#------------------------------------------------------------------------------
#$Date: 2016-02-16 22:30:59 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176467 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/65/4316571.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4316571
loop_
_publ_author_name
'Vitor Rosa'
'Carla I. M. Santos'
'Richard Welter'
'Gabriel Aullón'
'Carlos Lodeiro'
'Teresa Avilés'
_publ_contact_author_address
;
Institut Le Bel, rue Blaise Pascal, 67000 STRASBOURG, FRANCE
;
_publ_contact_author_email       welter@chimie.u-strasbg.fr
_publ_contact_author_fax         0390241232
_publ_contact_author_name
;
Richard Welter
;
_publ_contact_author_phone       0390241593
_publ_section_title
;
 Comparison of the Structure and Stability of New α-Diimine Complexes of
 Copper(I) and Silver(I): Density Functional Theory versus Experimental
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              8699
_journal_page_last               8708
_journal_paper_doi               10.1021/ic100450y
_journal_volume                  49
_journal_year                    2010
_chemical_formula_moiety         'C72 H80 Ag N4, B F4, 5/2 (C H2 Cl2)'
_chemical_formula_sum            'C74.5 H85 Ag B Cl5 F4 N4'
_chemical_formula_weight         1408.40
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 101.8980(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   20.886(3)
_cell_length_b                   15.096(4)
_cell_length_c                   25.225(6)
_cell_measurement_reflns_used    17793
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      27.49
_cell_measurement_theta_min      1.58
_cell_volume                     7782(3)
_computing_cell_refinement       'Denzo (Nonius B.V., 1998)'
_computing_data_collection       'Collect (Nonius B.V., 1998)'
_computing_data_reduction        'Denzo (Nonius B.V., 1998)'
_computing_molecular_graphics    'PLATON 98 (Spek, 1998)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  KappaCCD
_diffrn_measurement_method       'π scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0000
_diffrn_reflns_av_sigmaI/netI    0.0839
_diffrn_reflns_limit_h_max       26
_diffrn_reflns_limit_h_min       -27
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            17793
_diffrn_reflns_theta_full        27.49
_diffrn_reflns_theta_max         27.49
_diffrn_reflns_theta_min         1.58
_exptl_absorpt_coefficient_mu    0.481
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            'red orange'
_exptl_crystal_density_diffrn    1.202
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             2932
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.473
_refine_diff_density_min         -1.250
_refine_diff_density_rms         0.162
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.248
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     803
_refine_ls_number_reflns         17793
_refine_ls_number_restraints     8
_refine_ls_restrained_S_all      1.247
_refine_ls_R_factor_all          0.1512
_refine_ls_R_factor_gt           0.0931
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0300P)²+35.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2396
_refine_ls_wR_factor_ref         0.2544
_reflns_number_gt                9502
_reflns_number_total             17793
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic100450y_si_005.cif
_cod_data_source_block           complex_5
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_original_formula_sum        'C74.50 H85 Ag B Cl5 F4 N4'
_cod_database_code               4316571
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag Ag 0.75115(2) 0.19656(3) 1.004356(19) 0.04330(16) Uani 1 1 d . . .
Cl1 Cl 1.04293(16) 0.3553(4) 1.27909(12) 0.1582(18) Uani 1 1 d . . .
Cl2 Cl 1.01156(15) 0.4128(2) 1.16704(12) 0.1068(9) Uani 1 1 d . . .
Cl3 Cl 0.49167(17) 0.4020(2) 0.83181(13) 0.1194(10) Uani 1 1 d . . .
Cl4 Cl 0.45651(16) 0.3536(3) 0.71781(12) 0.1499(16) Uani 1 1 d . . .
Cl5 Cl 1.1967(3) 0.1879(3) 1.43748(18) 0.0971(18) Uani 0.50 1 d P . .
Cl6 Cl 1.1252(3) 0.0784(4) 1.3472(2) 0.113(2) Uani 0.50 1 d P . .
N1 N 0.8247(2) 0.1640(3) 1.0861(2) 0.0384(12) Uani 1 1 d . . .
N2 N 0.8622(2) 0.2376(3) 0.9942(2) 0.0363(12) Uani 1 1 d . . .
N3 N 0.6410(2) 0.2371(4) 1.0140(2) 0.0407(12) Uani 1 1 d . . .
N4 N 0.6756(2) 0.1472(4) 0.9264(2) 0.0458(14) Uani 1 1 d . . .
C7 C 1.0641(3) 0.1824(5) 1.1303(3) 0.0534(19) Uani 1 1 d . . .
C8 C 1.0763(3) 0.1404(6) 1.1811(3) 0.063(2) Uani 1 1 d . . .
H8 H 1.1198 0.1363 1.2015 0.075 Uiso 1 1 calc . . .
C9 C 1.0259(4) 0.1054(6) 1.2015(3) 0.064(2) Uani 1 1 d . . .
H9 H 1.0357 0.0751 1.2352 0.077 Uiso 1 1 calc . . .
C10 C 0.9598(3) 0.1126(5) 1.1744(3) 0.0527(18) Uani 1 1 d . . .
H10 H 0.9258 0.0887 1.1899 0.063 Uiso 1 1 calc . . .
C11 C 0.9456(3) 0.1548(5) 1.1251(3) 0.0453(16) Uani 1 1 d . . .
C12 C 0.9976(3) 0.1882(5) 1.1026(3) 0.0446(16) Uani 1 1 d . . .
C3 C 0.9773(3) 0.2270(5) 1.0506(3) 0.0442(16) Uani 1 1 d . . .
C4 C 1.0238(3) 0.2632(5) 1.0252(3) 0.056(2) Uani 1 1 d . . .
H4 H 1.0116 0.2887 0.9902 0.067 Uiso 1 1 calc . . .
C5 C 1.0904(3) 0.2615(6) 1.0529(4) 0.065(2) Uani 1 1 d . . .
H5 H 1.1226 0.2881 1.0363 0.078 Uiso 1 1 calc . . .
C6 C 1.1097(3) 0.2224(6) 1.1027(4) 0.068(2) Uani 1 1 d . . .
H6 H 1.1549 0.2219 1.1194 0.081 Uiso 1 1 calc . . .
C1 C 0.8847(3) 0.1749(4) 1.0853(2) 0.0369(14) Uani 1 1 d . . .
C2 C 0.9054(3) 0.2173(4) 1.0366(2) 0.0385(15) Uani 1 1 d . . .
C13 C 0.8112(3) 0.1322(5) 1.1362(3) 0.0437(16) Uani 1 1 d . . .
C18 C 0.7942(3) 0.0435(5) 1.1398(3) 0.0517(18) Uani 1 1 d . . .
C17 C 0.7876(4) 0.0113(6) 1.1909(4) 0.067(2) Uani 1 1 d . . .
H17 H 0.7766 -0.0491 1.1948 0.080 Uiso 1 1 calc . . .
C16 C 0.7971(4) 0.0663(7) 1.2348(3) 0.071(2) Uani 1 1 d . . .
H16 H 0.7948 0.0431 1.2694 0.086 Uiso 1 1 calc . . .
C15 C 0.8098(4) 0.1547(7) 1.2297(3) 0.064(2) Uani 1 1 d . . .
H15 H 0.8136 0.1919 1.2606 0.077 Uiso 1 1 calc . . .
C14 C 0.8171(3) 0.1915(5) 1.1808(3) 0.0512(17) Uani 1 1 d . . .
C22 C 0.7858(3) -0.0160(5) 1.0905(3) 0.0556(19) Uani 1 1 d . . .
H22 H 0.7727 0.0224 1.0577 0.067 Uiso 1 1 calc . . .
C23 C 0.7321(4) -0.0859(6) 1.0888(4) 0.077(3) Uani 1 1 d . . .
H23A H 0.7289 -0.1223 1.0562 0.115 Uiso 1 1 calc . . .
H23B H 0.6902 -0.0564 1.0881 0.115 Uiso 1 1 calc . . .
H23C H 0.7431 -0.1237 1.1210 0.115 Uiso 1 1 calc . . .
C24 C 0.8507(4) -0.0614(6) 1.0866(4) 0.083(3) Uani 1 1 d . . .
H24A H 0.8438 -0.0998 1.0546 0.124 Uiso 1 1 calc . . .
H24B H 0.8661 -0.0972 1.1192 0.124 Uiso 1 1 calc . . .
H24C H 0.8835 -0.0163 1.0837 0.124 Uiso 1 1 calc . . .
C19 C 0.8324(3) 0.2880(5) 1.1751(3) 0.0551(19) Uani 1 1 d . . .
H19 H 0.8679 0.2916 1.1539 0.066 Uiso 1 1 calc . . .
C20 C 0.8567(4) 0.3348(7) 1.2279(4) 0.081(3) Uani 1 1 d . . .
H20A H 0.8654 0.3971 1.2210 0.121 Uiso 1 1 calc . . .
H20B H 0.8971 0.3066 1.2472 0.121 Uiso 1 1 calc . . .
H20C H 0.8234 0.3314 1.2501 0.121 Uiso 1 1 calc . . .
C21 C 0.7735(4) 0.3358(6) 1.1428(4) 0.074(2) Uani 1 1 d . . .
H21A H 0.7841 0.3985 1.1393 0.111 Uiso 1 1 calc . . .
H21B H 0.7369 0.3307 1.1615 0.111 Uiso 1 1 calc . . .
H21C H 0.7611 0.3092 1.1067 0.111 Uiso 1 1 calc . . .
C25 C 0.8859(3) 0.2739(4) 0.9493(3) 0.0407(15) Uani 1 1 d . . .
C30 C 0.9092(3) 0.2159(5) 0.9138(3) 0.0488(17) Uani 1 1 d . . .
C29 C 0.9329(4) 0.2537(6) 0.8716(3) 0.061(2) Uani 1 1 d . . .
H29 H 0.9487 0.2164 0.8469 0.073 Uiso 1 1 calc . . .
C28 C 0.9340(4) 0.3429(6) 0.8649(3) 0.069(2) Uani 1 1 d . . .
H28 H 0.9517 0.3672 0.8363 0.083 Uiso 1 1 calc . . .
C27 C 0.9097(4) 0.3983(6) 0.8993(4) 0.071(2) Uani 1 1 d . . .
H27 H 0.9106 0.4606 0.8939 0.086 Uiso 1 1 calc . . .
C26 C 0.8838(4) 0.3645(5) 0.9419(3) 0.0556(19) Uani 1 1 d . . .
C34 C 0.9071(5) 0.1151(6) 0.9198(3) 0.075(3) Uani 1 1 d . . .
H34 H 0.8838 0.1003 0.9495 0.090 Uiso 1 1 calc . . .
C35 C 0.9734(7) 0.0746(8) 0.9326(5) 0.135(5) Uani 1 1 d . . .
H35A H 0.9694 0.0102 0.9352 0.202 Uiso 1 1 calc . . .
H35B H 0.9977 0.0981 0.9671 0.202 Uiso 1 1 calc . . .
H35C H 0.9969 0.0890 0.9038 0.202 Uiso 1 1 calc . . .
C36 C 0.8693(5) 0.0737(7) 0.8665(5) 0.110(4) Uani 1 1 d . . .
H36A H 0.8252 0.0992 0.8574 0.165 Uiso 1 1 calc . . .
H36B H 0.8661 0.0095 0.8710 0.165 Uiso 1 1 calc . . .
H36C H 0.8924 0.0862 0.8373 0.165 Uiso 1 1 calc . . .
C31 C 0.8553(5) 0.4264(6) 0.9779(4) 0.084(3) Uani 1 1 d . . .
H31 H 0.8229 0.3924 0.9940 0.101 Uiso 1 1 calc . . .
C32 C 0.8193(5) 0.5077(7) 0.9471(5) 0.106(4) Uani 1 1 d . . .
H32A H 0.8023 0.5455 0.9726 0.158 Uiso 1 1 calc . . .
H32B H 0.7830 0.4870 0.9188 0.158 Uiso 1 1 calc . . .
H32C H 0.8500 0.5417 0.9305 0.158 Uiso 1 1 calc . . .
C33 C 0.9081(8) 0.4594(10) 1.0236(5) 0.149(6) Uani 1 1 d . . .
H33A H 0.8889 0.4996 1.0465 0.223 Uiso 1 1 calc . . .
H33B H 0.9414 0.4911 1.0087 0.223 Uiso 1 1 calc . . .
H33C H 0.9283 0.4090 1.0452 0.223 Uiso 1 1 calc . . .
C43 C 0.4383(3) 0.1857(5) 0.8804(3) 0.055(2) Uani 1 1 d . . .
C44 C 0.3933(3) 0.2310(5) 0.9066(4) 0.063(2) Uani 1 1 d . . .
H44 H 0.3484 0.2346 0.8894 0.076 Uiso 1 1 calc . . .
C45 C 0.4141(3) 0.2690(6) 0.9561(4) 0.065(2) Uani 1 1 d . . .
H45 H 0.3827 0.2973 0.9728 0.078 Uiso 1 1 calc . . .
C46 C 0.4807(3) 0.2684(5) 0.9840(3) 0.0559(19) Uani 1 1 d . . .
H46 H 0.4940 0.2964 1.0182 0.067 Uiso 1 1 calc . . .
C47 C 0.5252(3) 0.2259(5) 0.9595(3) 0.0474(17) Uani 1 1 d . . .
C48 C 0.5042(3) 0.1863(4) 0.9082(3) 0.0465(17) Uani 1 1 d . . .
C39 C 0.5542(3) 0.1458(5) 0.8870(3) 0.0453(16) Uani 1 1 d . . .
C40 C 0.5392(3) 0.1010(5) 0.8383(3) 0.0561(19) Uani 1 1 d . . .
H40 H 0.5722 0.0718 0.8239 0.067 Uiso 1 1 calc . . .
C41 C 0.4726(4) 0.1001(6) 0.8106(3) 0.065(2) Uani 1 1 d . . .
H41 H 0.4613 0.0698 0.7769 0.078 Uiso 1 1 calc . . .
C42 C 0.4241(3) 0.1411(5) 0.8304(3) 0.061(2) Uani 1 1 d . . .
H42 H 0.3804 0.1394 0.8103 0.073 Uiso 1 1 calc . . .
C37 C 0.5973(3) 0.2127(4) 0.9734(3) 0.0408(15) Uani 1 1 d . . .
C38 C 0.6154(3) 0.1636(4) 0.9268(3) 0.0413(15) Uani 1 1 d . . .
C49 C 0.6187(3) 0.2822(5) 1.0573(3) 0.0433(16) Uani 1 1 d . . .
C54 C 0.5996(3) 0.2295(5) 1.0972(3) 0.0477(17) Uani 1 1 d . . .
C53 C 0.5743(4) 0.2753(6) 1.1365(3) 0.067(2) Uani 1 1 d . . .
H53 H 0.5596 0.2426 1.1638 0.080 Uiso 1 1 calc . . .
C52 C 0.5701(4) 0.3660(6) 1.1367(3) 0.069(2) Uani 1 1 d . . .
H52 H 0.5514 0.3949 1.1634 0.082 Uiso 1 1 calc . . .
C51 C 0.5925(4) 0.4146(5) 1.0991(3) 0.064(2) Uani 1 1 d . . .
H51 H 0.5910 0.4774 1.1008 0.077 Uiso 1 1 calc . . .
C50 C 0.6175(4) 0.3746(5) 1.0581(3) 0.0561(19) Uani 1 1 d . . .
C58 C 0.6054(4) 0.1295(5) 1.0980(3) 0.0574(19) Uani 1 1 d . . .
H58 H 0.6383 0.1135 1.0759 0.069 Uiso 1 1 calc . . .
C60 C 0.5425(5) 0.0823(6) 1.0733(4) 0.089(3) Uani 1 1 d . . .
H60A H 0.5499 0.0181 1.0750 0.133 Uiso 1 1 calc . . .
H60B H 0.5283 0.1004 1.0354 0.133 Uiso 1 1 calc . . .
H60C H 0.5087 0.0976 1.0934 0.133 Uiso 1 1 calc . . .
C59 C 0.6309(4) 0.0941(6) 1.1550(4) 0.074(2) Uani 1 1 d . . .
H59A H 0.6336 0.0293 1.1538 0.112 Uiso 1 1 calc . . .
H59B H 0.6010 0.1115 1.1784 0.112 Uiso 1 1 calc . . .
H59C H 0.6744 0.1186 1.1694 0.112 Uiso 1 1 calc . . .
C55 C 0.6426(6) 0.4292(6) 1.0169(5) 0.092(3) Uani 1 1 d . . .
H55 H 0.6704 0.3900 0.9989 0.110 Uiso 1 1 calc . . .
C57 C 0.6847(5) 0.5073(7) 1.0419(6) 0.116(4) Uani 1 1 d . . .
H57A H 0.6993 0.5408 1.0133 0.174 Uiso 1 1 calc . . .
H57B H 0.7229 0.4853 1.0678 0.174 Uiso 1 1 calc . . .
H57C H 0.6590 0.5460 1.0607 0.174 Uiso 1 1 calc . . .
C56 C 0.5864(8) 0.4650(10) 0.9727(5) 0.152(6) Uani 1 1 d . . .
H56A H 0.6044 0.5018 0.9473 0.228 Uiso 1 1 calc . . .
H56B H 0.5568 0.5007 0.9896 0.228 Uiso 1 1 calc . . .
H56C H 0.5621 0.4153 0.9532 0.228 Uiso 1 1 calc . . .
C61 C 0.6898(3) 0.1069(5) 0.8782(3) 0.0525(19) Uani 1 1 d . . .
C62 C 0.6865(3) 0.1607(6) 0.8322(3) 0.061(2) Uani 1 1 d . . .
C63 C 0.6964(4) 0.1189(7) 0.7851(3) 0.073(3) Uani 1 1 d . . .
H63 H 0.6948 0.1529 0.7532 0.088 Uiso 1 1 calc . . .
C64 C 0.7083(4) 0.0294(8) 0.7842(4) 0.083(3) Uani 1 1 d . . .
H64 H 0.7139 0.0024 0.7514 0.100 Uiso 1 1 calc . . .
C65 C 0.7124(4) -0.0213(7) 0.8298(4) 0.074(3) Uani 1 1 d . . .
H65 H 0.7211 -0.0829 0.8284 0.089 Uiso 1 1 calc . . .
C66 C 0.7037(3) 0.0173(5) 0.8790(3) 0.0551(19) Uani 1 1 d . . .
C67 C 0.6723(4) 0.2587(7) 0.8339(3) 0.072(2) Uani 1 1 d . . .
H67 H 0.6379 0.2649 0.8560 0.086 Uiso 1 1 calc . . .
C68 C 0.6453(5) 0.3010(9) 0.7811(4) 0.114(4) Uani 1 1 d . . .
H68A H 0.6378 0.3641 0.7867 0.171 Uiso 1 1 calc . . .
H68B H 0.6039 0.2725 0.7646 0.171 Uiso 1 1 calc . . .
H68C H 0.6765 0.2945 0.7572 0.171 Uiso 1 1 calc . . .
C69 C 0.7324(4) 0.3098(6) 0.8646(4) 0.077(3) Uani 1 1 d . . .
H69A H 0.7494 0.2808 0.8994 0.116 Uiso 1 1 calc . . .
H69B H 0.7197 0.3708 0.8710 0.116 Uiso 1 1 calc . . .
H69C H 0.7663 0.3105 0.8430 0.116 Uiso 1 1 calc . . .
C70 C 0.7064(4) -0.0372(6) 0.9290(3) 0.064(2) Uani 1 1 d . . .
H70 H 0.7198 0.0032 0.9608 0.077 Uiso 1 1 calc . . .
C72 C 0.6383(4) -0.0750(6) 0.9319(4) 0.084(3) Uani 1 1 d . . .
H72A H 0.6418 -0.1103 0.9650 0.126 Uiso 1 1 calc . . .
H72B H 0.6225 -0.1125 0.9002 0.126 Uiso 1 1 calc . . .
H72C H 0.6076 -0.0261 0.9323 0.126 Uiso 1 1 calc . . .
C71 C 0.7582(5) -0.1121(7) 0.9347(4) 0.101(4) Uani 1 1 d . . .
H71A H 0.7579 -0.1459 0.9679 0.151 Uiso 1 1 calc . . .
H71B H 0.8016 -0.0862 0.9366 0.151 Uiso 1 1 calc . . .
H71C H 0.7477 -0.1517 0.9033 0.151 Uiso 1 1 calc . . .
C73 C 1.0717(5) 0.3761(8) 1.2217(4) 0.103(3) Uani 1 1 d . . .
H73A H 1.0917 0.3213 1.2109 0.123 Uiso 1 1 calc . . .
H73B H 1.1066 0.4215 1.2299 0.123 Uiso 1 1 calc . . .
C74 C 0.4299(6) 0.3698(8) 0.7781(4) 0.104(3) Uani 1 1 d . . .
H74A H 0.3953 0.4156 0.7723 0.125 Uiso 1 1 calc . . .
H74B H 0.4103 0.3140 0.7879 0.125 Uiso 1 1 calc . . .
C75 C 1.1668(9) 0.1722(10) 1.3675(6) 0.065(4) Uani 0.50 1 d P . .
H75A H 1.1379 0.2229 1.3540 0.078 Uiso 0.50 1 calc P . .
H75B H 1.2045 0.1751 1.3494 0.078 Uiso 0.50 1 calc P . .
B B 1.2479(4) 0.2415(6) 1.2554(3) 0.1255(16) Uiso 1 1 d D . .
F1 F 1.2434(7) 0.2153(10) 1.2036(4) 0.1255(16) Uiso 0.50 1 d PD . .
F2 F 1.1902(5) 0.2719(9) 1.2642(6) 0.1255(16) Uiso 0.50 1 d PD . .
F3 F 1.2261(7) 0.1588(7) 1.2618(6) 0.1255(16) Uiso 0.50 1 d PD . .
F4 F 1.2163(6) 0.2750(10) 1.2075(4) 0.1255(16) Uiso 0.50 1 d PD . .
F5 F 1.3104(5) 0.2294(9) 1.2502(6) 0.1255(16) Uiso 0.50 1 d PD . .
F6 F 1.2893(6) 0.2033(9) 1.2974(4) 0.1255(16) Uiso 0.50 1 d PD . .
F7 F 1.2789(6) 0.3203(7) 1.2643(6) 0.1255(16) Uiso 0.50 1 d PD . .
F8 F 1.2517(7) 0.2856(9) 1.3025(4) 0.1255(16) Uiso 0.50 1 d PD . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ag N4 149.55(19) . . ?
N1 Ag N3 115.03(17) . . ?
N4 Ag N3 71.47(18) . . ?
N1 Ag N2 71.66(16) . . ?
N4 Ag N2 118.15(18) . . ?
N3 Ag N2 150.94(17) . . ?
C1 N1 C13 115.7(5) . . ?
C1 N1 Ag 115.3(4) . . ?
C13 N1 Ag 129.0(4) . . ?
C2 N2 C25 116.8(5) . . ?
C2 N2 Ag 111.6(4) . . ?
C25 N2 Ag 131.5(4) . . ?
C37 N3 C49 116.9(5) . . ?
C37 N3 Ag 112.4(4) . . ?
C49 N3 Ag 130.7(4) . . ?
C38 N4 C61 117.4(5) . . ?
C38 N4 Ag 114.7(4) . . ?
C61 N4 Ag 127.8(4) . . ?
C8 C7 C12 116.8(7) . . ?
C8 C7 C6 128.5(7) . . ?
C12 C7 C6 114.7(7) . . ?
C9 C8 C7 120.5(6) . . ?
C9 C8 H8 119.7 . . ?
C7 C8 H8 119.7 . . ?
C8 C9 C10 122.6(7) . . ?
C8 C9 H9 118.7 . . ?
C10 C9 H9 118.7 . . ?
C11 C10 C9 118.7(7) . . ?
C11 C10 H10 120.6 . . ?
C9 C10 H10 120.6 . . ?
C10 C11 C12 119.1(6) . . ?
C10 C11 C1 134.7(6) . . ?
C12 C11 C1 106.2(6) . . ?
C11 C12 C3 114.1(5) . . ?
C11 C12 C7 122.2(7) . . ?
C3 C12 C7 123.7(6) . . ?
C4 C3 C12 119.1(6) . . ?
C4 C3 C2 134.9(7) . . ?
C12 C3 C2 106.0(5) . . ?
C3 C4 C5 118.4(7) . . ?
C3 C4 H4 120.8 . . ?
C5 C4 H4 120.8 . . ?
C6 C5 C4 122.0(7) . . ?
C6 C5 H5 119.0 . . ?
C4 C5 H5 119.0 . . ?
C5 C6 C7 122.0(7) . . ?
C5 C6 H6 119.0 . . ?
C7 C6 H6 119.0 . . ?
N1 C1 C11 132.6(6) . . ?
N1 C1 C2 120.8(5) . . ?
C11 C1 C2 106.6(5) . . ?
N2 C2 C3 132.9(6) . . ?
N2 C2 C1 120.2(5) . . ?
C3 C2 C1 106.9(5) . . ?
C18 C13 C14 122.3(6) . . ?
C18 C13 N1 118.7(6) . . ?
C14 C13 N1 119.1(6) . . ?
C13 C18 C17 117.8(7) . . ?
C13 C18 C22 120.2(6) . . ?
C17 C18 C22 122.0(7) . . ?
C16 C17 C18 120.4(8) . . ?
C16 C17 H17 119.8 . . ?
C18 C17 H17 119.8 . . ?
C17 C16 C15 120.9(7) . . ?
C17 C16 H16 119.5 . . ?
C15 C16 H16 119.5 . . ?
C16 C15 C14 122.0(8) . . ?
C16 C15 H15 119.0 . . ?
C14 C15 H15 119.0 . . ?
C15 C14 C13 116.3(7) . . ?
C15 C14 C19 122.4(7) . . ?
C13 C14 C19 121.3(6) . . ?
C18 C22 C23 113.0(7) . . ?
C18 C22 C24 111.2(6) . . ?
C23 C22 C24 109.8(7) . . ?
C18 C22 H22 107.5 . . ?
C23 C22 H22 107.5 . . ?
C24 C22 H22 107.5 . . ?
C22 C23 H23A 109.5 . . ?
C22 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
C22 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C22 C24 H24A 109.5 . . ?
C22 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C22 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C20 C19 C14 114.2(7) . . ?
C20 C19 C21 110.0(7) . . ?
C14 C19 C21 110.3(6) . . ?
C20 C19 H19 107.3 . . ?
C14 C19 H19 107.3 . . ?
C21 C19 H19 107.3 . . ?
C19 C20 H20A 109.5 . . ?
C19 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
C19 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C19 C21 H21A 109.5 . . ?
C19 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
C19 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C26 C25 C30 122.4(6) . . ?
C26 C25 N2 118.6(6) . . ?
C30 C25 N2 119.0(6) . . ?
C29 C30 C25 117.2(7) . . ?
C29 C30 C34 120.4(7) . . ?
C25 C30 C34 122.4(6) . . ?
C28 C29 C30 121.5(7) . . ?
C28 C29 H29 119.3 . . ?
C30 C29 H29 119.3 . . ?
C29 C28 C27 120.5(7) . . ?
C29 C28 H28 119.8 . . ?
C27 C28 H28 119.8 . . ?
C28 C27 C26 121.0(8) . . ?
C28 C27 H27 119.5 . . ?
C26 C27 H27 119.5 . . ?
C25 C26 C27 117.4(7) . . ?
C25 C26 C31 122.6(7) . . ?
C27 C26 C31 120.0(7) . . ?
C35 C34 C30 112.7(9) . . ?
C35 C34 C36 108.1(8) . . ?
C30 C34 C36 109.6(8) . . ?
C35 C34 H34 108.8 . . ?
C30 C34 H34 108.8 . . ?
C36 C34 H34 108.8 . . ?
C34 C35 H35A 109.5 . . ?
C34 C35 H35B 109.5 . . ?
H35A C35 H35B 109.5 . . ?
C34 C35 H35C 109.5 . . ?
H35A C35 H35C 109.5 . . ?
H35B C35 H35C 109.5 . . ?
C34 C36 H36A 109.5 . . ?
C34 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
C34 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
C33 C31 C26 110.4(9) . . ?
C33 C31 C32 108.8(9) . . ?
C26 C31 C32 113.5(8) . . ?
C33 C31 H31 108.0 . . ?
C26 C31 H31 108.0 . . ?
C32 C31 H31 108.0 . . ?
C31 C32 H32A 109.5 . . ?
C31 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C31 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
C31 C33 H33A 109.5 . . ?
C31 C33 H33B 109.5 . . ?
H33A C33 H33B 109.5 . . ?
C31 C33 H33C 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
C42 C43 C48 116.9(7) . . ?
C42 C43 C44 127.5(6) . . ?
C48 C43 C44 115.6(7) . . ?
C45 C44 C43 120.7(6) . . ?
C45 C44 H44 119.6 . . ?
C43 C44 H44 119.6 . . ?
C44 C45 C46 123.0(7) . . ?
C44 C45 H45 118.5 . . ?
C46 C45 H45 118.5 . . ?
C47 C46 C45 117.6(8) . . ?
C47 C46 H46 121.2 . . ?
C45 C46 H46 121.2 . . ?
C46 C47 C48 119.8(6) . . ?
C46 C47 C37 134.6(7) . . ?
C48 C47 C37 105.5(6) . . ?
C39 C48 C47 114.7(5) . . ?
C39 C48 C43 122.1(7) . . ?
C47 C48 C43 123.2(7) . . ?
C40 C39 C48 120.1(6) . . ?
C40 C39 C38 134.4(6) . . ?
C48 C39 C38 105.5(6) . . ?
C39 C40 C41 117.5(7) . . ?
C39 C40 H40 121.2 . . ?
C41 C40 H40 121.2 . . ?
C42 C41 C40 122.5(7) . . ?
C42 C41 H41 118.7 . . ?
C40 C41 H41 118.7 . . ?
C41 C42 C43 120.8(6) . . ?
C41 C42 H42 119.6 . . ?
C43 C42 H42 119.6 . . ?
N3 C37 C47 132.2(6) . . ?
N3 C37 C38 121.0(5) . . ?
C47 C37 C38 106.7(5) . . ?
N4 C38 C39 132.0(6) . . ?
N4 C38 C37 120.5(5) . . ?
C39 C38 C37 107.5(5) . . ?
C50 C49 C54 123.3(6) . . ?
C50 C49 N3 119.4(6) . . ?
C54 C49 N3 117.3(6) . . ?
C53 C54 C49 115.6(7) . . ?
C53 C54 C58 121.6(7) . . ?
C49 C54 C58 122.7(6) . . ?
C52 C53 C54 122.0(8) . . ?
C52 C53 H53 119.0 . . ?
C54 C53 H53 119.0 . . ?
C51 C52 C53 120.3(7) . . ?
C51 C52 H52 119.8 . . ?
C53 C52 H52 119.8 . . ?
C52 C51 C50 121.5(7) . . ?
C52 C51 H51 119.3 . . ?
C50 C51 H51 119.3 . . ?
C51 C50 C49 117.1(7) . . ?
C51 C50 C55 121.0(7) . . ?
C49 C50 C55 121.9(7) . . ?
C60 C58 C54 113.9(7) . . ?
C60 C58 C59 109.1(7) . . ?
C54 C58 C59 111.9(7) . . ?
C60 C58 H58 107.2 . . ?
C54 C58 H58 107.2 . . ?
C59 C58 H58 107.2 . . ?
C58 C60 H60A 109.5 . . ?
C58 C60 H60B 109.5 . . ?
H60A C60 H60B 109.5 . . ?
C58 C60 H60C 109.5 . . ?
H60A C60 H60C 109.5 . . ?
H60B C60 H60C 109.5 . . ?
C58 C59 H59A 109.5 . . ?
C58 C59 H59B 109.5 . . ?
H59A C59 H59B 109.5 . . ?
C58 C59 H59C 109.5 . . ?
H59A C59 H59C 109.5 . . ?
H59B C59 H59C 109.5 . . ?
C50 C55 C57 113.0(10) . . ?
C50 C55 C56 111.7(9) . . ?
C57 C55 C56 108.4(8) . . ?
C50 C55 H55 107.8 . . ?
C57 C55 H55 107.8 . . ?
C56 C55 H55 107.8 . . ?
C55 C57 H57A 109.5 . . ?
C55 C57 H57B 109.5 . . ?
H57A C57 H57B 109.5 . . ?
C55 C57 H57C 109.5 . . ?
H57A C57 H57C 109.5 . . ?
H57B C57 H57C 109.5 . . ?
C55 C56 H56A 109.5 . . ?
C55 C56 H56B 109.5 . . ?
H56A C56 H56B 109.5 . . ?
C55 C56 H56C 109.5 . . ?
H56A C56 H56C 109.5 . . ?
H56B C56 H56C 109.5 . . ?
C66 C61 C62 123.5(7) . . ?
C66 C61 N4 118.5(7) . . ?
C62 C61 N4 118.0(7) . . ?
C63 C62 C61 116.8(8) . . ?
C63 C62 C67 122.1(8) . . ?
C61 C62 C67 121.1(7) . . ?
C64 C63 C62 121.2(9) . . ?
C64 C63 H63 119.4 . . ?
C62 C63 H63 119.4 . . ?
C65 C64 C63 121.0(8) . . ?
C65 C64 H64 119.5 . . ?
C63 C64 H64 119.5 . . ?
C64 C65 C66 120.6(9) . . ?
C64 C65 H65 119.7 . . ?
C66 C65 H65 119.7 . . ?
C61 C66 C65 117.0(8) . . ?
C61 C66 C70 121.4(7) . . ?
C65 C66 C70 121.5(8) . . ?
C68 C67 C62 115.9(9) . . ?
C68 C67 C69 110.8(8) . . ?
C62 C67 C69 111.2(7) . . ?
C68 C67 H67 106.1 . . ?
C62 C67 H67 106.1 . . ?
C69 C67 H67 106.1 . . ?
C67 C68 H68A 109.5 . . ?
C67 C68 H68B 109.5 . . ?
H68A C68 H68B 109.5 . . ?
C67 C68 H68C 109.5 . . ?
H68A C68 H68C 109.5 . . ?
H68B C68 H68C 109.5 . . ?
C67 C69 H69A 109.5 . . ?
C67 C69 H69B 109.5 . . ?
H69A C69 H69B 109.5 . . ?
C67 C69 H69C 109.5 . . ?
H69A C69 H69C 109.5 . . ?
H69B C69 H69C 109.5 . . ?
C66 C70 C72 111.5(6) . . ?
C66 C70 C71 112.6(8) . . ?
C72 C70 C71 110.9(8) . . ?
C66 C70 H70 107.2 . . ?
C72 C70 H70 107.2 . . ?
C71 C70 H70 107.2 . . ?
C70 C72 H72A 109.5 . . ?
C70 C72 H72B 109.5 . . ?
H72A C72 H72B 109.5 . . ?
C70 C72 H72C 109.5 . . ?
H72A C72 H72C 109.5 . . ?
H72B C72 H72C 109.5 . . ?
C70 C71 H71A 109.5 . . ?
C70 C71 H71B 109.5 . . ?
H71A C71 H71B 109.5 . . ?
C70 C71 H71C 109.5 . . ?
H71A C71 H71C 109.5 . . ?
H71B C71 H71C 109.5 . . ?
Cl1 C73 Cl2 113.8(6) . . ?
Cl1 C73 H73A 108.8 . . ?
Cl2 C73 H73A 108.8 . . ?
Cl1 C73 H73B 108.8 . . ?
Cl2 C73 H73B 108.8 . . ?
H73A C73 H73B 107.7 . . ?
Cl3 C74 Cl4 113.7(6) . . ?
Cl3 C74 H74A 108.8 . . ?
Cl4 C74 H74A 108.8 . . ?
Cl3 C74 H74B 108.8 . . ?
Cl4 C74 H74B 108.8 . . ?
H74A C74 H74B 107.7 . . ?
Cl6 C75 Cl5 118.1(9) . . ?
Cl6 C75 H75A 107.8 . . ?
Cl5 C75 H75A 107.8 . . ?
Cl6 C75 H75B 107.8 . . ?
Cl5 C75 H75B 107.8 . . ?
H75A C75 H75B 107.1 . . ?
F4 B F6 167.9(11) . . ?
F4 B F8 122.1(11) . . ?
F6 B F8 67.0(9) . . ?
F4 B F1 47.1(8) . . ?
F6 B F1 122.7(11) . . ?
F8 B F1 167.4(12) . . ?
F4 B F7 87.0(10) . . ?
F6 B F7 92.2(10) . . ?
F8 B F7 58.6(8) . . ?
F1 B F7 110.8(11) . . ?
F4 B F2 74.5(9) . . ?
F6 B F2 117.7(10) . . ?
F8 B F2 65.1(8) . . ?
F1 B F2 111.9(10) . . ?
F7 B F2 94.9(10) . . ?
F4 B F3 109.8(11) . . ?
F6 B F3 71.9(9) . . ?
F8 B F3 108.0(11) . . ?
F1 B F3 83.6(10) . . ?
F7 B F3 163.0(10) . . ?
F2 B F3 87.6(10) . . ?
F4 B F5 105.6(10) . . ?
F6 B F5 62.8(8) . . ?
F8 B F5 105.6(10) . . ?
F1 B F5 75.1(9) . . ?
F7 B F5 72.3(9) . . ?
F2 B F5 167.2(11) . . ?
F3 B F5 104.1(10) . . ?
F4 F1 B 66.4(4) . . ?
F4 F1 F5 102.2(10) . . ?
B F1 F5 52.4(5) . . ?
B F2 F8 57.4(4) . . ?
B F2 F4 52.8(5) . . ?
F8 F2 F4 99.7(7) . . ?
B F3 F6 54.1(4) . . ?
F1 F4 B 66.4(4) . . ?
F1 F4 F2 109.4(9) . . ?
B F4 F2 52.8(5) . . ?
B F5 F6 58.6(4) . . ?
B F5 F7 53.8(5) . . ?
F6 F5 F7 80.6(9) . . ?
B F5 F1 52.4(5) . . ?
F6 F5 F1 101.5(8) . . ?
F7 F5 F1 86.6(8) . . ?
B F6 F5 58.6(4) . . ?
B F6 F8 56.5(4) . . ?
F5 F6 F8 95.9(9) . . ?
B F6 F3 54.1(4) . . ?
F5 F6 F3 90.6(9) . . ?
F8 F6 F3 90.6(8) . . ?
F8 F7 B 60.7(4) . . ?
F8 F7 F5 94.7(9) . . ?
B F7 F5 53.9(5) . . ?
F7 F8 B 60.7(4) . . ?
F7 F8 F2 91.5(10) . . ?
B F8 F2 57.5(4) . . ?
F7 F8 F6 87.3(9) . . ?
B F8 F6 56.5(4) . . ?
F2 F8 F6 103.5(8) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag N1 2.356(5) . ?
Ag N4 2.374(5) . ?
Ag N3 2.440(5) . ?
Ag N2 2.465(5) . ?
Cl1 C73 1.707(11) . ?
Cl2 C73 1.753(12) . ?
Cl3 C74 1.736(12) . ?
Cl4 C74 1.741(11) . ?
Cl5 C75 1.762(17) . ?
Cl6 C75 1.685(17) . ?
N1 C1 1.268(7) . ?
N1 C13 1.433(8) . ?
N2 C2 1.286(7) . ?
N2 C25 1.435(8) . ?
N3 C37 1.278(8) . ?
N3 C49 1.444(8) . ?
N4 C38 1.284(8) . ?
N4 C61 1.444(8) . ?
C7 C8 1.406(11) . ?
C7 C12 1.421(8) . ?
C7 C6 1.424(11) . ?
C8 C9 1.369(11) . ?
C8 H8 0.9500 . ?
C9 C10 1.413(9) . ?
C9 H9 0.9500 . ?
C10 C11 1.374(9) . ?
C10 H10 0.9500 . ?
C11 C12 1.417(9) . ?
C11 C1 1.479(8) . ?
C12 C3 1.420(9) . ?
C3 C4 1.381(9) . ?
C3 C2 1.477(8) . ?
C4 C5 1.422(10) . ?
C4 H4 0.9500 . ?
C5 C6 1.372(12) . ?
C5 H5 0.9500 . ?
C6 H6 0.9500 . ?
C1 C2 1.526(8) . ?
C13 C18 1.394(10) . ?
C13 C14 1.422(10) . ?
C18 C17 1.409(10) . ?
C18 C22 1.515(11) . ?
C17 C16 1.367(12) . ?
C17 H17 0.9500 . ?
C16 C15 1.371(12) . ?
C16 H16 0.9500 . ?
C15 C14 1.392(10) . ?
C15 H15 0.9500 . ?
C14 C19 1.506(11) . ?
C22 C23 1.534(10) . ?
C22 C24 1.541(11) . ?
C22 H22 1.0000 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C19 C20 1.502(11) . ?
C19 C21 1.512(11) . ?
C19 H19 1.0000 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C25 C26 1.380(10) . ?
C25 C30 1.408(9) . ?
C30 C29 1.386(10) . ?
C30 C34 1.531(11) . ?
C29 C28 1.358(11) . ?
C29 H29 0.9500 . ?
C28 C27 1.375(12) . ?
C28 H28 0.9500 . ?
C27 C26 1.397(10) . ?
C27 H27 0.9500 . ?
C26 C31 1.508(11) . ?
C34 C35 1.486(14) . ?
C34 C36 1.543(14) . ?
C34 H34 1.0000 . ?
C35 H35A 0.9800 . ?
C35 H35B 0.9800 . ?
C35 H35C 0.9800 . ?
C36 H36A 0.9800 . ?
C36 H36B 0.9800 . ?
C36 H36C 0.9800 . ?
C31 C33 1.506(16) . ?
C31 C32 1.560(14) . ?
C31 H31 1.0000 . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?
C33 H33A 0.9800 . ?
C33 H33B 0.9800 . ?
C33 H33C 0.9800 . ?
C43 C42 1.405(11) . ?
C43 C48 1.411(8) . ?
C43 C44 1.430(11) . ?
C44 C45 1.360(12) . ?
C44 H44 0.9500 . ?
C45 C46 1.425(10) . ?
C45 H45 0.9500 . ?
C46 C47 1.375(9) . ?
C46 H46 0.9500 . ?
C47 C48 1.411(10) . ?
C47 C37 1.487(8) . ?
C48 C39 1.409(9) . ?
C39 C40 1.379(10) . ?
C39 C38 1.478(8) . ?
C40 C41 1.424(9) . ?
C40 H40 0.9500 . ?
C41 C42 1.366(11) . ?
C41 H41 0.9500 . ?
C42 H42 0.9500 . ?
C37 C38 1.502(9) . ?
C49 C50 1.395(10) . ?
C49 C54 1.402(9) . ?
C54 C53 1.399(10) . ?
C54 C58 1.515(10) . ?
C53 C52 1.373(12) . ?
C53 H53 0.9500 . ?
C52 C51 1.357(11) . ?
C52 H52 0.9500 . ?
C51 C50 1.390(10) . ?
C51 H51 0.9500 . ?
C50 C55 1.503(11) . ?
C58 C60 1.512(12) . ?
C58 C59 1.524(11) . ?
C58 H58 1.0000 . ?
C60 H60A 0.9800 . ?
C60 H60B 0.9800 . ?
C60 H60C 0.9800 . ?
C59 H59A 0.9800 . ?
C59 H59B 0.9800 . ?
C59 H59C 0.9800 . ?
C55 C57 1.527(15) . ?
C55 C56 1.541(17) . ?
C55 H55 1.0000 . ?
C57 H57A 0.9800 . ?
C57 H57B 0.9800 . ?
C57 H57C 0.9800 . ?
C56 H56A 0.9800 . ?
C56 H56B 0.9800 . ?
C56 H56C 0.9800 . ?
C61 C66 1.383(10) . ?
C61 C62 1.406(11) . ?
C62 C63 1.397(11) . ?
C62 C67 1.510(12) . ?
C63 C64 1.374(14) . ?
C63 H63 0.9500 . ?
C64 C65 1.370(14) . ?
C64 H64 0.9500 . ?
C65 C66 1.418(10) . ?
C65 H65 0.9500 . ?
C66 C70 1.497(12) . ?
C67 C68 1.480(13) . ?
C67 C69 1.539(12) . ?
C67 H67 1.0000 . ?
C68 H68A 0.9800 . ?
C68 H68B 0.9800 . ?
C68 H68C 0.9800 . ?
C69 H69A 0.9800 . ?
C69 H69B 0.9800 . ?
C69 H69C 0.9800 . ?
C70 C72 1.548(12) . ?
C70 C71 1.551(11) . ?
C70 H70 1.0000 . ?
C72 H72A 0.9800 . ?
C72 H72B 0.9800 . ?
C72 H72C 0.9800 . ?
C71 H71A 0.9800 . ?
C71 H71B 0.9800 . ?
C71 H71C 0.9800 . ?
C73 H73A 0.9900 . ?
C73 H73B 0.9900 . ?
C74 H74A 0.9900 . ?
C74 H74B 0.9900 . ?
C75 H75A 0.9900 . ?
C75 H75B 0.9900 . ?
B F4 1.3498(10) . ?
B F6 1.3499(10) . ?
B F8 1.3500(11) . ?
B F1 1.3500(11) . ?
B F7 1.3503(11) . ?
B F2 1.3503(10) . ?
B F3 1.3504(11) . ?
B F5 1.3505(11) . ?
F1 F4 1.079(16) . ?
F1 F5 1.647(17) . ?
F2 F8 1.453(17) . ?
F2 F4 1.634(17) . ?
F3 F6 1.585(17) . ?
F5 F6 1.407(17) . ?
F5 F7 1.593(17) . ?
F6 F8 1.490(17) . ?
F7 F8 1.322(17) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N4 Ag N1 C1 109.1(5) . . . . ?
N3 Ag N1 C1 -155.1(4) . . . . ?
N2 Ag N1 C1 -5.6(4) . . . . ?
N4 Ag N1 C13 -69.8(7) . . . . ?
N3 Ag N1 C13 26.1(6) . . . . ?
N2 Ag N1 C13 175.6(6) . . . . ?
N1 Ag N2 C2 3.3(4) . . . . ?
N4 Ag N2 C2 -145.2(4) . . . . ?
N3 Ag N2 C2 112.0(5) . . . . ?
N1 Ag N2 C25 179.0(6) . . . . ?
N4 Ag N2 C25 30.5(6) . . . . ?
N3 Ag N2 C25 -72.2(6) . . . . ?
N1 Ag N3 C37 -147.9(4) . . . . ?
N4 Ag N3 C37 -0.1(5) . . . . ?
N2 Ag N3 C37 114.9(5) . . . . ?
N1 Ag N3 C49 31.6(6) . . . . ?
N4 Ag N3 C49 179.4(6) . . . . ?
N2 Ag N3 C49 -65.7(7) . . . . ?
N1 Ag N4 C38 107.2(5) . . . . ?
N3 Ag N4 C38 -0.8(5) . . . . ?
N2 Ag N4 C38 -150.9(5) . . . . ?
N1 Ag N4 C61 -77.2(7) . . . . ?
N3 Ag N4 C61 174.8(6) . . . . ?
N2 Ag N4 C61 24.7(7) . . . . ?
C12 C7 C8 C9 1.5(11) . . . . ?
C6 C7 C8 C9 -180.0(8) . . . . ?
C7 C8 C9 C10 -2.8(13) . . . . ?
C8 C9 C10 C11 1.4(12) . . . . ?
C9 C10 C11 C12 1.2(11) . . . . ?
C9 C10 C11 C1 179.9(8) . . . . ?
C10 C11 C12 C3 177.4(6) . . . . ?
C1 C11 C12 C3 -1.6(8) . . . . ?
C10 C11 C12 C7 -2.4(10) . . . . ?
C1 C11 C12 C7 178.6(6) . . . . ?
C8 C7 C12 C11 1.0(10) . . . . ?
C6 C7 C12 C11 -177.7(7) . . . . ?
C8 C7 C12 C3 -178.8(7) . . . . ?
C6 C7 C12 C3 2.5(10) . . . . ?
C11 C12 C3 C4 178.8(6) . . . . ?
C7 C12 C3 C4 -1.4(10) . . . . ?
C11 C12 C3 C2 -1.1(8) . . . . ?
C7 C12 C3 C2 178.8(6) . . . . ?
C12 C3 C4 C5 -1.1(10) . . . . ?
C2 C3 C4 C5 178.8(7) . . . . ?
C3 C4 C5 C6 2.3(12) . . . . ?
C4 C5 C6 C7 -1.1(13) . . . . ?
C8 C7 C6 C5 -179.8(8) . . . . ?
C12 C7 C6 C5 -1.3(11) . . . . ?
C13 N1 C1 C11 5.6(11) . . . . ?
Ag N1 C1 C11 -173.4(6) . . . . ?
C13 N1 C1 C2 -173.7(6) . . . . ?
Ag N1 C1 C2 7.3(8) . . . . ?
C10 C11 C1 N1 5.3(14) . . . . ?
C12 C11 C1 N1 -175.9(7) . . . . ?
C10 C11 C1 C2 -175.3(8) . . . . ?
C12 C11 C1 C2 3.5(7) . . . . ?
C25 N2 C2 C3 3.0(10) . . . . ?
Ag N2 C2 C3 179.4(6) . . . . ?
C25 N2 C2 C1 -177.5(5) . . . . ?
Ag N2 C2 C1 -1.1(7) . . . . ?
C4 C3 C2 N2 2.8(13) . . . . ?
C12 C3 C2 N2 -177.3(7) . . . . ?
C4 C3 C2 C1 -176.7(8) . . . . ?
C12 C3 C2 C1 3.2(7) . . . . ?
N1 C1 C2 N2 -4.3(9) . . . . ?
C11 C1 C2 N2 176.3(6) . . . . ?
N1 C1 C2 C3 175.3(6) . . . . ?
C11 C1 C2 C3 -4.1(7) . . . . ?
C1 N1 C13 C18 -103.5(7) . . . . ?
Ag N1 C13 C18 75.4(7) . . . . ?
C1 N1 C13 C14 74.9(8) . . . . ?
Ag N1 C13 C14 -106.3(6) . . . . ?
C14 C13 C18 C17 -4.7(9) . . . . ?
N1 C13 C18 C17 173.6(6) . . . . ?
C14 C13 C18 C22 177.5(6) . . . . ?
N1 C13 C18 C22 -4.2(9) . . . . ?
C13 C18 C17 C16 0.7(10) . . . . ?
C22 C18 C17 C16 178.5(7) . . . . ?
C18 C17 C16 C15 3.3(12) . . . . ?
C17 C16 C15 C14 -3.5(13) . . . . ?
C16 C15 C14 C13 -0.4(11) . . . . ?
C16 C15 C14 C19 -178.7(7) . . . . ?
C18 C13 C14 C15 4.5(9) . . . . ?
N1 C13 C14 C15 -173.7(6) . . . . ?
C18 C13 C14 C19 -177.1(6) . . . . ?
N1 C13 C14 C19 4.6(9) . . . . ?
C13 C18 C22 C23 -145.7(7) . . . . ?
C17 C18 C22 C23 36.5(9) . . . . ?
C13 C18 C22 C24 90.3(8) . . . . ?
C17 C18 C22 C24 -87.4(8) . . . . ?
C15 C14 C19 C20 15.7(10) . . . . ?
C13 C14 C19 C20 -162.6(6) . . . . ?
C15 C14 C19 C21 -108.8(8) . . . . ?
C13 C14 C19 C21 73.0(8) . . . . ?
C2 N2 C25 C26 -99.5(8) . . . . ?
Ag N2 C25 C26 84.9(7) . . . . ?
C2 N2 C25 C30 81.7(7) . . . . ?
Ag N2 C25 C30 -93.9(7) . . . . ?
C26 C25 C30 C29 2.6(11) . . . . ?
N2 C25 C30 C29 -178.6(6) . . . . ?
C26 C25 C30 C34 -175.7(8) . . . . ?
N2 C25 C30 C34 3.0(10) . . . . ?
C25 C30 C29 C28 0.4(12) . . . . ?
C34 C30 C29 C28 178.7(8) . . . . ?
C30 C29 C28 C27 -1.8(14) . . . . ?
C29 C28 C27 C26 0.4(14) . . . . ?
C30 C25 C26 C27 -3.9(11) . . . . ?
N2 C25 C26 C27 177.3(7) . . . . ?
C30 C25 C26 C31 176.4(8) . . . . ?
N2 C25 C26 C31 -2.4(11) . . . . ?
C28 C27 C26 C25 2.4(13) . . . . ?
C28 C27 C26 C31 -177.9(9) . . . . ?
C29 C30 C34 C35 66.0(11) . . . . ?
C25 C30 C34 C35 -115.8(9) . . . . ?
C29 C30 C34 C36 -54.5(11) . . . . ?
C25 C30 C34 C36 123.8(8) . . . . ?
C25 C26 C31 C33 92.8(11) . . . . ?
C27 C26 C31 C33 -86.9(12) . . . . ?
C25 C26 C31 C32 -144.8(8) . . . . ?
C27 C26 C31 C32 35.6(12) . . . . ?
C42 C43 C44 C45 177.9(8) . . . . ?
C48 C43 C44 C45 -2.0(11) . . . . ?
C43 C44 C45 C46 1.6(12) . . . . ?
C44 C45 C46 C47 -1.1(12) . . . . ?
C45 C46 C47 C48 1.1(11) . . . . ?
C45 C46 C47 C37 177.7(7) . . . . ?
C46 C47 C48 C39 179.3(6) . . . . ?
C37 C47 C48 C39 1.7(8) . . . . ?
C46 C47 C48 C43 -1.7(11) . . . . ?
C37 C47 C48 C43 -179.2(6) . . . . ?
C42 C43 C48 C39 1.1(10) . . . . ?
C44 C43 C48 C39 -178.9(6) . . . . ?
C42 C43 C48 C47 -177.8(7) . . . . ?
C44 C43 C48 C47 2.1(10) . . . . ?
C47 C48 C39 C40 176.8(7) . . . . ?
C43 C48 C39 C40 -2.2(10) . . . . ?
C47 C48 C39 C38 -2.9(8) . . . . ?
C43 C48 C39 C38 178.1(6) . . . . ?
C48 C39 C40 C41 1.8(11) . . . . ?
C38 C39 C40 C41 -178.7(7) . . . . ?
C39 C40 C41 C42 -0.3(12) . . . . ?
C40 C41 C42 C43 -0.8(13) . . . . ?
C48 C43 C42 C41 0.4(11) . . . . ?
C44 C43 C42 C41 -179.5(8) . . . . ?
C49 N3 C37 C47 4.0(11) . . . . ?
Ag N3 C37 C47 -176.4(6) . . . . ?
C49 N3 C37 C38 -178.7(6) . . . . ?
Ag N3 C37 C38 0.9(8) . . . . ?
C46 C47 C37 N3 0.8(14) . . . . ?
C48 C47 C37 N3 177.8(7) . . . . ?
C46 C47 C37 C38 -176.8(8) . . . . ?
C48 C47 C37 C38 0.2(7) . . . . ?
C61 N4 C38 C39 2.9(11) . . . . ?
Ag N4 C38 C39 179.0(6) . . . . ?
C61 N4 C38 C37 -174.5(6) . . . . ?
Ag N4 C38 C37 1.6(8) . . . . ?
C40 C39 C38 N4 5.5(14) . . . . ?
C48 C39 C38 N4 -174.9(7) . . . . ?
C40 C39 C38 C37 -176.8(8) . . . . ?
C48 C39 C38 C37 2.8(7) . . . . ?
N3 C37 C38 N4 -1.8(10) . . . . ?
C47 C37 C38 N4 176.1(6) . . . . ?
N3 C37 C38 C39 -179.8(6) . . . . ?
C47 C37 C38 C39 -1.8(7) . . . . ?
C37 N3 C49 C50 -94.8(8) . . . . ?
Ag N3 C49 C50 85.7(7) . . . . ?
C37 N3 C49 C54 85.8(8) . . . . ?
Ag N3 C49 C54 -93.7(7) . . . . ?
C50 C49 C54 C53 4.6(10) . . . . ?
N3 C49 C54 C53 -176.0(6) . . . . ?
C50 C49 C54 C58 -175.7(7) . . . . ?
N3 C49 C54 C58 3.6(9) . . . . ?
C49 C54 C53 C52 -1.7(12) . . . . ?
C58 C54 C53 C52 178.7(8) . . . . ?
C54 C53 C52 C51 -1.9(14) . . . . ?
C53 C52 C51 C50 2.8(14) . . . . ?
C52 C51 C50 C49 0.0(12) . . . . ?
C52 C51 C50 C55 -179.5(9) . . . . ?
C54 C49 C50 C51 -3.8(11) . . . . ?
N3 C49 C50 C51 176.8(6) . . . . ?
C54 C49 C50 C55 175.7(8) . . . . ?
N3 C49 C50 C55 -3.7(12) . . . . ?
C53 C54 C58 C60 81.8(10) . . . . ?
C49 C54 C58 C60 -97.8(9) . . . . ?
C53 C54 C58 C59 -42.5(10) . . . . ?
C49 C54 C58 C59 137.9(7) . . . . ?
C51 C50 C55 C57 43.6(12) . . . . ?
C49 C50 C55 C57 -135.9(8) . . . . ?
C51 C50 C55 C56 -79.0(13) . . . . ?
C49 C50 C55 C56 101.5(10) . . . . ?
C38 N4 C61 C66 -102.8(7) . . . . ?
Ag N4 C61 C66 81.7(8) . . . . ?
C38 N4 C61 C62 75.1(8) . . . . ?
Ag N4 C61 C62 -100.4(6) . . . . ?
C66 C61 C62 C63 1.7(10) . . . . ?
N4 C61 C62 C63 -176.1(6) . . . . ?
C66 C61 C62 C67 -178.8(7) . . . . ?
N4 C61 C62 C67 3.3(10) . . . . ?
C61 C62 C63 C64 0.3(11) . . . . ?
C67 C62 C63 C64 -179.1(8) . . . . ?
C62 C63 C64 C65 -1.5(13) . . . . ?
C63 C64 C65 C66 0.6(13) . . . . ?
C62 C61 C66 C65 -2.5(10) . . . . ?
N4 C61 C66 C65 175.3(6) . . . . ?
C62 C61 C66 C70 -179.8(6) . . . . ?
N4 C61 C66 C70 -2.0(10) . . . . ?
C64 C65 C66 C61 1.4(11) . . . . ?
C64 C65 C66 C70 178.6(7) . . . . ?
C63 C62 C67 C68 22.1(12) . . . . ?
C61 C62 C67 C68 -157.4(8) . . . . ?
C63 C62 C67 C69 -105.7(9) . . . . ?
C61 C62 C67 C69 74.9(9) . . . . ?
C61 C66 C70 C72 88.4(9) . . . . ?
C65 C66 C70 C72 -88.7(9) . . . . ?
C61 C66 C70 C71 -146.3(7) . . . . ?
C65 C66 C70 C71 36.6(10) . . . . ?
F6 B F1 F4 -171.6(14) . . . . ?
F8 B F1 F4 -33(5) . . . . ?
F7 B F1 F4 -64.6(14) . . . . ?
F2 B F1 F4 39.9(15) . . . . ?
F3 B F1 F4 124.8(14) . . . . ?
F5 B F1 F4 -128.7(14) . . . . ?
F4 B F1 F5 128.7(14) . . . . ?
F6 B F1 F5 -42.9(12) . . . . ?
F8 B F1 F5 95(5) . . . . ?
F7 B F1 F5 64.1(10) . . . . ?
F2 B F1 F5 168.7(13) . . . . ?
F3 B F1 F5 -106.5(10) . . . . ?
F4 B F2 F8 -137.5(12) . . . . ?
F6 B F2 F8 43.1(12) . . . . ?
F1 B F2 F8 -166.7(13) . . . . ?
F7 B F2 F8 -52.0(9) . . . . ?
F3 B F2 F8 111.2(11) . . . . ?
F5 B F2 F8 -46(5) . . . . ?
F6 B F2 F4 -179.4(13) . . . . ?
F8 B F2 F4 137.5(12) . . . . ?
F1 B F2 F4 -29.2(11) . . . . ?
F7 B F2 F4 85.5(10) . . . . ?
F3 B F2 F4 -111.4(10) . . . . ?
F5 B F2 F4 92(5) . . . . ?
F4 B F3 F6 167.3(12) . . . . ?
F8 B F3 F6 -57.3(10) . . . . ?
F1 B F3 F6 127.5(11) . . . . ?
F7 B F3 F6 -21(4) . . . . ?
F2 B F3 F6 -120.2(10) . . . . ?
F5 B F3 F6 54.6(9) . . . . ?
F5 F1 F4 B -39.3(8) . . . . ?
B F1 F4 F2 -31.5(10) . . . . ?
F5 F1 F4 F2 -70.7(14) . . . . ?
F6 B F4 F1 36(6) . . . . ?
F8 B F4 F1 171.9(14) . . . . ?
F7 B F4 F1 122.2(14) . . . . ?
F2 B F4 F1 -141.8(14) . . . . ?
F3 B F4 F1 -60.2(14) . . . . ?
F5 B F4 F1 51.5(14) . . . . ?
F6 B F4 F2 178(6) . . . . ?
F8 B F4 F2 -46.3(12) . . . . ?
F1 B F4 F2 141.8(14) . . . . ?
F7 B F4 F2 -96.0(10) . . . . ?
F3 B F4 F2 81.6(11) . . . . ?
F5 B F4 F2 -166.7(12) . . . . ?
B F2 F4 F1 36.9(12) . . . . ?
F8 F2 F4 F1 72.2(16) . . . . ?
F8 F2 F4 B 35.3(9) . . . . ?
F4 B F5 F6 -176.3(12) . . . . ?
F8 B F5 F6 53.1(11) . . . . ?
F1 B F5 F6 -139.9(12) . . . . ?
F7 B F5 F6 102.0(11) . . . . ?
F2 B F5 F6 95(5) . . . . ?
F3 B F5 F6 -60.6(11) . . . . ?
F4 B F5 F7 81.6(11) . . . . ?
F6 B F5 F7 -102.0(11) . . . . ?
F8 B F5 F7 -49.0(10) . . . . ?
F1 B F5 F7 118.0(11) . . . . ?
F2 B F5 F7 -7(5) . . . . ?
F3 B F5 F7 -162.7(11) . . . . ?
F4 B F5 F1 -36.4(9) . . . . ?
F6 B F5 F1 139.9(12) . . . . ?
F8 B F5 F1 -167.0(12) . . . . ?
F7 B F5 F1 -118.0(11) . . . . ?
F2 B F5 F1 -125(5) . . . . ?
F3 B F5 F1 79.3(10) . . . . ?
F4 F1 F5 B 47.0(10) . . . . ?
F4 F1 F5 F6 81.1(15) . . . . ?
B F1 F5 F6 34.1(9) . . . . ?
F4 F1 F5 F7 1.5(13) . . . . ?
B F1 F5 F7 -45.5(7) . . . . ?
F4 B F6 F5 17(6) . . . . ?
F8 B F6 F5 -123.2(12) . . . . ?
F1 B F6 F5 47.7(13) . . . . ?
F7 B F6 F5 -68.8(10) . . . . ?
F2 B F6 F5 -165.5(13) . . . . ?
F3 B F6 F5 117.2(12) . . . . ?
F4 B F6 F8 140(6) . . . . ?
F1 B F6 F8 170.9(14) . . . . ?
F7 B F6 F8 54.4(9) . . . . ?
F2 B F6 F8 -42.3(12) . . . . ?
F3 B F6 F8 -119.6(11) . . . . ?
F5 B F6 F8 123.2(12) . . . . ?
F4 B F6 F3 -100(5) . . . . ?
F8 B F6 F3 119.6(11) . . . . ?
F1 B F6 F3 -69.5(13) . . . . ?
F7 B F6 F3 174.0(11) . . . . ?
F2 B F6 F3 77.3(12) . . . . ?
F5 B F6 F3 -117.2(11) . . . . ?
F7 F5 F6 B 53.2(6) . . . . ?
F1 F5 F6 B -31.4(8) . . . . ?
B F5 F6 F8 -44.5(7) . . . . ?
F7 F5 F6 F8 8.6(9) . . . . ?
F1 F5 F6 F8 -75.9(11) . . . . ?
B F5 F6 F3 46.1(7) . . . . ?
F7 F5 F6 F3 99.2(8) . . . . ?
F1 F5 F6 F3 14.7(11) . . . . ?
B F3 F6 F5 -49.4(7) . . . . ?
B F3 F6 F8 46.5(7) . . . . ?
F4 B F7 F8 130.9(12) . . . . ?
F6 B F7 F8 -61.2(10) . . . . ?
F1 B F7 F8 172.4(12) . . . . ?
F2 B F7 F8 56.8(10) . . . . ?
F3 B F7 F8 -41(4) . . . . ?
F5 B F7 F8 -121.7(12) . . . . ?
F4 B F7 F5 -107.4(10) . . . . ?
F6 B F7 F5 60.5(9) . . . . ?
F8 B F7 F5 121.7(12) . . . . ?
F1 B F7 F5 -65.9(11) . . . . ?
F2 B F7 F5 178.5(10) . . . . ?
F3 B F7 F5 80(4) . . . . ?
B F5 F7 F8 48.1(8) . . . . ?
F6 F5 F7 F8 -9.7(10) . . . . ?
F1 F5 F7 F8 92.6(10) . . . . ?
F6 F5 F7 B -57.8(7) . . . . ?
F1 F5 F7 B 44.5(7) . . . . ?
F5 F7 F8 B -43.6(7) . . . . ?
B F7 F8 F2 -50.8(7) . . . . ?
F5 F7 F8 F2 -94.4(10) . . . . ?
B F7 F8 F6 52.6(6) . . . . ?
F5 F7 F8 F6 9.1(9) . . . . ?
F4 B F8 F7 -63.0(14) . . . . ?
F6 B F8 F7 107.9(12) . . . . ?
F1 B F8 F7 -35(5) . . . . ?
F2 B F8 F7 -113.2(12) . . . . ?
F3 B F8 F7 168.3(12) . . . . ?
F5 B F8 F7 57.3(11) . . . . ?
F4 B F8 F2 50.2(13) . . . . ?
F6 B F8 F2 -138.9(12) . . . . ?
F1 B F8 F2 79(5) . . . . ?
F7 B F8 F2 113.2(12) . . . . ?
F3 B F8 F2 -78.5(11) . . . . ?
F5 B F8 F2 170.5(12) . . . . ?
F4 B F8 F6 -170.9(13) . . . . ?
F1 B F8 F6 -142(5) . . . . ?
F7 B F8 F6 -107.9(12) . . . . ?
F2 B F8 F6 138.9(12) . . . . ?
F3 B F8 F6 60.4(10) . . . . ?
F5 B F8 F6 -50.6(10) . . . . ?
B F2 F8 F7 53.3(7) . . . . ?
F4 F2 F8 F7 20.2(11) . . . . ?
F4 F2 F8 B -33.1(8) . . . . ?
B F2 F8 F6 -34.3(9) . . . . ?
F4 F2 F8 F6 -67.4(13) . . . . ?
B F6 F8 F7 -56.2(7) . . . . ?
F5 F6 F8 F7 -10.3(10) . . . . ?
F3 F6 F8 F7 -101.0(9) . . . . ?
F5 F6 F8 B 45.9(8) . . . . ?
F3 F6 F8 B -44.8(7) . . . . ?
B F6 F8 F2 34.7(9) . . . . ?
F5 F6 F8 F2 80.6(12) . . . . ?
F3 F6 F8 F2 -10.0(11) . . . . ?
