#------------------------------------------------------------------------------
#$Date: 2016-03-23 21:05:52 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179439 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/36/4333619.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4333619
loop_
_publ_author_name
'Guibo Zhu'
'Yurii V. Geletii'
'Jie Song'
'Chongchao Zhao'
'Elliot N. Glass'
'John Bacsa'
'Craig L. Hill'
_publ_section_title
;
 Di- and Tri-Cobalt Silicotungstates: Synthesis, Characterization, and
 Stability Studies
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1018
_journal_page_last               1024
_journal_paper_doi               10.1021/ic302279m
_journal_volume                  52
_journal_year                    2013
_chemical_formula_moiety         'Co3 Na3 O66 Si2 W18 (H2O)7, K6, Na, (H2O)24'
_chemical_formula_sum            'Co3 H62 K6 Na4 O97 Si2 W18'
_chemical_formula_weight         5483.25
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           11
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yb'
_symmetry_space_group_name_H-M   'P 1 21/m 1'
_atom_sites_solution_hydrogens   none
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 106.3640(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   13.3935(12)
_cell_length_b                   16.1715(15)
_cell_length_c                   20.3596(18)
_cell_measurement_reflns_used    5178
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      29.76
_cell_measurement_theta_min      2.44
_cell_volume                     4231.1(7)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1308
_diffrn_reflns_av_sigmaI/netI    0.0947
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_number            82692
_diffrn_reflns_theta_full        30.51
_diffrn_reflns_theta_max         30.51
_diffrn_reflns_theta_min         2.02
_exptl_absorpt_coefficient_mu    25.390
_exptl_absorpt_correction_T_max  0.7464
_exptl_absorpt_correction_T_min  0.4292
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            pink
_exptl_crystal_density_diffrn    4.164
_exptl_crystal_description       needle
_exptl_crystal_F_000             4635
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.02
_exptl_crystal_size_min          0.02
_refine_diff_density_max         4.860
_refine_diff_density_min         -3.256
_refine_diff_density_rms         0.598
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.016
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     562
_refine_ls_number_reflns         13265
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.016
_refine_ls_R_factor_all          0.0952
_refine_ls_R_factor_gt           0.0487
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0462P)²+40.9220P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1025
_refine_ls_wR_factor_ref         0.1212
_reflns_number_gt                8727
_reflns_number_total             13265
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic302279m_si_002_2.cif
_cod_data_source_block           Co3NaSi2W18
_cod_database_code               4333619
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'
'-x, -y, -z'
'x, -y-1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Co1 Co 0.7552(2) 0.2500 0.75970(14) 0.0140(5) Uani 1 2 d S
Co2 Co 0.55190(14) 0.55303(11) 0.68400(9) 0.0128(4) Uani 1 1 d .
K1 K 0.5000 0.5000 0.0000 0.0333(13) Uani 1 2 d S
K2 K 0.7718(2) 0.48482(19) 0.42637(16) 0.0176(6) Uani 1 1 d .
K3 K 1.2196(7) 0.2500 0.5833(5) 0.022(2) Uani 0.50 2 d SP
K4 K 0.0874(16) 0.3962(11) 0.0711(9) 0.051(5) Uani 0.25 1 d P
K5 K 0.7989(6) 0.5902(5) 0.0343(4) 0.0307(16) Uani 0.50 1 d P
K6 K 1.2720(7) 0.3563(7) 0.5256(6) 0.060(3) Uani 0.50 1 d P
Na1 Na 0.6270(7) 0.7500 0.8213(5) 0.0244(19) Uiso 1 2 d S
Na2 Na 1.1781(5) 0.5213(4) 0.7950(3) 0.0307(15) Uani 1 1 d .
Na3 Na 0.5371(6) 0.2500 0.6228(5) 0.028(2) Uani 1 2 d S
O1 O 1.0558(7) 0.4204(6) 0.5447(5) 0.019(2) Uani 1 1 d .
O2 O 1.0326(10) 0.2500 0.5589(7) 0.017(3) Uani 1 2 d S
O3 O 0.8921(6) 0.3336(6) 0.4610(5) 0.0129(19) Uani 1 1 d .
O4 O 0.9971(7) 0.3467(5) 0.6560(5) 0.0114(19) Uani 1 1 d .
O5 O 0.8418(9) 0.2500 0.5545(6) 0.011(3) Uani 1 2 d S
O6 O 0.8547(6) 0.4262(6) 0.5617(5) 0.0114(19) Uani 1 1 d .
O7 O 0.7534(10) 0.2500 0.3473(7) 0.016(3) Uani 1 2 d S
O8 O 0.6856(7) 0.3327(6) 0.4464(5) 0.0133(19) Uani 1 1 d .
O9 O 0.7844(7) 0.5695(6) 0.6073(5) 0.017(2) Uani 1 1 d .
O10 O 0.6912(6) 0.3329(5) 0.5874(5) 0.0108(19) Uani 1 1 d .
O11 O 0.6491(7) 0.4651(6) 0.5176(5) 0.015(2) Uani 1 1 d .
O12 O 0.6508(7) 0.4738(5) 0.6549(5) 0.0129(19) Uani 1 1 d .
O13 O 0.4863(7) 0.3963(6) 0.4130(5) 0.016(2) Uani 1 1 d .
O14 O 0.5431(9) 0.2500 0.4846(7) 0.013(3) Uani 1 2 d S
O15 O 0.4842(7) 0.3791(6) 0.5478(5) 0.016(2) Uani 1 1 d .
O16 O 0.6344(7) 0.3341(5) 0.7213(5) 0.0120(19) Uani 1 1 d .
O17 O 0.8342(9) 0.2500 0.6825(6) 0.007(2) Uiso 1 2 d S
O18 O 0.8702(7) 0.3382(6) 0.8015(4) 0.0098(18) Uani 1 1 d .
O19 O 0.6710(8) 0.6387(6) 0.7246(5) 0.020(2) Uani 1 1 d .
O20 O 0.4450(9) 0.6362(7) 0.7083(6) 0.031(3) Uani 1 1 d .
O21 O 0.4299(7) 0.4678(6) 0.6460(5) 0.018(2) Uani 1 1 d .
O22 O 0.5902(7) 0.4889(6) 0.7758(5) 0.017(2) Uani 1 1 d .
O23 O 1.0177(10) 0.2500 0.7658(8) 0.018(3) Uani 1 2 d S
O24 O 1.0440(7) 0.4195(6) 0.7840(5) 0.018(2) Uani 1 1 d .
O25 O 0.7485(9) 0.2500 0.8629(6) 0.010(3) Uani 1 2 d S
O26 O 0.9488(10) 0.2500 0.9152(7) 0.015(3) Uani 1 2 d S
O27 O 0.9806(7) 0.4192(6) 0.9197(5) 0.017(2) Uani 1 1 d .
O28 O 0.8440(7) 0.3467(6) 0.9815(5) 0.0123(19) Uani 1 1 d .
O29 O 0.7604(6) 0.4271(6) 0.8661(4) 0.0105(18) Uani 1 1 d .
O30 O 0.5724(7) 0.3348(5) 0.8444(5) 0.0115(19) Uani 1 1 d .
O31 O 0.6579(8) 0.5725(7) 0.8959(5) 0.023(2) Uani 1 1 d .
O32 O 0.6695(7) 0.4259(6) 0.9647(5) 0.016(2) Uani 1 1 d .
O33 O 0.4867(7) 0.4663(6) 0.8719(5) 0.016(2) Uani 1 1 d .
O34 O 0.3886(7) 0.3827(6) 0.7526(5) 0.015(2) Uiso 1 1 d .
O35 O 0.3787(9) 0.2500 0.8291(7) 0.012(3) Uani 1 2 d S
O36 O 0.2917(7) 0.4024(7) 0.8514(6) 0.023(2) Uani 1 1 d .
O37 O 0.6539(9) 0.2500 0.9601(6) 0.009(2) Uani 1 2 d S
O38 O 0.4598(7) 0.3325(6) 0.9441(5) 0.015(2) Uani 1 1 d .
O39 O 0.7939(10) 0.2500 1.0744(7) 0.018(3) Uani 1 2 d S
O40 O 0.7995(7) 0.4216(6) 1.0958(5) 0.017(2) Uani 1 1 d .
O41 O 0.6162(7) 0.3317(6) 1.0605(5) 0.016(2) Uani 1 1 d .
O42 O 0.4286(10) 0.2500 1.0583(7) 0.020(3) Uani 1 2 d S
O43 O 0.8492(7) 0.4269(5) 0.6879(5) 0.0113(18) Uiso 1 1 d .
O1W O 1.1957(8) 0.4552(6) 0.6926(5) 0.024(2) Uiso 1 1 d .
O2W O 1.3531(9) 0.5922(7) 0.8060(6) 0.034(3) Uiso 1 1 d .
O3W O 1.1988(13) 0.2500 0.6965(9) 0.036(4) Uiso 1 2 d S
O4W O 1.3986(12) 0.2500 0.6645(8) 0.024(3) Uiso 1 2 d S
O5W O 0.9972(13) 0.6073(10) 0.6195(8) 0.037(4) Uiso 0.75 1 d P
O6W O 1.0329(11) 0.6077(9) 0.7556(7) 0.051(4) Uiso 1 1 d .
O7W O 0.3155(12) 0.2500 0.3742(8) 0.030(4) Uiso 1 2 d S
O8W O 0.1486(10) 0.4396(8) 0.2094(6) 0.039(3) Uiso 1 1 d .
O9W O 0.749(2) 0.6850(18) -0.0563(15) 0.034(7) Uiso 0.40 1 d P
O10W O 0.136(3) 0.2500 0.3999(18) 0.039(9) Uiso 0.50 2 d SP
O11W O 0.843(3) 0.7500 0.879(2) 0.046(10) Uiso 0.50 2 d SP
O12W O 0.979(2) 0.2500 0.1716(17) 0.031(8) Uiso 0.50 2 d SP
O13W O 0.8517(15) 0.6907(12) 0.1025(10) 0.019(4) Uiso 0.50 1 d P
Si1 Si 0.7626(4) 0.2500 0.6034(2) 0.0073(9) Uani 1 2 d S
Si2 Si 0.6338(4) 0.2500 0.8759(3) 0.0080(10) Uani 1 2 d S
W1 W 0.95898(4) 0.35422(3) 0.55437(3) 0.01014(11) Uani 1 1 d .
W2 W 0.77230(5) 0.2500 0.43548(4) 0.00950(15) Uani 1 2 d S
W3 W 0.74524(4) 0.46801(3) 0.60776(3) 0.00995(11) Uani 1 1 d .
W4 W 0.56632(4) 0.36613(3) 0.49351(3) 0.00865(11) Uani 1 1 d .
W5 W 0.95268(4) 0.35384(3) 0.73541(3) 0.00998(11) Uani 1 1 d .
W6 W 0.87520(4) 0.35366(3) 0.89852(3) 0.01042(11) Uani 1 1 d .
W7 W 0.62820(4) 0.47216(3) 0.86451(3) 0.01149(11) Uani 1 1 d .
W8 W 0.40726(4) 0.36587(3) 0.84040(3) 0.01268(12) Uani 1 1 d .
W9 W 0.73713(4) 0.35486(3) 1.03256(3) 0.01192(11) Uani 1 1 d .
W10 W 0.51120(6) 0.2500 1.00589(4) 0.01287(16) Uani 1 2 d S
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O16 Co1 O16 81.2(5) 4_565 .
O16 Co1 O18 176.3(4) 4_565 .
O16 Co1 O18 96.4(3) . .
O16 Co1 O18 96.4(3) 4_565 4_565
O16 Co1 O18 176.3(4) . 4_565
O18 Co1 O18 85.8(5) . 4_565
O16 Co1 O17 102.6(4) 4_565 .
O16 Co1 O17 102.6(4) . .
O18 Co1 O17 80.7(3) . .
O18 Co1 O17 80.7(3) 4_565 .
O16 Co1 O25 97.2(4) 4_565 .
O16 Co1 O25 97.2(3) . .
O18 Co1 O25 80.2(3) . .
O18 Co1 O25 80.2(3) 4_565 .
O17 Co1 O25 153.8(5) . .
O16 Co1 Na3 45.7(2) 4_565 .
O16 Co1 Na3 45.7(2) . .
O18 Co1 Na3 133.8(2) . .
O18 Co1 Na3 133.8(2) 4_565 .
O17 Co1 Na3 83.5(4) . .
O25 Co1 Na3 122.7(4) . .
O12 Co2 O13 88.8(4) . 3_666
O12 Co2 O22 86.1(4) . .
O13 Co2 O22 173.3(4) 3_666 .
O12 Co2 O19 92.6(4) . .
O13 Co2 O19 94.0(4) 3_666 .
O22 Co2 O19 90.4(4) . .
O12 Co2 O21 89.0(4) . .
O13 Co2 O21 87.2(4) 3_666 .
O22 Co2 O21 88.5(4) . .
O19 Co2 O21 178.0(4) . .
O12 Co2 O20 176.8(4) . .
O13 Co2 O20 88.2(4) 3_666 .
O22 Co2 O20 96.8(4) . .
O19 Co2 O20 88.7(4) . .
O21 Co2 O20 89.8(4) . .
O33 K1 O33 180.0 3_666 1_554
O33 K1 O32 59.6(3) 3_666 3_666
O33 K1 O32 120.4(3) 1_554 3_666
O33 K1 O32 120.4(3) 3_666 1_554
O33 K1 O32 59.6(3) 1_554 1_554
O32 K1 O32 180.0(4) 3_666 1_554
O33 K1 O38 122.2(3) 3_666 1_554
O33 K1 O38 57.8(3) 1_554 1_554
O32 K1 O38 114.6(3) 3_666 1_554
O32 K1 O38 65.4(3) 1_554 1_554
O33 K1 O38 57.8(3) 3_666 3_666
O33 K1 O38 122.2(3) 1_554 3_666
O32 K1 O38 65.4(3) 3_666 3_666
O32 K1 O38 114.6(3) 1_554 3_666
O38 K1 O38 180.0(4) 1_554 3_666
O33 K1 O41 95.5(3) 3_666 3_666
O33 K1 O41 84.5(3) 1_554 3_666
O32 K1 O41 53.2(2) 3_666 3_666
O32 K1 O41 126.8(2) 1_554 3_666
O38 K1 O41 128.3(2) 1_554 3_666
O38 K1 O41 51.7(2) 3_666 3_666
O33 K1 O41 84.5(3) 3_666 1_554
O33 K1 O41 95.5(3) 1_554 1_554
O32 K1 O41 126.8(2) 3_666 1_554
O32 K1 O41 53.2(2) 1_554 1_554
O38 K1 O41 51.7(2) 1_554 1_554
O38 K1 O41 128.3(2) 3_666 1_554
O41 K1 O41 180.000(1) 3_666 1_554
O33 K1 W7 30.7(2) 3_666 3_666
O33 K1 W7 149.3(2) 1_554 3_666
O32 K1 W7 34.71(19) 3_666 3_666
O32 K1 W7 145.29(19) 1_554 3_666
O38 K1 W7 109.41(18) 1_554 3_666
O38 K1 W7 70.59(18) 3_666 3_666
O41 K1 W7 84.55(16) 3_666 3_666
O41 K1 W7 95.45(16) 1_554 3_666
O33 K1 W7 149.3(2) 3_666 1_554
O33 K1 W7 30.7(2) 1_554 1_554
O32 K1 W7 145.29(19) 3_666 1_554
O32 K1 W7 34.71(19) 1_554 1_554
O38 K1 W7 70.59(18) 1_554 1_554
O38 K1 W7 109.41(18) 3_666 1_554
O41 K1 W7 95.45(16) 3_666 1_554
O41 K1 W7 84.55(16) 1_554 1_554
W7 K1 W7 180.0 3_666 1_554
O33 K1 W8 28.2(2) 3_666 3_666
O33 K1 W8 151.8(2) 1_554 3_666
O32 K1 W8 68.6(2) 3_666 3_666
O32 K1 W8 111.4(2) 1_554 3_666
O38 K1 W8 146.90(19) 1_554 3_666
O38 K1 W8 33.10(19) 3_666 3_666
O41 K1 W8 81.40(17) 3_666 3_666
O41 K1 W8 98.60(17) 1_554 3_666
W7 K1 W8 52.968(13) 3_666 3_666
W7 K1 W8 127.032(13) 1_554 3_666
O33 K1 W8 151.8(2) 3_666 1_554
O33 K1 W8 28.2(2) 1_554 1_554
O32 K1 W8 111.4(2) 3_666 1_554
O32 K1 W8 68.6(2) 1_554 1_554
O38 K1 W8 33.10(19) 1_554 1_554
O38 K1 W8 146.90(19) 3_666 1_554
O41 K1 W8 98.60(17) 3_666 1_554
O41 K1 W8 81.40(17) 1_554 1_554
W7 K1 W8 127.032(13) 3_666 1_554
W7 K1 W8 52.968(12) 1_554 1_554
W8 K1 W8 180.000(14) 3_666 1_554
O1 K2 O1W 69.8(3) 3_766 3_766
O1 K2 O21 126.9(3) 3_766 3_666
O1W K2 O21 79.0(3) 3_766 3_666
O1 K2 O8 146.4(3) 3_766 .
O1W K2 O8 127.7(3) 3_766 .
O21 K2 O8 86.6(3) 3_666 .
O1 K2 O11 122.8(3) 3_766 .
O1W K2 O11 152.1(3) 3_766 .
O21 K2 O11 73.9(3) 3_666 .
O8 K2 O11 57.6(3) . .
O1 K2 O6 84.3(3) 3_766 .
O1W K2 O6 149.2(3) 3_766 .
O21 K2 O6 131.4(3) 3_666 .
O8 K2 O6 68.2(3) . .
O11 K2 O6 57.5(3) . .
O1 K2 K6 70.2(3) 3_766 3_766
O1W K2 K6 94.8(3) 3_766 3_766
O21 K2 K6 71.0(3) 3_666 3_766
O8 K2 K6 127.3(3) . 3_766
O11 K2 K6 70.4(3) . 3_766
O6 K2 K6 91.7(3) . 3_766
O1 K2 O3 92.5(3) 3_766 .
O1W K2 O3 107.2(3) 3_766 .
O21 K2 O3 138.3(3) 3_666 .
O8 K2 O3 56.5(3) . .
O11 K2 O3 97.5(3) . .
O6 K2 O3 56.1(3) . .
K6 K2 O3 145.5(3) 3_766 .
O1 K2 W1 78.7(2) 3_766 .
O1W K2 W1 125.0(2) 3_766 .
O21 K2 W1 152.2(2) 3_666 .
O8 K2 W1 67.86(19) . .
O11 K2 W1 82.9(2) . .
O6 K2 W1 29.04(17) . .
K6 K2 W1 115.6(2) 3_766 .
O3 K2 W1 30.01(19) . .
O1 K2 W2 124.6(2) 3_766 .
O1W K2 W2 113.3(2) 3_766 .
O21 K2 W2 106.7(2) 3_666 .
O8 K2 W2 27.01(19) . .
O11 K2 W2 81.3(2) . .
O6 K2 W2 67.8(2) . .
K6 K2 W2 151.1(2) 3_766 .
O3 K2 W2 32.21(17) . .
W1 K2 W2 53.67(5) . .
O1 K2 W3 97.9(2) 3_766 .
O1W K2 W3 163.0(2) 3_766 .
O21 K2 W3 100.9(2) 3_666 .
O8 K2 W3 69.0(2) . .
O11 K2 W3 29.02(19) . .
O6 K2 W3 31.98(17) . .
K6 K2 W3 69.5(2) 3_766 .
O3 K2 W3 84.4(2) . .
W1 K2 W3 60.68(5) . .
W2 K2 W3 83.17(6) . .
O1 K2 W4 148.0(2) 3_766 .
O1W K2 W4 141.5(2) 3_766 .
O21 K2 W4 69.4(2) 3_666 .
O8 K2 W4 32.41(19) . .
O11 K2 W4 27.85(19) . .
O6 K2 W4 67.42(18) . .
K6 K2 W4 95.1(2) 3_766 .
O3 K2 W4 84.19(19) . .
W1 K2 W4 83.00(6) . .
W2 K2 W4 58.91(5) . .
W3 K2 W4 50.17(4) . .
K6 K3 K6 96.7(7) 4_565 .
K6 K3 O3W 128.7(4) 4_565 .
K6 K3 O3W 128.7(4) . .
K6 K3 O2 110.1(4) 4_565 .
K6 K3 O2 110.1(4) . .
O3W K3 O2 78.7(6) . .
K6 K3 O4W 88.0(4) 4_565 .
K6 K3 O4W 88.0(4) . .
O3W K3 O4W 73.4(6) . .
O2 K3 O4W 152.0(6) . .
K6 K3 W1 89.3(3) 4_565 4_565
K6 K3 W1 131.0(4) . 4_565
O3W K3 W1 78.3(4) . 4_565
O2 K3 W1 26.61(6) . 4_565
O4W K3 W1 140.9(4) . 4_565
K6 K3 W1 131.0(4) 4_565 .
K6 K3 W1 89.3(3) . .
O3W K3 W1 78.3(4) . .
O2 K3 W1 26.61(6) . .
O4W K3 W1 140.9(4) . .
W1 K3 W1 53.11(12) 4_565 .
K6 K3 Na3 69.6(3) 4_565 1_655
K6 K3 Na3 69.6(3) . 1_655
O3W K3 Na3 101.9(5) . 1_655
O2 K3 Na3 179.4(5) . 1_655
O4W K3 Na3 28.5(4) . 1_655
W1 K3 Na3 153.42(6) 4_565 1_655
W1 K3 Na3 153.42(6) . 1_655
K6 K3 K2 135.0(4) 4_565 3_766
K6 K3 K2 38.2(3) . 3_766
O3W K3 K2 93.20(14) . 3_766
O2 K3 K2 91.73(12) . 3_766
O4W K3 K2 89.84(13) . 3_766
W1 K3 K2 118.34(17) 4_565 3_766
W1 K3 K2 65.30(7) . 3_766
Na3 K3 K2 88.24(12) 1_655 3_766
K6 K3 K2 38.2(3) 4_565 2_746
K6 K3 K2 135.0(4) . 2_746
O3W K3 K2 93.20(14) . 2_746
O2 K3 K2 91.73(12) . 2_746
O4W K3 K2 89.84(13) . 2_746
W1 K3 K2 65.30(7) 4_565 2_746
W1 K3 K2 118.34(17) . 2_746
Na3 K3 K2 88.24(12) 1_655 2_746
K2 K3 K2 173.2(3) 3_766 2_746
O11W K4 O9W 52.1(11) 3_666 3_665
O11W K4 O8W 82.1(10) 3_666 .
O9W K4 O8W 102.8(9) 3_665 .
O11W K4 K5 98.5(11) 3_666 3_665
O9W K4 K5 49.0(8) 3_665 3_665
O8W K4 K5 130.2(8) . 3_665
O11W K4 O27 121.2(10) 3_666 1_454
O9W K4 O27 96.6(9) 3_665 1_454
O8W K4 O27 156.1(8) . 1_454
K5 K4 O27 56.5(4) 3_665 1_454
O11W K4 O27 154.8(11) 3_666 3_666
O9W K4 O27 137.8(10) 3_665 3_666
O8W K4 O27 73.1(5) . 3_666
K5 K4 O27 100.9(6) 3_665 3_666
O27 K4 O27 83.2(5) 1_454 3_666
O11W K4 O31 80.0(10) 3_666 3_666
O9W K4 O31 42.4(7) 3_665 3_666
O8W K4 O31 76.4(5) . 3_666
K5 K4 O31 55.1(4) 3_665 3_666
O27 K4 O31 110.5(7) 1_454 3_666
O27 K4 O31 98.1(5) 3_666 3_666
O11W K4 O28 100.5(9) 3_666 1_454
O9W K4 O28 122.1(9) 3_665 1_454
O8W K4 O28 124.9(8) . 1_454
K5 K4 O28 104.0(5) 3_665 1_454
O27 K4 O28 50.9(3) 1_454 1_454
O27 K4 O28 90.3(6) 3_666 1_454
O31 K4 O28 158.6(7) 3_666 1_454
O11W K4 W6 106.3(9) 3_666 1_454
O9W K4 W6 103.1(8) 3_665 1_454
O8W K4 W6 152.1(8) . 1_454
K5 K4 W6 75.8(4) 3_665 1_454
O27 K4 W6 24.9(2) 1_454 1_454
O27 K4 W6 94.1(5) 3_666 1_454
O31 K4 W6 130.8(6) 3_666 1_454
O28 K4 W6 28.3(2) 1_454 1_454
O11W K4 W6 144.0(9) 3_666 3_666
O9W K4 W6 115.8(9) 3_665 3_666
O8W K4 W6 67.1(4) . 3_666
K5 K4 W6 88.3(5) 3_665 3_666
O27 K4 W6 92.0(5) 1_454 3_666
O27 K4 W6 22.9(2) 3_666 3_666
O31 K4 W6 75.2(4) 3_666 3_666
O28 K4 W6 112.1(5) 1_454 3_666
W6 K4 W6 109.6(4) 1_454 3_666
O11W K4 Na1 35.1(8) 3_666 3_666
O9W K4 Na1 34.6(7) 3_665 3_666
O8W K4 Na1 70.9(5) . 3_666
K5 K4 Na1 81.5(5) 3_665 3_666
O27 K4 Na1 130.6(6) 1_454 3_666
O27 K4 Na1 133.6(5) 3_666 3_666
O31 K4 Na1 45.5(3) 3_666 3_666
O28 K4 Na1 134.5(5) 1_454 3_666
W6 K4 Na1 130.4(5) 1_454 3_666
W6 K4 Na1 113.2(4) 3_666 3_666
O11W K4 K4 162.9(11) 3_666 3_565
O9W K4 K4 125.4(11) 3_665 3_565
O8W K4 K4 113.7(7) . 3_565
K5 K4 K4 76.4(5) 3_665 3_565
O27 K4 K4 42.5(3) 1_454 3_565
O27 K4 K4 40.7(4) 3_666 3_565
O31 K4 K4 109.0(7) 3_666 3_565
O28 K4 K4 65.7(5) 1_454 3_565
W6 K4 K4 56.8(3) 1_454 3_565
W6 K4 K4 52.9(3) 3_666 3_565
Na1 K4 K4 153.8(8) 3_666 3_565
O13W K5 O9W 89.0(9) . .
O13W K5 O27 72.7(6) . 3_766
O9W K5 O27 109.7(8) . 3_766
O13W K5 O36 65.4(6) . 3_666
O9W K5 O36 120.6(8) . 3_666
O27 K5 O36 111.6(4) 3_766 3_666
O13W K5 O31 135.1(7) . 1_554
O9W K5 O31 48.9(8) . 1_554
O27 K5 O31 129.8(4) 3_766 1_554
O36 K5 O31 118.1(4) 3_666 1_554
O13W K5 K4 105.8(7) . 3_665
O9W K5 K4 58.4(8) . 3_665
O27 K5 K4 62.9(4) 3_766 3_665
O36 K5 K4 171.1(5) 3_666 3_665
O31 K5 K4 68.6(4) 1_554 3_665
O13W K5 O40 117.5(6) . 1_554
O9W K5 O40 152.6(8) . 1_554
O27 K5 O40 86.2(3) 3_766 1_554
O36 K5 O40 69.9(3) 3_666 1_554
O31 K5 O40 103.7(4) 1_554 1_554
K4 K5 O40 115.3(5) 3_665 1_554
O13W K5 O32 160.6(6) . 1_554
O9W K5 O32 100.9(8) . 1_554
O27 K5 O32 118.3(4) 3_766 1_554
O36 K5 O32 95.2(3) 3_666 1_554
O31 K5 O32 52.0(3) 1_554 1_554
K4 K5 O32 93.7(4) 3_665 1_554
O40 K5 O32 51.7(3) 1_554 1_554
O13W K5 Na2 80.9(6) . 3_766
O9W K5 Na2 161.4(8) . 3_766
O27 K5 Na2 82.3(3) 3_766 3_766
O36 K5 Na2 40.9(2) 3_666 3_766
O31 K5 Na2 133.5(3) 1_554 3_766
K4 K5 Na2 139.5(5) 3_665 3_766
O40 K5 Na2 37.6(2) 1_554 3_766
O32 K5 Na2 84.8(3) 1_554 3_766
O13W K5 W9 141.7(6) . 1_554
O9W K5 W9 128.2(8) . 1_554
O27 K5 W9 98.6(3) 3_766 1_554
O36 K5 W9 85.0(3) 3_666 1_554
O31 K5 W9 79.5(3) 1_554 1_554
K4 K5 W9 102.5(4) 3_665 1_554
O40 K5 W9 24.6(2) 1_554 1_554
O32 K5 W9 27.89(18) 1_554 1_554
Na2 K5 W9 60.85(15) 3_766 1_554
O13W K5 W7 157.4(6) . 1_554
O9W K5 W7 70.6(8) . 1_554
O27 K5 W7 122.8(3) 3_766 1_554
O36 K5 W7 116.1(3) 3_666 1_554
O31 K5 W7 22.6(2) 1_554 1_554
K4 K5 W7 72.5(4) 3_665 1_554
O40 K5 W7 82.1(3) 1_554 1_554
O32 K5 W7 31.02(18) 1_554 1_554
Na2 K5 W7 115.6(2) 3_766 1_554
W9 K5 W7 57.55(11) 1_554 1_554
O13W K5 K1 120.6(6) . .
O9W K5 K1 92.7(8) . .
O27 K5 K1 154.8(3) 3_766 .
O36 K5 K1 63.1(2) 3_666 .
O31 K5 K1 58.1(2) 1_554 .
K4 K5 K1 125.0(4) 3_665 .
O40 K5 K1 68.8(2) 1_554 .
O32 K5 K1 43.09(18) 1_554 .
Na2 K5 K1 79.30(16) 3_766 .
W9 K5 K1 57.31(10) 1_554 .
W7 K5 K1 53.23(9) 1_554 .
K3 K6 O15 117.5(5) . 1_655
K3 K6 O9 139.4(5) . 3_766
O15 K6 O9 94.8(4) 1_655 3_766
K3 K6 K2 112.0(5) . 3_766
O15 K6 K2 97.1(4) 1_655 3_766
O9 K6 K2 85.6(3) 3_766 3_766
K3 K6 O10W 79.6(6) . 1_655
O15 K6 O10W 121.9(8) 1_655 1_655
O9 K6 O10W 61.9(5) 3_766 1_655
K2 K6 O10W 129.1(6) 3_766 1_655
K3 K6 O1 76.3(4) . .
O15 K6 O1 149.1(5) 1_655 .
O9 K6 O1 88.5(4) 3_766 .
K2 K6 O1 52.4(3) 3_766 .
O10W K6 O1 86.6(7) 1_655 .
K3 K6 O11 164.3(6) . 3_766
O15 K6 O11 62.2(3) 1_655 3_766
O9 K6 O11 52.9(3) 3_766 3_766
K2 K6 O11 54.2(3) 3_766 3_766
O10W K6 O11 114.4(6) 1_655 3_766
O1 K6 O11 96.8(4) . 3_766
K3 K6 O21 104.7(5) . 1_655
O15 K6 O21 52.5(3) 1_655 1_655
O9 K6 O21 114.7(4) 3_766 1_655
K2 K6 O21 53.5(3) 3_766 1_655
O10W K6 O21 174.0(8) 1_655 1_655
O1 K6 O21 98.4(4) . 1_655
O11 K6 O21 61.9(3) 3_766 1_655
K3 K6 O4W 48.5(4) . .
O15 K6 O4W 71.2(4) 1_655 .
O9 K6 O4W 162.5(5) 3_766 .
K2 K6 O4W 106.0(4) 3_766 .
O10W K6 O4W 116.1(5) 1_655 .
O1 K6 O4W 108.9(4) . .
O11 K6 O4W 123.8(4) 3_766 .
O21 K6 O4W 65.4(3) 1_655 .
K3 K6 K6 41.6(3) . 4_565
O15 K6 K6 97.6(3) 1_655 4_565
O9 K6 K6 114.8(3) 3_766 4_565
K2 K6 K6 153.6(2) 3_766 4_565
O10W K6 K6 57.4(4) 1_655 4_565
O1 K6 K6 108.9(3) . 4_565
O11 K6 K6 151.7(3) 3_766 4_565
O21 K6 K6 123.2(2) 1_655 4_565
O4W K6 K6 59.0(2) . 4_565
K3 K6 W3 159.3(4) . 3_766
O15 K6 W3 82.7(3) 1_655 3_766
O9 K6 W3 23.9(2) 3_766 3_766
K2 K6 W3 66.8(2) 3_766 3_766
O10W K6 W3 85.7(5) 1_655 3_766
O1 K6 W3 88.3(3) . 3_766
O11 K6 W3 29.56(19) 3_766 3_766
O21 K6 W3 91.1(3) 1_655 3_766
O4W K6 W3 152.1(4) . 3_766
K6 K6 W3 136.90(17) 4_565 3_766
K3 K6 Na3 77.2(3) . 1_655
O15 K6 Na3 40.5(3) 1_655 1_655
O9 K6 Na3 128.2(4) 3_766 1_655
K2 K6 Na3 117.5(3) 3_766 1_655
O10W K6 Na3 113.4(5) 1_655 1_655
O1 K6 Na3 142.9(4) . 1_655
O11 K6 Na3 101.9(3) 3_766 1_655
O21 K6 Na3 64.2(2) 1_655 1_655
O4W K6 Na3 34.7(3) . 1_655
K6 K6 Na3 64.12(16) 4_565 1_655
W3 K6 Na3 122.5(3) 3_766 1_655
O42 Na1 O9W 55.8(7) 3_667 4_576
O42 Na1 O9W 55.8(7) 3_667 1_556
O9W Na1 O9W 44.6(12) 4_576 1_556
O42 Na1 O11W 97.8(9) 3_667 .
O9W Na1 O11W 49.3(9) 4_576 .
O9W Na1 O11W 49.3(9) 1_556 .
O42 Na1 O19 140.8(2) 3_667 .
O9W Na1 O19 132.7(7) 4_576 .
O9W Na1 O19 101.4(7) 1_556 .
O11W Na1 O19 84.1(7) . .
O42 Na1 O19 140.8(2) 3_667 4_575
O9W Na1 O19 101.4(7) 4_576 4_575
O9W Na1 O19 132.7(7) 1_556 4_575
O11W Na1 O19 84.1(7) . 4_575
O19 Na1 O19 78.4(5) . 4_575
O42 Na1 K4 88.4(4) 3_667 2_656
O9W Na1 K4 32.9(7) 4_576 2_656
O9W Na1 K4 63.8(7) 1_556 2_656
O11W Na1 K4 32.9(3) . 2_656
O19 Na1 K4 110.8(4) . 2_656
O19 Na1 K4 72.1(3) 4_575 2_656
O42 Na1 K4 88.4(4) 3_667 3_666
O9W Na1 K4 63.8(7) 4_576 3_666
O9W Na1 K4 32.9(7) 1_556 3_666
O11W Na1 K4 32.9(3) . 3_666
O19 Na1 K4 72.1(3) . 3_666
O19 Na1 K4 110.8(4) 4_575 3_666
K4 Na1 K4 63.3(5) 2_656 3_666
O6W Na2 O40 87.8(5) . 3_767
O6W Na2 O24 81.4(5) . .
O40 Na2 O24 104.5(4) 3_767 .
O6W Na2 O1W 104.0(5) . .
O40 Na2 O1W 167.2(5) 3_767 .
O24 Na2 O1W 82.4(4) . .
O6W Na2 O36 161.2(5) . 1_655
O40 Na2 O36 88.2(4) 3_767 1_655
O24 Na2 O36 81.9(4) . 1_655
O1W Na2 O36 82.1(4) . 1_655
O6W Na2 O2W 114.5(5) . .
O40 Na2 O2W 82.6(4) 3_767 .
O24 Na2 O2W 163.2(5) . .
O1W Na2 O2W 87.9(4) . .
O36 Na2 O2W 83.2(4) 1_655 .
O6W Na2 K5 115.8(4) . 3_766
O40 Na2 K5 51.2(3) 3_767 3_766
O24 Na2 K5 68.3(3) . 3_766
O1W Na2 K5 124.7(4) . 3_766
O36 Na2 K5 49.2(3) 1_655 3_766
O2W Na2 K5 107.0(4) . 3_766
O4W Na3 O16 89.8(5) 1_455 .
O4W Na3 O16 89.8(5) 1_455 4_565
O16 Na3 O16 66.8(5) . 4_565
O4W Na3 O15 96.1(4) 1_455 4_565
O16 Na3 O15 157.7(4) . 4_565
O16 Na3 O15 91.7(3) 4_565 4_565
O4W Na3 O15 96.1(4) 1_455 .
O16 Na3 O15 91.7(3) . .
O16 Na3 O15 157.7(4) 4_565 .
O15 Na3 O15 108.9(5) 4_565 .
O4W Na3 O10 150.2(2) 1_455 .
O16 Na3 O10 71.2(3) . .
O16 Na3 O10 102.7(4) 4_565 .
O15 Na3 O10 110.2(4) 4_565 .
O15 Na3 O10 62.9(3) . .
O4W Na3 O10 150.2(2) 1_455 4_565
O16 Na3 O10 102.7(4) . 4_565
O16 Na3 O10 71.2(3) 4_565 4_565
O15 Na3 O10 62.9(3) 4_565 4_565
O15 Na3 O10 110.2(4) . 4_565
O10 Na3 O10 59.0(4) . 4_565
O4W Na3 O14 129.2(6) 1_455 .
O16 Na3 O14 130.5(4) . .
O16 Na3 O14 130.5(4) 4_565 .
O15 Na3 O14 59.3(3) 4_565 .
O15 Na3 O14 59.3(3) . .
O10 Na3 O14 60.1(3) . .
O10 Na3 O14 60.1(3) 4_565 .
O4W Na3 Si1 165.7(6) 1_455 .
O16 Na3 Si1 78.3(3) . .
O16 Na3 Si1 78.3(3) 4_565 .
O15 Na3 Si1 92.2(3) 4_565 .
O15 Na3 Si1 92.2(3) . .
O10 Na3 Si1 31.0(2) . .
O10 Na3 Si1 31.0(2) 4_565 .
O14 Na3 Si1 65.1(3) . .
O4W Na3 W4 126.1(4) 1_455 4_565
O16 Na3 W4 142.7(4) . 4_565
O16 Na3 W4 100.2(2) 4_565 4_565
O15 Na3 W4 31.6(2) 4_565 4_565
O15 Na3 W4 93.6(3) . 4_565
O10 Na3 W4 78.6(3) . 4_565
O10 Na3 W4 41.4(2) 4_565 4_565
O14 Na3 W4 34.65(10) . 4_565
Si1 Na3 W4 64.70(16) . 4_565
O4W Na3 W4 126.1(4) 1_455 .
O16 Na3 W4 100.2(2) . .
O16 Na3 W4 142.7(4) 4_565 .
O15 Na3 W4 93.6(3) 4_565 .
O15 Na3 W4 31.6(2) . .
O10 Na3 W4 41.4(2) . .
O10 Na3 W4 78.6(3) 4_565 .
O14 Na3 W4 34.65(10) . .
Si1 Na3 W4 64.70(16) . .
W4 Na3 W4 68.30(17) 4_565 .
O4W Na3 Co1 107.4(5) 1_455 .
O16 Na3 Co1 37.3(2) . .
O16 Na3 Co1 37.3(2) 4_565 .
O15 Na3 Co1 120.9(3) 4_565 .
O15 Na3 Co1 120.9(3) . .
O10 Na3 Co1 71.2(3) . .
O10 Na3 Co1 71.2(3) 4_565 .
O14 Na3 Co1 123.4(4) . .
Si1 Na3 Co1 58.29(18) . .
W4 Na3 Co1 112.2(2) 4_565 .
W4 Na3 Co1 112.2(2) . .
W1 O1 K2 161.4(5) . 3_766
W1 O1 K6 123.0(5) . .
K2 O1 K6 57.4(3) 3_766 .
W1 O2 W1 120.4(7) 4_565 .
W1 O2 K3 119.6(3) 4_565 .
W1 O2 K3 119.6(3) . .
W1 O3 W2 119.1(5) . .
W1 O3 K2 99.8(4) . .
W2 O3 K2 98.8(3) . .
W5 O4 W1 147.2(5) . .
Si1 O5 W1 123.8(4) . .
Si1 O5 W1 123.8(4) . 4_565
W1 O5 W1 94.1(4) . 4_565
Si1 O5 W2 119.3(7) . .
W1 O5 W2 94.1(4) . .
W1 O5 W2 94.1(4) 4_565 .
W1 O6 W3 152.7(5) . .
W1 O6 K2 103.3(4) . .
W3 O6 K2 101.5(3) . .
W2 O8 W4 144.6(5) . .
W2 O8 K2 108.9(4) . .
W4 O8 K2 103.5(3) . .
W3 O9 K6 113.9(5) . 3_766
Si1 O10 W4 128.9(5) . .
Si1 O10 W3 127.6(5) . .
W4 O10 W3 92.7(3) . .
Si1 O10 Na3 89.3(4) . .
W4 O10 Na3 84.5(3) . .
W3 O10 Na3 130.0(4) . .
W3 O11 W4 116.5(5) . .
W3 O11 K2 105.5(4) . .
W4 O11 K2 109.0(4) . .
W3 O11 K6 93.1(4) . 3_766
W4 O11 K6 150.2(5) . 3_766
K2 O11 K6 55.4(3) . 3_766
W3 O12 Co2 143.1(5) . .
W4 O13 Co2 157.6(6) . 3_666
W4 O14 W4 161.1(7) . 4_565
W4 O14 Na3 87.4(4) . .
W4 O14 Na3 87.4(4) 4_565 .
W4 O15 Na3 99.1(4) . .
W4 O15 K6 131.9(5) . 1_455
Na3 O15 K6 95.0(4) . 1_455
Co1 O16 Na3 97.0(4) . .
Si1 O17 Co1 117.1(6) . .
Si1 O17 W5 125.9(4) . .
Co1 O17 W5 94.2(4) . .
Si1 O17 W5 125.9(4) . 4_565
Co1 O17 W5 94.2(4) . 4_565
W5 O17 W5 91.1(4) . 4_565
W6 O18 W5 142.6(5) . .
W6 O18 Co1 107.9(4) . .
W5 O18 Co1 107.3(4) . .
Co2 O19 Na1 114.0(4) . .
Co2 O21 K2 123.2(4) . 3_666
Co2 O21 K6 154.2(5) . 1_455
K2 O21 K6 55.5(3) 3_666 1_455
W7 O22 Co2 158.8(5) . .
W5 O23 W5 122.8(7) 4_565 .
W5 O24 Na2 151.1(5) . .
Si2 O25 Co1 117.7(7) . .
Si2 O25 W6 125.5(4) . .
Co1 O25 W6 94.4(4) . .
Si2 O25 W6 125.5(4) . 4_565
Co1 O25 W6 94.4(4) . 4_565
W6 O25 W6 91.0(4) . 4_565
W6 O26 W6 121.0(7) 4_565 .
W6 O27 K5 138.9(5) . 3_766
W6 O27 K4 107.3(6) . 1_656
K5 O27 K4 60.6(5) 3_766 1_656
W6 O27 K4 111.7(6) . 3_666
K5 O27 K4 108.9(5) 3_766 3_666
K4 O27 K4 96.8(5) 1_656 3_666
W6 O28 W9 148.1(5) . .
W6 O28 K4 92.7(5) . 1_656
W9 O28 K4 115.5(5) . 1_656
W7 O29 W6 153.9(5) . .
Si2 O30 W8 125.7(5) . .
Si2 O30 W7 128.8(5) . .
W8 O30 W7 93.2(3) . .
W7 O31 K5 117.4(5) . 1_556
W7 O31 K4 109.2(5) . 3_666
K5 O31 K4 56.2(4) 1_556 3_666
W9 O32 W7 154.0(5) . .
W9 O32 K1 109.6(4) . 1_556
W7 O32 K1 94.9(3) . 1_556
W9 O32 K5 95.4(4) . 1_556
W7 O32 K5 95.4(3) . 1_556
K1 O32 K5 84.9(3) 1_556 1_556
W7 O33 W8 118.0(5) . .
W7 O33 K1 105.8(4) . 1_556
W8 O33 K1 112.2(4) . 1_556
W8 O35 W8 156.7(7) . 4_565
W8 O36 Na2 130.5(5) . 1_455
W8 O36 K5 135.0(5) . 3_666
Na2 O36 K5 90.0(4) 1_455 3_666
Si2 O37 W9 124.6(4) . .
Si2 O37 W9 124.6(4) . 4_565
W9 O37 W9 94.1(4) . 4_565
Si2 O37 W10 119.8(6) . .
W9 O37 W10 92.6(4) . .
W9 O37 W10 92.6(4) 4_565 .
W10 O38 W8 146.5(5) . .
W10 O38 K1 114.5(4) . 1_556
W8 O38 K1 97.2(3) . 1_556
W9 O39 W9 120.5(7) 4_565 .
W9 O40 Na2 150.2(5) . 3_767
W9 O40 K5 108.5(5) . 1_556
Na2 O40 K5 91.3(4) 3_767 1_556
W9 O41 W10 119.0(5) . .
W9 O41 K1 94.6(3) . 1_556
W10 O41 K1 99.0(3) . 1_556
W10 O42 Na1 157.5(8) . 3_667
W5 O43 W3 154.5(5) . .
Na2 O1W K2 133.0(5) . 3_766
Na3 O4W K3 119.4(7) 1_655 .
Na3 O4W K6 87.5(5) 1_655 4_565
K3 O4W K6 43.6(3) . 4_565
Na3 O4W K6 87.5(5) 1_655 .
K3 O4W K6 43.6(3) . .
K6 O4W K6 62.1(5) 4_565 .
K5 O9W K4 72.6(9) . 3_665
K5 O9W Na1 157.0(13) . 1_554
K4 O9W Na1 112.4(11) 3_665 1_554
K6 O10W K6 65.2(8) 1_455 4_465
K4 O11W K4 127.0(17) 2_656 3_666
K4 O11W Na1 112.0(9) 2_656 .
K4 O11W Na1 112.0(9) 3_666 .
O10 Si1 O10 111.1(7) 4_565 .
O10 Si1 O17 110.3(4) 4_565 .
O10 Si1 O17 110.3(4) . .
O10 Si1 O5 108.8(4) 4_565 .
O10 Si1 O5 108.8(4) . .
O17 Si1 O5 107.3(7) . .
O10 Si1 Na3 59.7(3) 4_565 .
O10 Si1 Na3 59.7(3) . .
O17 Si1 Na3 101.2(5) . .
O5 Si1 Na3 151.5(5) . .
O25 Si2 O30 109.2(4) . 4_565
O25 Si2 O30 109.2(4) . .
O30 Si2 O30 114.0(7) 4_565 .
O25 Si2 O37 106.4(7) . .
O30 Si2 O37 108.9(4) 4_565 .
O30 Si2 O37 108.9(4) . .
O1 W1 O6 103.1(4) . .
O1 W1 O3 98.8(4) . .
O6 W1 O3 92.1(4) . .
O1 W1 O2 98.9(5) . .
O6 W1 O2 157.5(4) . .
O3 W1 O2 89.1(5) . .
O1 W1 O4 100.1(4) . .
O6 W1 O4 86.2(4) . .
O3 W1 O4 161.0(4) . .
O2 W1 O4 85.4(5) . .
O1 W1 O5 169.4(4) . .
O6 W1 O5 86.0(4) . .
O3 W1 O5 75.1(4) . .
O2 W1 O5 72.7(4) . .
O4 W1 O5 85.9(4) . .
O1 W1 K2 87.0(3) . .
O6 W1 K2 47.7(3) . .
O3 W1 K2 50.2(3) . .
O2 W1 K2 139.3(4) . .
O4 W1 K2 133.4(3) . .
O5 W1 K2 95.3(3) . .
O1 W1 K3 66.7(3) . .
O6 W1 K3 162.2(3) . .
O3 W1 K3 103.5(3) . .
O2 W1 K3 33.8(3) . .
O4 W1 K3 81.7(3) . .
O5 W1 K3 105.9(2) . .
K2 W1 K3 140.74(15) . .
O7 W2 O8 102.3(4) . 4_565
O7 W2 O8 102.3(4) . .
O8 W2 O8 94.3(6) 4_565 .
O7 W2 O3 97.9(4) . .
O8 W2 O3 158.7(4) 4_565 .
O8 W2 O3 88.0(4) . .
O7 W2 O3 97.9(4) . 4_565
O8 W2 O3 88.0(4) 4_565 4_565
O8 W2 O3 158.7(4) . 4_565
O3 W2 O3 82.5(5) . 4_565
O7 W2 O5 165.6(5) . .
O8 W2 O5 87.4(4) 4_565 .
O8 W2 O5 87.4(4) . .
O3 W2 O5 71.5(3) . .
O3 W2 O5 71.5(3) 4_565 .
O7 W2 K2 87.25(5) . 4_565
O8 W2 K2 44.1(3) 4_565 4_565
O8 W2 K2 138.2(3) . 4_565
O3 W2 K2 131.4(3) . 4_565
O3 W2 K2 49.0(3) 4_565 4_565
O5 W2 K2 92.59(5) . 4_565
O7 W2 K2 87.25(5) . .
O8 W2 K2 138.2(3) 4_565 .
O8 W2 K2 44.1(3) . .
O3 W2 K2 49.0(3) . .
O3 W2 K2 131.4(3) 4_565 .
O5 W2 K2 92.59(5) . .
K2 W2 K2 174.46(10) 4_565 .
O9 W3 O12 102.4(4) . .
O9 W3 O11 98.1(4) . .
O12 W3 O11 97.4(4) . .
O9 W3 O43 100.6(4) . .
O12 W3 O43 90.9(4) . .
O11 W3 O43 157.4(4) . .
O9 W3 O6 93.1(4) . .
O12 W3 O6 163.5(4) . .
O11 W3 O6 85.9(4) . .
O43 W3 O6 80.6(4) . .
O9 W3 O10 169.5(4) . .
O12 W3 O10 85.0(4) . .
O11 W3 O10 73.3(4) . .
O43 W3 O10 86.6(3) . .
O6 W3 O10 80.5(3) . .
O9 W3 K2 79.4(3) . .
O12 W3 K2 141.8(3) . .
O11 W3 K2 45.4(3) . .
O43 W3 K2 126.7(3) . .
O6 W3 K2 46.6(2) . .
O10 W3 K2 90.2(2) . .
O9 W3 K6 42.2(4) . 3_766
O12 W3 K6 115.0(3) . 3_766
O11 W3 K6 57.3(3) . 3_766
O43 W3 K6 136.4(3) . 3_766
O6 W3 K6 80.4(3) . 3_766
O10 W3 K6 127.9(3) . 3_766
K2 W3 K6 43.67(18) . 3_766
O13 W4 O15 103.1(4) . .
O13 W4 O14 98.3(5) . .
O15 W4 O14 93.6(5) . .
O13 W4 O11 99.4(4) . .
O15 W4 O11 99.0(4) . .
O14 W4 O11 155.3(5) . .
O13 W4 O8 89.3(4) . .
O15 W4 O8 167.0(4) . .
O14 W4 O8 80.3(4) . .
O11 W4 O8 82.9(4) . .
O13 W4 O10 169.6(4) . .
O15 W4 O10 86.6(4) . .
O14 W4 O10 84.6(4) . .
O11 W4 O10 75.1(4) . .
O8 W4 O10 81.4(3) . .
O13 W4 Na3 135.6(3) . .
O15 W4 Na3 49.2(3) . .
O14 W4 Na3 57.9(4) . .
O11 W4 Na3 116.8(3) . .
O8 W4 Na3 118.5(3) . .
O10 W4 Na3 54.1(3) . .
O13 W4 K2 80.9(3) . .
O15 W4 K2 141.3(3) . .
O14 W4 K2 124.3(4) . .
O11 W4 K2 43.1(3) . .
O8 W4 K2 44.1(2) . .
O10 W4 K2 89.2(2) . .
Na3 W4 K2 143.30(16) . .
O24 W5 O43 102.2(4) . .
O24 W5 O4 100.8(4) . .
O43 W5 O4 87.8(4) . .
O24 W5 O23 99.9(5) . .
O43 W5 O23 157.8(4) . .
O4 W5 O23 89.9(5) . .
O24 W5 O18 97.5(4) . .
O43 W5 O18 87.6(4) . .
O4 W5 O18 161.6(4) . .
O23 W5 O18 87.6(5) . .
O24 W5 O17 171.5(4) . .
O43 W5 O17 84.8(3) . .
O4 W5 O17 84.2(4) . .
O23 W5 O17 73.0(4) . .
O18 W5 O17 77.7(4) . .
O27 W6 O28 100.9(4) . .
O27 W6 O29 103.1(4) . .
O28 W6 O29 89.2(4) . .
O27 W6 O26 98.6(5) . .
O28 W6 O26 91.3(5) . .
O29 W6 O26 157.8(4) . .
O27 W6 O18 97.1(4) . .
O28 W6 O18 162.1(4) . .
O29 W6 O18 86.3(4) . .
O26 W6 O18 86.5(5) . .
O27 W6 O25 170.8(4) . .
O28 W6 O25 84.8(4) . .
O29 W6 O25 84.0(3) . .
O26 W6 O25 73.9(4) . .
O18 W6 O25 77.5(4) . .
O27 W6 K4 47.8(4) . 1_656
O28 W6 K4 59.0(4) . 1_656
O29 W6 K4 120.8(4) . 1_656
O26 W6 K4 77.8(5) . 1_656
O18 W6 K4 137.2(4) . 1_656
O25 W6 K4 133.0(4) . 1_656
O27 W6 K4 45.4(4) . 3_666
O28 W6 K4 88.4(4) . 3_666
O29 W6 K4 59.3(4) . 3_666
O26 W6 K4 142.9(4) . 3_666
O18 W6 K4 104.1(4) . 3_666
O25 W6 K4 142.9(4) . 3_666
K4 W6 K4 70.4(4) 1_656 3_666
O31 W7 O22 101.7(4) . .
O31 W7 O29 103.5(4) . .
O22 W7 O29 94.3(4) . .
O31 W7 O33 98.2(4) . .
O22 W7 O33 94.6(4) . .
O29 W7 O33 154.2(4) . .
O31 W7 O32 90.3(4) . .
O22 W7 O32 167.9(4) . .
O29 W7 O32 81.8(4) . .
O33 W7 O32 84.5(4) . .
O31 W7 O30 166.5(4) . .
O22 W7 O30 88.9(4) . .
O29 W7 O30 83.7(3) . .
O33 W7 O30 72.4(4) . .
O32 W7 O30 79.4(3) . .
O31 W7 K1 73.6(3) . 1_556
O22 W7 K1 134.0(3) . 1_556
O29 W7 K1 131.6(3) . 1_556
O33 W7 K1 43.5(3) . 1_556
O32 W7 K1 50.4(3) . 1_556
O30 W7 K1 93.1(2) . 1_556
O31 W7 K5 40.0(4) . 1_556
O22 W7 K5 137.5(3) . 1_556
O29 W7 K5 82.3(3) . 1_556
O33 W7 K5 106.6(3) . 1_556
O32 W7 K5 53.6(3) . 1_556
O30 W7 K5 132.3(2) . 1_556
K1 W7 K5 64.58(10) 1_556 1_556
O36 W8 O34 101.8(5) . .
O36 W8 O35 101.2(5) . .
O34 W8 O35 93.7(5) . .
O36 W8 O33 95.6(4) . .
O34 W8 O33 96.5(4) . .
O35 W8 O33 158.1(5) . .
O36 W8 O38 90.9(4) . .
O34 W8 O38 167.3(4) . .
O35 W8 O38 82.4(5) . .
O33 W8 O38 83.5(4) . .
O36 W8 O30 168.4(4) . .
O34 W8 O30 85.8(4) . .
O35 W8 O30 86.9(4) . .
O33 W8 O30 74.6(3) . .
O38 W8 O30 81.9(3) . .
O36 W8 K1 77.5(4) . 1_556
O34 W8 K1 134.3(3) . 1_556
O35 W8 K1 131.7(4) . 1_556
O33 W8 K1 39.5(3) . 1_556
O38 W8 K1 49.7(3) . 1_556
O30 W8 K1 90.9(2) . 1_556
O40 W9 O32 101.9(4) . .
O40 W9 O41 100.2(4) . .
O32 W9 O41 93.9(4) . .
O40 W9 O39 99.9(5) . .
O32 W9 O39 157.5(5) . .
O41 W9 O39 87.6(5) . .
O40 W9 O28 99.4(4) . .
O32 W9 O28 85.6(4) . .
O41 W9 O28 160.0(4) . .
O39 W9 O28 85.5(5) . .
O40 W9 O37 171.3(4) . .
O32 W9 O37 86.1(4) . .
O41 W9 O37 75.4(4) . .
O39 W9 O37 72.6(4) . .
O28 W9 O37 84.6(4) . .
O40 W9 K1 87.1(3) . 1_556
O32 W9 K1 43.9(3) . 1_556
O41 W9 K1 56.0(3) . 1_556
O39 W9 K1 143.6(4) . 1_556
O28 W9 K1 128.9(3) . 1_556
O37 W9 K1 96.4(3) . 1_556
O40 W9 K5 47.0(3) . 1_556
O32 W9 K5 56.8(3) . 1_556
O41 W9 K5 112.8(3) . 1_556
O39 W9 K5 142.1(4) . 1_556
O28 W9 K5 83.5(3) . 1_556
O37 W9 K5 141.6(2) . 1_556
K1 W9 K5 64.46(11) 1_556 1_556
O42 W10 O38 103.9(4) . 4_565
O42 W10 O38 103.9(4) . .
O38 W10 O38 93.6(6) 4_565 .
O42 W10 O41 97.3(4) . .
O38 W10 O41 157.5(4) 4_565 .
O38 W10 O41 88.3(4) . .
O42 W10 O41 97.3(4) . 4_565
O38 W10 O41 88.3(4) 4_565 4_565
O38 W10 O41 157.5(4) . 4_565
O41 W10 O41 81.7(5) . 4_565
O42 W10 O37 166.3(6) . .
O38 W10 O37 85.3(3) 4_565 .
O38 W10 O37 85.3(3) . .
O41 W10 O37 72.6(3) . .
O41 W10 O37 72.6(3) 4_565 .
O42 W10 K1 89.63(3) . 2_646
O38 W10 K1 41.2(3) 4_565 2_646
O38 W10 K1 134.8(3) . 2_646
O41 W10 K1 133.2(3) . 2_646
O41 W10 K1 51.5(3) 4_565 2_646
O37 W10 K1 90.903(17) . 2_646
O42 W10 K1 89.63(3) . 1_556
O38 W10 K1 134.8(3) 4_565 1_556
O38 W10 K1 41.2(3) . 1_556
O41 W10 K1 51.5(3) . 1_556
O41 W10 K1 133.2(3) 4_565 1_556
O37 W10 K1 90.903(17) . 1_556
K1 W10 K1 175.37(2) 2_646 1_556
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Co1 O16 2.089(9) 4_565
Co1 O16 2.089(9) .
Co1 O18 2.096(9) .
Co1 O18 2.096(9) 4_565
Co1 O17 2.127(12) .
Co1 O25 2.128(13) .
Co1 Na3 3.423(10) .
Co2 O12 2.046(9) .
Co2 O13 2.064(10) 3_666
Co2 O22 2.071(10) .
Co2 O19 2.098(10) .
Co2 O21 2.111(10) .
Co2 O20 2.121(10) .
K1 O33 2.621(10) 3_666
K1 O33 2.621(10) 1_554
K1 O32 2.834(9) 3_666
K1 O32 2.834(9) 1_554
K1 O38 2.929(9) 1_554
K1 O38 2.929(9) 3_666
K1 O41 3.205(9) 3_666
K1 O41 3.205(9) 1_554
K1 W7 3.6646(6) 3_666
K1 W7 3.6646(6) 1_554
K1 W8 3.8121(6) 3_666
K1 W8 3.8121(6) 1_554
K2 O1 2.695(10) 3_766
K2 O1W 2.755(11) 3_766
K2 O21 2.795(9) 3_666
K2 O8 2.795(10) .
K2 O11 2.824(10) .
K2 O6 2.828(9) .
K2 K6 2.868(12) 3_766
K2 O3 2.903(10) .
K2 W1 3.722(3) .
K2 W2 3.802(3) .
K2 W3 3.818(3) .
K2 W4 3.905(3) .
K3 K6 2.301(12) 4_565
K3 K6 2.301(12) .
K3 O3W 2.40(2) .
K3 O2 2.412(15) .
K3 O4W 2.499(18) .
K3 W1 3.770(8) 4_565
K3 W1 3.770(8) .
K3 Na3 4.098(12) 1_655
K3 K2 4.296(3) 3_766
K3 K2 4.296(3) 2_746
K4 O11W 2.64(3) 3_666
K4 O9W 2.65(4) 3_665
K4 O8W 2.79(2) .
K4 K5 2.97(2) 3_665
K4 O27 3.033(19) 1_454
K4 O27 3.14(2) 3_666
K4 O31 3.33(2) 3_666
K4 O28 3.35(2) 1_454
K4 W6 3.907(16) 1_454
K4 W6 4.102(18) 3_666
K4 Na1 4.51(2) 3_666
K4 K4 4.62(4) 3_565
K5 O13W 2.13(2) .
K5 O9W 2.35(3) .
K5 O27 2.839(12) 3_766
K5 O36 2.913(13) 3_666
K5 O31 2.931(13) 1_554
K5 K4 2.97(2) 3_665
K5 O40 3.000(12) 1_554
K5 O32 3.270(12) 1_554
K5 Na2 3.850(10) 3_766
K5 W9 3.893(8) 1_554
K5 W7 4.046(8) 1_554
K6 O15 2.774(13) 1_655
K6 O9 2.859(15) 3_766
K6 K2 2.868(12) 3_766
K6 O10W 3.19(3) 1_655
K6 O1 3.201(14) .
K6 O11 3.279(14) 3_766
K6 O21 3.288(15) 1_655
K6 O4W 3.336(17) .
K6 K6 3.44(2) 4_565
K6 W3 3.890(11) 3_766
K6 Na3 3.940(13) 1_655
Na1 O42 2.755(16) 3_667
Na1 O9W 2.77(3) 4_576
Na1 O9W 2.77(3) 1_556
Na1 O11W 2.79(4) .
Na1 O19 2.849(12) .
Na1 O19 2.849(12) 4_575
Na1 K4 4.51(2) 2_656
Na1 K4 4.51(2) 3_666
Na2 O6W 2.344(16) .
Na2 O40 2.348(12) 3_767
Na2 O24 2.401(12) .
Na2 O1W 2.414(13) .
Na2 O36 2.519(12) 1_655
Na2 O2W 2.561(13) .
Na2 K5 3.850(10) 3_766
Na3 O4W 2.247(17) 1_455
Na3 O16 2.469(12) .
Na3 O16 2.469(12) 4_565
Na3 O15 2.566(11) 4_565
Na3 O15 2.566(11) .
Na3 O10 2.723(11) .
Na3 O10 2.723(11) 4_565
Na3 O14 2.838(16) .
Na3 Si1 3.155(9) .
Na3 W4 3.345(7) 4_565
Na3 W4 3.345(7) .
O1 W1 1.734(10) .
O1 K2 2.695(10) 3_766
O2 W1 1.942(6) 4_565
O2 W1 1.942(6) .
O3 W1 1.889(9) .
O3 W2 2.051(9) .
O4 W5 1.877(9) .
O4 W1 1.990(9) .
O5 Si1 1.646(13) .
O5 W1 2.304(8) .
O5 W1 2.304(8) 4_565
O5 W2 2.339(13) .
O6 W1 1.856(8) .
O6 W3 2.064(8) .
O7 W2 1.742(13) .
O8 W2 1.825(9) .
O8 W4 2.152(9) .
O9 W3 1.724(10) .
O9 K6 2.859(15) 3_766
O10 Si1 1.626(9) .
O10 W4 2.223(9) .
O10 W3 2.302(9) .
O11 W3 1.922(9) .
O11 W4 1.930(9) .
O11 K6 3.279(14) 3_766
O12 W3 1.793(9) .
O13 W4 1.756(9) .
O13 Co2 2.064(10) 3_666
O14 W4 1.904(2) .
O14 W4 1.904(2) 4_565
O15 W4 1.777(9) .
O15 K6 2.774(13) 1_455
O17 Si1 1.627(13) .
O17 W5 2.353(8) .
O17 W5 2.353(8) 4_565
O18 W6 1.973(9) .
O18 W5 1.983(9) .
O21 K2 2.795(9) 3_666
O21 K6 3.288(15) 1_455
O22 W7 1.754(10) .
O23 W5 1.912(6) 4_565
O23 W5 1.912(6) .
O24 W5 1.708(10) .
O25 Si2 1.631(13) .
O25 W6 2.350(8) .
O25 W6 2.350(8) 4_565
O26 W6 1.926(6) 4_565
O26 W6 1.926(6) .
O27 W6 1.721(9) .
O27 K5 2.839(12) 3_766
O27 K4 3.033(19) 1_656
O27 K4 3.14(2) 3_666
O28 W6 1.855(9) .
O28 W9 1.995(9) .
O28 K4 3.35(2) 1_656
O29 W7 1.907(8) .
O29 W6 1.907(9) .
O30 Si2 1.634(9) .
O30 W8 2.247(9) .
O30 W7 2.343(9) .
O31 W7 1.749(11) .
O31 K5 2.931(13) 1_556
O31 K4 3.33(2) 3_666
O32 W9 1.829(9) .
O32 W7 2.095(10) .
O32 K1 2.834(9) 1_556
O32 K5 3.270(12) 1_556
O33 W7 1.946(9) .
O33 W8 1.948(9) .
O33 K1 2.621(10) 1_556
O34 W8 1.756(9) .
O35 W8 1.913(3) .
O35 W8 1.913(3) 4_565
O36 W8 1.730(10) .
O36 Na2 2.519(12) 1_455
O36 K5 2.913(13) 3_666
O37 Si2 1.657(13) .
O37 W9 2.317(8) .
O37 W9 2.317(8) 4_565
O37 W10 2.352(12) .
O38 W10 1.830(10) .
O38 W8 2.099(9) .
O38 K1 2.929(9) 1_556
O39 W9 1.953(7) 4_565
O39 W9 1.953(7) .
O40 W9 1.706(10) .
O40 Na2 2.348(12) 3_767
O40 K5 3.000(12) 1_556
O41 W9 1.899(9) .
O41 W10 2.019(10) .
O41 K1 3.205(9) 1_556
O42 W10 1.740(13) .
O42 Na1 2.755(16) 3_667
O43 W5 1.870(9) .
O43 W3 1.940(9) .
O1W K2 2.755(11) 3_766
O4W Na3 2.247(17) 1_655
O4W K6 3.336(17) 4_565
O9W K4 2.65(4) 3_665
O9W Na1 2.77(3) 1_554
O10W K6 3.19(3) 1_455
O10W K6 3.19(3) 4_465
O11W K4 2.64(3) 2_656
O11W K4 2.64(3) 3_666
Si1 O10 1.626(9) 4_565
Si2 O30 1.634(9) 4_565
W2 O8 1.825(9) 4_565
W2 O3 2.051(9) 4_565
W2 K2 3.802(3) 4_565
W3 K6 3.890(11) 3_766
W6 K4 3.907(16) 1_656
W6 K4 4.102(18) 3_666
W7 K1 3.6646(6) 1_556
W7 K5 4.046(8) 1_556
W8 K1 3.8121(6) 1_556
W9 K1 3.8534(6) 1_556
W9 K5 3.893(8) 1_556
W10 O38 1.830(10) 4_565
W10 O41 2.019(10) 4_565
W10 K1 4.0462(4) 2_646
W10 K1 4.0462(4) 1_556
