#------------------------------------------------------------------------------
#$Date: 2016-02-16 22:30:59 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176467 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/19/4331919.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided the Crystal Eye server at
# http://wwmm.ch.cam.ac.uk/crystaleye/, created by Nick Day at the
# Peter Murray-Rust laboratory.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_4331919
loop_
_publ_author_name
'Kubatko, Karrie-Ann'
'Burns, Peter C.'
_publ_section_title
;
 Expanding the Crystal Chemistry of Actinyl Peroxides:  Open Sheets
 of Uranyl Polyhedra in Na5[(UO2)3(O2)4(OH)3](H2O)13
;
_journal_issue                   16
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6096
_journal_page_last               6098
_journal_paper_doi               10.1021/ic0518677
_journal_volume                  45
_journal_year                    2006
_chemical_formula_moiety         'H3.87 Na0.67 O4 U0.40'
_chemical_formula_sum            'H3.87 Na0.67 O4 U0.4'
_chemical_formula_weight         178.44
_chemical_name_common            'H3.87 Na0.67 O4 U0.40'
_chemical_name_systematic
; 
Na5[(UO2)3(O2)4(OH)3](H2O)13
;
_space_group_IT_number           64
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-C 2ac 2'
_symmetry_space_group_name_H-M   'C m c a'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            60
_cell_length_a                   23.6315(14)
_cell_length_b                   15.8862(14)
_cell_length_c                   13.9518(10)
_cell_measurement_reflns_used    5675
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      69
_cell_measurement_theta_min      2
_cell_volume                     5237.7(7)
_computing_cell_refinement       'SMART (Bruker, 2001)'
_computing_data_collection       'SMART (Bruker, 2001)'
_computing_data_reduction        'SAINT (Bruker, 2000)'
_computing_molecular_graphics    'ATOMS, (Dowty, 2000)'
_computing_publication_material  'SHELXTL (Bruker, 1998)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'Bruker APEX CCD area-detector'
_diffrn_measurement_method       'φ and ω'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1713
_diffrn_reflns_av_sigmaI/netI    0.1920
_diffrn_reflns_limit_h_max       37
_diffrn_reflns_limit_h_min       -37
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            52295
_diffrn_reflns_theta_full        34.51
_diffrn_reflns_theta_max         34.51
_diffrn_reflns_theta_min         1.72
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    18.706
_exptl_absorpt_correction_T_max  0.688
_exptl_absorpt_correction_T_min  0.244
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'via ψ-scan (SHELXTL-NT; Bruker, 1998)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    3.394
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       'yellow blocky crystals'
_exptl_crystal_F_000             4800
_exptl_crystal_size_max          0.08
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.02
_refine_diff_density_max         10.775
_refine_diff_density_min         -2.463
_refine_diff_density_rms         0.440
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.755
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     181
_refine_ls_number_reflns         5628
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.755
_refine_ls_R_factor_all          0.1264
_refine_ls_R_factor_gt           0.0547
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0652P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1233
_refine_ls_wR_factor_ref         0.1515
_reflns_number_gt                2501
_reflns_number_total             5628
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic0518677sup1.cif
_cod_data_source_block           play
_cod_original_sg_symbol_H-M      Cmca
_cod_original_formula_sum        'H3.87 Na0.67 O4 U0.40'
_cod_database_code               4331919
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y+1/2, z+1/2'
'-x, y+1/2, -z+1/2'
'x, -y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, -y+1, z+1/2'
'-x+1/2, y+1, -z+1/2'
'x+1/2, -y+1/2, -z'
'-x, -y, -z'
'x, y-1/2, -z-1/2'
'x, -y-1/2, z-1/2'
'-x, y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, y, -z-1/2'
'x+1/2, -y, z-1/2'
'-x+1/2, y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
U1 U 0.327253(19) 0.22358(3) 0.04935(3) 0.01899(11) Uani 1 1 d .
U2 U 0.41675(3) 0.0000 0.0000 0.02080(15) Uani 1 2 d S
Na1 Na 0.5000 0.1613(5) -0.1559(6) 0.0296(18) Uani 1 2 d S
Na2 Na 0.5000 0.3508(6) -0.1370(8) 0.054(3) Uani 1 2 d S
Na3 Na 0.3941(3) 0.0703(5) 0.2713(6) 0.069(2) Uani 1 1 d .
Na4 Na 0.2689(8) 0.3526(12) 0.2795(15) 0.097(7) Uiso 0.50 1 d P
O1 O 0.1985(4) 0.2335(6) 0.3303(6) 0.027(2) Uani 1 1 d .
O2 O 0.4226(4) 0.0691(5) -0.1044(6) 0.0223(19) Uani 1 1 d .
O3 O 0.3518(4) 0.2166(6) -0.0740(6) 0.027(2) Uani 1 1 d .
O4 O 0.4124(4) 0.2809(6) 0.0991(7) 0.026(2) Uani 1 1 d .
O5 O 0.3371(3) 0.0714(6) 0.0606(6) 0.022(2) Uani 1 1 d .
O6 O 0.3744(4) 0.3499(6) 0.0705(6) 0.026(2) Uani 1 1 d .
O7 O 0.3889(4) 0.1111(6) 0.1007(6) 0.0225(19) Uani 1 1 d .
O8 O 0.5000 0.0683(8) 0.0562(10) 0.025(3) Uani 1 2 d S
O9 O 0.2372(4) 0.1693(6) 0.0044(7) 0.027(2) Uani 1 1 d .
O10 O 0.4310(5) 0.4275(7) -0.0658(7) 0.047(3) Uani 1 1 d .
O11 O 0.5000 0.2380(8) -0.0092(10) 0.026(3) Uani 1 2 d S
O12 O 0.4295(4) 0.2647(6) -0.2108(7) 0.031(2) Uani 1 1 d .
O13 O 0.5000 0.3833(9) 0.1787(10) 0.030(3) Uani 1 2 d S
O14 O 0.5000 0.0495(10) 0.2480(10) 0.040(4) Uani 1 2 d S
O15 O 0.1927(5) 0.1178(8) 0.1783(8) 0.052(3) Uani 1 1 d .
O16 O 0.2541(6) -0.0339(8) 0.1280(9) 0.067(4) Uani 1 1 d .
O17 O 0.3579(6) 0.4268(8) 0.2334(9) 0.068(4) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
U U -9.6767 9.6646 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 U1 O3 178.0(4) 7_545 .
O1 U1 O6 88.2(4) 7_545 .
O3 U1 O6 91.1(4) . .
O1 U1 O4 88.9(4) 7_545 .
O3 U1 O4 91.7(4) . .
O6 U1 O4 37.1(3) . .
O1 U1 O9 88.5(4) 7_545 .
O3 U1 O9 90.8(4) . .
O6 U1 O9 141.1(3) . .
O4 U1 O9 176.9(3) . .
O1 U1 O9 90.9(4) 7_545 13
O3 U1 O9 87.1(4) . 13
O6 U1 O9 74.4(3) . 13
O4 U1 O9 111.5(3) . 13
O9 U1 O9 66.9(4) . 13
O1 U1 O7 89.5(4) 7_545 .
O3 U1 O7 92.5(4) . .
O6 U1 O7 108.3(3) . .
O4 U1 O7 71.2(3) . .
O9 U1 O7 110.4(3) . .
O9 U1 O7 177.3(3) 13 .
O1 U1 O5 93.4(4) 7_545 .
O3 U1 O5 88.3(4) . .
O6 U1 O5 143.8(3) . .
O4 U1 O5 106.8(3) . .
O9 U1 O5 75.1(3) . .
O9 U1 O5 141.6(3) 13 .
O7 U1 O5 35.7(3) . .
O1 U1 Na4 34.8(4) 7_545 7_545
O3 U1 Na4 143.2(4) . 7_545
O6 U1 Na4 75.2(4) . 7_545
O4 U1 Na4 96.7(4) . 7_545
O9 U1 Na4 80.2(4) . 7_545
O9 U1 Na4 56.5(3) 13 7_545
O7 U1 Na4 124.2(3) . 7_545
O5 U1 Na4 122.7(4) . 7_545
O1 U1 U1 89.6(3) 7_545 13
O3 U1 U1 88.8(3) . 13
O6 U1 U1 107.6(2) . 13
O4 U1 U1 144.7(2) . 13
O9 U1 U1 33.7(2) . 13
O9 U1 U1 33.3(2) 13 13
O7 U1 U1 144.1(2) . 13
O5 U1 U1 108.6(2) . 13
Na4 U1 U1 64.3(3) 7_545 13
O1 U1 Na4 25.6(4) 7_545 .
O3 U1 Na4 152.7(4) . .
O6 U1 Na4 67.9(4) . .
O4 U1 Na4 81.9(3) . .
O9 U1 Na4 95.0(4) . .
O9 U1 Na4 70.9(4) 13 .
O7 U1 Na4 110.2(3) . .
O5 U1 Na4 118.9(4) . .
Na4 U1 Na4 17.4(5) 7_545 .
U1 U1 Na4 81.7(3) 13 .
O2 U2 O2 171.3(5) . 4
O2 U2 O7 89.8(4) . 4
O2 U2 O7 92.6(3) 4 4
O2 U2 O7 92.6(3) . .
O2 U2 O7 89.8(4) 4 .
O7 U2 O7 147.5(4) 4 .
O2 U2 O5 93.7(4) . 4
O2 U2 O5 93.3(3) 4 4
O7 U2 O5 36.8(3) 4 4
O7 U2 O5 110.6(3) . 4
O2 U2 O5 93.3(3) . .
O2 U2 O5 93.7(4) 4 .
O7 U2 O5 110.6(3) 4 .
O7 U2 O5 36.8(3) . .
O5 U2 O5 73.9(4) 4 .
O2 U2 O8 85.7(4) . .
O2 U2 O8 87.0(4) 4 .
O7 U2 O8 140.4(3) 4 .
O7 U2 O8 72.1(3) . .
O5 U2 O8 177.3(4) 4 .
O5 U2 O8 108.9(3) . .
O2 U2 O8 87.0(4) . 9_655
O2 U2 O8 85.7(4) 4 9_655
O7 U2 O8 72.1(3) 4 9_655
O7 U2 O8 140.4(3) . 9_655
O5 U2 O8 108.9(3) 4 9_655
O5 U2 O8 177.3(4) . 9_655
O8 U2 O8 68.4(5) . 9_655
O2 U2 Na1 28.6(3) . .
O2 U2 Na1 143.2(3) 4 .
O7 U2 Na1 107.6(2) 4 .
O7 U2 Na1 88.9(3) . .
O5 U2 Na1 121.3(2) 4 .
O5 U2 Na1 106.7(2) . .
O8 U2 Na1 57.8(3) . .
O8 U2 Na1 72.4(3) 9_655 .
O2 U2 Na1 143.2(3) . 9_655
O2 U2 Na1 28.6(3) 4 9_655
O7 U2 Na1 88.9(3) 4 9_655
O7 U2 Na1 107.6(2) . 9_655
O5 U2 Na1 106.7(2) 4 9_655
O5 U2 Na1 121.3(2) . 9_655
O8 U2 Na1 72.4(3) . 9_655
O8 U2 Na1 57.8(3) 9_655 9_655
Na1 U2 Na1 119.33(12) . 9_655
O2 U2 U2 85.6(3) . 9_655
O2 U2 U2 85.6(3) 4 9_655
O7 U2 U2 106.3(2) 4 9_655
O7 U2 U2 106.3(2) . 9_655
O5 U2 U2 143.1(2) 4 9_655
O5 U2 U2 143.1(2) . 9_655
O8 U2 U2 34.2(3) . 9_655
O8 U2 U2 34.2(3) 9_655 9_655
Na1 U2 U2 59.66(6) . 9_655
Na1 U2 U2 59.66(6) 9_655 9_655
O2 U2 Na3 54.7(3) . 4
O2 U2 Na3 126.8(3) 4 4
O7 U2 Na3 35.3(2) 4 4
O7 U2 Na3 137.8(2) . 4
O5 U2 Na3 54.3(2) 4 4
O5 U2 Na3 111.7(2) . 4
O8 U2 Na3 123.5(3) . 4
O8 U2 Na3 70.7(3) 9_655 4
Na1 U2 Na3 73.83(16) . 4
Na1 U2 Na3 114.46(17) 9_655 4
U2 U2 Na3 97.72(12) 9_655 4
O11 Na1 O13 166.3(6) . 2_654
O11 Na1 O2 93.0(4) . .
O13 Na1 O2 96.0(4) 2_654 .
O11 Na1 O2 93.0(4) . 12_655
O13 Na1 O2 96.0(4) 2_654 12_655
O2 Na1 O2 96.5(5) . 12_655
O11 Na1 O12 85.8(4) . .
O13 Na1 O12 84.2(4) 2_654 .
O2 Na1 O12 89.2(3) . .
O2 Na1 O12 174.3(4) 12_655 .
O11 Na1 O12 85.8(4) . 12_655
O13 Na1 O12 84.2(4) 2_654 12_655
O2 Na1 O12 174.3(4) . 12_655
O2 Na1 O12 89.2(3) 12_655 12_655
O12 Na1 O12 85.2(5) . 12_655
O11 Na1 Na2 54.2(4) . .
O13 Na1 Na2 112.1(5) 2_654 .
O2 Na1 Na2 124.7(3) . .
O2 Na1 Na2 124.7(3) 12_655 .
O12 Na1 Na2 50.4(3) . .
O12 Na1 Na2 50.4(3) 12_655 .
O11 Na1 U2 81.7(3) . .
O13 Na1 U2 109.9(3) 2_654 .
O2 Na1 U2 20.9(2) . .
O2 Na1 U2 79.6(3) 12_655 .
O12 Na1 U2 105.7(2) . .
O12 Na1 U2 162.7(3) 12_655 .
Na2 Na1 U2 127.3(2) . .
O11 Na1 U2 81.7(3) . 9_655
O13 Na1 U2 109.9(3) 2_654 9_655
O2 Na1 U2 79.6(3) . 9_655
O2 Na1 U2 20.9(2) 12_655 9_655
O12 Na1 U2 162.7(3) . 9_655
O12 Na1 U2 105.7(2) 12_655 9_655
Na2 Na1 U2 127.3(2) . 9_655
U2 Na1 U2 60.67(12) . 9_655
O14 Na2 O10 86.2(5) 2_654 12_655
O14 Na2 O10 86.2(5) 2_654 .
O10 Na2 O10 92.1(7) 12_655 .
O14 Na2 O12 95.5(5) 2_654 .
O10 Na2 O12 177.6(6) 12_655 .
O10 Na2 O12 89.7(4) . .
O14 Na2 O12 95.5(5) 2_654 12_655
O10 Na2 O12 89.7(4) 12_655 12_655
O10 Na2 O12 177.6(6) . 12_655
O12 Na2 O12 88.4(6) . 12_655
O14 Na2 O11 179.5(7) 2_654 .
O10 Na2 O11 94.1(5) 12_655 .
O10 Na2 O11 94.1(5) . .
O12 Na2 O11 84.2(4) . .
O12 Na2 O11 84.2(4) 12_655 .
O14 Na2 Na1 129.6(6) 2_654 .
O10 Na2 Na1 125.0(4) 12_655 .
O10 Na2 Na1 125.0(4) . .
O12 Na2 Na1 52.5(3) . .
O12 Na2 Na1 52.5(3) 12_655 .
O11 Na2 Na1 49.9(4) . .
O14 Na2 Na3 54.4(2) 2_654 11_565
O10 Na2 Na3 123.3(5) 12_655 11_565
O10 Na2 Na3 51.5(3) . 11_565
O12 Na2 Na3 59.1(3) . 11_565
O12 Na2 Na3 128.4(5) 12_655 11_565
O11 Na2 Na3 125.6(2) . 11_565
Na1 Na2 Na3 111.7(3) . 11_565
O14 Na2 Na3 54.4(2) 2_654 2_654
O10 Na2 Na3 51.5(3) 12_655 2_654
O10 Na2 Na3 123.3(5) . 2_654
O12 Na2 Na3 128.4(5) . 2_654
O12 Na2 Na3 59.1(3) 12_655 2_654
O11 Na2 Na3 125.6(2) . 2_654
Na1 Na2 Na3 111.7(3) . 2_654
Na3 Na2 Na3 108.8(4) 11_565 2_654
O15 Na3 O10 91.6(5) 7_545 11_566
O15 Na3 O17 90.1(5) 7_545 10_556
O10 Na3 O17 99.4(5) 11_566 10_556
O15 Na3 O7 99.5(5) 7_545 .
O10 Na3 O7 156.1(5) 11_566 .
O17 Na3 O7 101.7(5) 10_556 .
O15 Na3 O14 163.8(6) 7_545 .
O10 Na3 O14 76.7(5) 11_566 .
O17 Na3 O14 102.8(5) 10_556 .
O7 Na3 O14 87.7(5) . .
O15 Na3 O12 86.0(5) 7_545 11_566
O10 Na3 O12 78.1(4) 11_566 11_566
O17 Na3 O12 175.3(5) 10_556 11_566
O7 Na3 O12 81.6(4) . 11_566
O14 Na3 O12 80.6(5) . 11_566
O15 Na3 Na2 117.7(5) 7_545 2_655
O10 Na3 Na2 46.8(4) 11_566 2_655
O17 Na3 Na2 132.7(5) 10_556 2_655
O7 Na3 Na2 109.5(4) . 2_655
O14 Na3 Na2 46.1(4) . 2_655
O12 Na3 Na2 47.9(3) 11_566 2_655
O15 Na3 U2 120.2(4) 7_545 .
O10 Na3 U2 147.5(4) 11_566 .
O17 Na3 U2 76.1(4) 10_556 .
O7 Na3 U2 33.3(2) . .
O14 Na3 U2 73.2(4) . .
O12 Na3 U2 108.2(3) 11_566 .
Na2 Na3 U2 113.6(3) 2_655 .
Na4 Na4 O16 106.0(14) 7_545 10_566
Na4 Na4 O17 116(2) 7_545 .
O16 Na4 O17 84.2(8) 10_566 .
Na4 Na4 O1 79.3(14) 7_545 7_545
O16 Na4 O1 170.8(11) 10_566 7_545
O17 Na4 O1 86.6(8) . 7_545
Na4 Na4 O1 73.5(14) 7_545 .
O16 Na4 O1 109.1(9) 10_566 .
O17 Na4 O1 161.3(9) . .
O1 Na4 O1 79.5(7) 7_545 .
Na4 Na4 O16 49.7(11) 7_545 16
O16 Na4 O16 83.5(8) 10_566 16
O17 Na4 O16 70.6(7) . 16
O1 Na4 O16 94.7(7) 7_545 16
O1 Na4 O16 122.8(8) . 16
Na4 Na4 U1 89.3(18) 7_545 7_545
O16 Na4 U1 88.8(7) 10_566 7_545
O17 Na4 U1 154.4(7) . 7_545
O1 Na4 U1 98.9(6) 7_545 7_545
O1 Na4 U1 23.0(3) . 7_545
O16 Na4 U1 133.1(7) 16 7_545
Na4 Na4 U1 73.3(18) 7_545 .
O16 Na4 U1 156.2(9) 10_566 .
O17 Na4 U1 75.4(6) . .
O1 Na4 U1 17.6(3) 7_545 .
O1 Na4 U1 93.7(6) . .
O16 Na4 U1 78.2(5) 16 .
U1 Na4 U1 114.8(5) 7_545 .
U1 O1 Na4 136.8(7) 7_545 7_545
U1 O1 Na4 122.2(6) 7_545 .
Na4 O1 Na4 27.1(8) 7_545 .
U2 O2 Na1 130.5(5) . .
O6 O4 U1 71.4(5) . .
O7 O5 U2 71.4(5) . .
O7 O5 U1 71.4(5) . .
U2 O5 U1 122.1(3) . .
O4 O6 U1 71.5(5) . .
O5 O7 U2 71.8(5) . .
O5 O7 U1 72.9(5) . .
U2 O7 U1 123.2(4) . .
O5 O7 Na3 107.0(6) . .
U2 O7 Na3 111.4(4) . .
U1 O7 Na3 120.7(4) . .
U2 O8 U2 111.6(5) . 9_655
U1 O9 U1 113.1(4) . 13
Na2 O10 Na3 81.7(5) . 11_565
Na1 O11 Na2 75.9(5) . .
Na2 O12 Na1 77.1(4) . .
Na2 O12 Na3 73.0(4) . 11_565
Na1 O12 Na3 150.0(5) . 11_565
Na2 O14 Na3 79.5(4) 2_655 .
Na2 O14 Na3 79.5(4) 2_655 12_655
Na3 O14 Na3 159.0(8) . 12_655
Na4 O16 Na4 24.3(8) 10_556 16_545
Na3 O17 Na4 138.2(7) 10_566 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
U1 O1 1.793(9) 7_545
U1 O3 1.820(9) .
U1 O6 2.314(9) .
U1 O4 2.315(9) .
U1 O9 2.380(9) .
U1 O9 2.404(9) 13
U1 O7 2.414(9) .
U1 O5 2.433(9) .
U1 Na4 3.88(2) 7_545
U1 U1 3.9915(9) 13
U1 Na4 4.05(2) .
U2 O2 1.829(9) .
U2 O2 1.829(9) 4
U2 O7 2.350(9) 4
U2 O7 2.350(9) .
U2 O5 2.355(8) 4
U2 O5 2.355(8) .
U2 O8 2.379(8) .
U2 O8 2.379(8) 9_655
U2 Na1 3.895(7) .
U2 Na1 3.895(7) 9_655
U2 U2 3.9347(13) 9_655
U2 Na3 3.982(8) 4
Na1 O11 2.382(16) .
Na1 O13 2.413(16) 2_654
Na1 O2 2.450(10) .
Na1 O2 2.450(10) 12_655
Na1 O12 2.461(11) .
Na1 O12 2.461(11) 12_655
Na1 Na2 3.021(13) .
Na1 U2 3.895(7) 9_655
Na2 O14 2.255(18) 2_654
Na2 O10 2.266(14) 12_655
Na2 O10 2.266(14) .
Na2 O12 2.388(13) .
Na2 O12 2.388(13) 12_655
Na2 O11 2.528(17) .
Na2 Na3 3.077(11) 11_565
Na2 Na3 3.077(11) 2_654
Na3 O15 2.296(14) 7_545
Na3 O10 2.435(14) 11_566
Na3 O17 2.436(17) 10_556
Na3 O7 2.470(12) .
Na3 O14 2.545(8) .
Na3 O12 2.763(13) 11_566
Na3 Na2 3.077(11) 2_655
Na4 Na4 1.21(4) 7_545
Na4 O16 2.25(2) 10_566
Na4 O17 2.50(3) .
Na4 O1 2.55(2) 7_545
Na4 O1 2.62(2) .
Na4 O16 2.83(2) 16
Na4 U1 3.88(2) 7_545
O1 U1 1.793(9) 7_545
O1 Na4 2.55(2) 7_545
O4 O6 1.473(12) .
O5 O7 1.486(12) .
O8 U2 2.379(8) 9_655
O9 U1 2.404(9) 13
O10 Na3 2.435(14) 11_565
O12 Na3 2.763(13) 11_565
O13 Na1 2.413(16) 2_655
O14 Na2 2.255(18) 2_655
O14 Na3 2.545(8) 12_655
O15 Na3 2.296(14) 7_545
O16 Na4 2.25(2) 10_556
O16 Na4 2.83(2) 16_545
O17 Na3 2.436(17) 10_566
