#------------------------------------------------------------------------------
#$Date: 2016-03-23 21:11:09 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179443 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/40/4334091.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4334091
loop_
_publ_author_name
'Saskia Stegmaier'
'Thomas F. Fässler'
_publ_contact_author_address
;Department Chemie
Technische Universität München
Lichtenbergstr. 4
85747 Garching
Germany
;
_publ_contact_author_email       thomas.faessler@lrz.tu-muenchen.de
_publ_contact_author_fax         '+49 89 28913186'
_publ_contact_author_name        'Prof. Dr. Thomas F. Fässler'
_publ_contact_author_phone       '+49 89 28913134'
_publ_section_title
;
 Lithium-Stuffed Diamond Polytype Zn-Tt Structures (Tt = Sn, Ge): The Two
 Lithium-Zinc-Tetrelides Li3Zn2Sn4 and Li2ZnGe3
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              2809
_journal_page_last               2816
_journal_paper_doi               10.1021/ic3011037
_journal_volume                  52
_journal_year                    2013
_chemical_formula_sum            'Li3 Sn4 Zn2'
_chemical_formula_weight         626.32
_space_group_IT_number           194
_symmetry_cell_setting           hexagonal
_symmetry_Int_Tables_number      194
_symmetry_space_group_name_Hall  '-P 6c 2c'
_symmetry_space_group_name_H-M   'P 63/m m c'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           'manual editing of SHELXL-97 cif-file'
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_formula_units_Z            2
_cell_length_a                   4.5282(2)
_cell_length_b                   4.5282(2)
_cell_length_c                   22.119(2)
_cell_measurement_reflns_used    11060
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      59.13
_cell_measurement_theta_min      10.39
_cell_volume                     392.78(4)
_computing_cell_refinement       'STOE X-AREA (STOE, 2004)'
_computing_data_collection       'STOE X-AREA (STOE, 2004)'
_computing_data_reduction        'STOE X-AREA, STOE X-RED (STOE, 2004)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.910
_diffrn_measured_fraction_theta_max 0.910
_diffrn_measurement_device_type  'STOE IPDS 2T imaging plate diffractomter'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0285
_diffrn_reflns_av_sigmaI/netI    0.0080
_diffrn_reflns_limit_h_max       5
_diffrn_reflns_limit_h_min       -5
_diffrn_reflns_limit_k_max       5
_diffrn_reflns_limit_k_min       -5
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            2970
_diffrn_reflns_theta_full        27.09
_diffrn_reflns_theta_max         27.09
_diffrn_reflns_theta_min         5.20
_diffrn_source                   'rotating anode'
_diffrn_source_type              'BRUKER NONIUS FR591'
_exptl_absorpt_coefficient_mu    18.416
_exptl_absorpt_correction_T_max  0.1843
_exptl_absorpt_correction_T_min  0.0852
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details
'STOE X-RED (crystal shape optimized with STOE X-SHAPE)'
_exptl_crystal_colour            'lustrous dark silver'
_exptl_crystal_density_diffrn    5.296
_exptl_crystal_description       'block shaped'
_exptl_crystal_F_000             538
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.04
_refine_diff_density_max         0.915
_refine_diff_density_min         -0.645
_refine_diff_density_rms         0.136
_refine_ls_extinction_coef       0.0044(5)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.580
_refine_ls_matrix_type           full
_refine_ls_number_parameters     16
_refine_ls_number_reflns         208
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.580
_refine_ls_R_factor_all          0.0239
_refine_ls_R_factor_gt           0.0231
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0172P)²+1.1120P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0464
_refine_ls_wR_factor_ref         0.0467
_reflns_number_gt                206
_reflns_number_total             208
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic3011037_si_002_2.cif
_cod_data_source_block           Li3Zn2Sn4
_cod_database_code               4334091
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'-x, -y, z+1/2'
'y, -x+y, z+1/2'
'x-y, x, z+1/2'
'y, x, -z'
'x-y, -y, -z'
'-x, -x+y, -z'
'-y, -x, -z+1/2'
'-x+y, y, -z+1/2'
'x, x-y, -z+1/2'
'-x, -y, -z'
'y, -x+y, -z'
'x-y, x, -z'
'x, y, -z-1/2'
'-y, x-y, -z-1/2'
'-x+y, -x, -z-1/2'
'-y, -x, z'
'-x+y, y, z'
'x, x-y, z'
'y, x, z-1/2'
'x-y, -y, z-1/2'
'-x, -x+y, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Sn1 Sn 0.3333 0.6667 0.52900(3) 0.0154(2) Uani 1 6 d S
Sn2 Sn 0.0000 0.0000 0.18351(3) 0.0127(2) Uani 1 6 d S
Zn1 Zn 0.3333 0.6667 0.65497(5) 0.0166(3) Uani 1 6 d S
Li1 Li 0.3333 0.6667 0.2500 0.016(5) Uani 1 12 d S
Li2 Li 0.3333 0.6667 0.1079(8) 0.034(5) Uani 1 6 d S
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Li Li -0.0003 0.0001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Zn1 Sn1 Sn1 116.14(2) . 13_666
Zn1 Sn1 Sn1 116.14(2) . 13_566
Sn1 Sn1 Sn1 102.06(3) 13_666 13_566
Zn1 Sn1 Sn1 116.14(2) . 13_676
Sn1 Sn1 Sn1 102.06(3) 13_666 13_676
Sn1 Sn1 Sn1 102.06(3) 13_566 13_676
Zn1 Sn1 Li2 180.000(2) . 16_556
Sn1 Sn1 Li2 63.86(2) 13_666 16_556
Sn1 Sn1 Li2 63.86(2) 13_566 16_556
Sn1 Sn1 Li2 63.86(2) 13_676 16_556
Zn1 Sn1 Li2 56.3(3) . 4_665
Sn1 Sn1 Li2 59.9(3) 13_666 4_665
Sn1 Sn1 Li2 128.17(4) 13_566 4_665
Sn1 Sn1 Li2 128.17(4) 13_676 4_665
Li2 Sn1 Li2 123.7(3) 16_556 4_665
Zn1 Sn1 Li2 56.3(3) . 4_675
Sn1 Sn1 Li2 128.17(4) 13_666 4_675
Sn1 Sn1 Li2 128.17(4) 13_566 4_675
Sn1 Sn1 Li2 59.9(3) 13_676 4_675
Li2 Sn1 Li2 123.7(3) 16_556 4_675
Li2 Sn1 Li2 92.1(4) 4_665 4_675
Zn1 Sn1 Li2 56.3(3) . 4_565
Sn1 Sn1 Li2 128.17(4) 13_666 4_565
Sn1 Sn1 Li2 59.9(3) 13_566 4_565
Sn1 Sn1 Li2 128.17(4) 13_676 4_565
Li2 Sn1 Li2 123.7(3) 16_556 4_565
Li2 Sn1 Li2 92.1(4) 4_665 4_565
Li2 Sn1 Li2 92.1(4) 4_675 4_565
Zn1 Sn2 Zn1 114.67(2) 4_554 4_664
Zn1 Sn2 Zn1 114.67(2) 4_554 4_564
Zn1 Sn2 Zn1 114.67(2) 4_664 4_564
Zn1 Sn2 Sn2 103.58(3) 4_554 16_556
Zn1 Sn2 Sn2 103.58(3) 4_664 16_556
Zn1 Sn2 Sn2 103.58(3) 4_564 16_556
Zn1 Sn2 Li1 72.030(15) 4_554 1_445
Zn1 Sn2 Li1 164.22(3) 4_664 1_445
Zn1 Sn2 Li1 72.031(15) 4_564 1_445
Sn2 Sn2 Li1 60.641(10) 16_556 1_445
Zn1 Sn2 Li1 72.031(15) 4_554 1_545
Zn1 Sn2 Li1 72.031(15) 4_664 1_545
Zn1 Sn2 Li1 164.22(3) 4_564 1_545
Sn2 Sn2 Li1 60.642(10) 16_556 1_545
Li1 Sn2 Li1 98.016(12) 1_445 1_545
Zn1 Sn2 Li1 164.22(3) 4_554 .
Zn1 Sn2 Li1 72.031(15) 4_664 .
Zn1 Sn2 Li1 72.031(15) 4_564 .
Sn2 Sn2 Li1 60.640(10) 16_556 .
Li1 Sn2 Li1 98.016(13) 1_445 .
Li1 Sn2 Li1 98.015(13) 1_545 .
Zn1 Sn2 Li2 57.59(2) 4_554 1_445
Zn1 Sn2 Li2 133.8(3) 4_664 1_445
Zn1 Sn2 Li2 57.59(2) 4_564 1_445
Sn2 Sn2 Li2 122.6(3) 16_556 1_445
Li1 Sn2 Li2 62.0(3) 1_445 1_445
Li1 Sn2 Li2 129.14(6) 1_545 1_445
Li1 Sn2 Li2 129.14(6) . 1_445
Zn1 Sn2 Li2 133.8(3) 4_554 .
Zn1 Sn2 Li2 57.59(2) 4_664 .
Zn1 Sn2 Li2 57.59(2) 4_564 .
Sn2 Sn2 Li2 122.6(3) 16_556 .
Li1 Sn2 Li2 129.14(6) 1_445 .
Li1 Sn2 Li2 129.14(6) 1_545 .
Li1 Sn2 Li2 62.0(3) . .
Li2 Sn2 Li2 93.7(4) 1_445 .
Zn1 Sn2 Li2 57.59(2) 4_554 1_545
Zn1 Sn2 Li2 57.59(2) 4_664 1_545
Zn1 Sn2 Li2 133.8(3) 4_564 1_545
Sn2 Sn2 Li2 122.6(3) 16_556 1_545
Li1 Sn2 Li2 129.14(6) 1_445 1_545
Li1 Sn2 Li2 62.0(3) 1_545 1_545
Li1 Sn2 Li2 129.14(6) . 1_545
Li2 Sn2 Li2 93.7(4) 1_445 1_545
Li2 Sn2 Li2 93.7(4) . 1_545
Sn2 Zn1 Sn2 114.67(2) 4_565 4_665
Sn2 Zn1 Sn2 114.67(2) 4_565 4
Sn2 Zn1 Sn2 114.67(2) 4_665 4
Sn2 Zn1 Sn1 103.58(3) 4_565 .
Sn2 Zn1 Sn1 103.58(3) 4_665 .
Sn2 Zn1 Sn1 103.58(3) 4 .
Sn2 Zn1 Li2 171.9(3) 4_565 4_665
Sn2 Zn1 Li2 68.60(14) 4_665 4_665
Sn2 Zn1 Li2 68.60(14) 4 4_665
Sn1 Zn1 Li2 68.3(3) . 4_665
Sn2 Zn1 Li2 68.60(14) 4_565 4_565
Sn2 Zn1 Li2 171.9(3) 4_665 4_565
Sn2 Zn1 Li2 68.60(14) 4 4_565
Sn1 Zn1 Li2 68.3(3) . 4_565
Li2 Zn1 Li2 107.2(4) 4_665 4_565
Sn2 Zn1 Li2 68.60(14) 4_565 4_675
Sn2 Zn1 Li2 68.60(14) 4_665 4_675
Sn2 Zn1 Li2 171.9(3) 4 4_675
Sn1 Zn1 Li2 68.3(3) . 4_675
Li2 Zn1 Li2 107.2(4) 4_665 4_675
Li2 Zn1 Li2 107.2(4) 4_565 4_675
Sn2 Zn1 Li1 127.62(4) 4_565 13_666
Sn2 Zn1 Li1 58.274(14) 4_665 13_666
Sn2 Zn1 Li1 58.274(14) 4 13_666
Sn1 Zn1 Li1 128.800(15) . 13_666
Li2 Zn1 Li1 60.5(3) 4_665 13_666
Li2 Zn1 Li1 126.42(18) 4_565 13_666
Li2 Zn1 Li1 126.42(18) 4_675 13_666
Sn2 Zn1 Li1 58.273(14) 4_565 13_676
Sn2 Zn1 Li1 58.274(14) 4_665 13_676
Sn2 Zn1 Li1 127.62(4) 4 13_676
Sn1 Zn1 Li1 128.800(15) . 13_676
Li2 Zn1 Li1 126.42(18) 4_665 13_676
Li2 Zn1 Li1 126.42(18) 4_565 13_676
Li2 Zn1 Li1 60.5(3) 4_675 13_676
Li1 Zn1 Li1 84.90(2) 13_666 13_676
Sn2 Zn1 Li1 58.273(14) 4_565 13_566
Sn2 Zn1 Li1 127.62(4) 4_665 13_566
Sn2 Zn1 Li1 58.274(14) 4 13_566
Sn1 Zn1 Li1 128.800(15) . 13_566
Li2 Zn1 Li1 126.42(18) 4_665 13_566
Li2 Zn1 Li1 60.5(3) 4_565 13_566
Li2 Zn1 Li1 126.42(18) 4_675 13_566
Li1 Zn1 Li1 84.90(2) 13_666 13_566
Li1 Zn1 Li1 84.90(2) 13_676 13_566
Sn2 Li1 Sn2 98.016(13) 16_566 16_666
Sn2 Li1 Sn2 98.016(13) 16_566 16_556
Sn2 Li1 Sn2 98.016(13) 16_666 16_556
Sn2 Li1 Sn2 128.330(5) 16_566 .
Sn2 Li1 Sn2 128.330(5) 16_666 .
Sn2 Li1 Sn2 58.718(19) 16_556 .
Sn2 Li1 Sn2 58.72(2) 16_566 1_565
Sn2 Li1 Sn2 128.330(5) 16_666 1_565
Sn2 Li1 Sn2 128.330(5) 16_556 1_565
Sn2 Li1 Sn2 98.014(13) . 1_565
Sn2 Li1 Sn2 128.330(5) 16_566 1_665
Sn2 Li1 Sn2 58.72(2) 16_666 1_665
Sn2 Li1 Sn2 128.330(5) 16_556 1_665
Sn2 Li1 Sn2 98.014(13) . 1_665
Sn2 Li1 Sn2 98.013(13) 1_565 1_665
Sn2 Li1 Li2 119.359(10) 16_566 .
Sn2 Li1 Li2 119.359(10) 16_666 .
Sn2 Li1 Li2 119.359(10) 16_556 .
Sn2 Li1 Li2 60.640(10) . .
Sn2 Li1 Li2 60.639(10) 1_565 .
Sn2 Li1 Li2 60.639(10) 1_665 .
Sn2 Li1 Li2 60.642(10) 16_566 16_556
Sn2 Li1 Li2 60.641(10) 16_666 16_556
Sn2 Li1 Li2 60.641(10) 16_556 16_556
Sn2 Li1 Li2 119.359(10) . 16_556
Sn2 Li1 Li2 119.361(10) 1_565 16_556
Sn2 Li1 Li2 119.360(10) 1_665 16_556
Li2 Li1 Li2 180.000(1) . 16_556
Sn2 Li1 Zn1 170.557(18) 16_566 4_664
Sn2 Li1 Zn1 88.143(13) 16_666 4_664
Sn2 Li1 Zn1 88.143(12) 16_556 4_664
Sn2 Li1 Zn1 49.696(5) . 4_664
Sn2 Li1 Zn1 111.838(18) 1_565 4_664
Sn2 Li1 Zn1 49.696(5) 1_665 4_664
Li2 Li1 Zn1 51.199(15) . 4_664
Li2 Li1 Zn1 128.801(15) 16_556 4_664
Sn2 Li1 Zn1 88.143(12) 16_566 4_564
Sn2 Li1 Zn1 170.558(18) 16_666 4_564
Sn2 Li1 Zn1 88.143(12) 16_556 4_564
Sn2 Li1 Zn1 49.697(5) . 4_564
Sn2 Li1 Zn1 49.696(5) 1_565 4_564
Sn2 Li1 Zn1 111.839(18) 1_665 4_564
Li2 Li1 Zn1 51.199(15) . 4_564
Li2 Li1 Zn1 128.801(15) 16_556 4_564
Zn1 Li1 Zn1 84.90(2) 4_664 4_564
Sn2 Li1 Zn1 88.143(12) 16_566 4_674
Sn2 Li1 Zn1 88.143(12) 16_666 4_674
Sn2 Li1 Zn1 170.558(18) 16_556 4_674
Sn2 Li1 Zn1 111.840(18) . 4_674
Sn2 Li1 Zn1 49.696(5) 1_565 4_674
Sn2 Li1 Zn1 49.696(5) 1_665 4_674
Li2 Li1 Zn1 51.199(15) . 4_674
Li2 Li1 Zn1 128.801(15) 16_556 4_674
Zn1 Li1 Zn1 84.90(2) 4_664 4_674
Zn1 Li1 Zn1 84.90(2) 4_564 4_674
Sn2 Li1 Zn1 111.840(18) 16_566 13_666
Sn2 Li1 Zn1 49.697(5) 16_666 13_666
Sn2 Li1 Zn1 49.697(5) 16_556 13_666
Sn2 Li1 Zn1 88.144(12) . 13_666
Sn2 Li1 Zn1 170.559(18) 1_565 13_666
Sn2 Li1 Zn1 88.145(13) 1_665 13_666
Li2 Li1 Zn1 128.802(15) . 13_666
Li2 Li1 Zn1 51.198(15) 16_556 13_666
Zn1 Li1 Zn1 77.60(3) 4_664 13_666
Zn1 Li1 Zn1 134.133(11) 4_564 13_666
Zn1 Li1 Zn1 134.133(11) 4_674 13_666
Sn2 Li1 Zn1 49.696(5) 16_566 13_676
Sn2 Li1 Zn1 49.697(5) 16_666 13_676
Sn2 Li1 Zn1 111.840(18) 16_556 13_676
Sn2 Li1 Zn1 170.558(18) . 13_676
Sn2 Li1 Zn1 88.145(12) 1_565 13_676
Sn2 Li1 Zn1 88.145(13) 1_665 13_676
Li2 Li1 Zn1 128.801(15) . 13_676
Li2 Li1 Zn1 51.199(15) 16_556 13_676
Zn1 Li1 Zn1 134.133(11) 4_664 13_676
Zn1 Li1 Zn1 134.132(11) 4_564 13_676
Zn1 Li1 Zn1 77.60(3) 4_674 13_676
Zn1 Li1 Zn1 84.89(2) 13_666 13_676
Sn2 Li1 Zn1 49.696(5) 16_566 13_566
Sn2 Li1 Zn1 111.840(18) 16_666 13_566
Sn2 Li1 Zn1 49.697(5) 16_556 13_566
Sn2 Li1 Zn1 88.144(12) . 13_566
Sn2 Li1 Zn1 88.145(13) 1_565 13_566
Sn2 Li1 Zn1 170.559(18) 1_665 13_566
Li2 Li1 Zn1 128.801(15) . 13_566
Li2 Li1 Zn1 51.199(15) 16_556 13_566
Zn1 Li1 Zn1 134.133(11) 4_664 13_566
Zn1 Li1 Zn1 77.60(3) 4_564 13_566
Zn1 Li1 Zn1 134.132(10) 4_674 13_566
Zn1 Li1 Zn1 84.89(2) 13_666 13_566
Zn1 Li1 Zn1 84.89(2) 13_676 13_566
Zn1 Li2 Zn1 107.2(4) 4_664 4_674
Zn1 Li2 Zn1 107.2(4) 4_664 4_564
Zn1 Li2 Zn1 107.2(4) 4_674 4_564
Zn1 Li2 Sn1 111.7(3) 4_664 16_556
Zn1 Li2 Sn1 111.7(3) 4_674 16_556
Zn1 Li2 Sn1 111.7(3) 4_564 16_556
Zn1 Li2 Sn2 53.80(16) 4_664 1_665
Zn1 Li2 Sn2 53.80(16) 4_674 1_665
Zn1 Li2 Sn2 125.7(6) 4_564 1_665
Sn1 Li2 Sn2 122.6(3) 16_556 1_665
Zn1 Li2 Sn2 125.7(6) 4_664 1_565
Zn1 Li2 Sn2 53.80(16) 4_674 1_565
Zn1 Li2 Sn2 53.80(16) 4_564 1_565
Sn1 Li2 Sn2 122.6(3) 16_556 1_565
Sn2 Li2 Sn2 93.7(4) 1_665 1_565
Zn1 Li2 Sn2 53.80(16) 4_664 .
Zn1 Li2 Sn2 125.7(6) 4_674 .
Zn1 Li2 Sn2 53.80(16) 4_564 .
Sn1 Li2 Sn2 122.6(3) 16_556 .
Sn2 Li2 Sn2 93.7(4) 1_665 .
Sn2 Li2 Sn2 93.7(4) 1_565 .
Zn1 Li2 Li1 68.3(3) 4_664 .
Zn1 Li2 Li1 68.3(3) 4_674 .
Zn1 Li2 Li1 68.3(3) 4_564 .
Sn1 Li2 Li1 180.0 16_556 .
Sn2 Li2 Li1 57.4(3) 1_665 .
Sn2 Li2 Li1 57.4(3) 1_565 .
Sn2 Li2 Li1 57.4(3) . .
Zn1 Li2 Sn1 55.43(7) 4_664 4_664
Zn1 Li2 Sn1 126.28(13) 4_674 4_664
Zn1 Li2 Sn1 126.28(13) 4_564 4_664
Sn1 Li2 Sn1 56.3(3) 16_556 4_664
Sn2 Li2 Sn1 87.068(12) 1_665 4_664
Sn2 Li2 Sn1 178.9(5) 1_565 4_664
Sn2 Li2 Sn1 87.068(12) . 4_664
Li1 Li2 Sn1 123.7(3) . 4_664
Zn1 Li2 Sn1 126.28(13) 4_664 4_564
Zn1 Li2 Sn1 126.27(13) 4_674 4_564
Zn1 Li2 Sn1 55.43(7) 4_564 4_564
Sn1 Li2 Sn1 56.3(3) 16_556 4_564
Sn2 Li2 Sn1 178.9(5) 1_665 4_564
Sn2 Li2 Sn1 87.067(12) 1_565 4_564
Sn2 Li2 Sn1 87.068(12) . 4_564
Li1 Li2 Sn1 123.7(3) . 4_564
Sn1 Li2 Sn1 92.1(4) 4_664 4_564
Zn1 Li2 Sn1 126.28(13) 4_664 4_674
Zn1 Li2 Sn1 55.43(7) 4_674 4_674
Zn1 Li2 Sn1 126.27(13) 4_564 4_674
Sn1 Li2 Sn1 56.3(3) 16_556 4_674
Sn2 Li2 Sn1 87.068(12) 1_665 4_674
Sn2 Li2 Sn1 87.067(12) 1_565 4_674
Sn2 Li2 Sn1 178.9(5) . 4_674
Li1 Li2 Sn1 123.7(3) . 4_674
Sn1 Li2 Sn1 92.1(4) 4_664 4_674
Sn1 Li2 Sn1 92.1(4) 4_564 4_674
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Sn1 Zn1 2.7862(13) .
Sn1 Sn1 2.9122(5) 13_666
Sn1 Sn1 2.9122(5) 13_566
Sn1 Sn1 2.9122(5) 13_676
Sn1 Li2 3.029(17) 16_556
Sn1 Li2 3.144(10) 4_665
Sn1 Li2 3.144(10) 4_675
Sn1 Li2 3.144(10) 4_565
Sn2 Zn1 2.6895(3) 4_554
Sn2 Zn1 2.6895(3) 4_664
Sn2 Zn1 2.6895(3) 4_564
Sn2 Sn2 2.9413(12) 16_556
Sn2 Li1 2.9996(3) 1_445
Sn2 Li1 2.9996(3) 1_545
Sn2 Li1 2.9996(3) .
Sn2 Li2 3.103(9) 1_445
Sn2 Li2 3.103(9) .
Sn2 Li2 3.103(9) 1_545
Zn1 Sn2 2.6895(3) 4_565
Zn1 Sn2 2.6895(3) 4_665
Zn1 Sn2 2.6895(3) 4
Zn1 Li2 2.814(6) 4_665
Zn1 Li2 2.814(6) 4_565
Zn1 Li2 2.814(6) 4_675
Zn1 Li1 3.3546(7) 13_666
Zn1 Li1 3.3546(7) 13_676
Zn1 Li1 3.3546(7) 13_566
Li1 Sn2 2.9996(3) 16_566
Li1 Sn2 2.9996(3) 16_666
Li1 Sn2 2.9996(3) 16_556
Li1 Sn2 2.9997(3) 1_565
Li1 Sn2 2.9997(3) 1_665
Li1 Li2 3.142(17) .
Li1 Li2 3.142(17) 16_556
Li1 Zn1 3.3546(7) 4_664
Li1 Zn1 3.3546(7) 4_564
Li1 Zn1 3.3546(7) 4_674
Li1 Zn1 3.3546(7) 13_666
Li1 Zn1 3.3547(7) 13_676
Li1 Zn1 3.3547(7) 13_566
Li2 Zn1 2.814(6) 4_664
Li2 Zn1 2.814(6) 4_674
Li2 Zn1 2.814(6) 4_564
Li2 Sn1 3.029(17) 16_556
Li2 Sn2 3.103(9) 1_665
Li2 Sn2 3.103(9) 1_565
Li2 Sn1 3.144(10) 4_664
Li2 Sn1 3.144(10) 4_564
Li2 Sn1 3.144(10) 4_674
