#------------------------------------------------------------------------------
#$Date: 2016-03-23 15:12:49 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179317 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/14/4321489.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4321489
loop_
_publ_author_name
'Ruppa P. Kamalesh Babu'
'Kasani Aparna'
'Robert McDonald'
'Ronald G. Cavell'
_publ_section_title
;
 Dimeric Bridged and Chelated Alkali Metal (Li and Na)
 Bis(iminophosphorano)methanide Complexes with Contrasting Structures
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4981
_journal_page_last               4984
_journal_paper_doi               10.1021/ic991364z
_journal_volume                  39
_journal_year                    2000
_chemical_formula_sum            'C69 H86 Li2 N4 P4 Si4'
_chemical_formula_weight         1221.54
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 91.086(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   13.5173(12)
_cell_length_b                   21.335(2)
_cell_length_c                   24.581(2)
_cell_measurement_reflns_used    6818
_cell_measurement_temperature    193(2)
_cell_volume                     7087.7(11)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      193(2)
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0858
_diffrn_reflns_av_sigmaI/netI    0.1105
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            32936
_diffrn_reflns_theta_full        25.78
_diffrn_reflns_theta_max         25.78
_diffrn_reflns_theta_min         1.26
_exptl_absorpt_coefficient_mu    0.215
_exptl_absorpt_correction_T_max  0.9621
_exptl_absorpt_correction_T_min  0.6401
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.145
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       fragment
_exptl_crystal_F_000             2600
_exptl_crystal_size_max          0.34
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.18
_refine_diff_density_max         0.766
_refine_diff_density_min         -0.516
_refine_diff_density_rms         0.066
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.024
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     721
_refine_ls_number_reflns         13485
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.024
_refine_ls_R_factor_all          0.1407
_refine_ls_R_factor_gt           0.0807
_refine_ls_shift/su_max          0.011
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0932P)²+6.7197P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2042
_refine_ls_wR_factor_ref         0.2281
_reflns_number_gt                7569
_reflns_number_total             13485
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic991364z_2.cif
_cod_data_source_block           '[Li{?2-?N,?C,?N-CH(Ph2P=NSiMe3)2}]2'
_cod_database_code               4321489
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
P1 P -0.05988(10) 0.26327(6) 0.37267(5) 0.0380(3) Uani 1 1 d . . .
P2 P -0.25870(10) 0.33497(7) 0.34055(5) 0.0456(4) Uani 1 1 d . . .
P3 P 0.01695(9) 0.43375(6) 0.21411(5) 0.0349(3) Uani 1 1 d . . .
P4 P -0.05850(9) 0.30926(6) 0.15417(5) 0.0343(3) Uani 1 1 d . . .
Si1 Si 0.15553(14) 0.29421(9) 0.38336(8) 0.0744(6) Uani 1 1 d . . .
Si2 Si -0.40524(12) 0.38809(8) 0.25896(6) 0.0557(4) Uani 1 1 d . . .
Si3 Si 0.11173(12) 0.50594(8) 0.30433(6) 0.0525(4) Uani 1 1 d . . .
Si4 Si -0.22472(13) 0.21241(7) 0.14809(6) 0.0566(4) Uani 1 1 d . . .
N1 N 0.0331(3) 0.30820(19) 0.37034(17) 0.0501(11) Uani 1 1 d . . .
N2 N -0.2952(3) 0.35857(19) 0.28242(15) 0.0447(10) Uani 1 1 d . . .
N3 N 0.0399(3) 0.44743(18) 0.27679(14) 0.0401(10) Uani 1 1 d . . .
N4 N -0.1602(3) 0.27735(18) 0.16789(15) 0.0396(10) Uani 1 1 d . . .
C1 C -0.1575(4) 0.2871(2) 0.33108(18) 0.0423(12) Uani 1 1 d . . .
H1 H -0.1548 0.2702 0.2954 0.051 Uiso 1 1 calc R . .
C2 C -0.0212(3) 0.3560(2) 0.20834(18) 0.0371(11) Uani 1 1 d . . .
H2 H -0.0216 0.3346 0.2422 0.045 Uiso 1 1 calc R . .
C11 C -0.0297(3) 0.1852(2) 0.34936(18) 0.0357(11) Uani 1 1 d . . .
C12 C -0.0074(5) 0.1768(3) 0.2949(2) 0.0599(16) Uani 1 1 d . . .
H12 H -0.0148 0.2109 0.2703 0.072 Uiso 1 1 calc R . .
C13 C 0.0257(5) 0.1193(3) 0.2758(2) 0.0685(18) Uani 1 1 d . . .
H13 H 0.0437 0.1149 0.2388 0.082 Uiso 1 1 calc R . .
C14 C 0.0325(5) 0.0688(3) 0.3101(2) 0.0666(17) Uani 1 1 d . . .
H14 H 0.0540 0.0293 0.2969 0.080 Uiso 1 1 calc R . .
C15 C 0.0081(4) 0.0757(3) 0.3637(2) 0.0622(17) Uani 1 1 d . . .
H15 H 0.0120 0.0407 0.3875 0.075 Uiso 1 1 calc R . .
C16 C -0.0223(4) 0.1333(2) 0.3833(2) 0.0474(13) Uani 1 1 d . . .
H16 H -0.0384 0.1374 0.4206 0.057 Uiso 1 1 calc R . .
C17 C 0.1835(5) 0.2189(3) 0.4196(3) 0.090(2) Uani 1 1 d . . .
H17A H 0.1528 0.1840 0.3996 0.108 Uiso 1 1 calc R . .
H17B H 0.1569 0.2206 0.4564 0.108 Uiso 1 1 calc R . .
H17C H 0.2552 0.2127 0.4219 0.108 Uiso 1 1 calc R . .
C18 C 0.2100(8) 0.3572(4) 0.4267(4) 0.159(5) Uani 1 1 d . . .
H18A H 0.1992 0.3979 0.4091 0.191 Uiso 1 1 calc R . .
H18B H 0.2811 0.3499 0.4317 0.191 Uiso 1 1 calc R . .
H18C H 0.1782 0.3570 0.4622 0.191 Uiso 1 1 calc R . .
C19 C 0.2230(6) 0.2957(6) 0.3198(4) 0.148(5) Uani 1 1 d . . .
H19A H 0.1959 0.2638 0.2951 0.178 Uiso 1 1 calc R . .
H19B H 0.2931 0.2870 0.3273 0.178 Uiso 1 1 calc R . .
H19C H 0.2161 0.3371 0.3030 0.178 Uiso 1 1 calc R . .
C21 C -0.0972(4) 0.2516(2) 0.44314(19) 0.0502(14) Uani 1 1 d . . .
C22 C -0.1836(5) 0.2166(3) 0.4536(2) 0.0603(17) Uani 1 1 d . . .
H22 H -0.2191 0.1970 0.4246 0.072 Uiso 1 1 calc R . .
C23 C -0.2163(6) 0.2110(3) 0.5068(3) 0.094(3) Uani 1 1 d . . .
H23 H -0.2745 0.1879 0.5143 0.113 Uiso 1 1 calc R . .
C24 C -0.1628(9) 0.2397(5) 0.5486(3) 0.115(4) Uani 1 1 d . . .
H24 H -0.1847 0.2360 0.5850 0.138 Uiso 1 1 calc R . .
C25 C -0.0807(8) 0.2726(4) 0.5386(3) 0.108(3) Uani 1 1 d . . .
H25 H -0.0455 0.2922 0.5678 0.130 Uiso 1 1 calc R . .
C26 C -0.0461(6) 0.2786(3) 0.4854(2) 0.0745(19) Uani 1 1 d . . .
H26 H 0.0129 0.3014 0.4788 0.089 Uiso 1 1 calc R . .
C27 C -0.4413(5) 0.4609(3) 0.2961(2) 0.081(2) Uani 1 1 d . . .
H27A H -0.3870 0.4913 0.2949 0.097 Uiso 1 1 calc R . .
H27B H -0.4552 0.4506 0.3340 0.097 Uiso 1 1 calc R . .
H27C H -0.5006 0.4790 0.2787 0.097 Uiso 1 1 calc R . .
C28 C -0.3881(5) 0.4063(3) 0.1857(2) 0.0632(16) Uani 1 1 d . . .
H28A H -0.3332 0.4359 0.1820 0.076 Uiso 1 1 calc R . .
H28B H -0.4488 0.4250 0.1706 0.076 Uiso 1 1 calc R . .
H28C H -0.3731 0.3676 0.1660 0.076 Uiso 1 1 calc R . .
C29 C -0.5100(5) 0.3331(4) 0.2638(3) 0.089(2) Uani 1 1 d . . .
H29A H -0.5207 0.3226 0.3020 0.107 Uiso 1 1 calc R . .
H29B H -0.4952 0.2948 0.2435 0.107 Uiso 1 1 calc R . .
H29C H -0.5698 0.3526 0.2483 0.107 Uiso 1 1 calc R . .
C31 C -0.3597(4) 0.2971(3) 0.3766(2) 0.0581(16) Uani 1 1 d . . .
C32 C -0.4212(4) 0.3297(3) 0.4114(2) 0.072(2) Uani 1 1 d . . .
H32 H -0.4089 0.3728 0.4184 0.086 Uiso 1 1 calc R . .
C33 C -0.5003(6) 0.3000(4) 0.4360(3) 0.098(3) Uani 1 1 d . . .
H33 H -0.5418 0.3229 0.4597 0.118 Uiso 1 1 calc R . .
C34 C -0.5177(6) 0.2400(5) 0.4263(4) 0.112(3) Uani 1 1 d . . .
H34 H -0.5709 0.2200 0.4442 0.135 Uiso 1 1 calc R . .
C35 C -0.4601(6) 0.2049(4) 0.3904(3) 0.102(3) Uani 1 1 d . . .
H35 H -0.4743 0.1621 0.3831 0.123 Uiso 1 1 calc R . .
C36 C -0.3813(5) 0.2352(3) 0.3660(3) 0.077(2) Uani 1 1 d . . .
H36 H -0.3414 0.2126 0.3413 0.093 Uiso 1 1 calc R . .
C37 C 0.2468(4) 0.4952(3) 0.2928(2) 0.0724(19) Uani 1 1 d . . .
H37A H 0.2595 0.4972 0.2537 0.087 Uiso 1 1 calc R . .
H37B H 0.2679 0.4544 0.3071 0.087 Uiso 1 1 calc R . .
H37C H 0.2839 0.5285 0.3116 0.087 Uiso 1 1 calc R . .
C38 C 0.0929(5) 0.5060(4) 0.3786(2) 0.093(3) Uani 1 1 d . . .
H38A H 0.0222 0.5110 0.3858 0.111 Uiso 1 1 calc R . .
H38B H 0.1299 0.5408 0.3952 0.111 Uiso 1 1 calc R . .
H38C H 0.1164 0.4663 0.3941 0.111 Uiso 1 1 calc R . .
C39 C 0.0788(6) 0.5857(3) 0.2790(3) 0.094(2) Uani 1 1 d . . .
H39A H 0.0895 0.5878 0.2398 0.113 Uiso 1 1 calc R . .
H39B H 0.1204 0.6169 0.2976 0.113 Uiso 1 1 calc R . .
H39C H 0.0090 0.5942 0.2864 0.113 Uiso 1 1 calc R . .
C41 C -0.2211(4) 0.3979(3) 0.3861(2) 0.0500(14) Uani 1 1 d . . .
C42 C -0.2035(4) 0.4566(3) 0.3648(3) 0.0603(16) Uani 1 1 d . . .
H42 H -0.2146 0.4639 0.3270 0.072 Uiso 1 1 calc R . .
C43 C -0.1692(5) 0.5060(3) 0.3982(3) 0.0772(19) Uani 1 1 d . . .
H43 H -0.1575 0.5462 0.3831 0.093 Uiso 1 1 calc R . .
C44 C -0.1528(6) 0.4957(4) 0.4527(3) 0.090(2) Uani 1 1 d . . .
H44 H -0.1284 0.5285 0.4753 0.108 Uiso 1 1 calc R . .
C45 C -0.1718(6) 0.4377(4) 0.4743(3) 0.091(2) Uani 1 1 d . . .
H45 H -0.1607 0.4307 0.5121 0.109 Uiso 1 1 calc R . .
C46 C -0.2066(5) 0.3898(3) 0.4418(2) 0.074(2) Uani 1 1 d . . .
H46 H -0.2210 0.3504 0.4577 0.088 Uiso 1 1 calc R . .
C47 C -0.1531(6) 0.1384(3) 0.1595(3) 0.089(2) Uani 1 1 d . . .
H47A H -0.0903 0.1408 0.1403 0.107 Uiso 1 1 calc R . .
H47B H -0.1917 0.1027 0.1457 0.107 Uiso 1 1 calc R . .
H47C H -0.1397 0.1329 0.1986 0.107 Uiso 1 1 calc R . .
C48 C -0.3362(6) 0.2066(4) 0.1892(4) 0.123(4) Uani 1 1 d . . .
H48A H -0.3178 0.2104 0.2279 0.148 Uiso 1 1 calc R . .
H48B H -0.3681 0.1660 0.1827 0.148 Uiso 1 1 calc R . .
H48C H -0.3821 0.2404 0.1791 0.148 Uiso 1 1 calc R . .
C49 C -0.2585(9) 0.2117(5) 0.0746(3) 0.167(5) Uani 1 1 d . . .
H49A H -0.1985 0.2159 0.0531 0.200 Uiso 1 1 calc R . .
H49B H -0.3032 0.2468 0.0664 0.200 Uiso 1 1 calc R . .
H49C H -0.2916 0.1721 0.0655 0.200 Uiso 1 1 calc R . .
C51 C -0.0774(4) 0.4866(2) 0.18708(19) 0.0377(11) Uani 1 1 d . . .
C52 C -0.0937(4) 0.4994(2) 0.1319(2) 0.0435(12) Uani 1 1 d . . .
H52 H -0.0524 0.4809 0.1055 0.052 Uiso 1 1 calc R . .
C53 C -0.1696(4) 0.5389(3) 0.1153(2) 0.0537(14) Uani 1 1 d . . .
H53 H -0.1801 0.5472 0.0777 0.064 Uiso 1 1 calc R . .
C54 C -0.2301(4) 0.5663(3) 0.1529(3) 0.0646(17) Uani 1 1 d . . .
H54 H -0.2829 0.5925 0.1409 0.077 Uiso 1 1 calc R . .
C55 C -0.2150(4) 0.5560(3) 0.2079(3) 0.0659(17) Uani 1 1 d . . .
H55 H -0.2554 0.5759 0.2340 0.079 Uiso 1 1 calc R . .
C56 C -0.1390(4) 0.5159(2) 0.2241(2) 0.0511(14) Uani 1 1 d . . .
H56 H -0.1287 0.5081 0.2618 0.061 Uiso 1 1 calc R . .
C61 C 0.1249(4) 0.4498(3) 0.17334(18) 0.0445(13) Uani 1 1 d . . .
C62 C 0.1449(4) 0.5058(3) 0.1494(2) 0.0646(17) Uani 1 1 d . . .
H62 H 0.0992 0.5395 0.1518 0.077 Uiso 1 1 calc R . .
C63 C 0.2352(6) 0.5137(4) 0.1205(3) 0.085(2) Uani 1 1 d . . .
H63 H 0.2493 0.5520 0.1025 0.102 Uiso 1 1 calc R . .
C64 C 0.3019(6) 0.4640(5) 0.1193(3) 0.094(3) Uani 1 1 d . . .
H64 H 0.3622 0.4690 0.1005 0.113 Uiso 1 1 calc R . .
C65 C 0.2832(5) 0.4090(4) 0.1439(3) 0.089(2) Uani 1 1 d . . .
H65 H 0.3299 0.3758 0.1428 0.107 Uiso 1 1 calc R . .
C66 C 0.1969(4) 0.4018(3) 0.1704(2) 0.0631(16) Uani 1 1 d . . .
H66 H 0.1841 0.3629 0.1877 0.076 Uiso 1 1 calc R . .
C71 C -0.0632(4) 0.3533(2) 0.09052(18) 0.0367(11) Uani 1 1 d . . .
C72 C 0.0228(4) 0.3722(2) 0.06553(18) 0.0427(12) Uani 1 1 d . . .
H72 H 0.0854 0.3624 0.0816 0.051 Uiso 1 1 calc R . .
C73 C 0.0177(5) 0.4056(2) 0.0170(2) 0.0543(15) Uani 1 1 d . . .
H73 H 0.0769 0.4185 0.0000 0.065 Uiso 1 1 calc R . .
C74 C -0.0712(5) 0.4200(3) -0.0064(2) 0.0607(16) Uani 1 1 d . . .
H74 H -0.0740 0.4436 -0.0391 0.073 Uiso 1 1 calc R . .
C75 C -0.1579(5) 0.4001(3) 0.0175(2) 0.0579(15) Uani 1 1 d . . .
H75 H -0.2200 0.4087 0.0004 0.069 Uiso 1 1 calc R . .
C76 C -0.1536(4) 0.3675(2) 0.06635(19) 0.0461(13) Uani 1 1 d . . .
H76 H -0.2130 0.3550 0.0832 0.055 Uiso 1 1 calc R . .
C81 C 0.0382(4) 0.2521(2) 0.13935(19) 0.0444(13) Uani 1 1 d . . .
C82 C 0.1096(5) 0.2351(3) 0.1771(2) 0.0626(16) Uani 1 1 d . . .
H82 H 0.1128 0.2563 0.2111 0.075 Uiso 1 1 calc R . .
C83 C 0.1772(5) 0.1878(3) 0.1667(3) 0.089(2) Uani 1 1 d . . .
H83 H 0.2259 0.1767 0.1933 0.107 Uiso 1 1 calc R . .
C84 C 0.1728(6) 0.1571(3) 0.1173(3) 0.089(3) Uani 1 1 d . . .
H84 H 0.2177 0.1240 0.1103 0.107 Uiso 1 1 calc R . .
C85 C 0.1056(6) 0.1738(3) 0.0792(3) 0.077(2) Uani 1 1 d . . .
H85 H 0.1054 0.1537 0.0447 0.093 Uiso 1 1 calc R . .
C86 C 0.0365(5) 0.2201(2) 0.0895(2) 0.0574(15) Uani 1 1 d . . .
H86 H -0.0124 0.2302 0.0626 0.069 Uiso 1 1 calc R . .
Li1 Li -0.0136(7) 0.3763(4) 0.3202(3) 0.054(2) Uani 1 1 d . . .
Li2 Li -0.1845(6) 0.3320(4) 0.2349(3) 0.050(2) Uani 1 1 d . . .
C10S C 0.0271(11) 0.1059(7) 0.5379(6) 0.079(4) Uiso 0.50 1 d P . .
C11S C 0.0080(7) 0.0574(5) 0.5196(4) 0.109(3) Uiso 1 1 d . . .
C12S C -0.0781(6) 0.0366(4) 0.4929(3) 0.097(2) Uiso 1 1 d . . .
C13S C -0.0920(8) -0.0164(5) 0.4734(4) 0.129(3) Uiso 1 1 d . . .
C20S C 0.4057(11) 0.4871(7) 0.4313(6) 0.181(5) Uiso 1 1 d . . .
C21S C 0.4555(11) 0.4922(6) 0.4668(6) 0.072(4) Uiso 0.50 1 d P . .
C22S C 0.5595(8) 0.5253(4) 0.4713(5) 0.109(3) Uiso 1 1 d . . .
C23S C 0.6050(11) 0.5313(7) 0.5060(6) 0.078(4) Uiso 0.50 1 d P . .
C24S C 0.4848(14) 0.4824(8) 0.5608(7) 0.095(5) Uiso 0.50 1 d P . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Li Li -0.0003 0.0001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 P1 C1 113.5(2) . . ?
N1 P1 C11 111.2(2) . . ?
C1 P1 C11 104.9(2) . . ?
N1 P1 C21 110.5(3) . . ?
C1 P1 C21 112.3(2) . . ?
C11 P1 C21 104.0(2) . . ?
N2 P2 C1 107.5(2) . . ?
N2 P2 C41 113.5(2) . . ?
C1 P2 C41 107.9(3) . . ?
N2 P2 C31 110.8(2) . . ?
C1 P2 C31 113.8(2) . . ?
C41 P2 C31 103.4(3) . . ?
N3 P3 C2 107.8(2) . . ?
N3 P3 C51 111.3(2) . . ?
C2 P3 C51 110.9(2) . . ?
N3 P3 C61 110.8(2) . . ?
C2 P3 C61 111.9(2) . . ?
C51 P3 C61 104.3(2) . . ?
N4 P4 C2 109.1(2) . . ?
N4 P4 C71 112.9(2) . . ?
C2 P4 C71 111.6(2) . . ?
N4 P4 C81 112.6(2) . . ?
C2 P4 C81 109.8(2) . . ?
C71 P4 C81 100.7(2) . . ?
N1 Si1 C19 109.6(3) . . ?
N1 Si1 C18 110.7(4) . . ?
C19 Si1 C18 106.2(5) . . ?
N1 Si1 C17 115.2(3) . . ?
C19 Si1 C17 108.9(4) . . ?
C18 Si1 C17 105.9(4) . . ?
N2 Si2 C29 114.1(3) . . ?
N2 Si2 C28 106.3(2) . . ?
C29 Si2 C28 107.7(3) . . ?
N2 Si2 C27 112.1(3) . . ?
C29 Si2 C27 106.8(3) . . ?
C28 Si2 C27 109.7(3) . . ?
N3 Si3 C38 107.7(3) . . ?
N3 Si3 C39 113.8(3) . . ?
C38 Si3 C39 107.0(4) . . ?
N3 Si3 C37 113.5(2) . . ?
C38 Si3 C37 107.7(3) . . ?
C39 Si3 C37 106.9(3) . . ?
N4 Si4 C48 108.6(3) . . ?
N4 Si4 C49 113.6(3) . . ?
C48 Si4 C49 110.3(5) . . ?
N4 Si4 C47 112.5(3) . . ?
C48 Si4 C47 106.8(4) . . ?
C49 Si4 C47 104.9(5) . . ?
P1 N1 Si1 131.0(3) . . ?
P1 N1 Li1 102.7(4) . . ?
Si1 N1 Li1 122.5(4) . . ?
P2 N2 Si2 132.6(2) . . ?
P2 N2 Li2 102.3(3) . . ?
Si2 N2 Li2 124.4(3) . . ?
P3 N3 Si3 127.9(2) . . ?
P3 N3 Li1 108.1(3) . . ?
Si3 N3 Li1 123.4(3) . . ?
P4 N4 Si4 137.2(2) . . ?
P4 N4 Li2 94.6(3) . . ?
Si4 N4 Li2 127.1(3) . . ?
P2 C1 P1 133.7(3) . . ?
P2 C1 Li2 78.7(3) . . ?
P1 C1 Li2 138.3(3) . . ?
P2 C1 Li1 99.7(3) . . ?
P1 C1 Li1 74.1(3) . . ?
Li2 C1 Li1 74.9(3) . . ?
P4 C2 P3 133.8(3) . . ?
P4 C2 Li2 80.1(3) . . ?
P3 C2 Li2 117.3(3) . . ?
P4 C2 Li1 148.7(3) . . ?
P3 C2 Li1 76.5(2) . . ?
Li2 C2 Li1 77.2(3) . . ?
C16 C11 C12 117.6(4) . . ?
C16 C11 P1 123.8(3) . . ?
C12 C11 P1 118.5(4) . . ?
C11 C12 C13 121.0(5) . . ?
C14 C13 C12 120.3(5) . . ?
C13 C14 C15 119.5(5) . . ?
C14 C15 C16 120.5(5) . . ?
C15 C16 C11 121.0(5) . . ?
C26 C21 C22 119.5(5) . . ?
C26 C21 P1 121.2(5) . . ?
C22 C21 P1 119.2(4) . . ?
C23 C22 C21 119.6(7) . . ?
C24 C23 C22 119.2(8) . . ?
C25 C24 C23 121.0(7) . . ?
C24 C25 C26 120.8(8) . . ?
C21 C26 C25 119.9(8) . . ?
C36 C31 C32 118.1(6) . . ?
C36 C31 P2 119.3(4) . . ?
C32 C31 P2 122.4(5) . . ?
C31 C32 C33 120.9(7) . . ?
C34 C33 C32 119.8(7) . . ?
C33 C34 C35 122.0(7) . . ?
C36 C35 C34 117.5(8) . . ?
C31 C36 C35 121.7(7) . . ?
C42 C41 C46 117.6(6) . . ?
C42 C41 P2 119.1(4) . . ?
C46 C41 P2 123.2(4) . . ?
C41 C42 C43 121.0(6) . . ?
C44 C43 C42 119.7(7) . . ?
C43 C44 C45 119.7(7) . . ?
C44 C45 C46 120.6(7) . . ?
C45 C46 C41 121.4(6) . . ?
C56 C51 C52 117.4(5) . . ?
C56 C51 P3 117.6(4) . . ?
C52 C51 P3 125.0(4) . . ?
C53 C52 C51 120.5(5) . . ?
C54 C53 C52 120.6(5) . . ?
C53 C54 C55 120.8(5) . . ?
C54 C55 C56 118.1(5) . . ?
C55 C56 C51 122.6(5) . . ?
C62 C61 C66 118.1(5) . . ?
C62 C61 P3 124.8(5) . . ?
C66 C61 P3 116.9(4) . . ?
C61 C62 C63 119.6(7) . . ?
C64 C63 C62 118.6(7) . . ?
C65 C64 C63 121.9(7) . . ?
C64 C65 C66 119.0(8) . . ?
C65 C66 C61 122.8(7) . . ?
C76 C71 C72 119.2(4) . . ?
C76 C71 P4 119.9(4) . . ?
C72 C71 P4 120.9(4) . . ?
C71 C72 C73 120.0(5) . . ?
C74 C73 C72 120.6(5) . . ?
C73 C74 C75 120.0(5) . . ?
C74 C75 C76 119.8(6) . . ?
C71 C76 C75 120.3(5) . . ?
C82 C81 C86 117.4(5) . . ?
C82 C81 P4 122.4(4) . . ?
C86 C81 P4 119.9(4) . . ?
C81 C82 C83 121.5(6) . . ?
C84 C83 C82 119.4(7) . . ?
C85 C84 C83 120.4(6) . . ?
C84 C85 C86 120.8(6) . . ?
C85 C86 C81 120.4(6) . . ?
N3 Li1 N1 140.1(6) . . ?
N3 Li1 C1 147.7(5) . . ?
N1 Li1 C1 69.6(3) . . ?
N3 Li1 C2 66.3(3) . . ?
N1 Li1 C2 120.0(4) . . ?
C1 Li1 C2 88.6(3) . . ?
N2 Li2 N4 139.9(5) . . ?
N2 Li2 C2 144.3(5) . . ?
N4 Li2 C2 74.7(3) . . ?
N2 Li2 C1 70.3(3) . . ?
N4 Li2 C1 120.3(4) . . ?
C2 Li2 C1 102.6(4) . . ?
C10S C11S C12S 130.2(12) . . ?
C10S C11S C13S 109.1(12) . 3_556 ?
C12S C11S C13S 120.7(9) . 3_556 ?
C13S C12S C11S 126.1(9) . . ?
C12S C13S C11S 113.2(10) . 3_556 ?
C20S C21S C22S 129.2(15) . . ?
C20S C21S C22S 130.8(16) . 3_666 ?
C22S C21S C22S 99.8(10) . 3_666 ?
C23S C22S C21S 128.2(13) . . ?
C22S C23S C20S 133.7(15) . 3_666 ?
C22S C24S C20S 134.0(18) 3_666 3_666 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
P1 N1 1.583(4) . ?
P1 C1 1.730(5) . ?
P1 C11 1.812(5) . ?
P1 C21 1.830(5) . ?
P2 N2 1.585(4) . ?
P2 C1 1.727(5) . ?
P2 C41 1.814(6) . ?
P2 C31 1.831(5) . ?
P3 N3 1.593(4) . ?
P3 C2 1.743(5) . ?
P3 C51 1.818(5) . ?
P3 C61 1.818(5) . ?
P4 N4 1.576(4) . ?
P4 C2 1.731(5) . ?
P4 C71 1.825(5) . ?
P4 C81 1.829(5) . ?
Si1 N1 1.706(5) . ?
Si1 C19 1.823(8) . ?
Si1 C18 1.858(9) . ?
Si1 C17 1.873(7) . ?
Si2 N2 1.706(4) . ?
Si2 C29 1.845(7) . ?
Si2 C28 1.861(5) . ?
Si2 C27 1.871(6) . ?
Si3 N3 1.713(4) . ?
Si3 C38 1.848(6) . ?
Si3 C39 1.862(7) . ?
Si3 C37 1.867(6) . ?
Si4 N4 1.703(4) . ?
Si4 C48 1.834(7) . ?
Si4 C49 1.854(8) . ?
Si4 C47 1.871(7) . ?
N1 Li1 2.000(10) . ?
N2 Li2 1.997(9) . ?
N3 Li1 1.999(9) . ?
N4 Li2 2.050(9) . ?
C1 Li2 2.569(10) . ?
C1 Li1 2.737(11) . ?
C2 Li2 2.370(9) . ?
C2 Li1 2.784(10) . ?
C11 C16 1.388(6) . ?
C11 C12 1.390(6) . ?
C12 C13 1.390(7) . ?
C13 C14 1.370(8) . ?
C14 C15 1.370(7) . ?
C15 C16 1.387(7) . ?
C21 C26 1.363(8) . ?
C21 C22 1.414(8) . ?
C22 C23 1.393(8) . ?
C23 C24 1.389(13) . ?
C24 C25 1.340(13) . ?
C25 C26 1.403(9) . ?
C31 C36 1.375(9) . ?
C31 C32 1.389(7) . ?
C32 C33 1.391(9) . ?
C33 C34 1.323(12) . ?
C34 C35 1.405(11) . ?
C35 C36 1.392(9) . ?
C41 C42 1.380(7) . ?
C41 C46 1.391(7) . ?
C42 C43 1.409(9) . ?
C43 C44 1.370(10) . ?
C44 C45 1.373(10) . ?
C45 C46 1.375(9) . ?
C51 C56 1.392(7) . ?
C51 C52 1.398(6) . ?
C52 C53 1.382(7) . ?
C53 C54 1.375(8) . ?
C54 C55 1.382(8) . ?
C55 C56 1.389(8) . ?
C61 C62 1.363(7) . ?
C61 C66 1.415(8) . ?
C62 C63 1.434(9) . ?
C63 C64 1.392(11) . ?
C64 C65 1.346(11) . ?
C65 C66 1.356(8) . ?
C71 C76 1.381(7) . ?
C71 C72 1.386(6) . ?
C72 C73 1.391(7) . ?
C73 C74 1.356(8) . ?
C74 C75 1.387(8) . ?
C75 C76 1.388(7) . ?
C81 C82 1.375(8) . ?
C81 C86 1.403(7) . ?
C82 C83 1.389(8) . ?
C83 C84 1.378(10) . ?
C84 C85 1.342(10) . ?
C85 C86 1.385(8) . ?
C10S C11S 1.155(14) . ?
C11S C12S 1.397(11) . ?
C11S C13S 1.441(12) 3_556 ?
C12S C13S 1.242(11) . ?
C13S C11S 1.441(12) 3_556 ?
C20S C21S 1.098(17) . ?
C21S C22S 1.575(17) . ?
C21S C22S 1.584(16) 3_666 ?
C22S C23S 1.051(15) . ?
C23S C20S 1.600(19) 3_666 ?
C24S C22S 0.995(17) 3_666 ?
C24S C20S 1.62(2) 3_666 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 P1 N1 Si1 -154.9(3) . . . . ?
C11 P1 N1 Si1 -36.9(4) . . . . ?
C21 P1 N1 Si1 78.0(4) . . . . ?
C1 P1 N1 Li1 2.7(4) . . . . ?
C11 P1 N1 Li1 120.7(3) . . . . ?
C21 P1 N1 Li1 -124.3(3) . . . . ?
C19 Si1 N1 P1 109.0(5) . . . . ?
C18 Si1 N1 P1 -134.1(5) . . . . ?
C17 Si1 N1 P1 -14.1(5) . . . . ?
C19 Si1 N1 Li1 -44.9(6) . . . . ?
C18 Si1 N1 Li1 72.0(5) . . . . ?
C17 Si1 N1 Li1 -168.0(5) . . . . ?
C1 P2 N2 Si2 159.5(4) . . . . ?
C41 P2 N2 Si2 -81.2(4) . . . . ?
C31 P2 N2 Si2 34.6(5) . . . . ?
C1 P2 N2 Li2 -11.0(4) . . . . ?
C41 P2 N2 Li2 108.3(4) . . . . ?
C31 P2 N2 Li2 -135.9(4) . . . . ?
C29 Si2 N2 P2 -62.5(5) . . . . ?
C28 Si2 N2 P2 178.9(4) . . . . ?
C27 Si2 N2 P2 59.1(5) . . . . ?
C29 Si2 N2 Li2 106.2(5) . . . . ?
C28 Si2 N2 Li2 -12.4(5) . . . . ?
C27 Si2 N2 Li2 -132.2(4) . . . . ?
C2 P3 N3 Si3 159.4(3) . . . . ?
C51 P3 N3 Si3 -78.9(3) . . . . ?
C61 P3 N3 Si3 36.7(4) . . . . ?
C2 P3 N3 Li1 -12.3(4) . . . . ?
C51 P3 N3 Li1 109.4(4) . . . . ?
C61 P3 N3 Li1 -135.1(4) . . . . ?
C38 Si3 N3 P3 170.4(4) . . . . ?
C39 Si3 N3 P3 52.0(4) . . . . ?
C37 Si3 N3 P3 -70.6(4) . . . . ?
C38 Si3 N3 Li1 -19.0(5) . . . . ?
C39 Si3 N3 Li1 -137.4(5) . . . . ?
C37 Si3 N3 Li1 100.0(5) . . . . ?
C2 P4 N4 Si4 -156.5(4) . . . . ?
C71 P4 N4 Si4 78.8(4) . . . . ?
C81 P4 N4 Si4 -34.4(5) . . . . ?
C2 P4 N4 Li2 11.5(4) . . . . ?
C71 P4 N4 Li2 -113.2(3) . . . . ?
C81 P4 N4 Li2 133.6(3) . . . . ?
C48 Si4 N4 P4 175.6(5) . . . . ?
C49 Si4 N4 P4 -61.3(6) . . . . ?
C47 Si4 N4 P4 57.7(5) . . . . ?
C48 Si4 N4 Li2 10.7(6) . . . . ?
C49 Si4 N4 Li2 133.8(6) . . . . ?
C47 Si4 N4 Li2 -107.3(5) . . . . ?
N2 P2 C1 P1 158.1(4) . . . . ?
C41 P2 C1 P1 35.3(5) . . . . ?
C31 P2 C1 P1 -78.8(5) . . . . ?
N2 P2 C1 Li2 8.5(3) . . . . ?
C41 P2 C1 Li2 -114.3(3) . . . . ?
C31 P2 C1 Li2 131.6(3) . . . . ?
N2 P2 C1 Li1 80.8(3) . . . . ?
C41 P2 C1 Li1 -42.0(3) . . . . ?
C31 P2 C1 Li1 -156.1(3) . . . . ?
N1 P1 C1 P2 -90.3(4) . . . . ?
C11 P1 C1 P2 148.1(4) . . . . ?
C21 P1 C1 P2 35.8(5) . . . . ?
N1 P1 C1 Li2 41.6(5) . . . . ?
C11 P1 C1 Li2 -80.0(5) . . . . ?
C21 P1 C1 Li2 167.7(5) . . . . ?
N1 P1 C1 Li1 -2.0(3) . . . . ?
C11 P1 C1 Li1 -123.6(2) . . . . ?
C21 P1 C1 Li1 124.1(3) . . . . ?
N4 P4 C2 P3 -128.6(4) . . . . ?
C71 P4 C2 P3 -3.2(5) . . . . ?
C81 P4 C2 P3 107.6(4) . . . . ?
N4 P4 C2 Li2 -10.0(3) . . . . ?
C71 P4 C2 Li2 115.4(3) . . . . ?
C81 P4 C2 Li2 -133.8(3) . . . . ?
N4 P4 C2 Li1 33.9(7) . . . . ?
C71 P4 C2 Li1 159.4(6) . . . . ?
C81 P4 C2 Li1 -89.9(6) . . . . ?
N3 P3 C2 P4 179.4(3) . . . . ?
C51 P3 C2 P4 57.4(4) . . . . ?
C61 P3 C2 P4 -58.6(5) . . . . ?
N3 P3 C2 Li2 76.2(4) . . . . ?
C51 P3 C2 Li2 -45.8(4) . . . . ?
C61 P3 C2 Li2 -161.7(3) . . . . ?
N3 P3 C2 Li1 8.6(3) . . . . ?
C51 P3 C2 Li1 -113.3(3) . . . . ?
C61 P3 C2 Li1 130.7(3) . . . . ?
N1 P1 C11 C16 109.2(4) . . . . ?
C1 P1 C11 C16 -127.8(4) . . . . ?
C21 P1 C11 C16 -9.7(5) . . . . ?
N1 P1 C11 C12 -67.3(5) . . . . ?
C1 P1 C11 C12 55.8(5) . . . . ?
C21 P1 C11 C12 173.8(4) . . . . ?
C16 C11 C12 C13 -3.0(9) . . . . ?
P1 C11 C12 C13 173.6(5) . . . . ?
C11 C12 C13 C14 3.1(10) . . . . ?
C12 C13 C14 C15 -1.1(10) . . . . ?
C13 C14 C15 C16 -0.7(10) . . . . ?
C14 C15 C16 C11 0.6(9) . . . . ?
C12 C11 C16 C15 1.2(8) . . . . ?
P1 C11 C16 C15 -175.3(4) . . . . ?
N1 P1 C21 C26 -1.4(5) . . . . ?
C1 P1 C21 C26 -129.1(5) . . . . ?
C11 P1 C21 C26 118.0(5) . . . . ?
N1 P1 C21 C22 175.3(4) . . . . ?
C1 P1 C21 C22 47.6(5) . . . . ?
C11 P1 C21 C22 -65.3(4) . . . . ?
C26 C21 C22 C23 1.1(8) . . . . ?
P1 C21 C22 C23 -175.6(4) . . . . ?
C21 C22 C23 C24 -0.5(9) . . . . ?
C22 C23 C24 C25 0.2(12) . . . . ?
C23 C24 C25 C26 -0.5(14) . . . . ?
C22 C21 C26 C25 -1.4(9) . . . . ?
P1 C21 C26 C25 175.3(5) . . . . ?
C24 C25 C26 C21 1.2(12) . . . . ?
N2 P2 C31 C36 82.8(5) . . . . ?
C1 P2 C31 C36 -38.4(6) . . . . ?
C41 P2 C31 C36 -155.2(5) . . . . ?
N2 P2 C31 C32 -91.9(5) . . . . ?
C1 P2 C31 C32 146.9(5) . . . . ?
C41 P2 C31 C32 30.1(6) . . . . ?
C36 C31 C32 C33 2.0(9) . . . . ?
P2 C31 C32 C33 176.7(5) . . . . ?
C31 C32 C33 C34 0.0(11) . . . . ?
C32 C33 C34 C35 -1.8(13) . . . . ?
C33 C34 C35 C36 1.6(13) . . . . ?
C32 C31 C36 C35 -2.2(10) . . . . ?
P2 C31 C36 C35 -177.1(5) . . . . ?
C34 C35 C36 C31 0.5(11) . . . . ?
N2 P2 C41 C42 -15.6(5) . . . . ?
C1 P2 C41 C42 103.4(4) . . . . ?
C31 P2 C41 C42 -135.7(4) . . . . ?
N2 P2 C41 C46 166.0(5) . . . . ?
C1 P2 C41 C46 -75.0(5) . . . . ?
C31 P2 C41 C46 45.9(5) . . . . ?
C46 C41 C42 C43 1.8(8) . . . . ?
P2 C41 C42 C43 -176.7(4) . . . . ?
C41 C42 C43 C44 0.2(9) . . . . ?
C42 C43 C44 C45 -1.3(11) . . . . ?
C43 C44 C45 C46 0.4(11) . . . . ?
C44 C45 C46 C41 1.7(11) . . . . ?
C42 C41 C46 C45 -2.8(9) . . . . ?
P2 C41 C46 C45 175.6(5) . . . . ?
N3 P3 C51 C56 -20.5(5) . . . . ?
C2 P3 C51 C56 99.4(4) . . . . ?
C61 P3 C51 C56 -139.9(4) . . . . ?
N3 P3 C51 C52 160.4(4) . . . . ?
C2 P3 C51 C52 -79.7(4) . . . . ?
C61 P3 C51 C52 40.9(5) . . . . ?
C56 C51 C52 C53 -1.1(7) . . . . ?
P3 C51 C52 C53 178.0(4) . . . . ?
C51 C52 C53 C54 0.1(8) . . . . ?
C52 C53 C54 C55 1.5(9) . . . . ?
C53 C54 C55 C56 -1.9(9) . . . . ?
C54 C55 C56 C51 0.9(9) . . . . ?
C52 C51 C56 C55 0.6(8) . . . . ?
P3 C51 C56 C55 -178.6(4) . . . . ?
N3 P3 C61 C62 -91.4(5) . . . . ?
C2 P3 C61 C62 148.3(5) . . . . ?
C51 P3 C61 C62 28.4(5) . . . . ?
N3 P3 C61 C66 83.1(4) . . . . ?
C2 P3 C61 C66 -37.2(5) . . . . ?
C51 P3 C61 C66 -157.1(4) . . . . ?
C66 C61 C62 C63 2.4(8) . . . . ?
P3 C61 C62 C63 176.8(4) . . . . ?
C61 C62 C63 C64 -2.1(9) . . . . ?
C62 C63 C64 C65 0.7(11) . . . . ?
C63 C64 C65 C66 0.4(11) . . . . ?
C64 C65 C66 C61 -0.1(10) . . . . ?
C62 C61 C66 C65 -1.3(9) . . . . ?
P3 C61 C66 C65 -176.2(5) . . . . ?
N4 P4 C71 C76 14.2(4) . . . . ?
C2 P4 C71 C76 -109.1(4) . . . . ?
C81 P4 C71 C76 134.5(4) . . . . ?
N4 P4 C71 C72 -165.1(4) . . . . ?
C2 P4 C71 C72 71.7(4) . . . . ?
C81 P4 C71 C72 -44.8(4) . . . . ?
C76 C71 C72 C73 0.6(7) . . . . ?
P4 C71 C72 C73 179.8(4) . . . . ?
C71 C72 C73 C74 0.0(8) . . . . ?
C72 C73 C74 C75 -1.5(8) . . . . ?
C73 C74 C75 C76 2.4(8) . . . . ?
C72 C71 C76 C75 0.4(7) . . . . ?
P4 C71 C76 C75 -178.9(4) . . . . ?
C74 C75 C76 C71 -1.8(8) . . . . ?
N4 P4 C81 C82 -100.4(5) . . . . ?
C2 P4 C81 C82 21.3(5) . . . . ?
C71 P4 C81 C82 139.1(4) . . . . ?
N4 P4 C81 C86 74.4(4) . . . . ?
C2 P4 C81 C86 -163.9(4) . . . . ?
C71 P4 C81 C86 -46.1(4) . . . . ?
C86 C81 C82 C83 -0.5(8) . . . . ?
P4 C81 C82 C83 174.4(5) . . . . ?
C81 C82 C83 C84 0.1(10) . . . . ?
C82 C83 C84 C85 1.7(11) . . . . ?
C83 C84 C85 C86 -3.0(11) . . . . ?
C84 C85 C86 C81 2.6(9) . . . . ?
C82 C81 C86 C85 -0.8(8) . . . . ?
P4 C81 C86 C85 -175.9(4) . . . . ?
P3 N3 Li1 N1 117.1(7) . . . . ?
Si3 N3 Li1 N1 -55.1(9) . . . . ?
P3 N3 Li1 C1 -33.8(9) . . . . ?
Si3 N3 Li1 C1 154.0(6) . . . . ?
P3 N3 Li1 C2 8.0(3) . . . . ?
Si3 N3 Li1 C2 -164.2(3) . . . . ?
P1 N1 Li1 N3 -165.6(7) . . . . ?
Si1 N1 Li1 N3 -5.5(10) . . . . ?
P1 N1 Li1 C1 -1.7(2) . . . . ?
Si1 N1 Li1 C1 158.4(3) . . . . ?
P1 N1 Li1 C2 -77.5(5) . . . . ?
Si1 N1 Li1 C2 82.6(5) . . . . ?
P2 C1 Li1 N3 -65.0(9) . . . . ?
P1 C1 Li1 N3 162.1(9) . . . . ?
Li2 C1 Li1 N3 10.5(8) . . . . ?
P2 C1 Li1 N1 134.5(3) . . . . ?
P1 C1 Li1 N1 1.6(2) . . . . ?
Li2 C1 Li1 N1 -150.1(4) . . . . ?
P2 C1 Li1 C2 -102.6(3) . . . . ?
P1 C1 Li1 C2 124.5(3) . . . . ?
Li2 C1 Li1 C2 -27.2(3) . . . . ?
P4 C2 Li1 N3 -174.3(5) . . . . ?
P3 C2 Li1 N3 -7.1(2) . . . . ?
Li2 C2 Li1 N3 -129.7(4) . . . . ?
P4 C2 Li1 N1 50.2(9) . . . . ?
P3 C2 Li1 N1 -142.7(5) . . . . ?
Li2 C2 Li1 N1 94.7(5) . . . . ?
P4 C2 Li1 C1 -15.2(7) . . . . ?
P3 C2 Li1 C1 152.0(3) . . . . ?
Li2 C2 Li1 C1 29.4(3) . . . . ?
P2 N2 Li2 N4 121.5(7) . . . . ?
Si2 N2 Li2 N4 -50.0(9) . . . . ?
P2 N2 Li2 C2 -76.7(8) . . . . ?
Si2 N2 Li2 C2 111.8(8) . . . . ?
P2 N2 Li2 C1 7.4(3) . . . . ?
Si2 N2 Li2 C1 -164.1(3) . . . . ?
P4 N4 Li2 N2 160.9(7) . . . . ?
Si4 N4 Li2 N2 -29.3(10) . . . . ?
P4 N4 Li2 C2 -8.2(3) . . . . ?
Si4 N4 Li2 C2 161.6(3) . . . . ?
P4 N4 Li2 C1 -104.0(4) . . . . ?
Si4 N4 Li2 C1 65.8(6) . . . . ?
P4 C2 Li2 N2 -160.4(8) . . . . ?
P3 C2 Li2 N2 -25.9(10) . . . . ?
Li1 C2 Li2 N2 41.3(8) . . . . ?
P4 C2 Li2 N4 7.5(2) . . . . ?
P3 C2 Li2 N4 142.0(3) . . . . ?
Li1 C2 Li2 N4 -150.8(4) . . . . ?
P4 C2 Li2 C1 126.0(3) . . . . ?
P3 C2 Li2 C1 -99.5(4) . . . . ?
Li1 C2 Li2 C1 -32.3(3) . . . . ?
P2 C1 Li2 N2 -6.8(2) . . . . ?
P1 C1 Li2 N2 -153.5(5) . . . . ?
Li1 C1 Li2 N2 -110.2(3) . . . . ?
P2 C1 Li2 N4 -143.8(5) . . . . ?
P1 C1 Li2 N4 69.5(7) . . . . ?
Li1 C1 Li2 N4 112.8(5) . . . . ?
P2 C1 Li2 C2 136.7(3) . . . . ?
P1 C1 Li2 C2 -10.0(6) . . . . ?
Li1 C1 Li2 C2 33.3(3) . . . . ?
C10S C11S C12S C13S 178.6(13) . . . . ?
C13S C11S C12S C13S 0.2(17) 3_556 . . . ?
C11S C12S C13S C11S -0.2(16) . . . 3_556 ?
C20S C21S C22S C23S 177.4(18) . . . . ?
C22S C21S C22S C23S 2.4(16) 3_666 . . . ?
C21S C22S C23S C20S -1(3) . . . 3_666 ?
