#------------------------------------------------------------------------------
#$Date: 2016-03-23 15:18:08 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179321 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/18/4321887.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4321887
loop_
_publ_author_name
'Jian Jun Li'
'Wei Li'
'Alan J. James'
'Todd Holbert'
'Tristan P. Sharp'
'Paul R. Sharp'
_publ_contact_author
;
Paul R. Sharp
Department of Chemistry
University of Missouri
Columbia, MO 65211
;
_publ_contact_author_email       SharpP@missouri.edu
_publ_contact_author_fax         1-573-882-2574
_publ_contact_author_phone       1-573-882-7715
_publ_section_title
;
 Phosphine-Based Dinuclear Platinum(II) Diamido, Amido-Hydroxo, Oxo-Amido,
 Oxo-Imido, Diimido, and Dihydrazido Complexes1
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1563
_journal_page_last               1572
_journal_paper_doi               10.1021/ic981246w
_journal_volume                  38
_journal_year                    1999
_chemical_formula_moiety         '[(dppm-H)Pt(NHPh)]2'
_chemical_formula_sum            'C62 H54 N2 P4 Pt2'
_chemical_formula_weight         1341.13
_chemical_name_systematic
; 

 ? 

;
_space_group_IT_number           33
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  'P 2c -2n'
_symmetry_space_group_name_H-M   'P n a 21'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   38.2725(19)
_cell_length_b                   9.2841(5)
_cell_length_c                   15.0099(7)
_cell_measurement_temperature    173(2)
_cell_volume                     5333.4(5)
_computing_cell_refinement
'Siemens SMART Software Reference Manual (1994)'
_computing_data_collection
'Siemens SMART Software Reference Manual (1994)'
_computing_data_reduction        'Siemens SAINT version 4'
_computing_molecular_graphics    'Siemens SHELXTL'
_computing_publication_material  'Siemens SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution
'SHELXS-97 (Sheldrick, 1997) , RES2INS (Len Barbour, 1996)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'Siemens SMART CCD'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.0362
_diffrn_reflns_av_sigmaI/netI    0.0444
_diffrn_reflns_limit_h_max       49
_diffrn_reflns_limit_h_min       -48
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -9
_diffrn_reflns_number            31063
_diffrn_reflns_theta_full        27.22
_diffrn_reflns_theta_max         27.22
_diffrn_reflns_theta_min         1.06
_exptl_absorpt_coefficient_mu    5.402
_exptl_absorpt_correction_T_max  1.000000
_exptl_absorpt_correction_T_min  0.728627
_exptl_absorpt_correction_type   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.670
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       'rectangular prism'
_exptl_crystal_F_000             2624
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.25
_refine_diff_density_max         3.156
_refine_diff_density_min         -3.510
_refine_diff_density_rms         0.174
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.010(11)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.171
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     631
_refine_ls_number_reflns         9285
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.171
_refine_ls_R_factor_all          0.0662
_refine_ls_R_factor_gt           0.0535
_refine_ls_shift/su_max          0.090
_refine_ls_shift/su_mean         0.002
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0282P)²+44.4714P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1128
_refine_ls_wR_factor_ref         0.1196
_reflns_number_gt                7930
_reflns_number_total             9285
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic981246w_3.cif
_cod_data_source_block           '[(dppm-H)Pt(NHPh)]2'
_cod_database_code               4321887
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z+1/2'
'x+1/2, -y+1/2, z'
'-x+1/2, y+1/2, z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.845747(11) 0.71519(7) 0.37997(3) 0.04217(15) Uani 1 1 d . . .
Pt2 Pt 0.901797(11) 0.71742(6) 0.22087(2) 0.03976(13) Uani 1 1 d . . .
P1 P 0.84126(8) 0.7118(4) 0.5282(2) 0.0343(8) Uani 1 1 d . . .
P2 P 0.79221(8) 0.7939(4) 0.4204(3) 0.0374(8) Uani 1 1 d . . .
P3 P 0.95930(7) 0.7076(4) 0.1904(2) 0.0332(7) Uani 1 1 d . . .
P4 P 0.91174(8) 0.8072(4) 0.0835(2) 0.0345(7) Uani 1 1 d . . .
N1 N 0.8984(2) 0.6459(15) 0.3579(7) 0.043(3) Uani 1 1 d . . .
H1 H 0.9129 0.7056 0.3915 0.052 Uiso 1 1 calc R . .
N2 N 0.8492(3) 0.7726(19) 0.2447(9) 0.073(5) Uani 1 1 d . . .
H2 H 0.8479 0.8726 0.2422 0.088 Uiso 1 1 calc R . .
C1 C 0.8000(3) 0.7872(14) 0.5330(9) 0.035(3) Uani 1 1 d . . .
H1A H 0.7861 0.8159 0.5823 0.042 Uiso 1 1 calc R . .
C2 C 0.9569(3) 0.8040(15) 0.0933(8) 0.037(3) Uani 1 1 d . . .
H2A H 0.9746 0.8434 0.0565 0.044 Uiso 1 1 calc R . .
C3 C 0.9083(3) 0.510(2) 0.3740(9) 0.064(5) Uani 1 1 d . . .
C4 C 0.9409(4) 0.482(3) 0.4176(11) 0.088(7) Uani 1 1 d . . .
H4 H 0.9553 0.5588 0.4371 0.105 Uiso 1 1 calc R . .
C5 C 0.9511(4) 0.336(3) 0.4310(13) 0.090(8) Uani 1 1 d . . .
H5 H 0.9727 0.3153 0.4594 0.108 Uiso 1 1 calc R . .
C6 C 0.9301(5) 0.226(3) 0.4033(13) 0.106(9) Uani 1 1 d . . .
H6 H 0.9380 0.1296 0.4087 0.127 Uiso 1 1 calc R . .
C7 C 0.8968(5) 0.255(2) 0.3665(12) 0.082(6) Uani 1 1 d . . .
H7 H 0.8811 0.1794 0.3522 0.098 Uiso 1 1 calc R . .
C8 C 0.8877(5) 0.398(2) 0.3522(10) 0.075(6) Uani 1 1 d . . .
H8 H 0.8657 0.4177 0.3255 0.091 Uiso 1 1 calc R . .
C9 C 0.8230(3) 0.7163(19) 0.1794(9) 0.045(3) Uani 1 1 d . . .
C10 C 0.8230(4) 0.580(3) 0.1673(12) 0.077(6) Uani 1 1 d . . .
H10 H 0.8390 0.5186 0.1969 0.092 Uiso 1 1 calc R . .
C11 C 0.7992(5) 0.530(2) 0.1107(12) 0.073(5) Uani 1 1 d . . .
H11 H 0.7986 0.4290 0.1024 0.088 Uiso 1 1 calc R . .
C12 C 0.7757(3) 0.6074(19) 0.0638(10) 0.059(4) Uani 1 1 d . . .
H12 H 0.7600 0.5602 0.0243 0.071 Uiso 1 1 calc R . .
C13 C 0.7745(4) 0.7515(17) 0.0732(12) 0.059(4) Uani 1 1 d . . .
H13 H 0.7586 0.8093 0.0402 0.071 Uiso 1 1 calc R . .
C14 C 0.8008(4) 0.8184(16) 0.1414(13) 0.069(6) Uani 1 1 d . . .
H14 H 0.8016 0.9181 0.1555 0.083 Uiso 1 1 calc R . .
C41 C 0.8935(3) 0.9876(13) 0.0651(10) 0.039(3) Uani 1 1 d . . .
C1A C 0.8450(3) 0.5361(12) 0.5805(8) 0.032(3) Uani 1 1 d . . .
C2A C 0.8150(3) 0.4604(15) 0.6049(10) 0.050(4) Uani 1 1 d . . .
H2A1 H 0.7926 0.5024 0.5957 0.060 Uiso 1 1 calc R . .
C3A C 0.8174(4) 0.3259(15) 0.6420(13) 0.065(5) Uani 1 1 d . . .
H3A H 0.7968 0.2780 0.6610 0.078 Uiso 1 1 calc R . .
C4A C 0.8497(4) 0.2581(14) 0.6522(11) 0.054(4) Uani 1 1 d . . .
H4A H 0.8513 0.1638 0.6765 0.065 Uiso 1 1 calc R . .
C5A C 0.8794(4) 0.3325(15) 0.6260(10) 0.047(3) Uani 1 1 d . . .
H5A H 0.9016 0.2871 0.6308 0.057 Uiso 1 1 calc R . .
C6A C 0.8774(3) 0.4703(13) 0.5931(8) 0.036(3) Uani 1 1 d . . .
H6A H 0.8982 0.5211 0.5789 0.043 Uiso 1 1 calc R . .
C7A C 0.8745(3) 0.8164(11) 0.5903(9) 0.032(3) Uani 1 1 d . . .
C8A C 0.8774(4) 0.8072(12) 0.6813(9) 0.045(3) Uani 1 1 d . . .
H8A H 0.8629 0.7408 0.7121 0.054 Uiso 1 1 calc R . .
C9A C 0.8999(4) 0.8878(15) 0.7290(12) 0.058(4) Uani 1 1 d . . .
H9A H 0.8999 0.8817 0.7921 0.070 Uiso 1 1 calc R . .
C10A C 0.9219(4) 0.9759(15) 0.6878(11) 0.053(4) Uani 1 1 d . . .
H10A H 0.9387 1.0279 0.7215 0.064 Uiso 1 1 calc R . .
C11A C 0.9206(3) 0.9920(14) 0.5982(11) 0.051(4) Uani 1 1 d . . .
H11A H 0.9361 1.0564 0.5691 0.061 Uiso 1 1 calc R . .
C12A C 0.8962(3) 0.9132(12) 0.5490(9) 0.038(3) Uani 1 1 d . . .
H12A H 0.8946 0.9268 0.4864 0.045 Uiso 1 1 calc R . .
C1B C 0.7532(3) 0.6872(13) 0.3897(10) 0.041(3) Uani 1 1 d . . .
C2B C 0.7296(3) 0.6477(19) 0.4568(12) 0.065(5) Uani 1 1 d . . .
H2B H 0.7337 0.6782 0.5163 0.078 Uiso 1 1 calc R . .
C3B C 0.7007(4) 0.566(2) 0.4381(14) 0.086(7) Uani 1 1 d . . .
H3B H 0.6851 0.5392 0.4844 0.103 Uiso 1 1 calc R . .
C4B C 0.6945(4) 0.5225(19) 0.3526(13) 0.070(5) Uani 1 1 d . . .
H4B H 0.6740 0.4688 0.3396 0.084 Uiso 1 1 calc R . .
C5B C 0.7173(3) 0.5553(15) 0.2852(12) 0.055(4) Uani 1 1 d . . .
H5B H 0.7136 0.5203 0.2265 0.066 Uiso 1 1 calc R . .
C6B C 0.7462(3) 0.6415(13) 0.3051(10) 0.039(3) Uani 1 1 d . . .
H6B H 0.7614 0.6692 0.2582 0.047 Uiso 1 1 calc R . .
C7B C 0.7833(3) 0.9728(13) 0.3809(10) 0.040(3) Uani 1 1 d . . .
C8B C 0.7574(4) 1.0074(16) 0.3181(9) 0.047(4) Uani 1 1 d . . .
H8B H 0.7427 0.9345 0.2943 0.056 Uiso 1 1 calc R . .
C9B C 0.7536(5) 1.150(2) 0.2916(13) 0.073(5) Uani 1 1 d . . .
H9B H 0.7353 1.1732 0.2517 0.088 Uiso 1 1 calc R . .
C10B C 0.7755(5) 1.258(2) 0.3207(15) 0.091(7) Uani 1 1 d . . .
H10B H 0.7740 1.3514 0.2951 0.110 Uiso 1 1 calc R . .
C11B C 0.8001(5) 1.2295(18) 0.3889(16) 0.081(6) Uani 1 1 d . . .
H11B H 0.8134 1.3042 0.4157 0.097 Uiso 1 1 calc R . .
C12B C 0.8038(4) 1.0855(17) 0.4149(12) 0.062(5) Uani 1 1 d . . .
H12B H 0.8211 1.0628 0.4580 0.075 Uiso 1 1 calc R . .
C1C C 0.9873(3) 0.7893(16) 0.2754(9) 0.043(3) Uani 1 1 d . . .
C2C C 1.0069(4) 0.711(2) 0.3377(11) 0.063(4) Uani 1 1 d . . .
H2C H 1.0074 0.6086 0.3333 0.075 Uiso 1 1 calc R . .
C3C C 1.0249(4) 0.776(3) 0.4037(12) 0.083(6) Uani 1 1 d . . .
H3C H 1.0382 0.7198 0.4445 0.100 Uiso 1 1 calc R . .
C4C C 1.0240(4) 0.921(2) 0.4112(12) 0.078(6) Uani 1 1 d . . .
H4C H 1.0365 0.9661 0.4583 0.094 Uiso 1 1 calc R . .
C5C C 1.0057(4) 1.004(2) 0.3535(14) 0.081(6) Uani 1 1 d . . .
H5C H 1.0053 1.1061 0.3596 0.097 Uiso 1 1 calc R . .
C6C C 0.9869(4) 0.9342(18) 0.2831(12) 0.059(4) Uani 1 1 d . . .
H6C H 0.9741 0.9903 0.2414 0.071 Uiso 1 1 calc R . .
C7C C 0.9778(3) 0.5254(13) 0.1743(8) 0.034(3) Uani 1 1 d . . .
C8C C 1.0136(3) 0.5045(16) 0.1600(11) 0.053(4) Uani 1 1 d . . .
H8C H 1.0295 0.5829 0.1625 0.064 Uiso 1 1 calc R . .
C9C C 1.0250(4) 0.3669(18) 0.1422(12) 0.064(5) Uani 1 1 d . . .
H9C H 1.0492 0.3510 0.1327 0.077 Uiso 1 1 calc R . .
C10C C 1.0028(4) 0.2533(16) 0.1378(12) 0.061(5) Uani 1 1 d . . .
H10C H 1.0115 0.1593 0.1259 0.073 Uiso 1 1 calc R . .
C11C C 0.9681(4) 0.2757(17) 0.1507(12) 0.064(5) Uani 1 1 d . . .
H11C H 0.9524 0.1966 0.1471 0.077 Uiso 1 1 calc R . .
C12C C 0.9552(3) 0.4118(13) 0.1689(10) 0.040(3) Uani 1 1 d . . .
H12C H 0.9309 0.4262 0.1776 0.048 Uiso 1 1 calc R . .
C1D C 0.8954(3) 0.7087(12) -0.0117(8) 0.030(2) Uani 1 1 d . . .
C2D C 0.9185(4) 0.6191(14) -0.0609(9) 0.044(3) Uani 1 1 d . . .
H2D H 0.9426 0.6153 -0.0454 0.052 Uiso 1 1 calc R . .
C3D C 0.9062(4) 0.5386(14) -0.1303(10) 0.052(4) Uani 1 1 d . . .
H3D H 0.9222 0.4826 -0.1643 0.062 Uiso 1 1 calc R . .
C4D C 0.8717(4) 0.5366(13) -0.1521(8) 0.044(3) Uani 1 1 d . . .
H4D H 0.8635 0.4766 -0.1989 0.053 Uiso 1 1 calc R . .
C5D C 0.8488(3) 0.6224(14) -0.1055(9) 0.045(3) Uani 1 1 d . . .
H5D H 0.8248 0.6243 -0.1215 0.054 Uiso 1 1 calc R . .
C6D C 0.8606(3) 0.7059(14) -0.0355(8) 0.038(3) Uani 1 1 d . . .
H6D H 0.8443 0.7628 -0.0031 0.046 Uiso 1 1 calc R . .
C7D C 0.8918(3) 1.0459(13) -0.0193(10) 0.044(3) Uani 1 1 d . . .
H7D H 0.8979 0.9877 -0.0689 0.053 Uiso 1 1 calc R . .
C8D C 0.8816(4) 1.1864(14) -0.0335(12) 0.052(4) Uani 1 1 d . . .
H8D H 0.8803 1.2234 -0.0924 0.062 Uiso 1 1 calc R . .
C9D C 0.8732(4) 1.2725(17) 0.0376(14) 0.064(5) Uani 1 1 d . . .
H9D H 0.8667 1.3701 0.0284 0.077 Uiso 1 1 calc R . .
C10D C 0.8744(4) 1.2163(18) 0.1222(13) 0.067(5) Uani 1 1 d . . .
H10D H 0.8680 1.2742 0.1717 0.081 Uiso 1 1 calc R . .
C11D C 0.8850(4) 1.0744(15) 0.1352(10) 0.050(4) Uani 1 1 d . . .
H11D H 0.8864 1.0374 0.1941 0.060 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 Pt1 N1 82.4(4) . . ?
N2 Pt1 P1 166.1(5) . . ?
N1 Pt1 P1 102.8(3) . . ?
N2 Pt1 P2 103.5(3) . . ?
N1 Pt1 P2 173.0(3) . . ?
P1 Pt1 P2 70.55(12) . . ?
N2 Pt1 Pt2 40.4(3) . . ?
N1 Pt1 Pt2 42.1(3) . . ?
P1 Pt1 Pt2 142.48(8) . . ?
P2 Pt1 Pt2 143.52(9) . . ?
N2 Pt2 N1 81.8(5) . . ?
N2 Pt2 P3 168.1(5) . . ?
N1 Pt2 P3 103.8(3) . . ?
N2 Pt2 P4 103.1(4) . . ?
N1 Pt2 P4 172.5(3) . . ?
P3 Pt2 P4 70.37(12) . . ?
N2 Pt2 Pt1 40.3(4) . . ?
N1 Pt2 Pt1 41.5(2) . . ?
P3 Pt2 Pt1 143.59(9) . . ?
P4 Pt2 Pt1 142.64(8) . . ?
C1 P1 C1A 114.6(6) . . ?
C1 P1 C7A 113.2(6) . . ?
C1A P1 C7A 101.5(5) . . ?
C1 P1 Pt1 96.1(5) . . ?
C1A P1 Pt1 116.0(4) . . ?
C7A P1 Pt1 116.2(4) . . ?
C1 P1 P2 41.1(4) . . ?
C1A P1 P2 126.2(4) . . ?
C7A P1 P2 131.1(4) . . ?
Pt1 P1 P2 55.21(11) . . ?
C1 P2 C7B 113.0(7) . . ?
C1 P2 C1B 111.5(7) . . ?
C7B P2 C1B 105.1(6) . . ?
C1 P2 Pt1 95.4(4) . . ?
C7B P2 Pt1 112.4(4) . . ?
C1B P2 Pt1 119.5(4) . . ?
C1 P2 P1 41.3(4) . . ?
C7B P2 P1 127.9(5) . . ?
C1B P2 P1 125.6(4) . . ?
Pt1 P2 P1 54.25(10) . . ?
C2 P3 C1C 114.1(7) . . ?
C2 P3 C7C 112.8(6) . . ?
C1C P3 C7C 104.2(6) . . ?
C2 P3 Pt2 95.7(4) . . ?
C1C P3 Pt2 114.4(4) . . ?
C7C P3 Pt2 116.0(4) . . ?
C2 P3 P4 41.4(4) . . ?
C1C P3 P4 133.9(5) . . ?
C7C P3 P4 120.9(4) . . ?
Pt2 P3 P4 54.94(10) . . ?
C2 P4 C1D 113.8(6) . . ?
C2 P4 C41 114.1(6) . . ?
C1D P4 C41 102.2(6) . . ?
C2 P4 Pt2 94.8(4) . . ?
C1D P4 Pt2 118.5(4) . . ?
C41 P4 Pt2 114.2(5) . . ?
C2 P4 P3 40.8(4) . . ?
C1D P4 P3 123.4(4) . . ?
C41 P4 P3 133.2(4) . . ?
Pt2 P4 P3 54.69(10) . . ?
C3 N1 Pt1 121.4(9) . . ?
C3 N1 Pt2 116.3(9) . . ?
Pt1 N1 Pt2 96.4(4) . . ?
C9 N2 Pt1 120.1(10) . . ?
C9 N2 Pt2 116.4(9) . . ?
Pt1 N2 Pt2 99.3(6) . . ?
P2 C1 P1 97.6(6) . . ?
P3 C2 P4 97.8(6) . . ?
N1 C3 C8 121.2(14) . . ?
N1 C3 C4 120.0(19) . . ?
C8 C3 C4 119(2) . . ?
C5 C4 C3 119(2) . . ?
C6 C5 C4 120.4(17) . . ?
C5 C6 C7 121(2) . . ?
C8 C7 C6 118(2) . . ?
C3 C8 C7 123.5(19) . . ?
C10 C9 C14 127.9(17) . . ?
C10 C9 N2 116.1(14) . . ?
C14 C9 N2 116.0(16) . . ?
C9 C10 C11 116(2) . . ?
C10 C11 C12 127(2) . . ?
C13 C12 C11 119.7(16) . . ?
C12 C13 C14 116.1(15) . . ?
C9 C14 C13 112.9(14) . . ?
C11D C41 C7D 117.8(13) . . ?
C11D C41 P4 120.9(12) . . ?
C7D C41 P4 120.9(10) . . ?
C2A C1A C6A 118.4(11) . . ?
C2A C1A P1 120.1(9) . . ?
C6A C1A P1 121.4(9) . . ?
C3A C2A C1A 120.6(12) . . ?
C2A C3A C4A 121.1(13) . . ?
C5A C4A C3A 118.0(12) . . ?
C6A C5A C4A 121.4(13) . . ?
C5A C6A C1A 120.3(12) . . ?
C12A C7A C8A 116.2(12) . . ?
C12A C7A P1 122.1(10) . . ?
C8A C7A P1 121.6(9) . . ?
C9A C8A C7A 123.1(14) . . ?
C10A C9A C8A 120.1(17) . . ?
C9A C10A C11A 120.4(15) . . ?
C10A C11A C12A 119.5(13) . . ?
C7A C12A C11A 120.5(13) . . ?
C6B C1B C2B 117.3(13) . . ?
C6B C1B P2 123.9(10) . . ?
C2B C1B P2 118.8(12) . . ?
C3B C2B C1B 121.2(17) . . ?
C4B C3B C2B 119.8(16) . . ?
C3B C4B C5B 121.0(15) . . ?
C4B C5B C6B 118.3(17) . . ?
C1B C6B C5B 122.2(13) . . ?
C12B C7B C8B 117.9(12) . . ?
C12B C7B P2 117.7(11) . . ?
C8B C7B P2 124.5(11) . . ?
C9B C8B C7B 118.9(15) . . ?
C10B C9B C8B 122.7(17) . . ?
C9B C10B C11B 119.7(17) . . ?
C12B C11B C10B 116.5(19) . . ?
C11B C12B C7B 123.7(16) . . ?
C6C C1C C2C 117.8(14) . . ?
C6C C1C P3 117.8(11) . . ?
C2C C1C P3 124.2(12) . . ?
C3C C2C C1C 122.1(19) . . ?
C2C C3C C4C 119.5(19) . . ?
C5C C4C C3C 121.8(16) . . ?
C4C C5C C6C 118.1(17) . . ?
C1C C6C C5C 120.7(17) . . ?
C12C C7C C8C 120.2(12) . . ?
C12C C7C P3 118.1(9) . . ?
C8C C7C P3 121.4(10) . . ?
C9C C8C C7C 117.9(13) . . ?
C10C C9C C8C 122.4(13) . . ?
C9C C10C C11C 119.0(14) . . ?
C10C C11C C12C 121.0(15) . . ?
C7C C12C C11C 119.5(12) . . ?
C6D C1D C2D 117.2(12) . . ?
C6D C1D P4 123.2(9) . . ?
C2D C1D P4 119.4(9) . . ?
C3D C2D C1D 120.1(13) . . ?
C4D C3D C2D 121.7(12) . . ?
C3D C4D C5D 119.2(13) . . ?
C4D C5D C6D 120.3(13) . . ?
C1D C6D C5D 121.5(12) . . ?
C8D C7D C41 121.8(14) . . ?
C9D C8D C7D 119.8(16) . . ?
C8D C9D C10D 119.4(14) . . ?
C9D C10D C11D 119.9(15) . . ?
C41 C11D C10D 121.3(15) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 N2 2.104(15) . ?
Pt1 N1 2.142(9) . ?
Pt1 P1 2.232(4) . ?
Pt1 P2 2.258(3) . ?
Pt1 Pt2 3.2102(6) . ?
Pt2 N2 2.108(11) . ?
Pt2 N1 2.166(10) . ?
Pt2 P3 2.250(3) . ?
Pt2 P4 2.257(4) . ?
P1 C1 1.728(10) . ?
P1 C1A 1.816(12) . ?
P1 C7A 1.852(13) . ?
P1 P2 2.593(5) . ?
P2 C1 1.718(13) . ?
P2 C7B 1.796(12) . ?
P2 C1B 1.849(13) . ?
P3 C2 1.712(13) . ?
P3 C1C 1.829(13) . ?
P3 C7C 1.850(12) . ?
P3 P4 2.597(4) . ?
P4 C2 1.734(11) . ?
P4 C1D 1.808(13) . ?
P4 C41 1.836(13) . ?
N1 C3 1.34(2) . ?
N2 C9 1.50(2) . ?
C3 C8 1.35(3) . ?
C3 C4 1.431(19) . ?
C4 C5 1.42(3) . ?
C5 C6 1.36(3) . ?
C6 C7 1.42(3) . ?
C7 C8 1.39(2) . ?
C9 C10 1.28(2) . ?
C9 C14 1.39(2) . ?
C10 C11 1.33(2) . ?
C11 C12 1.35(2) . ?
C12 C13 1.35(2) . ?
C13 C14 1.57(2) . ?
C41 C11D 1.364(18) . ?
C41 C7D 1.38(2) . ?
C1A C2A 1.395(17) . ?
C1A C6A 1.398(15) . ?
C2A C3A 1.370(18) . ?
C3A C4A 1.40(2) . ?
C4A C5A 1.39(2) . ?
C5A C6A 1.373(18) . ?
C7A C12A 1.372(16) . ?
C7A C8A 1.373(18) . ?
C8A C9A 1.35(2) . ?
C9A C10A 1.33(2) . ?
C10A C11A 1.35(2) . ?
C11A C12A 1.398(18) . ?
C1B C6B 1.366(19) . ?
C1B C2B 1.400(18) . ?
C2B C3B 1.37(2) . ?
C3B C4B 1.37(3) . ?
C4B C5B 1.37(2) . ?
C5B C6B 1.396(18) . ?
C7B C12B 1.40(2) . ?
C7B C8B 1.405(19) . ?
C8B C9B 1.39(2) . ?
C9B C10B 1.38(3) . ?
C10B C11B 1.42(3) . ?
C11B C12B 1.40(2) . ?
C1C C6C 1.35(2) . ?
C1C C2C 1.40(2) . ?
C2C C3C 1.35(2) . ?
C3C C4C 1.36(3) . ?
C4C C5C 1.36(3) . ?
C5C C6C 1.43(2) . ?
C7C C12C 1.366(17) . ?
C7C C8C 1.399(15) . ?
C8C C9C 1.38(2) . ?
C9C C10C 1.35(2) . ?
C10C C11C 1.36(2) . ?
C11C C12C 1.384(19) . ?
C1D C6D 1.379(16) . ?
C1D C2D 1.422(16) . ?
C2D C3D 1.366(19) . ?
C3D C4D 1.36(2) . ?
C4D C5D 1.375(18) . ?
C5D C6D 1.381(18) . ?
C7D C8D 1.379(17) . ?
C8D C9D 1.37(2) . ?
C9D C10D 1.37(2) . ?
C10D C11D 1.39(2) . ?
