#------------------------------------------------------------------------------
#$Date: 2016-02-14 06:40:26 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176432 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/39/4333904.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4333904
loop_
_publ_author_name
'Sui-Jun Liu'
'Jiong-Peng Zhao'
'Wei-Chao Song'
'Song-De Han'
'Zhong-Yi Liu'
'Xian-He Bu'
_publ_section_title
;
 Slow Magnetic Relaxation in Two New 1D/0D DyIII Complexes with a
 Sterically Hindered Carboxylate Ligand
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              2103
_journal_page_last               2109
_journal_paper_doi               10.1021/ic302496g
_journal_volume                  52
_journal_year                    2013
_chemical_formula_moiety         'C54 H70 Dy2 N4 O12'
_chemical_formula_sum            'C54 H70 Dy2 N4 O12'
_chemical_formula_weight         1292.14
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                113.06(3)
_cell_angle_beta                 99.57(3)
_cell_angle_gamma                96.94(3)
_cell_formula_units_Z            1
_cell_length_a                   10.321(2)
_cell_length_b                   11.966(2)
_cell_length_c                   12.772(3)
_cell_measurement_reflns_used    14492
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.0
_cell_volume                     1400.7(7)
_computing_cell_refinement       CrystalClear
_computing_data_collection       'CrystalClear (Rigaku/MSC Inc., 2005)'
_computing_data_reduction        CrystalClear
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 0
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1001
_diffrn_reflns_av_sigmaI/netI    0.1042
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            12262
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         3.01
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.708
_exptl_absorpt_correction_T_max  0.7735
_exptl_absorpt_correction_T_min  0.7030
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   CrystalClear
_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    1.532
_exptl_crystal_description       strip
_exptl_crystal_F_000             650
_exptl_crystal_size_max          0.14
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.876
_refine_diff_density_min         -3.325
_refine_diff_density_rms         0.202
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.114
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     334
_refine_ls_number_reflns         4931
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.114
_refine_ls_R_factor_all          0.0654
_refine_ls_R_factor_gt           0.0608
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0723P)²+0.8900P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1545
_refine_ls_wR_factor_ref         0.1587
_reflns_number_gt                4575
_reflns_number_total             4931
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic302496g_si_002_2.cif
_cod_data_source_block           2
_cod_original_sg_symbol_Hall     -P1
_cod_database_code               4333904
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
O6 O 1.0168(6) 0.5655(5) 0.6824(5) 0.0388(13) Uani 1 1 d .
Dy1 Dy 0.88050(3) 0.26691(2) 0.34416(2) 0.02527(16) Uani 1 1 d .
O1 O 0.8957(5) 0.1216(5) 0.4288(5) 0.0385(13) Uani 1 1 d .
O2 O 0.7025(5) 0.1083(5) 0.3204(5) 0.0432(14) Uani 1 1 d .
O3 O 0.7565(6) 0.2336(5) 0.1543(4) 0.0421(13) Uani 1 1 d .
O4 O 0.6931(5) 0.3603(5) 0.3058(5) 0.0371(12) Uani 1 1 d .
O5 O 0.9068(7) 0.3936(5) 0.5336(5) 0.0499(15) Uani 1 1 d .
N1 N 1.1331(6) 0.2734(5) 0.3833(5) 0.0282(13) Uani 1 1 d .
N2 N 0.9516(6) 0.0832(5) 0.2008(5) 0.0307(13) Uani 1 1 d .
C1 C 1.2190(7) 0.3669(7) 0.4708(7) 0.0375(18) Uani 1 1 d .
H1 H 1.1864 0.4271 0.5257 0.045 Uiso 1 1 calc R
C2 C 1.3589(8) 0.3783(7) 0.4834(7) 0.0390(19) Uani 1 1 d .
H2 H 1.4168 0.4457 0.5458 0.047 Uiso 1 1 calc R
C3 C 1.4093(8) 0.2923(8) 0.4058(8) 0.046(2) Uani 1 1 d .
H3 H 1.5015 0.3005 0.4125 0.056 Uiso 1 1 calc R
C4 C 1.3182(8) 0.1892(7) 0.3137(7) 0.0362(18) Uani 1 1 d .
C5 C 1.1817(7) 0.1845(7) 0.3050(6) 0.0285(15) Uani 1 1 d .
C6 C 1.0841(7) 0.0782(7) 0.2111(6) 0.0303(16) Uani 1 1 d .
C7 C 1.1318(9) -0.0198(8) 0.1375(7) 0.0397(19) Uani 1 1 d .
C8 C 1.2735(9) -0.0113(8) 0.1491(8) 0.049(2) Uani 1 1 d .
H8 H 1.3044 -0.0764 0.0980 0.059 Uiso 1 1 calc R
C9 C 1.3638(9) 0.0887(8) 0.2323(8) 0.047(2) Uani 1 1 d .
H9 H 1.4552 0.0923 0.2368 0.056 Uiso 1 1 calc R
C10 C 1.0362(9) -0.1208(8) 0.0522(8) 0.047(2) Uani 1 1 d .
H10 H 1.0629 -0.1896 0.0020 0.056 Uiso 1 1 calc R
C11 C 0.9030(10) -0.1180(8) 0.0432(8) 0.051(2) Uani 1 1 d .
H11 H 0.8379 -0.1854 -0.0120 0.061 Uiso 1 1 calc R
C12 C 0.8658(8) -0.0114(7) 0.1189(7) 0.044(2) Uani 1 1 d .
H12 H 0.7751 -0.0086 0.1096 0.053 Uiso 1 1 calc R
C13 C 0.7754(8) 0.0658(7) 0.3791(7) 0.0322(17) Uani 1 1 d .
C14 C 0.7232(9) -0.0546(8) 0.3883(8) 0.047(2) Uani 1 1 d .
C15 C 0.5803(12) -0.1050(14) 0.3259(16) 0.128(7) Uani 1 1 d .
H15A H 0.5703 -0.1186 0.2455 0.193 Uiso 1 1 calc R
H15B H 0.5271 -0.0470 0.3619 0.193 Uiso 1 1 calc R
H15C H 0.5510 -0.1822 0.3299 0.193 Uiso 1 1 calc R
C16 C 0.746(2) -0.0219(16) 0.5191(14) 0.159(10) Uani 1 1 d .
H16A H 0.7139 0.0522 0.5572 0.238 Uiso 1 1 calc R
H16B H 0.8404 -0.0086 0.5520 0.238 Uiso 1 1 calc R
H16C H 0.6986 -0.0889 0.5303 0.238 Uiso 1 1 calc R
C17 C 0.8084(17) -0.1451(12) 0.3429(19) 0.143(8) Uani 1 1 d .
H17A H 0.8284 -0.1839 0.3950 0.214 Uiso 1 1 calc R
H17B H 0.8905 -0.1029 0.3374 0.214 Uiso 1 1 calc R
H17C H 0.7616 -0.2071 0.2667 0.214 Uiso 1 1 calc R
C18 C 0.9336(7) 0.4653(6) 0.6397(6) 0.0267(15) Uani 1 1 d .
C19 C 0.8652(9) 0.4278(8) 0.7206(7) 0.042(2) Uani 1 1 d .
C20 C 0.8701(15) 0.5414(11) 0.8326(10) 0.089(5) Uani 1 1 d .
H20A H 0.8493 0.5150 0.8909 0.134 Uiso 1 1 calc R
H20B H 0.8058 0.5876 0.8165 0.134 Uiso 1 1 calc R
H20C H 0.9584 0.5929 0.8607 0.134 Uiso 1 1 calc R
C21 C 0.7172(11) 0.3650(11) 0.6581(11) 0.077(3) Uani 1 1 d .
H21A H 0.7131 0.2988 0.5836 0.116 Uiso 1 1 calc R
H21B H 0.6697 0.4249 0.6465 0.116 Uiso 1 1 calc R
H21C H 0.6768 0.3321 0.7052 0.116 Uiso 1 1 calc R
C22 C 0.9356(13) 0.3342(11) 0.7448(11) 0.079(3) Uani 1 1 d .
H22A H 0.9317 0.2653 0.6723 0.118 Uiso 1 1 calc R
H22B H 0.8922 0.3055 0.7932 0.118 Uiso 1 1 calc R
H22C H 1.0276 0.3723 0.7844 0.118 Uiso 1 1 calc R
C23 C 0.6859(8) 0.3136(7) 0.1978(7) 0.0365(18) Uani 1 1 d .
C24 C 0.5991(10) 0.3557(10) 0.1177(8) 0.053(2) Uani 1 1 d .
C25 C 0.6679(15) 0.3690(16) 0.0289(13) 0.113(6) Uani 1 1 d .
H25A H 0.6023 0.3517 -0.0412 0.169 Uiso 1 1 calc R
H25B H 0.7272 0.3117 0.0115 0.169 Uiso 1 1 calc R
H25C H 0.7186 0.4522 0.0588 0.169 Uiso 1 1 calc R
C26 C 0.553(2) 0.4673(19) 0.1839(13) 0.206(14) Uani 1 1 d .
H26A H 0.5324 0.4629 0.2528 0.310 Uiso 1 1 calc R
H26B H 0.4747 0.4737 0.1364 0.310 Uiso 1 1 calc R
H26C H 0.6230 0.5388 0.2062 0.310 Uiso 1 1 calc R
C27 C 0.4764(13) 0.2445(18) 0.0460(13) 0.135(7) Uani 1 1 d .
H27A H 0.4088 0.2506 0.0902 0.203 Uiso 1 1 calc R
H27B H 0.5055 0.1676 0.0309 0.203 Uiso 1 1 calc R
H27C H 0.4398 0.2474 -0.0268 0.203 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C18 O6 Dy1 147.8(5) . 2_766
O5 Dy1 O6 88.5(2) . 2_766
O5 Dy1 O2 100.6(2) . .
O6 Dy1 O2 156.2(2) 2_766 .
O5 Dy1 O1 79.8(2) . .
O6 Dy1 O1 149.20(19) 2_766 .
O2 Dy1 O1 54.59(18) . .
O5 Dy1 O3 140.1(2) . .
O6 Dy1 O3 77.2(2) 2_766 .
O2 Dy1 O3 81.9(2) . .
O1 Dy1 O3 128.65(19) . .
O5 Dy1 O4 86.5(2) . .
O6 Dy1 O4 77.75(19) 2_766 .
O2 Dy1 O4 80.90(18) . .
O1 Dy1 O4 129.15(19) . .
O3 Dy1 O4 54.24(18) . .
O5 Dy1 N2 145.3(2) . .
O6 Dy1 N2 103.7(2) 2_766 .
O2 Dy1 N2 81.2(2) . .
O1 Dy1 N2 73.13(19) . .
O3 Dy1 N2 74.68(19) . .
O4 Dy1 N2 127.61(18) . .
O5 Dy1 N1 88.9(2) . .
O6 Dy1 N1 72.5(2) 2_766 .
O2 Dy1 N1 129.02(19) . .
O1 Dy1 N1 78.78(18) . .
O3 Dy1 N1 120.68(19) . .
O4 Dy1 N1 150.03(19) . .
N2 Dy1 N1 65.03(19) . .
C13 O1 Dy1 92.3(4) . .
C13 O2 Dy1 93.4(4) . .
C23 O3 Dy1 92.6(4) . .
C23 O4 Dy1 92.3(5) . .
C18 O5 Dy1 174.4(6) . .
C1 N1 C5 118.6(6) . .
C1 N1 Dy1 122.0(5) . .
C5 N1 Dy1 119.1(4) . .
C12 N2 C6 117.3(7) . .
C12 N2 Dy1 122.5(5) . .
C6 N2 Dy1 120.1(4) . .
N1 C1 C2 121.9(8) . .
N1 C1 H1 119.1 . .
C2 C1 H1 119.1 . .
C3 C2 C1 120.5(8) . .
C3 C2 H2 119.7 . .
C1 C2 H2 119.7 . .
C2 C3 C4 118.1(8) . .
C2 C3 H3 120.9 . .
C4 C3 H3 120.9 . .
C5 C4 C3 118.5(7) . .
C5 C4 C9 119.8(7) . .
C3 C4 C9 121.7(8) . .
N1 C5 C4 122.3(7) . .
N1 C5 C6 117.6(6) . .
C4 C5 C6 120.0(7) . .
N2 C6 C7 123.9(7) . .
N2 C6 C5 117.5(6) . .
C7 C6 C5 118.5(7) . .
C6 C7 C10 116.9(8) . .
C6 C7 C8 119.7(8) . .
C10 C7 C8 123.4(8) . .
C9 C8 C7 122.0(8) . .
C9 C8 H8 119.0 . .
C7 C8 H8 119.0 . .
C8 C9 C4 119.9(8) . .
C8 C9 H9 120.1 . .
C4 C9 H9 120.1 . .
C11 C10 C7 119.4(8) . .
C11 C10 H10 120.3 . .
C7 C10 H10 120.3 . .
C10 C11 C12 119.0(8) . .
C10 C11 H11 120.5 . .
C12 C11 H11 120.5 . .
N2 C12 C11 123.3(8) . .
N2 C12 H12 118.4 . .
C11 C12 H12 118.4 . .
O2 C13 O1 119.4(7) . .
O2 C13 C14 121.6(7) . .
O1 C13 C14 119.0(7) . .
C15 C14 C17 111.7(12) . .
C15 C14 C16 112.7(11) . .
C17 C14 C16 105.9(13) . .
C15 C14 C13 111.0(8) . .
C17 C14 C13 109.4(9) . .
C16 C14 C13 105.9(8) . .
C14 C15 H15A 109.5 . .
C14 C15 H15B 109.5 . .
H15A C15 H15B 109.5 . .
C14 C15 H15C 109.5 . .
H15A C15 H15C 109.5 . .
H15B C15 H15C 109.5 . .
C14 C16 H16A 109.5 . .
C14 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
C14 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
C14 C17 H17A 109.5 . .
C14 C17 H17B 109.5 . .
H17A C17 H17B 109.5 . .
C14 C17 H17C 109.5 . .
H17A C17 H17C 109.5 . .
H17B C17 H17C 109.5 . .
O5 C18 O6 122.6(7) . .
O5 C18 C19 118.8(6) . .
O6 C18 C19 118.6(6) . .
C22 C19 C18 107.1(7) . .
C22 C19 C20 112.1(9) . .
C18 C19 C20 110.5(7) . .
C22 C19 C21 108.5(9) . .
C18 C19 C21 109.4(7) . .
C20 C19 C21 109.1(9) . .
C19 C20 H20A 109.5 . .
C19 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
C19 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
C19 C21 H21A 109.5 . .
C19 C21 H21B 109.5 . .
H21A C21 H21B 109.5 . .
C19 C21 H21C 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
C19 C22 H22A 109.5 . .
C19 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
C19 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
O4 C23 O3 120.2(7) . .
O4 C23 C24 120.6(7) . .
O3 C23 C24 119.1(7) . .
C26 C24 C25 112.8(14) . .
C26 C24 C23 111.6(9) . .
C25 C24 C23 111.3(8) . .
C26 C24 C27 110.4(14) . .
C25 C24 C27 104.9(10) . .
C23 C24 C27 105.3(9) . .
C24 C25 H25A 109.5 . .
C24 C25 H25B 109.5 . .
H25A C25 H25B 109.5 . .
C24 C25 H25C 109.5 . .
H25A C25 H25C 109.5 . .
H25B C25 H25C 109.5 . .
C24 C26 H26A 109.5 . .
C24 C26 H26B 109.5 . .
H26A C26 H26B 109.5 . .
C24 C26 H26C 109.5 . .
H26A C26 H26C 109.5 . .
H26B C26 H26C 109.5 . .
C24 C27 H27A 109.5 . .
C24 C27 H27B 109.5 . .
H27A C27 H27B 109.5 . .
C24 C27 H27C 109.5 . .
H27A C27 H27C 109.5 . .
H27B C27 H27C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
O6 C18 1.248(8) .
O6 Dy1 2.323(5) 2_766
Dy1 O5 2.244(5) .
Dy1 O6 2.323(5) 2_766
Dy1 O2 2.365(5) .
Dy1 O1 2.387(5) .
Dy1 O3 2.400(5) .
Dy1 O4 2.422(5) .
Dy1 N2 2.532(6) .
Dy1 N1 2.557(6) .
O1 C13 1.263(9) .
O2 C13 1.260(9) .
O3 C23 1.281(9) .
O4 C23 1.254(9) .
O5 C18 1.247(9) .
N1 C1 1.319(9) .
N1 C5 1.359(9) .
N2 C12 1.297(9) .
N2 C6 1.362(9) .
C1 C2 1.409(11) .
C1 H1 0.9300 .
C2 C3 1.347(12) .
C2 H2 0.9300 .
C3 C4 1.416(12) .
C3 H3 0.9300 .
C4 C5 1.386(10) .
C4 C9 1.439(11) .
C5 C6 1.471(10) .
C6 C7 1.390(10) .
C7 C10 1.394(12) .
C7 C8 1.432(12) .
C8 C9 1.355(12) .
C8 H8 0.9300 .
C9 H9 0.9300 .
C10 C11 1.366(13) .
C10 H10 0.9300 .
C11 C12 1.409(11) .
C11 H11 0.9300 .
C12 H12 0.9300 .
C13 C14 1.532(11) .
C14 C15 1.480(13) .
C14 C17 1.480(17) .
C14 C16 1.527(17) .
C15 H15A 0.9600 .
C15 H15B 0.9600 .
C15 H15C 0.9600 .
C16 H16A 0.9600 .
C16 H16B 0.9600 .
C16 H16C 0.9600 .
C17 H17A 0.9600 .
C17 H17B 0.9600 .
C17 H17C 0.9600 .
C18 C19 1.515(10) .
C19 C22 1.507(14) .
C19 C20 1.527(13) .
C19 C21 1.543(13) .
C20 H20A 0.9600 .
C20 H20B 0.9600 .
C20 H20C 0.9600 .
C21 H21A 0.9600 .
C21 H21B 0.9600 .
C21 H21C 0.9600 .
C22 H22A 0.9600 .
C22 H22B 0.9600 .
C22 H22C 0.9600 .
C23 C24 1.521(11) .
C24 C26 1.456(16) .
C24 C25 1.482(16) .
C24 C27 1.570(17) .
C25 H25A 0.9600 .
C25 H25B 0.9600 .
C25 H25C 0.9600 .
C26 H26A 0.9600 .
C26 H26B 0.9600 .
C26 H26C 0.9600 .
C27 H27A 0.9600 .
C27 H27B 0.9600 .
C27 H27C 0.9600 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
O5 Dy1 O1 C13 113.6(5) .
O6 Dy1 O1 C13 -177.0(4) 2_766
O2 Dy1 O1 C13 2.7(4) .
O3 Dy1 O1 C13 -35.0(5) .
O4 Dy1 O1 C13 36.7(5) .
N2 Dy1 O1 C13 -88.4(4) .
N1 Dy1 O1 C13 -155.5(5) .
O5 Dy1 O2 C13 -72.0(5) .
O6 Dy1 O2 C13 176.9(4) 2_766
O1 Dy1 O2 C13 -2.7(4) .
O3 Dy1 O2 C13 148.5(5) .
O4 Dy1 O2 C13 -156.6(5) .
N2 Dy1 O2 C13 72.8(5) .
N1 Dy1 O2 C13 25.3(6) .
O5 Dy1 O3 C23 -7.6(6) .
O6 Dy1 O3 C23 -79.4(5) 2_766
O2 Dy1 O3 C23 89.3(5) .
O1 Dy1 O3 C23 119.5(4) .
O4 Dy1 O3 C23 4.6(4) .
N2 Dy1 O3 C23 172.3(5) .
N1 Dy1 O3 C23 -139.9(4) .
O5 Dy1 O4 C23 167.4(5) .
O6 Dy1 O4 C23 78.2(4) 2_766
O2 Dy1 O4 C23 -91.2(5) .
O1 Dy1 O4 C23 -118.7(4) .
O3 Dy1 O4 C23 -4.7(4) .
N2 Dy1 O4 C23 -19.8(5) .
N1 Dy1 O4 C23 85.8(5) .
O6 Dy1 O5 C18 -63(5) 2_766
O2 Dy1 O5 C18 139(5) .
O1 Dy1 O5 C18 88(6) .
O3 Dy1 O5 C18 -131(5) .
O4 Dy1 O5 C18 -141(6) .
N2 Dy1 O5 C18 49(6) .
N1 Dy1 O5 C18 10(5) .
O5 Dy1 N1 C1 -24.7(6) .
O6 Dy1 N1 C1 64.1(6) 2_766
O2 Dy1 N1 C1 -127.5(5) .
O1 Dy1 N1 C1 -104.6(6) .
O3 Dy1 N1 C1 126.9(5) .
O4 Dy1 N1 C1 56.3(7) .
N2 Dy1 N1 C1 178.9(6) .
O5 Dy1 N1 C5 162.2(5) .
O6 Dy1 N1 C5 -109.0(5) 2_766
O2 Dy1 N1 C5 59.4(6) .
O1 Dy1 N1 C5 82.3(5) .
O3 Dy1 N1 C5 -46.2(6) .
O4 Dy1 N1 C5 -116.8(5) .
N2 Dy1 N1 C5 5.9(5) .
O5 Dy1 N2 C12 130.4(6) .
O6 Dy1 N2 C12 -121.9(6) 2_766
O2 Dy1 N2 C12 34.4(6) .
O1 Dy1 N2 C12 89.9(6) .
O3 Dy1 N2 C12 -49.5(6) .
O4 Dy1 N2 C12 -36.9(7) .
N1 Dy1 N2 C12 175.2(7) .
O5 Dy1 N2 C6 -46.5(7) .
O6 Dy1 N2 C6 61.2(5) 2_766
O2 Dy1 N2 C6 -142.5(5) .
O1 Dy1 N2 C6 -87.0(5) .
O3 Dy1 N2 C6 133.6(5) .
O4 Dy1 N2 C6 146.2(5) .
N1 Dy1 N2 C6 -1.7(5) .
C5 N1 C1 C2 1.5(11) .
Dy1 N1 C1 C2 -171.7(6) .
N1 C1 C2 C3 -0.4(13) .
C1 C2 C3 C4 -1.7(13) .
C2 C3 C4 C5 2.7(12) .
C2 C3 C4 C9 -175.3(9) .
C1 N1 C5 C4 -0.3(10) .
Dy1 N1 C5 C4 173.0(5) .
C1 N1 C5 C6 177.4(6) .
Dy1 N1 C5 C6 -9.3(8) .
C3 C4 C5 N1 -1.8(11) .
C9 C4 C5 N1 176.3(7) .
C3 C4 C5 C6 -179.4(7) .
C9 C4 C5 C6 -1.4(11) .
C12 N2 C6 C7 1.9(11) .
Dy1 N2 C6 C7 179.0(6) .
C12 N2 C6 C5 -179.2(7) .
Dy1 N2 C6 C5 -2.1(8) .
N1 C5 C6 N2 7.6(9) .
C4 C5 C6 N2 -174.7(7) .
N1 C5 C6 C7 -173.5(7) .
C4 C5 C6 C7 4.3(10) .
N2 C6 C7 C10 -3.4(12) .
C5 C6 C7 C10 177.7(7) .
N2 C6 C7 C8 174.5(8) .
C5 C6 C7 C8 -4.4(12) .
C6 C7 C8 C9 1.8(14) .
C10 C7 C8 C9 179.4(9) .
C7 C8 C9 C4 1.2(14) .
C5 C4 C9 C8 -1.4(13) .
C3 C4 C9 C8 176.6(9) .
C6 C7 C10 C11 1.5(13) .
C8 C7 C10 C11 -176.2(9) .
C7 C10 C11 C12 1.5(14) .
C6 N2 C12 C11 1.3(12) .
Dy1 N2 C12 C11 -175.6(7) .
C10 C11 C12 N2 -3.1(14) .
Dy1 O2 C13 O1 4.8(8) .
Dy1 O2 C13 C14 -173.1(7) .
Dy1 O1 C13 O2 -4.7(7) .
Dy1 O1 C13 C14 173.2(7) .
O2 C13 C14 C15 -2.8(14) .
O1 C13 C14 C15 179.4(10) .
O2 C13 C14 C17 120.9(12) .
O1 C13 C14 C17 -57.0(13) .
O2 C13 C14 C16 -125.4(12) .
O1 C13 C14 C16 56.8(13) .
Dy1 O5 C18 O6 47(6) .
Dy1 O5 C18 C19 -131(5) .
Dy1 O6 C18 O5 31.1(14) 2_766
Dy1 O6 C18 C19 -150.6(8) 2_766
O5 C18 C19 C22 77.8(10) .
O6 C18 C19 C22 -100.6(9) .
O5 C18 C19 C20 -159.8(9) .
O6 C18 C19 C20 21.8(12) .
O5 C18 C19 C21 -39.7(11) .
O6 C18 C19 C21 141.9(8) .
Dy1 O4 C23 O3 8.4(7) .
Dy1 O4 C23 C24 -168.5(7) .
Dy1 O3 C23 O4 -8.4(7) .
Dy1 O3 C23 C24 168.5(7) .
O4 C23 C24 C26 11.4(17) .
O3 C23 C24 C26 -165.5(14) .
O4 C23 C24 C25 138.4(10) .
O3 C23 C24 C25 -38.5(13) .
O4 C23 C24 C27 -108.4(10) .
O3 C23 C24 C27 74.7(11) .
