#------------------------------------------------------------------------------
#$Date: 2016-03-23 04:03:07 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179275 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/95/4319519.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4319519
loop_
_publ_author_name
'Oliver Just'
'William S. Rees'
_publ_section_title
;
 Synthesis and Single-Crystal X-ray Diffraction Examination of a
 Structurally Homologous Series of Tetracoordinate Heteroleptic Anionic
 Lanthanide Complexes: Ln{N[Si(CH3)2CH2CH2Si(CH3)2]}3(μ-Cl)Li(L)3 [Ln =
 Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb; (L)3= (THF)3, (Et2O)3, (THF)2(Et2O)]
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1751
_journal_page_last               1755
_journal_paper_doi               10.1021/ic9912023
_journal_volume                  40
_journal_year                    2001
_chemical_formula_sum            'C30 H72 Cl Eu Li N3 O3 Si6'
_chemical_formula_weight         885.80
_chemical_name_systematic
; 
? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 93.5390(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   25.6070(5)
_cell_length_b                   17.4284(4)
_cell_length_c                   21.2201(5)
_cell_measurement_temperature    173(2)
_cell_volume                     9452.2(4)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0550
_diffrn_reflns_av_sigmaI/netI    0.0662
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -30
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            48752
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         0.80
_exptl_absorpt_coefficient_mu    1.565
_exptl_crystal_density_diffrn    1.245
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3712
_refine_diff_density_max         1.179
_refine_diff_density_min         -1.201
_refine_diff_density_rms         0.101
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.013
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     895
_refine_ls_number_reflns         16639
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.013
_refine_ls_R_factor_all          0.0999
_refine_ls_R_factor_gt           0.0495
_refine_ls_shift/su_max          0.170
_refine_ls_shift/su_mean         0.002
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0429P)²+13.6264P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1042
_refine_ls_wR_factor_ref         0.1256
_reflns_number_gt                9760
_reflns_number_total             16639
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic9912023_2.cif
_cod_data_source_block           just35
_cod_database_code               4319519
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.130822(11) 0.246778(17) 0.223833(13) 0.02886(10) Uani 1 1 d . . .
Cl1 Cl 0.02923(7) 0.23864(12) 0.19031(9) 0.0627(5) Uani 1 1 d . . .
Cl2 Cl 0.46960(6) 0.76693(12) 0.07896(8) 0.0545(5) Uani 1 1 d . . .
Si1 Si 0.19063(9) 0.41945(13) 0.29094(11) 0.0659(7) Uani 1 1 d . . .
Si2 Si 0.11762(18) 0.43615(15) 0.19097(15) 0.1395(17) Uani 1 1 d . . .
Si3 Si 0.09039(9) 0.17260(13) 0.36325(9) 0.0556(6) Uani 1 1 d . . .
Si4 Si 0.19422(8) 0.13067(13) 0.34959(9) 0.0533(6) Uani 1 1 d . . .
Si5 Si 0.14358(8) 0.11805(11) 0.10241(8) 0.0427(5) Uani 1 1 d . . .
Si6 Si 0.23313(8) 0.20943(13) 0.11816(9) 0.0514(5) Uani 1 1 d . . .
Si7 Si 0.31939(8) 0.58237(11) -0.04276(8) 0.0444(5) Uani 1 1 d . . .
Si8 Si 0.38382(8) 0.56397(11) 0.06803(9) 0.0477(5) Uani 1 1 d . . .
Si9 Si 0.25813(7) 0.78484(12) 0.12538(9) 0.0442(5) Uani 1 1 d . . .
Si10 Si 0.34687(7) 0.87600(10) 0.15248(8) 0.0349(4) Uani 1 1 d . . .
Si11 Si 0.42396(7) 0.83983(11) -0.09892(8) 0.0391(4) Uani 1 1 d . . .
Si12 Si 0.31730(7) 0.87437(11) -0.09722(8) 0.0414(5) Uani 1 1 d . . .
Eu2 Eu 0.371659(11) 0.755499(16) 0.030963(12) 0.02493(9) Uani 1 1 d . . .
O1 O -0.0596(2) 0.3249(3) 0.0688(3) 0.0754(17) Uani 1 1 d . . .
O2 O -0.1017(2) 0.2860(4) 0.1951(3) 0.0741(16) Uani 1 1 d . . .
O3 O -0.0697(2) 0.1532(3) 0.1039(3) 0.087(2) Uani 1 1 d . . .
O4 O 0.56142(18) 0.6708(3) 0.1789(2) 0.0592(14) Uani 1 1 d . . .
O5 O 0.60546(18) 0.7719(3) 0.0730(2) 0.0559(13) Uani 1 1 d . . .
O6 O 0.56152(19) 0.8430(3) 0.1919(2) 0.0704(16) Uani 1 1 d . . .
N1 N 0.1521(2) 0.3709(3) 0.2359(2) 0.0519(15) Uani 1 1 d . . .
N2 N 0.1421(2) 0.1804(3) 0.3155(2) 0.0412(13) Uani 1 1 d . . .
N3 N 0.17260(19) 0.1915(3) 0.1453(2) 0.0380(13) Uani 1 1 d . . .
N4 N 0.35580(19) 0.6304(3) 0.0150(2) 0.0351(12) Uani 1 1 d . . .
N5 N 0.32035(18) 0.8041(3) 0.1042(2) 0.0318(12) Uani 1 1 d . . .
N6 N 0.36827(17) 0.8255(3) -0.0589(2) 0.0316(12) Uani 1 1 d . . .
Li2 Li 0.5519(4) 0.7628(7) 0.1322(5) 0.047(3) Uani 1 1 d . . .
Li1 Li -0.0527(5) 0.2529(7) 0.1366(6) 0.057(3) Uani 1 1 d . . .
C1 C 0.1766(4) 0.5231(5) 0.2724(4) 0.085(3) Uani 1 1 d . . .
H1A H 0.1558 0.5449 0.3033 0.11(3) Uiso 1 1 calc R . .
H1B H 0.2083 0.5513 0.2719 0.11(3) Uiso 1 1 calc R . .
C2 C 0.1471(5) 0.5260(6) 0.2069(5) 0.137(5) Uani 1 1 d . . .
H2A H 0.1709 0.5376 0.1755 0.24(5) Uiso 1 1 calc R . .
H2B H 0.1212 0.5649 0.2062 0.24(5) Uiso 1 1 calc R . .
C3 C 0.2607(4) 0.4005(7) 0.2831(7) 0.163(6) Uani 1 1 d . . .
H3A H 0.2808 0.4287 0.3143 0.19(3) Uiso 1 1 calc R . .
H3B H 0.2701 0.4157 0.2423 0.19(3) Uiso 1 1 calc R . .
H3C H 0.2674 0.3472 0.2888 0.19(3) Uiso 1 1 calc R . .
C4 C 0.1760(5) 0.3954(6) 0.3719(4) 0.130(5) Uani 1 1 d . . .
H4A H 0.1999 0.4212 0.4007 0.15(3) Uiso 1 1 calc R . .
H4B H 0.1792 0.3416 0.3780 0.15(3) Uiso 1 1 calc R . .
H4C H 0.1413 0.4110 0.3791 0.15(3) Uiso 1 1 calc R . .
C5 C 0.0471(5) 0.4519(8) 0.2285(7) 0.220(9) Uani 1 1 d . . .
H5A H 0.0298 0.4944 0.2086 0.100 Uiso 1 1 calc R . .
H5B H 0.0524 0.4614 0.2725 0.100 Uiso 1 1 calc R . .
H5C H 0.0264 0.4071 0.2219 0.100 Uiso 1 1 calc R . .
C6 C 0.0986(5) 0.4059(5) 0.1133(4) 0.122(4) Uani 1 1 d . . .
H6A H 0.0801 0.4460 0.0915 0.13(2) Uiso 1 1 calc R . .
H6B H 0.0767 0.3620 0.1150 0.13(2) Uiso 1 1 calc R . .
H6C H 0.1289 0.3933 0.0917 0.13(2) Uiso 1 1 calc R . .
C7 C 0.1225(3) 0.1411(5) 0.4402(4) 0.079(3) Uani 1 1 d . . .
H7A H 0.1354 0.1840 0.4640 0.12(3) Uiso 1 1 calc R . .
H7B H 0.0986 0.1138 0.4643 0.12(3) Uiso 1 1 calc R . .
C8 C 0.1676(3) 0.0888(5) 0.4225(3) 0.064(2) Uani 1 1 d . . .
H8A H 0.1553 0.0381 0.4145 0.068(17) Uiso 1 1 calc R . .
H8B H 0.1941 0.0871 0.4559 0.068(17) Uiso 1 1 calc R . .
C9 C 0.0527(3) 0.2635(5) 0.3691(3) 0.072(3) Uani 1 1 d . . .
H9A H 0.0353 0.2637 0.4074 0.12(2) Uiso 1 1 calc R . .
H9B H 0.0276 0.2671 0.3343 0.12(2) Uiso 1 1 calc R . .
H9C H 0.0760 0.3059 0.3687 0.12(2) Uiso 1 1 calc R . .
C10 C 0.0430(4) 0.0973(5) 0.3343(5) 0.097(3) Uani 1 1 d . . .
H10A H 0.0135 0.0979 0.3593 0.20(3) Uiso 1 1 calc R . .
H10B H 0.0594 0.0484 0.3375 0.20(3) Uiso 1 1 calc R . .
H10C H 0.0321 0.1072 0.2915 0.20(3) Uiso 1 1 calc R . .
C11 C 0.2176(4) 0.0529(6) 0.2991(4) 0.095(3) Uani 1 1 d . . .
H11A H 0.2441 0.0244 0.3219 0.102(18) Uiso 1 1 calc R . .
H11B H 0.2314 0.0745 0.2625 0.102(18) Uiso 1 1 calc R . .
H11C H 0.1892 0.0199 0.2868 0.102(18) Uiso 1 1 calc R . .
C12 C 0.2507(3) 0.1941(6) 0.3724(4) 0.096(3) Uani 1 1 d . . .
H12A H 0.2772 0.1651 0.3949 0.14(2) Uiso 1 1 calc R . .
H12B H 0.2395 0.2345 0.3984 0.14(2) Uiso 1 1 calc R . .
H12C H 0.2643 0.2151 0.3355 0.14(2) Uiso 1 1 calc R . .
C13 C 0.1996(3) 0.0749(5) 0.0621(4) 0.077(3) Uani 1 1 d . . .
H13A H 0.2158 0.0357 0.0875 0.14(3) Uiso 1 1 calc R . .
H13B H 0.1876 0.0532 0.0227 0.14(3) Uiso 1 1 calc R . .
C14 C 0.2381(5) 0.1399(9) 0.0521(8) 0.201(9) Uani 1 1 d . . .
H14A H 0.2298 0.1645 0.0128 0.43(11) Uiso 1 1 calc R . .
H14B H 0.2727 0.1203 0.0519 0.43(11) Uiso 1 1 calc R . .
C15 C 0.0931(3) 0.1533(4) 0.0418(3) 0.058(2) Uani 1 1 d . . .
H15A H 0.0675 0.1822 0.0619 0.116(19) Uiso 1 1 calc R . .
H15B H 0.0769 0.1108 0.0205 0.116(19) Uiso 1 1 calc R . .
H15C H 0.1094 0.1849 0.0122 0.116(19) Uiso 1 1 calc R . .
C16 C 0.1120(3) 0.0490(4) 0.1544(4) 0.066(2) Uani 1 1 d . . .
H16A H 0.0908 0.0145 0.1293 0.079(15) Uiso 1 1 calc R . .
H16B H 0.0908 0.0761 0.1821 0.079(15) Uiso 1 1 calc R . .
H16C H 0.1382 0.0210 0.1783 0.079(15) Uiso 1 1 calc R . .
C17 C 0.2871(4) 0.1955(10) 0.1760(5) 0.181(8) Uani 1 1 d . . .
H17A H 0.2882 0.2368 0.2053 0.23(4) Uiso 1 1 calc R . .
H17B H 0.3189 0.1938 0.1554 0.23(4) Uiso 1 1 calc R . .
H17C H 0.2825 0.1486 0.1978 0.23(4) Uiso 1 1 calc R . .
C18 C 0.2387(4) 0.3077(7) 0.0888(6) 0.147(6) Uani 1 1 d . . .
H18A H 0.2261 0.3098 0.0458 0.26(5) Uiso 1 1 calc R . .
H18B H 0.2744 0.3231 0.0923 0.26(5) Uiso 1 1 calc R . .
H18C H 0.2187 0.3412 0.1131 0.26(5) Uiso 1 1 calc R . .
C19 C -0.0294(5) 0.3262(9) 0.0155(5) 0.144(6) Uani 1 1 d . . .
H19A H -0.0299 0.2777 -0.0051 0.41(10) Uiso 1 1 calc R . .
H19B H 0.0059 0.3400 0.0268 0.41(10) Uiso 1 1 calc R . .
C20 C -0.0555(6) 0.3849(11) -0.0247(7) 0.215(10) Uani 1 1 d . . .
H20A H -0.0346 0.4300 -0.0237 0.21(5) Uiso 1 1 calc R . .
H20B H -0.0586 0.3670 -0.0670 0.21(5) Uiso 1 1 calc R . .
C21 C -0.1033(6) 0.4021(8) -0.0059(6) 0.137(5) Uani 1 1 d . . .
H21A H -0.1297 0.3765 -0.0313 0.40(10) Uiso 1 1 calc R . .
H21B H -0.1094 0.4558 -0.0082 0.40(10) Uiso 1 1 calc R . .
C22 C -0.1027(5) 0.3752(8) 0.0604(6) 0.159(7) Uani 1 1 d . . .
H22A H -0.0988 0.4173 0.0887 0.8(2) Uiso 1 1 calc R . .
H22B H -0.1343 0.3492 0.0678 0.8(2) Uiso 1 1 calc R . .
C23 C -0.0970(4) 0.3570(6) 0.2320(6) 0.105(3) Uani 1 1 d . . .
H23A H -0.1280 0.3868 0.2260 0.25(6) Uiso 1 1 calc R . .
H23B H -0.0683 0.3867 0.2196 0.25(6) Uiso 1 1 calc R . .
C24 C -0.0887(4) 0.3331(5) 0.2999(6) 0.095(3) Uani 1 1 d . . .
H24A H -0.0538 0.3437 0.3153 0.20(4) Uiso 1 1 calc R . .
H24B H -0.1121 0.3595 0.3253 0.20(4) Uiso 1 1 calc R . .
C25 C -0.0990(4) 0.2490(5) 0.3006(5) 0.084(3) Uani 1 1 d . . .
H25A H -0.1224 0.2363 0.3320 0.17(4) Uiso 1 1 calc R . .
H25B H -0.0675 0.2210 0.3084 0.17(4) Uiso 1 1 calc R . .
C26 C -0.1230(4) 0.2325(7) 0.2360(5) 0.092(3) Uani 1 1 d . . .
H26A H -0.1150 0.1817 0.2237 0.18(4) Uiso 1 1 calc R . .
H26B H -0.1600 0.2379 0.2353 0.18(4) Uiso 1 1 calc R . .
C27 C -0.1094(5) 0.1375(8) 0.0578(5) 0.126(5) Uani 1 1 d . . .
H27A H -0.1163 0.1812 0.0319 0.34(8) Uiso 1 1 calc R . .
H27B H -0.1407 0.1233 0.0767 0.34(8) Uiso 1 1 calc R . .
C28 C -0.0903(8) 0.0745(10) 0.0209(10) 0.232(11) Uani 1 1 d . . .
H28A H -0.0738 0.0932 -0.0150 0.27(7) Uiso 1 1 calc R . .
H28B H -0.1182 0.0414 0.0071 0.27(7) Uiso 1 1 calc R . .
C29 C -0.0526(7) 0.0343(10) 0.0641(9) 0.196(8) Uani 1 1 d . . .
H29A H -0.0664 -0.0139 0.0759 1.5(6) Uiso 1 1 calc R . .
H29B H -0.0209 0.0256 0.0442 1.5(6) Uiso 1 1 calc R . .
C30 C -0.0433(4) 0.0823(6) 0.1188(6) 0.109(4) Uani 1 1 d . . .
H30A H -0.0570 0.0592 0.1549 0.65(17) Uiso 1 1 calc R . .
H30B H -0.0069 0.0908 0.1272 0.65(17) Uiso 1 1 calc R . .
C31 C 0.3299(4) 0.4792(4) -0.0218(4) 0.074(3) Uani 1 1 d . . .
H31A H 0.2992 0.4502 -0.0327 0.11(2) Uiso 1 1 calc R . .
H31B H 0.3580 0.4586 -0.0438 0.11(2) Uiso 1 1 calc R . .
C32 C 0.3430(4) 0.4764(4) 0.0503(4) 0.080(3) Uani 1 1 d . . .
H32A H 0.3620 0.4311 0.0618 0.10(2) Uiso 1 1 calc R . .
H32B H 0.3120 0.4776 0.0726 0.10(2) Uiso 1 1 calc R . .
C33 C 0.3409(3) 0.6025(5) -0.1232(3) 0.073(3) Uani 1 1 d . . .
H33A H 0.3352 0.6551 -0.1330 0.092(16) Uiso 1 1 calc R . .
H33B H 0.3215 0.5715 -0.1531 0.092(16) Uiso 1 1 calc R . .
H33C H 0.3771 0.5911 -0.1245 0.092(16) Uiso 1 1 calc R . .
C34 C 0.2485(3) 0.6050(5) -0.0426(4) 0.077(3) Uani 1 1 d . . .
H34A H 0.2298 0.5753 -0.0740 0.105(18) Uiso 1 1 calc R . .
H34B H 0.2433 0.6580 -0.0515 0.105(18) Uiso 1 1 calc R . .
H34C H 0.2363 0.5934 -0.0024 0.105(18) Uiso 1 1 calc R . .
C35 C 0.3803(3) 0.5975(4) 0.1501(3) 0.056(2) Uani 1 1 d . . .
H35A H 0.3988 0.5628 0.1779 0.074(14) Uiso 1 1 calc R . .
H35B H 0.3448 0.5998 0.1604 0.074(14) Uiso 1 1 calc R . .
H35C H 0.3956 0.6470 0.1544 0.074(14) Uiso 1 1 calc R . .
C36 C 0.4535(3) 0.5449(5) 0.0542(4) 0.090(3) Uani 1 1 d . . .
H36A H 0.4669 0.5074 0.0833 0.094(16) Uiso 1 1 calc R . .
H36B H 0.4730 0.5910 0.0598 0.094(16) Uiso 1 1 calc R . .
H36C H 0.4562 0.5266 0.0123 0.094(16) Uiso 1 1 calc R . .
C37 C 0.2486(3) 0.8540(5) 0.1930(4) 0.065(2) Uani 1 1 d . . .
H37A H 0.2136 0.8724 0.1913 0.16(3) Uiso 1 1 calc R . .
H37B H 0.2559 0.8294 0.2325 0.16(3) Uiso 1 1 calc R . .
C38 C 0.2870(3) 0.9205(4) 0.1844(3) 0.058(2) Uani 1 1 d . . .
H38A H 0.2957 0.9451 0.2236 0.066(16) Uiso 1 1 calc R . .
H38B H 0.2722 0.9574 0.1556 0.066(16) Uiso 1 1 calc R . .
C39 C 0.2076(3) 0.8042(6) 0.0600(4) 0.084(3) Uani 1 1 d . . .
H39A H 0.1739 0.7920 0.0736 0.14(2) Uiso 1 1 calc R . .
H39B H 0.2146 0.7736 0.0244 0.14(2) Uiso 1 1 calc R . .
H39C H 0.2086 0.8569 0.0487 0.14(2) Uiso 1 1 calc R . .
C40 C 0.2481(3) 0.6850(5) 0.1504(4) 0.078(3) Uani 1 1 d . . .
H40A H 0.2546 0.6513 0.1166 0.12(2) Uiso 1 1 calc R . .
H40B H 0.2131 0.6787 0.1618 0.12(2) Uiso 1 1 calc R . .
H40C H 0.2715 0.6736 0.1857 0.12(2) Uiso 1 1 calc R . .
C41 C 0.3890(3) 0.8368(4) 0.2192(3) 0.0451(17) Uani 1 1 d . . .
H41A H 0.4015 0.8777 0.2456 0.060(12) Uiso 1 1 calc R . .
H41B H 0.4177 0.8103 0.2032 0.060(12) Uiso 1 1 calc R . .
H41C H 0.3692 0.8024 0.2430 0.060(12) Uiso 1 1 calc R . .
C42 C 0.3859(3) 0.9460(4) 0.1070(3) 0.057(2) Uani 1 1 d . . .
H42A H 0.4030 0.9813 0.1354 0.12(2) Uiso 1 1 calc R . .
H42B H 0.3632 0.9731 0.0777 0.12(2) Uiso 1 1 calc R . .
H42C H 0.4113 0.9190 0.0848 0.12(2) Uiso 1 1 calc R . .
C43 C 0.3978(3) 0.8748(4) -0.1776(3) 0.0550(19) Uani 1 1 d . . .
H43A H 0.4231 0.9054 -0.1969 0.056(15) Uiso 1 1 calc R . .
H43B H 0.3885 0.8329 -0.2047 0.056(15) Uiso 1 1 calc R . .
C44 C 0.3492(3) 0.9227(4) -0.1640(3) 0.0520(19) Uani 1 1 d . . .
H44A H 0.3257 0.9248 -0.2004 0.10(2) Uiso 1 1 calc R . .
H44B H 0.3592 0.9736 -0.1526 0.10(2) Uiso 1 1 calc R . .
C45 C 0.4678(3) 0.9143(5) -0.0606(3) 0.061(2) Uani 1 1 d . . .
H45A H 0.4495 0.9617 -0.0592 0.089(16) Uiso 1 1 calc R . .
H45B H 0.4978 0.9205 -0.0842 0.089(16) Uiso 1 1 calc R . .
H45C H 0.4783 0.8986 -0.0188 0.089(16) Uiso 1 1 calc R . .
C46 C 0.4627(3) 0.7503(4) -0.1062(4) 0.057(2) Uani 1 1 d . . .
H46A H 0.4944 0.7617 -0.1253 0.091(16) Uiso 1 1 calc R . .
H46B H 0.4430 0.7143 -0.1315 0.091(16) Uiso 1 1 calc R . .
H46C H 0.4705 0.7291 -0.0654 0.091(16) Uiso 1 1 calc R . .
C47 C 0.2868(3) 0.9458(5) -0.0468(3) 0.074(3) Uani 1 1 d . . .
H47A H 0.2783 0.9223 -0.0083 0.089(16) Uiso 1 1 calc R . .
H47B H 0.2559 0.9652 -0.0681 0.089(16) Uiso 1 1 calc R . .
H47C H 0.3106 0.9868 -0.0379 0.089(16) Uiso 1 1 calc R . .
C48 C 0.2633(3) 0.8097(5) -0.1283(4) 0.077(3) Uani 1 1 d . . .
H48A H 0.2355 0.8397 -0.1468 0.13(2) Uiso 1 1 calc R . .
H48B H 0.2510 0.7801 -0.0946 0.13(2) Uiso 1 1 calc R . .
H48C H 0.2761 0.7764 -0.1593 0.13(2) Uiso 1 1 calc R . .
C49 C 0.5241(3) 0.6480(6) 0.2246(4) 0.088(3) Uani 1 1 d . . .
H49A H 0.4970 0.6172 0.2054 156(84) Uiso 1 1 calc R . .
H49B H 0.5090 0.6916 0.2432 156(84) Uiso 1 1 calc R . .
C50 C 0.5571(4) 0.6031(6) 0.2725(5) 0.096(3) Uani 1 1 d . . .
H50A H 0.5725 0.6358 0.3043 0.20(5) Uiso 1 1 calc R . .
H50B H 0.5369 0.5651 0.2919 0.20(5) Uiso 1 1 calc R . .
C51 C 0.5977(4) 0.5674(6) 0.2348(5) 0.106(4) Uani 1 1 d . . .
H51A H 0.6297 0.5622 0.2596 0.19(4) Uiso 1 1 calc R . .
H51B H 0.5867 0.5181 0.2203 0.19(4) Uiso 1 1 calc R . .
C52 C 0.6043(4) 0.6194(5) 0.1810(4) 0.089(3) Uani 1 1 d . . .
H52A H 0.6363 0.6468 0.1868 0.20(4) Uiso 1 1 calc R . .
H52B H 0.6046 0.5911 0.1428 0.20(4) Uiso 1 1 calc R . .
C53 C 0.6260(5) 0.8433(6) 0.0541(6) 0.114(4) Uani 1 1 d . . .
H53A H 0.6626 0.8455 0.0639 0.23(5) Uiso 1 1 calc R . .
H53B H 0.6098 0.8844 0.0749 0.23(5) Uiso 1 1 calc R . .
C54 C 0.6145(5) 0.8485(10) -0.0148(7) 0.147(6) Uani 1 1 d . . .
H54A H 0.5827 0.8756 -0.0242 0.24(6) Uiso 1 1 calc R . .
H54B H 0.6420 0.8740 -0.0344 0.24(6) Uiso 1 1 calc R . .
C55 C 0.6099(5) 0.7706(9) -0.0360(6) 0.123(5) Uani 1 1 d . . .
H55A H 0.6401 0.7561 -0.0571 0.21(5) Uiso 1 1 calc R . .
H55B H 0.5801 0.7648 -0.0645 0.21(5) Uiso 1 1 calc R . .
C56 C 0.6049(3) 0.7230(5) 0.0203(4) 0.074(2) Uani 1 1 d . . .
H56A H 0.5730 0.6949 0.0166 0.11(2) Uiso 1 1 calc R . .
H56B H 0.6330 0.6876 0.0247 0.11(2) Uiso 1 1 calc R . .
C57 C 0.5312(3) 0.9084(5) 0.2041(4) 0.068(2) Uani 1 1 d . . .
H57A H 0.4959 0.9013 0.1886 0.13(3) Uiso 1 1 calc R . .
H57B H 0.5448 0.9526 0.1848 0.13(3) Uiso 1 1 calc R . .
C58 C 0.5346(4) 0.9166(6) 0.2749(5) 0.100(3) Uani 1 1 d . . .
H58A H 0.5335 0.9690 0.2870 0.32(7) Uiso 1 1 calc R . .
H58B H 0.5069 0.8899 0.2931 0.32(7) Uiso 1 1 calc R . .
C59 C 0.5864(5) 0.8816(8) 0.2943(6) 0.138(5) Uani 1 1 d . . .
H59A H 0.6113 0.9203 0.3059 0.24(6) Uiso 1 1 calc R . .
H59B H 0.5834 0.8480 0.3291 0.24(6) Uiso 1 1 calc R . .
C60 C 0.6017(5) 0.8403(8) 0.2403(6) 0.148(6) Uani 1 1 d . . .
H60A H 0.6327 0.8621 0.2257 0.30(7) Uiso 1 1 calc R . .
H60B H 0.6088 0.7884 0.2516 0.30(7) Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Li Li -0.0003 0.0001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Eu1 N3 112.0(2) . . ?
N1 Eu1 N2 112.18(19) . . ?
N3 Eu1 N2 112.06(18) . . ?
N1 Eu1 Cl1 107.99(15) . . ?
N3 Eu1 Cl1 106.32(13) . . ?
N2 Eu1 Cl1 105.86(14) . . ?
N1 Eu1 Si2 26.27(14) . . ?
N3 Eu1 Si2 108.09(15) . . ?
N2 Eu1 Si2 132.87(14) . . ?
Cl1 Eu1 Si2 85.02(9) . . ?
N1 Eu1 Si3 110.35(14) . . ?
N3 Eu1 Si3 131.04(13) . . ?
N2 Eu1 Si3 25.94(13) . . ?
Cl1 Eu1 Si3 82.46(6) . . ?
Si2 Eu1 Si3 120.74(8) . . ?
N1 Eu1 Si5 132.84(15) . . ?
N3 Eu1 Si5 25.45(13) . . ?
N2 Eu1 Si5 107.23(14) . . ?
Cl1 Eu1 Si5 84.35(5) . . ?
Si2 Eu1 Si5 119.56(7) . . ?
Si3 Eu1 Si5 116.42(5) . . ?
N1 Eu1 Si6 93.70(15) . . ?
N3 Eu1 Si6 21.13(13) . . ?
N2 Eu1 Si6 112.46(13) . . ?
Cl1 Eu1 Si6 124.04(5) . . ?
Si2 Eu1 Si6 96.59(9) . . ?
Si3 Eu1 Si6 137.18(5) . . ?
Si5 Eu1 Si6 46.58(5) . . ?
N1 Eu1 Si1 20.10(14) . . ?
N3 Eu1 Si1 115.92(13) . . ?
N2 Eu1 Si1 93.34(14) . . ?
Cl1 Eu1 Si1 122.13(6) . . ?
Si2 Eu1 Si1 46.10(6) . . ?
Si3 Eu1 Si1 96.67(6) . . ?
Si5 Eu1 Si1 140.90(5) . . ?
Si6 Eu1 Si1 95.07(6) . . ?
N1 Eu1 Si4 110.96(14) . . ?
N3 Eu1 Si4 95.38(13) . . ?
N2 Eu1 Si4 20.26(13) . . ?
Cl1 Eu1 Si4 123.37(6) . . ?
Si2 Eu1 Si4 136.50(6) . . ?
Si3 Eu1 Si4 46.20(5) . . ?
Si5 Eu1 Si4 97.31(5) . . ?
Si6 Eu1 Si4 92.70(5) . . ?
Si1 Eu1 Si4 90.86(5) . . ?
Li1 Cl1 Eu1 163.5(3) . . ?
Li2 Cl2 Eu2 171.2(3) . . ?
N1 Si1 C4 112.7(4) . . ?
N1 Si1 C3 112.0(5) . . ?
C4 Si1 C3 107.5(6) . . ?
N1 Si1 C1 103.8(3) . . ?
C4 Si1 C1 111.7(5) . . ?
C3 Si1 C1 109.2(5) . . ?
N1 Si1 Si2 35.8(2) . . ?
C4 Si1 Si2 125.3(4) . . ?
C3 Si1 Si2 124.6(5) . . ?
C1 Si1 Si2 68.0(3) . . ?
N1 Si1 Eu1 26.85(19) . . ?
C4 Si1 Eu1 94.2(3) . . ?
C3 Si1 Eu1 101.9(4) . . ?
C1 Si1 Eu1 130.1(3) . . ?
Si2 Si1 Eu1 62.32(7) . . ?
N1 Si2 C2 106.6(4) . . ?
N1 Si2 C6 115.3(4) . . ?
C2 Si2 C6 122.2(5) . . ?
N1 Si2 C5 108.3(5) . . ?
C2 Si2 C5 100.7(6) . . ?
C6 Si2 C5 101.8(6) . . ?
N1 Si2 Si1 36.05(19) . . ?
C2 Si2 Si1 71.6(4) . . ?
C6 Si2 Si1 145.1(4) . . ?
C5 Si2 Si1 106.8(4) . . ?
N1 Si2 Eu1 35.81(19) . . ?
C2 Si2 Eu1 142.2(4) . . ?
C6 Si2 Eu1 85.4(3) . . ?
C5 Si2 Eu1 97.5(4) . . ?
Si1 Si2 Eu1 71.58(7) . . ?
N2 Si3 C9 113.1(3) . . ?
N2 Si3 C7 103.0(3) . . ?
C9 Si3 C7 113.2(4) . . ?
N2 Si3 C10 111.7(3) . . ?
C9 Si3 C10 106.9(4) . . ?
C7 Si3 C10 108.9(4) . . ?
N2 Si3 Si4 35.59(17) . . ?
C9 Si3 Si4 136.9(3) . . ?
C7 Si3 Si4 69.0(3) . . ?
C10 Si3 Si4 112.7(3) . . ?
N2 Si3 Eu1 35.17(16) . . ?
C9 Si3 Eu1 85.6(3) . . ?
C7 Si3 Eu1 136.3(3) . . ?
C10 Si3 Eu1 101.8(3) . . ?
Si4 Si3 Eu1 70.75(6) . . ?
N2 Si4 C11 113.4(3) . . ?
N2 Si4 C12 112.5(4) . . ?
C11 Si4 C12 108.2(5) . . ?
N2 Si4 C8 103.4(3) . . ?
C11 Si4 C8 109.8(4) . . ?
C12 Si4 C8 109.4(4) . . ?
N2 Si4 Si3 35.79(17) . . ?
C11 Si4 Si3 126.6(3) . . ?
C12 Si4 Si3 123.3(3) . . ?
C8 Si4 Si3 67.6(2) . . ?
N2 Si4 Eu1 27.28(17) . . ?
C11 Si4 Eu1 97.3(3) . . ?
C12 Si4 Eu1 99.5(3) . . ?
C8 Si4 Eu1 130.6(2) . . ?
Si3 Si4 Eu1 63.06(5) . . ?
N3 Si5 C16 111.1(3) . . ?
N3 Si5 C15 112.2(3) . . ?
C16 Si5 C15 108.3(3) . . ?
N3 Si5 C13 102.9(3) . . ?
C16 Si5 C13 112.7(4) . . ?
C15 Si5 C13 109.5(4) . . ?
N3 Si5 Si6 35.42(17) . . ?
C16 Si5 Si6 133.2(2) . . ?
C15 Si5 Si6 115.0(2) . . ?
C13 Si5 Si6 68.8(3) . . ?
N3 Si5 Eu1 34.38(17) . . ?
C16 Si5 Eu1 85.0(3) . . ?
C15 Si5 Eu1 101.9(2) . . ?
C13 Si5 Eu1 135.5(3) . . ?
Si6 Si5 Eu1 69.80(6) . . ?
N3 Si6 C17 114.6(4) . . ?
N3 Si6 C18 112.1(4) . . ?
C17 Si6 C18 106.5(7) . . ?
N3 Si6 C14 103.8(4) . . ?
C17 Si6 C14 109.8(7) . . ?
C18 Si6 C14 110.0(8) . . ?
N3 Si6 Si5 35.38(17) . . ?
C17 Si6 Si5 126.3(5) . . ?
C18 Si6 Si5 125.0(3) . . ?
C14 Si6 Si5 68.5(4) . . ?
N3 Si6 Eu1 28.25(16) . . ?
C17 Si6 Eu1 99.0(4) . . ?
C18 Si6 Eu1 96.8(4) . . ?
C14 Si6 Eu1 132.1(4) . . ?
Si5 Si6 Eu1 63.62(5) . . ?
N4 Si7 C34 112.6(3) . . ?
N4 Si7 C33 112.7(3) . . ?
C34 Si7 C33 107.9(4) . . ?
N4 Si7 C31 103.7(3) . . ?
C34 Si7 C31 109.3(4) . . ?
C33 Si7 C31 110.7(4) . . ?
N4 Si7 Si8 35.94(17) . . ?
C34 Si7 Si8 123.2(3) . . ?
C33 Si7 Si8 126.7(3) . . ?
C31 Si7 Si8 67.8(2) . . ?
N4 Si7 Eu2 27.34(16) . . ?
C34 Si7 Eu2 99.1(3) . . ?
C33 Si7 Eu2 96.7(2) . . ?
C31 Si7 Eu2 131.0(2) . . ?
Si8 Si7 Eu2 63.27(5) . . ?
N4 Si8 C35 111.0(3) . . ?
N4 Si8 C36 112.3(3) . . ?
C35 Si8 C36 108.0(4) . . ?
N4 Si8 C32 102.1(3) . . ?
C35 Si8 C32 112.8(4) . . ?
C36 Si8 C32 110.6(4) . . ?
N4 Si8 Si7 35.28(16) . . ?
C35 Si8 Si7 134.0(2) . . ?
C36 Si8 Si7 114.1(3) . . ?
C32 Si8 Si7 68.5(2) . . ?
N4 Si8 Eu2 34.67(16) . . ?
C35 Si8 Eu2 84.3(2) . . ?
C36 Si8 Eu2 102.2(3) . . ?
C32 Si8 Eu2 134.7(3) . . ?
Si7 Si8 Eu2 69.95(6) . . ?
N5 Si9 C40 114.1(3) . . ?
N5 Si9 C39 112.4(3) . . ?
C40 Si9 C39 106.4(4) . . ?
N5 Si9 C37 103.8(3) . . ?
C40 Si9 C37 110.8(4) . . ?
C39 Si9 C37 109.3(4) . . ?
N5 Si9 Si10 35.75(16) . . ?
C40 Si9 Si10 127.0(3) . . ?
C39 Si9 Si10 124.4(3) . . ?
C37 Si9 Si10 68.1(2) . . ?
N5 Si9 Eu2 26.28(16) . . ?
C40 Si9 Eu2 98.9(2) . . ?
C39 Si9 Eu2 98.9(3) . . ?
C37 Si9 Eu2 130.1(2) . . ?
Si10 Si9 Eu2 62.04(5) . . ?
N5 Si10 C41 112.0(3) . . ?
N5 Si10 C38 102.3(3) . . ?
C41 Si10 C38 108.9(3) . . ?
N5 Si10 C42 111.5(3) . . ?
C41 Si10 C42 109.2(3) . . ?
C38 Si10 C42 112.8(4) . . ?
N5 Si10 Si9 35.39(16) . . ?
C41 Si10 Si9 111.9(2) . . ?
C38 Si10 Si9 68.9(2) . . ?
C42 Si10 Si9 135.4(2) . . ?
N5 Si10 Eu2 36.11(15) . . ?
C41 Si10 Eu2 102.9(2) . . ?
C38 Si10 Eu2 136.0(2) . . ?
C42 Si10 Eu2 83.2(2) . . ?
Si9 Si10 Eu2 71.50(5) . . ?
N6 Si11 C46 112.4(3) . . ?
N6 Si11 C43 103.2(3) . . ?
C46 Si11 C43 111.3(3) . . ?
N6 Si11 C45 112.3(3) . . ?
C46 Si11 C45 108.0(4) . . ?
C43 Si11 C45 109.6(3) . . ?
N6 Si11 Si12 35.61(16) . . ?
C46 Si11 Si12 135.0(3) . . ?
C43 Si11 Si12 69.2(2) . . ?
C45 Si11 Si12 113.9(3) . . ?
N6 Si11 Eu2 34.27(15) . . ?
C46 Si11 Eu2 86.8(2) . . ?
C43 Si11 Eu2 135.8(2) . . ?
C45 Si11 Eu2 101.5(2) . . ?
Si12 Si11 Eu2 69.86(5) . . ?
N6 Si12 C47 113.3(3) . . ?
N6 Si12 C48 113.0(3) . . ?
C47 Si12 C48 106.4(4) . . ?
N6 Si12 C44 103.1(3) . . ?
C47 Si12 C44 110.7(4) . . ?
C48 Si12 C44 110.5(4) . . ?
N6 Si12 Si11 35.65(16) . . ?
C47 Si12 Si11 126.9(3) . . ?
C48 Si12 Si11 124.5(3) . . ?
C44 Si12 Si11 67.4(2) . . ?
N6 Si12 Eu2 28.09(15) . . ?
C47 Si12 Eu2 96.1(2) . . ?
C48 Si12 Eu2 99.3(2) . . ?
C44 Si12 Eu2 131.1(2) . . ?
Si11 Si12 Eu2 63.73(5) . . ?
N4 Eu2 N6 113.59(17) . . ?
N4 Eu2 N5 111.19(17) . . ?
N6 Eu2 N5 112.55(17) . . ?
N4 Eu2 Cl2 106.82(13) . . ?
N6 Eu2 Cl2 105.61(12) . . ?
N5 Eu2 Cl2 106.48(12) . . ?
N4 Eu2 Si10 132.27(12) . . ?
N6 Eu2 Si10 107.80(12) . . ?
N5 Eu2 Si10 26.83(12) . . ?
Cl2 Eu2 Si10 83.08(5) . . ?
N4 Eu2 Si8 26.22(12) . . ?
N6 Eu2 Si8 135.63(12) . . ?
N5 Eu2 Si8 104.78(12) . . ?
Cl2 Eu2 Si8 85.13(6) . . ?
Si10 Eu2 Si8 116.27(4) . . ?
N4 Eu2 Si11 111.57(12) . . ?
N6 Eu2 Si11 25.42(12) . . ?
N5 Eu2 Si11 131.08(12) . . ?
Cl2 Eu2 Si11 82.59(5) . . ?
Si10 Eu2 Si11 116.02(4) . . ?
Si8 Eu2 Si11 124.03(5) . . ?
N4 Eu2 Si7 20.55(12) . . ?
N6 Eu2 Si7 95.25(12) . . ?
N5 Eu2 Si7 113.25(12) . . ?
Cl2 Eu2 Si7 122.95(5) . . ?
Si10 Eu2 Si7 139.32(4) . . ?
Si8 Eu2 Si7 46.78(4) . . ?
Si11 Eu2 Si7 99.25(4) . . ?
N4 Eu2 Si12 112.62(12) . . ?
N6 Eu2 Si12 21.01(12) . . ?
N5 Eu2 Si12 95.09(12) . . ?
Cl2 Eu2 Si12 123.66(5) . . ?
Si10 Eu2 Si12 97.72(4) . . ?
Si8 Eu2 Si12 138.67(4) . . ?
Si11 Eu2 Si12 46.42(4) . . ?
Si7 Eu2 Si12 92.15(4) . . ?
N4 Eu2 Si9 94.37(13) . . ?
N6 Eu2 Si9 113.27(12) . . ?
N5 Eu2 Si9 19.64(12) . . ?
Cl2 Eu2 Si9 122.81(5) . . ?
Si10 Eu2 Si9 46.46(4) . . ?
Si8 Eu2 Si9 94.25(5) . . ?
Si11 Eu2 Si9 137.21(4) . . ?
Si7 Eu2 Si9 93.90(5) . . ?
Si12 Eu2 Si9 92.84(4) . . ?
C22 O1 C19 110.6(8) . . ?
C22 O1 Li1 122.7(7) . . ?
C19 O1 Li1 125.8(8) . . ?
C26 O2 C23 104.5(8) . . ?
C26 O2 Li1 119.8(7) . . ?
C23 O2 Li1 124.6(7) . . ?
C27 O3 C30 107.5(8) . . ?
C27 O3 Li1 125.0(8) . . ?
C30 O3 Li1 127.5(7) . . ?
C52 O4 C49 110.2(6) . . ?
C52 O4 Li2 128.9(6) . . ?
C49 O4 Li2 120.6(6) . . ?
C56 O5 C53 107.0(7) . . ?
C56 O5 Li2 119.8(6) . . ?
C53 O5 Li2 123.2(7) . . ?
C60 O6 C57 106.1(7) . . ?
C60 O6 Li2 121.5(7) . . ?
C57 O6 Li2 132.0(6) . . ?
Si2 N1 Si1 108.2(3) . . ?
Si2 N1 Eu1 117.9(3) . . ?
Si1 N1 Eu1 133.1(3) . . ?
Si4 N2 Si3 108.6(3) . . ?
Si4 N2 Eu1 132.5(3) . . ?
Si3 N2 Eu1 118.9(3) . . ?
Si5 N3 Si6 109.2(3) . . ?
Si5 N3 Eu1 120.2(3) . . ?
Si6 N3 Eu1 130.6(3) . . ?
Si7 N4 Si8 108.8(3) . . ?
Si7 N4 Eu2 132.1(3) . . ?
Si8 N4 Eu2 119.1(2) . . ?
Si9 N5 Si10 108.9(3) . . ?
Si9 N5 Eu2 134.1(3) . . ?
Si10 N5 Eu2 117.1(2) . . ?
Si12 N6 Si11 108.7(3) . . ?
Si12 N6 Eu2 130.9(2) . . ?
Si11 N6 Eu2 120.3(2) . . ?
O6 Li2 O4 105.6(6) . . ?
O6 Li2 O5 107.9(6) . . ?
O4 Li2 O5 109.7(6) . . ?
O6 Li2 Cl2 112.3(5) . . ?
O4 Li2 Cl2 111.3(5) . . ?
O5 Li2 Cl2 109.9(5) . . ?
O1 Li1 O2 104.8(6) . . ?
O1 Li1 O3 108.4(7) . . ?
O2 Li1 O3 111.5(7) . . ?
O1 Li1 Cl1 118.4(6) . . ?
O2 Li1 Cl1 108.8(6) . . ?
O3 Li1 Cl1 105.0(5) . . ?
C2 C1 Si1 107.3(6) . . ?
C1 C2 Si2 108.9(7) . . ?
C8 C7 Si3 105.0(5) . . ?
C7 C8 Si4 106.7(5) . . ?
C14 C13 Si5 106.6(7) . . ?
C13 C14 Si6 107.7(9) . . ?
O1 C19 C20 102.9(11) . . ?
C21 C20 C19 112.0(13) . . ?
C20 C21 C22 104.8(12) . . ?
O1 C22 C21 106.3(10) . . ?
O2 C23 C24 106.3(9) . . ?
C25 C24 C23 105.6(9) . . ?
C24 C25 C26 104.1(9) . . ?
O2 C26 C25 106.6(8) . . ?
O3 C27 C28 105.8(12) . . ?
C27 C28 C29 104.8(14) . . ?
C30 C29 C28 107.2(14) . . ?
O3 C30 C29 105.7(12) . . ?
C32 C31 Si7 106.5(5) . . ?
C31 C32 Si8 104.9(5) . . ?
C38 C37 Si9 105.9(5) . . ?
C37 C38 Si10 105.9(5) . . ?
C44 C43 Si11 105.0(4) . . ?
C43 C44 Si12 107.0(5) . . ?
O4 C49 C50 103.2(6) . . ?
C51 C50 C49 103.7(8) . . ?
C52 C51 C50 106.0(8) . . ?
O4 C52 C51 106.7(7) . . ?
O5 C53 C54 106.2(10) . . ?
C55 C54 C53 105.1(11) . . ?
C54 C55 C56 106.8(11) . . ?
O5 C56 C55 107.9(9) . . ?
O6 C57 C58 105.2(7) . . ?
C59 C58 C57 103.4(9) . . ?
C60 C59 C58 105.5(10) . . ?
O6 C60 C59 110.2(10) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 N1 2.242(5) . ?
Eu1 N3 2.252(5) . ?
Eu1 N2 2.267(5) . ?
Eu1 Cl1 2.6580(17) . ?
Eu1 Si2 3.386(3) . ?
Eu1 Si3 3.446(2) . ?
Eu1 Si5 3.4472(18) . ?
Eu1 Si6 3.611(2) . ?
Eu1 Si1 3.628(2) . ?
Eu1 Si4 3.6492(19) . ?
Cl1 Li1 2.338(12) . ?
Cl2 Li2 2.330(11) . ?
Cl2 Eu2 2.6554(16) . ?
Si1 N1 1.706(5) . ?
Si1 C4 1.830(10) . ?
Si1 C3 1.843(11) . ?
Si1 C1 1.879(9) . ?
Si1 Si2 2.755(4) . ?
Si2 N1 1.696(6) . ?
Si2 C2 1.762(10) . ?
Si2 C6 1.770(9) . ?
Si2 C5 2.036(14) . ?
Si3 N2 1.722(5) . ?
Si3 C9 1.863(8) . ?
Si3 C7 1.864(7) . ?
Si3 C10 1.865(10) . ?
Si3 Si4 2.790(3) . ?
Si4 N2 1.713(5) . ?
Si4 C11 1.850(8) . ?
Si4 C12 1.861(9) . ?
Si4 C8 1.876(7) . ?
Si5 N3 1.713(5) . ?
Si5 C16 1.851(7) . ?
Si5 C15 1.869(7) . ?
Si5 C13 1.872(8) . ?
Si5 Si6 2.795(3) . ?
Si6 N3 1.715(5) . ?
Si6 C17 1.807(10) . ?
Si6 C18 1.831(12) . ?
Si6 C14 1.863(12) . ?
Si7 N4 1.712(5) . ?
Si7 C34 1.857(8) . ?
Si7 C33 1.859(7) . ?
Si7 C31 1.868(8) . ?
Si7 Si8 2.806(3) . ?
Si7 Eu2 3.6172(18) . ?
Si8 N4 1.739(5) . ?
Si8 C35 1.845(7) . ?
Si8 C36 1.856(8) . ?
Si8 C32 1.875(8) . ?
Si8 Eu2 3.4392(19) . ?
Si9 N5 1.715(5) . ?
Si9 C40 1.841(9) . ?
Si9 C39 1.869(8) . ?
Si9 C37 1.902(7) . ?
Si9 Si10 2.803(3) . ?
Si9 Eu2 3.6670(18) . ?
Si10 N5 1.731(5) . ?
Si10 C41 1.856(6) . ?
Si10 C38 1.880(7) . ?
Si10 C42 1.882(7) . ?
Si10 Eu2 3.4153(17) . ?
Si11 N6 1.723(5) . ?
Si11 C46 1.861(7) . ?
Si11 C43 1.863(7) . ?
Si11 C45 1.869(7) . ?
Si11 Si12 2.799(3) . ?
Si11 Eu2 3.4650(17) . ?
Si12 N6 1.721(5) . ?
Si12 C47 1.846(8) . ?
Si12 C48 1.871(8) . ?
Si12 C44 1.879(7) . ?
Si12 Eu2 3.6278(17) . ?
Eu2 N4 2.239(5) . ?
Eu2 N6 2.260(4) . ?
Eu2 N5 2.260(5) . ?
O1 C22 1.411(11) . ?
O1 C19 1.412(11) . ?
O1 Li1 1.909(14) . ?
O2 C26 1.408(10) . ?
O2 C23 1.466(11) . ?
O2 Li1 1.907(14) . ?
O3 C27 1.393(10) . ?
O3 C30 1.433(11) . ?
O3 Li1 1.912(13) . ?
O4 C52 1.415(9) . ?
O4 C49 1.457(8) . ?
O4 Li2 1.893(12) . ?
O5 C56 1.405(9) . ?
O5 C53 1.419(10) . ?
O5 Li2 1.925(13) . ?
O6 C60 1.409(9) . ?
O6 C57 1.413(9) . ?
O6 Li2 1.891(13) . ?
C1 C2 1.541(12) . ?
C7 C8 1.537(10) . ?
C13 C14 1.525(15) . ?
C19 C20 1.467(15) . ?
C20 C21 1.344(14) . ?
C21 C22 1.481(14) . ?
C23 C24 1.502(13) . ?
C24 C25 1.489(11) . ?
C25 C26 1.494(13) . ?
C27 C28 1.451(18) . ?
C28 C29 1.47(2) . ?
C29 C30 1.441(15) . ?
C31 C32 1.548(10) . ?
C37 C38 1.539(10) . ?
C43 C44 1.541(9) . ?
C49 C50 1.502(11) . ?
C50 C51 1.487(12) . ?
C51 C52 1.476(11) . ?
C53 C54 1.475(15) . ?
C54 C55 1.432(17) . ?
C55 C56 1.468(13) . ?
C57 C58 1.506(11) . ?
C58 C59 1.494(13) . ?
C59 C60 1.428(14) . ?
