H64 0.9500 .
C47 C48 1.387(4) .
C47 H65 0.9500 .
C48 C46 1.388(4) 2_766
C48 H66 0.9500 .
C49 C50 1.536(5) .
C49 H67 0.9800 .
C49 H68 0.9800 .
C49 H69 0.9800 .
C50 C51 1.513(5) .
C50 H70 0.9900 .
C50 H71 0.9900 .
C51 C51 1.469(6) 2_665
C51 H72 0.9900 .
C51 H73 0.9900 .
C52 H74 0.9800 .
C52 H75 0.9800 .
C52 H76 0.9800 .
C53 H77 0.9800 .
C53 H78 0.9800 .
C53 H79 0.9800 .
C54 H80 0.9800 .
C54 H81 0.9800 .
C54 H82 0.9800 .
C55 H83 0.9800 .
C55 H84 0.9800 .
C55 H85 0.9800 .
C56 H86 0.9800 .
C56 H87 0.9800 .
C56 H88 0.9800 .
C57 H89 0.9800 .
C57 H90 0.9800 .
C57 H91 0.9800 .
C58 H92 0.9800 .
C58 H93 0.9800 .
C58 H94 0.9800 .
C59 H95 0.9800 .
C59 H96 0.9800 .
C59 H97 0.9800 .
C60 H98 0.9800 .
C60 H99 0.9800 .
C60 H100 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C2 Rh1 C1 O1 -89(7) . .
P2 Rh1 C1 O1 111(7) . .
P1 Rh1 C1 O1 13(8) . .
C1 Rh1 C2 O2 -94(6) . .
P2 Rh1 C2 O2 19(6) . .
P1 Rh1 C2 O2 103(6) . .
C1 Rh1 P1 C3 103.9(3) . .
C2 Rh1 P1 C3 -153.71(15) . .
P2 Rh1 P1 C3 5.67(11) . .
C1 Rh1 P1 C10 -113.4(3) . .
C2 Rh1 P1 C10 -10.98(14) . .
P2 Rh1 P1 C10 148.41(10) . .
C10 P1 C3 C4 25.8(2) . .
Rh1 P1 C3 C4 172.46(16) . .
C10 P1 C3 C8 -161.5(2) . .
Rh1 P1 C3 C8 -14.9(3) . .
C8 C3 C4 C5 -0.5(4) . .
P1 C3 C4 C5 172.7(2) . .
C3 C4 C5 C6 0.0(4) . .
C4 C5 C6 C7 0.6(4) . .
C5 C6 C7 C8 -0.5(4) . .
C6 C7 C8 C9 177.3(2) . .
C6 C7 C8 C3 -0.1(4) . .
C4 C3 C8 C7 0.6(4) . .
P1 C3 C8 C7 -172.24(19) . .
C4 C3 C8 C9 -176.6(2) . .
P1 C3 C8 C9 10.6(4) . .
C7 C8 C9 P2 -174.5(2) . .
C3 C8 C9 P2 2.7(4) . .
C8 C9 P2 C28 177.8(2) . .
C8 C9 P2 Rh1 -11.4(3) . .
C1 Rh1 P2 C9 -156.82(15) . .
C2 Rh1 P2 C9 90.6(3) . .
P1 Rh1 P2 C9 5.22(12) . .
C1 Rh1 P2 C28 11.35(15) . .
C2 Rh1 P2 C28 -101.2(3) . .
P1 Rh1 P2 C28 173.38(12) . .
C3 P1 C10 C15 73.9(2) . .
Rh1 P1 C10 C15 -75.7(2) . .
C3 P1 C10 C11 -109.8(2) . .
Rh1 P1 C10 C11 100.57(19) . .
C15 C10 C11 C12 0.2(4) . .
P1 C10 C11 C12 -176.24(19) . .
C15 C10 C11 C16 179.7(2) . .
P1 C10 C11 C16 3.3(3) . .
C10 C11 C12 C13 -0.8(4) . .
C16 C11 C12 C13 179.7(2) . .
C11 C12 C13 C14 0.5(4) . .
C11 C12 C13 C20 -179.9(2) . .
C12 C13 C14 C15 0.4(4) . .
C20 C13 C14 C15 -179.2(3) . .
C13 C14 C15 C10 -0.9(4) . .
C13 C14 C15 C24 178.3(3) . .
C11 C10 C15 C14 0.6(4) . .
P1 C10 C15 C14 176.8(2) . .
C11 C10 C15 C24 -178.5(3) . .
P1 C10 C15 C24 -2.3(4) . .
C12 C11 C16 C17 -125.7(3) . .
C10 C11 C16 C17 54.8(3) . .
C12 C11 C16 C18 109.5(3) . .
C10 C11 C16 C18 -70.0(3) . .
C12 C11 C16 C19 -7.7(3) . .
C10 C11 C16 C19 172.8(3) . .
C14 C13 C20 C23 -4.9(4) . .
C12 C13 C20 C23 175.5(3) . .
C14 C13 C20 C22 -126.6(3) . .
C12 C13 C20 C22 53.8(3) . .
C14 C13 C20 C21 114.9(3) . .
C12 C13 C20 C21 -64.7(3) . .
C14 C15 C24 C54 148.9(6) . .
C10 C15 C24 C54 -32.0(7) . .
C14 C15 C24 C53 -0.2(8) . .
C10 C15 C24 C53 179.0(8) . .
C14 C15 C24 C25 -53.8(4) . .
C10 C15 C24 C25 125.4(4) . .
C14 C15 C24 C27 176.3(4) . .
C10 C15 C24 C27 -4.6(5) . .
C14 C15 C24 C26 61.4(3) . .
C10 C15 C24 C26 -119.4(3) . .
C14 C15 C24 C52 -101.6(4) . .
C10 C15 C24 C52 77.6(5) . .
C9 P2 C28 C33 76.8(2) . .
Rh1 P2 C28 C33 -93.3(2) . .
C9 P2 C28 C29 -93.1(2) . .
Rh1 P2 C28 C29 96.7(2) . .
C33 C28 C29 C30 -5.8(4) . .
P2 C28 C29 C30 164.3(2) . .
C33 C28 C29 C34 174.6(2) . .
P2 C28 C29 C34 -15.3(4) . .
C28 C29 C30 C31 2.2(4) . .
C34 C29 C30 C31 -178.1(2) . .
C29 C30 C31 C32 2.0(4) . .
C29 C30 C31 C38 -178.9(2) . .
C30 C31 C32 C33 -2.8(4) . .
C38 C31 C32 C33 178.2(3) . .
C31 C32 C33 C28 -0.7(4) . .
C31 C32 C33 C42 179.3(3) . .
C29 C28 C33 C32 5.1(4) . .
P2 C28 C33 C32 -164.8(2) . .
C29 C28 C33 C42 -175.0(3) . .
P2 C28 C33 C42 15.2(4) . .
C30 C29 C34 C36 -104.7(3) . .
C28 C29 C34 C36 74.9(3) . .
C30 C29 C34 C37 129.7(3) . .
C28 C29 C34 C37 -50.7(4) . .
C30 C29 C34 C35 13.7(3) . .
C28 C29 C34 C35 -166.7(3) . .
C32 C31 C38 C55 -122.5(4) . .
C30 C31 C38 C55 58.5(5) . .
C32 C31 C38 C57 110.4(5) . .
C30 C31 C38 C57 -68.6(6) . .
C32 C31 C38 C40 -63.0(5) . .
C30 C31 C38 C40 118.0(4) . .
C32 C31 C38 C39 63.6(5) . .
C30 C31 C38 C39 -115.4(4) . .
C32 C31 C38 C56 -4.9(5) . .
C30 C31 C38 C56 176.1(4) . .
C32 C31 C38 C41 -178.1(3) . .
C30 C31 C38 C41 2.9(4) . .
C32 C33 C42 C60 100.1(12) . .
C28 C33 C42 C60 -79.9(13) . .
C32 C33 C42 C44 -58.5(4) . .
C28 C33 C42 C44 121.5(4) . .
C32 C33 C42 C45 179.9(5) . .
C28 C33 C42 C45 0.0(6) . .
C32 C33 C42 C59 -137.4(10) . .
C28 C33 C42 C59 42.7(10) . .
C32 C33 C42 C43 60.0(4) . .
C28 C33 C42 C43 -119.9(4) . .
C32 C33 C42 C58 -22.6(13) . .
C28 C33 C42 C58 157.5(13) . .
C48 C46 C47 C48 -0.9(5) 2_766 .
C46 C47 C48 C46 0.9(5) . 2_766
C49 C50 C51 C51 -178.5(4) . 2_665
