#------------------------------------------------------------------------------
#$Date: 2016-03-23 00:56:45 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179136 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/98/4309873.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4309873
loop_
_publ_author_name
'P. Chandrasekaran'
'Joel T. Mague'
'Maravanji S. Balakrishna'
_publ_section_title
;
Cyclodiphosphazanes with Hemilabile Ponytails: Synthesis, Transition
Metal Chemistry (Ru(II), Rh(I), Pd(II), Pt(II)), and Crystal and Molecular
Structures of Mononuclear (Pd(II), Rh(I)) and Bi- and Tetranuclear
Rhodium(I) Complexes
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              7925
_journal_page_last               7932
_journal_paper_doi               10.1021/ic0509478
_journal_volume                  44
_journal_year                    2005
_chemical_formula_moiety         'C16 H32 Cl2 N2 O6 P2 Rh2'
_chemical_formula_sum            'C16 H32 Cl2 N2 O6 P2 Rh2'
_chemical_formula_weight         687.10
_chemical_name_systematic
; 
 Tetra(μ-chloro)tetracarbonylbis(μ-(1,3-di-tert
-butyl-2,4-bis(2-methoxyethoxy)-[1,3,2,4]
diazadiphosphetidine,κ,P;κ,P)tetrarhodium(I)
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 99.753(1)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   9.3390(9)
_cell_length_b                   18.286(2)
_cell_length_c                   14.916(1)
_cell_measurement_reflns_used    7050
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      28.27
_cell_measurement_theta_min      2.62
_cell_volume                     2510.4(4)
_computing_cell_refinement       'Bruker SMART (Bruker-AXS, 2000)'
_computing_data_collection       'Bruker SMART (Bruker-AXS, 2000)'
_computing_data_reduction        'Bruker SAINT+ (Bruker-AXS, 2002)'
_computing_molecular_graphics    'Bruker SHELXTL (Bruker-AXS, 2000a)'
_computing_publication_material  'Bruker SHELXTL (Bruker-AXS, 2000a)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.976
_diffrn_measured_fraction_theta_max 0.976
_diffrn_measurement_device_type  'BRUKER-AXS APEX CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0259
_diffrn_reflns_av_sigmaI/netI    0.0249
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            21656
_diffrn_reflns_theta_full        27.69
_diffrn_reflns_theta_max         27.69
_diffrn_reflns_theta_min         1.78
_exptl_absorpt_coefficient_mu    1.688
_exptl_absorpt_correction_T_max  0.8726
_exptl_absorpt_correction_T_min  0.7208
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 2002)'
_exptl_crystal_colour            Yellow
_exptl_crystal_density_diffrn    1.818
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Column
_exptl_crystal_F_000             1376
_exptl_crystal_size_max          0.21
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.08
_refine_diff_density_max         1.745
_refine_diff_density_min         -0.800
_refine_diff_density_rms         0.120
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.095
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     286
_refine_ls_number_reflns         5749
_refine_ls_number_restraints     3
_refine_ls_restrained_S_all      1.095
_refine_ls_R_factor_all          0.0368
_refine_ls_R_factor_gt           0.0320
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0424P)²+4.1258P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0816
_refine_ls_wR_factor_ref         0.0839
_reflns_number_gt                5139
_reflns_number_total             5749
_reflns_threshold_expression     >2\sw(I)
_cod_data_source_file            ic0509478si20050611_094104.cif
_cod_data_source_block           msb165
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'multiscan' changed to
'multi-scan' according to
'/home/saulius/struct/CIF-dictionaries/cif_core.dic' dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_database_code               4309873
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 1.05356(3) 0.092782(13) 0.317765(16) 0.01740(8) Uani 1 1 d . . .
Rh2 Rh 1.23579(3) 0.138223(13) 0.531685(17) 0.01813(8) Uani 1 1 d . . .
Cl1 Cl 1.00938(11) 0.08714(5) 0.46935(6) 0.0370(2) Uani 1 1 d . . .
Cl2 Cl 1.23494(9) 0.18276(4) 0.37820(5) 0.02224(16) Uani 1 1 d . . .
P1 P 0.88695(9) 0.01177(4) 0.26620(5) 0.01670(16) Uani 1 1 d . . .
P2 P 1.23849(9) 0.09326(4) 0.66865(6) 0.01775(16) Uani 1 1 d . . .
O1 O 1.1210(3) 0.10815(18) 0.13233(18) 0.0430(7) Uani 1 1 d . . .
O2 O 0.8415(2) 0.02371(12) 0.15916(15) 0.0211(5) Uani 1 1 d . . .
O3 O 0.6255(4) 0.08623(15) 0.0142(2) 0.0485(8) Uani 1 1 d . . .
O4 O 1.5201(3) 0.20893(17) 0.58923(19) 0.0386(7) Uani 1 1 d . . .
O5 O 1.3582(3) 0.12622(12) 0.74764(16) 0.0233(5) Uani 1 1 d . . .
O6 O 1.2539(3) 0.20520(14) 0.88905(18) 0.0330(6) Uani 1 1 d . . .
N1 N 0.7356(3) -0.00268(13) 0.31169(18) 0.0177(5) Uani 1 1 d . . .
N2 N 1.0844(3) 0.07838(14) 0.71147(18) 0.0188(5) Uani 1 1 d . . .
C1 C 1.0928(4) 0.10201(19) 0.2027(2) 0.0264(7) Uani 1 1 d . . .
C2 C 0.6134(4) 0.04627(17) 0.3260(2) 0.0228(7) Uani 1 1 d D . .
C3 C 0.4688(6) 0.0064(4) 0.2933(5) 0.0398(14) Uani 0.627(5) 1 d PD A 1
H3A H 0.4581 -0.0029 0.2278 0.060 Uiso 0.627(5) 1 calc PR A 1
H3B H 0.3880 0.0369 0.3056 0.060 Uiso 0.627(5) 1 calc PR A 1
H3C H 0.4682 -0.0402 0.3258 0.060 Uiso 0.627(5) 1 calc PR A 1
C4 C 0.6270(9) 0.0605(5) 0.4284(4) 0.0450(18) Uani 0.627(5) 1 d PD A 1
H4A H 0.7186 0.0859 0.4503 0.067 Uiso 0.627(5) 1 calc PR A 1
H4B H 0.6256 0.0138 0.4605 0.067 Uiso 0.627(5) 1 calc PR A 1
H4C H 0.5455 0.0908 0.4398 0.067 Uiso 0.627(5) 1 calc PR A 1
C5 C 0.6193(8) 0.1154(3) 0.2736(6) 0.0407(17) Uani 0.627(5) 1 d PD A 1
H5A H 0.7114 0.1406 0.2951 0.061 Uiso 0.627(5) 1 calc PR A 1
H5B H 0.5382 0.1472 0.2824 0.061 Uiso 0.627(5) 1 calc PR A 1
H5C H 0.6121 0.1040 0.2088 0.061 Uiso 0.627(5) 1 calc PR A 1
C3A C 0.4897(10) 0.0419(6) 0.2437(8) 0.0398(14) Uani 0.373(5) 1 d PD A 2
H3AA H 0.4497 -0.0078 0.2387 0.060 Uiso 0.373(5) 1 calc PR A 2
H3AB H 0.5276 0.0540 0.1881 0.060 Uiso 0.373(5) 1 calc PR A 2
H3AC H 0.4130 0.0766 0.2517 0.060 Uiso 0.373(5) 1 calc PR A 2
C4A C 0.5585(15) 0.0276(8) 0.4121(8) 0.0450(18) Uani 0.373(5) 1 d PD A 2
H4AA H 0.5233 -0.0230 0.4089 0.067 Uiso 0.373(5) 1 calc PR A 2
H4AB H 0.4789 0.0607 0.4196 0.067 Uiso 0.373(5) 1 calc PR A 2
H4AC H 0.6376 0.0329 0.4641 0.067 Uiso 0.373(5) 1 calc PR A 2
C5A C 0.6680(13) 0.1253(5) 0.3294(10) 0.0407(17) Uani 0.373(5) 1 d PD A 2
H5AA H 0.7476 0.1311 0.3809 0.061 Uiso 0.373(5) 1 calc PR A 2
H5AB H 0.5884 0.1584 0.3368 0.061 Uiso 0.373(5) 1 calc PR A 2
H5AC H 0.7029 0.1369 0.2727 0.061 Uiso 0.373(5) 1 calc PR A 2
C6 C 0.7340(4) -0.01894(18) 0.0997(2) 0.0248(7) Uani 1 1 d . . .
H6A H 0.6444 -0.0237 0.1265 0.030 Uiso 1 1 calc R . .
H6B H 0.7720 -0.0686 0.0913 0.030 Uiso 1 1 calc R . .
C7 C 0.7011(5) 0.0201(2) 0.0096(3) 0.0337(8) Uani 1 1 d . . .
H7A H 0.7935 0.0304 -0.0122 0.040 Uiso 1 1 calc R . .
H7B H 0.6425 -0.0125 -0.0354 0.040 Uiso 1 1 calc R . .
C8 C 0.7165(6) 0.1488(2) 0.0342(3) 0.0488(12) Uani 1 1 d . . .
H8A H 0.7689 0.1455 0.0968 0.073 Uiso 1 1 calc R . .
H8B H 0.6567 0.1932 0.0274 0.073 Uiso 1 1 calc R . .
H8C H 0.7864 0.1508 -0.0079 0.073 Uiso 1 1 calc R . .
C9 C 1.4096(4) 0.18118(19) 0.5691(2) 0.0255(7) Uani 1 1 d . . .
C10 C 0.9529(4) 0.12348(19) 0.7193(3) 0.0261(7) Uani 1 1 d . . .
C11 C 0.9865(4) 0.20306(19) 0.7002(3) 0.0332(8) Uani 1 1 d . . .
H11A H 1.0658 0.2206 0.7468 0.050 Uiso 1 1 calc R . .
H11B H 0.8998 0.2330 0.7012 0.050 Uiso 1 1 calc R . .
H11C H 1.0155 0.2067 0.6402 0.050 Uiso 1 1 calc R . .
C12 C 0.8234(4) 0.0965(2) 0.6532(3) 0.0402(10) Uani 1 1 d . . .
H12A H 0.8411 0.1033 0.5909 0.060 Uiso 1 1 calc R . .
H12B H 0.7369 0.1242 0.6618 0.060 Uiso 1 1 calc R . .
H12C H 0.8080 0.0445 0.6641 0.060 Uiso 1 1 calc R . .
C13 C 0.9231(5) 0.1165(2) 0.8170(3) 0.0396(10) Uani 1 1 d . . .
H13A H 0.9062 0.0651 0.8303 0.059 Uiso 1 1 calc R . .
H13B H 0.8370 0.1453 0.8235 0.059 Uiso 1 1 calc R . .
H13C H 1.0071 0.1347 0.8596 0.059 Uiso 1 1 calc R . .
C14 C 1.3893(4) 0.20258(18) 0.7682(2) 0.0283(8) Uani 1 1 d . . .
H14A H 1.3127 0.2338 0.7335 0.034 Uiso 1 1 calc R . .
H14B H 1.4837 0.2162 0.7511 0.034 Uiso 1 1 calc R . .
C15 C 1.3945(4) 0.2133(2) 0.8685(2) 0.0301(8) Uani 1 1 d . . .
H15A H 1.4605 0.1768 0.9027 0.036 Uiso 1 1 calc R . .
H15B H 1.4322 0.2627 0.8865 0.036 Uiso 1 1 calc R . .
C16 C 1.2544(6) 0.2153(3) 0.9840(3) 0.0487(12) Uani 1 1 d . . .
H16A H 1.3234 0.1810 1.0187 0.073 Uiso 1 1 calc R . .
H16B H 1.1568 0.2061 0.9974 0.073 Uiso 1 1 calc R . .
H16C H 1.2834 0.2655 1.0011 0.073 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Rh1 P1 88.63(11) . . ?
C1 Rh1 Cl1 176.77(11) . . ?
P1 Rh1 Cl1 94.44(3) . . ?
C1 Rh1 Cl2 92.75(11) . . ?
P1 Rh1 Cl2 178.54(3) . . ?
Cl1 Rh1 Cl2 84.16(3) . . ?
C9 Rh2 P2 90.40(11) . . ?
C9 Rh2 Cl1 174.62(11) . . ?
P2 Rh2 Cl1 94.98(3) . . ?
C9 Rh2 Cl2 90.28(11) . . ?
P2 Rh2 Cl2 177.59(3) . . ?
Cl1 Rh2 Cl2 84.35(3) . . ?
Rh2 Cl1 Rh1 93.99(3) . . ?
Rh1 Cl2 Rh2 90.77(3) . . ?
O2 P1 N1 108.91(13) . . ?
O2 P1 N2 109.64(13) . 3_756 ?
N1 P1 N2 83.33(13) . 3_756 ?
O2 P1 Rh1 108.16(9) . . ?
N1 P1 Rh1 123.88(10) . . ?
N2 P1 Rh1 120.64(10) 3_756 . ?
O2 P1 P2 115.23(9) . 3_756 ?
N1 P1 P2 41.67(9) . 3_756 ?
N2 P1 P2 41.69(9) 3_756 3_756 ?
Rh1 P1 P2 136.58(4) . 3_756 ?
O5 P2 N1 100.35(13) . 3_756 ?
O5 P2 N2 108.41(14) . . ?
N1 P2 N2 83.30(12) 3_756 . ?
O5 P2 Rh2 116.13(9) . . ?
N1 P2 Rh2 120.38(10) 3_756 . ?
N2 P2 Rh2 122.28(10) . . ?
O5 P2 P1 108.36(9) . 3_756 ?
N1 P2 P1 41.57(9) 3_756 3_756 ?
N2 P2 P1 41.74(9) . 3_756 ?
Rh2 P2 P1 135.09(4) . 3_756 ?
C6 O2 P1 125.3(2) . . ?
C7 O3 C8 114.4(4) . . ?
C14 O5 P2 127.6(2) . . ?
C15 O6 C16 110.9(3) . . ?
C2 N1 P1 132.5(2) . . ?
C2 N1 P2 130.7(2) . 3_756 ?
P1 N1 P2 96.76(13) . 3_756 ?
C10 N2 P2 134.5(2) . . ?
C10 N2 P1 128.6(2) . 3_756 ?
P2 N2 P1 96.57(13) . 3_756 ?
O1 C1 Rh1 178.1(3) . . ?
C5 C2 N1 109.6(3) . . ?
C5 C2 C4A 133.6(6) . . ?
N1 C2 C4A 111.5(5) . . ?
C5 C2 C5A 34.5(5) . . ?
N1 C2 C5A 108.2(5) . . ?
C4A C2 C5A 110.3(8) . . ?
C5 C2 C4 112.0(5) . . ?
N1 C2 C4 107.9(3) . . ?
C4A C2 C4 33.8(6) . . ?
C5A C2 C4 80.5(7) . . ?
C5 C2 C3A 73.5(6) . . ?
N1 C2 C3A 110.0(5) . . ?
C4A C2 C3A 110.6(8) . . ?
C5A C2 C3A 106.1(7) . . ?
C4 C2 C3A 136.7(6) . . ?
C5 C2 C3 110.1(5) . . ?
N1 C2 C3 108.7(3) . . ?
C4A C2 C3 75.8(7) . . ?
C5A C2 C3 136.6(6) . . ?
C4 C2 C3 108.4(5) . . ?
C3A C2 C3 39.0(5) . . ?
C2 C3 H3A 109.5 . . ?
C2 C3 H3B 109.5 . . ?
H3A C3 H3B 109.5 . . ?
C2 C3 H3C 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
C2 C4 H4A 109.5 . . ?
C2 C4 H4B 109.5 . . ?
H4A C4 H4B 109.5 . . ?
C2 C4 H4C 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
C2 C5 H5A 109.5 . . ?
C2 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
C2 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
C2 C3A H3AA 109.5 . . ?
C2 C3A H3AB 109.5 . . ?
H3AA C3A H3AB 109.5 . . ?
C2 C3A H3AC 109.5 . . ?
H3AA C3A H3AC 109.5 . . ?
H3AB C3A H3AC 109.5 . . ?
C2 C4A H4AA 109.5 . . ?
C2 C4A H4AB 109.5 . . ?
H4AA C4A H4AB 109.5 . . ?
C2 C4A H4AC 109.5 . . ?
H4AA C4A H4AC 109.5 . . ?
H4AB C4A H4AC 109.5 . . ?
C2 C5A H5AA 109.5 . . ?
C2 C5A H5AB 109.5 . . ?
H5AA C5A H5AB 109.5 . . ?
C2 C5A H5AC 109.5 . . ?
H5AA C5A H5AC 109.5 . . ?
H5AB C5A H5AC 109.5 . . ?
O2 C6 C7 107.8(3) . . ?
O2 C6 H6A 110.1 . . ?
C7 C6 H6A 110.1 . . ?
O2 C6 H6B 110.1 . . ?
C7 C6 H6B 110.1 . . ?
H6A C6 H6B 108.5 . . ?
O3 C7 C6 113.0(3) . . ?
O3 C7 H7A 109.0 . . ?
C6 C7 H7A 109.0 . . ?
O3 C7 H7B 109.0 . . ?
C6 C7 H7B 109.0 . . ?
H7A C7 H7B 107.8 . . ?
O3 C8 H8A 109.5 . . ?
O3 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
O3 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
O4 C9 Rh2 177.2(3) . . ?
N2 C10 C12 110.2(3) . . ?
N2 C10 C11 108.2(3) . . ?
C12 C10 C11 111.0(3) . . ?
N2 C10 C13 108.1(3) . . ?
C12 C10 C13 109.8(3) . . ?
C11 C10 C13 109.4(3) . . ?
C10 C11 H11A 109.5 . . ?
C10 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
C10 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
C10 C12 H12A 109.5 . . ?
C10 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
C10 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
C10 C13 H13A 109.5 . . ?
C10 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
C10 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
O5 C14 C15 108.0(3) . . ?
O5 C14 H14A 110.1 . . ?
C15 C14 H14A 110.1 . . ?
O5 C14 H14B 110.1 . . ?
C15 C14 H14B 110.1 . . ?
H14A C14 H14B 108.4 . . ?
O6 C15 C14 109.3(3) . . ?
O6 C15 H15A 109.8 . . ?
C14 C15 H15A 109.8 . . ?
O6 C15 H15B 109.8 . . ?
C14 C15 H15B 109.8 . . ?
H15A C15 H15B 108.3 . . ?
O6 C16 H16A 109.5 . . ?
O6 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
O6 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 C1 1.822(4) . ?
Rh1 P1 2.1912(8) . ?
Rh1 Cl1 2.3684(10) . ?
Rh1 Cl2 2.4232(8) . ?
Rh2 C9 1.804(4) . ?
Rh2 P2 2.1984(8) . ?
Rh2 Cl1 2.3541(10) . ?
Rh2 Cl2 2.4286(8) . ?
P1 O2 1.596(2) . ?
P1 N1 1.689(3) . ?
P1 N2 1.694(3) 3_756 ?
P1 P2 2.5281(11) 3_756 ?
P2 O5 1.598(2) . ?
P2 N1 1.692(3) 3_756 ?
P2 N2 1.693(3) . ?
P2 P1 2.5282(11) 3_756 ?
O1 C1 1.130(4) . ?
O2 C6 1.449(4) . ?
O3 C7 1.409(5) . ?
O3 C8 1.426(5) . ?
O4 C9 1.144(4) . ?
O5 C14 1.449(4) . ?
O6 C15 1.405(4) . ?
O6 C16 1.428(5) . ?
N1 C2 1.494(4) . ?
N1 P2 1.692(3) 3_756 ?
N2 C10 1.500(4) . ?
N2 P1 1.694(3) 3_756 ?
C2 C5 1.493(7) . ?
C2 C4A 1.501(11) . ?
C2 C5A 1.530(11) . ?
C2 C4 1.533(7) . ?
C2 C3A 1.539(10) . ?
C2 C3 1.539(7) . ?
C3 H3A 0.9800 . ?
C3 H3B 0.9800 . ?
C3 H3C 0.9800 . ?
C4 H4A 0.9800 . ?
C4 H4B 0.9800 . ?
C4 H4C 0.9800 . ?
C5 H5A 0.9800 . ?
C5 H5B 0.9800 . ?
C5 H5C 0.9800 . ?
C3A H3AA 0.9800 . ?
C3A H3AB 0.9800 . ?
C3A H3AC 0.9800 . ?
C4A H4AA 0.9800 . ?
C4A H4AB 0.9800 . ?
C4A H4AC 0.9800 . ?
C5A H5AA 0.9800 . ?
C5A H5AB 0.9800 . ?
C5A H5AC 0.9800 . ?
C6 C7 1.507(5) . ?
C6 H6A 0.9900 . ?
C6 H6B 0.9900 . ?
C7 H7A 0.9900 . ?
C7 H7B 0.9900 . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C10 C12 1.508(6) . ?
C10 C11 1.525(5) . ?
C10 C13 1.535(5) . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C14 C15 1.500(5) . ?
C14 H14A 0.9900 . ?
C14 H14B 0.9900 . ?
C15 H15A 0.9900 . ?
C15 H15B 0.9900 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
