#------------------------------------------------------------------------------
#$Date: 2016-03-23 15:33:56 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179335 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/32/4323214.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4323214
loop_
_publ_author_name
'K. E. Litz'
'M. M. Banaszak Holl'
'J. W. Kampf'
'G. B. Carpenter'
_publ_section_title
;
 Active Role of a Germylene Ligand in Promoting Reactions of Platinum
 Complexes with Oxygen and Sulfur Dioxide
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6461
_journal_page_last               6469
_journal_paper_doi               10.1021/ic9808044
_journal_volume                  37
_journal_year                    1998
_chemical_formula_sum            'C24 H66 Ge N2 O2 P2 Pt Si4'
_chemical_formula_weight         856.77
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL
_cell_angle_alpha                108.740(10)
_cell_angle_beta                 97.560(10)
_cell_angle_gamma                95.440(10)
_cell_formula_units_Z            4
_cell_length_a                   11.689(2)
_cell_length_b                   18.753(2)
_cell_length_c                   19.160(2)
_cell_measurement_reflns_used    42
_cell_measurement_temperature    148(2)
_cell_measurement_theta_max      12.55
_cell_measurement_theta_min      5.92
_cell_volume                     3900.5(9)
_computing_cell_refinement       'Siemens XSCANS, v2.1'
_computing_data_collection       'Siemens XSCANS, v2.1'
_computing_data_reduction        'Siemens XSCANS, v2.1'
_computing_molecular_graphics    'Siemens SHELXTL PLUS'
_computing_publication_material  'Siemens SHELXTL PLUS'
_computing_structure_refinement  'Siemens SHELXTL PLUS'
_computing_structure_solution    'Siemens SHELXTL PLUS'
_diffrn_ambient_temperature      148(2)
_diffrn_measurement_device       'Siemens P4U 4-circle diffractometer'
_diffrn_measurement_method       'w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0000
_diffrn_reflns_av_sigmaI/netI    0.0562
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            9823
_diffrn_reflns_theta_max         22.50
_diffrn_reflns_theta_min         2.64
_diffrn_standards_decay_%        15
_diffrn_standards_interval_count 97
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    4.580
_exptl_absorpt_correction_T_max  0.636
_exptl_absorpt_correction_T_min  1.341
_exptl_absorpt_correction_type   psi-scans
_exptl_crystal_colour            'pale yellow'
_exptl_crystal_density_diffrn    1.459
_exptl_crystal_description       plate
_exptl_crystal_F_000             1744
_exptl_crystal_size_max          0.42
_exptl_crystal_size_mid          0.32
_exptl_crystal_size_min          0.26
_refine_diff_density_max         5.757
_refine_diff_density_min         -2.521
_refine_diff_density_rms         0.181
_refine_ls_extinction_coef       0.00013(15)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_all   1.085
_refine_ls_goodness_of_fit_obs   1.225
_refine_ls_matrix_type           full
_refine_ls_number_parameters     688
_refine_ls_number_reflns         9814
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.085
_refine_ls_restrained_S_obs      1.225
_refine_ls_R_factor_all          0.0750
_refine_ls_R_factor_obs          0.0550
_refine_ls_shift/esd_max         -0.001
_refine_ls_shift/esd_mean        0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0928P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.1488
_refine_ls_wR_factor_obs         0.1421
_reflns_number_observed          7192
_reflns_number_total             9823
_reflns_observed_criterion       >2sigma(I)
_cod_data_source_file            ic9808044_1.cif
_cod_data_source_block           ptge
_cod_depositor_comments
;
The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.0928P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3' was
changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.0928P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_database_code               4323214
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_group
Pt1 Pt 0.26495(4) 0.48005(2) 0.22078(2) 0.0280(2) Uani 1 d . .
Ge1 Ge 0.37724(10) 0.60204(7) 0.23795(6) 0.0265(3) Uani 1 d . .
P1 P 0.1765(3) 0.3857(2) 0.2581(2) 0.0284(7) Uani 1 d . .
P2 P 0.2219(3) 0.4161(2) 0.0989(2) 0.0351(8) Uani 1 d . .
Si1 Si 0.6095(3) 0.5396(2) 0.2271(2) 0.0383(9) Uani 1 d . .
Si2 Si 0.6012(3) 0.6900(2) 0.3477(2) 0.0373(9) Uani 1 d . .
Si3 Si 0.1937(3) 0.7019(2) 0.2144(2) 0.0365(9) Uani 1 d . .
Si4 Si 0.4068(3) 0.7193(2) 0.1464(2) 0.0398(9) Uani 1 d . .
O1 O 0.2955(7) 0.5506(4) 0.3302(4) 0.040(2) Uani 1 d . .
O2 O 0.3308(7) 0.6298(4) 0.3303(4) 0.038(2) Uani 1 d . .
N1 N 0.5386(7) 0.6162(5) 0.2634(5) 0.025(2) Uani 1 d . .
N2 N 0.3298(8) 0.6771(5) 0.1990(5) 0.031(2) Uani 1 d . .
C1 C 0.0223(10) 0.3830(6) 0.2597(6) 0.032(3) Uani 1 d . .
H1A H -0.0199(10) 0.3683(6) 0.2077(6) 0.055(8) Uiso 1 calc R .
H1B H -0.0037(10) 0.3432(6) 0.2803(6) 0.055(8) Uiso 1 calc R .
C2 C -0.0111(12) 0.4592(7) 0.3065(7) 0.045(3) Uani 1 d . .
H2A H -0.0963(12) 0.4562(17) 0.2991(36) 0.072(4) Uiso 1 calc R .
H2B H 0.0224(61) 0.5002(10) 0.2906(32) 0.072(4) Uiso 1 calc R .
H2C H 0.0192(62) 0.4699(24) 0.3596(9) 0.072(4) Uiso 1 calc R .
C3 C 0.2415(10) 0.4035(6) 0.3539(6) 0.034(3) Uani 1 d . .
H3A H 0.3262(10) 0.4016(6) 0.3557(6) 0.055(8) Uiso 1 calc R .
H3B H 0.2326(10) 0.4560(6) 0.3835(6) 0.055(8) Uiso 1 calc R .
C4 C 0.1947(11) 0.3504(8) 0.3928(7) 0.047(4) Uani 1 d . .
H4A H 0.2319(54) 0.3689(27) 0.4455(13) 0.072(4) Uiso 1 calc R .
H4B H 0.2120(63) 0.2990(13) 0.3685(29) 0.072(4) Uiso 1 calc R .
H4C H 0.1101(15) 0.3491(37) 0.3894(40) 0.072(4) Uiso 1 calc R .
C5 C 0.1882(10) 0.2857(6) 0.2122(7) 0.035(3) Uani 1 d . .
H5A H 0.1396(10) 0.2544(6) 0.2332(7) 0.055(8) Uiso 1 calc R .
H5B H 0.1563(10) 0.2713(6) 0.1583(7) 0.055(8) Uiso 1 calc R .
C6 C 0.3112(11) 0.2676(7) 0.2206(8) 0.048(4) Uani 1 d . .
H6A H 0.3139(18) 0.2170(20) 0.1852(32) 0.072(4) Uiso 1 calc R .
H6B H 0.3361(27) 0.2685(45) 0.2718(15) 0.072(4) Uiso 1 calc R .
H6C H 0.3634(16) 0.3056(27) 0.2102(44) 0.072(4) Uiso 1 calc R .
C7 C 0.3195(17) 0.3442(8) 0.0631(8) 0.076(5) Uani 1 d . .
H7A H 0.3732(17) 0.3648(8) 0.0361(8) 0.055(8) Uiso 1 calc R .
H7B H 0.3676(17) 0.3376(8) 0.1065(8) 0.055(8) Uiso 1 calc R .
C8 C 0.2629(18) 0.2716(11) 0.0149(10) 0.101(7) Uani 1 d . .
H8A H 0.2081(55) 0.2506(23) 0.0403(20) 0.072(4) Uiso 1 calc R .
H8B H 0.3212(19) 0.2375(17) 0.0015(37) 0.072(4) Uiso 1 calc R .
H8C H 0.2203(61) 0.2764(13) -0.0306(23) 0.072(4) Uiso 1 calc R .
C9 C 0.0702(11) 0.3665(8) 0.0655(7) 0.048(4) Uani 1 d . .
H9A H 0.0601(11) 0.3379(8) 0.0112(7) 0.055(8) Uiso 1 calc R .
H9B H 0.0561(11) 0.3292(8) 0.0913(7) 0.055(8) Uiso 1 calc R .
C10 C -0.0183(11) 0.4200(7) 0.0791(7) 0.050(4) Uani 1 d . .
H10A H -0.0954(16) 0.3911(9) 0.0731(45) 0.072(4) Uiso 1 calc R .
H10B H -0.0199(51) 0.4471(34) 0.0430(30) 0.072(4) Uiso 1 calc R .
H10C H 0.0027(40) 0.4568(30) 0.1300(17) 0.072(4) Uiso 1 calc R .
C11 C 0.2324(11) 0.4772(7) 0.0409(6) 0.041(3) Uani 1 d . .
H11A H 0.1871(11) 0.5194(7) 0.0591(6) 0.055(8) Uiso 1 calc R .
H11B H 0.3150(11) 0.4999(7) 0.0484(6) 0.055(8) Uiso 1 calc R .
C12 C 0.1888(12) 0.4372(8) -0.0436(6) 0.051(4) Uani 1 d . .
H12A H 0.1998(68) 0.4739(14) -0.0698(8) 0.072(4) Uiso 1 calc R .
H12B H 0.1058(21) 0.4170(42) -0.0523(7) 0.072(4) Uiso 1 calc R .
H12C H 0.2332(51) 0.3954(31) -0.0627(11) 0.072(4) Uiso 1 calc R .
C13 C 0.5617(11) 0.4975(8) 0.1239(8) 0.057(4) Uani 1 d . .
H13A H 0.4764(12) 0.4914(44) 0.1121(8) 0.072(4) Uiso 1 calc R .
H13B H 0.5878(62) 0.4477(22) 0.1055(10) 0.072(4) Uiso 1 calc R .
H13C H 0.5957(59) 0.5313(24) 0.0999(8) 0.072(4) Uiso 1 calc R .
C14 C 0.7704(10) 0.5661(8) 0.2415(7) 0.047(4) Uani 1 d . .
H14A H 0.8051(13) 0.5221(15) 0.2141(37) 0.072(4) Uiso 1 calc R .
H14B H 0.8025(13) 0.5820(44) 0.2950(8) 0.072(4) Uiso 1 calc R .
H14C H 0.7885(11) 0.6081(31) 0.2229(41) 0.072(4) Uiso 1 calc R .
C15 C 0.5809(13) 0.4632(7) 0.2684(9) 0.062(4) Uani 1 d . .
H15A H 0.6306(52) 0.4771(23) 0.3175(22) 0.072(4) Uiso 1 calc R .
H15B H 0.5984(69) 0.4151(12) 0.2353(24) 0.072(4) Uiso 1 calc R .
H15C H 0.4988(21) 0.4574(32) 0.2740(43) 0.072(4) Uiso 1 calc R .
C16 C 0.5104(11) 0.7667(7) 0.3722(7) 0.046(3) Uani 1 d . .
H16A H 0.5522(32) 0.8087(21) 0.4161(29) 0.072(4) Uiso 1 calc R .
H16B H 0.4370(33) 0.7470(14) 0.3836(45) 0.072(4) Uiso 1 calc R .
H16C H 0.4937(61) 0.7850(33) 0.3300(19) 0.072(4) Uiso 1 calc R .
C17 C 0.7455(12) 0.7404(7) 0.3462(8) 0.052(4) Uani 1 d . .
H17A H 0.7662(34) 0.7866(25) 0.3904(24) 0.072(4) Uiso 1 calc R .
H17B H 0.7412(23) 0.7542(41) 0.3009(23) 0.072(4) Uiso 1 calc R .
H17C H 0.8048(17) 0.7069(18) 0.3466(46) 0.072(4) Uiso 1 calc R .
C18 C 0.6272(14) 0.6512(7) 0.4259(7) 0.055(4) Uani 1 d . .
H18A H 0.6485(73) 0.6934(7) 0.4736(8) 0.072(4) Uiso 1 calc R .
H18B H 0.6907(49) 0.6205(39) 0.4187(26) 0.072(4) Uiso 1 calc R .
H18C H 0.5560(25) 0.6195(39) 0.4265(29) 0.072(4) Uiso 1 calc R .
C19 C 0.1135(12) 0.7229(9) 0.1340(8) 0.061(4) Uani 1 d . .
H19A H 0.0350(28) 0.7327(47) 0.1433(22) 0.072(4) Uiso 1 calc R .
H19B H 0.1076(64) 0.6792(20) 0.0880(11) 0.072(4) Uiso 1 calc R .
H19C H 0.1558(39) 0.7679(29) 0.1283(30) 0.072(4) Uiso 1 calc R .
C20 C 0.2058(13) 0.7877(8) 0.2999(8) 0.061(4) Uani 1 d . .
H20A H 0.1287(18) 0.8036(29) 0.3040(26) 0.072(4) Uiso 1 calc R .
H20B H 0.2596(57) 0.8292(17) 0.2961(22) 0.072(4) Uiso 1 calc R .
H20C H 0.2353(69) 0.7754(16) 0.3443(9) 0.072(4) Uiso 1 calc R .
C21 C 0.0940(11) 0.6261(7) 0.2267(8) 0.048(4) Uani 1 d . .
H21A H 0.0161(20) 0.6412(22) 0.2284(47) 0.072(4) Uiso 1 calc R .
H21B H 0.1233(40) 0.6182(33) 0.2736(24) 0.072(4) Uiso 1 calc R .
H21C H 0.0897(56) 0.5788(14) 0.1847(24) 0.072(4) Uiso 1 calc R .
C22 C 0.4024(15) 0.8241(7) 0.1760(8) 0.070(5) Uani 1 d . .
H22A H 0.3214(17) 0.8332(7) 0.1670(43) 0.072(4) Uiso 1 calc R .
H22B H 0.4487(62) 0.8464(10) 0.1472(35) 0.072(4) Uiso 1 calc R .
H22C H 0.4346(68) 0.8476(10) 0.2294(14) 0.072(4) Uiso 1 calc R .
C23 C 0.5643(12) 0.7112(10) 0.1561(9) 0.078(5) Uani 1 d . .
H23A H 0.6027(18) 0.7401(39) 0.2075(16) 0.072(4) Uiso 1 calc R .
H23B H 0.5992(19) 0.7316(45) 0.1214(35) 0.072(4) Uiso 1 calc R .
H23C H 0.5743(13) 0.6576(11) 0.1445(45) 0.072(4) Uiso 1 calc R .
C24 C 0.3469(13) 0.6759(8) 0.0438(7) 0.058(4) Uani 1 d . .
H24A H 0.3925(46) 0.7003(33) 0.0160(8) 0.072(4) Uiso 1 calc R .
H24B H 0.2653(25) 0.6836(41) 0.0346(9) 0.072(4) Uiso 1 calc R .
H24C H 0.3518(66) 0.6213(12) 0.0271(12) 0.072(4) Uiso 1 calc R .
Pt2 Pt -0.21796(4) 0.19396(3) 0.35647(2) 0.0320(2) Uani 1 d . .
Ge2 Ge -0.16257(11) 0.11580(7) 0.24214(7) 0.0317(3) Uani 1 d . .
P3 P -0.3287(3) 0.1154(2) 0.3950(2) 0.0422(9) Uani 1 d . .
P4 P -0.2300(3) 0.3081(2) 0.4502(2) 0.0341(8) Uani 1 d . .
Si5 Si -0.3802(3) 0.1380(2) 0.1460(2) 0.0386(9) Uani 1 d . .
Si6 Si -0.1653(3) 0.1115(2) 0.0769(2) 0.0362(9) Uani 1 d . .
Si7 Si 0.0596(3) 0.0563(2) 0.2928(2) 0.0462(10) Uani 1 d . .
Si8 Si -0.1342(3) -0.0603(2) 0.1818(2) 0.0462(10) Uani 1 d . .
O3 O -0.0996(7) 0.2536(4) 0.3206(4) 0.039(2) Uani 1 d . .
O4 O -0.0456(7) 0.1965(4) 0.2621(4) 0.036(2) Uani 1 d . .
N3 N -0.2438(8) 0.1077(5) 0.1469(5) 0.030(2) Uani 1 d . .
N4 N -0.0793(8) 0.0341(5) 0.2364(5) 0.036(2) Uani 1 d . .
C25 C -0.2829(11) 0.1252(8) 0.4933(7) 0.051(4) Uani 1 d . .
H25A H -0.2973(11) 0.1753(8) 0.5256(7) 0.055(8) Uiso 1 calc R .
H25B H -0.3306(11) 0.0853(8) 0.5050(7) 0.055(8) Uiso 1 calc R .
C26 C -0.1551(12) 0.1182(8) 0.5104(7) 0.057(4) Uani 1 d . .
H26A H -0.1357(21) 0.1195(46) 0.5622(15) 0.072(4) Uiso 1 calc R .
H26B H -0.1073(13) 0.1605(26) 0.5037(44) 0.072(4) Uiso 1 calc R .
H26C H -0.1396(19) 0.0699(22) 0.4764(30) 0.072(4) Uiso 1 calc R .
C27 C -0.4854(11) 0.1246(9) 0.3907(8) 0.061(4) Uani 1 d . .
H27A H -0.4906(11) 0.1773(9) 0.4219(8) 0.055(8) Uiso 1 calc R .
H27B H -0.5173(11) 0.1191(9) 0.3385(8) 0.055(8) Uiso 1 calc R .
C28 C -0.5654(14) 0.0725(10) 0.4137(9) 0.080(5) Uani 1 d . .
H28A H -0.5865(59) 0.0234(19) 0.3732(20) 0.072(4) Uiso 1 calc R .
H28B H -0.6361(34) 0.0951(24) 0.4245(45) 0.072(4) Uiso 1 calc R .
H28C H -0.5260(29) 0.0649(38) 0.4587(28) 0.072(4) Uiso 1 calc R .
C29 C -0.3218(16) 0.0152(7) 0.3431(8) 0.068(5) Uani 1 d . .
H29A H -0.3744(16) 0.0008(7) 0.2943(8) 0.055(8) Uiso 1 calc R .
H29B H -0.2415(16) 0.0113(7) 0.3327(8) 0.055(8) Uiso 1 calc R .
C30 C -0.3548(18) -0.0449(8) 0.3814(9) 0.088(6) Uani 1 d . .
H30A H -0.2982(44) -0.0352(31) 0.4271(28) 0.072(4) Uiso 1 calc R .
H30B H -0.3537(76) -0.0963(9) 0.3468(21) 0.072(4) Uiso 1 calc R .
H30C H -0.4330(32) -0.0407(33) 0.3940(43) 0.072(4) Uiso 1 calc R .
C31 C -0.1855(13) 0.3819(7) 0.4134(7) 0.050(4) Uani 1 d . .
H31A H -0.1065(13) 0.3762(7) 0.4012(7) 0.055(8) Uiso 1 calc R .
H31B H -0.2390(13) 0.3737(7) 0.3661(7) 0.055(8) Uiso 1 calc R .
C32 C -0.1833(13) 0.4653(7) 0.4661(7) 0.052(4) Uani 1 d . .
H32A H -0.1625(71) 0.5007(7) 0.4402(18) 0.072(4) Uiso 1 calc R .
H32B H -0.1255(52) 0.4758(17) 0.5114(22) 0.072(4) Uiso 1 calc R .
H32C H -0.2605(23) 0.4716(14) 0.4798(37) 0.072(4) Uiso 1 calc R .
C33 C -0.3683(12) 0.3285(8) 0.4762(7) 0.046(3) Uani 1 d . .
H33A H -0.3991(12) 0.2898(8) 0.4968(7) 0.055(8) Uiso 1 calc R .
H33B H -0.3571(12) 0.3788(8) 0.5162(7) 0.055(8) Uiso 1 calc R .
C34 C -0.4585(11) 0.3289(8) 0.4101(7) 0.048(4) Uani 1 d . .
H34A H -0.5328(23) 0.3389(47) 0.4269(13) 0.072(4) Uiso 1 calc R .
H34B H -0.4698(54) 0.2792(17) 0.3702(20) 0.072(4) Uiso 1 calc R .
H34C H -0.4302(34) 0.3687(32) 0.3910(30) 0.072(4) Uiso 1 calc R .
C35 C -0.1361(11) 0.3308(7) 0.5413(6) 0.044(3) Uani 1 d . .
H35A H -0.1501(11) 0.3804(7) 0.5749(6) 0.055(8) Uiso 1 calc R .
H35B H -0.1585(11) 0.2917(7) 0.5636(6) 0.055(8) Uiso 1 calc R .
C36 C -0.0080(11) 0.3344(8) 0.5375(7) 0.053(4) Uani 1 d . .
H36A H 0.0067(15) 0.2856(17) 0.5039(35) 0.072(4) Uiso 1 calc R .
H36B H 0.0366(12) 0.3447(45) 0.5877(10) 0.072(4) Uiso 1 calc R .
H36C H 0.0163(19) 0.3751(30) 0.5186(42) 0.072(4) Uiso 1 calc R .
C37 C -0.4557(12) 0.1230(7) 0.0500(7) 0.051(4) Uani 1 d . .
H37A H -0.5324(31) 0.1398(43) 0.0522(8) 0.072(4) Uiso 1 calc R .
H37B H -0.4655(64) 0.0688(10) 0.0201(15) 0.072(4) Uiso 1 calc R .
H37C H -0.4091(36) 0.1524(37) 0.0269(18) 0.072(4) Uiso 1 calc R .
C38 C -0.4800(12) 0.0818(8) 0.1831(8) 0.058(4) Uani 1 d . .
H38A H -0.5554(26) 0.1007(32) 0.1829(43) 0.072(4) Uiso 1 calc R .
H38B H -0.4461(35) 0.0871(38) 0.2344(18) 0.072(4) Uiso 1 calc R .
H38C H -0.4913(57) 0.0281(11) 0.1515(28) 0.072(4) Uiso 1 calc R .
C39 C -0.3688(12) 0.2419(7) 0.2000(7) 0.051(4) Uani 1 d . .
H39A H -0.4470(13) 0.2567(12) 0.1994(39) 0.072(4) Uiso 1 calc R .
H39B H -0.3220(60) 0.2713(7) 0.1770(28) 0.072(4) Uiso 1 calc R .
H39C H -0.3313(66) 0.2521(10) 0.2517(14) 0.072(4) Uiso 1 calc R .
C40 C -0.1591(12) 0.2072(7) 0.0645(8) 0.054(4) Uani 1 d . .
H40A H -0.1127(61) 0.2083(17) 0.0257(33) 0.072(4) Uiso 1 calc R .
H40B H -0.1230(66) 0.2470(8) 0.1118(15) 0.072(4) Uiso 1 calc R .
H40C H -0.2384(13) 0.2163(21) 0.0495(45) 0.072(4) Uiso 1 calc R .
C41 C -0.2319(13) 0.0351(7) -0.0149(7) 0.054(4) Uani 1 d . .
H41A H -0.1837(41) 0.0364(31) -0.0527(14) 0.072(4) Uiso 1 calc R .
H41B H -0.3107(30) 0.0440(28) -0.0310(24) 0.072(4) Uiso 1 calc R .
H41C H -0.2358(67) -0.0149(8) -0.0085(13) 0.072(4) Uiso 1 calc R .
C42 C -0.0133(10) 0.0983(7) 0.0974(7) 0.043(3) Uani 1 d . .
H42A H 0.0261(21) 0.1004(46) 0.0558(21) 0.072(4) Uiso 1 calc R .
H42B H -0.0102(10) 0.0488(21) 0.1039(45) 0.072(4) Uiso 1 calc R .
H42C H 0.0257(21) 0.1388(27) 0.1434(25) 0.072(4) Uiso 1 calc R .
C43 C 0.1777(13) 0.0887(8) 0.2503(8) 0.063(4) Uani 1 d . .
H43A H 0.2510(19) 0.1027(44) 0.2861(18) 0.072(4) Uiso 1 calc R .
H43B H 0.1589(35) 0.1331(29) 0.2371(42) 0.072(4) Uiso 1 calc R .
H43C H 0.1861(49) 0.0477(17) 0.2052(26) 0.072(4) Uiso 1 calc R .
C44 C 0.0658(12) 0.1337(8) 0.3856(8) 0.060(4) Uani 1 d . .
H44A H 0.1464(17) 0.1476(34) 0.4125(22) 0.072(4) Uiso 1 calc R .
H44B H 0.0159(58) 0.1154(18) 0.4154(20) 0.072(4) Uiso 1 calc R .
H44C H 0.0383(70) 0.1785(19) 0.3770(8) 0.072(4) Uiso 1 calc R .
C45 C 0.1045(16) -0.0261(9) 0.3170(11) 0.098(7) Uani 1 d . .
H45A H 0.0460(41) -0.0444(31) 0.3419(42) 0.072(4) Uiso 1 calc R .
H45B H 0.1801(39) -0.0105(16) 0.3506(40) 0.072(4) Uiso 1 calc R .
H45C H 0.1113(72) -0.0670(21) 0.2712(12) 0.072(4) Uiso 1 calc R .
C46 C -0.0422(15) -0.1023(9) 0.1109(9) 0.077(5) Uani 1 d . .
H46A H -0.0467(58) -0.0768(33) 0.0735(27) 0.072(4) Uiso 1 calc R .
H46B H -0.0706(47) -0.1567(13) 0.0863(34) 0.072(4) Uiso 1 calc R .
H46C H 0.0389(20) -0.0954(42) 0.1357(11) 0.072(4) Uiso 1 calc R .
C47 C -0.1487(14) -0.1272(7) 0.2352(8) 0.064(4) Uani 1 d . .
H47A H -0.0720(18) -0.1407(37) 0.2488(40) 0.072(4) Uiso 1 calc R .
H47B H -0.2020(57) -0.1733(21) 0.2042(19) 0.072(4) Uiso 1 calc R .
H47C H -0.1797(68) -0.1026(19) 0.2807(25) 0.072(4) Uiso 1 calc R .
C48 C -0.2866(12) -0.0705(7) 0.1313(8) 0.057(4) Uani 1 d . .
H48A H -0.3145(29) -0.1242(9) 0.1024(37) 0.072(4) Uiso 1 calc R .
H48B H -0.2874(17) -0.0410(38) 0.0973(34) 0.072(4) Uiso 1 calc R .
H48C H -0.3378(18) -0.0515(43) 0.1676(8) 0.072(4) Uiso 1 calc R .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Pt1 P2 172.5(2) . . ?
O1 Pt1 P1 88.5(2) . . ?
P2 Pt1 P1 96.17(11) . . ?
O1 Pt1 Ge1 67.8(2) . . ?
P2 Pt1 Ge1 107.79(9) . . ?
P1 Pt1 Ge1 156.00(8) . . ?
O2 Ge1 N1 102.4(4) . . ?
O2 Ge1 N2 103.1(4) . . ?
N1 Ge1 N2 110.2(4) . . ?
O2 Ge1 Pt1 83.3(2) . . ?
N1 Ge1 Pt1 119.9(3) . . ?
N2 Ge1 Pt1 126.8(3) . . ?
C3 P1 C1 104.5(5) . . ?
C3 P1 C5 103.2(6) . . ?
C1 P1 C5 102.3(5) . . ?
C3 P1 Pt1 107.3(4) . . ?
C1 P1 Pt1 116.6(4) . . ?
C5 P1 Pt1 121.1(4) . . ?
C11 P2 C9 102.1(6) . . ?
C11 P2 C7 103.5(6) . . ?
C9 P2 C7 106.9(7) . . ?
C11 P2 Pt1 113.4(4) . . ?
C9 P2 Pt1 114.8(4) . . ?
C7 P2 Pt1 114.8(5) . . ?
N1 Si1 C14 112.9(5) . . ?
N1 Si1 C13 110.2(5) . . ?
C14 Si1 C13 105.5(6) . . ?
N1 Si1 C15 112.4(5) . . ?
C14 Si1 C15 107.3(7) . . ?
C13 Si1 C15 108.2(7) . . ?
N1 Si2 C16 112.3(5) . . ?
N1 Si2 C17 114.8(5) . . ?
C16 Si2 C17 103.8(6) . . ?
N1 Si2 C18 110.4(5) . . ?
C16 Si2 C18 109.8(6) . . ?
C17 Si2 C18 105.4(7) . . ?
N2 Si3 C21 113.9(5) . . ?
N2 Si3 C19 112.2(6) . . ?
C21 Si3 C19 104.4(7) . . ?
N2 Si3 C20 111.4(6) . . ?
C21 Si3 C20 106.8(7) . . ?
C19 Si3 C20 107.7(6) . . ?
N2 Si4 C23 114.6(6) . . ?
N2 Si4 C22 111.3(6) . . ?
C23 Si4 C22 104.4(8) . . ?
N2 Si4 C24 111.5(5) . . ?
C23 Si4 C24 105.9(8) . . ?
C22 Si4 C24 108.7(7) . . ?
O2 O1 Pt1 107.0(5) . . ?
O1 O2 Ge1 96.9(5) . . ?
Si1 N1 Si2 121.0(5) . . ?
Si1 N1 Ge1 117.6(5) . . ?
Si2 N1 Ge1 116.6(5) . . ?
Si3 N2 Si4 118.6(5) . . ?
Si3 N2 Ge1 115.2(5) . . ?
Si4 N2 Ge1 126.1(5) . . ?
C2 C1 P1 113.7(8) . . ?
C4 C3 P1 117.6(8) . . ?
C6 C5 P1 113.9(8) . . ?
C8 C7 P2 115.9(15) . . ?
C10 C9 P2 112.7(9) . . ?
C12 C11 P2 115.5(9) . . ?
O3 Pt2 P3 171.1(2) . . ?
O3 Pt2 P4 87.7(2) . . ?
P3 Pt2 P4 98.18(12) . . ?
O3 Pt2 Ge2 68.4(2) . . ?
P3 Pt2 Ge2 106.22(9) . . ?
P4 Pt2 Ge2 155.49(9) . . ?
O4 Ge2 N4 102.7(4) . . ?
O4 Ge2 N3 103.0(4) . . ?
N4 Ge2 N3 111.4(4) . . ?
O4 Ge2 Pt2 84.0(2) . . ?
N4 Ge2 Pt2 123.6(3) . . ?
N3 Ge2 Pt2 121.5(3) . . ?
C25 P3 C29 104.4(7) . . ?
C25 P3 C27 102.2(6) . . ?
C29 P3 C27 106.2(8) . . ?
C25 P3 Pt2 113.7(5) . . ?
C29 P3 Pt2 111.6(5) . . ?
C27 P3 Pt2 117.5(5) . . ?
C33 P4 C31 104.1(6) . . ?
C33 P4 C35 102.2(6) . . ?
C31 P4 C35 106.4(6) . . ?
C33 P4 Pt2 120.1(4) . . ?
C31 P4 Pt2 104.9(4) . . ?
C35 P4 Pt2 117.8(4) . . ?
N3 Si5 C37 112.4(6) . . ?
N3 Si5 C38 111.1(6) . . ?
C37 Si5 C38 104.4(6) . . ?
N3 Si5 C39 111.7(5) . . ?
C37 Si5 C39 106.8(6) . . ?
C38 Si5 C39 110.1(7) . . ?
N3 Si6 C42 113.2(5) . . ?
N3 Si6 C40 111.1(6) . . ?
C42 Si6 C40 105.2(6) . . ?
N3 Si6 C41 110.9(5) . . ?
C42 Si6 C41 106.9(6) . . ?
C40 Si6 C41 109.2(6) . . ?
N4 Si7 C43 114.4(6) . . ?
N4 Si7 C45 112.2(6) . . ?
C43 Si7 C45 106.0(8) . . ?
N4 Si7 C44 112.8(6) . . ?
C43 Si7 C44 105.7(7) . . ?
C45 Si7 C44 105.0(8) . . ?
N4 Si8 C46 112.6(6) . . ?
N4 Si8 C47 115.0(6) . . ?
C46 Si8 C47 105.6(7) . . ?
N4 Si8 C48 112.2(5) . . ?
C46 Si8 C48 107.9(7) . . ?
C47 Si8 C48 102.8(7) . . ?
O4 O3 Pt2 107.8(5) . . ?
O3 O4 Ge2 95.9(5) . . ?
Si6 N3 Si5 119.1(5) . . ?
Si6 N3 Ge2 119.3(5) . . ?
Si5 N3 Ge2 115.7(5) . . ?
Si8 N4 Si7 120.0(5) . . ?
Si8 N4 Ge2 123.7(6) . . ?
Si7 N4 Ge2 116.2(5) . . ?
C26 C25 P3 112.0(10) . . ?
C28 C27 P3 120.4(12) . . ?
C30 C29 P3 117.2(10) . . ?
C32 C31 P4 115.7(9) . . ?
C34 C33 P4 112.7(9) . . ?
C36 C35 P4 113.8(9) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 O1 2.050(8) . ?
Pt1 P2 2.219(3) . ?
Pt1 P1 2.318(3) . ?
Pt1 Ge1 2.4286(13) . ?
Ge1 O2 1.847(8) . ?
Ge1 N1 1.857(8) . ?
Ge1 N2 1.888(8) . ?
P1 C3 1.802(11) . ?
P1 C1 1.803(12) . ?
P1 C5 1.824(11) . ?
P2 C11 1.841(11) . ?
P2 C9 1.851(13) . ?
P2 C7 1.87(2) . ?
Si1 N1 1.723(9) . ?
Si1 C14 1.861(13) . ?
Si1 C13 1.862(13) . ?
Si1 C15 1.868(13) . ?
Si2 N1 1.766(9) . ?
Si2 C16 1.845(12) . ?
Si2 C17 1.861(13) . ?
Si2 C18 1.869(12) . ?
Si3 N2 1.735(10) . ?
Si3 C21 1.844(12) . ?
Si3 C19 1.869(13) . ?
Si3 C20 1.869(14) . ?
Si4 N2 1.751(10) . ?
Si4 C23 1.851(15) . ?
Si4 C22 1.870(13) . ?
Si4 C24 1.877(12) . ?
O1 O2 1.503(11) . ?
C1 C2 1.54(2) . ?
C3 C4 1.53(2) . ?
C5 C6 1.51(2) . ?
C7 C8 1.42(2) . ?
C9 C10 1.50(2) . ?
C11 C12 1.54(2) . ?
Pt2 O3 2.022(8) . ?
Pt2 P3 2.232(3) . ?
Pt2 P4 2.341(3) . ?
Pt2 Ge2 2.4200(13) . ?
Ge2 O4 1.845(7) . ?
Ge2 N4 1.873(9) . ?
Ge2 N3 1.896(9) . ?
P3 C25 1.834(13) . ?
P3 C29 1.836(14) . ?
P3 C27 1.851(14) . ?
P4 C33 1.793(13) . ?
P4 C31 1.807(13) . ?
P4 C35 1.834(12) . ?
Si5 N3 1.742(10) . ?
Si5 C37 1.853(12) . ?
Si5 C38 1.855(14) . ?
Si5 C39 1.872(12) . ?
Si6 N3 1.737(9) . ?
Si6 C42 1.826(13) . ?
Si6 C40 1.882(13) . ?
Si6 C41 1.887(12) . ?
Si7 N4 1.760(10) . ?
Si7 C43 1.843(15) . ?
Si7 C45 1.850(15) . ?
Si7 C44 1.887(14) . ?
Si8 N4 1.750(10) . ?
Si8 C46 1.865(15) . ?
Si8 C47 1.865(13) . ?
Si8 C48 1.874(14) . ?
O3 O4 1.532(10) . ?
C25 C26 1.51(2) . ?
C27 C28 1.49(2) . ?
C29 C30 1.58(2) . ?
C31 C32 1.56(2) . ?
C33 C34 1.54(2) . ?
C35 C36 1.51(2) . ?
