#------------------------------------------------------------------------------
#$Date: 2016-03-23 20:54:45 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179430 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/27/4332780.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided the Crystal Eye server at
# http://wwmm.ch.cam.ac.uk/crystaleye/, created by Nick Day at the
# Peter Murray-Rust laboratory.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_4332780
loop_
_publ_author_name
'Gil, Belén'
'Forniés, Juan'
'Gómez, Julio'
'Lalinde, Elena'
'Martín, Antonio'
'Moreno, M. Teresa'
_publ_section_title
;
 Influence of Solvent and Weak C−H···O
 Contacts in the Self-Assembled [Pt2M4{C⋮C(3-OMe)C6H4}8] (M = Cu,
 Ag) Clusters and Their Role in the Luminescence Behavior
;
_journal_issue                   19
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              7788
_journal_page_last               7798
_journal_paper_doi               10.1021/ic0608344
_journal_volume                  45
_journal_year                    2006
_chemical_formula_sum            'C65 H41 Ag4 Cl3 Pt2'
_chemical_formula_weight         1749.99
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_conform_dict_location     ftp://ftp.iucr.org/pub/cif_core.dic
_audit_conform_dict_name         cif_core.dic
_audit_conform_dict_version      2.3
_audit_creation_date             2006-04-19T13:55:08-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                91.544(14)
_cell_angle_beta                 108.992(14)
_cell_angle_gamma                91.305(11)
_cell_formula_units_Z            2
_cell_length_a                   11.6956(13)
_cell_length_b                   15.1811(8)
_cell_length_c                   16.858(2)
_cell_measurement_temperature    150(2)
_cell_volume                     2827.6(5)
_computing_structure_refinement  'SHELXL-93 (Sheldrick, 1993)'
_computing_structure_solution    'SHELXS-86 (Sheldrick, 1990)'
_diffrn_ambient_temperature      150(2)
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.015
_diffrn_reflns_av_unetI/netI     0.0417
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            10417
_diffrn_reflns_theta_max         24.98
_diffrn_reflns_theta_min         2.24
_exptl_absorpt_coefficient_mu    6.468
_exptl_absorpt_correction_type   psi-scans
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.055
_exptl_crystal_description       block
_exptl_crystal_F_000             1652
_exptl_crystal_size_max          0.4
_exptl_crystal_size_mid          0.3
_exptl_crystal_size_min          0.3
_refine_diff_density_max         2.069
_refine_diff_density_min         -2.013
_refine_diff_density_rms         0.181
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_all   1.174
_refine_ls_goodness_of_fit_gt    1.197
_refine_ls_matrix_type           full
_refine_ls_number_parameters     697
_refine_ls_number_reflns         9878
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      1.224
_refine_ls_restrained_S_gt       1.197
_refine_ls_R_factor_all          0.0565
_refine_ls_R_factor_gt           0.0406
_refine_ls_shift/su_max          -0.001
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ2^(Fo2^)+(0.0177P)2^+32.5495P] where P=(Fo2+2Fc2)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.097
_refine_ls_wR_factor_gt          0.0871
_reflns_number_gt                8426
_reflns_number_total             9887
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic0608344sup1.cif
_cod_data_source_block           '[Pt2Ag4(CCPh)8].CHCl3'
_cod_depositor_comments
;
The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s2^(Fo2^)+(0.0177P)2^+32.5495P] where P=(Fo2^+2Fc2^)/3' was
changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s2^(Fo2^)+(0.0177P)2^+32.5495P] where P=(Fo2^+2Fc2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4332780
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
Pt1 Pt -0.18329(3) 0.98687(2) -0.99824(2) 0.01731(9) Uani 1 d .
Ag1 Ag -0.03231(6) 1.12732(5) -1.06939(4) 0.0239(2) Uani 1 d .
Ag2 Ag -0.03277(6) 0.92088(5) -1.12162(4) 0.0247(2) Uani 1 d .
C1 C -0.1560(8) 1.0482(6) -0.8857(5) 0.022(2) Uani 1 d .
C2 C -0.1437(8) 1.0818(6) -0.8166(6) 0.022(2) Uani 1 d .
C3 C -0.1476(8) 1.1202(6) -0.7385(6) 0.023(2) Uani 1 d .
C4 C -0.2406(10) 1.1761(7) -0.7387(7) 0.035(2) Uani 1 d .
H4 H -0.2996(10) 1.1904(7) -0.7901(7) 0.042 Uiso 1 calc R
C5 C -0.2462(11) 1.2104(8) -0.6636(8) 0.047(3) Uani 1 d .
H5 H -0.3103(11) 1.2477(8) -0.6634(8) 0.056 Uiso 1 calc R
C6 C -0.1605(12) 1.1914(9) -0.5893(8) 0.053(3) Uani 1 d .
H6 H -0.1651(12) 1.2163(9) -0.5382(8) 0.063 Uiso 1 calc R
C7 C -0.0682(11) 1.1368(8) -0.5880(7) 0.047(3) Uani 1 d .
H7 H -0.0097(11) 1.1228(8) -0.5362(7) 0.056 Uiso 1 calc R
C8 C -0.0615(9) 1.1020(7) -0.6641(6) 0.031(2) Uani 1 d .
H8 H 0.0034(9) 1.0655(7) -0.6641(6) 0.037 Uiso 1 calc R
C9 C -0.1613(9) 0.8691(6) -0.9420(6) 0.024(2) Uani 1 d .
C10 C -0.1479(8) 0.7995(6) -0.9087(5) 0.023(2) Uani 1 d .
C11 C -0.1483(8) 0.7170(6) -0.8677(5) 0.022(2) Uani 1 d .
C12 C -0.2174(9) 0.7075(7) -0.8142(6) 0.029(2) Uani 1 d .
H12 H -0.2655(9) 0.7544(7) -0.8064(6) 0.035 Uiso 1 calc R
C13 C -0.2157(11) 0.6299(8) -0.7729(8) 0.044(3) Uani 1 d .
H13 H -0.2619(11) 0.6236(8) -0.7362(8) 0.053 Uiso 1 calc R
C14 C -0.1465(11) 0.5615(7) -0.7850(8) 0.047(3) Uani 1 d .
H14 H -0.1453(11) 0.5081(7) -0.7566(8) 0.057 Uiso 1 calc R
C15 C -0.0796(10) 0.5704(7) -0.8378(8) 0.043(3) Uani 1 d .
H15 H -0.0327(10) 0.5229(7) -0.8460(8) 0.052 Uiso 1 calc R
C16 C -0.0798(9) 0.6482(6) -0.8796(6) 0.032(2) Uani 1 d .
H16 H -0.0331(9) 0.6539(6) -0.9160(6) 0.038 Uiso 1 calc R
C18 C -0.2306(8) 1.1737(6) -1.0876(5) 0.023(2) Uani 1 d .
C18 C -0.2130(8) 1.1038(6) -1.0549(5) 0.023(2) Uani 1 d .
C19 C -0.2756(9) 1.2558(6) -1.1258(6) 0.025(2) Uani 1 d .
C20 C -0.3686(10) 1.2966(7) -1.1040(7) 0.039(3) Uani 1 d .
H20 H -0.4004(10) 1.2704(7) -1.0647(7) 0.047 Uiso 1 calc R
C21 C -0.4131(12) 1.3735(8) -1.1392(7) 0.051(3) Uani 1 d .
H21 H -0.4768(12) 1.4000(8) -1.1248(7) 0.062 Uiso 1 calc R
C22 C -0.3670(11) 1.4141(7) -1.1960(7) 0.044(3) Uani 1 d .
H22 H -0.3982(11) 1.4681(7) -1.2197(7) 0.053 Uiso 1 calc R
C23 C -0.2746(10) 1.3741(7) -1.2173(6) 0.033(2) Uani 1 d .
H23 H -0.2426(10) 1.4009(7) -1.2562(6) 0.04 Uiso 1 calc R
C24 C -0.2287(8) 1.2953(6) -1.1821(5) 0.024(2) Uani 1 d .
H24 H -0.1652(8) 1.2685(6) -1.1966(5) 0.029 Uiso 1 calc R
C25 C -0.2190(8) 0.9263(5) -1.1107(5) 0.019(2) Uani 1 d .
C26 C -0.2452(8) 0.8968(6) -1.1833(6) 0.023(2) Uani 1 d .
C27 C -0.2991(8) 0.8665(6) -1.2693(6) 0.021(2) Uani 1 d .
C28 C -0.2326(9) 0.8248(6) -1.3133(6) 0.027(2) Uani 1 d .
H28 H -0.1500(9) 0.8126(6) -1.2857(6) 0.032 Uiso 1 calc R
C29 C -0.2867(11) 0.8010(7) -1.3974(7) 0.039(3) Uani 1 d .
H29 H -0.2403(11) 0.7742(7) -1.4278(7) 0.047 Uiso 1 calc R
C30 C -0.4057(10) 0.8157(7) -1.4367(7) 0.040(3) Uani 1 d .
H30 H -0.4418(10) 0.7980(7) -1.4941(7) 0.048 Uiso 1 calc R
C31 C -0.4744(10) 0.8556(8) -1.3950(7) 0.042(3) Uani 1 d .
H31 H -0.5573(10) 0.8660(8) -1.4233(7) 0.051 Uiso 1 calc R
C32 C -0.4216(9) 0.8808(7) -1.3111(6) 0.033(2) Uani 1 d .
H32 H -0.4690(9) 0.9080(7) -1.2816(6) 0.04 Uiso 1 calc R
Pt2 Pt 0.32526(3) 1.50822(2) -0.48366(2) 0.01912(9) Uani 1 d .
Ag3 Ag 0.53335(6) 1.37153(5) -0.43439(5) 0.0251(2) Uani 1 d .
Ag4 Ag 0.41479(7) 1.42612(5) -0.62365(4) 0.0261(2) Uani 1 d .
C33 C 0.3998(8) 1.5677(6) -0.3691(6) 0.022(2) Uani 1 d .
C34 C 0.4420(8) 1.6003(6) -0.2998(6) 0.023(2) Uani 1 d .
C35 C 0.4772(8) 1.6284(6) -0.2117(6) 0.023(2) Uani 1 d .
C36 C 0.4249(10) 1.5862(7) -0.1593(6) 0.035(2) Uani 1 d .
H36 H 0.3658(10) 1.5400(7) -0.1807(6) 0.042 Uiso 1 calc R
C37 C 0.4601(11) 1.6122(8) -0.0759(7) 0.047(3) Uani 1 d .
H37 H 0.4232(11) 1.5842(8) -0.0403(7) 0.057 Uiso 1 calc R
C38 C 0.5465(11) 1.6771(9) -0.0429(7) 0.048(3) Uani 1 d .
H38 H 0.5723(11) 1.6922(9) 0.0154(7) 0.058 Uiso 1 calc R
C39 C 0.5950(11) 1.7196(8) -0.0947(8) 0.046(3) Uani 1 d .
H39 H 0.6533(11) 1.7662(8) -0.0726(8) 0.055 Uiso 1 calc R
C40 C 0.5612(10) 1.6962(7) -0.1785(7) 0.038(3) Uani 1 d .
H40 H 0.5959(10) 1.7269(7) -0.2139(7) 0.045 Uiso 1 calc R
C41 C 0.2935(8) 1.6248(6) -0.5386(5) 0.021(2) Uani 1 d .
C42 C 0.2685(9) 1.6929(7) -0.5753(6) 0.027(2) Uani 1 d .
C43 C 0.2208(9) 1.7712(6) -0.6205(6) 0.024(2) Uani 1 d .
C44 C 0.2943(10) 1.8405(7) -0.6302(7) 0.039(3) Uani 1 d .
H44 H 0.3795(10) 1.8378(7) -0.6050(7) 0.046 Uiso 1 calc R
C45 C 0.2483(12) 1.9107(8) -0.6741(9) 0.053(3) Uani 1 d .
H45 H 0.3010(12) 1.9568(8) -0.6799(9) 0.064 Uiso 1 calc R
C46 C 0.1242(11) 1.9169(7) -0.7116(7) 0.041(3) Uani 1 d .
H46 H 0.0920(11) 1.9667(7) -0.7433(7) 0.05 Uiso 1 calc R
C47 C 0.0484(10) 1.8506(7) -0.7023(6) 0.035(3) Uani 1 d .
H47 H -0.0367(10) 1.8550(7) -0.7265(6) 0.042 Uiso 1 calc R
C48 C 0.0970(9) 1.7759(7) -0.6570(6) 0.029(2) Uani 1 d .
H48 H 0.0449(9) 1.7292(7) -0.6515(6) 0.035 Uiso 1 calc R
C49 C 0.3461(9) 1.3906(6) -0.4308(6) 0.023(2) Uani 1 d .
C50 C 0.3583(9) 1.3197(6) -0.3968(6) 0.026(2) Uani 1 d .
C51 C 0.3523(9) 1.2359(6) -0.3605(6) 0.025(2) Uani 1 d .
C52 C 0.2444(10) 1.1860(7) -0.3873(7) 0.037(3) Uani 1 d .
H52 H 0.1759(10) 1.2079(7) -0.4289(7) 0.044 Uiso 1 calc R
C53 C 0.2360(12) 1.1047(8) -0.3539(8) 0.051(3) Uani 1 d .
H53 H 0.1613(12) 1.0720(8) -0.3715(8) 0.061 Uiso 1 calc R
C54 C 0.3345(12) 1.0713(8) -0.2959(9) 0.057(4) Uani 1 d .
H54 H 0.3291(12) 1.0148(8) -0.2741(9) 0.068 Uiso 1 calc R
C55 C 0.4419(12) 1.1202(8) -0.2692(9) 0.054(4) Uani 1 d .
H55 H 0.5103(12) 1.0979(8) -0.2278(9) 0.065 Uiso 1 calc R
C56 C 0.4504(10) 1.2014(7) -0.3021(7) 0.039(3) Uani 1 d .
H56 H 0.5254(10) 1.2338(7) -0.2841(7) 0.046 Uiso 1 calc R
C57 C 0.2435(8) 1.4491(6) -0.5979(5) 0.022(2) Uani 1 d .
C58 C 0.1948(9) 1.4175(6) -0.6657(6) 0.027(2) Uani 1 d .
C59 C 0.1179(9) 1.3779(6) -0.7460(6) 0.024(2) Uani 1 d .
C60 C 0.0030(10) 1.3456(7) -0.7574(7) 0.035(2) Uani 1 d .
H60 H -0.0282(10) 1.3484(7) -0.7119(7) 0.042 Uiso 1 calc R
C61 C -0.0674(11) 1.3095(7) -0.8336(8) 0.047(3) Uani 1 d .
H61 H -0.1467(11) 1.2874(7) -0.8400(8) 0.056 Uiso 1 calc R
C62 C -0.0261(13) 1.3046(9) -0.9001(8) 0.057(4) Uani 1 d .
H62 H -0.0760(13) 1.2800(9) -0.9527(8) 0.068 Uiso 1 calc R
C63 C 0.0900(13) 1.3362(11) -0.8896(8) 0.067(4) Uani 1 d .
H63 H 0.1211(13) 1.3316(11) -0.9350(8) 0.08 Uiso 1 calc R
C64 C 0.1612(11) 1.3743(8) -0.8138(7) 0.044(3) Uani 1 d .
H64 H 0.2395(11) 1.3980(8) -0.8080(7) 0.053 Uiso 1 calc R
C65 C -0.5 1 -1 0.102(9) Uani 1 d SD
H65 H -0.4118 1.0039 -0.9933 0.123 Uiso 0.5 calc PR
Cl1 Cl -0.5174(9) 0.88641(9) -1.0063(9) 0.114(4) Uani 0.5 d PD
Cl2 Cl -0.4919(7) 1.0535(6) -0.9063(3) 0.088(3) Uani 0.5 d PD
Cl3 Cl -0.5489(8) 1.0743(7) -1.0791(6) 0.114(4) Uani 0.5 d PD
C66 C 0 1.5 -0.5 0.106(10) Uani 1 d SD
H66 H 0.0794 1.498 -0.5103 0.127 Uiso 0.5 calc PR
Cl4 Cl -0.0830(8) 1.4280(8) -0.5805(6) 0.128(5) Uani 0.5 d PD
Cl5 Cl -0.0249(10) 1.6114(2) -0.5133(9) 0.123(5) Uani 0.5 d PD
Cl6 Cl 0.0450(9) 1.4618(9) -0.3991(4) 0.123(4) Uani 0.5 d PD
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C25 Pt1 C1 177.2(4) . .
C25 Pt1 C18 89.2(3) . .
C1 Pt1 C18 90.4(4) . .
C25 Pt1 C9 90.8(3) . .
C1 Pt1 C9 89.5(3) . .
C18 Pt1 C9 177.5(4) . .
C25 Pt1 Ag2 134.5(3) . 2_573
C1 Pt1 Ag2 48.2(3) . 2_573
C18 Pt1 Ag2 84.8(3) . 2_573
C9 Pt1 Ag2 97.0(3) . 2_573
C25 Pt1 Ag1 89.4(2) . 2_573
C1 Pt1 Ag1 92.9(2) . 2_573
C18 Pt1 Ag1 135.4(3) . 2_573
C9 Pt1 Ag1 47.1(3) . 2_573
Ag2 Pt1 Ag1 65.40(2) 2_573 2_573
C25 Pt1 Ag1 84.3(2) . .
C1 Pt1 Ag1 97.3(3) . .
C18 Pt1 Ag1 42.9(3) . .
C9 Pt1 Ag1 139.6(3) . .
Ag2 Pt1 Ag1 61.32(2) 2_573 .
Ag1 Pt1 Ag1 92.68(2) 2_573 .
C25 Pt1 Ag2 42.2(3) . .
C1 Pt1 Ag2 140.6(3) . .
C18 Pt1 Ag2 90.8(3) . .
C9 Pt1 Ag2 90.8(3) . .
Ag2 Pt1 Ag2 92.77(2) 2_573 .
Ag1 Pt1 Ag2 60.22(2) 2_573 .
Ag1 Pt1 Ag2 59.47(2) . .
C9 Ag1 C18 166.5(3) 2_573 .
C9 Ag1 C18 161.0(3) 2_573 .
C18 Ag1 C18 30.1(3) . .
C9 Ag1 C10 28.7(3) 2_573 2_573
C18 Ag1 C10 162.5(3) . 2_573
C18 Ag1 C10 132.9(3) . 2_573
C9 Ag1 Pt1 42.3(2) 2_573 2_573
C18 Ag1 Pt1 125.4(2) . 2_573
C18 Ag1 Pt1 155.2(2) . 2_573
C10 Ag1 Pt1 71.0(2) 2_573 2_573
C9 Ag1 Ag2 90.7(2) 2_573 2_573
C18 Ag1 Ag2 76.9(2) . 2_573
C18 Ag1 Ag2 96.7(2) . 2_573
C10 Ag1 Ag2 109.2(2) 2_573 2_573
Pt1 Ag1 Ag2 64.07(2) 2_573 2_573
C9 Ag1 Ag2 86.2(2) 2_573 .
C18 Ag1 Ag2 88.6(2) . .
C18 Ag1 Ag2 111.2(2) . .
C10 Ag1 Ag2 107.4(2) 2_573 .
Pt1 Ag1 Ag2 56.54(2) 2_573 .
Ag2 Ag1 Ag2 90.08(3) 2_573 .
C9 Ag1 Pt1 129.5(2) 2_573 .
C18 Ag1 Pt1 38.2(2) . .
C18 Ag1 Pt1 68.3(2) . .
C10 Ag1 Pt1 157.9(2) 2_573 .
Pt1 Ag1 Pt1 87.32(2) 2_573 .
Ag2 Ag1 Pt1 55.18(2) 2_573 .
Ag2 Ag1 Pt1 61.05(2) . .
C1 Ag2 C25 164.0(3) 2_573 .
C1 Ag2 C26 158.3(3) 2_573 .
C25 Ag2 C26 30.7(3) . .
C1 Ag2 C2 28.0(3) 2_573 2_573
C25 Ag2 C2 162.1(3) . 2_573
C26 Ag2 C2 132.5(3) . 2_573
C1 Ag2 Pt1 42.8(2) 2_573 2_573
C25 Ag2 Pt1 123.5(2) . 2_573
C26 Ag2 Pt1 152.4(2) . 2_573
C2 Ag2 Pt1 70.8(2) 2_573 2_573
C1 Ag2 Ag1 95.1(2) 2_573 2_573
C25 Ag2 Ag1 81.4(2) . 2_573
C26 Ag2 Ag1 106.5(2) . 2_573
C2 Ag2 Ag1 116.2(2) 2_573 2_573
Pt1 Ag2 Ag1 63.50(2) 2_573 2_573
C1 Ag2 Ag1 83.7(2) 2_573 .
C25 Ag2 Ag1 80.7(2) . .
C26 Ag2 Ag1 98.1(2) . .
C2 Ag2 Ag1 101.5(2) 2_573 .
Pt1 Ag2 Ag1 58.06(2) 2_573 .
Ag1 Ag2 Ag1 89.92(3) 2_573 .
C1 Ag2 Pt1 129.8(2) 2_573 .
C25 Ag2 Pt1 36.6(2) . .
C26 Ag2 Pt1 67.2(2) . .
C2 Ag2 Pt1 157.0(2) 2_573 .
Pt1 Ag2 Pt1 87.23(2) 2_573 .
Ag1 Ag2 Pt1 55.71(2) 2_573 .
Ag1 Ag2 Pt1 59.48(2) . .
C2 C1 Pt1 176.4(8) . .
C2 C1 Ag2 93.9(7) . 2_573
Pt1 C1 Ag2 89.0(3) . 2_573
C1 C2 C3 171.8(10) . .
C1 C2 Ag2 58.1(6) . 2_573
C3 C2 Ag2 129.9(6) . 2_573
C8 C3 C4 119.7(9) . .
C8 C3 C2 120.7(9) . .
C4 C3 C2 119.6(9) . .
C5 C4 C3 119.4(10) . .
C6 C5 C4 120.8(11) . .
C5 C6 C7 120.7(10) . .
C6 C7 C8 118.9(11) . .
C3 C8 C7 120.5(10) . .
C10 C9 Pt1 179.8(8) . .
C10 C9 Ag1 89.1(7) . 2_573
Pt1 C9 Ag1 90.7(4) . 2_573
C9 C10 C11 172.0(10) . .
C9 C10 Ag1 62.2(6) . 2_573
C11 C10 Ag1 125.6(6) . 2_573
C16 C11 C12 119.6(9) . .
C16 C11 C10 120.8(9) . .
C12 C11 C10 119.6(9) . .
C13 C12 C11 120.1(10) . .
C14 C13 C12 119.8(11) . .
C15 C14 C13 120.2(10) . .
C14 C15 C16 120.7(10) . .
C11 C16 C15 119.6(10) . .
C18 C18 C19 168.7(10) . .
C18 C18 Ag1 68.6(6) . .
C19 C18 Ag1 122.8(7) . .
C18 C18 Pt1 179.1(8) . .
C18 C18 Ag1 81.3(7) . .
Pt1 C18 Ag1 99.0(4) . .
C24 C19 C20 119.5(9) . .
C24 C19 C18 121.8(9) . .
C20 C19 C18 118.8(9) . .
C21 C20 C19 120.1(10) . .
C20 C21 C22 121.3(11) . .
C23 C22 C21 118.9(9) . .
C22 C23 C24 120.4(9) . .
C19 C24 C23 119.9(9) . .
C26 C25 Pt1 173.7(8) . .
C26 C25 Ag2 80.4(6) . .
Pt1 C25 Ag2 101.2(4) . .
C25 C26 C27 168.9(10) . .
C25 C26 Ag2 68.9(6) . .
C27 C26 Ag2 121.8(6) . .
C28 C27 C32 118.6(8) . .
C28 C27 C26 121.9(8) . .
C32 C27 C26 119.5(9) . .
C29 C28 C27 119.9(9) . .
C30 C29 C28 120.5(10) . .
C29 C30 C31 121.2(10) . .
C30 C31 C32 119.3(10) . .
C31 C32 C27 120.6(10) . .
C49 Pt2 C41 176.5(4) . .
C49 Pt2 C57 90.3(4) . .
C41 Pt2 C57 88.2(3) . .
C49 Pt2 C33 89.7(4) . .
C41 Pt2 C33 91.6(4) . .
C57 Pt2 C33 177.5(4) . .
C49 Pt2 Ag3 137.1(3) . 2_684
C41 Pt2 Ag3 46.0(3) . 2_684
C57 Pt2 Ag3 88.3(3) . 2_684
C33 Pt2 Ag3 93.3(3) . 2_684
C49 Pt2 Ag4 92.5(3) . 2_684
C41 Pt2 Ag4 90.7(3) . 2_684
C57 Pt2 Ag4 137.4(3) . 2_684
C33 Pt2 Ag4 45.1(3) . 2_684
Ag3 Pt2 Ag4 61.80(2) 2_684 2_684
C49 Pt2 Ag4 87.9(3) . .
C41 Pt2 Ag4 93.2(2) . .
C57 Pt2 Ag4 45.1(3) . .
C33 Pt2 Ag4 137.3(3) . .
Ag3 Pt2 Ag4 61.82(2) 2_684 .
Ag4 Pt2 Ag4 92.50(2) 2_684 .
C49 Pt2 Ag3 44.9(3) . .
C41 Pt2 Ag3 138.3(3) . .
C57 Pt2 Ag3 93.3(3) . .
C33 Pt2 Ag3 88.5(3) . .
Ag3 Pt2 Ag3 92.40(2) 2_684 .
Ag4 Pt2 Ag3 61.07(2) 2_684 .
Ag4 Pt2 Ag3 60.93(2) . .
C41 Ag3 C49 166.6(3) 2_684 .
C41 Ag3 C50 162.2(3) 2_684 .
C49 Ag3 C50 29.8(3) . .
C41 Ag3 C42 29.1(3) 2_684 2_684
C49 Ag3 C42 163.4(3) . 2_684
C50 Ag3 C42 133.7(3) . 2_684
C41 Ag3 Pt2 40.6(2) 2_684 2_684
C49 Ag3 Pt2 126.7(2) . 2_684
C50 Ag3 Pt2 156.3(2) . 2_684
C42 Ag3 Pt2 69.6(2) 2_684 2_684
C41 Ag3 Pt2 128.2(2) 2_684 .
C49 Ag3 Pt2 39.2(2) . .
C50 Ag3 Pt2 69.0(2) . .
C42 Ag3 Pt2 157.2(2) 2_684 .
Pt2 Ag3 Pt2 87.60(2) 2_684 .
C41 Ag3 Ag4 85.4(2) 2_684 .
C49 Ag3 Ag4 82.6(2) . .
C50 Ag3 Ag4 102.9(2) . .
C42 Ag3 Ag4 106.3(2) 2_684 .
Pt2 Ag3 Ag4 59.68(2) 2_684 .
Pt2 Ag3 Ag4 59.05(2) . .
C41 Ag3 Ag4 87.6(2) 2_684 2_684
C49 Ag3 Ag4 86.4(2) . 2_684
C50 Ag3 Ag4 107.8(2) . 2_684
C42 Ag3 Ag4 107.2(2) 2_684 2_684
Pt2 Ag3 Ag4 59.76(2) 2_684 2_684
Pt2 Ag3 Ag4 58.89(2) . 2_684
Ag4 Ag3 Ag4 90.10(3) . 2_684
C33 Ag4 C57 166.4(3) 2_684 .
C33 Ag4 C58 161.0(3) 2_684 .
C57 Ag4 C58 28.9(3) . .
C33 Ag4 C34 29.1(3) 2_684 2_684
C57 Ag4 C34 160.9(3) . 2_684
C58 Ag4 C34 132.8(3) . 2_684
C33 Ag4 Pt2 40.3(2) 2_684 2_684
C57 Ag4 Pt2 127.7(2) . 2_684
C58 Ag4 Pt2 156.0(2) . 2_684
C34 Ag4 Pt2 69.4(2) 2_684 2_684
C33 Ag4 Pt2 127.6(2) 2_684 .
C57 Ag4 Pt2 40.3(2) . .
C58 Ag4 Pt2 69.2(2) . .
C34 Ag4 Pt2 156.2(2) 2_684 .
Pt2 Ag4 Pt2 87.50(2) 2_684 .
C33 Ag4 Ag3 87.0(2) 2_684 .
C57 Ag4 Ag3 88.9(2) . .
C58 Ag4 Ag3 111.0(2) . .
C34 Ag4 Ag3 109.2(2) 2_684 .
Pt2 Ag4 Ag3 58.52(2) 2_684 .
Pt2 Ag4 Ag3 60.03(2) . .
C33 Ag4 Ag3 84.5(2) 2_684 2_684
C57 Ag4 Ag3 82.5(2) . 2_684
C58 Ag4 Ag3 100.8(2) . 2_684
C34 Ag4 Ag3 103.0(2) 2_684 2_684
Pt2 Ag4 Ag3 60.04(2) 2_684 2_684
Pt2 Ag4 Ag3 58.42(2) . 2_684
Ag3 Ag4 Ag3 89.90(3) . 2_684
C34 C33 Pt2 177.4(8) . .
C34 C33 Ag4 86.9(7) . 2_684
Pt2 C33 Ag4 94.6(4) . 2_684
C33 C34 C35 169.0(10) . .
C33 C34 Ag4 63.9(6) . 2_684
C35 C34 Ag4 124.3(6) . 2_684
C40 C35 C36 118.7(9) . .
C40 C35 C34 121.9(9) . .
C36 C35 C34 119.4(9) . .
C37 C36 C35 119.0(10) . .
C38 C37 C36 121.8(11) . .
C39 C38 C37 119.0(11) . .
C38 C39 C40 120.9(11) . .
C39 C40 C35 120.5(10) . .
C42 C41 Pt2 176.2(8) . .
C42 C41 Ag3 88.3(7) . 2_684
Pt2 C41 Ag3 93.4(3) . 2_684
C41 C42 C43 171.9(10) . .
C41 C42 Ag3 62.6(6) . 2_684
C43 C42 Ag3 125.0(7) . 2_684
C48 C43 C44 118.7(9) . .
C48 C43 C42 118.3(9) . .
C44 C43 C42 122.9(9) . .
C45 C44 C43 121.7(11) . .
C44 C45 C46 120.6(11) . .
C47 C46 C45 119.4(10) . .
C46 C47 C48 119.9(10) . .
C43 C48 C47 119.5(10) . .
C50 C49 Pt2 178.4(8) . .
C50 C49 Ag3 85.0(7) . .
Pt2 C49 Ag3 95.9(4) . .
C49 C50 C51 171.0(10) . .
C49 C50 Ag3 65.2(6) . .
C51 C50 Ag3 123.2(7) . .
C56 C51 C52 118.3(9) . .
C56 C51 C50 122.4(9) . .
C52 C51 C50 119.3(9) . .
C53 C52 C51 120.6(10) . .
C54 C53 C52 120.4(11) . .
C53 C54 C55 119.4(11) . .
C56 C55 C54 120.4(11) . .
C51 C56 C55 121.0(11) . .
C58 C57 Pt2 177.6(8) . .
C58 C57 Ag4 85.9(7) . .
Pt2 C57 Ag4 94.6(4) . .
C57 C58 C59 171.3(11) . .
C57 C58 Ag4 65.2(6) . .
C59 C58 Ag4 123.3(7) . .
C60 C59 C64 118.6(9) . .
C60 C59 C58 122.1(9) . .
C64 C59 C58 119.3(9) . .
C59 C60 C61 120.8(11) . .
C62 C61 C60 121.4(12) . .
C61 C62 C63 118.6(11) . .
C64 C63 C62 120.7(13) . .
C63 C64 C59 119.9(12) . .
Cl1 C65 Cl3 128.8(6) . .
Cl1 C65 Cl2 117.8(5) . .
Cl3 C65 Cl2 107.9(5) . .
Cl3 Cl1 C65 64.4(3) 2_473 .
Cl3 Cl1 Cl2 116.8(4) 2_473 2_473
C65 Cl1 Cl2 59.0(3) . 2_473
C65 Cl2 Cl1 58.8(3) . 2_473
C65 Cl2 Cl3 53.9(3) . 2_473
Cl1 Cl2 Cl3 109.1(3) 2_473 2_473
Cl1 Cl3 C65 64.3(3) 2_473 .
Cl1 Cl3 Cl2 113.2(3) 2_473 2_473
C65 Cl3 Cl2 54.0(3) . 2_473
Cl6 C66 Cl4 117.6(6) . .
Cl6 C66 Cl5 118.3(6) . .
Cl4 C66 Cl5 117.3(7) . .
C66 Cl4 Cl5 58.7(3) . 2_584
C66 Cl4 Cl6 58.8(3) . 2_584
Cl5 Cl4 Cl6 111.6(4) 2_584 2_584
C66 Cl5 Cl6 59.1(3) . 2_584
C66 Cl5 Cl4 58.7(3) . 2_584
Cl6 Cl5 Cl4 111.8(4) 2_584 2_584
C66 Cl6 Cl5 59.2(3) . 2_584
C66 Cl6 Cl4 58.9(3) . 2_584
Cl5 Cl6 Cl4 112.0(4) 2_584 2_584
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 C25 1.997(9) .
Pt1 C1 2.016(9) .
Pt1 C18 2.022(9) .
Pt1 C9 2.029(9) .
Pt1 Ag2 2.9652(9) 2_573
Pt1 Ag1 3.0162(9) 2_573
Pt1 Ag1 3.2323(9) .
Pt1 Ag2 3.2833(9) .
Ag1 C9 2.209(10) 2_573
Ag1 C18 2.226(10) .
Ag1 C18 2.365(9) .
Ag1 C10 2.496(9) 2_573
Ag1 Pt1 3.0162(9) 2_573
Ag1 Ag2 3.1686(11) 2_573
Ag1 Ag2 3.2319(10) .
Ag2 C1 2.210(9) 2_573
Ag2 C25 2.248(9) .
Ag2 C26 2.375(9) .
Ag2 C2 2.597(9) 2_573
Ag2 Pt1 2.9652(9) 2_573
Ag2 Ag1 3.1686(11) 2_573
C1 C2 1.221(13) .
C1 Ag2 2.210(9) 2_573
C2 C3 1.441(13) .
C2 Ag2 2.597(9) 2_573
C3 C8 1.369(13) .
C3 C4 1.394(14) .
C4 C5 1.38(2) .
C5 C6 1.37(2) .
C6 C7 1.37(2) .
C7 C8 1.402(14) .
C9 C10 1.198(13) .
C9 Ag1 2.209(10) 2_573
C10 C11 1.448(12) .
C10 Ag1 2.496(9) 2_573
C11 C16 1.380(13) .
C11 C12 1.402(13) .
C12 C13 1.382(14) .
C13 C14 1.38(2) .
C14 C15 1.37(2) .
C15 C16 1.391(15) .
C18 C18 1.200(13) .
C18 C19 1.448(13) .
C19 C24 1.384(13) .
C19 C20 1.407(14) .
C20 C21 1.359(15) .
C21 C22 1.39(2) .
C22 C23 1.392(15) .
C23 C24 1.391(13) .
C25 C26 1.230(12) .
C26 C27 1.437(12) .
C27 C28 1.389(13) .
C27 C32 1.400(13) .
C28 C29 1.385(13) .
C29 C30 1.36(2) .
C30 C31 1.37(2) .
C31 C32 1.387(14) .
Pt2 C49 2.001(9) .
Pt2 C41 2.005(8) .
Pt2 C57 2.025(9) .
Pt2 C33 2.020(9) .
Pt2 Ag3 3.0759(9) 2_684
Pt2 Ag4 3.1136(10) 2_684
Pt2 Ag4 3.1191(9) .
Pt2 Ag3 3.1506(9) .
Ag3 C41 2.216(9) 2_684
Ag3 C49 2.235(10) .
Ag3 C50 2.452(10) .
Ag3 C42 2.494(10) 2_684
Ag3 Pt2 3.0760(9) 2_684
Ag3 Ag4 3.1789(11) .
Ag3 Ag4 3.1826(11) 2_684
Ag4 C33 2.211(9) 2_684
Ag4 C57 2.216(9) .
Ag4 C58 2.435(10) .
Ag4 C34 2.458(9) 2_684
Ag4 Pt2 3.1136(10) 2_684
Ag4 Ag3 3.1826(11) 2_684
C33 C34 1.198(13) .
C33 Ag4 2.211(9) 2_684
C34 C35 1.454(13) .
C34 Ag4 2.458(9) 2_684
C35 C40 1.379(13) .
C35 C36 1.390(14) .
C36 C37 1.373(14) .
C37 C38 1.36(2) .
C38 C39 1.35(2) .
C39 C40 1.37(2) .
C41 C42 1.212(13) .
C41 Ag3 2.216(9) 2_684
C42 C43 1.451(13) .
C42 Ag3 2.494(10) 2_684
C43 C48 1.382(13) .
C43 C44 1.390(14) .
C44 C45 1.34(2) .
C45 C46 1.39(2) .
C46 C47 1.37(2) .
C47 C48 1.409(14) .
C49 C50 1.223(13) .
C50 C51 1.435(13) .
C51 C56 1.372(14) .
C51 C52 1.392(14) .
C52 C53 1.38(2) .
C53 C54 1.36(2) .
C54 C55 1.38(2) .
C55 C56 1.380(15) .
C57 C58 1.181(13) .
C58 C59 1.464(13) .
C59 C60 1.371(14) .
C59 C64 1.393(15) .
C60 C61 1.37(2) .
C61 C62 1.36(2) .
C62 C63 1.38(2) .
C63 C64 1.38(2) .
C65 Cl1 1.7281(10) .
C65 Cl3 1.7294(11) .
C65 Cl2 1.7312(11) .
Cl1 Cl3 1.49(2) 2_473
Cl1 Cl2 1.786(14) 2_473
Cl2 Cl1 1.786(14) 2_473
Cl2 Cl3 2.037(13) 2_473
Cl3 Cl1 1.49(2) 2_473
Cl3 Cl2 2.037(14) 2_473
C66 Cl6 1.7286(11) .
C66 Cl4 1.7301(11) .
C66 Cl5 1.7304(10) .
Cl4 Cl5 1.80(2) 2_584
Cl4 Cl6 1.79(2) 2_584
Cl5 Cl6 1.77(2) 2_584
Cl5 Cl4 1.80(2) 2_584
Cl6 Cl5 1.77(2) 2_584
Cl6 Cl4 1.79(2) 2_584
