#------------------------------------------------------------------------------
#$Date: 2016-03-21 18:33:37 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178816 $
#$URL: svn://www.crystallography.net/cod/cif/4/10/70/4107081.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4107081
loop_
_publ_author_name
'Wai Yiu Hung'
'Bin Liu'
'Wangge Shou'
'Ting Bin Wen'
'Chuan Shi'
'Herman H.-Y. Sung'
'Ian D. Williams'
'Zhenyang Lin'
'Guochen Jia'
_publ_section_title
;
 Electrophilic Substitution Reactions of Metallabenzynes
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              18350
_journal_page_last               18360
_journal_paper_doi               10.1021/ja207315h
_journal_volume                  133
_journal_year                    2011
_chemical_formula_sum            'C48 H50 Cl3 O Os P2 Si'
_chemical_formula_weight         1029.46
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 94.9460(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   10.0996(7)
_cell_length_b                   18.2847(12)
_cell_length_c                   23.7928(16)
_cell_measurement_reflns_used    4066
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      28.28
_cell_measurement_theta_min      2.31
_cell_volume                     4377.4(5)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 8
_diffrn_measured_fraction_theta_full 0.984
_diffrn_measured_fraction_theta_max 0.984
_diffrn_measurement_device_type  'Bruker SMART APEX CCD area detector'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0870
_diffrn_reflns_av_sigmaI/netI    0.0828
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            33907
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.13
_exptl_absorpt_coefficient_mu    3.233
_exptl_absorpt_correction_T_max  1.00
_exptl_absorpt_correction_T_min  0.82
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.562
_exptl_crystal_description       bar
_exptl_crystal_F_000             2068
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.05
_refine_diff_density_max         0.928
_refine_diff_density_min         -1.087
_refine_diff_density_rms         0.121
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.029
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     500
_refine_ls_number_reflns         7584
_refine_ls_number_restraints     9
_refine_ls_restrained_S_all      1.035
_refine_ls_R_factor_all          0.0744
_refine_ls_R_factor_gt           0.0368
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
; calc 
 [0.00000+1.00000exp(0.50(sinθ/λ)²)]/ 
   [σ²(Fo²)+0.0000+0.0000*P+(0.0120P)²+0.0000sinθ/λ] 
 where P = 0.33333Fo² + 0.66667Fc² 
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0549
_refine_ls_wR_factor_ref         0.0591
_reflns_number_gt                5221
_reflns_number_total             7584
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ja207315h_si_005.cif
_cod_data_source_block           yiu37
_cod_database_code               4107081
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Os1 Os 0.37508(2) 0.385600(11) 0.178971(8) 0.01952(6) Uani 1 1 d . . .
Cl1 Cl 0.45633(15) 0.26185(7) 0.19955(5) 0.0338(4) Uani 1 1 d . . .
Cl2 Cl 0.58049(14) 0.40537(7) 0.13845(5) 0.0325(4) Uani 1 1 d . . .
Cl3 Cl -0.03694(16) 0.44492(10) 0.23555(6) 0.0523(5) Uani 1 1 d . . .
P1 P 0.47804(14) 0.42642(7) 0.26892(5) 0.0215(3) Uani 1 1 d . . .
P2 P 0.27463(16) 0.33212(7) 0.09290(5) 0.0250(4) Uani 1 1 d . A .
Si1 Si 0.29579(19) 0.64015(8) 0.13095(7) 0.0389(5) Uani 1 1 d . . .
O1 O 0.2103(4) 0.3465(2) 0.22051(13) 0.0284(9) Uani 1 1 d . . .
C1 C 0.2013(6) 0.4099(3) 0.2023(2) 0.0254(14) Uani 1 1 d . . .
C2 C 0.1098(5) 0.4648(3) 0.2055(2) 0.0300(14) Uani 1 1 d . . .
C3 C 0.1401(6) 0.5350(3) 0.1884(2) 0.0293(14) Uani 1 1 d . . .
C4 C 0.2570(5) 0.5466(3) 0.1596(2) 0.0221(13) Uani 1 1 d . . .
C5 C 0.3463(5) 0.4914(2) 0.15302(19) 0.0178(12) Uani 1 1 d . . .
H5 H 0.4136 0.5066 0.1300 0.021 Uiso 1 1 calc R . .
C6 C 0.0482(6) 0.5969(4) 0.2004(3) 0.061(2) Uani 1 1 d . . .
H6A H -0.0263 0.5779 0.2198 0.091 Uiso 1 1 calc R . .
H6B H 0.0143 0.6198 0.1648 0.091 Uiso 1 1 calc R . .
H6C H 0.0969 0.6332 0.2243 0.091 Uiso 1 1 calc R . .
C7 C 0.3494(8) 0.7018(3) 0.1910(3) 0.065(2) Uani 1 1 d . . .
H7A H 0.3691 0.7504 0.1765 0.098 Uiso 1 1 calc R . .
H7B H 0.4292 0.6818 0.2118 0.098 Uiso 1 1 calc R . .
H7C H 0.2780 0.7057 0.2162 0.098 Uiso 1 1 calc R . .
C8 C 0.1584(7) 0.6815(4) 0.0846(3) 0.075(2) Uani 1 1 d . . .
H8A H 0.1860 0.7296 0.0717 0.113 Uiso 1 1 calc R . .
H8B H 0.0799 0.6869 0.1058 0.113 Uiso 1 1 calc R . .
H8C H 0.1369 0.6497 0.0520 0.113 Uiso 1 1 calc R . .
C9 C 0.4372(6) 0.6330(3) 0.0860(2) 0.0447(17) Uani 1 1 d . . .
H9A H 0.4569 0.6814 0.0712 0.067 Uiso 1 1 calc R . .
H9B H 0.4135 0.5996 0.0546 0.067 Uiso 1 1 calc R . .
H9C H 0.5156 0.6143 0.1086 0.067 Uiso 1 1 calc R . .
C11 C 0.5878(6) 0.3595(3) 0.3057(2) 0.0265(14) Uani 1 1 d . . .
C12 C 0.6983(6) 0.3388(3) 0.2791(2) 0.0359(16) Uani 1 1 d . . .
H12 H 0.7074 0.3552 0.2418 0.043 Uiso 1 1 calc R . .
C13 C 0.7949(6) 0.2953(3) 0.3054(3) 0.0391(16) Uani 1 1 d . . .
H13 H 0.8700 0.2816 0.2863 0.047 Uiso 1 1 calc R . .
C14 C 0.7831(7) 0.2714(3) 0.3593(3) 0.0476(18) Uani 1 1 d . . .
H14 H 0.8500 0.2413 0.3778 0.057 Uiso 1 1 calc R . .
C15 C 0.6746(7) 0.2910(3) 0.3862(3) 0.0491(19) Uani 1 1 d . . .
H15 H 0.6671 0.2743 0.4236 0.059 Uiso 1 1 calc R . .
C16 C 0.5746(6) 0.3348(3) 0.3601(2) 0.0359(16) Uani 1 1 d . . .
H16 H 0.4989 0.3475 0.3791 0.043 Uiso 1 1 calc R . .
C21 C 0.5912(5) 0.5045(3) 0.2735(2) 0.0241(13) Uani 1 1 d . . .
C22 C 0.6630(5) 0.5181(3) 0.3251(2) 0.0326(15) Uani 1 1 d . . .
H22 H 0.6483 0.4885 0.3568 0.039 Uiso 1 1 calc R . .
C23 C 0.7553(6) 0.5740(3) 0.3308(3) 0.0413(16) Uani 1 1 d . . .
H23 H 0.8034 0.5825 0.3663 0.050 Uiso 1 1 calc R . .
C24 C 0.7778(5) 0.6171(3) 0.2857(3) 0.0412(15) Uani 1 1 d . . .
H24 H 0.8418 0.6552 0.2894 0.049 Uiso 1 1 calc R . .
C25 C 0.7077(5) 0.6047(3) 0.2356(3) 0.0415(16) Uani 1 1 d . . .
H25 H 0.7223 0.6353 0.2044 0.050 Uiso 1 1 calc R . .
C26 C 0.6164(6) 0.5495(3) 0.2283(2) 0.0357(15) Uani 1 1 d . . .
H26 H 0.5700 0.5417 0.1923 0.043 Uiso 1 1 calc R . .
C31 C 0.3520(5) 0.4514(3) 0.3152(2) 0.0260(13) Uani 1 1 d . . .
C32 C 0.3199(6) 0.5239(3) 0.3231(2) 0.0349(15) Uani 1 1 d . . .
H32 H 0.3731 0.5612 0.3088 0.042 Uiso 1 1 calc R . .
C33 C 0.2101(7) 0.5432(4) 0.3520(3) 0.0503(18) Uani 1 1 d . . .
H33 H 0.1865 0.5931 0.3558 0.060 Uiso 1 1 calc R . .
C34 C 0.1368(7) 0.4892(4) 0.3748(3) 0.057(2) Uani 1 1 d . . .
H34 H 0.0650 0.5020 0.3962 0.068 Uiso 1 1 calc R . .
C35 C 0.1671(6) 0.4162(4) 0.3666(2) 0.0429(17) Uani 1 1 d . . .
H35 H 0.1148 0.3790 0.3816 0.051 Uiso 1 1 calc R . .
C36 C 0.2722(6) 0.3978(3) 0.33705(19) 0.0315(14) Uani 1 1 d . . .
H36 H 0.2914 0.3477 0.3312 0.038 Uiso 1 1 calc R . .
C41 C 0.1094(6) 0.3002(3) 0.1051(2) 0.0251(13) Uani 1 1 d . . .
C42 C 0.0946(6) 0.2412(3) 0.1410(2) 0.0376(16) Uani 1 1 d . . .
H42 H 0.1710 0.2147 0.1553 0.045 Uiso 1 1 calc R . .
C43 C -0.0287(7) 0.2203(3) 0.1562(2) 0.0421(17) Uani 1 1 d . . .
H43 H -0.0358 0.1798 0.1807 0.050 Uiso 1 1 calc R . .
C44 C -0.1388(7) 0.2566(3) 0.1367(2) 0.0461(18) Uani 1 1 d . . .
H44 H -0.2239 0.2417 0.1466 0.055 Uiso 1 1 calc R . .
C45 C -0.1256(8) 0.3167(4) 0.1015(3) 0.071(2) Uani 1 1 d . . .
H45 H -0.2021 0.3434 0.0876 0.085 Uiso 1 1 calc R . .
C46 C -0.0017(7) 0.3374(4) 0.0868(3) 0.065(2) Uani 1 1 d . . .
H46 H 0.0057 0.3788 0.0632 0.078 Uiso 1 1 calc R . .
C51 C 0.2480(5) 0.3917(3) 0.03076(19) 0.0272(12) Uani 1 1 d D . .
C52A C 0.1632(10) 0.3696(5) -0.0131(4) 0.023(3) Uiso 0.50 1 d PD A 1
H52 H 0.1131 0.3261 -0.0102 0.027 Uiso 0.50 1 calc PR A 1
C53A C 0.1493(11) 0.4107(5) -0.0627(4) 0.029(3) Uiso 0.50 1 d PD A 1
H53 H 0.0869 0.3967 -0.0930 0.035 Uiso 0.50 1 calc PR A 1
C54A C 0.2291(13) 0.4732(7) -0.0673(5) 0.024(3) Uiso 0.50 1 d PD A 1
H54 H 0.2177 0.5024 -0.1004 0.029 Uiso 0.50 1 calc PR A 1
C55A C 0.3196(10) 0.4918(5) -0.0264(4) 0.025(3) Uiso 0.50 1 d PD A 1
H55 H 0.3723 0.5343 -0.0300 0.030 Uiso 0.50 1 calc PR A 1
C56A C 0.3377(11) 0.4488(5) 0.0225(4) 0.026(3) Uiso 0.50 1 d PD A 1
H56 H 0.4100 0.4581 0.0498 0.031 Uiso 0.50 1 calc PR A 1
C52B C 0.2748(12) 0.3759(7) -0.0211(5) 0.054(4) Uiso 0.50 1 d PD A 2
H52A H 0.3186 0.3312 -0.0279 0.065 Uiso 0.50 1 calc PR A 2
C53B C 0.2401(12) 0.4238(7) -0.0674(5) 0.041(3) Uiso 0.50 1 d PD A 2
H53A H 0.2642 0.4115 -0.1039 0.050 Uiso 0.50 1 calc PR A 2
C54B C 0.1754(15) 0.4844(8) -0.0599(6) 0.049(4) Uiso 0.50 1 d PD A 2
H54A H 0.1528 0.5154 -0.0913 0.058 Uiso 0.50 1 calc PR A 2
C55B C 0.1383(12) 0.5048(7) -0.0065(5) 0.049(4) Uiso 0.50 1 d PD A 2
H55A H 0.0945 0.5501 -0.0019 0.059 Uiso 0.50 1 calc PR A 2
C56B C 0.1653(11) 0.4591(6) 0.0392(5) 0.034(3) Uiso 0.50 1 d PD A 2
H56A H 0.1332 0.4697 0.0747 0.041 Uiso 0.50 1 calc PR A 2
C61 C 0.3567(7) 0.2530(3) 0.0632(2) 0.0326(15) Uani 1 1 d . . .
C62 C 0.2822(7) 0.1947(3) 0.0403(2) 0.0499(19) Uani 1 1 d . A .
H62 H 0.1885 0.1933 0.0417 0.060 Uiso 1 1 calc R . .
C63 C 0.3489(9) 0.1381(3) 0.0151(2) 0.060(2) Uani 1 1 d . . .
H63 H 0.2991 0.0978 -0.0005 0.073 Uiso 1 1 calc R A .
C64 C 0.4806(10) 0.1389(4) 0.0121(2) 0.062(2) Uani 1 1 d . A .
H64 H 0.5231 0.0997 -0.0055 0.075 Uiso 1 1 calc R . .
C65 C 0.5530(8) 0.1961(4) 0.0345(3) 0.061(2) Uani 1 1 d . . .
H65 H 0.6465 0.1969 0.0324 0.073 Uiso 1 1 calc R A .
C66 C 0.4917(7) 0.2533(3) 0.0603(2) 0.0478(18) Uani 1 1 d . A .
H66 H 0.5434 0.2929 0.0761 0.057 Uiso 1 1 calc R . .
C1S C 0.4824(11) 0.4673(3) 0.4877(4) 0.115(4) Uani 1 1 d D . .
H1SA H 0.5607 0.4455 0.4717 0.138 Uiso 1 1 calc R . .
H1SB H 0.4130 0.4755 0.4564 0.138 Uiso 1 1 calc R . .
C2S C 0.4317(11) 0.4159(5) 0.5289(4) 0.104(3) Uani 1 1 d D . .
H2SA H 0.4974 0.4095 0.5619 0.125 Uiso 1 1 calc R . .
H2SB H 0.3475 0.4340 0.5421 0.125 Uiso 1 1 calc R . .
C3S C 0.4104(11) 0.3470(6) 0.4982(4) 0.142(4) Uani 1 1 d D . .
H3SA H 0.3763 0.3102 0.5233 0.213 Uiso 1 1 calc R . .
H3SB H 0.4947 0.3300 0.4853 0.213 Uiso 1 1 calc R . .
H3SC H 0.3458 0.3545 0.4656 0.213 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Os Os -1.2165 7.6030 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
C1 Os1 C5 76.2(2) .
C1 Os1 O1 35.03(16) .
C5 Os1 O1 111.20(17) .
C1 Os1 Cl2 156.99(16) .
C5 Os1 Cl2 80.83(14) .
O1 Os1 Cl2 167.91(10) .
C1 Os1 P2 90.61(15) .
C5 Os1 P2 95.10(13) .
O1 Os1 P2 88.25(9) .
Cl2 Os1 P2 92.01(5) .
C1 Os1 P1 90.41(15) .
C5 Os1 P1 90.81(13) .
O1 Os1 P1 89.24(9) .
Cl2 Os1 P1 89.33(5) .
P2 Os1 P1 174.07(5) .
C1 Os1 Cl1 116.87(16) .
C5 Os1 Cl1 166.94(15) .
O1 Os1 Cl1 81.85(11) .
Cl2 Os1 Cl1 86.14(5) .
P2 Os1 Cl1 84.50(4) .
P1 Os1 Cl1 89.84(4) .
C31 P1 C11 107.9(2) .
C31 P1 C21 103.6(2) .
C11 P1 C21 98.3(2) .
C31 P1 Os1 110.20(17) .
C11 P1 Os1 114.52(16) .
C21 P1 Os1 120.94(17) .
C41 P2 C51 104.3(2) .
C41 P2 C61 105.1(3) .
C51 P2 C61 101.3(2) .
C41 P2 Os1 108.62(16) .
C51 P2 Os1 117.68(17) .
C61 P2 Os1 118.34(19) .
C8 Si1 C9 105.0(3) .
C8 Si1 C7 111.2(3) .
C9 Si1 C7 107.2(3) .
C8 Si1 C4 114.4(3) .
C9 Si1 C4 109.6(2) .
C7 Si1 C4 109.0(2) .
C1 O1 Os1 63.9(3) .
O1 C1 C2 134.0(6) .
O1 C1 Os1 81.1(4) .
C2 C1 Os1 144.7(4) .
C1 C2 C3 119.6(5) .
C1 C2 Cl3 118.2(4) .
C3 C2 Cl3 122.0(5) .
C2 C3 C4 119.2(5) .
C2 C3 C6 119.0(5) .
C4 C3 C6 121.8(5) .
C5 C4 C3 121.5(5) .
C5 C4 Si1 117.8(4) .
C3 C4 Si1 120.7(4) .
C4 C5 Os1 137.8(4) .
C12 C11 C16 118.9(5) .
C12 C11 P1 116.5(4) .
C16 C11 P1 124.2(5) .
C13 C12 C11 121.6(6) .
C12 C13 C14 119.8(6) .
C15 C14 C13 119.6(6) .
C14 C15 C16 121.5(6) .
C11 C16 C15 118.5(6) .
C22 C21 C26 117.4(5) .
C22 C21 P1 117.9(4) .
C26 C21 P1 124.7(4) .
C23 C22 C21 120.9(6) .
C24 C23 C22 120.4(6) .
C25 C24 C23 119.1(6) .
C24 C25 C26 122.1(6) .
C25 C26 C21 120.1(6) .
C32 C31 C36 118.2(5) .
C32 C31 P1 120.6(4) .
C36 C31 P1 120.5(4) .
C31 C32 C33 120.9(6) .
C34 C33 C32 119.4(6) .
C33 C34 C35 120.2(6) .
C36 C35 C34 120.0(6) .
C35 C36 C31 121.2(5) .
C46 C41 C42 117.2(6) .
C46 C41 P2 122.4(4) .
C42 C41 P2 119.8(5) .
C43 C42 C41 121.5(6) .
C44 C43 C42 120.7(6) .
C43 C44 C45 118.5(7) .
C46 C45 C44 120.3(7) .
C41 C46 C45 121.7(6) .
C52B C51 C52A 51.6(5) .
C52B C51 C56A 81.1(7) .
C52A C51 C56A 119.0(7) .
C52B C51 C56B 117.7(8) .
C52A C51 C56B 91.5(6) .
C56A C51 C56B 77.5(6) .
C52B C51 P2 126.6(7) .
C52A C51 P2 118.9(5) .
C56A C51 P2 120.0(5) .
C56B C51 P2 114.9(5) .
C51 C52A C53A 120.2(9) .
C52A C53A C54A 119.1(10) .
C55A C54A C53A 121.1(11) .
C54A C55A C56A 119.9(10) .
C55A C56A C51 119.5(9) .
C51 C52B C53B 122.1(12) .
C54B C53B C52B 120.5(12) .
C53B C54B C55B 121.6(14) .
C56B C55B C54B 120.2(12) .
C55B C56B C51 117.5(10) .
C66 C61 C62 119.5(6) .
C66 C61 P2 119.9(5) .
C62 C61 P2 120.5(5) .
C61 C62 C63 118.1(7) .
C64 C63 C62 122.2(7) .
C63 C64 C65 119.4(7) .
C64 C65 C66 120.6(8) .
C61 C66 C65 120.2(7) .
C1S C1S C2S 111.4(11) 3_666
C3S C2S C1S 105.2(7) .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Os1 C1 1.937(6) .
Os1 C5 2.044(4) .
Os1 O1 2.131(3) .
Os1 Cl2 2.3894(14) .
Os1 P2 2.4126(14) .
Os1 P1 2.4155(13) .
Os1 Cl1 2.4422(12) .
Cl3 C2 1.738(6) .
P1 C31 1.813(5) .
P1 C11 1.823(5) .
P1 C21 1.826(5) .
P2 C41 1.815(6) .
P2 C51 1.838(5) .
P2 C61 1.839(6) .
Si1 C8 1.856(6) .
Si1 C9 1.861(6) .
Si1 C7 1.863(6) .
Si1 C4 1.894(5) .
O1 C1 1.238(6) .
C1 C2 1.371(7) .
C2 C3 1.390(7) .
C3 C4 1.433(7) .
C3 C6 1.505(7) .
C4 C5 1.371(6) .
C11 C12 1.382(7) .
C11 C16 1.389(7) .
C12 C13 1.367(7) .
C13 C14 1.369(8) .
C14 C15 1.364(8) .
C15 C16 1.393(7) .
C21 C22 1.394(7) .
C21 C26 1.396(7) .
C22 C23 1.382(7) .
C23 C24 1.367(8) .
C24 C25 1.352(7) .
C25 C26 1.368(7) .
C31 C32 1.382(7) .
C31 C36 1.396(7) .
C32 C33 1.399(8) .
C33 C34 1.372(8) .
C34 C35 1.388(8) .
C35 C36 1.365(7) .
C41 C46 1.351(8) .
C41 C42 1.392(7) .
C42 C43 1.379(8) .
C43 C44 1.344(8) .
C44 C45 1.393(8) .
C45 C46 1.381(9) .
C51 C52B 1.318(12) .
C51 C52A 1.354(10) .
C51 C56A 1.407(11) .
C51 C56B 1.512(11) .
C52A C53A 1.395(13) .
C53A C54A 1.408(16) .
C54A C55A 1.323(14) .
C55A C56A 1.402(13) .
C52B C53B 1.427(15) .
C53B C54B 1.306(18) .
C54B C55B 1.405(16) .
C55B C56B 1.379(14) .
C61 C66 1.371(8) .
C61 C62 1.389(8) .
C62 C63 1.398(8) .
C63 C64 1.338(9) .
C64 C65 1.359(9) .
C65 C66 1.386(8) .
C1S C1S 1.365(12) 3_666
C1S C2S 1.480(10) .
C2S C3S 1.462(10) .
