#------------------------------------------------------------------------------
#$Date: 2018-08-20 18:13:25 +0300 (Mon, 20 Aug 2018) $
#$Revision: 209994 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/30/23/4302312.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4302312
loop_
_publ_author_name
'Kornev, Alexander N.'
'Belina, Natalia V.'
'Sushev, Vyacheslav V.'
'Fukin, Georgy K.'
'Baranov, Evgenii V.'
'Kurskiy, Yuriy A.'
'Poddelskii, Andrei I.'
'Abakumov, Gleb A.'
'Lönnecke, Peter'
'Hey-Hawkins, Evamarie'
_publ_section_title
;
 The First Structurally Characterized Metal (κ²N,P)-Phosphinohydrazides:
 The Key to Understanding the Intramolecular Rearrangement
 R₂P--NR'--NR'--M →  R'N=PR₂--NR'--M.
 Metalloderivatives of Diisopropylphosphinohydrazines:
 Synthesis and Properties
;
_journal_coden_ASTM              INOCAJ
_journal_issue                   12
_journal_name_full               'Inorganic chemistry'
_journal_page_first              5574
_journal_page_last               5583
_journal_paper_doi               10.1021/ic900135b
_journal_volume                  48
_journal_year                    2009
_chemical_formula_sum            'C34 H80 Cl6 Co3 N4 O2 P4'
_chemical_formula_weight         1090.39
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_conform_dict_location     ftp://ftp.iucr.org/pub/cif_core.dic
_audit_conform_dict_name         cif_core.dic
_audit_conform_dict_version      2.3
_audit_creation_date             2007-10-24T17:09:34-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                90
_cell_angle_beta                 103.4420(10)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   10.08200(10)
_cell_length_b                   27.9551(2)
_cell_length_c                   18.4152(3)
_cell_measurement_reflns_used    31861
_cell_measurement_temperature    130(2)
_cell_measurement_theta_max      32.2224
_cell_measurement_theta_min      2.526
_cell_volume                     5048.02(10)
_computing_cell_refinement
;
        CrysAlis RED, Oxford Diffraction Ltd.,
        Version 1.171.32.5 (release 08-05-2007 CrysAlis171 .NET)
        (compiled May  8 2007,13:10:02)
;
_computing_data_collection
;
        CrysAlis CCD, Oxford Diffraction Ltd.,
        Version 1.171.32.5 (release 08-05-2007 CrysAlis171 .NET)
        (compiled May  8 2007,13:10:02)
;
_computing_data_reduction
;
        CrysAlis RED, Oxford Diffraction Ltd.,
        Version 1.171.32.5 (release 08-05-2007 CrysAlis171 .NET)
        (compiled May  8 2007,13:10:02)
;
_computing_molecular_graphics    'ORTEP3 for Windows (L. J. Farrugia, 1997)'
_computing_publication_material  'WINGX  (L.J. Farrugia,1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SIR92 (Giacovazzo 1993)'
_diffrn_ambient_temperature      130(2)
_diffrn_detector_area_resol_mean 16.356
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'ccd Xcalibur S'
_diffrn_measurement_method       'ω- amd φ-scans'
_diffrn_orient_matrix_UB_11      -0.0216378336
_diffrn_orient_matrix_UB_12      0.0238967078
_diffrn_orient_matrix_UB_13      -0.0085515932
_diffrn_orient_matrix_UB_21      -0.0019204858
_diffrn_orient_matrix_UB_22      -0.0042209346
_diffrn_orient_matrix_UB_23      -0.0381534137
_diffrn_orient_matrix_UB_31      -0.0689461595
_diffrn_orient_matrix_UB_32      -0.0073720323
_diffrn_orient_matrix_UB_33      -0.0058827178
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0798
_diffrn_reflns_av_unetI/netI     0.0732
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       39
_diffrn_reflns_limit_k_min       -39
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            153679
_diffrn_reflns_theta_full        30.51
_diffrn_reflns_theta_max         30.51
_diffrn_reflns_theta_min         2.54
_exptl_absorpt_coefficient_mu    1.452
_exptl_absorpt_correction_T_max  1
_exptl_absorpt_correction_T_min  0.83553
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
        CrysAlis RED, Oxford Diffraction Ltd.,
        Version 1.171.32.5 (release 08-05-2007 CrysAlis171 .NET)
        (compiled May  8 2007,13:10:02)
        Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'dark red'
_exptl_crystal_density_diffrn    1.435
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             2284
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.2
_refine_diff_density_max         1.441
_refine_diff_density_min         -0.662
_refine_diff_density_rms         0.086
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.968
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     532
_refine_ls_number_reflns         15410
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.968
_refine_ls_R_factor_all          0.0887
_refine_ls_R_factor_gt           0.0406
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0504P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0891
_refine_ls_wR_factor_ref         0.1041
_reflns_number_gt                9319
_reflns_number_total             15410
_reflns_threshold_expression     >2sigma(I)
_cod_duplicate_entry             4338596
_cod_data_source_file            ic900135b_si_001_7.cif
_cod_data_source_block           710341
_cod_database_code               4302312
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Co1 Co 0.73864(3) 0.651762(11) 0.38076(2) 0.01984(8) Uani 1 1 d . . .
Co2 Co 0.85898(3) 0.745647(11) 0.36470(2) 0.01997(8) Uani 1 1 d . . .
Cl1 Cl 0.67999(7) 0.72221(2) 0.43068(4) 0.02605(14) Uani 1 1 d . . .
Cl2 Cl 0.97367(6) 0.68035(2) 0.42549(4) 0.02773(15) Uani 1 1 d . . .
Cl3 Cl 0.74484(7) 0.69466(2) 0.27251(4) 0.02585(14) Uani 1 1 d . . .
P1 P 0.77048(7) 0.58341(2) 0.32905(4) 0.02292(15) Uani 1 1 d . . .
P2 P 0.66588(7) 0.60836(2) 0.46135(4) 0.02133(14) Uani 1 1 d . . .
P3 P 0.77152(6) 0.81054(2) 0.30455(4) 0.02099(14) Uani 1 1 d . . .
P4 P 1.00593(7) 0.79425(2) 0.42939(4) 0.02491(15) Uani 1 1 d . . .
N1 N 0.7321(2) 0.53965(7) 0.38347(13) 0.0272(5) Uani 1 1 d . . .
N2 N 0.6408(2) 0.55095(7) 0.42962(14) 0.0251(5) Uani 1 1 d . . .
N3 N 0.8659(2) 0.85727(7) 0.34566(13) 0.0267(5) Uani 1 1 d . . .
N4 N 1.0041(2) 0.84731(8) 0.38370(14) 0.0268(5) Uani 1 1 d . . .
C1 C 0.6619(3) 0.57900(10) 0.23451(17) 0.0307(6) Uani 1 1 d . . .
C2 C 0.6637(4) 0.53044(12) 0.1971(2) 0.0540(10) Uani 1 1 d . . .
H2A H 0.6292 0.506 0.2261 0.081 Uiso 1 1 calc R . .
H2B H 0.7573 0.5225 0.1948 0.081 Uiso 1 1 calc R . .
H2C H 0.6058 0.5316 0.1464 0.081 Uiso 1 1 calc R . .
C3 C 0.5161(3) 0.59285(12) 0.23646(18) 0.0420(8) Uani 1 1 d . . .
H3A H 0.4594 0.5937 0.1854 0.063 Uiso 1 1 calc R . .
H3B H 0.5163 0.6245 0.2594 0.063 Uiso 1 1 calc R . .
H3C H 0.4791 0.5692 0.2658 0.063 Uiso 1 1 calc R . .
C4 C 0.9407(3) 0.56566(10) 0.31814(18) 0.0338(7) Uani 1 1 d . . .
C5 C 0.9933(3) 0.60016(11) 0.2665(2) 0.0452(8) Uani 1 1 d . . .
H5A H 1.0028 0.6322 0.2885 0.068 Uiso 1 1 calc R . .
H5B H 0.9285 0.6012 0.2177 0.068 Uiso 1 1 calc R . .
H5C H 1.0822 0.5891 0.2601 0.068 Uiso 1 1 calc R . .
C6 C 1.0435(3) 0.55908(11) 0.3925(2) 0.0417(8) Uani 1 1 d . . .
H6A H 1.1293 0.5468 0.3835 0.063 Uiso 1 1 calc R . .
H6B H 1.0073 0.5363 0.4235 0.063 Uiso 1 1 calc R . .
H6C H 1.0601 0.5899 0.4183 0.063 Uiso 1 1 calc R . .
C7 C 0.7519(3) 0.48848(9) 0.37844(18) 0.0356(7) Uani 1 1 d . . .
H7A H 0.787 0.4754 0.4286 0.053 Uiso 1 1 calc R . .
H7B H 0.8173 0.4822 0.3477 0.053 Uiso 1 1 calc R . .
H7C H 0.6646 0.4732 0.3557 0.053 Uiso 1 1 calc R . .
C8 C 0.4966(3) 0.62562(10) 0.47388(17) 0.0288(6) Uani 1 1 d . . .
C9 C 0.3975(3) 0.63581(10) 0.40016(18) 0.0363(7) Uani 1 1 d . . .
H9A H 0.3817 0.6065 0.3703 0.054 Uiso 1 1 calc R . .
H9B H 0.4356 0.6604 0.3731 0.054 Uiso 1 1 calc R . .
H9C H 0.3109 0.6471 0.4094 0.054 Uiso 1 1 calc R . .
C10 C 0.4370(3) 0.58950(12) 0.5203(2) 0.0450(8) Uani 1 1 d . . .
H10A H 0.3491 0.6013 0.5271 0.068 Uiso 1 1 calc R . .
H10B H 0.5 0.5855 0.5692 0.068 Uiso 1 1 calc R . .
H10C H 0.4237 0.5587 0.4943 0.068 Uiso 1 1 calc R . .
C11 C 0.7720(3) 0.60171(10) 0.55562(16) 0.0300(6) Uani 1 1 d . . .
C12 C 0.9026(3) 0.57501(11) 0.55625(18) 0.0395(7) Uani 1 1 d . . .
H12A H 0.9605 0.5945 0.5318 0.059 Uiso 1 1 calc R . .
H12B H 0.8811 0.5447 0.5294 0.059 Uiso 1 1 calc R . .
H12C H 0.9509 0.5686 0.608 0.059 Uiso 1 1 calc R . .
C13 C 0.8009(3) 0.64986(11) 0.59458(17) 0.0416(8) Uani 1 1 d . . .
H13A H 0.8542 0.645 0.6458 0.062 Uiso 1 1 calc R . .
H13B H 0.7145 0.6656 0.5957 0.062 Uiso 1 1 calc R . .
H13C H 0.8525 0.67 0.5674 0.062 Uiso 1 1 calc R . .
C14 C 0.7695(3) 0.80801(10) 0.20456(16) 0.0272(6) Uani 1 1 d . . .
C15 C 0.9097(3) 0.79423(13) 0.19345(18) 0.0449(8) Uani 1 1 d . . .
H15A H 0.9036 0.7881 0.1404 0.067 Uiso 1 1 calc R . .
H15B H 0.9416 0.7653 0.2224 0.067 Uiso 1 1 calc R . .
H15C H 0.974 0.8204 0.2104 0.067 Uiso 1 1 calc R . .
C16 C 0.7151(4) 0.85229(13) 0.1595(2) 0.0528(9) Uani 1 1 d . . .
H16A H 0.7755 0.8795 0.177 0.079 Uiso 1 1 calc R . .
H16B H 0.6233 0.8595 0.1657 0.079 Uiso 1 1 calc R . .
H16C H 0.7115 0.8465 0.1066 0.079 Uiso 1 1 calc R . .
C17 C 0.5982(3) 0.82899(10) 0.30687(17) 0.0276(6) Uani 1 1 d . . .
C18 C 0.4950(3) 0.79128(10) 0.27098(17) 0.0322(7) Uani 1 1 d . . .
H18A H 0.5115 0.7617 0.3003 0.048 Uiso 1 1 calc R . .
H18B H 0.5042 0.785 0.2201 0.048 Uiso 1 1 calc R . .
H18C H 0.4026 0.8029 0.2694 0.048 Uiso 1 1 calc R . .
C19 C 0.5840(3) 0.84231(10) 0.38460(17) 0.0332(7) Uani 1 1 d . . .
H19A H 0.4918 0.8545 0.3819 0.05 Uiso 1 1 calc R . .
H19B H 0.651 0.8671 0.4054 0.05 Uiso 1 1 calc R . .
H19C H 0.5999 0.814 0.4168 0.05 Uiso 1 1 calc R . .
C20 C 0.8461(3) 0.90773(9) 0.3276(2) 0.0407(8) Uani 1 1 d . . .
H20A H 0.8692 0.9267 0.3736 0.061 Uiso 1 1 calc R . .
H20B H 0.7505 0.9134 0.3023 0.061 Uiso 1 1 calc R . .
H20C H 0.9051 0.9172 0.2946 0.061 Uiso 1 1 calc R . .
C21 C 1.1853(3) 0.77698(11) 0.4421(2) 0.0411(8) Uani 1 1 d . . .
H21 H 1.201 0.7496 0.478 0.049 Uiso 1 1 calc R . .
C22 C 1.2116(3) 0.75848(11) 0.3697(2) 0.0485(9) Uani 1 1 d . . .
H22A H 1.1953 0.7841 0.3324 0.073 Uiso 1 1 calc R . .
H22B H 1.1502 0.7316 0.3517 0.073 Uiso 1 1 calc R . .
H22C H 1.3064 0.7477 0.378 0.073 Uiso 1 1 calc R . .
C23 C 1.2803(4) 0.81729(16) 0.4786(3) 0.0882(16) Uani 1 1 d . . .
H23A H 1.3752 0.8065 0.4875 0.132 Uiso 1 1 calc R . .
H23B H 1.2593 0.826 0.5262 0.132 Uiso 1 1 calc R . .
H23C H 1.2673 0.8452 0.4454 0.132 Uiso 1 1 calc R . .
C24 C 0.9677(4) 0.81162(12) 0.51885(19) 0.0476(9) Uani 1 1 d . . .
C25 C 1.0177(5) 0.77520(15) 0.5775(2) 0.0728(13) Uani 1 1 d . . .
H25A H 1.1176 0.7743 0.5891 0.109 Uiso 1 1 calc R . .
H25B H 0.9815 0.7437 0.5596 0.109 Uiso 1 1 calc R . .
H25C H 0.987 0.7835 0.6226 0.109 Uiso 1 1 calc R . .
C26 C 1.0017(7) 0.86168(17) 0.5425(3) 0.132(3) Uani 1 1 d . . .
H26A H 0.962 0.8694 0.5849 0.198 Uiso 1 1 calc R . .
H26B H 0.9645 0.8833 0.5009 0.198 Uiso 1 1 calc R . .
H26C H 1.101 0.8654 0.5574 0.198 Uiso 1 1 calc R . .
H1 H 0.697(3) 0.6029(11) 0.2076(17) 0.035(8) Uiso 1 1 d . . .
H1N H 0.563(3) 0.5447(11) 0.4063(18) 0.039(9) Uiso 1 1 d . . .
H2N H 1.056(3) 0.8482(11) 0.3507(18) 0.041(9) Uiso 1 1 d . . .
H4 H 0.918(3) 0.5343(10) 0.2942(16) 0.035(8) Uiso 1 1 d . . .
H8 H 0.517(3) 0.6553(11) 0.5030(18) 0.041(9) Uiso 1 1 d . . .
H11 H 0.723(3) 0.5818(10) 0.5804(16) 0.026(7) Uiso 1 1 d . . .
H14 H 0.718(3) 0.7840(12) 0.1895(19) 0.051(10) Uiso 1 1 d . . .
H17 H 0.590(3) 0.8539(10) 0.2795(16) 0.026(8) Uiso 1 1 d . . .
H24 H 0.861(4) 0.8161(12) 0.515(2) 0.062(11) Uiso 1 1 d . . .
Co3 Co 0.22529(4) 0.454751(13) 0.23408(2) 0.03215(10) Uani 1 1 d . . .
Cl4 Cl 0.34505(8) 0.49905(3) 0.32747(5) 0.04157(19) Uani 1 1 d . . .
Cl5 Cl -0.00092(7) 0.45819(3) 0.21707(6) 0.0535(3) Uani 1 1 d . . .
Cl6 Cl 0.30580(9) 0.38013(3) 0.23203(5) 0.0487(2) Uani 1 1 d . . .
O1 O 0.2567(2) 0.48399(8) 0.13723(13) 0.0520(6) Uani 1 1 d . . .
C27 C 0.2611(7) 0.45674(19) 0.0746(3) 0.105(2) Uani 1 1 d . . .
H27A H 0.1796 0.4359 0.0611 0.126 Uiso 1 1 calc R . .
H27B H 0.3434 0.4362 0.0849 0.126 Uiso 1 1 calc R . .
C28 C 0.2647(8) 0.4898(2) 0.0136(3) 0.138(3) Uani 1 1 d . . .
H28A H 0.3591 0.4936 0.0074 0.165 Uiso 1 1 calc R . .
H28B H 0.2065 0.478 -0.0339 0.165 Uiso 1 1 calc R . .
C29 C 0.2133(7) 0.5350(2) 0.0344(3) 0.119(2) Uani 1 1 d . . .
H29A H 0.1261 0.5433 -0.0007 0.143 Uiso 1 1 calc R . .
H29B H 0.2798 0.561 0.0335 0.143 Uiso 1 1 calc R . .
C30 C 0.1924(5) 0.52857(14) 0.1119(2) 0.0706(12) Uani 1 1 d . . .
H30A H 0.235 0.5551 0.1447 0.085 Uiso 1 1 calc R . .
H30B H 0.0939 0.5275 0.1112 0.085 Uiso 1 1 calc R . .
O2 O 0.7333(3) 0.85344(11) 0.64826(19) 0.0890(10) Uani 1 1 d . . .
C31 C 0.6158(5) 0.84248(16) 0.5945(3) 0.0762(13) Uani 1 1 d . . .
H31A H 0.6304 0.848 0.5439 0.091 Uiso 1 1 calc R . .
H31B H 0.5391 0.8628 0.6012 0.091 Uiso 1 1 calc R . .
C32 C 0.5847(5) 0.79105(18) 0.6043(3) 0.0992(18) Uani 1 1 d . . .
H32A H 0.4979 0.7877 0.6202 0.119 Uiso 1 1 calc R . .
H32B H 0.577 0.7734 0.5569 0.119 Uiso 1 1 calc R . .
C33 C 0.7002(5) 0.77241(17) 0.6627(3) 0.0876(16) Uani 1 1 d . . .
H33A H 0.6681 0.7502 0.6968 0.105 Uiso 1 1 calc R . .
H33B H 0.7677 0.7558 0.6402 0.105 Uiso 1 1 calc R . .
C34 C 0.7580(5) 0.81609(16) 0.7016(3) 0.0771(13) Uani 1 1 d . . .
H34A H 0.7139 0.8233 0.7431 0.093 Uiso 1 1 calc R . .
H34B H 0.8572 0.8122 0.7224 0.093 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.006 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P2 Co1 P1 85.22(3) . . ?
P2 Co1 Cl1 92.64(3) . . ?
P1 Co1 Cl1 173.76(3) . . ?
P2 Co1 Cl3 161.54(3) . . ?
P1 Co1 Cl3 92.35(3) . . ?
Cl1 Co1 Cl3 87.83(2) . . ?
P2 Co1 Cl2 113.93(3) . . ?
P1 Co1 Cl2 101.67(3) . . ?
Cl1 Co1 Cl2 84.56(2) . . ?
Cl3 Co1 Cl2 84.50(2) . . ?
P2 Co1 Co2 141.40(2) . . ?
P1 Co1 Co2 129.06(2) . . ?
Cl1 Co1 Co2 55.059(18) . . ?
Cl3 Co1 Co2 50.378(17) . . ?
Cl2 Co1 Co2 49.700(17) . . ?
P4 Co2 P3 84.37(3) . . ?
P4 Co2 Cl2 91.61(3) . . ?
P3 Co2 Cl2 173.62(3) . . ?
P4 Co2 Cl3 163.21(3) . . ?
P3 Co2 Cl3 93.78(3) . . ?
Cl2 Co2 Cl3 88.64(3) . . ?
P4 Co2 Cl1 112.33(3) . . ?
P3 Co2 Cl1 102.23(3) . . ?
Cl2 Co2 Cl1 83.87(2) . . ?
Cl3 Co2 Cl1 84.39(2) . . ?
P4 Co2 Co1 139.08(2) . . ?
P3 Co2 Co1 131.40(2) . . ?
Cl2 Co2 Co1 54.253(18) . . ?
Cl3 Co2 Co1 51.313(18) . . ?
Cl1 Co2 Co1 49.541(16) . . ?
Co1 Cl1 Co2 75.40(2) . . ?
Co2 Cl2 Co1 76.05(2) . . ?
Co2 Cl3 Co1 78.31(2) . . ?
N1 P1 C1 110.34(13) . . ?
N1 P1 C4 102.61(12) . . ?
C1 P1 C4 104.13(14) . . ?
N1 P1 Co1 107.34(8) . . ?
C1 P1 Co1 110.85(9) . . ?
C4 P1 Co1 121.11(10) . . ?
N2 P2 C11 103.74(12) . . ?
N2 P2 C8 102.80(12) . . ?
C11 P2 C8 105.28(14) . . ?
N2 P2 Co1 109.76(9) . . ?
C11 P2 Co1 119.36(10) . . ?
C8 P2 Co1 114.19(9) . . ?
N3 P3 C17 102.29(12) . . ?
N3 P3 C14 110.66(12) . . ?
C17 P3 C14 104.22(13) . . ?
N3 P3 Co2 107.11(8) . . ?
C17 P3 Co2 119.55(9) . . ?
C14 P3 Co2 112.48(9) . . ?
N4 P4 C21 100.93(13) . . ?
N4 P4 C24 103.40(14) . . ?
C21 P4 C24 111.12(18) . . ?
N4 P4 Co2 110.43(8) . . ?
C21 P4 Co2 115.82(11) . . ?
C24 P4 Co2 113.64(12) . . ?
N2 N1 C7 111.9(2) . . ?
N2 N1 P1 117.63(16) . . ?
C7 N1 P1 128.7(2) . . ?
N1 N2 P2 110.32(16) . . ?
N4 N3 C20 111.5(2) . . ?
N4 N3 P3 116.81(16) . . ?
C20 N3 P3 128.0(2) . . ?
N3 N4 P4 107.95(16) . . ?
C2 C1 C3 110.4(3) . . ?
C2 C1 P1 115.0(2) . . ?
C3 C1 P1 109.0(2) . . ?
C6 C4 C5 111.8(3) . . ?
C6 C4 P1 113.0(2) . . ?
C5 C4 P1 111.3(2) . . ?
C9 C8 C10 111.2(2) . . ?
C9 C8 P2 112.0(2) . . ?
C10 C8 P2 113.1(2) . . ?
C12 C11 C13 111.3(3) . . ?
C12 C11 P2 112.0(2) . . ?
C13 C11 P2 111.4(2) . . ?
C16 C14 C15 111.1(3) . . ?
C16 C14 P3 115.8(2) . . ?
C15 C14 P3 110.5(2) . . ?
C19 C17 C18 112.0(2) . . ?
C19 C17 P3 113.0(2) . . ?
C18 C17 P3 110.79(19) . . ?
C22 C21 C23 114.8(3) . . ?
C22 C21 P4 110.4(2) . . ?
C23 C21 P4 111.1(3) . . ?
C26 C24 C25 114.7(4) . . ?
C26 C24 P4 115.5(3) . . ?
C25 C24 P4 111.3(3) . . ?
O1 Co3 Cl5 102.71(7) . . ?
O1 Co3 Cl4 106.47(7) . . ?
Cl5 Co3 Cl4 115.88(3) . . ?
O1 Co3 Cl6 103.08(7) . . ?
Cl5 Co3 Cl6 113.58(3) . . ?
Cl4 Co3 Cl6 113.33(4) . . ?
C27 O1 C30 107.8(3) . . ?
C27 O1 Co3 122.9(3) . . ?
C30 O1 Co3 118.7(2) . . ?
O1 C27 C28 107.6(4) . . ?
C29 C28 C27 105.9(4) . . ?
C28 C29 C30 106.5(4) . . ?
O1 C30 C29 105.1(4) . . ?
C31 O2 C34 108.3(3) . . ?
O2 C31 C32 107.2(4) . . ?
C33 C32 C31 105.9(4) . . ?
C34 C33 C32 102.6(4) . . ?
O2 C34 C33 106.8(4) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Co1 P2 2.1723(7) . ?
Co1 P1 2.1915(7) . ?
Co1 Cl1 2.3077(7) . ?
Co1 Cl3 2.3396(7) . ?
Co1 Cl2 2.4546(7) . ?
Co1 Co2 2.9351(4) . ?
Co2 P4 2.1540(8) . ?
Co2 P3 2.2003(7) . ?
Co2 Cl2 2.3066(7) . ?
Co2 Cl3 2.3087(7) . ?
Co2 Cl1 2.4863(7) . ?
P1 N1 1.682(2) . ?
P1 C1 1.833(3) . ?
P1 C4 1.842(3) . ?
P2 N2 1.707(2) . ?
P2 C11 1.825(3) . ?
P2 C8 1.839(3) . ?
P3 N3 1.688(2) . ?
P3 C17 1.832(3) . ?
P3 C14 1.838(3) . ?
P4 N4 1.703(2) . ?
P4 C21 1.833(3) . ?
P4 C24 1.842(3) . ?
N1 N2 1.426(3) . ?
N1 C7 1.450(3) . ?
N3 N4 1.434(3) . ?
N3 C20 1.453(3) . ?
C1 C2 1.524(4) . ?
C1 C3 1.529(4) . ?
C4 C6 1.525(4) . ?
C4 C5 1.533(4) . ?
C8 C9 1.514(4) . ?
C8 C10 1.533(4) . ?
C11 C12 1.511(4) . ?
C11 C13 1.521(4) . ?
C14 C16 1.520(4) . ?
C14 C15 1.524(4) . ?
C17 C19 1.518(4) . ?
C17 C18 1.520(4) . ?
C21 C22 1.510(5) . ?
C21 C23 1.530(5) . ?
C24 C26 1.482(5) . ?
C24 C25 1.485(5) . ?
Co3 O1 2.052(2) . ?
Co3 Cl5 2.2308(8) . ?
Co3 Cl4 2.2325(9) . ?
Co3 Cl6 2.2419(8) . ?
O1 C27 1.392(5) . ?
O1 C30 1.432(4) . ?
C27 C28 1.462(7) . ?
C28 C29 1.450(7) . ?
C29 C30 1.501(6) . ?
O2 C31 1.390(5) . ?
O2 C34 1.416(5) . ?
C31 C32 1.491(6) . ?
C32 C33 1.484(6) . ?
C33 C34 1.467(6) . ?
