#------------------------------------------------------------------------------
#$Date: 2016-03-23 20:16:41 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179405 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/02/4330271.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4330271
loop_
_publ_author_name
'Stanislav S. Stoyko'
'Mansura Khatun'
'Arthur Mar'
_publ_contact_author_address
; Department of Chemistry
  University of Alberta
  Edmonton, AB
  Canada  T6G 2G2
;
_publ_contact_author_email       arthur.mar@ualberta.ca
_publ_contact_author_fax         '(780) 492-8231'
_publ_contact_author_name        'Dr. Arthur Mar'
_publ_contact_author_phone       '(780) 492-5592'
_publ_section_title
;
 Ternary Arsenides A2Zn5As4(A = K, Rb): Zintl Phases Built fromStellae
 Quadrangulae
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              9517
_journal_page_last               9521
_journal_paper_doi               10.1021/ic301311m
_journal_volume                  51
_journal_year                    2012
_chemical_formula_structural     'K2 Zn5 As4'
_chemical_formula_sum            'As4 K2 Zn5'
_chemical_formula_weight         704.73
_chemical_name_common            'potassium zinc arsenide (2/5/4)'
_chemical_name_systematic        'potassium zinc arsenide (2/5/4)'
_space_group_IT_number           63
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-C 2c 2'
_symmetry_space_group_name_H-M   'C m c m'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.5758(5)
_cell_length_b                   7.0476(3)
_cell_length_c                   11.6352(5)
_cell_measurement_reflns_used    8648
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      33.11
_cell_measurement_theta_min      3.38
_cell_volume                     949.22(7)
_computing_cell_refinement       'Bruker SAINT 7.68A (Bruker, 2009)'
_computing_data_collection       'Bruker SMART 5.054 (Bruker, 1999)'
_computing_data_reduction        'Bruker SAINT 7.68A'
_computing_molecular_graphics    'ATOMS 5.1 (Dowty, 1999)'
_computing_publication_material  'Bruker SHELXTL 6.12'
_computing_structure_refinement  'Bruker SHELXTL 6.12'
_computing_structure_solution    'Bruker SHELXTL 6.12'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'Bruker D8/SMART APEX II CCD'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0177
_diffrn_reflns_av_sigmaI/netI    0.0114
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            6481
_diffrn_reflns_theta_full        33.16
_diffrn_reflns_theta_max         33.16
_diffrn_reflns_theta_min         3.38
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    27.088
_exptl_absorpt_correction_T_max  0.2645
_exptl_absorpt_correction_T_min  0.0315
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'Bruker SHELXTL 6.12 (Sheldrick, 2001)'
_exptl_crystal_colour            grey
_exptl_crystal_density_diffrn    4.931
_exptl_crystal_description       prism
_exptl_crystal_F_000             1280
_exptl_crystal_size_max          0.21
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.07
_refine_diff_density_max         0.767
_refine_diff_density_min         -0.609
_refine_diff_density_rms         0.147
_refine_ls_extinction_coef       0.00304(9)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.280
_refine_ls_matrix_type           full
_refine_ls_number_parameters     35
_refine_ls_number_reflns         981
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.280
_refine_ls_R_factor_all          0.0146
_refine_ls_R_factor_gt           0.0138
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0138P)²+0.8459P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0314
_refine_ls_wR_factor_ref         0.0317
_reflns_number_gt                948
_reflns_number_total             981
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            ic301311m_si_002_2.cif
_cod_data_source_block           K2Zn5As4
_cod_database_code               4330271
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z+1/2'
'-x, y, -z+1/2'
'x, -y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, -y+1/2, z+1/2'
'-x+1/2, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
'-x, -y, -z'
'x, y, -z-1/2'
'x, -y, z-1/2'
'-x, y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, y+1/2, -z-1/2'
'x+1/2, -y+1/2, z-1/2'
'-x+1/2, y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
K K 0.21456(4) 0.0000 0.0000 0.01331(9) Uani 1 2 d S
Zn1 Zn 0.14314(2) 0.38609(4) 0.2500 0.00968(6) Uani 1 2 d S
Zn2 Zn 0.0000 0.65236(4) 0.10852(2) 0.01013(6) Uani 1 2 d S
Zn3 Zn 0.0000 0.00784(5) 0.2500 0.01072(8) Uani 1 4 d S
As1 As 0.341532(17) 0.25779(3) 0.2500 0.00756(6) Uani 1 2 d S
As2 As 0.0000 0.27484(3) 0.097688(17) 0.00759(6) Uani 1 2 d S
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
As As 0.0499 2.0058 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
As2 K As2 84.240(12) 9 .
As2 K As1 81.940(8) 9 13
As2 K As1 81.938(8) . 13
As2 K As1 81.938(8) 9 7_545
As2 K As1 81.940(8) . 7_545
As1 K As1 158.205(17) 13 7_545
As2 K Zn1 120.500(7) 9 7_545
As2 K Zn1 101.729(6) . 7_545
As1 K Zn1 157.400(13) 13 7_545
As1 K Zn1 42.094(5) 7_545 7_545
As2 K Zn1 101.729(6) 9 13
As2 K Zn1 120.499(7) . 13
As1 K Zn1 42.094(5) 13 13
As1 K Zn1 157.400(13) 7_545 13
Zn1 K Zn1 122.741(16) 7_545 13
As2 K K 137.019(17) 9 13
As2 K K 66.723(10) . 13
As1 K K 63.821(4) 13 13
As1 K K 121.798(3) 7_545 13
Zn1 K K 96.821(11) 7_545 13
Zn1 K K 70.361(8) 13 13
As2 K K 66.723(10) 9 13_545
As2 K K 137.019(17) . 13_545
As1 K K 121.798(3) 13 13_545
As1 K K 63.821(4) 7_545 13_545
Zn1 K K 70.361(8) 7_545 13_545
Zn1 K K 96.821(11) 13 13_545
K K K 153.79(3) 13 13_545
As2 K Zn2 161.256(8) 9 5_545
As2 K Zn2 112.274(6) . 5_545
As1 K Zn2 108.294(9) 13 5_545
As1 K Zn2 91.380(8) 7_545 5_545
Zn1 K Zn2 49.500(7) 7_545 5_545
Zn1 K Zn2 78.046(10) 13 5_545
K K Zn2 60.948(12) 13 5_545
K K Zn2 94.601(16) 13_545 5_545
As2 K Zn2 112.274(6) 9 13
As2 K Zn2 161.256(8) . 13
As1 K Zn2 91.380(8) 13 13
As1 K Zn2 108.294(9) 7_545 13
Zn1 K Zn2 78.046(10) 7_545 13
Zn1 K Zn2 49.500(7) 13 13
K K Zn2 94.601(16) 13 13
K K Zn2 60.948(12) 13_545 13
Zn2 K Zn2 53.279(10) 5_545 13
As2 K Zn2 40.270(6) 9 1_545
As2 K Zn2 76.698(10) . 1_545
As1 K Zn2 119.330(12) 13 1_545
As1 K Zn2 42.016(5) 7_545 1_545
Zn1 K Zn2 83.028(6) 7_545 1_545
Zn1 K Zn2 139.719(7) 13 1_545
K K Zn2 142.651(16) 13 1_545
K K Zn2 60.571(10) 13_545 1_545
Zn2 K Zn2 132.372(8) 5_545 1_545
Zn2 K Zn2 121.519(4) 13 1_545
As2 K Zn2 76.698(10) 9 9_565
As2 K Zn2 40.270(6) . 9_565
As1 K Zn2 42.016(5) 13 9_565
As1 K Zn2 119.330(12) 7_545 9_565
Zn1 K Zn2 139.719(7) 7_545 9_565
Zn1 K Zn2 83.028(6) 13 9_565
K K Zn2 60.571(9) 13 9_565
K K Zn2 142.651(16) 13_545 9_565
Zn2 K Zn2 121.519(4) 5_545 9_565
Zn2 K Zn2 132.372(8) 13 9_565
Zn2 K Zn2 95.954(12) 1_545 9_565
As1 Zn1 As2 119.473(8) . .
As1 Zn1 As2 119.473(8) . 10_556
As2 Zn1 As2 88.064(11) . 10_556
As1 Zn1 As1 107.615(10) . 7
As2 Zn1 As1 110.533(9) . 7
As2 Zn1 As1 110.533(9) 10_556 7
As1 Zn1 Zn2 138.076(7) . 10_556
As2 Zn1 Zn2 102.422(9) . 10_556
As2 Zn1 Zn2 56.724(7) 10_556 10_556
As1 Zn1 Zn2 54.019(7) 7 10_556
As1 Zn1 Zn2 138.076(7) . .
As2 Zn1 Zn2 56.724(7) . .
As2 Zn1 Zn2 102.422(9) 10_556 .
As1 Zn1 Zn2 54.019(7) 7 .
Zn2 Zn1 Zn2 66.657(10) 10_556 .
As1 Zn1 Zn3 100.373(10) . .
As2 Zn1 Zn3 52.826(7) . .
As2 Zn1 Zn3 52.826(7) 10_556 .
As1 Zn1 Zn3 152.012(11) 7 .
Zn2 Zn1 Zn3 103.887(8) 10_556 .
Zn2 Zn1 Zn3 103.887(8) . .
As1 Zn1 K 68.882(8) . 6
As2 Zn1 K 166.236(10) . 6
As2 Zn1 K 78.176(8) 10_556 6
As1 Zn1 K 74.611(5) 7 6
Zn2 Zn1 K 69.747(8) 10_556 6
Zn2 Zn1 K 125.705(9) . 6
Zn3 Zn1 K 116.825(5) . 6
As1 Zn1 K 68.882(8) . 13
As2 Zn1 K 78.176(8) . 13
As2 Zn1 K 166.236(10) 10_556 13
As1 Zn1 K 74.611(5) 7 13
Zn2 Zn1 K 125.705(9) 10_556 13
Zn2 Zn1 K 69.747(8) . 13
Zn3 Zn1 K 116.825(5) . 13
K Zn1 K 115.580(14) 6 13
As1 Zn1 K 64.268(8) . .
As2 Zn1 K 55.207(8) . .
As2 Zn1 K 115.049(10) 10_556 .
As1 Zn1 K 130.815(4) 7 .
Zn2 Zn1 K 157.550(9) 10_556 .
Zn2 Zn1 K 97.959(7) . .
Zn3 Zn1 K 62.562(6) . .
K Zn1 K 131.591(7) 6 .
K Zn1 K 56.894(4) 13 .
As1 Zn1 K 64.268(8) . 10_556
As2 Zn1 K 115.049(10) . 10_556
As2 Zn1 K 55.207(8) 10_556 10_556
As1 Zn1 K 130.815(4) 7 10_556
Zn2 Zn1 K 97.959(7) 10_556 10_556
Zn2 Zn1 K 157.550(9) . 10_556
Zn3 Zn1 K 62.562(6) . 10_556
K Zn1 K 56.894(5) 6 10_556
K Zn1 K 131.591(7) 13 10_556
K Zn1 K 91.294(7) . 10_556
As2 Zn2 As1 124.400(8) 9_565 7
As2 Zn2 As1 124.400(8) 9_565 5_455
As1 Zn2 As1 90.890(11) 7 5_455
As2 Zn2 As2 99.361(10) 9_565 .
As1 Zn2 As2 108.576(9) 7 .
As1 Zn2 As2 108.576(9) 5_455 .
As2 Zn2 Zn1 131.934(8) 9_565 3
As1 Zn2 Zn1 102.915(9) 7 3
As1 Zn2 Zn1 55.623(7) 5_455 3
As2 Zn2 Zn1 53.156(7) . 3
As2 Zn2 Zn1 131.934(8) 9_565 .
As1 Zn2 Zn1 55.623(7) 7 .
As1 Zn2 Zn1 102.915(9) 5_455 .
As2 Zn2 Zn1 53.156(7) . .
Zn1 Zn2 Zn1 67.149(10) 3 .
As2 Zn2 Zn3 111.237(11) 9_565 1_565
As1 Zn2 Zn3 53.674(6) 7 1_565
As1 Zn2 Zn3 53.674(6) 5_455 1_565
As2 Zn2 Zn3 149.403(11) . 1_565
Zn1 Zn2 Zn3 102.810(8) 3 1_565
Zn1 Zn2 Zn3 102.810(8) . 1_565
As2 Zn2 K 74.142(5) 9_565 5_455
As1 Zn2 K 159.917(8) 7 5_455
As1 Zn2 K 70.447(6) 5_455 5_455
As2 Zn2 K 72.163(5) . 5_455
Zn1 Zn2 K 60.753(4) 3 5_455
Zn1 Zn2 K 120.004(9) . 5_455
Zn3 Zn2 K 115.488(5) 1_565 5_455
As2 Zn2 K 74.142(5) 9_565 13
As1 Zn2 K 70.447(6) 7 13
As1 Zn2 K 159.917(8) 5_455 13
As2 Zn2 K 72.163(5) . 13
Zn1 Zn2 K 120.004(9) 3 13
Zn1 Zn2 K 60.753(4) . 13
Zn3 Zn2 K 115.488(5) 1_565 13
K Zn2 K 126.721(10) 5_455 13
As2 Zn2 K 61.908(6) 9_565 1_565
As1 Zn2 K 63.256(6) 7 1_565
As1 Zn2 K 120.267(10) 5_455 1_565
As2 Zn2 K 130.054(7) . 1_565
Zn1 Zn2 K 166.114(8) 3 1_565
Zn1 Zn2 K 103.318(8) . 1_565
Zn3 Zn2 K 68.593(6) 1_565 1_565
K Zn2 K 132.372(8) 5_455 1_565
K Zn2 K 58.481(4) 13 1_565
As2 Zn2 K 61.908(6) 9_565 9_565
As1 Zn2 K 120.267(10) 7 9_565
As1 Zn2 K 63.256(6) 5_455 9_565
As2 Zn2 K 130.054(7) . 9_565
Zn1 Zn2 K 103.318(8) 3 9_565
Zn1 Zn2 K 166.114(8) . 9_565
Zn3 Zn2 K 68.593(6) 1_565 9_565
K Zn2 K 58.481(4) 5_455 9_565
K Zn2 K 132.372(8) 13 9_565
K Zn2 K 84.046(12) 1_565 9_565
As1 Zn3 As1 92.298(15) 5_445 7_545
As1 Zn3 As2 120.287(4) 5_445 10_556
As1 Zn3 As2 120.287(4) 7_545 10_556
As1 Zn3 As2 120.287(4) 5_445 .
As1 Zn3 As2 120.287(4) 7_545 .
As2 Zn3 As2 86.567(14) 10_556 .
As1 Zn3 Zn2 54.621(7) 5_445 1_545
As1 Zn3 Zn2 54.621(7) 7_545 1_545
As2 Zn3 Zn2 170.025(11) 10_556 1_545
As2 Zn3 Zn2 103.408(7) . 1_545
As1 Zn3 Zn2 54.621(7) 5_445 10_546
As1 Zn3 Zn2 54.621(7) 7_545 10_546
As2 Zn3 Zn2 103.408(7) 10_556 10_546
As2 Zn3 Zn2 170.025(11) . 10_546
Zn2 Zn3 Zn2 66.617(12) 1_545 10_546
As1 Zn3 Zn1 165.714(11) 5_445 .
As1 Zn3 Zn1 101.988(7) 7_545 .
As2 Zn3 Zn1 51.810(7) 10_556 .
As2 Zn3 Zn1 51.810(7) . .
Zn2 Zn3 Zn1 135.218(4) 1_545 .
Zn2 Zn3 Zn1 135.218(4) 10_546 .
As1 Zn3 Zn1 101.988(7) 5_445 3
As1 Zn3 Zn1 165.714(11) 7_545 3
As2 Zn3 Zn1 51.810(7) 10_556 3
As2 Zn3 Zn1 51.810(7) . 3
Zn2 Zn3 Zn1 135.218(5) 1_545 3
Zn2 Zn3 Zn1 135.218(5) 10_546 3
Zn1 Zn3 Zn1 63.727(11) . 3
As1 Zn3 K 61.430(4) 5_445 9
As1 Zn3 K 117.273(8) 7_545 9
As2 Zn3 K 122.131(9) 10_556 9
As2 Zn3 K 59.281(5) . 9
Zn2 Zn3 K 64.555(5) 1_545 9
Zn2 Zn3 K 113.923(8) 10_546 9
Zn1 Zn3 K 110.795(8) . 9
Zn1 Zn3 K 70.702(5) 3 9
As1 Zn3 K 117.273(8) 5_445 10_556
As1 Zn3 K 61.430(4) 7_545 10_556
As2 Zn3 K 59.281(5) 10_556 10_556
As2 Zn3 K 122.131(9) . 10_556
Zn2 Zn3 K 113.923(9) 1_545 10_556
Zn2 Zn3 K 64.555(5) 10_546 10_556
Zn1 Zn3 K 70.702(5) . 10_556
Zn1 Zn3 K 110.795(8) 3 10_556
K Zn3 K 178.345(10) 9 10_556
As1 Zn3 K 61.430(4) 5_445 2
As1 Zn3 K 117.273(8) 7_545 2
As2 Zn3 K 59.281(5) 10_556 2
As2 Zn3 K 122.131(9) . 2
Zn2 Zn3 K 113.923(8) 1_545 2
Zn2 Zn3 K 64.555(5) 10_546 2
Zn1 Zn3 K 110.795(8) . 2
Zn1 Zn3 K 70.702(5) 3 2
K Zn3 K 99.000(11) 9 2
K Zn3 K 80.975(11) 10_556 2
As1 Zn3 K 117.273(8) 5_445 .
As1 Zn3 K 61.430(4) 7_545 .
As2 Zn3 K 122.131(9) 10_556 .
As2 Zn3 K 59.281(5) . .
Zn2 Zn3 K 64.555(5) 1_545 .
Zn2 Zn3 K 113.923(8) 10_546 .
Zn1 Zn3 K 70.702(5) . .
Zn1 Zn3 K 110.795(8) 3 .
K Zn3 K 80.976(11) 9 .
K Zn3 K 99.000(11) 10_556 .
K Zn3 K 178.345(10) 2 .
Zn1 As1 Zn3 114.659(11) . 5
Zn1 As1 Zn2 140.244(5) . 14_546
Zn3 As1 Zn2 71.705(8) 5 14_546
Zn1 As1 Zn2 140.244(5) . 5_545
Zn3 As1 Zn2 71.705(8) 5 5_545
Zn2 As1 Zn2 79.505(11) 14_546 5_545
Zn1 As1 Zn1 115.366(10) . 7_545
Zn3 As1 Zn1 129.975(11) 5 7_545
Zn2 As1 Zn1 70.358(8) 14_546 7_545
Zn2 As1 Zn1 70.358(8) 5_545 7_545
Zn1 As1 K 69.024(8) . 6
Zn3 As1 K 77.996(8) 5 6
Zn2 As1 K 74.728(8) 14_546 6
Zn2 As1 K 145.059(11) 5_545 6
Zn1 As1 K 120.573(3) 7_545 6
Zn1 As1 K 69.023(8) . 13
Zn3 As1 K 77.996(8) 5 13
Zn2 As1 K 145.059(11) 14_546 13
Zn2 As1 K 74.728(8) 5_545 13
Zn1 As1 K 120.573(3) 7_545 13
K As1 K 115.753(8) 6 13
Zn1 As1 K 79.155(8) . .
Zn3 As1 K 128.418(5) 5 .
Zn2 As1 K 129.693(10) 14_546 .
Zn2 As1 K 69.000(8) 5_545 .
Zn1 As1 K 62.666(5) 7_545 .
K As1 K 145.869(6) 6 .
K As1 K 60.481(4) 13 .
Zn1 As1 K 79.155(8) . 10_556
Zn3 As1 K 128.418(5) 5 10_556
Zn2 As1 K 69.000(8) 14_546 10_556
Zn2 As1 K 129.693(10) 5_545 10_556
Zn1 As1 K 62.666(5) 7_545 10_556
K As1 K 60.481(4) 6 10_556
K As1 K 145.869(6) 13 10_556
K As1 K 102.444(9) . 10_556
Zn2 As2 Zn1 127.979(8) 9_565 .
Zn2 As2 Zn1 127.979(8) 9_565 3
Zn1 As2 Zn1 81.062(11) . 3
Zn2 As2 Zn3 145.355(12) 9_565 .
Zn1 As2 Zn3 75.364(8) . .
Zn1 As2 Zn3 75.364(8) 3 .
Zn2 As2 Zn2 80.639(10) 9_565 .
Zn1 As2 Zn2 70.120(8) . .
Zn1 As2 Zn2 70.120(8) 3 .
Zn3 As2 Zn2 134.006(11) . .
Zn2 As2 K 77.821(6) 9_565 9
Zn1 As2 K 153.617(9) . 9
Zn1 As2 K 86.089(8) 3 9
Zn3 As2 K 79.142(6) . 9
Zn2 As2 K 126.431(6) . 9
Zn2 As2 K 77.821(6) 9_565 .
Zn1 As2 K 86.089(8) . .
Zn1 As2 K 153.617(9) 3 .
Zn3 As2 K 79.142(6) . .
Zn2 As2 K 126.431(6) . .
K As2 K 95.760(12) 9 .
Zn2 As2 K 67.907(5) 9_565 13
Zn1 As2 K 61.261(5) . 13
Zn1 As2 K 129.659(9) 3 13
Zn3 As2 K 120.270(5) . 13
Zn2 As2 K 66.483(4) . 13
K As2 K 141.012(7) 9 13
K As2 K 60.002(4) . 13
Zn2 As2 K 67.907(5) 9_565 5_455
Zn1 As2 K 129.659(9) . 5_455
Zn1 As2 K 61.261(5) 3 5_455
Zn3 As2 K 120.270(5) . 5_455
Zn2 As2 K 66.483(5) . 5_455
K As2 K 60.002(4) 9 5_455
K As2 K 141.012(7) . 5_455
K As2 K 118.855(9) 13 5_455
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
K As2 3.3485(4) 9
K As2 3.3485(4) .
K As1 3.43462(18) 13
K As1 3.43462(18) 7_545
K Zn1 3.4379(3) 7_545
K Zn1 3.4379(3) 13
K K 3.6181(3) 13
K K 3.6181(3) 13_545
K Zn2 3.6966(5) 5_545
K Zn2 3.6966(5) 13
K Zn2 3.7102(4) 1_545
K Zn2 3.7102(4) 9_565
Zn1 As1 2.4682(3) .
Zn1 As2 2.5497(2) .
Zn1 As2 2.5497(2) 10_556
Zn1 As1 2.6256(3) 7
Zn1 Zn2 2.9961(3) 10_556
Zn1 Zn2 2.9961(3) .
Zn1 Zn3 3.1387(4) .
Zn1 K 3.4379(3) 6
Zn1 K 3.4379(3) 13
Zn1 K 4.0680(2) 10_556
Zn2 As2 2.4535(3) 9_565
Zn2 As1 2.5743(2) 7
Zn2 As1 2.5743(2) 5_455
Zn2 As2 2.6636(3) .
Zn2 Zn1 2.9961(3) 3
Zn2 Zn3 2.9977(4) 1_565
Zn2 K 3.6966(5) 5_455
Zn2 K 3.6966(5) 13
Zn2 K 3.7102(4) 1_565
Zn2 K 3.7102(4) 9_565
Zn3 As1 2.5437(3) 5_445
Zn3 As1 2.5437(3) 7_545
Zn3 As2 2.5848(3) 10_556
Zn3 As2 2.5848(3) .
Zn3 Zn2 2.9977(4) 1_545
Zn3 Zn2 2.9977(4) 10_546
Zn3 Zn1 3.1387(4) 3
Zn3 K 3.8253(3) 9
Zn3 K 3.8253(3) 10_556
Zn3 K 3.8253(3) 2
As1 Zn3 2.5437(3) 5
As1 Zn2 2.5743(2) 14_546
As1 Zn2 2.5743(2) 5_545
As1 Zn1 2.6256(3) 7_545
As1 K 3.43462(18) 6
As1 K 3.43462(18) 13
As1 K 3.7312(2) 10_556
As2 Zn2 2.4535(3) 9_565
As2 Zn1 2.5497(2) 3
As2 K 3.3485(4) 9
As2 K 3.8377(4) 13
As2 K 3.8377(4) 5_455
