#------------------------------------------------------------------------------
#$Date: 2016-03-23 20:53:20 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179429 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/26/4332636.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided the Crystal Eye server at
# http://wwmm.ch.cam.ac.uk/crystaleye/, created by Nick Day at the
# Peter Murray-Rust laboratory.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_4332636
loop_
_publ_author_name
'Li, Lei'
'Sarjeant, Amy A. Narducci'
'Karlin, Kenneth D.'
_publ_section_title
;
 Reactivity Study of a Hydroperoxodicopper(II) Complex: 
 Hydroxylation, Dehydrogenation, and Ligand Cross-Link Reactions
;
_journal_issue                   18
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              7160
_journal_page_last               7172
_journal_paper_doi               10.1021/ic060598x
_journal_volume                  45
_journal_year                    2006
_chemical_formula_moiety         'C68 H72 Cu4 N12 O4, 6(C2 H3 N), 4(Cl O4)'
_chemical_formula_sum            'C80 H90 Cl4 Cu4 N18 O20'
_chemical_formula_weight         2019.66
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date
;
'Wed Mar 22 17:37:08 2006'
;
_audit_creation_method           SHELXL-97
_cell_angle_alpha                106.197(8)
_cell_angle_beta                 109.379(9)
_cell_angle_gamma                100.108(7)
_cell_formula_units_Z            1
_cell_length_a                   11.9993(10)
_cell_length_b                   13.4080(11)
_cell_length_c                   16.1375(17)
_cell_measurement_reflns_used    5981
_cell_measurement_temperature    110
_cell_measurement_theta_max      27.88
_cell_measurement_theta_min      3.71
_cell_volume                     2246.7(4)
_computing_cell_refinement       'Oxford Diffraction CrysAlis RED'
_computing_data_collection       'Oxford Diffraction CrysAlis CCD'
_computing_data_reduction        'Oxford Diffraction CrysAlis RED'
_computing_molecular_graphics    'Sheldrick, G.M. (2000). SHELXTL v6.10.'
_computing_publication_material  'Sheldrick, G.M. (2000). SHELXTL v6.10.'
_computing_structure_refinement  'Sheldrick, G.M. (2000). SHELXTL v6.10.'
_computing_structure_solution    'Sheldrick, G.M. (2000). SHELXTL v6.10.'
_diffrn_ambient_temperature      110
_diffrn_detector_area_resol_mean 15.9890
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_details      'see scan set'
_diffrn_measurement_device       Kappa
_diffrn_measurement_device_type  Xcalibur3
_diffrn_measurement_method       ' omega scans'
_diffrn_orient_matrix_UB_11      0.0274002664
_diffrn_orient_matrix_UB_12      0.0138970747
_diffrn_orient_matrix_UB_13      0.0496732571
_diffrn_orient_matrix_UB_21      0.0196521167
_diffrn_orient_matrix_UB_22      0.0557467175
_diffrn_orient_matrix_UB_23      0.0062139644
_diffrn_orient_matrix_UB_31      -0.0564523898
_diffrn_orient_matrix_UB_32      0.0061775923
_diffrn_orient_matrix_UB_33      0.0027518236
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Enhance (Mo) X-ray Source'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0640
_diffrn_reflns_av_sigmaI/netI    0.1056
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            21363
_diffrn_reflns_resolution_max    0.83
_diffrn_reflns_theta_full        25.35
_diffrn_reflns_theta_max         25.35
_diffrn_reflns_theta_min         3.64
_diffrn_source_current           40
_diffrn_source_power             2
_diffrn_source_voltage           50
_diffrn_standards_interval_count 1
_diffrn_standards_interval_time  50
_exptl_absorpt_coefficient_mu    1.13111
_exptl_absorpt_correction_T_max  0.92869
_exptl_absorpt_correction_T_min  0.82162
_exptl_absorpt_correction_type   analytical
_exptl_absorpt_process_details
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.29.1 (release 13-01-2006 CrysAlis171 .NET)
(compiled Jan 13 2006,17:25:00)
Analytical numeric absorption correction using a multifaceted crystal
        model based on expressions derived by R.C. Clark & J.S. Reid.
(Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
;
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    1.493
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1040
_exptl_crystal_size_max          0.13077
_exptl_crystal_size_mid          0.07446
_exptl_crystal_size_min          0.03234
_refine_diff_density_max         1.414
_refine_diff_density_min         -0.456
_refine_diff_density_rms         0.103
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.910
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     630
_refine_ls_number_reflns         8173
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.910
_refine_ls_R_factor_all          0.1068
_refine_ls_R_factor_gt           0.0523
_refine_ls_shift/su_max          0.047
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0798P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1248
_refine_ls_wR_factor_ref         0.1401
_reflns_number_gt                4756
_reflns_number_total             8173
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic060598xsup3.cif
_cod_data_source_block           x0108
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      'P-1   '
_cod_database_code               4332636
#BEGIN Tags that were not found in dictionaries:
_audit_creation_method_reference
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.29.1 (release 13-01-2006 CrysAlis171 .NET)
(compiled Jan 13 2006,17:25:00)
;
_computing_data_collection_reference
;
CrysAlis CCD, Oxford Diffraction Ltd.,
Version 1.171.29.1 (release 13-01-2006 CrysAlis171 .NET)
(compiled Jan 13 2006,17:25:00)
;
_computing_cell_refinment_reference
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.29.1 (release 13-01-2006 CrysAlis171 .NET)
(compiled Jan 13 2006,17:25:00)
;
_computing_data_reduction_reference
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.29.1 (release 13-01-2006 CrysAlis171 .NET)
(compiled Jan 13 2006,17:25:00)
;
_cell_measurement_resolution_max 0.76
#END Tags that were not found in dictionaries
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Cu1 Cu 1.17975(5) 0.60832(5) -0.03195(4) 0.02243(17) Uani 1 1 d . . .
Cu2 Cu 0.97095(5) 0.31394(5) -0.13010(4) 0.02264(17) Uani 1 1 d . . .
O1 O 1.0591(3) 0.6161(2) 0.0212(2) 0.0257(8) Uani 1 1 d . . .
H1O H 0.9982 0.6277 -0.0152 0.039 Uiso 1 1 d R . .
O2 O 1.1091(3) 0.4447(2) -0.1065(2) 0.0231(8) Uani 1 1 d . . .
N1 N 1.1180(4) 0.6792(3) -0.1369(3) 0.0240(9) Uani 1 1 d . . .
N2 N 1.3041(3) 0.5941(3) -0.0915(3) 0.0213(9) Uani 1 1 d . . .
N3 N 1.3422(4) 0.6955(3) 0.0869(3) 0.0252(10) Uani 1 1 d . . .
N4 N 0.8340(4) 0.3535(3) -0.2326(3) 0.0261(10) Uani 1 1 d . . .
N5 N 0.9998(4) 0.2411(3) -0.2468(3) 0.0234(9) Uani 1 1 d . . .
N6 N 0.9396(4) 0.1626(3) -0.1279(3) 0.0275(10) Uani 1 1 d . . .
C1 C 1.0047(5) 0.6836(4) -0.1822(4) 0.0316(13) Uani 1 1 d . . .
H1A H 0.9434 0.6669 -0.1590 0.038 Uiso 1 1 calc R . .
C2 C 0.9728(5) 0.7112(4) -0.2612(4) 0.0369(14) Uani 1 1 d . . .
H2A H 0.8907 0.7121 -0.2925 0.044 Uiso 1 1 calc R . .
C3 C 1.0621(5) 0.7375(4) -0.2943(4) 0.0368(14) Uani 1 1 d . . .
H3A H 1.0431 0.7578 -0.3482 0.044 Uiso 1 1 calc R . .
C4 C 1.1806(5) 0.7335(4) -0.2467(4) 0.0304(12) Uani 1 1 d . . .
H4A H 1.2441 0.7518 -0.2675 0.036 Uiso 1 1 calc R . .
C5 C 1.2050(4) 0.7034(4) -0.1703(4) 0.0248(11) Uani 1 1 d . . .
C6 C 1.3285(4) 0.6924(4) -0.1150(4) 0.0239(11) Uani 1 1 d . . .
H6A H 1.3786 0.6855 -0.1531 0.029 Uiso 1 1 calc R . .
H6B H 1.3747 0.7574 -0.0566 0.029 Uiso 1 1 calc R . .
C7 C 1.4125(4) 0.5861(4) -0.0191(4) 0.0263(12) Uani 1 1 d . . .
H7A H 1.4850 0.5989 -0.0355 0.032 Uiso 1 1 calc R . .
H7B H 1.3954 0.5122 -0.0167 0.032 Uiso 1 1 calc R . .
C8 C 1.4403(5) 0.6692(4) 0.0756(4) 0.0263(12) Uani 1 1 d . . .
C9 C 1.5591(5) 0.7157(4) 0.1470(4) 0.0348(13) Uani 1 1 d . . .
H9A H 1.6272 0.6949 0.1378 0.042 Uiso 1 1 calc R . .
C10 C 1.5761(5) 0.7918(4) 0.2305(4) 0.0376(14) Uani 1 1 d . . .
H10A H 1.6558 0.8229 0.2807 0.045 Uiso 1 1 calc R . .
C11 C 1.4773(5) 0.8227(4) 0.2411(4) 0.0334(13) Uani 1 1 d . . .
H11A H 1.4881 0.8782 0.2972 0.040 Uiso 1 1 calc R . .
C12 C 1.3611(5) 0.7715(4) 0.1683(4) 0.0293(12) Uani 1 1 d . . .
H12A H 1.2921 0.7911 0.1766 0.035 Uiso 1 1 calc R . .
C13 C 1.2478(4) 0.4946(4) -0.1752(4) 0.0242(11) Uani 1 1 d . . .
C14 C 1.2859(4) 0.4717(4) -0.2473(4) 0.0261(12) Uani 1 1 d . . .
H14A H 1.3535 0.5237 -0.2442 0.031 Uiso 1 1 calc R . .
C15 C 1.2294(4) 0.3749(4) -0.3254(3) 0.0258(12) Uani 1 1 d . . .
C16 C 1.1356(4) 0.2980(4) -0.3242(4) 0.0259(11) Uani 1 1 d . . .
H16A H 1.0970 0.2296 -0.3746 0.031 Uiso 1 1 calc R . .
C17 C 1.0981(4) 0.3204(4) -0.2505(4) 0.0237(11) Uani 1 1 d . . .
C18 C 1.1487(4) 0.4186(4) -0.1758(3) 0.0199(11) Uani 1 1 d . . .
C19 C 1.2626(5) 0.3580(4) -0.4117(4) 0.0324(13) Uani 1 1 d . . .
C20 C 1.2107(5) 0.2396(5) -0.4801(4) 0.0388(14) Uani 1 1 d . . .
H20A H 1.1205 0.2164 -0.5020 0.058 Uiso 1 1 calc R . .
H20B H 1.2457 0.1932 -0.4479 0.058 Uiso 1 1 calc R . .
H20C H 1.2328 0.2334 -0.5342 0.058 Uiso 1 1 calc R . .
C21 C 1.4049(5) 0.3932(5) -0.3798(4) 0.0454(16) Uani 1 1 d . . .
H21A H 1.4390 0.4705 -0.3402 0.068 Uiso 1 1 calc R . .
H21B H 1.4247 0.3807 -0.4354 0.068 Uiso 1 1 calc R . .
H21C H 1.4410 0.3504 -0.3438 0.068 Uiso 1 1 calc R . .
C22 C 1.2081(6) 0.4285(5) -0.4640(4) 0.0495(17) Uani 1 1 d . . .
H22A H 1.1190 0.4106 -0.4800 0.074 Uiso 1 1 calc R . .
H22B H 1.2227 0.4147 -0.5218 0.074 Uiso 1 1 calc R . .
H22C H 1.2477 0.5053 -0.4236 0.074 Uiso 1 1 calc R . .
C23 C 0.7822(5) 0.4339(4) -0.2189(4) 0.0322(13) Uani 1 1 d . . .
H23A H 0.7872 0.4694 -0.1574 0.039 Uiso 1 1 calc R . .
C24 C 0.7217(5) 0.4677(5) -0.2904(5) 0.0396(15) Uani 1 1 d . . .
H24A H 0.6851 0.5245 -0.2782 0.047 Uiso 1 1 calc R . .
C25 C 0.7154(5) 0.4180(5) -0.3786(5) 0.0426(16) Uani 1 1 d . . .
H25A H 0.6752 0.4404 -0.4286 0.051 Uiso 1 1 calc R . .
C26 C 0.7678(5) 0.3350(5) -0.3945(4) 0.0403(15) Uani 1 1 d . . .
H26A H 0.7649 0.3001 -0.4555 0.048 Uiso 1 1 calc R . .
C27 C 0.8253(4) 0.3026(4) -0.3205(4) 0.0276(12) Uani 1 1 d . . .
C28 C 0.8802(5) 0.2101(4) -0.3297(4) 0.0289(12) Uani 1 1 d . . .
H28A H 0.8221 0.1452 -0.3333 0.035 Uiso 1 1 calc R . .
H28B H 0.8945 0.1919 -0.3884 0.035 Uiso 1 1 calc R . .
C29 C 1.0368(5) 0.1425(4) -0.2382(4) 0.0299(12) Uani 1 1 d . . .
H29A H 1.1276 0.1625 -0.2040 0.036 Uiso 1 1 calc R . .
H29B H 1.0132 0.0883 -0.3018 0.036 Uiso 1 1 calc R . .
C30 C 0.9741(5) 0.0939(4) -0.1860(4) 0.0304(12) Uani 1 1 d . . .
C31 C 0.9581(5) -0.0133(4) -0.1945(4) 0.0397(14) Uani 1 1 d . . .
H31A H 0.9830 -0.0600 -0.2365 0.048 Uiso 1 1 calc R . .
C32 C 0.9056(6) -0.0518(5) -0.1412(4) 0.0455(16) Uani 1 1 d . . .
H32A H 0.8947 -0.1252 -0.1453 0.055 Uiso 1 1 calc R . .
C33 C 0.8691(6) 0.0174(4) -0.0817(4) 0.0438(15) Uani 1 1 d . . .
H33A H 0.8320 -0.0077 -0.0447 0.053 Uiso 1 1 calc R . .
C34 C 0.8874(5) 0.1237(4) -0.0768(4) 0.0335(13) Uani 1 1 d . . .
H34A H 0.8621 0.1714 -0.0358 0.040 Uiso 1 1 calc R . .
Cl1 Cl 0.78090(13) 1.07537(11) 0.39514(10) 0.0383(3) Uani 1 1 d . . .
O1S O 0.8729(4) 1.1760(4) 0.4563(3) 0.0678(15) Uani 1 1 d . . .
O2S O 0.6805(4) 1.0968(4) 0.3311(3) 0.0660(13) Uani 1 1 d . . .
O3S O 0.7314(5) 1.0219(4) 0.4458(3) 0.0674(14) Uani 1 1 d . . .
O4S O 0.8276(5) 1.0090(4) 0.3395(4) 0.0788(16) Uani 1 1 d . . .
Cl2 Cl 1.28361(13) 0.30356(11) 0.05900(10) 0.0357(3) Uani 1 1 d . . .
O5S O 1.2559(6) 0.2933(5) -0.0344(4) 0.0885(18) Uani 1 1 d . A .
O6S O 1.3496(12) 0.4198(8) 0.1000(10) 0.083(4) Uani 0.50 1 d P A 1
O7S O 1.2064(10) 0.2770(9) 0.0981(8) 0.074(3) Uani 0.50 1 d P A 1
O8S O 1.3800(10) 0.2504(9) 0.0743(8) 0.076(3) Uani 0.50 1 d P A 1
O6T O 1.3971(7) 0.3680(8) 0.1319(6) 0.041(2) Uani 0.50 1 d P A 2
O7T O 1.1825(7) 0.3441(9) 0.0750(6) 0.051(2) Uani 0.50 1 d P A 2
O8T O 1.2560(12) 0.1956(7) 0.0541(7) 0.077(3) Uani 0.50 1 d P A 2
N1S N 0.6694(5) 0.0078(4) -0.3258(4) 0.0533(14) Uani 1 1 d . . .
C1S C 0.6062(6) -0.0521(5) -0.3992(5) 0.0461(16) Uani 1 1 d . . .
C2S C 0.5206(7) -0.1304(6) -0.4908(5) 0.068(2) Uani 1 1 d . . .
H2SA H 0.5590 -0.1332 -0.5361 0.102 Uiso 1 1 calc R . .
H2SB H 0.4453 -0.1087 -0.5119 0.102 Uiso 1 1 calc R . .
H2SC H 0.4995 -0.2023 -0.4866 0.102 Uiso 1 1 calc R . .
N3S N 1.3606(8) 0.3105(6) 0.3547(6) 0.091(2) Uani 1 1 d . . .
C5S C 1.4029(8) 0.2583(8) 0.3107(7) 0.075(2) Uani 1 1 d . . .
C6S C 1.4506(8) 0.1849(8) 0.2533(7) 0.097(3) Uani 1 1 d . . .
H6SA H 1.5317 0.1840 0.2938 0.146 Uiso 1 1 calc R . .
H6SB H 1.4586 0.2109 0.2039 0.146 Uiso 1 1 calc R . .
H6SC H 1.3930 0.1112 0.2242 0.146 Uiso 1 1 calc R . .
N2S N 1.3493(9) -0.0590(7) 0.0082(8) 0.050(2) Uani 0.64 1 d P B 1
C3S C 1.3461(9) -0.0147(8) -0.0411(8) 0.041(2) Uani 0.64 1 d P B 1
C4S C 1.346(3) 0.041(3) -0.102(2) 0.074(11) Uani 0.64 1 d P B 1
H4SA H 1.3429 0.1147 -0.0731 0.111 Uiso 0.64 1 calc PR B 1
H4SB H 1.2729 0.0027 -0.1614 0.111 Uiso 0.64 1 calc PR B 1
H4SC H 1.4209 0.0447 -0.1139 0.111 Uiso 0.64 1 calc PR B 1
N2S' N 1.570(2) 0.0530(13) -0.0734(13) 0.058(5) Uani 0.36 1 d P C 2
C3S' C 1.463(3) 0.0396(15) -0.0916(15) 0.060(6) Uani 0.36 1 d P C 2
C4S' C 1.330(4) 0.034(4) -0.113(4) 0.033(11) Uani 0.36 1 d P C 2
H4SD H 1.3231 0.1080 -0.0927 0.050 Uiso 0.36 1 calc PR C 2
H4SE H 1.2987 -0.0069 -0.0800 0.050 Uiso 0.36 1 calc PR C 2
H4SF H 1.2812 -0.0021 -0.1814 0.050 Uiso 0.36 1 calc PR C 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
0.00 -1.00 20.00 0.0323
-1.00 19.00 -6.00 0.0450
1.00 -19.00 6.00 0.0544
0.00 1.00 -20.00 0.0370
-16.00 5.00 11.00 0.1156
-13.00 -9.00 12.00 0.1153
17.00 -5.00 -8.00 0.1308
10.00 -17.00 0.00 0.0653
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Cu1 N2 177.83(15) . .
O1 Cu1 O2 95.16(13) . .
N2 Cu1 O2 82.69(14) . .
O1 Cu1 N3 101.04(15) . .
N2 Cu1 N3 80.63(16) . .
O2 Cu1 N3 129.81(14) . .
O1 Cu1 N1 101.28(14) . .
N2 Cu1 N1 79.01(15) . .
O2 Cu1 N1 103.83(14) . .
N3 Cu1 N1 118.67(15) . .
O1 Cu2 N6 98.35(15) 2_765 .
O1 Cu2 N5 178.76(16) 2_765 .
N6 Cu2 N5 82.30(16) . .
O1 Cu2 O2 94.77(13) 2_765 .
N6 Cu2 O2 142.16(15) . .
N5 Cu2 O2 85.32(14) . .
O1 Cu2 N4 97.93(15) 2_765 .
N6 Cu2 N4 120.22(16) . .
N5 Cu2 N4 80.83(16) . .
O2 Cu2 N4 92.61(13) . .
Cu1 O1 Cu2 145.50(19) . 2_765
Cu1 O1 H1O 109.2 . .
Cu2 O1 H1O 92.0 2_765 .
C18 O2 Cu2 108.0(3) . .
C18 O2 Cu1 109.6(3) . .
Cu2 O2 Cu1 140.64(17) . .
C1 N1 C5 118.2(4) . .
C1 N1 Cu1 129.2(3) . .
C5 N1 Cu1 111.5(3) . .
C13 N2 C7 111.3(4) . .
C13 N2 C6 112.3(4) . .
C7 N2 C6 114.1(4) . .
C13 N2 Cu1 107.5(3) . .
C7 N2 Cu1 105.1(3) . .
C6 N2 Cu1 106.0(3) . .
C12 N3 C8 118.2(4) . .
C12 N3 Cu1 130.1(4) . .
C8 N3 Cu1 111.7(3) . .
C23 N4 C27 118.2(4) . .
C23 N4 Cu2 129.4(4) . .
C27 N4 Cu2 110.6(3) . .
C17 N5 C28 111.8(4) . .
C17 N5 C29 111.6(4) . .
C28 N5 C29 110.7(4) . .
C17 N5 Cu2 107.6(3) . .
C28 N5 Cu2 106.9(3) . .
C29 N5 Cu2 108.1(3) . .
C30 N6 C34 117.9(4) . .
C30 N6 Cu2 114.6(3) . .
C34 N6 Cu2 127.5(3) . .
N1 C1 C2 122.8(5) . .
N1 C1 H1A 118.6 . .
C2 C1 H1A 118.6 . .
C1 C2 C3 119.0(5) . .
C1 C2 H2A 120.5 . .
C3 C2 H2A 120.5 . .
C2 C3 C4 118.2(5) . .
C2 C3 H3A 120.9 . .
C4 C3 H3A 120.9 . .
C5 C4 C3 119.7(5) . .
C5 C4 H4A 120.2 . .
C3 C4 H4A 120.2 . .
N1 C5 C4 122.1(5) . .
N1 C5 C6 113.4(4) . .
C4 C5 C6 124.5(4) . .
N2 C6 C5 107.7(4) . .
N2 C6 H6A 110.2 . .
C5 C6 H6A 110.2 . .
N2 C6 H6B 110.2 . .
C5 C6 H6B 110.2 . .
H6A C6 H6B 108.5 . .
N2 C7 C8 109.6(4) . .
N2 C7 H7A 109.8 . .
C8 C7 H7A 109.8 . .
N2 C7 H7B 109.8 . .
C8 C7 H7B 109.8 . .
H7A C7 H7B 108.2 . .
N3 C8 C9 121.9(5) . .
N3 C8 C7 115.2(4) . .
C9 C8 C7 122.9(5) . .
C10 C9 C8 118.9(5) . .
C10 C9 H9A 120.5 . .
C8 C9 H9A 120.5 . .
C11 C10 C9 119.5(5) . .
C11 C10 H10A 120.3 . .
C9 C10 H10A 120.3 . .
C10 C11 C12 118.8(5) . .
C10 C11 H11A 120.6 . .
C12 C11 H11A 120.6 . .
N3 C12 C11 122.6(5) . .
N3 C12 H12A 118.7 . .
C11 C12 H12A 118.7 . .
C14 C13 C18 120.7(5) . .
C14 C13 N2 124.8(4) . .
C18 C13 N2 114.4(4) . .
C13 C14 C15 122.6(4) . .
C13 C14 H14A 118.7 . .
C15 C14 H14A 118.7 . .
C14 C15 C16 116.7(4) . .
C14 C15 C19 121.2(4) . .
C16 C15 C19 121.9(5) . .
C17 C16 C15 120.7(5) . .
C17 C16 H16A 119.6 . .
C15 C16 H16A 119.6 . .
C18 C17 C16 122.7(4) . .
C18 C17 N5 115.2(4) . .
C16 C17 N5 122.2(4) . .
O2 C18 C17 123.8(4) . .
O2 C18 C13 119.8(4) . .
C17 C18 C13 116.4(4) . .
C22 C19 C20 108.4(5) . .
C22 C19 C15 108.1(4) . .
C20 C19 C15 112.6(4) . .
C22 C19 C21 109.0(5) . .
C20 C19 C21 108.3(4) . .
C15 C19 C21 110.3(4) . .
C19 C20 H20A 109.5 . .
C19 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
C19 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
C19 C21 H21A 109.5 . .
C19 C21 H21B 109.5 . .
H21A C21 H21B 109.5 . .
C19 C21 H21C 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
C19 C22 H22A 109.5 . .
C19 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
C19 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
N4 C23 C24 122.9(5) . .
N4 C23 H23A 118.5 . .
C24 C23 H23A 118.5 . .
C25 C24 C23 118.8(5) . .
C25 C24 H24A 120.6 . .
C23 C24 H24A 120.6 . .
C24 C25 C26 119.4(5) . .
C24 C25 H25A 120.3 . .
C26 C25 H25A 120.3 . .
C25 C26 C27 119.4(6) . .
C25 C26 H26A 120.3 . .
C27 C26 H26A 120.3 . .
N4 C27 C26 121.2(5) . .
N4 C27 C28 114.3(4) . .
C26 C27 C28 124.5(5) . .
N5 C28 C27 109.7(4) . .
N5 C28 H28A 109.7 . .
C27 C28 H28A 109.7 . .
N5 C28 H28B 109.7 . .
C27 C28 H28B 109.7 . .
H28A C28 H28B 108.2 . .
N5 C29 C30 110.0(4) . .
N5 C29 H29A 109.7 . .
C30 C29 H29A 109.7 . .
N5 C29 H29B 109.7 . .
C30 C29 H29B 109.7 . .
H29A C29 H29B 108.2 . .
N6 C30 C31 122.5(5) . .
N6 C30 C29 115.8(4) . .
C31 C30 C29 121.7(5) . .
C32 C31 C30 119.0(5) . .
C32 C31 H31A 120.5 . .
C30 C31 H31A 120.5 . .
C31 C32 C33 119.3(5) . .
C31 C32 H32A 120.4 . .
C33 C32 H32A 120.4 . .
C32 C33 C34 118.8(5) . .
C32 C33 H33A 120.6 . .
C34 C33 H33A 120.6 . .
N6 C34 C33 122.5(5) . .
N6 C34 H34A 118.7 . .
C33 C34 H34A 118.7 . .
O4S Cl1 O1S 110.5(3) . .
O4S Cl1 O3S 112.2(3) . .
O1S Cl1 O3S 111.7(3) . .
O4S Cl1 O2S 106.4(3) . .
O1S Cl1 O2S 108.6(3) . .
O3S Cl1 O2S 107.2(3) . .
O7S Cl2 O5S 128.5(6) . .
O7S Cl2 O6T 107.5(6) . .
O5S Cl2 O6T 122.5(4) . .
O7S Cl2 O8T 64.4(6) . .
O5S Cl2 O8T 103.4(5) . .
O6T Cl2 O8T 112.3(7) . .
O7S Cl2 O8S 111.9(7) . .
O5S Cl2 O8S 100.2(5) . .
O6T Cl2 O8S 65.0(6) . .
O8T Cl2 O8S 59.8(6) . .
O7S Cl2 O6S 112.3(6) . .
O5S Cl2 O6S 96.1(6) . .
O6T Cl2 O6S 45.3(6) . .
O8T Cl2 O6S 156.9(8) . .
O8S Cl2 O6S 104.8(7) . .
O7S Cl2 O7T 46.2(5) . .
O5S Cl2 O7T 101.1(4) . .
O6T Cl2 O7T 110.0(5) . .
O8T Cl2 O7T 105.9(7) . .
O8S Cl2 O7T 156.8(6) . .
O6S Cl2 O7T 82.0(6) . .
N1S C1S C2S 176.8(7) . .
C1S C2S H2SA 109.5 . .
C1S C2S H2SB 109.5 . .
H2SA C2S H2SB 109.5 . .
C1S C2S H2SC 109.5 . .
H2SA C2S H2SC 109.5 . .
H2SB C2S H2SC 109.5 . .
N3S C5S C6S 176.2(9) . .
C5S C6S H6SA 109.5 . .
C5S C6S H6SB 109.5 . .
H6SA C6S H6SB 109.5 . .
C5S C6S H6SC 109.5 . .
H6SA C6S H6SC 109.5 . .
H6SB C6S H6SC 109.5 . .
N2S C3S C4S 178.4(17) . .
N2S' C3S' C4S' 174(2) . .
C3S' C4S' H4SD 109.4 . .
C3S' C4S' H4SE 109.4 . .
H4SD C4S' H4SE 109.5 . .
C3S' C4S' H4SF 109.6 . .
H4SD C4S' H4SF 109.5 . .
H4SE C4S' H4SF 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Cu1 O1 1.915(3) .
Cu1 N2 2.034(4) .
Cu1 O2 2.043(3) .
Cu1 N3 2.077(4) .
Cu1 N1 2.152(4) .
Cu2 O1 1.928(3) 2_765
Cu2 N6 2.010(4) .
Cu2 N5 2.035(4) .
Cu2 O2 2.039(3) .
Cu2 N4 2.170(4) .
O1 Cu2 1.928(3) 2_765
O1 H1O 0.8417 .
O2 C18 1.339(5) .
N1 C1 1.334(6) .
N1 C5 1.356(6) .
N2 C13 1.460(6) .
N2 C7 1.477(6) .
N2 C6 1.478(5) .
N3 C12 1.338(6) .
N3 C8 1.341(6) .
N4 C23 1.337(6) .
N4 C27 1.352(6) .
N5 C17 1.472(6) .
N5 C28 1.493(6) .
N5 C29 1.495(6) .
N6 C30 1.345(6) .
N6 C34 1.346(6) .
C1 C2 1.378(7) .
C1 H1A 0.9500 .
C2 C3 1.382(8) .
C2 H2A 0.9500 .
C3 C4 1.393(7) .
C3 H3A 0.9500 .
C4 C5 1.360(7) .
C4 H4A 0.9500 .
C5 C6 1.512(7) .
C6 H6A 0.9900 .
C6 H6B 0.9900 .
C7 C8 1.506(7) .
C7 H7A 0.9900 .
C7 H7B 0.9900 .
C8 C9 1.395(7) .
C9 C10 1.371(8) .
C9 H9A 0.9500 .
C10 C11 1.369(8) .
C10 H10A 0.9500 .
C11 C12 1.386(7) .
C11 H11A 0.9500 .
C12 H12A 0.9500 .
C13 C14 1.364(7) .
C13 C18 1.419(6) .
C14 C15 1.395(7) .
C14 H14A 0.9500 .
C15 C16 1.396(7) .
C15 C19 1.539(7) .
C16 C17 1.383(7) .
C16 H16A 0.9500 .
C17 C18 1.379(7) .
C19 C22 1.525(8) .
C19 C20 1.532(7) .
C19 C21 1.550(7) .
C20 H20A 0.9800 .
C20 H20B 0.9800 .
C20 H20C 0.9800 .
C21 H21A 0.9800 .
C21 H21B 0.9800 .
C21 H21C 0.9800 .
C22 H22A 0.9800 .
C22 H22B 0.9800 .
C22 H22C 0.9800 .
C23 C24 1.384(7) .
C23 H23A 0.9500 .
C24 C25 1.362(8) .
C24 H24A 0.9500 .
C25 C26 1.376(8) .
C25 H25A 0.9500 .
C26 C27 1.393(7) .
C26 H26A 0.9500 .
C27 C28 1.497(7) .
C28 H28A 0.9900 .
C28 H28B 0.9900 .
C29 C30 1.501(7) .
C29 H29A 0.9900 .
C29 H29B 0.9900 .
C30 C31 1.378(7) .
C31 C32 1.377(8) .
C31 H31A 0.9500 .
C32 C33 1.378(8) .
C32 H32A 0.9500 .
C33 C34 1.380(7) .
C33 H33A 0.9500 .
C34 H34A 0.9500 .
Cl1 O4S 1.405(5) .
Cl1 O1S 1.422(4) .
Cl1 O3S 1.427(4) .
Cl1 O2S 1.437(5) .
Cl2 O7S 1.335(9) .
Cl2 O5S 1.392(5) .
Cl2 O6T 1.394(8) .
Cl2 O8T 1.400(8) .
Cl2 O8S 1.451(9) .
Cl2 O6S 1.462(9) .
Cl2 O7T 1.482(8) .
N1S C1S 1.132(8) .
C1S C2S 1.446(10) .
C2S H2SA 0.9800 .
C2S H2SB 0.9800 .
C2S H2SC 0.9800 .
N3S C5S 1.157(10) .
C5S C6S 1.481(12) .
C6S H6SA 0.9800 .
C6S H6SB 0.9800 .
C6S H6SC 0.9800 .
N2S C3S 1.112(12) .
C3S C4S 1.39(3) .
C4S H4SA 0.9800 .
C4S H4SB 0.9800 .
C4S H4SC 0.9800 .
N2S' C3S' 1.18(3) .
C3S' C4S' 1.50(6) .
C4S' H4SD 0.9800 .
C4S' H4SE 0.9800 .
C4S' H4SF 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N2 Cu1 O1 Cu2 153(4) . 2_765
O2 Cu1 O1 Cu2 145.5(3) . 2_765
N3 Cu1 O1 Cu2 13.3(3) . 2_765
N1 Cu1 O1 Cu2 -109.3(3) . 2_765
O1 Cu2 O2 C18 -179.2(3) 2_765 .
N6 Cu2 O2 C18 70.6(4) . .
N5 Cu2 O2 C18 -0.5(3) . .
N4 Cu2 O2 C18 -81.0(3) . .
O1 Cu2 O2 Cu1 -17.3(3) 2_765 .
N6 Cu2 O2 Cu1 -127.5(3) . .
N5 Cu2 O2 Cu1 161.5(3) . .
N4 Cu2 O2 Cu1 80.9(3) . .
O1 Cu1 O2 C18 160.0(3) . .
N2 Cu1 O2 C18 -19.7(3) . .
N3 Cu1 O2 C18 -91.0(3) . .
N1 Cu1 O2 C18 57.0(3) . .
O1 Cu1 O2 Cu2 -1.8(3) . .
N2 Cu1 O2 Cu2 178.5(3) . .
N3 Cu1 O2 Cu2 107.2(3) . .
N1 Cu1 O2 Cu2 -104.7(3) . .
O1 Cu1 N1 C1 -26.0(5) . .
N2 Cu1 N1 C1 151.8(5) . .
O2 Cu1 N1 C1 72.3(4) . .
N3 Cu1 N1 C1 -135.4(4) . .
O1 Cu1 N1 C5 166.9(3) . .
N2 Cu1 N1 C5 -15.3(3) . .
O2 Cu1 N1 C5 -94.8(3) . .
N3 Cu1 N1 C5 57.5(4) . .
O1 Cu1 N2 C13 14(4) . .
O2 Cu1 N2 C13 21.4(3) . .
N3 Cu1 N2 C13 153.9(3) . .
N1 Cu1 N2 C13 -84.2(3) . .
O1 Cu1 N2 C7 -105(4) . .
O2 Cu1 N2 C7 -97.2(3) . .
N3 Cu1 N2 C7 35.3(3) . .
N1 Cu1 N2 C7 157.1(3) . .
O1 Cu1 N2 C6 134(4) . .
O2 Cu1 N2 C6 141.7(3) . .
N3 Cu1 N2 C6 -85.8(3) . .
N1 Cu1 N2 C6 36.0(3) . .
O1 Cu1 N3 C12 -23.8(4) . .
N2 Cu1 N3 C12 157.7(4) . .
O2 Cu1 N3 C12 -130.1(4) . .
N1 Cu1 N3 C12 85.7(4) . .
O1 Cu1 N3 C8 157.3(3) . .
N2 Cu1 N3 C8 -21.2(3) . .
O2 Cu1 N3 C8 51.0(4) . .
N1 Cu1 N3 C8 -93.2(3) . .
O1 Cu2 N4 C23 22.8(4) 2_765 .
N6 Cu2 N4 C23 127.3(4) . .
N5 Cu2 N4 C23 -157.3(4) . .
O2 Cu2 N4 C23 -72.4(4) . .
O1 Cu2 N4 C27 -173.1(3) 2_765 .
N6 Cu2 N4 C27 -68.6(3) . .
N5 Cu2 N4 C27 6.9(3) . .
O2 Cu2 N4 C27 91.7(3) . .
O1 Cu2 N5 C17 93(7) 2_765 .
N6 Cu2 N5 C17 -145.3(3) . .
O2 Cu2 N5 C17 -1.1(3) . .
N4 Cu2 N5 C17 92.3(3) . .
O1 Cu2 N5 C28 -27(7) 2_765 .
N6 Cu2 N5 C28 94.5(3) . .
O2 Cu2 N5 C28 -121.3(3) . .
N4 Cu2 N5 C28 -27.9(3) . .
O1 Cu2 N5 C29 -146(7) 2_765 .
N6 Cu2 N5 C29 -24.7(3) . .
O2 Cu2 N5 C29 119.5(3) . .
N4 Cu2 N5 C29 -147.1(3) . .
O1 Cu2 N6 C30 -168.6(4) 2_765 .
N5 Cu2 N6 C30 12.5(4) . .
O2 Cu2 N6 C30 -59.6(5) . .
N4 Cu2 N6 C30 87.1(4) . .
O1 Cu2 N6 C34 12.5(5) 2_765 .
N5 Cu2 N6 C34 -166.5(5) . .
O2 Cu2 N6 C34 121.5(4) . .
N4 Cu2 N6 C34 -91.8(5) . .
C5 N1 C1 C2 0.2(7) . .
Cu1 N1 C1 C2 -166.2(4) . .
N1 C1 C2 C3 -1.3(8) . .
C1 C2 C3 C4 0.8(8) . .
C2 C3 C4 C5 0.6(8) . .
C1 N1 C5 C4 1.3(7) . .
Cu1 N1 C5 C4 169.9(4) . .
C1 N1 C5 C6 -178.3(4) . .
Cu1 N1 C5 C6 -9.6(5) . .
C3 C4 C5 N1 -1.6(8) . .
C3 C4 C5 C6 177.9(5) . .
C13 N2 C6 C5 65.9(5) . .
C7 N2 C6 C5 -166.3(4) . .
Cu1 N2 C6 C5 -51.2(4) . .
N1 C5 C6 N2 40.3(5) . .
C4 C5 C6 N2 -139.2(5) . .
C13 N2 C7 C8 -160.2(4) . .
C6 N2 C7 C8 71.5(5) . .
Cu1 N2 C7 C8 -44.1(4) . .
C12 N3 C8 C9 2.4(7) . .
Cu1 N3 C8 C9 -178.6(4) . .
C12 N3 C8 C7 -177.9(4) . .
Cu1 N3 C8 C7 1.2(5) . .
N2 C7 C8 N3 29.3(6) . .
N2 C7 C8 C9 -151.0(4) . .
N3 C8 C9 C10 -1.2(7) . .
C7 C8 C9 C10 179.1(5) . .
C8 C9 C10 C11 -1.8(8) . .
C9 C10 C11 C12 3.4(8) . .
C8 N3 C12 C11 -0.7(7) . .
Cu1 N3 C12 C11 -179.5(3) . .
C10 C11 C12 N3 -2.2(7) . .
C7 N2 C13 C14 -84.3(6) . .
C6 N2 C13 C14 45.0(6) . .
Cu1 N2 C13 C14 161.2(4) . .
C7 N2 C13 C18 94.1(5) . .
C6 N2 C13 C18 -136.7(4) . .
Cu1 N2 C13 C18 -20.5(5) . .
C18 C13 C14 C15 1.2(7) . .
N2 C13 C14 C15 179.5(4) . .
C13 C14 C15 C16 -3.9(7) . .
C13 C14 C15 C19 171.5(5) . .
C14 C15 C16 C17 2.8(7) . .
C19 C15 C16 C17 -172.6(4) . .
C15 C16 C17 C18 0.9(8) . .
C15 C16 C17 N5 -179.8(4) . .
C28 N5 C17 C18 119.7(5) . .
C29 N5 C17 C18 -115.8(5) . .
Cu2 N5 C17 C18 2.6(5) . .
C28 N5 C17 C16 -59.7(6) . .
C29 N5 C17 C16 64.9(6) . .
Cu2 N5 C17 C16 -176.7(4) . .
Cu2 O2 C18 C17 2.4(5) . .
Cu1 O2 C18 C17 -165.6(4) . .
Cu2 O2 C18 C13 -178.3(3) . .
Cu1 O2 C18 C13 13.8(5) . .
C16 C17 C18 O2 175.8(4) . .
N5 C17 C18 O2 -3.6(7) . .
C16 C17 C18 C13 -3.6(7) . .
N5 C17 C18 C13 177.0(4) . .
C14 C13 C18 O2 -176.9(4) . .
N2 C13 C18 O2 4.7(6) . .
C14 C13 C18 C17 2.5(7) . .
N2 C13 C18 C17 -175.9(4) . .
C14 C15 C19 C22 -72.0(6) . .
C16 C15 C19 C22 103.2(6) . .
C14 C15 C19 C20 168.3(5) . .
C16 C15 C19 C20 -16.5(7) . .
C14 C15 C19 C21 47.1(6) . .
C16 C15 C19 C21 -137.7(5) . .
C27 N4 C23 C24 -0.7(7) . .
Cu2 N4 C23 C24 162.4(4) . .
N4 C23 C24 C25 -0.8(8) . .
C23 C24 C25 C26 0.8(8) . .
C24 C25 C26 C27 0.6(8) . .
C23 N4 C27 C26 2.2(7) . .
Cu2 N4 C27 C26 -163.9(4) . .
C23 N4 C27 C28 -177.0(4) . .
Cu2 N4 C27 C28 16.9(5) . .
C25 C26 C27 N4 -2.2(7) . .
C25 C26 C27 C28 176.9(5) . .
C17 N5 C28 C27 -72.5(5) . .
C29 N5 C28 C27 162.5(4) . .
Cu2 N5 C28 C27 44.9(4) . .
N4 C27 C28 N5 -41.8(5) . .
C26 C27 C28 N5 139.1(5) . .
C17 N5 C29 C30 150.6(4) . .
C28 N5 C29 C30 -84.3(5) . .
Cu2 N5 C29 C30 32.4(5) . .
C34 N6 C30 C31 -0.1(8) . .
Cu2 N6 C30 C31 -179.2(4) . .
C34 N6 C30 C29 -177.5(5) . .
Cu2 N6 C30 C29 3.5(6) . .
N5 C29 C30 N6 -24.4(6) . .
N5 C29 C30 C31 158.2(5) . .
N6 C30 C31 C32 -0.5(9) . .
C29 C30 C31 C32 176.8(5) . .
C30 C31 C32 C33 0.8(9) . .
C31 C32 C33 C34 -0.6(9) . .
C30 N6 C34 C33 0.4(8) . .
Cu2 N6 C34 C33 179.3(4) . .
C32 C33 C34 N6 0.0(9) . .
#BEGIN Loops that were not found in dictionaries:
loop_
_diffrn_scan_number
_diffrn_scan_type
_diffrn_scan_start
_diffrn_scan_end
_diffrn_scan_width
_diffrn_scan_exptime
_diffrn_scan_omega
_diffrn_scan_theta
_diffrn_scan_kappa
_diffrn_scan_phi
_diffrn_scan_omega1
_diffrn_scan_theta1
_diffrn_scan_frames
1 omega -70.80 37.20 1.00 60.00 - -35.00 81.00 350.00 0.00 0.00 108
2 omega -5.50 96.50 1.00 60.00 - 25.00 71.00 120.00 0.00 0.00 102
3 omega -5.50 96.50 1.00 60.00 - 25.00 71.00 240.00 0.00 0.00 102
4 omega -111.47 38.53 1.00 60.00 - -35.00 -9.00 0.00 0.00 0.00 150
5 omega -39.00 111.00 1.00 60.00 - 35.00 1.00 20.00 0.00 0.00 150
#END Loops that were not found in dictionaries
