#------------------------------------------------------------------------------
#$Date: 2016-03-21 18:11:13 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178804 $
#$URL: svn://www.crystallography.net/cod/cif/4/10/58/4105877.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4105877
loop_
_publ_author_name
'Vladimir Ya. Lee'
'Yuki Ito'
'Hiroyuki Yasuda'
'Kazunori Takanashi'
'Akira Sekiguchi'
_publ_section_title
;
 From Tetragermacyclobutene to Tetragermacyclobutadiene Dianion to
 Tetragermacyclobutadiene Transition Metal Complexes
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              5103
_journal_page_last               5108
_journal_paper_doi               10.1021/ja111596g
_journal_volume                  133
_journal_year                    2011
_chemical_formula_sum            'C36 H84 Cl2 Ge4 Si4'
_chemical_formula_weight         990.65
_chemical_name_systematic
; 
 dichlorotetragermetene
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 112.773(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   41.2970(9)
_cell_length_b                   15.6660(7)
_cell_length_c                   17.2710(7)
_cell_measurement_reflns_used    51989
_cell_measurement_temperature    150
_cell_measurement_theta_max      27.94
_cell_measurement_theta_min      2.06
_cell_volume                     10302.6(7)
_computing_cell_refinement       'HKL scalepack'
_computing_data_collection       'MacScience Xpress'
_computing_data_reduction        Denzo
_computing_molecular_graphics    ORTEP
_computing_publication_material  CIFTAB
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    SIR92
_diffrn_ambient_temperature      150
_diffrn_measured_fraction_theta_full 0.951
_diffrn_measured_fraction_theta_max 0.951
_diffrn_measurement_device       'MacScience DIP2030 Image plate'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.051
_diffrn_reflns_av_sigmaI/netI    0.0432
_diffrn_reflns_limit_h_max       53
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            51989
_diffrn_reflns_theta_full        27.94
_diffrn_reflns_theta_max         27.94
_diffrn_reflns_theta_min         2.06
_exptl_absorpt_coefficient_mu    2.530
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.277
_exptl_crystal_description       cube
_exptl_crystal_F_000             4144
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.35
_exptl_crystal_size_min          0.3
_refine_diff_density_max         1.006
_refine_diff_density_min         -1.063
_refine_diff_density_rms         0.099
_refine_ls_extinction_coef       0.00133(7)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   0.997
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     488
_refine_ls_number_reflns         11764
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.997
_refine_ls_R_factor_all          0.0613
_refine_ls_R_factor_gt           0.0432
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0783P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1108
_refine_ls_wR_factor_ref         0.1203
_reflns_number_gt                8979
_reflns_number_total             11764
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ja111596g_si_004.cif
_cod_data_source_block           shelxl
_cod_original_sg_symbol_H-M      'C 2/c '
_cod_database_code               4105877
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ge1 Ge 0.589651(9) 0.26797(3) 0.51879(2) 0.03528(10) Uani 1 1 d .
Ge2 Ge 0.642171(8) 0.21472(2) 0.52286(2) 0.03125(10) Uani 1 1 d .
Ge3 Ge 0.674281(8) 0.32765(2) 0.61626(2) 0.02711(9) Uani 1 1 d .
Ge4 Ge 0.617324(8) 0.40361(2) 0.57116(2) 0.03004(10) Uani 1 1 d .
Cl1 Cl 0.71689(2) 0.39218(6) 0.58722(6) 0.0418(2) Uani 1 1 d .
Cl2 Cl 0.60283(2) 0.45677(6) 0.67436(5) 0.03856(19) Uani 1 1 d .
Si1 Si 0.53640(4) 0.23084(13) 0.53107(11) 0.0309(3) Uani 0.55 1 d P
Si2 Si 0.66068(2) 0.12329(7) 0.43592(6) 0.0388(2) Uani 1 1 d .
Si3 Si 0.70058(2) 0.28525(6) 0.76231(5) 0.02667(18) Uani 1 1 d .
Si4 Si 0.61040(2) 0.51646(7) 0.46914(6) 0.0350(2) Uani 1 1 d .
Si5 Si 0.54112(5) 0.17662(16) 0.52863(13) 0.0297(4) Uani 0.45 1 d P
C1 C 0.51675(18) 0.3298(4) 0.5558(5) 0.0459(17) Uani 0.55 1 d P
H1A H 0.5109 0.3690 0.5097 0.069 Uiso 0.55 1 calc PR
H1B H 0.5334 0.3559 0.6056 0.069 Uiso 0.55 1 calc PR
H1C H 0.4959 0.3151 0.5648 0.069 Uiso 0.55 1 calc PR
C2 C 0.50363(9) 0.1858(2) 0.4242(2) 0.0411(8) Uani 1 1 d .
C3 C 0.4675(3) 0.1788(8) 0.4171(8) 0.060(3) Uani 0.55 1 d P
H3A H 0.4596 0.2333 0.4283 0.090 Uiso 0.55 1 calc PR
H3B H 0.4662 0.1377 0.4570 0.090 Uiso 0.55 1 calc PR
H3C H 0.4529 0.1607 0.3613 0.090 Uiso 0.55 1 calc PR
C4 C 0.5057(2) 0.2497(7) 0.3559(5) 0.072(3) Uani 0.55 1 d P
H4A H 0.5296 0.2547 0.3612 0.108 Uiso 0.55 1 calc PR
H4B H 0.4972 0.3046 0.3639 0.108 Uiso 0.55 1 calc PR
H4C H 0.4915 0.2286 0.3010 0.108 Uiso 0.55 1 calc PR
C5 C 0.5167(2) 0.0991(6) 0.4079(6) 0.066(2) Uani 0.55 1 d P
H5A H 0.5406 0.1042 0.4132 0.098 Uiso 0.55 1 calc PR
H5B H 0.5023 0.0802 0.3523 0.098 Uiso 0.55 1 calc PR
H5C H 0.5153 0.0585 0.4482 0.098 Uiso 0.55 1 calc PR
C6 C 0.54776(17) 0.1568(4) 0.6258(4) 0.0391(14) Uani 0.55 1 d P
C7 C 0.5150(3) 0.1140(6) 0.6296(6) 0.053(2) Uani 0.55 1 d P
H7A H 0.5041 0.0788 0.5808 0.079 Uiso 0.55 1 calc PR
H7B H 0.4987 0.1571 0.6311 0.079 Uiso 0.55 1 calc PR
H7C H 0.5216 0.0794 0.6792 0.079 Uiso 0.55 1 calc PR
C8 C 0.56622(12) 0.2151(3) 0.7035(3) 0.0578(11) Uani 1 1 d .
H8A H 0.5862 0.2421 0.6985 0.087 Uiso 1 1 calc R
H8B H 0.5738 0.1812 0.7537 0.087 Uiso 1 1 calc R
H8C H 0.5500 0.2579 0.7061 0.087 Uiso 1 1 calc R
C9 C 0.5749(2) 0.0878(5) 0.6285(6) 0.056(2) Uani 0.55 1 d P
H9A H 0.5951 0.1146 0.6245 0.084 Uiso 0.55 1 calc PR
H9B H 0.5646 0.0492 0.5822 0.084 Uiso 0.55 1 calc PR
H9C H 0.5819 0.0568 0.6803 0.084 Uiso 0.55 1 calc PR
C10 C 0.70851(10) 0.1024(3) 0.4959(3) 0.0516(10) Uani 1 1 d .
H10A H 0.7116 0.0705 0.5457 0.077 Uiso 1 1 calc R
H10B H 0.7208 0.1557 0.5112 0.077 Uiso 1 1 calc R
H10C H 0.7176 0.0702 0.4615 0.077 Uiso 1 1 calc R
C11 C 0.63552(12) 0.0177(3) 0.4230(3) 0.0652(14) Uani 1 1 d .
C12 C 0.63769(16) -0.0113(3) 0.5108(4) 0.0814(17) Uani 1 1 d .
H12A H 0.6275 0.0317 0.5340 0.122 Uiso 1 1 calc R
H12B H 0.6618 -0.0196 0.5473 0.122 Uiso 1 1 calc R
H12C H 0.6251 -0.0639 0.5054 0.122 Uiso 1 1 calc R
C13 C 0.59670(13) 0.0287(4) 0.3619(4) 0.108(3) Uani 1 1 d .
H13A H 0.5859 0.0725 0.3826 0.161 Uiso 1 1 calc R
H13B H 0.5844 -0.0241 0.3579 0.161 Uiso 1 1 calc R
H13C H 0.5958 0.0444 0.3074 0.161 Uiso 1 1 calc R
C14 C 0.65229(16) -0.0522(4) 0.3881(5) 0.095(2) Uani 1 1 d .
H14A H 0.6763 -0.0601 0.4255 0.143 Uiso 1 1 calc R
H14B H 0.6513 -0.0354 0.3338 0.143 Uiso 1 1 calc R
H14C H 0.6397 -0.1047 0.3833 0.143 Uiso 1 1 calc R
C15 C 0.65512(12) 0.1869(3) 0.3374(3) 0.0594(12) Uani 1 1 d .
C16 C 0.61875(14) 0.2274(4) 0.2953(3) 0.091(2) Uani 1 1 d .
H16A H 0.6141 0.2632 0.3349 0.136 Uiso 1 1 calc R
H16B H 0.6013 0.1833 0.2763 0.136 Uiso 1 1 calc R
H16C H 0.6180 0.2611 0.2482 0.136 Uiso 1 1 calc R
C17 C 0.66284(16) 0.1307(4) 0.2728(3) 0.0898(19) Uani 1 1 d .
H17A H 0.6856 0.1048 0.2993 0.135 Uiso 1 1 calc R
H17B H 0.6624 0.1654 0.2267 0.135 Uiso 1 1 calc R
H17C H 0.6453 0.0869 0.2525 0.135 Uiso 1 1 calc R
C18 C 0.68192(14) 0.2598(4) 0.3631(3) 0.0753(16) Uani 1 1 d .
H18A H 0.7052 0.2367 0.3895 0.113 Uiso 1 1 calc R
H18B H 0.6772 0.2968 0.4018 0.113 Uiso 1 1 calc R
H18C H 0.6802 0.2917 0.3142 0.113 Uiso 1 1 calc R
C19 C 0.66207(8) 0.2637(2) 0.7916(2) 0.0328(7) Uani 1 1 d .
H19A H 0.6488 0.2166 0.7591 0.049 Uiso 1 1 calc R
H19B H 0.6474 0.3135 0.7804 0.049 Uiso 1 1 calc R
H19C H 0.6703 0.2499 0.8502 0.049 Uiso 1 1 calc R
C20 C 0.72664(8) 0.3794(2) 0.8284(2) 0.0341(7) Uani 1 1 d .
C21 C 0.70633(10) 0.4621(2) 0.7954(2) 0.0437(8) Uani 1 1 d .
H21A H 0.7036 0.4708 0.7382 0.066 Uiso 1 1 calc R
H21B H 0.7190 0.5092 0.8291 0.066 Uiso 1 1 calc R
H21C H 0.6836 0.4582 0.7983 0.066 Uiso 1 1 calc R
C22 C 0.73030(10) 0.3683(3) 0.9202(2) 0.0445(9) Uani 1 1 d .
H22A H 0.7429 0.3166 0.9428 0.067 Uiso 1 1 calc R
H22B H 0.7074 0.3653 0.9221 0.067 Uiso 1 1 calc R
H22C H 0.7429 0.4160 0.9530 0.067 Uiso 1 1 calc R
C23 C 0.76355(9) 0.3879(3) 0.8277(2) 0.0462(9) Uani 1 1 d .
H23A H 0.7764 0.3362 0.8483 0.069 Uiso 1 1 calc R
H23B H 0.7756 0.4347 0.8630 0.069 Uiso 1 1 calc R
H23C H 0.7617 0.3982 0.7714 0.069 Uiso 1 1 calc R
C24 C 0.72592(9) 0.1814(2) 0.7701(2) 0.0339(7) Uani 1 1 d .
C25 C 0.70020(10) 0.1089(2) 0.7288(2) 0.0427(8) Uani 1 1 d .
H25A H 0.6838 0.1035 0.7555 0.064 Uiso 1 1 calc R
H25B H 0.7129 0.0564 0.7347 0.064 Uiso 1 1 calc R
H25C H 0.6877 0.1213 0.6702 0.064 Uiso 1 1 calc R
C26 C 0.75220(9) 0.1897(3) 0.7271(2) 0.0450(9) Uani 1 1 d .
H26A H 0.7684 0.2351 0.7530 0.068 Uiso 1 1 calc R
H26B H 0.7397 0.2022 0.6686 0.068 Uiso 1 1 calc R
H26C H 0.7648 0.1371 0.7330 0.068 Uiso 1 1 calc R
C27 C 0.74593(10) 0.1571(3) 0.8636(2) 0.0459(9) Uani 1 1 d .
H27A H 0.7625 0.2012 0.8915 0.069 Uiso 1 1 calc R
H27B H 0.7582 0.1043 0.8671 0.069 Uiso 1 1 calc R
H27C H 0.7295 0.1506 0.8902 0.069 Uiso 1 1 calc R
C28 C 0.64202(10) 0.4888(3) 0.4189(2) 0.0517(11) Uani 1 1 d .
H28A H 0.6656 0.4913 0.4603 0.078 Uiso 1 1 calc R
H28B H 0.6395 0.5288 0.3748 0.078 Uiso 1 1 calc R
H28C H 0.6372 0.4323 0.3959 0.078 Uiso 1 1 calc R
C29 C 0.56378(9) 0.5114(3) 0.3857(2) 0.0417(8) Uani 1 1 d .
C30 C 0.56062(11) 0.4342(3) 0.3277(2) 0.0547(11) Uani 1 1 d .
H30A H 0.5770 0.4404 0.3011 0.082 Uiso 1 1 calc R
H30B H 0.5372 0.4314 0.2857 0.082 Uiso 1 1 calc R
H30C H 0.5657 0.3826 0.3604 0.082 Uiso 1 1 calc R
C31 C 0.55525(11) 0.5920(3) 0.3311(3) 0.0567(11) Uani 1 1 d .
H31A H 0.5721 0.5986 0.3058 0.085 Uiso 1 1 calc R
H31B H 0.5562 0.6410 0.3653 0.085 Uiso 1 1 calc R
H31C H 0.5321 0.5871 0.2879 0.085 Uiso 1 1 calc R
C32 C 0.53684(9) 0.4994(3) 0.4266(3) 0.0482(9) Uani 1 1 d .
H32A H 0.5424 0.4486 0.4602 0.072 Uiso 1 1 calc R
H32B H 0.5137 0.4945 0.3836 0.072 Uiso 1 1 calc R
H32C H 0.5377 0.5478 0.4614 0.072 Uiso 1 1 calc R
C33 C 0.62406(9) 0.6230(2) 0.5273(2) 0.0394(8) Uani 1 1 d .
C34 C 0.63354(12) 0.6878(3) 0.4717(3) 0.0590(12) Uani 1 1 d .
H34A H 0.6513 0.6639 0.4552 0.089 Uiso 1 1 calc R
H34B H 0.6422 0.7394 0.5029 0.089 Uiso 1 1 calc R
H34C H 0.6130 0.7004 0.4226 0.089 Uiso 1 1 calc R
C35 C 0.59590(10) 0.6625(3) 0.5533(3) 0.0460(9) Uani 1 1 d .
H35A H 0.5899 0.6230 0.5881 0.069 Uiso 1 1 calc R
H35B H 0.5754 0.6751 0.5041 0.069 Uiso 1 1 calc R
H35C H 0.6048 0.7142 0.5840 0.069 Uiso 1 1 calc R
C36 C 0.65749(9) 0.6082(3) 0.6074(3) 0.0487(10) Uani 1 1 d .
H36A H 0.6755 0.5837 0.5923 0.073 Uiso 1 1 calc R
H36B H 0.6522 0.5700 0.6444 0.073 Uiso 1 1 calc R
H36C H 0.6655 0.6617 0.6354 0.073 Uiso 1 1 calc R
C37 C 0.5573(2) 0.0632(5) 0.5479(6) 0.0405(18) Uani 0.45 1 d P
H37A H 0.5764 0.0593 0.6016 0.061 Uiso 0.45 1 calc PR
H37B H 0.5651 0.0458 0.5047 0.061 Uiso 0.45 1 calc PR
H37C H 0.5385 0.0266 0.5473 0.061 Uiso 0.45 1 calc PR
C38 C 0.4689(3) 0.1440(9) 0.4346(8) 0.049(3) Uani 0.45 1 d P
H38A H 0.4758 0.0941 0.4694 0.074 Uiso 0.45 1 calc PR
H38B H 0.4519 0.1286 0.3803 0.074 Uiso 0.45 1 calc PR
H38C H 0.4588 0.1850 0.4601 0.074 Uiso 0.45 1 calc PR
C39 C 0.4920(2) 0.2752(6) 0.3904(7) 0.049(2) Uani 0.45 1 d P
H39A H 0.5114 0.3051 0.3855 0.073 Uiso 0.45 1 calc PR
H39B H 0.4841 0.3054 0.4282 0.073 Uiso 0.45 1 calc PR
H39C H 0.4732 0.2714 0.3362 0.073 Uiso 0.45 1 calc PR
C40 C 0.5114(3) 0.1344(7) 0.3567(6) 0.054(2) Uani 0.45 1 d P
H40A H 0.5356 0.1418 0.3649 0.082 Uiso 0.45 1 calc PR
H40B H 0.4966 0.1546 0.3019 0.082 Uiso 0.45 1 calc PR
H40C H 0.5068 0.0750 0.3615 0.082 Uiso 0.45 1 calc PR
C41 C 0.5332(2) 0.2148(5) 0.6250(5) 0.0366(17) Uani 0.45 1 d P
C42 C 0.5104(4) 0.1490(9) 0.6500(8) 0.072(4) Uani 0.45 1 d P
H42A H 0.5213 0.0938 0.6578 0.108 Uiso 0.45 1 calc PR
H42B H 0.4874 0.1460 0.6062 0.108 Uiso 0.45 1 calc PR
H42C H 0.5086 0.1669 0.7013 0.108 Uiso 0.45 1 calc PR
C43 C 0.5154(2) 0.3029(6) 0.6129(6) 0.052(2) Uani 0.45 1 d P
H43A H 0.5293 0.3440 0.5985 0.078 Uiso 0.45 1 calc PR
H43B H 0.5132 0.3198 0.6641 0.078 Uiso 0.45 1 calc PR
H43C H 0.4925 0.2997 0.5686 0.078 Uiso 0.45 1 calc PR
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
Ge2 Ge1 Si1 143.89(5)
Ge2 Ge1 Ge4 90.214(17)
Si1 Ge1 Ge4 120.31(5)
Ge2 Ge1 Si5 123.85(6)
Si1 Ge1 Si5 20.34(6)
Ge4 Ge1 Si5 138.33(6)
Ge1 Ge2 Si2 136.16(3)
Ge1 Ge2 Ge3 91.274(17)
Si2 Ge2 Ge3 128.94(3)
Cl1 Ge3 Ge2 117.08(3)
Cl1 Ge3 Si3 106.35(3)
Ge2 Ge3 Si3 113.81(3)
Cl1 Ge3 Ge4 116.35(3)
Ge2 Ge3 Ge4 86.151(15)
Si3 Ge3 Ge4 116.60(2)
Cl2 Ge4 Ge1 112.96(3)
Cl2 Ge4 Si4 108.19(4)
Ge1 Ge4 Si4 117.50(3)
Cl2 Ge4 Ge3 116.13(3)
Ge1 Ge4 Ge3 87.086(16)
Si4 Ge4 Ge3 114.06(3)
C1 Si1 C6 107.0(3)
C1 Si1 C2 108.2(3)
C6 Si1 C2 116.2(2)
C1 Si1 Ge1 108.5(2)
C6 Si1 Ge1 107.3(2)
C2 Si1 Ge1 109.46(14)
C10 Si2 C15 108.78(19)
C10 Si2 C11 108.8(2)
C15 Si2 C11 118.2(2)
C10 Si2 Ge2 106.36(14)
C15 Si2 Ge2 106.75(14)
C11 Si2 Ge2 107.33(13)
C19 Si3 C24 109.02(15)
C19 Si3 C20 108.46(15)
C24 Si3 C20 116.51(15)
C19 Si3 Ge3 104.18(11)
C24 Si3 Ge3 108.63(11)
C20 Si3 Ge3 109.33(11)
C28 Si4 C29 108.69(18)
C28 Si4 C33 109.06(19)
C29 Si4 C33 116.00(16)
C28 Si4 Ge4 105.04(12)
C29 Si4 Ge4 108.52(13)
C33 Si4 Ge4 108.97(12)
C2 Si5 C37 110.3(3)
C2 Si5 C41 117.3(3)
C37 Si5 C41 108.0(4)
C2 Si5 Ge1 105.88(15)
C37 Si5 Ge1 108.1(3)
C41 Si5 Ge1 106.8(2)
Si1 C1 H1A 109.5
Si1 C1 H1B 109.5
H1A C1 H1B 109.5
Si1 C1 H1C 109.5
H1A C1 H1C 109.5
H1B C1 H1C 109.5
C3 C2 C39 82.9(6)
C3 C2 C5 109.9(7)
C39 C2 C5 146.1(6)
C3 C2 C40 113.7(7)
C39 C2 C40 108.5(6)
C5 C2 C40 37.7(5)
C3 C2 C4 109.7(6)
C39 C2 C4 39.5(5)
C5 C2 C4 107.6(6)
C40 C2 C4 71.3(6)
C3 C2 C38 21.7(6)
C39 C2 C38 104.4(6)
C5 C2 C38 92.9(7)
C40 C2 C38 108.5(8)
C4 C2 C38 129.5(5)
C3 C2 Si5 120.9(5)
C39 C2 Si5 117.4(4)
C5 C2 Si5 83.7(4)
C40 C2 Si5 110.5(4)
C4 C2 Si5 120.4(4)
C38 C2 Si5 107.1(4)
C3 C2 Si1 114.9(6)
C39 C2 Si1 91.7(4)
C5 C2 Si1 109.3(4)
C40 C2 Si1 129.1(4)
C4 C2 Si1 105.1(4)
C38 C2 Si1 110.8(6)
Si5 C2 Si1 26.40(9)
C2 C3 H3A 109.5
C2 C3 H3B 109.5
H3A C3 H3B 109.5
C2 C3 H3C 109.5
H3A C3 H3C 109.5
H3B C3 H3C 109.5
C2 C4 H4A 109.5
C2 C4 H4B 109.5
H4A C4 H4B 109.5
C2 C4 H4C 109.5
H4A C4 H4C 109.5
H4B C4 H4C 109.5
C2 C5 H5A 109.5
C2 C5 H5B 109.5
H5A C5 H5B 109.5
C2 C5 H5C 109.5
H5A C5 H5C 109.5
H5B C5 H5C 109.5
C7 C6 C9 109.6(6)
C7 C6 C8 111.5(5)
C9 C6 C8 106.1(6)
C7 C6 Si1 111.9(6)
C9 C6 Si1 112.6(5)
C8 C6 Si1 104.9(4)
C6 C7 H7A 109.5
C6 C7 H7B 109.5
H7A C7 H7B 109.5
C6 C7 H7C 109.5
H7A C7 H7C 109.5
H7B C7 H7C 109.5
C6 C8 H8A 109.5
C6 C8 H8B 109.5
H8A C8 H8B 109.5
C6 C8 H8C 109.5
H8A C8 H8C 109.5
H8B C8 H8C 109.5
C6 C9 H9A 109.5
C6 C9 H9B 109.5
H9A C9 H9B 109.5
C6 C9 H9C 109.5
H9A C9 H9C 109.5
H9B C9 H9C 109.5
Si2 C10 H10A 109.5
Si2 C10 H10B 109.5
H10A C10 H10B 109.5
Si2 C10 H10C 109.5
H10A C10 H10C 109.5
H10B C10 H10C 109.5
C14 C11 C13 108.5(5)
C14 C11 C12 108.0(5)
C13 C11 C12 110.5(5)
C14 C11 Si2 110.7(3)
C13 C11 Si2 110.8(4)
C12 C11 Si2 108.3(3)
C11 C12 H12A 109.5
C11 C12 H12B 109.5
H12A C12 H12B 109.5
C11 C12 H12C 109.5
H12A C12 H12C 109.5
H12B C12 H12C 109.5
C11 C13 H13A 109.5
C11 C13 H13B 109.5
H13A C13 H13B 109.5
C11 C13 H13C 109.5
H13A C13 H13C 109.5
H13B C13 H13C 109.5
C11 C14 H14A 109.5
C11 C14 H14B 109.5
H14A C14 H14B 109.5
C11 C14 H14C 109.5
H14A C14 H14C 109.5
H14B C14 H14C 109.5
C16 C15 C18 107.1(5)
C16 C15 C17 109.4(4)
C18 C15 C17 107.8(4)
C16 C15 Si2 113.4(3)
C18 C15 Si2 107.9(3)
C17 C15 Si2 111.0(4)
C15 C16 H16A 109.5
C15 C16 H16B 109.5
H16A C16 H16B 109.5
C15 C16 H16C 109.5
H16A C16 H16C 109.5
H16B C16 H16C 109.5
C15 C17 H17A 109.5
C15 C17 H17B 109.5
H17A C17 H17B 109.5
C15 C17 H17C 109.5
H17A C17 H17C 109.5
H17B C17 H17C 109.5
C15 C18 H18A 109.5
C15 C18 H18B 109.5
H18A C18 H18B 109.5
C15 C18 H18C 109.5
H18A C18 H18C 109.5
H18B C18 H18C 109.5
Si3 C19 H19A 109.5
Si3 C19 H19B 109.5
H19A C19 H19B 109.5
Si3 C19 H19C 109.5
H19A C19 H19C 109.5
H19B C19 H19C 109.5
C21 C20 C23 109.0(3)
C21 C20 C22 107.4(3)
C23 C20 C22 108.4(3)
C21 C20 Si3 109.2(2)
C23 C20 Si3 113.1(3)
C22 C20 Si3 109.5(2)
C20 C21 H21A 109.5
C20 C21 H21B 109.5
H21A C21 H21B 109.5
C20 C21 H21C 109.5
H21A C21 H21C 109.5
H21B C21 H21C 109.5
C20 C22 H22A 109.5
C20 C22 H22B 109.5
H22A C22 H22B 109.5
C20 C22 H22C 109.5
H22A C22 H22C 109.5
H22B C22 H22C 109.5
C20 C23 H23A 109.5
C20 C23 H23B 109.5
H23A C23 H23B 109.5
C20 C23 H23C 109.5
H23A C23 H23C 109.5
H23B C23 H23C 109.5
C25 C24 C26 109.2(3)
C25 C24 C27 107.3(3)
C26 C24 C27 109.4(3)
C25 C24 Si3 109.7(2)
C26 C24 Si3 111.3(2)
C27 C24 Si3 109.9(2)
C24 C25 H25A 109.5
C24 C25 H25B 109.5
H25A C25 H25B 109.5
C24 C25 H25C 109.5
H25A C25 H25C 109.5
H25B C25 H25C 109.5
C24 C26 H26A 109.5
C24 C26 H26B 109.5
H26A C26 H26B 109.5
C24 C26 H26C 109.5
H26A C26 H26C 109.5
H26B C26 H26C 109.5
C24 C27 H27A 109.5
C24 C27 H27B 109.5
H27A C27 H27B 109.5
C24 C27 H27C 109.5
H27A C27 H27C 109.5
H27B C27 H27C 109.5
Si4 C28 H28A 109.5
Si4 C28 H28B 109.5
H28A C28 H28B 109.5
Si4 C28 H28C 109.5
H28A C28 H28C 109.5
H28B C28 H28C 109.5
C31 C29 C32 110.3(3)
C31 C29 C30 107.7(3)
C32 C29 C30 107.9(3)
C31 C29 Si4 110.7(3)
C32 C29 Si4 110.8(2)
C30 C29 Si4 109.3(2)
C29 C30 H30A 109.5
C29 C30 H30B 109.5
H30A C30 H30B 109.5
C29 C30 H30C 109.5
H30A C30 H30C 109.5
H30B C30 H30C 109.5
C29 C31 H31A 109.5
C29 C31 H31B 109.5
H31A C31 H31B 109.5
C29 C31 H31C 109.5
H31A C31 H31C 109.5
H31B C31 H31C 109.5
C29 C32 H32A 109.5
C29 C32 H32B 109.5
H32A C32 H32B 109.5
C29 C32 H32C 109.5
H32A C32 H32C 109.5
H32B C32 H32C 109.5
C35 C33 C34 108.6(3)
C35 C33 C36 108.3(3)
C34 C33 C36 107.5(3)
C35 C33 Si4 113.8(3)
C34 C33 Si4 109.9(3)
C36 C33 Si4 108.5(3)
C33 C34 H34A 109.5
C33 C34 H34B 109.5
H34A C34 H34B 109.5
C33 C34 H34C 109.5
H34A C34 H34C 109.5
H34B C34 H34C 109.5
C33 C35 H35A 109.5
C33 C35 H35B 109.5
H35A C35 H35B 109.5
C33 C35 H35C 109.5
H35A C35 H35C 109.5
H35B C35 H35C 109.5
C33 C36 H36A 109.5
C33 C36 H36B 109.5
H36A C36 H36B 109.5
C33 C36 H36C 109.5
H36A C36 H36C 109.5
H36B C36 H36C 109.5
Si5 C37 H37A 109.5
Si5 C37 H37B 109.5
H37A C37 H37B 109.5
Si5 C37 H37C 109.5
H37A C37 H37C 109.5
H37B C37 H37C 109.5
C2 C38 H38A 109.5
C2 C38 H38B 109.5
H38A C38 H38B 109.5
C2 C38 H38C 109.5
H38A C38 H38C 109.5
H38B C38 H38C 109.5
C2 C39 H39A 109.5
C2 C39 H39B 109.5
H39A C39 H39B 109.5
C2 C39 H39C 109.5
H39A C39 H39C 109.5
H39B C39 H39C 109.5
C2 C40 H40A 109.5
C2 C40 H40B 109.5
H40A C40 H40B 109.5
C2 C40 H40C 109.5
H40A C40 H40C 109.5
H40B C40 H40C 109.5
C43 C41 C42 108.7(8)
C43 C41 Si5 113.3(6)
C42 C41 Si5 111.0(6)
C41 C42 H42A 109.5
C41 C42 H42B 109.5
H42A C42 H42B 109.5
C41 C42 H42C 109.5
H42A C42 H42C 109.5
H42B C42 H42C 109.5
C41 C43 H43A 109.5
C41 C43 H43B 109.5
H43A C43 H43B 109.5
C41 C43 H43C 109.5
H43A C43 H43C 109.5
H43B C43 H43C 109.5
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
Ge1 Ge2 2.2993(5)
Ge1 Si1 2.3625(16)
Ge1 Ge4 2.4165(5)
Ge1 Si5 2.522(2)
Ge2 Si2 2.4039(10)
Ge2 Ge3 2.4154(5)
Ge3 Cl1 2.2479(8)
Ge3 Si3 2.4213(9)
Ge3 Ge4 2.4773(4)
Ge4 Cl2 2.2481(8)
Ge4 Si4 2.4334(10)
Si1 C1 1.874(7)
Si1 C6 1.911(7)
Si1 C2 1.950(4)
Si2 C10 1.870(4)
Si2 C15 1.908(5)
Si2 C11 1.920(5)
Si3 C19 1.877(3)
Si3 C24 1.910(3)
Si3 C20 1.919(4)
Si4 C28 1.877(4)
Si4 C29 1.908(4)
Si4 C33 1.916(4)
Si5 C2 1.873(4)
Si5 C37 1.882(8)
Si5 C41 1.913(8)
C1 H1A 0.9600
C1 H1B 0.9600
C1 H1C 0.9600
C2 C3 1.452(12)
C2 C39 1.521(10)
C2 C5 1.527(10)
C2 C40 1.549(10)
C2 C4 1.573(9)
C2 C38 1.649(13)
C3 H3A 0.9600
C3 H3B 0.9600
C3 H3C 0.9600
C4 H4A 0.9600
C4 H4B 0.9600
C4 H4C 0.9600
C5 H5A 0.9600
C5 H5B 0.9600
C5 H5C 0.9600
C6 C7 1.534(11)
C6 C9 1.545(10)
C6 C8 1.556(8)
C7 H7A 0.9600
C7 H7B 0.9600
C7 H7C 0.9600
C8 H8A 0.9600
C8 H8B 0.9600
C8 H8C 0.9600
C9 H9A 0.9600
C9 H9B 0.9600
C9 H9C 0.9600
C10 H10A 0.9600
C10 H10B 0.9600
C10 H10C 0.9600
C11 C14 1.537(6)
C11 C13 1.550(7)
C11 C12 1.553(8)
C12 H12A 0.9600
C12 H12B 0.9600
C12 H12C 0.9600
C13 H13A 0.9600
C13 H13B 0.9600
C13 H13C 0.9600
C14 H14A 0.9600
C14 H14B 0.9600
C14 H14C 0.9600
C15 C16 1.530(6)
C15 C18 1.532(7)
C15 C17 1.548(6)
C16 H16A 0.9600
C16 H16B 0.9600
C16 H16C 0.9600
C17 H17A 0.9600
C17 H17B 0.9600
C17 H17C 0.9600
C18 H18A 0.9600
C18 H18B 0.9600
C18 H18C 0.9600
C19 H19A 0.9600
C19 H19B 0.9600
C19 H19C 0.9600
C20 C21 1.529(5)
C20 C23 1.535(5)
C20 C22 1.544(5)
C21 H21A 0.9600
C21 H21B 0.9600
C21 H21C 0.9600
C22 H22A 0.9600
C22 H22B 0.9600
C22 H22C 0.9600
C23 H23A 0.9600
C23 H23B 0.9600
C23 H23C 0.9600
C24 C25 1.530(5)
C24 C26 1.539(5)
C24 C27 1.550(4)
C25 H25A 0.9600
C25 H25B 0.9600
C25 H25C 0.9600
C26 H26A 0.9600
C26 H26B 0.9600
C26 H26C 0.9600
C27 H27A 0.9600
C27 H27B 0.9600
C27 H27C 0.9600
C28 H28A 0.9600
C28 H28B 0.9600
C28 H28C 0.9600
C29 C31 1.535(5)
C29 C32 1.542(5)
C29 C30 1.543(5)
C30 H30A 0.9600
C30 H30B 0.9600
C30 H30C 0.9600
C31 H31A 0.9600
C31 H31B 0.9600
C31 H31C 0.9600
C32 H32A 0.9600
C32 H32B 0.9600
C32 H32C 0.9600
C33 C35 1.531(5)
C33 C34 1.548(5)
C33 C36 1.548(5)
C34 H34A 0.9600
C34 H34B 0.9600
C34 H34C 0.9600
C35 H35A 0.9600
C35 H35B 0.9600
C35 H35C 0.9600
C36 H36A 0.9600
C36 H36B 0.9600
C36 H36C 0.9600
C37 H37A 0.9600
C37 H37B 0.9600
C37 H37C 0.9600
C38 H38A 0.9600
C38 H38B 0.9600
C38 H38C 0.9600
C39 H39A 0.9600
C39 H39B 0.9600
C39 H39C 0.9600
C40 H40A 0.9600
C40 H40B 0.9600
C40 H40C 0.9600
C41 C43 1.540(12)
C41 C42 1.564(13)
C42 H42A 0.9600
C42 H42B 0.9600
C42 H42C 0.9600
C43 H43A 0.9600
C43 H43B 0.9600
C43 H43C 0.9600
