#------------------------------------------------------------------------------
#$Date: 2015-07-05 13:56:24 +0300 (Sun, 05 Jul 2015) $
#$Revision: 140249 $
#$URL: svn://www.crystallography.net/cod/cif/4/08/57/4085700.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4085700
loop_
_publ_author_name
'Raphael Karikachery, Alice'
'Masjedi, Mehdi'
'Sharp, Paul R.'
_publ_section_title
;
 Thermal and Photochemical Ring-Bromination in Naphthyl-, Naphthdiyl-, and
 Dicarboximideperyl-Platinum Complexes
;
_journal_issue                   9
_journal_name_full               Organometallics
_journal_page_first              1635
_journal_paper_doi               10.1021/om501322f
_journal_volume                  34
_journal_year                    2015
_chemical_formula_sum            'C34 H66 Br2 P4 Pt2'
_chemical_formula_weight         1148.74
_chemical_name_systematic
;
 ?
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2014
_cell_angle_alpha                90.00
_cell_angle_beta                 99.486(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   23.456(4)
_cell_length_b                   12.643(2)
_cell_length_c                   14.518(3)
_cell_measurement_reflns_used    9905
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      27.6
_cell_measurement_theta_min      2.2
_cell_volume                     4246.5(13)
_computing_cell_refinement       'APEX2 (Bruker AXS, 2008)'
_computing_data_collection       'APEX2 (Bruker AXS, 2008)'
_computing_data_reduction        'APEX2 (Bruker AXS, 2008)'
_computing_molecular_graphics    'X-SEED, Barbour, 2001'
_computing_publication_material  'CIFTAB (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-2014 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker APEXII CCD area detector'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0376
_diffrn_reflns_av_unetI/netI     0.0293
_diffrn_reflns_laue_measured_fraction_full 1.000
_diffrn_reflns_laue_measured_fraction_max 0.995
_diffrn_reflns_limit_h_max       30
_diffrn_reflns_limit_h_min       -30
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            48984
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.588
_diffrn_reflns_theta_min         1.760
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    8.635
_exptl_absorpt_correction_T_max  0.67
_exptl_absorpt_correction_T_min  0.38
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
 Data were corrected for decay and absorption using the program SADABS 
 (Sheldrick, G. M. (2003). SADABS. Version 2.10. University of
 Göttingen, Germany).
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.797
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             2224
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.05
_refine_diff_density_max         3.160
_refine_diff_density_min         -1.443
_refine_diff_density_rms         0.113
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.017
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     391
_refine_ls_number_reflns         9789
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.017
_refine_ls_R_factor_all          0.0300
_refine_ls_R_factor_gt           0.0237
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0252P)²+6.8095P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0553
_refine_ls_wR_factor_ref         0.0580
_reflns_Friedel_coverage         0.000
_reflns_number_gt                8657
_reflns_number_total             9789
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            om501322f_si_002.cif
_cod_data_source_block           '[trans-Pt(PEt3)2(Br)]2(1,4-naphthdiyl)_9'
_cod_depositor_comments
'Adding full bibliography for 4085699--4085702.cif.'
_cod_original_cell_volume        4246.6(13)
_cod_database_code               4085700
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.182
_shelx_estimated_absorpt_t_max   0.672
_shelxl_version_number           2014-3
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
Pt1 Pt 0.37810(2) 0.10810(2) 0.14989(2) 0.02013(4) Uani 1 1 d . .
Br1 Br 0.47874(2) 0.15133(3) 0.23304(3) 0.03214(8) Uani 1 1 d . .
P1 P 0.35576(4) 0.28206(7) 0.11359(7) 0.02578(19) Uani 1 1 d . .
C1 C 0.30019(14) 0.0698(2) 0.0739(2) 0.0213(7) Uani 1 1 d . .
Pt2 Pt 0.11868(2) -0.02823(2) -0.12838(2) 0.02202(4) Uani 1 1 d . .
Br2 Br 0.02982(2) -0.07699(3) -0.24453(3) 0.03937(10) Uani 1 1 d . .
P2 P 0.40094(4) -0.06804(7) 0.17523(6) 0.02306(18) Uani 1 1 d . .
C2 C 0.29452(14) 0.0626(3) -0.0213(2) 0.0232(7) Uani 1 1 d . .
H2 H 0.3274 0.0757 -0.0501 0.028 Uiso 1 1 calc R U
P3 P 0.08634(4) 0.14402(7) -0.13756(6) 0.02423(18) Uani 1 1 d . .
C3 C 0.24158(15) 0.0364(3) -0.0782(2) 0.0242(7) Uani 1 1 d . .
H3 H 0.2399 0.0345 -0.1440 0.029 Uiso 1 1 calc R U
P4 P 0.15095(4) -0.19980(7) -0.13434(7) 0.02692(19) Uani 1 1 d . .
C4 C 0.19223(14) 0.0135(2) -0.0418(2) 0.0205(6) Uani 1 1 d . .
C5 C 0.14748(15) 0.0018(3) 0.1019(2) 0.0253(7) Uani 1 1 d . .
H5 H 0.1124 -0.0215 0.0652 0.030 Uiso 1 1 calc R U
C6 C 0.14924(16) 0.0164(3) 0.1953(3) 0.0279(8) Uani 1 1 d . .
H6 H 0.1155 0.0052 0.2224 0.033 Uiso 1 1 calc R U
C7 C 0.20132(16) 0.0481(3) 0.2518(3) 0.0292(8) Uani 1 1 d . .
H7 H 0.2027 0.0588 0.3168 0.035 Uiso 1 1 calc R U
C8 C 0.24987(15) 0.0634(3) 0.2123(2) 0.0256(7) Uani 1 1 d . .
H8 H 0.2849 0.0831 0.2512 0.031 Uiso 1 1 calc R U
C9 C 0.24958(14) 0.0507(2) 0.1152(2) 0.0192(6) Uani 1 1 d . .
C10 C 0.19625(14) 0.0203(2) 0.0572(2) 0.0208(7) Uani 1 1 d . .
C11 C 0.3707(2) 0.3164(3) -0.0033(3) 0.0430(10) Uani 1 1 d . .
H11A H 0.3464 0.2719 -0.0504 0.052 Uiso 1 1 calc R U
H11B H 0.3599 0.3911 -0.0168 0.052 Uiso 1 1 calc R U
C12 C 0.4332(2) 0.3010(5) -0.0121(4) 0.0627(15) Uani 1 1 d . .
H12A H 0.4574 0.3469 0.0327 0.094 Uiso 1 1 calc R U
H12B H 0.4388 0.3191 -0.0756 0.094 Uiso 1 1 calc R U
H12C H 0.4441 0.2270 0.0009 0.094 Uiso 1 1 calc R U
C13 C 0.39363(18) 0.3845(3) 0.1870(3) 0.0371(9) Uani 1 1 d . .
H13A H 0.4358 0.3721 0.1932 0.045 Uiso 1 1 calc R U
H13B H 0.3851 0.4539 0.1563 0.045 Uiso 1 1 calc R U
C14 C 0.3772(2) 0.3881(5) 0.2830(3) 0.0579(14) Uani 1 1 d . .
H14A H 0.3358 0.4034 0.2776 0.087 Uiso 1 1 calc R U
H14B H 0.3995 0.4436 0.3199 0.087 Uiso 1 1 calc R U
H14C H 0.3856 0.3196 0.3138 0.087 Uiso 1 1 calc R U
C15 C 0.27902(17) 0.3160(3) 0.1072(3) 0.0383(9) Uani 1 1 d . .
H15A H 0.2561 0.2687 0.0608 0.046 Uiso 1 1 calc R U
H15B H 0.2678 0.3003 0.1686 0.046 Uiso 1 1 calc R U
C16 C 0.2618(2) 0.4290(4) 0.0817(4) 0.0549(13) Uani 1 1 d . .
H16A H 0.2833 0.4772 0.1277 0.082 Uiso 1 1 calc R U
H16B H 0.2202 0.4378 0.0812 0.082 Uiso 1 1 calc R U
H16C H 0.2708 0.4452 0.0196 0.082 Uiso 1 1 calc R U
C17 C 0.45640(16) -0.1087(3) 0.1078(3) 0.0320(8) Uani 1 1 d . .
H17A H 0.4915 -0.0652 0.1269 0.038 Uiso 1 1 calc R U
H17B H 0.4668 -0.1834 0.1225 0.038 Uiso 1 1 calc R U
C18 C 0.4369(2) -0.0974(4) 0.0028(3) 0.0519(12) Uani 1 1 d . .
H18A H 0.4041 -0.1446 -0.0174 0.078 Uiso 1 1 calc R U
H18B H 0.4688 -0.1163 -0.0299 0.078 Uiso 1 1 calc R U
H18C H 0.4252 -0.0241 -0.0119 0.078 Uiso 1 1 calc R U
C19 C 0.43214(16) -0.1003(3) 0.2958(3) 0.0299(8) Uani 1 1 d . .
H19A H 0.4449 -0.1750 0.2987 0.036 Uiso 1 1 calc R U
H19B H 0.4667 -0.0557 0.3151 0.036 Uiso 1 1 calc R U
C20 C 0.3907(2) -0.0842(4) 0.3642(3) 0.0557(13) Uani 1 1 d . .
H20A H 0.3743 -0.0128 0.3566 0.084 Uiso 1 1 calc R U
H20B H 0.4115 -0.0927 0.4281 0.084 Uiso 1 1 calc R U
H20C H 0.3595 -0.1365 0.3522 0.084 Uiso 1 1 calc R U
C21 C 0.34267(17) -0.1648(3) 0.1450(3) 0.0338(9) Uani 1 1 d . .
H21A H 0.3124 -0.1501 0.1833 0.041 Uiso 1 1 calc R U
H21B H 0.3252 -0.1543 0.0787 0.041 Uiso 1 1 calc R U
C22 C 0.3607(2) -0.2803(3) 0.1587(4) 0.0482(12) Uani 1 1 d . .
H22A H 0.3901 -0.2967 0.1200 0.072 Uiso 1 1 calc R U
H22B H 0.3269 -0.3259 0.1403 0.072 Uiso 1 1 calc R U
H22C H 0.3767 -0.2927 0.2245 0.072 Uiso 1 1 calc R U
C23 C 0.13184(16) 0.2428(3) -0.0684(3) 0.0301(8) Uani 1 1 d . .
H23A H 0.1392 0.2191 -0.0025 0.036 Uiso 1 1 calc R U
H23B H 0.1695 0.2456 -0.0905 0.036 Uiso 1 1 calc R U
C24 C 0.10659(19) 0.3549(3) -0.0719(3) 0.0372(9) Uani 1 1 d . .
H24A H 0.0986 0.3792 -0.1368 0.056 Uiso 1 1 calc R U
H24B H 0.1344 0.4028 -0.0353 0.056 Uiso 1 1 calc R U
H24C H 0.0706 0.3544 -0.0458 0.056 Uiso 1 1 calc R U
C25 C 0.07894(18) 0.1921(3) -0.2576(3) 0.0349(9) Uani 1 1 d . .
H25A H 0.0473 0.1530 -0.2969 0.042 Uiso 1 1 calc R U
H25B H 0.0682 0.2679 -0.2592 0.042 Uiso 1 1 calc R U
C26 C 0.1340(2) 0.1789(4) -0.2980(3) 0.0474(11) Uani 1 1 d . .
H26A H 0.1655 0.2175 -0.2594 0.071 Uiso 1 1 calc R U
H26B H 0.1283 0.2071 -0.3618 0.071 Uiso 1 1 calc R U
H26C H 0.1439 0.1037 -0.2991 0.071 Uiso 1 1 calc R U
C27 C 0.01489(16) 0.1607(3) -0.1044(3) 0.0342(9) Uani 1 1 d . .
H27A H 0.0006 0.2328 -0.1218 0.041 Uiso 1 1 calc R U
H27B H -0.0122 0.1096 -0.1400 0.041 Uiso 1 1 calc R U
C28 C 0.01528(19) 0.1441(4) -0.0005(3) 0.0490(11) Uani 1 1 d . .
H28A H 0.0345 0.0770 0.0190 0.074 Uiso 1 1 calc R U
H28B H -0.0246 0.1423 0.0117 0.074 Uiso 1 1 calc R U
H28C H 0.0362 0.2023 0.0346 0.074 Uiso 1 1 calc R U
C29 C 0.21862(17) -0.2312(3) -0.0584(3) 0.0329(8) Uani 1 1 d . .
H29A H 0.2482 -0.1794 -0.0706 0.039 Uiso 1 1 calc R U
H29B H 0.2130 -0.2216 0.0071 0.039 Uiso 1 1 calc R U
C30 C 0.2424(2) -0.3424(3) -0.0685(3) 0.0465(11) Uani 1 1 d . .
H30A H 0.2138 -0.3948 -0.0563 0.070 Uiso 1 1 calc R U
H30B H 0.2781 -0.3518 -0.0237 0.070 Uiso 1 1 calc R U
H30C H 0.2505 -0.3519 -0.1321 0.070 Uiso 1 1 calc R U
C31 C 0.10054(19) -0.3044(3) -0.1118(3) 0.0390(9) Uani 1 1 d . .
H31A H 0.0612 -0.2851 -0.1432 0.047 Uiso 1 1 calc R U
H31B H 0.1115 -0.3710 -0.1402 0.047 Uiso 1 1 calc R U
C32 C 0.0989(2) -0.3242(4) -0.0085(3) 0.0500(12) Uani 1 1 d . .
H32A H 0.1334 -0.3638 0.0192 0.075 Uiso 1 1 calc R U
H32B H 0.0642 -0.3651 -0.0022 0.075 Uiso 1 1 calc R U
H32C H 0.0979 -0.2563 0.0239 0.075 Uiso 1 1 calc R U
C33 C 0.1640(2) -0.2306(3) -0.2525(3) 0.0383(9) Uani 1 1 d . .
H33A H 0.1771 -0.3049 -0.2542 0.046 Uiso 1 1 calc R U
H33B H 0.1272 -0.2240 -0.2966 0.046 Uiso 1 1 calc R U
C34 C 0.2085(2) -0.1591(4) -0.2843(3) 0.0505(12) Uani 1 1 d . .
H34A H 0.1944 -0.0860 -0.2875 0.076 Uiso 1 1 calc R U
H34B H 0.2153 -0.1814 -0.3462 0.076 Uiso 1 1 calc R U
H34C H 0.2447 -0.1634 -0.2398 0.076 Uiso 1 1 calc R U
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
C1 Pt1 P1 87.30(9)
C1 Pt1 P2 91.20(9)
P1 Pt1 P2 175.92(3)
C1 Pt1 Br1 175.29(10)
P1 Pt1 Br1 93.57(3)
P2 Pt1 Br1 87.62(2)
C13 P1 C15 104.11(19)
C13 P1 C11 103.0(2)
C15 P1 C11 103.4(2)
C13 P1 Pt1 118.46(14)
C15 P1 Pt1 114.76(13)
C11 P1 Pt1 111.44(14)
C2 C1 C9 117.5(3)
C2 C1 Pt1 119.5(2)
C9 C1 Pt1 123.0(2)
C4 Pt2 P3 91.61(9)
C4 Pt2 P4 90.98(9)
P3 Pt2 P4 174.53(3)
C4 Pt2 Br2 176.58(10)
P3 Pt2 Br2 87.97(3)
P4 Pt2 Br2 89.15(3)
C17 P2 C19 104.01(17)
C17 P2 C21 104.64(19)
C19 P2 C21 104.22(18)
C17 P2 Pt1 110.72(13)
C19 P2 Pt1 114.45(13)
C21 P2 Pt1 117.51(12)
C1 C2 C3 122.4(3)
C1 C2 H2 118.8
C3 C2 H2 118.8
C25 P3 C27 105.39(18)
C25 P3 C23 104.57(18)
C27 P3 C23 104.69(18)
C25 P3 Pt2 110.39(13)
C27 P3 Pt2 113.62(13)
C23 P3 Pt2 117.17(12)
C4 C3 C2 122.5(3)
C4 C3 H3 118.8
C2 C3 H3 118.8
C29 P4 C33 104.90(19)
C29 P4 C31 104.93(19)
C33 P4 C31 103.00(19)
C29 P4 Pt2 116.21(12)
C33 P4 Pt2 109.97(14)
C31 P4 Pt2 116.45(15)
C3 C4 C10 116.9(3)
C3 C4 Pt2 119.9(2)
C10 C4 Pt2 123.2(2)
C6 C5 C10 122.5(3)
C6 C5 H5 118.8
C10 C5 H5 118.8
C5 C6 C7 119.8(3)
C5 C6 H6 120.1
C7 C6 H6 120.1
C8 C7 C6 119.7(3)
C8 C7 H7 120.1
C6 C7 H7 120.1
C7 C8 C9 122.1(3)
C7 C8 H8 118.9
C9 C8 H8 118.9
C8 C9 C1 121.9(3)
C8 C9 C10 118.3(3)
C1 C9 C10 119.9(3)
C5 C10 C4 121.6(3)
C5 C10 C9 117.5(3)
C4 C10 C9 120.8(3)
C12 C11 P1 112.6(3)
C12 C11 H11A 109.1
P1 C11 H11A 109.1
C12 C11 H11B 109.1
P1 C11 H11B 109.1
H11A C11 H11B 107.8
C11 C12 H12A 109.5
C11 C12 H12B 109.5
H12A C12 H12B 109.5
C11 C12 H12C 109.5
H12A C12 H12C 109.5
H12B C12 H12C 109.5
C14 C13 P1 113.0(3)
C14 C13 H13A 109.0
P1 C13 H13A 109.0
C14 C13 H13B 109.0
P1 C13 H13B 109.0
H13A C13 H13B 107.8
C13 C14 H14A 109.5
C13 C14 H14B 109.5
H14A C14 H14B 109.5
C13 C14 H14C 109.5
H14A C14 H14C 109.5
H14B C14 H14C 109.5
C16 C15 P1 116.9(3)
C16 C15 H15A 108.1
P1 C15 H15A 108.1
C16 C15 H15B 108.1
P1 C15 H15B 108.1
H15A C15 H15B 107.3
C15 C16 H16A 109.5
C15 C16 H16B 109.5
H16A C16 H16B 109.5
C15 C16 H16C 109.5
H16A C16 H16C 109.5
H16B C16 H16C 109.5
C18 C17 P2 112.7(3)
C18 C17 H17A 109.0
P2 C17 H17A 109.0
C18 C17 H17B 109.0
P2 C17 H17B 109.0
H17A C17 H17B 107.8
C17 C18 H18A 109.5
C17 C18 H18B 109.5
H18A C18 H18B 109.5
C17 C18 H18C 109.5
H18A C18 H18C 109.5
H18B C18 H18C 109.5
C20 C19 P2 113.5(3)
C20 C19 H19A 108.9
P2 C19 H19A 108.9
C20 C19 H19B 108.9
P2 C19 H19B 108.9
H19A C19 H19B 107.7
C19 C20 H20A 109.5
C19 C20 H20B 109.5
H20A C20 H20B 109.5
C19 C20 H20C 109.5
H20A C20 H20C 109.5
H20B C20 H20C 109.5
C22 C21 P2 115.4(3)
C22 C21 H21A 108.4
P2 C21 H21A 108.4
C22 C21 H21B 108.4
P2 C21 H21B 108.4
H21A C21 H21B 107.5
C21 C22 H22A 109.5
C21 C22 H22B 109.5
H22A C22 H22B 109.5
C21 C22 H22C 109.5
H22A C22 H22C 109.5
H22B C22 H22C 109.5
C24 C23 P3 115.2(3)
C24 C23 H23A 108.5
P3 C23 H23A 108.5
C24 C23 H23B 108.5
P3 C23 H23B 108.5
H23A C23 H23B 107.5
C23 C24 H24A 109.5
C23 C24 H24B 109.5
H24A C24 H24B 109.5
C23 C24 H24C 109.5
H24A C24 H24C 109.5
H24B C24 H24C 109.5
C26 C25 P3 112.4(3)
C26 C25 H25A 109.1
P3 C25 H25A 109.1
C26 C25 H25B 109.1
P3 C25 H25B 109.1
H25A C25 H25B 107.9
C25 C26 H26A 109.5
C25 C26 H26B 109.5
H26A C26 H26B 109.5
C25 C26 H26C 109.5
H26A C26 H26C 109.5
H26B C26 H26C 109.5
C28 C27 P3 112.9(3)
C28 C27 H27A 109.0
P3 C27 H27A 109.0
C28 C27 H27B 109.0
P3 C27 H27B 109.0
H27A C27 H27B 107.8
C27 C28 H28A 109.5
C27 C28 H28B 109.5
H28A C28 H28B 109.5
C27 C28 H28C 109.5
H28A C28 H28C 109.5
H28B C28 H28C 109.5
C30 C29 P4 116.0(3)
C30 C29 H29A 108.3
P4 C29 H29A 108.3
C30 C29 H29B 108.3
P4 C29 H29B 108.3
H29A C29 H29B 107.4
C29 C30 H30A 109.5
C29 C30 H30B 109.5
H30A C30 H30B 109.5
C29 C30 H30C 109.5
H30A C30 H30C 109.5
H30B C30 H30C 109.5
C32 C31 P4 114.4(3)
C32 C31 H31A 108.6
P4 C31 H31A 108.6
C32 C31 H31B 108.6
P4 C31 H31B 108.6
H31A C31 H31B 107.6
C31 C32 H32A 109.5
C31 C32 H32B 109.5
H32A C32 H32B 109.5
C31 C32 H32C 109.5
H32A C32 H32C 109.5
H32B C32 H32C 109.5
C34 C33 P4 112.9(3)
C34 C33 H33A 109.0
P4 C33 H33A 109.0
C34 C33 H33B 109.0
P4 C33 H33B 109.0
H33A C33 H33B 107.8
C33 C34 H34A 109.5
C33 C34 H34B 109.5
H34A C34 H34B 109.5
C33 C34 H34C 109.5
H34A C34 H34C 109.5
H34B C34 H34C 109.5
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
Pt1 C1 2.032(3)
Pt1 P1 2.3019(10)
Pt1 P2 2.3058(10)
Pt1 Br1 2.5277(5)
P1 C13 1.814(4)
P1 C15 1.838(4)
P1 C11 1.840(4)
C1 C2 1.369(5)
C1 C9 1.436(5)
Pt2 C4 2.030(3)
Pt2 P3 2.3027(10)
Pt2 P4 2.3038(10)
Pt2 Br2 2.5317(5)
P2 C17 1.826(4)
P2 C19 1.829(4)
P2 C21 1.833(4)
C2 C3 1.413(5)
C2 H2 0.9500
P3 C25 1.827(4)
P3 C27 1.830(4)
P3 C23 1.832(4)
C3 C4 1.381(5)
C3 H3 0.9500
P4 C29 1.821(4)
P4 C33 1.833(4)
P4 C31 1.838(4)
C4 C10 1.427(5)
C5 C6 1.362(5)
C5 C10 1.425(5)
C5 H5 0.9500
C6 C7 1.413(5)
C6 H6 0.9500
C7 C8 1.370(5)
C7 H7 0.9500
C8 C9 1.417(5)
C8 H8 0.9500
C9 C10 1.441(4)
C11 C12 1.504(7)
C11 H11A 0.9900
C11 H11B 0.9900
C12 H12A 0.9800
C12 H12B 0.9800
C12 H12C 0.9800
C13 C14 1.506(6)
C13 H13A 0.9900
C13 H13B 0.9900
C14 H14A 0.9800
C14 H14B 0.9800
C14 H14C 0.9800
C15 C16 1.514(6)
C15 H15A 0.9900
C15 H15B 0.9900
C16 H16A 0.9800
C16 H16B 0.9800
C16 H16C 0.9800
C17 C18 1.525(6)
C17 H17A 0.9900
C17 H17B 0.9900
C18 H18A 0.9800
C18 H18B 0.9800
C18 H18C 0.9800
C19 C20 1.513(6)
C19 H19A 0.9900
C19 H19B 0.9900
C20 H20A 0.9800
C20 H20B 0.9800
C20 H20C 0.9800
C21 C22 1.525(5)
C21 H21A 0.9900
C21 H21B 0.9900
C22 H22A 0.9800
C22 H22B 0.9800
C22 H22C 0.9800
C23 C24 1.534(5)
C23 H23A 0.9900
C23 H23B 0.9900
C24 H24A 0.9800
C24 H24B 0.9800
C24 H24C 0.9800
C25 C26 1.514(6)
C25 H25A 0.9900
C25 H25B 0.9900
C26 H26A 0.9800
C26 H26B 0.9800
C26 H26C 0.9800
C27 C28 1.521(6)
C27 H27A 0.9900
C27 H27B 0.9900
C28 H28A 0.9800
C28 H28B 0.9800
C28 H28C 0.9800
C29 C30 1.528(5)
C29 H29A 0.9900
C29 H29B 0.9900
C30 H30A 0.9800
C30 H30B 0.9800
C30 H30C 0.9800
C31 C32 1.528(6)
C31 H31A 0.9900
C31 H31B 0.9900
C32 H32A 0.9800
C32 H32B 0.9800
C32 H32C 0.9800
C33 C34 1.511(6)
C33 H33A 0.9900
C33 H33B 0.9900
C34 H34A 0.9800
C34 H34B 0.9800
C34 H34C 0.9800
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C9 C1 C2 C3 -0.7(5)
Pt1 C1 C2 C3 -179.9(3)
C1 C2 C3 C4 -1.7(5)
C2 C3 C4 C10 1.8(5)
C2 C3 C4 Pt2 -177.9(3)
C10 C5 C6 C7 -1.8(5)
C5 C6 C7 C8 -0.5(5)
C6 C7 C8 C9 1.5(5)
C7 C8 C9 C1 178.2(3)
C7 C8 C9 C10 -0.3(5)
C2 C1 C9 C8 -175.5(3)
Pt1 C1 C9 C8 3.7(4)
C2 C1 C9 C10 2.9(5)
Pt1 C1 C9 C10 -177.9(2)
C6 C5 C10 C4 -174.5(3)
C6 C5 C10 C9 3.0(5)
C3 C4 C10 C5 177.9(3)
Pt2 C4 C10 C5 -2.5(4)
C3 C4 C10 C9 0.5(5)
Pt2 C4 C10 C9 -179.8(2)
C8 C9 C10 C5 -1.9(4)
C1 C9 C10 C5 179.7(3)
C8 C9 C10 C4 175.6(3)
C1 C9 C10 C4 -2.8(5)
C13 P1 C11 C12 68.2(4)
C15 P1 C11 C12 176.4(4)
Pt1 P1 C11 C12 -59.8(4)
C15 P1 C13 C14 59.5(4)
C11 P1 C13 C14 167.2(3)
Pt1 P1 C13 C14 -69.4(4)
C13 P1 C15 C16 50.1(4)
C11 P1 C15 C16 -57.3(4)
Pt1 P1 C15 C16 -178.8(3)
C19 P2 C17 C18 175.0(3)
C21 P2 C17 C18 65.9(3)
Pt1 P2 C17 C18 -61.6(3)
C17 P2 C19 C20 -173.7(3)
C21 P2 C19 C20 -64.3(4)
Pt1 P2 C19 C20 65.4(3)
C17 P2 C21 C22 53.9(4)
C19 P2 C21 C22 -55.0(4)
Pt1 P2 C21 C22 177.2(3)
C25 P3 C23 C24 61.2(3)
C27 P3 C23 C24 -49.3(3)
Pt2 P3 C23 C24 -176.2(2)
C27 P3 C25 C26 -177.2(3)
C23 P3 C25 C26 72.8(3)
Pt2 P3 C25 C26 -54.1(3)
C25 P3 C27 C28 -169.2(3)
C23 P3 C27 C28 -59.2(3)
Pt2 P3 C27 C28 69.8(3)
C33 P4 C29 C30 -53.5(4)
C31 P4 C29 C30 54.7(4)
Pt2 P4 C29 C30 -175.1(3)
C29 P4 C31 C32 49.1(4)
C33 P4 C31 C32 158.7(3)
Pt2 P4 C31 C32 -80.9(3)
C29 P4 C33 C34 -65.9(4)
C31 P4 C33 C34 -175.5(3)
Pt2 P4 C33 C34 59.7(4)
