#------------------------------------------------------------------------------
#$Date: 2016-03-23 03:57:53 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179271 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/91/4319147.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4319147
loop_
_publ_author_name
'Gabriele Wagner'
'Matti Haukka'
'João J. R. Fraústo da Silva'
'Armando J. L. Pombeiro'
'Vadim Yu. Kukushkin'
_publ_section_title
;
 [2 + 3] Cycloaddition of Nitrones to Platinum-Bound Organonitriles:
 Effect of Metal Oxidation State and of Nitrile Substituent
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              264
_journal_page_last               271
_journal_paper_doi               10.1021/ic000477b
_journal_volume                  40
_journal_year                    2001
_chemical_formula_sum            'C22 H28 Cl2 N4 O2 Pt'
_chemical_formula_weight         646.47
_chemical_name_common            PtCl2(C11H14N2O)2
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 111.062(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.6378(2)
_cell_length_b                   19.0767(7)
_cell_length_c                   11.5782(4)
_cell_measurement_temperature    120(2)
_cell_volume                     2398.76(13)
_computing_cell_refinement       'Denzo/Scalepack (Otwinowski & Minor, 1997)'
_computing_data_collection       'Collect (Nonius, 1999)'
_computing_data_reduction        'Denzo/Scalepack (Otwinowski & Minor, 1997)'
_computing_molecular_graphics    'XP in SHELXTL v.5.1 (Bruker Axs, 1998)'
_computing_publication_material  SHELXL-97
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'DIRDIF99 (Beurskens et al., 1999)'
_diffrn_ambient_temperature      120(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Nonius KappaCCD'
_diffrn_measurement_method       phi/omega-scan
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0929
_diffrn_reflns_av_sigmaI/netI    0.0530
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            32023
_diffrn_reflns_theta_full        25.25
_diffrn_reflns_theta_max         25.25
_diffrn_reflns_theta_min         2.84
_exptl_absorpt_coefficient_mu    6.098
_exptl_absorpt_correction_T_max  0.4098
_exptl_absorpt_correction_T_min  0.3516
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Xprep in Shelxtl v. 5.1, Bruker AXS, 1998)'
_exptl_crystal_colour            'pale yellow'
_exptl_crystal_density_diffrn    1.790
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             1264
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.05
_refine_diff_density_max         0.703
_refine_diff_density_min         -0.693
_refine_diff_density_rms         0.154
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.167
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     286
_refine_ls_number_reflns         4315
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.167
_refine_ls_R_factor_all          0.0525
_refine_ls_R_factor_gt           0.0316
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0000P)²+11.8547P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0605
_refine_ls_wR_factor_ref         0.0664
_reflns_number_gt                3355
_reflns_number_total             4315
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic000477b_3.cif
_cod_data_source_block           gw190_2a=compound3a
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to the built-in table from CIF Core dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4319147
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.12403(2) 0.217631(12) 0.24962(2) 0.01238(8) Uani 1 1 d . . .
Cl1 Cl 0.22964(14) 0.29256(8) 0.16682(14) 0.0206(3) Uani 1 1 d . . .
Cl1A Cl 0.01536(14) 0.13944(8) 0.32389(13) 0.0177(3) Uani 1 1 d . . .
N1 N -0.0122(4) 0.2893(3) 0.2044(4) 0.0130(10) Uani 1 1 d . . .
N2 N -0.1265(5) 0.3857(3) 0.0970(5) 0.0185(12) Uani 1 1 d . . .
O1 O -0.1165(4) 0.3825(2) 0.2289(4) 0.0186(10) Uani 1 1 d . . .
N1A N 0.2663(5) 0.1506(3) 0.3082(4) 0.0155(11) Uani 1 1 d . . .
N2A N 0.3691(5) 0.0441(3) 0.3778(5) 0.0188(12) Uani 1 1 d . . .
O1A O 0.4482(4) 0.1072(2) 0.4259(4) 0.0194(10) Uani 1 1 d . . .
C1 C -0.0843(6) 0.3140(3) 0.0774(5) 0.0136(13) Uani 1 1 d . . .
H1 H -0.0276 0.3185 0.0303 0.016 Uiso 1 1 calc R . .
C2 C -0.0371(6) 0.3297(3) 0.2812(5) 0.0153(13) Uani 1 1 d . . .
C3 C -0.0329(7) 0.4381(3) 0.0974(6) 0.0247(16) Uani 1 1 d . . .
H3A H -0.0529 0.4833 0.1257 0.037 Uiso 1 1 calc R . .
H3B H -0.0320 0.4431 0.0135 0.037 Uiso 1 1 calc R . .
H3C H 0.0483 0.4226 0.1533 0.037 Uiso 1 1 calc R . .
C4 C -0.1896(6) 0.2666(3) 0.0061(5) 0.0143(13) Uani 1 1 d . . .
C5 C -0.2237(6) 0.2082(3) 0.0569(5) 0.0160(13) Uani 1 1 d . . .
H5 H -0.1873 0.1998 0.1433 0.019 Uiso 1 1 calc R . .
C6 C -0.3110(6) 0.1616(3) -0.0177(5) 0.0163(13) Uani 1 1 d . . .
H6 H -0.3346 0.1222 0.0187 0.020 Uiso 1 1 calc R . .
C7 C -0.3645(6) 0.1721(3) -0.1457(6) 0.0215(15) Uani 1 1 d . . .
C8 C -0.3334(6) 0.2325(4) -0.1940(6) 0.0237(16) Uani 1 1 d . . .
H8 H -0.3720 0.2421 -0.2798 0.028 Uiso 1 1 calc R . .
C9 C -0.2467(6) 0.2793(4) -0.1193(5) 0.0216(14) Uani 1 1 d . . .
H9 H -0.2267 0.3203 -0.1547 0.026 Uiso 1 1 calc R . .
C16 C -0.4506(7) 0.1182(4) -0.2280(6) 0.0277(17) Uani 1 1 d . . .
H16A H -0.5354 0.1357 -0.2550 0.042 Uiso 1 1 calc R . .
H16B H -0.4442 0.0744 -0.1819 0.042 Uiso 1 1 calc R . .
H16C H -0.4280 0.1096 -0.3006 0.042 Uiso 1 1 calc R . .
C1A C 0.2600(6) 0.0755(3) 0.2765(5) 0.0164(14) Uani 1 1 d . . .
H1A H 0.1826 0.0553 0.2814 0.020 Uiso 1 1 calc R . .
C2A C 0.3723(6) 0.1631(3) 0.3890(5) 0.0166(14) Uani 1 1 d . . .
C3A C 0.3362(6) 0.0212(4) 0.4819(6) 0.0236(15) Uani 1 1 d . . .
H3A1 H 0.2904 0.0585 0.5045 0.035 Uiso 1 1 calc R . .
H3A2 H 0.4113 0.0106 0.5526 0.035 Uiso 1 1 calc R . .
H3A3 H 0.2849 -0.0210 0.4585 0.035 Uiso 1 1 calc R . .
C4A C 0.2636(6) 0.0611(3) 0.1485(6) 0.0180(14) Uani 1 1 d . . .
C5A C 0.3491(6) 0.0922(3) 0.1073(6) 0.0234(16) Uani 1 1 d . . .
H5A H 0.4055 0.1255 0.1582 0.028 Uiso 1 1 calc R . .
C6A C 0.3533(7) 0.0755(4) -0.0066(6) 0.0258(16) Uani 1 1 d . . .
H6A H 0.4124 0.0976 -0.0335 0.031 Uiso 1 1 calc R . .
C7A C 0.2722(6) 0.0267(3) -0.0833(6) 0.0195(14) Uani 1 1 d . . .
C8A C 0.1836(6) -0.0027(3) -0.0437(6) 0.0207(14) Uani 1 1 d . . .
H8A H 0.1246 -0.0343 -0.0959 0.025 Uiso 1 1 calc R . .
C9A C 0.1813(6) 0.0142(3) 0.0722(6) 0.0206(14) Uani 1 1 d . . .
H9A H 0.1216 -0.0072 0.0993 0.025 Uiso 1 1 calc R . .
C10A C 0.4230(6) 0.2305(3) 0.4514(6) 0.0225(15) Uani 1 1 d . . .
H10A H 0.3888 0.2694 0.3943 0.034 Uiso 1 1 calc R . .
H10B H 0.5129 0.2302 0.4762 0.034 Uiso 1 1 calc R . .
H10C H 0.4007 0.2360 0.5249 0.034 Uiso 1 1 calc R . .
C16A C 0.2807(7) 0.0053(4) -0.2062(6) 0.0273(17) Uani 1 1 d . . .
H16D H 0.3604 -0.0172 -0.1916 0.041 Uiso 1 1 calc R . .
H16E H 0.2730 0.0469 -0.2580 0.041 Uiso 1 1 calc R . .
H16F H 0.2143 -0.0277 -0.2483 0.041 Uiso 1 1 calc R . .
C10 C 0.0142(7) 0.3270(3) 0.4172(6) 0.0228(15) Uani 1 1 d . . .
H10D H 0.0486 0.2803 0.4440 0.034 Uiso 1 1 calc R . .
H10E H -0.0511 0.3367 0.4498 0.034 Uiso 1 1 calc R . .
H10F H 0.0794 0.3623 0.4484 0.034 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1A Pt1 N1 175.17(19) . . ?
N1A Pt1 Cl1 92.12(15) . . ?
N1 Pt1 Cl1 87.63(14) . . ?
N1A Pt1 Cl1A 87.62(15) . . ?
N1 Pt1 Cl1A 92.86(14) . . ?
Cl1 Pt1 Cl1A 177.24(6) . . ?
C2 N1 C1 107.9(5) . . ?
C2 N1 Pt1 125.3(4) . . ?
C1 N1 Pt1 125.8(4) . . ?
C3 N2 O1 103.9(4) . . ?
C3 N2 C1 109.7(5) . . ?
O1 N2 C1 102.0(4) . . ?
C2 O1 N2 106.2(4) . . ?
C2A N1A C1A 108.2(5) . . ?
C2A N1A Pt1 126.3(4) . . ?
C1A N1A Pt1 125.0(4) . . ?
C3A N2A O1A 104.1(5) . . ?
C3A N2A C1A 111.4(5) . . ?
O1A N2A C1A 101.7(4) . . ?
C2A O1A N2A 105.8(4) . . ?
N1 C1 N2 103.8(4) . . ?
N1 C1 C4 114.3(5) . . ?
N2 C1 C4 112.6(5) . . ?
N1 C1 H1 108.6 . . ?
N2 C1 H1 108.6 . . ?
C4 C1 H1 108.6 . . ?
N1 C2 O1 115.1(5) . . ?
N1 C2 C10 127.9(6) . . ?
O1 C2 C10 117.0(5) . . ?
N2 C3 H3A 109.5 . . ?
N2 C3 H3B 109.5 . . ?
H3A C3 H3B 109.5 . . ?
N2 C3 H3C 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
C5 C4 C9 119.0(6) . . ?
C5 C4 C1 123.4(5) . . ?
C9 C4 C1 117.3(5) . . ?
C4 C5 C6 120.5(6) . . ?
C4 C5 H5 119.7 . . ?
C6 C5 H5 119.7 . . ?
C5 C6 C7 120.9(6) . . ?
C5 C6 H6 119.6 . . ?
C7 C6 H6 119.6 . . ?
C8 C7 C6 117.7(6) . . ?
C8 C7 C16 121.5(6) . . ?
C6 C7 C16 120.8(6) . . ?
C7 C8 C9 121.3(6) . . ?
C7 C8 H8 119.3 . . ?
C9 C8 H8 119.3 . . ?
C4 C9 C8 120.5(6) . . ?
C4 C9 H9 119.8 . . ?
C8 C9 H9 119.8 . . ?
C7 C16 H16A 109.5 . . ?
C7 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C7 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
N1A C1A N2A 103.9(5) . . ?
N1A C1A C4A 113.6(5) . . ?
N2A C1A C4A 112.1(5) . . ?
N1A C1A H1A 109.0 . . ?
N2A C1A H1A 109.0 . . ?
C4A C1A H1A 109.0 . . ?
N1A C2A O1A 115.8(6) . . ?
N1A C2A C10A 128.9(6) . . ?
O1A C2A C10A 115.3(5) . . ?
N2A C3A H3A1 109.5 . . ?
N2A C3A H3A2 109.5 . . ?
H3A1 C3A H3A2 109.5 . . ?
N2A C3A H3A3 109.5 . . ?
H3A1 C3A H3A3 109.5 . . ?
H3A2 C3A H3A3 109.5 . . ?
C9A C4A C5A 118.6(6) . . ?
C9A C4A C1A 119.1(6) . . ?
C5A C4A C1A 122.3(6) . . ?
C6A C5A C4A 120.6(6) . . ?
C6A C5A H5A 119.7 . . ?
C4A C5A H5A 119.7 . . ?
C5A C6A C7A 121.1(6) . . ?
C5A C6A H6A 119.4 . . ?
C7A C6A H6A 119.4 . . ?
C8A C7A C6A 118.2(6) . . ?
C8A C7A C16A 120.5(6) . . ?
C6A C7A C16A 121.3(6) . . ?
C7A C8A C9A 120.0(6) . . ?
C7A C8A H8A 120.0 . . ?
C9A C8A H8A 120.0 . . ?
C4A C9A C8A 121.3(6) . . ?
C4A C9A H9A 119.3 . . ?
C8A C9A H9A 119.3 . . ?
C2A C10A H10A 109.5 . . ?
C2A C10A H10B 109.5 . . ?
H10A C10A H10B 109.5 . . ?
C2A C10A H10C 109.5 . . ?
H10A C10A H10C 109.5 . . ?
H10B C10A H10C 109.5 . . ?
C7A C16A H16D 109.5 . . ?
C7A C16A H16E 109.5 . . ?
H16D C16A H16E 109.5 . . ?
C7A C16A H16F 109.5 . . ?
H16D C16A H16F 109.5 . . ?
H16E C16A H16F 109.5 . . ?
C2 C10 H10D 109.5 . . ?
C2 C10 H10E 109.5 . . ?
H10D C10 H10E 109.5 . . ?
C2 C10 H10F 109.5 . . ?
H10D C10 H10F 109.5 . . ?
H10E C10 H10F 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 N1A 2.008(5) . ?
Pt1 N1 2.015(5) . ?
Pt1 Cl1 2.3064(15) . ?
Pt1 Cl1A 2.3121(15) . ?
N1 C2 1.286(8) . ?
N1 C1 1.483(7) . ?
N2 C3 1.476(8) . ?
N2 O1 1.491(6) . ?
N2 C1 1.499(8) . ?
O1 C2 1.354(7) . ?
N1A C2A 1.274(8) . ?
N1A C1A 1.474(8) . ?
N2A C3A 1.456(8) . ?
N2A O1A 1.496(7) . ?
N2A C1A 1.509(8) . ?
O1A C2A 1.351(8) . ?
C1 C4 1.507(8) . ?
C1 H1 1.0000 . ?
C2 C10 1.471(8) . ?
C3 H3A 0.9800 . ?
C3 H3B 0.9800 . ?
C3 H3C 0.9800 . ?
C4 C5 1.382(8) . ?
C4 C9 1.384(8) . ?
C5 C6 1.392(9) . ?
C5 H5 0.9500 . ?
C6 C7 1.400(9) . ?
C6 H6 0.9500 . ?
C7 C8 1.384(9) . ?
C7 C16 1.511(9) . ?
C8 C9 1.391(9) . ?
C8 H8 0.9500 . ?
C9 H9 0.9500 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C1A C4A 1.523(8) . ?
C1A H1A 1.0000 . ?
C2A C10A 1.489(9) . ?
C3A H3A1 0.9800 . ?
C3A H3A2 0.9800 . ?
C3A H3A3 0.9800 . ?
C4A C9A 1.376(9) . ?
C4A C5A 1.383(9) . ?
C5A C6A 1.374(9) . ?
C5A H5A 0.9500 . ?
C6A C7A 1.395(9) . ?
C6A H6A 0.9500 . ?
C7A C8A 1.387(9) . ?
C7A C16A 1.517(9) . ?
C8A C9A 1.390(9) . ?
C8A H8A 0.9500 . ?
C9A H9A 0.9500 . ?
C10A H10A 0.9800 . ?
C10A H10B 0.9800 . ?
C10A H10C 0.9800 . ?
C16A H16D 0.9800 . ?
C16A H16E 0.9800 . ?
C16A H16F 0.9800 . ?
C10 H10D 0.9800 . ?
C10 H10E 0.9800 . ?
C10 H10F 0.9800 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1A Pt1 N1 C2 -19(3) . . . . ?
Cl1 Pt1 N1 C2 -106.1(5) . . . . ?
Cl1A Pt1 N1 C2 76.6(5) . . . . ?
N1A Pt1 N1 C1 149(2) . . . . ?
Cl1 Pt1 N1 C1 61.4(4) . . . . ?
Cl1A Pt1 N1 C1 -115.9(4) . . . . ?
C3 N2 O1 C2 -93.1(5) . . . . ?
C1 N2 O1 C2 21.0(6) . . . . ?
N1 Pt1 N1A C2A -23(3) . . . . ?
Cl1 Pt1 N1A C2A 64.0(5) . . . . ?
Cl1A Pt1 N1A C2A -118.7(5) . . . . ?
N1 Pt1 N1A C1A 149(2) . . . . ?
Cl1 Pt1 N1A C1A -124.5(4) . . . . ?
Cl1A Pt1 N1A C1A 52.7(4) . . . . ?
C3A N2A O1A C2A -95.9(5) . . . . ?
C1A N2A O1A C2A 19.9(6) . . . . ?
C2 N1 C1 N2 14.9(6) . . . . ?
Pt1 N1 C1 N2 -154.4(4) . . . . ?
C2 N1 C1 C4 -108.2(6) . . . . ?
Pt1 N1 C1 C4 82.5(6) . . . . ?
C3 N2 C1 N1 88.5(5) . . . . ?
O1 N2 C1 N1 -21.1(5) . . . . ?
C3 N2 C1 C4 -147.3(5) . . . . ?
O1 N2 C1 C4 103.1(5) . . . . ?
C1 N1 C2 O1 -1.3(7) . . . . ?
Pt1 N1 C2 O1 168.1(4) . . . . ?
C1 N1 C2 C10 -178.4(6) . . . . ?
Pt1 N1 C2 C10 -9.1(9) . . . . ?
N2 O1 C2 N1 -13.1(7) . . . . ?
N2 O1 C2 C10 164.3(5) . . . . ?
N1 C1 C4 C5 5.3(8) . . . . ?
N2 C1 C4 C5 -112.9(6) . . . . ?
N1 C1 C4 C9 -168.7(5) . . . . ?
N2 C1 C4 C9 73.1(7) . . . . ?
C9 C4 C5 C6 2.2(9) . . . . ?
C1 C4 C5 C6 -171.6(6) . . . . ?
C4 C5 C6 C7 1.1(9) . . . . ?
C5 C6 C7 C8 -4.0(9) . . . . ?
C5 C6 C7 C16 174.5(6) . . . . ?
C6 C7 C8 C9 3.6(10) . . . . ?
C16 C7 C8 C9 -174.9(6) . . . . ?
C5 C4 C9 C8 -2.7(9) . . . . ?
C1 C4 C9 C8 171.5(6) . . . . ?
C7 C8 C9 C4 -0.3(10) . . . . ?
C2A N1A C1A N2A 14.3(6) . . . . ?
Pt1 N1A C1A N2A -158.4(4) . . . . ?
C2A N1A C1A C4A -107.7(6) . . . . ?
Pt1 N1A C1A C4A 79.5(6) . . . . ?
C3A N2A C1A N1A 90.2(6) . . . . ?
O1A N2A C1A N1A -20.1(5) . . . . ?
C3A N2A C1A C4A -146.7(5) . . . . ?
O1A N2A C1A C4A 102.9(5) . . . . ?
C1A N1A C2A O1A -1.3(7) . . . . ?
Pt1 N1A C2A O1A 171.4(4) . . . . ?
C1A N1A C2A C10A -179.1(6) . . . . ?
Pt1 N1A C2A C10A -6.5(10) . . . . ?
N2A O1A C2A N1A -12.6(7) . . . . ?
N2A O1A C2A C10A 165.6(5) . . . . ?
N1A C1A C4A C9A -134.3(6) . . . . ?
N2A C1A C4A C9A 108.4(7) . . . . ?
N1A C1A C4A C5A 47.6(8) . . . . ?
N2A C1A C4A C5A -69.8(8) . . . . ?
C9A C4A C5A C6A -1.2(10) . . . . ?
C1A C4A C5A C6A 176.9(6) . . . . ?
C4A C5A C6A C7A -0.4(11) . . . . ?
C5A C6A C7A C8A 2.6(10) . . . . ?
C5A C6A C7A C16A -176.8(6) . . . . ?
C6A C7A C8A C9A -3.2(10) . . . . ?
C16A C7A C8A C9A 176.2(6) . . . . ?
C5A C4A C9A C8A 0.6(10) . . . . ?
C1A C4A C9A C8A -177.6(6) . . . . ?
C7A C8A C9A C4A 1.7(10) . . . . ?
