#------------------------------------------------------------------------------
#$Date: 2016-02-14 06:40:26 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176432 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/24/4332433.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided the Crystal Eye server at
# http://wwmm.ch.cam.ac.uk/crystaleye/, created by Nick Day at the
# Peter Murray-Rust laboratory.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_4332433
loop_
_publ_author_name
'Jiang, Hai-Long'
'Mao, Jiang-Gao'
_publ_section_title
;
 New Members in the Nin+1(QO3)nX2Family:  Unusual 3D Network Based
 on Ni4ClO3Cubane-like Clusters in Ni7(TeO3)6Cl2
;
_journal_issue                   19
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              7593
_journal_page_last               7599
_journal_paper_doi               10.1021/ic060356x
_journal_volume                  45
_journal_year                    2006
_chemical_formula_sum            'Cl2 Ni11 O30 Te10'
_chemical_formula_weight         2472.71
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                100.2180(10)
_cell_angle_beta                 99.068(4)
_cell_angle_gamma                115.880(2)
_cell_formula_units_Z            1
_cell_length_a                   9.281(3)
_cell_length_b                   9.423(3)
_cell_length_c                   10.113(3)
_cell_measurement_temperature    293(2)
_cell_volume                     755.0(4)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.978
_diffrn_measured_fraction_theta_max 0.978
_diffrn_measurement_device_type  'Rigaku SATURN70'
_diffrn_measurement_method       CCD_Profile_fitting
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0256
_diffrn_reflns_av_sigmaI/netI    0.0419
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            5869
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         2.50
_diffrn_standards_decay_%        <1.0%
_exptl_absorpt_coefficient_mu    16.450
_exptl_absorpt_correction_T_max  0.1091
_exptl_absorpt_correction_T_min  0.0169
_exptl_absorpt_correction_type   numerical
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    5.438
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1102
_exptl_crystal_size_max          0.11
_exptl_crystal_size_mid          0.09
_exptl_crystal_size_min          0.07
_refine_diff_density_max         1.338
_refine_diff_density_min         -1.373
_refine_diff_density_rms         0.213
_refine_ls_extinction_coef       0.0016(2)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.059
_refine_ls_matrix_type           full
_refine_ls_number_parameters     260
_refine_ls_number_reflns         3383
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.059
_refine_ls_R_factor_all          0.0272
_refine_ls_R_factor_gt           0.0232
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0218P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0556
_refine_ls_wR_factor_ref         0.0567
_reflns_number_gt                3032
_reflns_number_total             3383
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic060356xsup3.cif
_cod_data_source_block           1
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from
2011-04-26.

'_exptl_absorpt_correction_type' value 'Numerical'
changed to 'numerical' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_Hall     -P1
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4332433
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ni1 Ni 0.51160(8) 0.39169(8) 0.86414(7) 0.00817(15) Uani 1 1 d .
Ni2 Ni 0.92910(8) 0.30259(8) 0.46421(7) 0.00904(15) Uani 1 1 d .
Ni3 Ni 0.33673(8) 0.37083(9) 0.38686(7) 0.01050(16) Uani 1 1 d .
Ni4 Ni 0.17433(8) 0.12582(8) 0.62253(7) 0.00787(15) Uani 1 1 d .
Ni5 Ni 0.46381(9) 0.76964(10) 0.46539(8) 0.02072(19) Uani 1 1 d .
Ni6 Ni 0.92285(16) 0.14259(17) 0.17945(14) 0.0099(3) Uani 0.50 1 d P
Te1 Te 0.31985(4) 0.56946(4) 0.71828(3) 0.00649(9) Uani 1 1 d .
Te2 Te 0.54612(4) 0.99800(4) 0.21840(4) 0.01517(10) Uani 1 1 d .
Te3 Te 0.13236(4) 0.51164(4) 0.25665(4) 0.01117(10) Uani 1 1 d .
Te4 Te 0.16167(4) 0.96683(4) 0.32515(3) 0.00965(9) Uani 1 1 d .
Te5 Te 0.22338(5) 0.17827(5) 0.03159(4) 0.02056(11) Uani 1 1 d .
Cl1 Cl 0.74290(18) 0.3550(2) 0.98309(15) 0.0230(3) Uani 1 1 d .
O1 O 0.0982(4) 0.4980(5) 0.6239(4) 0.0107(8) Uani 1 1 d .
O2 O 0.4135(4) 0.5710(5) 0.5612(4) 0.0106(8) Uani 1 1 d .
O3 O 0.2970(4) 0.3701(4) 0.7383(4) 0.0096(8) Uani 1 1 d .
O4 O 0.479(3) 0.0576(17) 0.372(3) 0.027(3) Uani 0.50 1 d P
O4' O 0.482(3) 0.0036(17) 0.382(3) 0.027(3) Uani 0.50 1 d P
O5 O 0.5849(17) 0.8373(18) 0.2811(12) 0.013(2) Uani 0.50 1 d P
O5' O 0.6191(17) 0.8512(18) 0.2404(12) 0.013(2) Uani 0.50 1 d P
O6 O 0.7575(5) 0.1734(5) 0.2844(4) 0.0206(10) Uani 1 1 d .
O7 O 0.0997(4) 0.3434(5) 0.3466(4) 0.0118(8) Uani 1 1 d .
O8 O 0.2235(4) 0.7017(4) 0.4081(4) 0.0114(8) Uani 1 1 d .
O9 O 0.3576(4) 0.5475(5) 0.2804(4) 0.0137(8) Uani 1 1 d .
O10 O 0.2894(4) 0.1741(4) 0.4687(4) 0.0118(8) Uani 1 1 d .
O11 O 0.9675(5) 0.9721(5) 0.2507(4) 0.0137(8) Uani 1 1 d .
O12 O 0.0586(4) 0.8879(4) 0.4705(4) 0.0103(8) Uani 1 1 d .
O13 O 0.2971(5) 0.1870(5) 0.2182(4) 0.0177(9) Uani 1 1 d .
O14 O 0.4057(5) 0.3675(5) 0.0301(4) 0.0145(8) Uani 1 1 d .
O15 O 0.2714(10) 0.0374(10) 0.9607(8) 0.0176(18) Uani 0.50 1 d P
O15' O 0.0608(9) 0.2252(11) 0.0483(8) 0.0186(19) Uani 0.50 1 d P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ni Ni 0.3393 1.1124 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Te Te -0.5308 1.6751 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O5' Ni1 O9 93.9(3) 2_666 2_666
O5' Ni1 O14 167.7(4) 2_666 2_666
O9 Ni1 O14 93.73(16) 2_666 2_666
O5' Ni1 O14 95.0(3) 2_666 1_556
O9 Ni1 O14 170.90(16) 2_666 1_556
O14 Ni1 O14 77.76(16) 2_666 1_556
O5' Ni1 O3 76.4(5) 2_666 .
O9 Ni1 O3 92.76(15) 2_666 .
O14 Ni1 O3 93.61(16) 2_666 .
O14 Ni1 O3 91.02(15) 1_556 .
O5' Ni1 O5 15.4(3) 2_666 2_666
O9 Ni1 O5 78.5(3) 2_666 2_666
O14 Ni1 O5 167.7(4) 2_666 2_666
O14 Ni1 O5 110.4(3) 1_556 2_666
O3 Ni1 O5 77.4(4) . 2_666
O5' Ni1 Cl1 91.3(4) 2_666 .
O9 Ni1 Cl1 86.08(12) 2_666 .
O14 Ni1 Cl1 98.85(13) 2_666 .
O14 Ni1 Cl1 91.99(13) 1_556 .
O3 Ni1 Cl1 167.54(11) . .
O5 Ni1 Cl1 90.2(4) 2_666 .
O6 Ni2 O1 159.95(17) . 1_655
O6 Ni2 O8 99.04(16) . 2_666
O1 Ni2 O8 81.90(15) 1_655 2_666
O6 Ni2 O12 98.75(16) . 2_666
O1 Ni2 O12 101.30(15) 1_655 2_666
O8 Ni2 O12 87.35(15) 2_666 2_666
O6 Ni2 O7 85.75(16) . 1_655
O1 Ni2 O7 91.29(15) 1_655 1_655
O8 Ni2 O7 171.73(15) 2_666 1_655
O12 Ni2 O7 98.64(15) 2_666 1_655
O6 Ni2 O1 77.06(16) . 2_666
O1 Ni2 O1 82.89(15) 1_655 2_666
O8 Ni2 O1 93.57(14) 2_666 2_666
O12 Ni2 O1 175.80(13) 2_666 2_666
O7 Ni2 O1 80.87(15) 1_655 2_666
O6 Ni2 Ni6 44.26(13) . .
O1 Ni2 Ni6 136.02(11) 1_655 .
O8 Ni2 Ni6 141.78(11) 2_666 .
O12 Ni2 Ni6 88.64(11) 2_666 .
O7 Ni2 Ni6 44.74(11) 1_655 .
O1 Ni2 Ni6 88.11(10) 2_666 .
O13 Ni3 O7 97.74(16) . .
O13 Ni3 O10 77.03(15) . .
O7 Ni3 O10 97.54(15) . .
O13 Ni3 O2 88.34(16) . 2_666
O7 Ni3 O2 172.96(15) . 2_666
O10 Ni3 O2 87.25(15) . 2_666
O13 Ni3 O9 97.22(16) . .
O7 Ni3 O9 77.81(14) . .
O10 Ni3 O9 172.18(14) . .
O2 Ni3 O9 97.98(14) 2_666 .
O13 Ni3 O2 171.82(16) . .
O7 Ni3 O2 90.08(15) . .
O10 Ni3 O2 104.40(15) . .
O2 Ni3 O2 83.71(16) 2_666 .
O9 Ni3 O2 82.06(15) . .
O13 Ni3 Te3 100.80(12) . .
O7 Ni3 Te3 38.39(10) . .
O10 Ni3 Te3 135.77(11) . .
O2 Ni3 Te3 136.97(11) 2_666 .
O9 Ni3 Te3 39.45(10) . .
O2 Ni3 Te3 83.86(11) . .
O11 Ni4 O10 167.75(15) 2_666 .
O11 Ni4 O3 99.03(15) 2_666 .
O10 Ni4 O3 93.19(14) . .
O11 Ni4 O5' 89.6(3) 2_666 2_666
O10 Ni4 O5' 94.2(3) . 2_666
O3 Ni4 O5' 75.8(4) . 2_666
O11 Ni4 O5 104.4(3) 2_666 2_666
O10 Ni4 O5 79.1(3) . 2_666
O3 Ni4 O5 76.8(4) . 2_666
O5' Ni4 O5 15.1(3) 2_666 2_666
O11 Ni4 O12 77.72(15) 2_666 2_566
O10 Ni4 O12 99.81(15) . 2_566
O3 Ni4 O12 98.29(14) . 2_566
O5' Ni4 O12 165.2(3) 2_666 2_566
O5 Ni4 O12 174.9(4) 2_666 2_566
O11 Ni4 O12 90.68(15) 2_666 1_545
O10 Ni4 O12 77.08(14) . 1_545
O3 Ni4 O12 169.69(14) . 1_545
O5' Ni4 O12 107.9(4) 2_666 1_545
O5 Ni4 O12 104.2(4) 2_666 1_545
O12 Ni4 O12 80.29(16) 2_566 1_545
O11 Ni4 Te4 37.41(11) 2_666 2_566
O10 Ni4 Te4 139.69(11) . 2_566
O3 Ni4 Te4 98.54(10) . 2_566
O5' Ni4 Te4 126.1(2) 2_666 2_566
O5 Ni4 Te4 141.2(2) 2_666 2_566
O12 Ni4 Te4 40.46(9) 2_566 2_566
O12 Ni4 Te4 87.03(10) 1_545 2_566
O11 Ni4 Te4 129.64(11) 2_666 1_545
O10 Ni4 Te4 38.20(10) . 1_545
O3 Ni4 Te4 130.52(10) . 1_545
O5' Ni4 Te4 108.5(3) 2_666 1_545
O5 Ni4 Te4 96.2(3) 2_666 1_545
O12 Ni4 Te4 85.71(10) 2_566 1_545
O12 Ni4 Te4 39.36(9) 1_545 1_545
Te4 Ni4 Te4 114.20(2) 2_566 1_545
O4 Ni5 O8 97.1(7) 2_666 .
O4 Ni5 O10 83.8(7) 2_666 2_666
O8 Ni5 O10 175.75(16) . 2_666
O4 Ni5 O2 98.8(5) 2_666 .
O8 Ni5 O2 90.77(15) . .
O10 Ni5 O2 84.98(14) 2_666 .
O4 Ni5 O4' 12.9(10) 2_666 2_666
O8 Ni5 O4' 92.4(6) . 2_666
O10 Ni5 O4' 89.3(6) 2_666 2_666
O2 Ni5 O4' 111.0(5) . 2_666
O4 Ni5 O9 171.2(7) 2_666 .
O8 Ni5 O9 75.32(15) . .
O10 Ni5 O9 103.49(14) 2_666 .
O2 Ni5 O9 77.15(14) . .
O4' Ni5 O9 165.7(6) 2_666 .
O4 Ni5 O5 118.5(7) 2_666 .
O8 Ni5 O5 109.9(4) . .
O10 Ni5 O5 73.1(4) 2_666 .
O2 Ni5 O5 133.3(4) . .
O4' Ni5 O5 109.4(7) 2_666 .
O9 Ni5 O5 69.1(4) . .
O4 Ni5 Te3 133.2(7) 2_666 .
O8 Ni5 Te3 36.44(11) . .
O10 Ni5 Te3 142.10(11) 2_666 .
O2 Ni5 Te3 81.66(10) . .
O4' Ni5 Te3 128.6(6) 2_666 .
O9 Ni5 Te3 38.91(9) . .
O5 Ni5 Te3 90.9(4) . .
O15 Ni6 O15' 97.1(3) 2_656 1_655
O15 Ni6 O11 88.4(3) 2_656 1_545
O15' Ni6 O11 110.8(3) 1_655 1_545
O15 Ni6 O6 87.0(3) 2_656 .
O15' Ni6 O6 144.2(3) 1_655 .
O11 Ni6 O6 104.89(17) 1_545 .
O15 Ni6 O7 169.4(3) 2_656 1_655
O15' Ni6 O7 90.9(3) 1_655 1_655
O11 Ni6 O7 95.22(16) 1_545 1_655
O6 Ni6 O7 82.47(15) . 1_655
O15 Ni6 Te5 31.9(3) 2_656 2_655
O15' Ni6 Te5 84.0(2) 1_655 2_655
O11 Ni6 Te5 66.36(11) 1_545 2_655
O6 Ni6 Te5 114.11(12) . 2_655
O7 Ni6 Te5 157.30(13) 1_655 2_655
O15 Ni6 Ni2 126.2(2) 2_656 .
O15' Ni6 Ni2 132.4(2) 1_655 .
O11 Ni6 Ni2 91.13(12) 1_545 .
O6 Ni6 Ni2 41.54(11) . .
O7 Ni6 Ni2 43.99(10) 1_655 .
Te5 Ni6 Ni2 143.15(5) 2_655 .
O15 Ni6 Te3 140.8(3) 2_656 1_655
O15' Ni6 Te3 65.5(3) 1_655 1_655
O11 Ni6 Te3 130.11(12) 1_545 1_655
O6 Ni6 Te3 89.04(12) . 1_655
O7 Ni6 Te3 38.48(11) 1_655 1_655
Te5 Ni6 Te3 148.63(5) 2_655 1_655
Ni2 Ni6 Te3 68.12(3) . 1_655
O3 Te1 O1 98.29(16) . .
O3 Te1 O2 96.93(16) . .
O1 Te1 O2 99.29(16) . .
O5' Te2 O6 92.6(5) . 1_565
O5' Te2 O4' 94.1(6) . 1_565
O6 Te2 O4' 99.1(7) 1_565 1_565
O5' Te2 O4 110.5(6) . 1_565
O6 Te2 O4 93.8(6) 1_565 1_565
O4' Te2 O4 17.0(6) 1_565 1_565
O5' Te2 O5 17.2(4) . .
O6 Te2 O5 99.5(5) 1_565 .
O4' Te2 O5 77.5(5) 1_565 .
O4 Te2 O5 94.3(6) 1_565 .
O8 Te3 O7 102.66(17) . .
O8 Te3 O9 85.64(17) . .
O7 Te3 O9 85.86(16) . .
O8 Te3 Ni3 94.42(12) . .
O7 Te3 Ni3 42.40(11) . .
O9 Te3 Ni3 43.49(12) . .
O8 Te3 Ni6 142.00(12) . 1_455
O7 Te3 Ni6 43.47(12) . 1_455
O9 Te3 Ni6 104.28(13) . 1_455
Ni3 Te3 Ni6 71.38(4) . 1_455
O8 Te3 Ni5 38.61(11) . .
O7 Te3 Ni5 95.46(11) . .
O9 Te3 Ni5 47.06(12) . .
Ni3 Te3 Ni5 65.70(3) . .
Ni6 Te3 Ni5 136.07(3) 1_455 .
O11 Te4 O10 103.11(17) 1_455 1_565
O11 Te4 O12 86.75(16) 1_455 .
O10 Te4 O12 84.36(15) 1_565 .
O11 Te4 O13 85.17(15) 1_455 1_565
O10 Te4 O13 70.54(14) 1_565 1_565
O12 Te4 O13 151.03(15) . 1_565
O11 Te4 Ni4 41.35(11) 1_455 2_566
O10 Te4 Ni4 98.55(11) 1_565 2_566
O12 Te4 Ni4 45.57(11) . 2_566
O13 Te4 Ni4 122.82(10) 1_565 2_566
O11 Te4 Ni4 91.82(12) 1_455 1_565
O10 Te4 Ni4 40.35(11) 1_565 1_565
O12 Te4 Ni4 44.55(11) . 1_565
O13 Te4 Ni4 107.96(10) 1_565 1_565
Ni4 Te4 Ni4 65.80(2) 2_566 1_565
O15 Te5 O15' 145.7(4) 1_554 .
O15 Te5 O14 100.4(3) 1_554 .
O15' Te5 O14 108.1(3) . .
O15 Te5 O13 97.0(3) 1_554 .
O15' Te5 O13 98.2(3) . .
O14 Te5 O13 96.88(17) . .
O15 Te5 Ni6 38.4(3) 1_554 2_655
O15' Te5 Ni6 107.7(3) . 2_655
O14 Te5 Ni6 124.89(12) . 2_655
O13 Te5 Ni6 117.63(13) . 2_655
Te1 O1 Ni2 133.8(2) . 1_455
Te1 O1 Ni2 111.67(16) . 2_666
Ni2 O1 Ni2 97.11(15) 1_455 2_666
Te1 O2 Ni3 113.89(17) . 2_666
Te1 O2 Ni3 126.51(18) . .
Ni3 O2 Ni3 96.29(16) 2_666 .
Te1 O2 Ni5 119.3(2) . .
Ni3 O2 Ni5 92.15(14) 2_666 .
Ni3 O2 Ni5 101.46(15) . .
Te1 O3 Ni4 138.5(2) . .
Te1 O3 Ni1 112.82(17) . .
Ni4 O3 Ni1 102.86(16) . .
O4' O4 Te2 81(5) . 1_545
O4' O4 Ni5 116(6) . 2_666
Te2 O4 Ni5 144.2(11) 1_545 2_666
O4 O4' Te2 82(5) . 1_545
O4 O4' Ni5 51(5) . 2_666
Te2 O4' Ni5 124.2(7) 1_545 2_666
O5' O5 Te2 74(3) . .
O5' O5 Ni1 76(3) . 2_666
Te2 O5 Ni1 116.8(6) . 2_666
O5' O5 Ni4 77(3) . 2_666
Te2 O5 Ni4 124.0(7) . 2_666
Ni1 O5 Ni4 100.6(7) 2_666 2_666
O5' O5 Ni5 173(3) . .
Te2 O5 Ni5 112.1(6) . .
Ni1 O5 Ni5 103.0(5) 2_666 .
Ni4 O5 Ni5 97.0(5) 2_666 .
O5 O5' Te2 89(3) . .
O5 O5' Ni1 88(3) . 2_666
Te2 O5' Ni1 123.5(8) . 2_666
O5 O5' Ni4 88(3) . 2_666
Te2 O5' Ni4 131.7(8) . 2_666
Ni1 O5' Ni4 104.6(7) 2_666 2_666
Te2 O6 Ni2 138.9(2) 1_545 .
Te2 O6 Ni6 112.6(2) 1_545 .
Ni2 O6 Ni6 94.21(17) . .
Te3 O7 Ni3 99.21(15) . .
Te3 O7 Ni2 115.7(2) . 1_455
Ni3 O7 Ni2 132.49(19) . 1_455
Te3 O7 Ni6 98.05(17) . 1_455
Ni3 O7 Ni6 115.72(19) . 1_455
Ni2 O7 Ni6 91.27(14) 1_455 1_455
Te3 O8 Ni5 104.95(18) . .
Te3 O8 Ni2 114.36(17) . 2_666
Ni5 O8 Ni2 127.30(19) . 2_666
Te3 O9 Ni1 123.37(19) . 2_666
Te3 O9 Ni3 97.06(15) . .
Ni1 O9 Ni3 127.8(2) 2_666 .
Te3 O9 Ni5 94.04(17) . .
Ni1 O9 Ni5 108.61(17) 2_666 .
Ni3 O9 Ni5 98.85(15) . .
Te4 O10 Ni4 101.45(16) 1_545 .
Te4 O10 Ni3 111.55(18) 1_545 .
Ni4 O10 Ni3 126.2(2) . .
Te4 O10 Ni5 111.53(19) 1_545 2_666
Ni4 O10 Ni5 110.72(18) . 2_666
Ni3 O10 Ni5 95.45(14) . 2_666
Te4 O11 Ni4 101.24(18) 1_655 2_666
Te4 O11 Ni6 133.2(2) 1_655 1_565
Ni4 O11 Ni6 113.5(2) 2_666 1_565
Te4 O12 Ni2 121.56(19) . 2_666
Te4 O12 Ni4 93.97(15) . 2_566
Ni2 O12 Ni4 122.18(16) 2_666 2_566
Te4 O12 Ni4 96.09(15) . 1_565
Ni2 O12 Ni4 117.62(17) 2_666 1_565
Ni4 O12 Ni4 99.71(16) 2_566 1_565
Te5 O13 Ni3 124.4(2) . .
Te5 O13 Te4 124.58(19) . 1_545
Ni3 O13 Te4 94.04(14) . 1_545
Te5 O14 Ni1 129.8(2) . 2_666
Te5 O14 Ni1 123.97(19) . 1_554
Ni1 O14 Ni1 102.24(16) 2_666 1_554
Te5 O15 Ni6 109.8(4) 1_556 2_656
Te5 O15' Ni6 120.7(4) . 1_455
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ni1 O5' 2.035(15) 2_666
Ni1 O9 2.046(4) 2_666
Ni1 O14 2.059(4) 2_666
Ni1 O14 2.072(4) 1_556
Ni1 O3 2.094(4) .
Ni1 O5 2.095(15) 2_666
Ni1 Cl1 2.4815(18) .
Ni2 O6 1.984(4) .
Ni2 O1 2.021(4) 1_655
Ni2 O8 2.054(4) 2_666
Ni2 O12 2.060(4) 2_666
Ni2 O7 2.072(4) 1_655
Ni2 O1 2.308(4) 2_666
Ni2 Ni6 2.9832(17) .
Ni3 O13 2.060(4) .
Ni3 O7 2.063(4) .
Ni3 O10 2.064(4) .
Ni3 O2 2.087(4) 2_666
Ni3 O9 2.094(4) .
Ni3 O2 2.104(4) .
Ni3 Te3 3.0202(10) .
Ni4 O11 2.029(4) 2_666
Ni4 O10 2.030(4) .
Ni4 O3 2.074(4) .
Ni4 O5' 2.083(15) 2_666
Ni4 O5 2.140(15) 2_666
Ni4 O12 2.156(4) 2_566
Ni4 O12 2.168(4) 1_545
Ni4 Te4 3.0125(11) 2_566
Ni4 Te4 3.0723(10) 1_545
Ni5 O4 1.91(2) 2_666
Ni5 O8 1.984(4) .
Ni5 O10 2.075(4) 2_666
Ni5 O2 2.164(4) .
Ni5 O4' 2.202(19) 2_666
Ni5 O9 2.254(4) .
Ni5 O5 2.366(9) .
Ni5 Te3 3.0714(10) .
Ni6 O15 1.951(8) 2_656
Ni6 O15' 2.009(8) 1_655
Ni6 O11 2.042(4) 1_545
Ni6 O6 2.087(5) .
Ni6 O7 2.100(4) 1_655
Ni6 Te5 2.9585(16) 2_655
Ni6 Te3 3.0230(16) 1_655
Te1 O3 1.848(4) .
Te1 O1 1.882(4) .
Te1 O2 1.926(4) .
Te2 O5' 1.817(16) .
Te2 O6 1.842(4) 1_565
Te2 O4' 1.84(3) 1_565
Te2 O4 1.85(2) 1_565
Te2 O5 1.889(15) .
Te3 O8 1.888(4) .
Te3 O7 1.900(4) .
Te3 O9 1.934(4) .
Te3 Ni6 3.0230(16) 1_455
Te4 O11 1.866(4) 1_455
Te4 O10 1.938(4) 1_565
Te4 O12 1.960(4) .
Te4 O13 2.450(4) 1_565
Te4 Ni4 3.0125(11) 2_566
Te4 Ni4 3.0723(10) 1_565
Te5 O15 1.659(9) 1_554
Te5 O15' 1.771(8) .
Te5 O14 1.851(4) .
Te5 O13 1.877(4) .
Te5 Ni6 2.9585(16) 2_655
O1 Ni2 2.021(4) 1_455
O1 Ni2 2.308(4) 2_666
O2 Ni3 2.087(4) 2_666
O4 O4' 0.54(2) .
O4 Te2 1.85(2) 1_545
O4 Ni5 1.91(2) 2_666
O4' Te2 1.84(3) 1_545
O4' Ni5 2.202(19) 2_666
O5 O5' 0.558(12) .
O5 Ni1 2.095(15) 2_666
O5 Ni4 2.140(15) 2_666
O5' Ni1 2.035(15) 2_666
O5' Ni4 2.083(15) 2_666
O6 Te2 1.842(4) 1_545
O7 Ni2 2.072(4) 1_455
O7 Ni6 2.100(4) 1_455
O8 Ni2 2.054(4) 2_666
O9 Ni1 2.046(4) 2_666
O10 Te4 1.938(4) 1_545
O10 Ni5 2.075(4) 2_666
O11 Te4 1.866(4) 1_655
O11 Ni4 2.029(4) 2_666
O11 Ni6 2.042(4) 1_565
O12 Ni2 2.060(4) 2_666
O12 Ni4 2.156(4) 2_566
O12 Ni4 2.168(4) 1_565
O13 Te4 2.450(4) 1_545
O14 Ni1 2.059(4) 2_666
O14 Ni1 2.072(4) 1_554
O15 Te5 1.659(9) 1_556
O15 Ni6 1.951(7) 2_656
O15' Ni6 2.009(8) 1_455
