#------------------------------------------------------------------------------
#$Date: 2016-03-22 12:10:19 +0200 (Tue, 22 Mar 2016) $
#$Revision: 178938 $
#$URL: svn://www.crystallography.net/cod/cif/4/11/67/4116710.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4116710
loop_
_publ_author_name
'Laura Crociani'
'Francesco Tisato'
'Fiorenzo Refosco'
'Giuliano Bandoli'
'Benedetto Corain'
'Luigi M. Venanzi'
_publ_contact_author
;
        Giuliano Bandoli
        Dipartimento di Scienze Farmaceutiche
        Universit. di Padova
        Via Marzolo 5
        35131 PADOVA
        Italy
;
_publ_contact_author_email       bandoli@pdfar3.dsfarm.unipd.it
_publ_contact_author_fax         'int.code +(49)8275345'
_publ_contact_author_phone       'int.code +(49)8275344'
_publ_section_title
;
 Synthesis and Characterization of the First Mononuclear NiII Phosphorane
 Imino Complex
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              2973
_journal_page_last               2974
_journal_paper_doi               10.1021/ja9738440
_journal_volume                  120
_journal_year                    1998
_chemical_formula_sum            'C24 H32 Cl F6 N Ni P4'
_chemical_formula_weight         666.55
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL
_cell_angle_alpha                90.00
_cell_angle_beta                 110.17(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   14.464(4)
_cell_length_b                   12.007(4)
_cell_length_c                   18.518(5)
_cell_measurement_reflns_used    50
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      16
_cell_measurement_theta_min      11
_cell_volume                     3018.8(16)
_computing_cell_refinement       'R3 diffractometer software'
_computing_data_collection       'R3 diffractometer software'
_computing_data_reduction        'R3 diffractometer software'
_computing_molecular_graphics    SHELXTL/PC
_computing_publication_material  'SHELXTL/PC(CIFTAB in SHELXL-93)'
_computing_structure_refinement  'SHELXL-93 (Sheldrick, 1993)'
_computing_structure_solution    'SHELXS-86 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measurement_device       'Siemens Nicolet R3m/V diffractometer'
_diffrn_measurement_method       'omega scans '
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1018
_diffrn_reflns_av_sigmaI/netI    0.0504
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            4963
_diffrn_reflns_theta_max         24.06
_diffrn_reflns_theta_min         2.26
_diffrn_standards_decay_%        4
_diffrn_standards_interval_count 150
_diffrn_standards_number         2
_exptl_absorpt_coefficient_mu    0.995
_exptl_absorpt_correction_T_max  1.00
_exptl_absorpt_correction_T_min  0.72
_exptl_absorpt_correction_type   psi-scan
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.467
_exptl_crystal_description       cuboids
_exptl_crystal_F_000             1368
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.15
_refine_diff_density_max         0.584
_refine_diff_density_min         -0.985
_refine_diff_density_rms         0.132
_refine_ls_extinction_coef       0.0000(5)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_all   1.160
_refine_ls_goodness_of_fit_obs   1.190
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     331
_refine_ls_number_reflns         4766
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.160
_refine_ls_restrained_S_obs      1.190
_refine_ls_R_factor_all          0.1080
_refine_ls_R_factor_obs          0.0627
_refine_ls_shift/esd_mean        0.037
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.1000P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.2022
_refine_ls_wR_factor_obs         0.1699
_reflns_number_observed          2555
_reflns_number_total             4766
_reflns_observed_criterion       >2sigma(I)
_cod_data_source_file            ja9738440.cif
_cod_data_source_block
J.Am.Chem.Soc.L.Crociani,F.Tisato,F.Refosco,G.Bandoli
_cod_depositor_comments
;
The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.1000P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3' was
changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.1000P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        3018.8(15)
_cod_database_code               4116710
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
Ni Ni 0.34158(7) 0.11889(9) 0.49282(6) 0.0396(3) Uani 1 d .
Cl Cl 0.4640(2) 0.1161(2) 0.60500(13) 0.0628(7) Uani 1 d .
P1 P 0.21930(14) 0.1103(2) 0.38558(12) 0.0418(6) Uani 1 d .
P2 P 0.43379(15) 0.2330(2) 0.45464(14) 0.0480(6) Uani 1 d .
N1 N 0.2554(5) 0.0196(6) 0.5300(4) 0.045(2) Uani 1 d .
C1 C 0.1672(6) -0.0222(7) 0.3961(5) 0.044(2) Uani 1 d .
C2 C 0.1054(6) -0.0881(8) 0.3372(5) 0.056(2) Uani 1 d .
H2A H 0.0869(6) -0.0628(8) 0.2850(5) 0.067 Uiso 1 d R
C3 C 0.0734(7) -0.1897(9) 0.3552(6) 0.069(3) Uani 1 d .
H3A H 0.0300(7) -0.2345(9) 0.3148(6) 0.083 Uiso 1 d R
C4 C 0.1021(7) -0.2243(9) 0.4294(6) 0.064(3) Uani 1 d .
H4A H 0.0793(7) -0.2945(9) 0.4417(6) 0.077 Uiso 1 d R
C5 C 0.1640(7) -0.1626(9) 0.4870(6) 0.068(3) Uani 1 d .
H5A H 0.1867(7) -0.1895(9) 0.5390(6) 0.082 Uiso 1 d R
C6 C 0.1937(5) -0.0547(7) 0.4715(4) 0.042(2) Uani 1 d .
C7 C 0.3931(8) 0.2950(10) 0.3599(6) 0.090(4) Uiso 1 d .
H7A H 0.3749(8) 0.2373(10) 0.3216(6) 0.135 Uiso 1 calc R
H7B H 0.4456(8) 0.3386(10) 0.3537(6) 0.135 Uiso 1 calc R
H7C H 0.3373(8) 0.3420(10) 0.3539(6) 0.135 Uiso 1 calc R
C8 C 0.5522(6) 0.1732(8) 0.4638(5) 0.065(3) Uiso 1 d .
H8A H 0.5425(6) 0.1068(8) 0.4332(5) 0.097 Uiso 1 calc R
H8B H 0.5871(6) 0.1551(8) 0.5167(5) 0.097 Uiso 1 calc R
H8C H 0.5897(6) 0.2260(8) 0.4463(5) 0.097 Uiso 1 calc R
C9 C 0.4636(8) 0.3560(9) 0.5150(6) 0.079(3) Uiso 1 d .
H9A H 0.4867(8) 0.3340(9) 0.5681(6) 0.119 Uiso 1 calc R
H9B H 0.4059(8) 0.4014(9) 0.5046(6) 0.119 Uiso 1 calc R
H9C H 0.5141(8) 0.3976(9) 0.5044(6) 0.119 Uiso 1 calc R
C10 C 0.1288(6) 0.2183(8) 0.3806(5) 0.050(2) Uani 1 d .
C11 C 0.0302(6) 0.2072(8) 0.3319(5) 0.062(3) Uani 1 d .
H11A H 0.0107(6) 0.1471(8) 0.2956(5) 0.074 Uiso 1 d R
C12 C -0.0369(7) 0.2880(12) 0.3359(7) 0.090(4) Uani 1 d .
H12A H -0.1045(7) 0.2820(12) 0.3031(7) 0.108 Uiso 1 d R
C13 C -0.0093(9) 0.3759(10) 0.3881(7) 0.081(3) Uani 1 d .
H13A H -0.0572(9) 0.4305(10) 0.3895(7) 0.098 Uiso 1 d R
C14 C 0.0857(7) 0.3816(9) 0.4347(7) 0.078(3) Uani 1 d .
H14A H 0.1059(7) 0.4422(9) 0.4706(7) 0.094 Uiso 1 d R
C15 C 0.1555(6) 0.3063(8) 0.4330(5) 0.057(2) Uani 1 d .
H15A H 0.2225(6) 0.3109(8) 0.4672(5) 0.068 Uiso 1 d R
C16 C 0.2346(6) 0.0983(8) 0.2918(5) 0.051(2) Uani 1 d .
C17 C 0.3012(7) 0.0225(8) 0.2848(5) 0.058(2) Uani 1 d .
H17A H 0.3353(7) -0.0234(8) 0.3283(5) 0.070 Uiso 1 d R
C18 C 0.3210(8) 0.0126(9) 0.2187(6) 0.071(3) Uani 1 d .
H18A H 0.3668(8) -0.0423(9) 0.2139(6) 0.085 Uiso 1 d R
C19 C 0.2743(9) 0.0789(12) 0.1573(6) 0.087(4) Uani 1 d .
H19A H 0.2876(9) 0.0732(12) 0.1101(6) 0.104 Uiso 1 d R
C20 C 0.2081(8) 0.1573(10) 0.1631(6) 0.073(3) Uani 1 d .
H20A H 0.1739(8) 0.2028(10) 0.1194(6) 0.088 Uiso 1 d R
C21 C 0.1891(7) 0.1703(9) 0.2303(5) 0.063(3) Uani 1 d .
H21A H 0.1457(7) 0.2278(9) 0.2356(5) 0.075 Uiso 1 d R
P3 P 0.2384(2) 0.0360(2) 0.60971(13) 0.0510(7) Uani 1 d .
C22 C 0.2542(7) 0.1765(8) 0.6397(6) 0.071(3) Uiso 1 d .
H22A H 0.2110(7) 0.2228(8) 0.6001(6) 0.106 Uiso 1 calc R
H22B H 0.3212(7) 0.1984(8) 0.6494(6) 0.106 Uiso 1 calc R
H22C H 0.2390(7) 0.1846(8) 0.6860(6) 0.106 Uiso 1 calc R
C23 C 0.3205(7) -0.0479(8) 0.6863(6) 0.073(3) Uiso 1 d .
H23A H 0.3133(7) -0.1248(8) 0.6713(6) 0.110 Uiso 1 calc R
H23B H 0.3044(7) -0.0385(8) 0.7321(6) 0.110 Uiso 1 calc R
H23C H 0.3873(7) -0.0249(8) 0.6961(6) 0.110 Uiso 1 calc R
C24 C 0.1127(7) 0.0031(9) 0.6029(6) 0.076(3) Uiso 1 d .
H24A H 0.0982(7) -0.0729(9) 0.5867(6) 0.114 Uiso 1 calc R
H24B H 0.0677(7) 0.0516(9) 0.5661(6) 0.114 Uiso 1 calc R
H24C H 0.1060(7) 0.0131(9) 0.6523(6) 0.114 Uiso 1 calc R
P4 P 0.8170(2) -0.0457(3) 0.1376(2) 0.0701(8) Uani 1 d .
F1 F 0.9318(12) -0.0164(16) 0.1558(9) 0.114(5) Uiso 0.50 d P
F2 F 0.8038(11) 0.0673(14) 0.0866(9) 0.099(5) Uiso 0.50 d P
F3 F 0.8706(24) -0.0613(26) 0.0768(18) 0.090(8) Uiso 0.25 d P
F4 F 0.8889(18) -0.1586(20) 0.1732(15) 0.097(7) Uiso 0.33 d P
F5 F 0.7137(16) 0.0245(20) 0.1346(14) 0.093(6) Uiso 0.33 d P
F6 F 0.7642(27) 0.0615(29) 0.1124(19) 0.104(10) Uiso 0.25 d P
F7 F 0.7021(34) -0.0693(47) 0.0803(29) 0.215(21) Uiso 0.33 d P
F8 F 0.7323(20) -0.1315(23) 0.1232(20) 0.083(7) Uiso 0.25 d P
F9 F 0.8194(24) -0.1098(26) 0.0574(16) 0.081(8) Uiso 0.25 d P
F10 F 0.8933(27) 0.0016(31) 0.2181(20) 0.114(11) Uiso 0.25 d P
F11 F 0.7332(20) -0.1212(24) 0.0738(17) 0.109(8) Uiso 0.33 d P
F12 F 0.8904(25) 0.0569(30) 0.1693(21) 0.115(10) Uiso 0.25 d P
F13 F 0.9045(21) -0.1028(29) 0.1310(20) 0.097(8) Uiso 0.25 d P
F14 F 0.8192(28) -0.0491(33) 0.2215(18) 0.103(9) Uiso 0.25 d P
F15 F 0.8272(26) -0.1788(27) 0.1487(18) 0.107(10) Uiso 0.25 d P
F16 F 0.8621(28) -0.1205(33) 0.2196(21) 0.124(11) Uiso 0.25 d P
F17 F 0.7474(29) -0.0317(35) 0.1823(23) 0.121(11) Uiso 0.25 d P
F18 F 0.8415(22) 0.0418(26) 0.2097(17) 0.128(9) Uiso 0.33 d P
F19 F 0.7938(27) -0.0415(34) 0.0486(20) 0.167(13) Uiso 0.33 d P
F20 F 0.7697(22) -0.1215(26) 0.1840(18) 0.090(8) Uiso 0.25 d P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ni Ni 0.3393 1.1124 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
N1 Ni P1 83.1(2)
N1 Ni P2 177.6(2)
P1 Ni P2 97.45(9)
N1 Ni Cl 93.4(2)
P1 Ni Cl 176.00(11)
P2 Ni Cl 86.17(9)
C1 P1 C10 108.3(4)
C1 P1 C16 103.0(4)
C10 P1 C16 109.1(4)
C1 P1 Ni 100.6(3)
C10 P1 Ni 111.1(3)
C16 P1 Ni 123.2(3)
C9 P2 C7 101.1(5)
C9 P2 C8 104.4(5)
C7 P2 C8 103.6(5)
C9 P2 Ni 110.6(4)
C7 P2 Ni 122.7(4)
C8 P2 Ni 112.5(3)
C6 N1 P3 121.2(5)
C6 N1 Ni 113.8(5)
P3 N1 Ni 123.9(4)
C6 C1 C2 120.9(8)
C6 C1 P1 112.4(6)
C2 C1 P1 126.6(7)
C3 C2 C1 119.2(9)
C4 C3 C2 120.2(9)
C5 C4 C3 121.3(10)
C4 C5 C6 120.2(10)
C1 C6 C5 117.8(8)
C1 C6 N1 118.0(7)
C5 C6 N1 124.0(7)
C15 C10 C11 119.5(8)
C15 C10 P1 118.8(6)
C11 C10 P1 121.2(8)
C12 C11 C10 118.1(10)
C13 C12 C11 121.8(9)
C14 C13 C12 117.8(10)
C13 C14 C15 123.4(11)
C14 C15 C10 119.3(9)
C17 C16 C21 118.9(8)
C17 C16 P1 117.6(7)
C21 C16 P1 123.1(7)
C18 C17 C16 121.4(10)
C17 C18 C19 120.3(11)
C18 C19 C20 119.7(10)
C21 C20 C19 120.8(10)
C20 C21 C16 118.9(10)
N1 P3 C22 111.5(4)
N1 P3 C23 112.9(4)
C22 P3 C23 107.8(5)
N1 P3 C24 112.3(4)
C22 P3 C24 104.3(5)
C23 P3 C24 107.6(5)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
Ni N1 2.011(7)
Ni P1 2.159(2)
Ni P2 2.192(2)
Ni Cl 2.217(2)
P1 C1 1.800(8)
P1 C10 1.822(9)
P1 C16 1.829(9)
P2 C9 1.812(10)
P2 C7 1.808(11)
P2 C8 1.810(9)
N1 C6 1.449(10)
N1 P3 1.589(7)
C1 C6 1.372(10)
C1 C2 1.394(11)
C2 C3 1.385(13)
C3 C4 1.356(13)
C4 C5 1.353(13)
C5 C6 1.425(12)
C10 C15 1.396(12)
C10 C11 1.406(11)
C11 C12 1.391(14)
C12 C13 1.394(15)
C13 C14 1.348(14)
C14 C15 1.364(12)
C16 C17 1.364(12)
C16 C21 1.401(12)
C17 C18 1.356(13)
C18 C19 1.361(15)
C19 C20 1.373(15)
C20 C21 1.373(13)
P3 C22 1.766(10)
P3 C23 1.810(10)
P3 C24 1.822(10)
P4 F13 1.48(3)
P4 F14 1.54(3)
P4 F8 1.55(3)
P4 F17 1.52(3)
P4 F6 1.49(3)
P4 F20 1.56(3)
P4 F11 1.64(3)
P4 F19 1.57(3)
P4 F2 1.63(2)
P4 F12 1.60(3)
P4 F1 1.62(2)
P4 F10 1.62(3)
F1 F3 1.52(3)
F1 F12 1.14(3)
F1 F13 1.15(3)
F1 F10 1.46(4)
F1 F4 1.88(3)
F1 F19 2.30(4)
F2 F6 0.86(4)
F2 F12 1.61(3)
F2 F19 1.47(4)
F2 F3 1.86(3)
F3 F19 1.08(4)
F3 F13 1.08(3)
F3 F12 2.16(5)
F4 F15 0.88(3)
F4 F16 1.15(4)
F4 F13 1.11(3)
F5 F17 1.08(4)
F5 F6 1.05(4)
F5 F7 1.48(5)
F6 F12 1.77(5)
F7 F11 0.80(5)
F7 F8 1.07(5)
F7 F9 1.95(6)
F7 F17 1.83(6)
F8 F11 0.93(3)
F8 F20 1.07(3)
F8 F17 1.59(4)
F8 F15 1.41(4)
F9 F19 0.89(4)
F9 F11 1.39(4)
F9 F13 1.49(4)
F10 F18 0.86(4)
F10 F12 1.11(4)
F10 F14 1.25(4)
F10 F16 1.54(5)
F11 F15 1.72(4)
F11 F19 1.48(4)
F12 F18 1.21(4)
F13 F19 1.94(4)
F13 F15 1.56(5)
F14 F16 1.07(4)
F14 F18 1.18(4)
F14 F17 1.06(4)
F14 F20 1.19(4)
F15 F20 1.40(4)
F15 F16 1.42(5)
F16 F20 1.27(4)
F17 F20 1.12(4)
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
N1 Ni P1 C1 -26.7(3)
P2 Ni P1 C1 155.6(3)
Cl Ni P1 C1 0.9(16)
N1 Ni P1 C10 87.7(4)
P2 Ni P1 C10 -89.9(3)
Cl Ni P1 C10 115.3(16)
N1 Ni P1 C16 -140.0(4)
P2 Ni P1 C16 42.3(4)
Cl Ni P1 C16 -112.5(16)
N1 Ni P2 C9 20.9(46)
P1 Ni P2 C9 123.0(4)
Cl Ni P2 C9 -58.7(4)
N1 Ni P2 C7 -98.1(46)
P1 Ni P2 C7 4.0(5)
Cl Ni P2 C7 -177.7(5)
N1 Ni P2 C8 137.3(45)
P1 Ni P2 C8 -120.6(4)
Cl Ni P2 C8 57.7(4)
P1 Ni N1 C6 32.4(5)
P2 Ni N1 C6 134.9(43)
Cl Ni N1 C6 -145.7(5)
P1 Ni N1 P3 -135.4(4)
P2 Ni N1 P3 -33.0(49)
Cl Ni N1 P3 46.4(4)
C10 P1 C1 C6 -95.1(7)
C16 P1 C1 C6 149.4(6)
Ni P1 C1 C6 21.4(6)
C10 P1 C1 C2 84.1(8)
C16 P1 C1 C2 -31.4(8)
Ni P1 C1 C2 -159.4(7)
C6 C1 C2 C3 -2.3(13)
P1 C1 C2 C3 178.5(7)
C1 C2 C3 C4 0.0(14)
C2 C3 C4 C5 -1.7(15)
C3 C4 C5 C6 5.6(15)
C2 C1 C6 C5 6.0(12)
P1 C1 C6 C5 -174.7(6)
C2 C1 C6 N1 -178.0(7)
P1 C1 C6 N1 1.3(9)
C4 C5 C6 C1 -7.7(13)
C4 C5 C6 N1 176.6(8)
P3 N1 C6 C1 141.1(6)
Ni N1 C6 C1 -27.1(9)
P3 N1 C6 C5 -43.1(10)
Ni N1 C6 C5 148.7(7)
C1 P1 C10 C15 124.3(7)
C16 P1 C10 C15 -124.3(7)
Ni P1 C10 C15 14.7(8)
C1 P1 C10 C11 -47.7(8)
C16 P1 C10 C11 63.8(8)
Ni P1 C10 C11 -157.2(7)
C15 C10 C11 C12 2.5(14)
P1 C10 C11 C12 174.4(8)
C10 C11 C12 C13 -2.2(16)
C11 C12 C13 C14 0.8(18)
C12 C13 C14 C15 0.3(18)
C13 C14 C15 C10 0.1(16)
C11 C10 C15 C14 -1.5(13)
P1 C10 C15 C14 -173.6(7)
C1 P1 C16 C17 -66.2(8)
C10 P1 C16 C17 178.9(7)
Ni P1 C16 C17 45.9(9)
C1 P1 C16 C21 120.5(8)
C10 P1 C16 C21 5.6(9)
Ni P1 C16 C21 -127.4(7)
C21 C16 C17 C18 -2.7(14)
P1 C16 C17 C18 -176.2(8)
C16 C17 C18 C19 0.0(16)
C17 C18 C19 C20 1.0(17)
C18 C19 C20 C21 0.7(17)
C19 C20 C21 C16 -3.3(16)
C17 C16 C21 C20 4.3(14)
P1 C16 C21 C20 177.5(7)
C6 N1 P3 C22 -140.4(6)
Ni N1 P3 C22 26.6(6)
C6 N1 P3 C23 98.1(7)
Ni N1 P3 C23 -94.9(5)
C6 N1 P3 C24 -23.8(8)
Ni N1 P3 C24 143.2(5)
