#------------------------------------------------------------------------------
#$Date: 2016-03-23 21:14:58 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179445 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/42/4334264.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4334264
loop_
_publ_author_name
'Daniel M. Whittaker'
'Tamara L. Griffiths'
'Madeleine Helliwell'
'Adam N. Swinburne'
'Louise S. Natrajan'
'Frank W. Lewis'
'Laurence M. Harwood'
'Stephen A. Parry'
'Clint A. Sharrad'
_publ_contact_author_address
;
Centre for Radiochemistry Research
School of Chemistry
University of Manchester
Oxford Road
Manchester
M13 9PL
;
_publ_contact_author_email       daniel.whittaker@postgrad.manchester.ac.uk
_publ_contact_author_name        'Daniel Whittaker'
_publ_contact_author_phone       +441612751405
_publ_section_title
;
 Lanthanide Speciation in Potential SANEX and GANEX Actinide/Lanthanide
 Separations Using Tetra-N-Donor Extractants
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              3429
_journal_page_last               3444
_journal_paper_doi               10.1021/ic301599y
_journal_volume                  52
_journal_year                    2013
_chemical_formula_moiety         'C64 H76 N16 O Tb, 3(N O3), 4(C2 H6 O)'
_chemical_formula_sum            'C72 H100 N19 O14 Tb'
_chemical_formula_weight         1614.63
_chemical_name_systematic        '[Tb(CyMe4-BTBP)2(H2O)](NO3)3.4EtOH'
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             2012-11-15
_audit_creation_method
;
  Olex2 1.2
  (compiled Nov  5 2012 18:22:26, GUI svn.r4372)
;
_cell_angle_alpha                90.00
_cell_angle_beta                 129.4280(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   30.5621(7)
_cell_length_b                   14.8217(4)
_cell_length_c                   23.9083(6)
_cell_measurement_reflns_used    9917
_cell_measurement_temperature    100.15
_cell_measurement_theta_max      66.633
_cell_measurement_theta_min      3.521
_cell_volume                     8365.4(4)
_computing_molecular_graphics
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_publication_material
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_structure_refinement
;
XL, G.M. Sheldrick, Acta Cryst.
(2008). A64, 112-122
;
_computing_structure_solution
;
XS, G.M. Sheldrick, Acta Cryst.
(2008). A64, 112-122
;
_diffrn_ambient_temperature      100.15
_diffrn_measured_fraction_theta_full 0.979
_diffrn_measured_fraction_theta_max 0.979
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_reflns_av_R_equivalents  0.0658
_diffrn_reflns_av_unetI/netI     0.0617
_diffrn_reflns_limit_h_max       36
_diffrn_reflns_limit_h_min       -33
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            25718
_diffrn_reflns_theta_full        66.72
_diffrn_reflns_theta_max         66.72
_diffrn_reflns_theta_min         3.52
_diffrn_source                   'micro-focus sealed tube'
_diffrn_source_current           0.65
_diffrn_source_power             0.02925
_diffrn_source_voltage           45.0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    4.723
_exptl_absorpt_correction_T_max  0.7528
_exptl_absorpt_correction_T_min  0.3405
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
SADABS-2008/1 (Bruker,2008) was used for absorption correction.
wR2(int) was 0.1495 before and 0.0830 after correction.
The Ratio of minimum to maximum transmission is 0.4523.
The λ/2 correction factor is 0.0000.
;
_exptl_crystal_colour            'clear ? yellow'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.282
_exptl_crystal_description       plate
_exptl_crystal_F_000             3368
_exptl_crystal_size_max          0.5
_exptl_crystal_size_mid          0.3
_exptl_crystal_size_min          0.03
_platon_squeeze_details
;
SQUEEZE was performed to remove residual unmodellable ethanol molecules
and water
;
_refine_diff_density_max         1.956
_refine_diff_density_min         -1.849
_refine_diff_density_rms         0.164
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.145
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     469
_refine_ls_number_reflns         7271
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.145
_refine_ls_R_factor_all          0.0944
_refine_ls_R_factor_gt           0.0915
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0853P)²+217.9753P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2363
_refine_ls_wR_factor_ref         0.2381
_reflns_number_gt                6866
_reflns_number_total             7271
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic301599y_si_002_10.cif
_cod_data_source_block           complex10
_cod_database_code               4334264
#BEGIN Tags that were not found in dictionaries:
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  {H27C,H27D} of C27B, {H26A,H26B} of C26A, H18 of C18, H19 of C19, {H1A,H1B}
  of C1, {H2A,H2B} of C2, H13 of C13, H14 of C14, H15 of C15, {H35A,H35B} of
  C35, {H33A,H33B} of C33, {H26C,H26D} of C26B, H20 of C20, {H27A,H27B} of C27A
 At 1.5 times of:
  {H9A,H9B,H9C} of C9, {H36A,H36B,H36C} of C36, {H31A,H31B,H31C} of C31,
  {H10A,H10B,H10C} of C10, {H30A,H30B,H30C} of C30, {H7A,H7B,H7C} of C7, {H8A,
  H8B,H8C} of C8, {H34A,H34B,H34C} of C34, {H32A,H32B,H32C} of C32, {H29A,H29B,
  H29C} of C29
2. Uiso/Uaniso restraints and constraints
Uanis(O2) = Uanis(O3) = Uanis(N9)
Uanis(C29) = Uanis(C30) = Uanis(C32) = Uanis(C31)
Uanis(C34) = Uanis(C33) = Uanis(O7) = Uanis(C36) = Uanis(C35) = Uanis(O8)
3. others
 Sof(O4A)=1-Sof(O4B)=Sof(O5A)=1-Sof(O4B)=Sof(O6A)=1-Sof(O4B)
 Sof(C26A)=Sof(H26A)=Sof(H26B)=1-Sof(H26A)=1-Sof(H26A)=1-Sof(H26A)=Sof(C27A)=
 Sof(H27A)=Sof(H27B)=1-Sof(H26A)=1-Sof(H26A)=1-Sof(H26A)
4.a Secondary CH2 refined with riding coordinates:
 C1(H1A,H1B), C2(H2A,H2B), C26A(H26A,H26B), C26B(H26C,H26D), C27A(H27A,H27B),
 C27B(H27C,H27D), C33(H33A,H33B), C35(H35A,H35B)
4.b Me refined with riding coordinates:
 C7(H7A,H7B,H7C), C8(H8A,H8B,H8C), C9(H9A,H9B,H9C), C10(H10A,H10B,H10C),
 C29(H29A,H29B,H29C), C30(H30A,H30B,H30C), C31(H31A,H31B,H31C), C32(H32A,H32B,
 H32C), C34(H34A,H34B,H34C), C36(H36A,H36B,H36C)
4.c Aromatic/amide H refined with riding coordinates:
 C13(H13), C14(H14), C15(H15), C18(H18), C19(H19), C20(H20)
;
#END Tags that were not found in dictionaries
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 'x, y, z'
2 '-x, y, -z+1/2'
3 'x+1/2, y+1/2, z'
4 '-x+1/2, y+1/2, -z+1/2'
5 '-x, -y, -z'
6 'x, -y, z-1/2'
7 '-x+1/2, -y+1/2, -z'
8 'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Tb1 Tb 0.0000 0.17358(4) 0.2500 0.0116(2) Uani 1 2 d S . .
O1 O 0.0000 0.3360(5) 0.2500 0.0272(18) Uani 1 2 d S . .
O2 O 0.0000 -0.2764(13) 0.2500 0.161(6) Uani 1 2 d S . .
O3 O 0.0390(8) -0.1519(9) 0.2538(10) 0.161(6) Uani 1 1 d . . .
O4A O -0.1597(8) 0.1141(11) -0.0098(9) 0.043(4) Uani 0.572(19) 1 d P A 1
O4B O -0.1274(13) 0.1118(18) 0.0033(14) 0.067(8) Uani 0.428(19) 1 d P A 2
O5A O -0.1056(7) 0.0991(13) -0.0333(11) 0.075(6) Uani 0.572(19) 1 d P A 1
O5B O -0.1400(8) 0.1173(15) -0.0935(11) 0.051(6) Uani 0.428(19) 1 d P A 2
O6A O -0.1861(7) 0.1525(15) -0.1137(8) 0.081(7) Uani 0.572(19) 1 d P A 1
O6B O -0.2010(6) 0.0632(12) -0.0915(10) 0.048(6) Uani 0.428(19) 1 d P A 2
O7 O 0.3359(5) 0.3080(7) 0.2928(6) 0.0843(16) Uani 1 1 d . . .
O8 O -0.0102(5) 0.4567(7) 0.1575(6) 0.0843(16) Uani 1 1 d . . .
N1 N -0.0210(3) 0.2490(4) 0.1006(3) 0.0197(13) Uani 1 1 d . . .
N2 N -0.0488(2) 0.2379(4) 0.1258(3) 0.0168(12) Uani 1 1 d . . .
N3 N -0.1263(3) 0.3230(5) 0.0297(4) 0.0337(18) Uani 1 1 d . . .
N4 N -0.1016(2) 0.2115(4) 0.1810(3) 0.0150(12) Uani 1 1 d . . .
N5 N -0.0468(3) 0.0993(4) 0.2939(3) 0.0177(13) Uani 1 1 d . . .
N6 N 0.0538(2) 0.0444(4) 0.3361(3) 0.0146(12) Uani 1 1 d . . .
N7 N 0.1041(3) 0.0190(4) 0.3553(3) 0.0190(13) Uani 1 1 d . . .
N8 N 0.0631(3) -0.0603(5) 0.4184(4) 0.0280(16) Uani 1 1 d . . .
N9 N 0.0000 -0.1954(19) 0.2500 0.161(6) Uani 1 2 d S . .
N10 N -0.1542(3) 0.1080(6) -0.0562(4) 0.038(2) Uani 1 1 d . . .
C1 C 0.2158(5) -0.1489(8) 0.4735(6) 0.048(3) Uani 1 1 d . . .
H1A H 0.1973 -0.2021 0.4414 0.057 Uiso 1 1 calc R . .
H1B H 0.2567 -0.1522 0.4980 0.057 Uiso 1 1 calc R . .
C2 C 0.2083(5) -0.1529(9) 0.5289(6) 0.055(3) Uani 1 1 d . . .
H2A H 0.2263 -0.0993 0.5607 0.066 Uiso 1 1 calc R . .
H2B H 0.2278 -0.2071 0.5594 0.066 Uiso 1 1 calc R . .
C3 C 0.1451(5) -0.1562(7) 0.4955(6) 0.044(3) Uani 1 1 d . . .
C4 C 0.1137(4) -0.0834(5) 0.4388(4) 0.0249(17) Uani 1 1 d . . .
C5 C 0.1336(3) -0.0434(5) 0.4057(4) 0.0194(15) Uani 1 1 d . . .
C6 C 0.1913(3) -0.0633(6) 0.4272(5) 0.0297(19) Uani 1 1 d . . .
C7 C 0.2291(4) 0.0194(8) 0.4674(8) 0.060(3) Uani 1 1 d . . .
H7A H 0.2123 0.0720 0.4353 0.090 Uiso 1 1 calc R . .
H7B H 0.2668 0.0079 0.4821 0.090 Uiso 1 1 calc R . .
H7C H 0.2326 0.0310 0.5104 0.090 Uiso 1 1 calc R . .
C8 C 0.1845(6) -0.0812(10) 0.3592(7) 0.064(4) Uani 1 1 d . . .
H8A H 0.1593 -0.1329 0.3331 0.096 Uiso 1 1 calc R . .
H8B H 0.2217 -0.0944 0.3729 0.096 Uiso 1 1 calc R . .
H8C H 0.1683 -0.0279 0.3279 0.096 Uiso 1 1 calc R . .
C9 C 0.1428(7) -0.1403(12) 0.5571(7) 0.085(6) Uani 1 1 d . . .
H9A H 0.1032 -0.1391 0.5373 0.128 Uiso 1 1 calc R . .
H9B H 0.1608 -0.0825 0.5807 0.128 Uiso 1 1 calc R . .
H9C H 0.1628 -0.1892 0.5927 0.128 Uiso 1 1 calc R . .
C10 C 0.1169(7) -0.2456(7) 0.4607(9) 0.071(4) Uani 1 1 d . . .
H10A H 0.1364 -0.2935 0.4972 0.107 Uiso 1 1 calc R . .
H10B H 0.1189 -0.2584 0.4221 0.107 Uiso 1 1 calc R . .
H10C H 0.0772 -0.2431 0.4401 0.107 Uiso 1 1 calc R . .
C11 C 0.0357(3) 0.0053(5) 0.3677(4) 0.0203(16) Uani 1 1 d . . .
C12 C -0.0194(3) 0.0363(5) 0.3454(4) 0.0234(17) Uani 1 1 d . . .
C13 C -0.0416(5) -0.0008(7) 0.3765(6) 0.044(3) Uani 1 1 d . . .
H13 H -0.0213 -0.0453 0.4133 0.052 Uiso 1 1 calc R . .
C14 C -0.0937(5) 0.0286(7) 0.3524(7) 0.045(3) Uani 1 1 d . . .
H14 H -0.1097 0.0047 0.3727 0.054 Uiso 1 1 calc R . .
C15 C -0.1227(4) 0.0932(6) 0.2984(5) 0.0305(19) Uani 1 1 d . . .
H15 H -0.1589 0.1138 0.2810 0.037 Uiso 1 1 calc R . .
C16 C -0.0979(3) 0.1276(5) 0.2701(4) 0.0197(16) Uani 1 1 d . . .
C17 C -0.1284(3) 0.1921(5) 0.2080(5) 0.0213(16) Uani 1 1 d . . .
C18 C -0.1819(4) 0.2258(6) 0.1767(5) 0.034(2) Uani 1 1 d . . .
H18 H -0.1995 0.2125 0.1972 0.041 Uiso 1 1 calc R . .
C19 C -0.2091(4) 0.2787(7) 0.1156(6) 0.043(3) Uani 1 1 d . . .
H19 H -0.2449 0.3045 0.0949 0.052 Uiso 1 1 calc R . .
C20 C -0.1841(3) 0.2941(6) 0.0845(5) 0.035(2) Uani 1 1 d . . .
H20 H -0.2033 0.3267 0.0404 0.042 Uiso 1 1 calc R . .
C21 C -0.1291(3) 0.2601(5) 0.1203(4) 0.0213(16) Uani 1 1 d . . .
C22 C -0.1003(3) 0.2749(5) 0.0901(4) 0.0202(16) Uani 1 1 d . . .
C23 C -0.0449(3) 0.2965(6) 0.0405(5) 0.030(2) Uani 1 1 d . B .
C24 C -0.0991(4) 0.3350(7) 0.0042(5) 0.040(2) Uani 1 1 d . B .
C25 C -0.1277(5) 0.3925(11) -0.0638(7) 0.079(5) Uani 1 1 d . . .
C26A C -0.0985(9) 0.344(3) -0.1049(12) 0.036(8) Uani 0.46(4) 1 d P B 1
H26A H -0.0957 0.2777 -0.1029 0.043 Uiso 0.46(4) 1 calc PR B 1
H26B H -0.1159 0.3677 -0.1538 0.043 Uiso 0.46(4) 1 calc PR B 1
C26B C -0.1011(7) 0.403(2) -0.0911(11) 0.039(7) Uani 0.54(4) 1 d P B 2
H26C H -0.0987 0.4685 -0.0959 0.046 Uiso 0.54(4) 1 calc PR B 2
H26D H -0.1267 0.3780 -0.1408 0.046 Uiso 0.54(4) 1 calc PR B 2
C27A C -0.0358(11) 0.401(3) -0.0335(16) 0.034(7) Uani 0.46(4) 1 d P B 1
H27A H -0.0130 0.4235 -0.0468 0.040 Uiso 0.46(4) 1 calc PR B 1
H27B H -0.0420 0.4485 -0.0103 0.040 Uiso 0.46(4) 1 calc PR B 1
C27B C -0.0340(10) 0.359(3) -0.0499(15) 0.044(7) Uani 0.54(4) 1 d P B 2
H27C H -0.0358 0.3221 -0.0860 0.053 Uiso 0.54(4) 1 calc PR B 2
H27D H -0.0075 0.4092 -0.0353 0.053 Uiso 0.54(4) 1 calc PR B 2
C28 C -0.0109(4) 0.3020(8) 0.0142(5) 0.047(3) Uani 1 1 d . . .
C29 C 0.0514(5) 0.3255(12) 0.0777(7) 0.077(2) Uani 1 1 d . B .
H29A H 0.0533 0.3845 0.0977 0.115 Uiso 1 1 calc R . .
H29B H 0.0730 0.3277 0.0602 0.115 Uiso 1 1 calc R . .
H29C H 0.0676 0.2794 0.1154 0.115 Uiso 1 1 calc R . .
C30 C -0.0128(5) 0.2118(12) -0.0156(7) 0.077(2) Uani 1 1 d . B .
H30A H 0.0046 0.1663 0.0228 0.115 Uiso 1 1 calc R . .
H30B H 0.0079 0.2148 -0.0342 0.115 Uiso 1 1 calc R . .
H30C H -0.0523 0.1952 -0.0550 0.115 Uiso 1 1 calc R . .
C31 C -0.1211(5) 0.4949(12) -0.0348(7) 0.077(2) Uani 1 1 d . B .
H31A H -0.1404 0.5000 -0.0143 0.115 Uiso 1 1 calc R . .
H31B H -0.1381 0.5373 -0.0752 0.115 Uiso 1 1 calc R . .
H31C H -0.0809 0.5092 0.0025 0.115 Uiso 1 1 calc R . .
C32 C -0.1908(5) 0.3736(12) -0.1160(7) 0.077(2) Uani 1 1 d . B .
H32A H -0.1973 0.3103 -0.1312 0.115 Uiso 1 1 calc R . .
H32B H -0.2090 0.4127 -0.1586 0.115 Uiso 1 1 calc R . .
H32C H -0.2069 0.3857 -0.0920 0.115 Uiso 1 1 calc R . .
C33 C 0.2789(7) 0.2770(11) 0.2336(9) 0.0843(16) Uani 1 1 d . . .
H33A H 0.2718 0.2192 0.2474 0.101 Uiso 1 1 calc R . .
H33B H 0.2758 0.2658 0.1904 0.101 Uiso 1 1 calc R . .
C34 C 0.2324(7) 0.3481(11) 0.2140(9) 0.0843(16) Uani 1 1 d . . .
H34A H 0.2351 0.3589 0.2565 0.126 Uiso 1 1 calc R . .
H34B H 0.1947 0.3245 0.1743 0.126 Uiso 1 1 calc R . .
H34C H 0.2386 0.4048 0.1989 0.126 Uiso 1 1 calc R . .
C35 C -0.0378(7) 0.5367(11) 0.1471(9) 0.0843(16) Uani 1 1 d . . .
H35A H -0.0473 0.5688 0.1043 0.101 Uiso 1 1 calc R . .
H35B H -0.0129 0.5762 0.1900 0.101 Uiso 1 1 calc R . .
C36 C -0.0914(7) 0.5155(11) 0.1358(9) 0.0843(16) Uani 1 1 d . . .
H36A H -0.0815 0.4968 0.1819 0.126 Uiso 1 1 calc R . .
H36B H -0.1118 0.4666 0.1004 0.126 Uiso 1 1 calc R . .
H36C H -0.1154 0.5693 0.1178 0.126 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Tb Tb -9.1472 9.1891 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Tb1 N2 67.72(14) . 2
O1 Tb1 N2 67.72(14) . .
O1 Tb1 N4 76.93(14) . .
O1 Tb1 N4 76.93(14) . 2
O1 Tb1 N5 116.07(14) . .
O1 Tb1 N5 116.06(14) . 2
O1 Tb1 N6 139.67(13) . 2
O1 Tb1 N6 139.67(14) . .
N2 Tb1 N2 135.4(3) . 2
N4 Tb1 N2 104.6(2) 2 .
N4 Tb1 N2 104.6(2) . 2
N4 Tb1 N2 64.94(19) 2 2
N4 Tb1 N2 64.94(19) . .
N4 Tb1 N4 153.9(3) 2 .
N4 Tb1 N5 64.6(2) . .
N4 Tb1 N5 128.8(2) 2 .
N4 Tb1 N5 64.6(2) 2 2
N4 Tb1 N5 128.9(2) . 2
N4 Tb1 N6 127.44(19) 2 2
N4 Tb1 N6 74.75(19) . 2
N4 Tb1 N6 127.43(19) . .
N4 Tb1 N6 74.75(19) 2 .
N5 Tb1 N2 74.9(2) 2 .
N5 Tb1 N2 126.4(2) . .
N5 Tb1 N2 74.9(2) . 2
N5 Tb1 N2 126.4(2) 2 2
N5 Tb1 N5 127.9(3) . 2
N5 Tb1 N6 64.7(2) 2 2
N5 Tb1 N6 64.7(2) . .
N5 Tb1 N6 76.00(19) 2 .
N5 Tb1 N6 76.00(19) . 2
N6 Tb1 N2 147.72(19) 2 2
N6 Tb1 N2 74.49(19) . 2
N6 Tb1 N2 74.49(19) 2 .
N6 Tb1 N2 147.72(19) . .
N6 Tb1 N6 80.7(3) 2 .
N2 N1 C23 119.0(7) . .
N1 N2 Tb1 120.8(4) . .
N1 N2 C22 119.5(6) . .
C22 N2 Tb1 118.8(5) . .
C24 N3 C22 117.2(7) . .
C17 N4 Tb1 120.9(5) . .
C21 N4 Tb1 120.1(5) . .
C21 N4 C17 118.6(6) . .
C12 N5 Tb1 120.2(5) . .
C12 N5 C16 119.3(6) . .
C16 N5 Tb1 120.3(5) . .
N7 N6 Tb1 120.2(4) . .
C11 N6 Tb1 120.7(5) . .
C11 N6 N7 118.9(6) . .
C5 N7 N6 118.5(6) . .
C4 N8 C11 115.1(7) . .
O2 N9 O3 119.6(14) . .
O2 N9 O3 119.6(14) . 2
O3 N9 O3 121(3) 2 .
O4A N10 O5B 165.4(16) . .
O4A N10 O6A 119.7(12) . .
O4A N10 O6B 84.4(14) . .
O4B N10 O4A 41.0(15) . .
O4B N10 O5A 75(2) . .
O4B N10 O5B 128(2) . .
O4B N10 O6A 144(2) . .
O4B N10 O6B 118.6(18) . .
O5A N10 O4A 115.4(14) . .
O5A N10 O5B 56.2(11) . .
O5A N10 O6A 115.1(13) . .
O5A N10 O6B 139.8(15) . .
O5B N10 O6A 62.0(13) . .
O5B N10 O6B 109.7(14) . .
O6A N10 O6B 77.6(13) . .
H1A C1 H1B 107.7 . .
C2 C1 H1A 108.9 . .
C2 C1 H1B 108.9 . .
C2 C1 C6 113.4(9) . .
C6 C1 H1A 108.9 . .
C6 C1 H1B 108.9 . .
C1 C2 H2A 109.0 . .
C1 C2 H2B 109.0 . .
C1 C2 C3 112.9(9) . .
H2A C2 H2B 107.8 . .
C3 C2 H2A 109.0 . .
C3 C2 H2B 109.0 . .
C4 C3 C2 108.3(8) . .
C4 C3 C9 111.2(8) . .
C4 C3 C10 108.6(9) . .
C9 C3 C2 107.6(10) . .
C10 C3 C2 113.5(9) . .
C10 C3 C9 107.8(11) . .
N8 C4 C3 116.1(7) . .
N8 C4 C5 120.2(7) . .
C5 C4 C3 123.7(8) . .
N7 C5 C4 121.4(7) . .
N7 C5 C6 114.8(7) . .
C4 C5 C6 123.7(7) . .
C1 C6 C7 112.4(9) . .
C5 C6 C1 109.6(7) . .
C5 C6 C7 107.9(7) . .
C5 C6 C8 109.3(8) . .
C8 C6 C1 107.4(8) . .
C8 C6 C7 110.1(10) . .
C6 C7 H7A 109.5 . .
C6 C7 H7B 109.5 . .
C6 C7 H7C 109.5 . .
H7A C7 H7B 109.5 . .
H7A C7 H7C 109.5 . .
H7B C7 H7C 109.5 . .
C6 C8 H8A 109.5 . .
C6 C8 H8B 109.5 . .
C6 C8 H8C 109.5 . .
H8A C8 H8B 109.5 . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
C3 C9 H9A 109.5 . .
C3 C9 H9B 109.5 . .
C3 C9 H9C 109.5 . .
H9A C9 H9B 109.5 . .
H9A C9 H9C 109.5 . .
H9B C9 H9C 109.5 . .
C3 C10 H10A 109.5 . .
C3 C10 H10B 109.5 . .
C3 C10 H10C 109.5 . .
H10A C10 H10B 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
N6 C11 N8 125.7(7) . .
N6 C11 C12 116.9(7) . .
N8 C11 C12 117.4(7) . .
N5 C12 C11 117.0(7) . .
N5 C12 C13 122.1(8) . .
C13 C12 C11 120.9(8) . .
C12 C13 H13 120.8 . .
C14 C13 C12 118.5(9) . .
C14 C13 H13 120.8 . .
C13 C14 H14 120.1 . .
C13 C14 C15 119.7(8) . .
C15 C14 H14 120.1 . .
C14 C15 H15 120.6 . .
C14 C15 C16 118.8(8) . .
C16 C15 H15 120.6 . .
N5 C16 C15 121.6(7) . .
N5 C16 C17 116.3(6) . .
C15 C16 C17 121.9(7) . .
N4 C17 C16 115.2(6) . .
N4 C17 C18 121.8(8) . .
C18 C17 C16 122.9(7) . .
C17 C18 H18 120.5 . .
C19 C18 C17 119.1(8) . .
C19 C18 H18 120.5 . .
C18 C19 H19 120.1 . .
C18 C19 C20 119.9(8) . .
C20 C19 H19 120.1 . .
C19 C20 H20 121.1 . .
C19 C20 C21 117.8(9) . .
C21 C20 H20 121.1 . .
N4 C21 C20 122.6(8) . .
N4 C21 C22 117.2(6) . .
C20 C21 C22 120.2(8) . .
N2 C22 C21 117.0(7) . .
N3 C22 N2 124.0(8) . .
N3 C22 C21 119.0(7) . .
N1 C23 C24 120.2(8) . .
N1 C23 C28 115.1(8) . .
C24 C23 C28 124.6(8) . .
N3 C24 C23 120.0(8) . .
N3 C24 C25 117.7(9) . .
C23 C24 C25 122.3(10) . .
C24 C25 C26A 102.0(13) . .
C24 C25 C31 103.6(11) . .
C26B C25 C24 118.1(14) . .
C26B C25 C26A 29.7(13) . .
C26B C25 C31 98.8(18) . .
C26B C25 C32 118.0(14) . .
C31 C25 C26A 128.2(13) . .
C32 C25 C24 110.0(9) . .
C32 C25 C26A 106.5(14) . .
C32 C25 C31 105.7(13) . .
C25 C26A H26A 114.6 . .
C25 C26A H26B 114.6 . .
H26A C26A H26B 111.7 . .
C27A C26A C25 84(2) . .
C27A C26A H26A 114.6 . .
C27A C26A H26B 114.6 . .
C25 C26B H26C 106.6 . .
C25 C26B H26D 106.6 . .
C25 C26B C27B 123.0(15) . .
H26C C26B H26D 106.5 . .
C27B C26B H26C 106.6 . .
C27B C26B H26D 106.6 . .
C26A C27A H27A 113.7 . .
C26A C27A H27B 113.7 . .
H27A C27A H27B 111.0 . .
C28 C27A C26A 89(2) . .
C28 C27A H27A 113.7 . .
C28 C27A H27B 113.7 . .
C26B C27B H27C 108.7 . .
C26B C27B H27D 108.7 . .
H27C C27B H27D 107.6 . .
C28 C27B C26B 114.4(18) . .
C28 C27B H27C 108.7 . .
C28 C27B H27D 108.7 . .
C23 C28 C27A 101.0(13) . .
C23 C28 C29 110.4(9) . .
C27B C28 C23 117.3(15) . .
C27B C28 C27A 26.2(11) . .
C27B C28 C29 111.7(13) . .
C27B C28 C30 99.4(19) . .
C29 C28 C27A 102.1(12) . .
C30 C28 C23 108.6(9) . .
C30 C28 C27A 125.4(15) . .
C30 C28 C29 108.6(12) . .
C28 C29 H29A 109.5 . .
C28 C29 H29B 109.5 . .
C28 C29 H29C 109.5 . .
H29A C29 H29B 109.5 . .
H29A C29 H29C 109.5 . .
H29B C29 H29C 109.5 . .
C28 C30 H30A 109.5 . .
C28 C30 H30B 109.5 . .
C28 C30 H30C 109.5 . .
H30A C30 H30B 109.5 . .
H30A C30 H30C 109.5 . .
H30B C30 H30C 109.5 . .
C25 C31 H31A 109.5 . .
C25 C31 H31B 109.5 . .
C25 C31 H31C 109.5 . .
H31A C31 H31B 109.5 . .
H31A C31 H31C 109.5 . .
H31B C31 H31C 109.5 . .
C25 C32 H32A 109.5 . .
C25 C32 H32B 109.5 . .
C25 C32 H32C 109.5 . .
H32A C32 H32B 109.5 . .
H32A C32 H32C 109.5 . .
H32B C32 H32C 109.5 . .
O7 C33 H33A 109.2 . .
O7 C33 H33B 109.2 . .
O7 C33 C34 111.9(13) . .
H33A C33 H33B 107.9 . .
C34 C33 H33A 109.2 . .
C34 C33 H33B 109.2 . .
C33 C34 H34A 109.5 . .
C33 C34 H34B 109.5 . .
C33 C34 H34C 109.5 . .
H34A C34 H34B 109.5 . .
H34A C34 H34C 109.5 . .
H34B C34 H34C 109.5 . .
O8 C35 H35A 109.9 . .
O8 C35 H35B 109.9 . .
O8 C35 C36 108.7(14) . .
H35A C35 H35B 108.3 . .
C36 C35 H35A 109.9 . .
C36 C35 H35B 109.9 . .
C35 C36 H36A 109.5 . .
C35 C36 H36B 109.5 . .
C35 C36 H36C 109.5 . .
H36A C36 H36B 109.5 . .
H36A C36 H36C 109.5 . .
H36B C36 H36C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Tb1 O1 2.407(8) .
Tb1 N2 2.516(6) .
Tb1 N2 2.516(6) 2
Tb1 N4 2.485(5) .
Tb1 N4 2.485(5) 2
Tb1 N5 2.504(6) 2
Tb1 N5 2.504(6) .
Tb1 N6 2.512(6) 2
Tb1 N6 2.512(6) .
O2 N9 1.20(3) .
O3 N9 1.31(2) .
O4A N10 1.223(17) .
O4B N10 1.10(3) .
O5A N10 1.221(16) .
O5B N10 1.224(18) .
O6A N10 1.254(17) .
O6B N10 1.289(16) .
O7 C33 1.454(18) .
O8 C35 1.384(19) .
N1 N2 1.326(9) .
N1 C23 1.328(11) .
N2 C22 1.342(10) .
N3 C22 1.329(11) .
N3 C24 1.318(13) .
N4 C17 1.357(10) .
N4 C21 1.334(10) .
N5 C12 1.335(10) .
N5 C16 1.345(10) .
N6 N7 1.348(8) .
N6 C11 1.319(10) .
N7 C5 1.319(10) .
N8 C4 1.337(11) .
N8 C11 1.353(10) .
N9 O3 1.31(2) 2
C1 H1A 0.9900 .
C1 H1B 0.9900 .
C1 C2 1.483(15) .
C1 C6 1.530(12) .
C2 H2A 0.9900 .
C2 H2B 0.9900 .
C2 C3 1.553(16) .
C3 C4 1.507(11) .
C3 C9 1.538(14) .
C3 C10 1.510(18) .
C4 C5 1.400(11) .
C5 C6 1.519(10) .
C6 C7 1.533(15) .
C6 C8 1.527(14) .
C7 H7A 0.9800 .
C7 H7B 0.9800 .
C7 H7C 0.9800 .
C8 H8A 0.9800 .
C8 H8B 0.9800 .
C8 H8C 0.9800 .
C9 H9A 0.9800 .
C9 H9B 0.9800 .
C9 H9C 0.9800 .
C10 H10A 0.9800 .
C10 H10B 0.9800 .
C10 H10C 0.9800 .
C11 C12 1.480(11) .
C12 C13 1.399(12) .
C13 H13 0.9500 .
C13 C14 1.375(14) .
C14 H14 0.9500 .
C14 C15 1.384(14) .
C15 H15 0.9500 .
C15 C16 1.395(11) .
C16 C17 1.494(11) .
C17 C18 1.388(11) .
C18 H18 0.9500 .
C18 C19 1.378(14) .
C19 H19 0.9500 .
C19 C20 1.383(14) .
C20 H20 0.9500 .
C20 C21 1.408(11) .
C21 C22 1.466(11) .
C23 C24 1.411(13) .
C23 C28 1.519(14) .
C24 C25 1.526(13) .
C25 C26A 1.84(4) .
C25 C26B 1.33(2) .
C25 C31 1.63(2) .
C25 C32 1.517(15) .
C26A H26A 0.9900 .
C26A H26B 0.9900 .
C26A C27A 1.77(4) .
C26B H26C 0.9900 .
C26B H26D 0.9900 .
C26B C27B 1.74(4) .
C27A H27A 0.9900 .
C27A H27B 0.9900 .
C27A C28 1.71(3) .
C27B H27C 0.9900 .
C27B H27D 0.9900 .
C27B C28 1.48(3) .
C28 C29 1.544(15) .
C28 C30 1.50(2) .
C29 H29A 0.9800 .
C29 H29B 0.9800 .
C29 H29C 0.9800 .
C30 H30A 0.9800 .
C30 H30B 0.9800 .
C30 H30C 0.9800 .
C31 H31A 0.9800 .
C31 H31B 0.9800 .
C31 H31C 0.9800 .
C32 H32A 0.9800 .
C32 H32B 0.9800 .
C32 H32C 0.9800 .
C33 H33A 0.9900 .
C33 H33B 0.9900 .
C33 C34 1.58(2) .
C34 H34A 0.9800 .
C34 H34B 0.9800 .
C34 H34C 0.9800 .
C35 H35A 0.9900 .
C35 H35B 0.9900 .
C35 C36 1.51(2) .
C36 H36A 0.9800 .
C36 H36B 0.9800 .
C36 H36C 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
Tb1 N2 C22 N3 169.2(6) .
Tb1 N2 C22 C21 -11.2(9) .
Tb1 N4 C17 C16 -14.9(9) .
Tb1 N4 C17 C18 169.0(6) .
Tb1 N4 C21 C20 -171.0(6) .
Tb1 N4 C21 C22 10.9(9) .
Tb1 N5 C12 C11 -7.5(9) .
Tb1 N5 C12 C13 173.8(8) .
Tb1 N5 C16 C15 -174.1(6) .
Tb1 N5 C16 C17 10.5(9) .
Tb1 N6 N7 C5 173.7(5) .
Tb1 N6 C11 N8 -175.2(6) .
Tb1 N6 C11 C12 4.7(9) .
O1 Tb1 N2 N1 95.1(5) .
O1 Tb1 N2 C22 -73.8(5) .
O1 Tb1 N4 C17 -113.1(5) .
O1 Tb1 N4 C21 59.6(5) .
O1 Tb1 N5 C12 -128.1(5) .
O1 Tb1 N5 C16 46.6(6) .
O1 Tb1 N6 N7 -79.2(5) .
O1 Tb1 N6 C11 95.2(6) .
N1 N2 C22 N3 0.1(11) .
N1 N2 C22 C21 179.8(6) .
N1 C23 C24 N3 -0.6(14) .
N1 C23 C24 C25 178.1(11) .
N1 C23 C28 C27A -154.5(13) .
N1 C23 C28 C27B -176.4(18) .
N1 C23 C28 C29 -47.0(13) .
N1 C23 C28 C30 72.0(10) .
N2 Tb1 N2 N1 95.1(5) 2
N2 Tb1 N2 C22 -73.8(5) 2
N2 Tb1 N4 C17 -50.7(6) 2
N2 Tb1 N4 C17 175.6(6) .
N2 Tb1 N4 C21 -11.7(5) .
N2 Tb1 N4 C21 122.1(6) 2
N2 Tb1 N5 C12 151.3(5) .
N2 Tb1 N5 C12 -72.7(6) 2
N2 Tb1 N5 C16 -34.0(6) .
N2 Tb1 N5 C16 101.9(6) 2
N2 Tb1 N6 N7 -100.0(5) 2
N2 Tb1 N6 N7 60.9(6) .
N2 Tb1 N6 C11 74.4(6) 2
N2 Tb1 N6 C11 -124.6(6) .
N2 N1 C23 C24 0.3(12) .
N2 N1 C23 C28 -177.5(7) .
N3 C24 C25 C26A -151.4(12) .
N3 C24 C25 C26B -178.1(19) .
N3 C24 C25 C31 74.0(11) .
N3 C24 C25 C32 -38.7(18) .
N4 Tb1 N2 N1 26.1(6) 2
N4 Tb1 N2 N1 -179.4(6) .
N4 Tb1 N2 C22 11.7(5) .
N4 Tb1 N2 C22 -142.8(5) 2
N4 Tb1 N4 C17 -113.1(5) 2
N4 Tb1 N4 C21 59.6(5) 2
N4 Tb1 N5 C12 -34.0(7) 2
N4 Tb1 N5 C12 172.6(6) .
N4 Tb1 N5 C16 -12.7(5) .
N4 Tb1 N5 C16 140.6(5) 2
N4 Tb1 N6 N7 163.3(5) .
N4 Tb1 N6 N7 -32.4(5) 2
N4 Tb1 N6 C11 -22.3(7) .
N4 Tb1 N6 C11 142.1(6) 2
N4 C17 C18 C19 1.5(14) .
N4 C21 C22 N2 0.3(10) .
N4 C21 C22 N3 -180.0(7) .
N5 Tb1 N2 N1 -158.2(5) .
N5 Tb1 N2 N1 -31.9(5) 2
N5 Tb1 N2 C22 32.9(6) .
N5 Tb1 N2 C22 159.1(6) 2
N5 Tb1 N4 C17 133.8(5) 2
N5 Tb1 N4 C17 14.4(5) .
N5 Tb1 N4 C21 -53.5(6) 2
N5 Tb1 N4 C21 -172.8(6) .
N5 Tb1 N5 C12 51.9(5) 2
N5 Tb1 N5 C16 -133.4(6) 2
N5 Tb1 N6 N7 34.7(5) 2
N5 Tb1 N6 N7 179.6(6) .
N5 Tb1 N6 C11 -150.8(6) 2
N5 Tb1 N6 C11 -5.9(5) .
N5 C12 C13 C14 0.4(16) .
N5 C16 C17 N4 2.7(10) .
N5 C16 C17 C18 178.8(8) .
N6 Tb1 N2 N1 -99.3(5) 2
N6 Tb1 N2 N1 -58.3(7) .
N6 Tb1 N2 C22 132.8(5) .
N6 Tb1 N2 C22 91.8(5) 2
N6 Tb1 N4 C17 30.8(6) .
N6 Tb1 N4 C17 95.9(6) 2
N6 Tb1 N4 C21 -156.5(5) .
N6 Tb1 N4 C21 -91.4(6) 2
N6 Tb1 N5 C12 6.9(5) .
N6 Tb1 N5 C12 93.1(6) 2
N6 Tb1 N5 C16 -178.4(6) .
N6 Tb1 N5 C16 -92.3(6) 2
N6 Tb1 N6 N7 100.8(5) 2
N6 Tb1 N6 C11 -84.8(6) 2
N6 N7 C5 C4 0.4(11) .
N6 N7 C5 C6 -176.3(7) .
N6 C11 C12 N5 1.9(11) .
N6 C11 C12 C13 -179.5(9) .
N7 N6 C11 N8 -0.7(12) .
N7 N6 C11 C12 179.2(6) .
N7 C5 C6 C1 -168.3(8) .
N7 C5 C6 C7 68.9(10) .
N7 C5 C6 C8 -50.8(11) .
N8 C4 C5 N7 1.6(12) .
N8 C4 C5 C6 177.9(8) .
N8 C11 C12 N5 -178.2(7) .
N8 C11 C12 C13 0.4(13) .
C1 C2 C3 C4 -48.2(13) .
C1 C2 C3 C9 -168.5(11) .
C1 C2 C3 C10 72.4(12) .
C2 C1 C6 C5 -43.4(13) .
C2 C1 C6 C7 76.7(12) .
C2 C1 C6 C8 -162.1(11) .
C2 C3 C4 N8 -162.7(9) .
C2 C3 C4 C5 20.1(13) .
C3 C4 C5 N7 178.7(8) .
C3 C4 C5 C6 -4.9(13) .
C4 N8 C11 N6 2.5(12) .
C4 N8 C11 C12 -177.4(7) .
C4 C5 C6 C1 15.1(12) .
C4 C5 C6 C7 -107.7(10) .
C4 C5 C6 C8 132.6(10) .
C6 C1 C2 C3 63.4(14) .
C9 C3 C4 N8 -44.7(14) .
C9 C3 C4 C5 138.1(11) .
C10 C3 C4 N8 73.7(10) .
C10 C3 C4 C5 -103.5(11) .
C11 N6 N7 C5 -0.8(10) .
C11 N8 C4 C3 179.8(8) .
C11 N8 C4 C5 -2.8(12) .
C11 C12 C13 C14 -178.2(10) .
C12 N5 C16 C15 0.6(11) .
C12 N5 C16 C17 -174.8(7) .
C12 C13 C14 C15 0.3(17) .
C13 C14 C15 C16 -0.5(16) .
C14 C15 C16 N5 0.1(13) .
C14 C15 C16 C17 175.2(9) .
C15 C16 C17 N4 -172.7(7) .
C15 C16 C17 C18 3.4(13) .
C16 N5 C12 C11 177.8(7) .
C16 N5 C12 C13 -0.9(13) .
C16 C17 C18 C19 -174.3(9) .
C17 N4 C21 C20 1.9(11) .
C17 N4 C21 C22 -176.2(7) .
C17 C18 C19 C20 2.9(15) .
C18 C19 C20 C21 -4.7(15) .
C19 C20 C21 N4 2.4(14) .
C19 C20 C21 C22 -179.6(8) .
C20 C21 C22 N2 -177.8(7) .
C20 C21 C22 N3 1.9(12) .
C21 N4 C17 C16 172.2(7) .
C21 N4 C17 C18 -3.9(11) .
C22 N3 C24 C23 0.6(14) .
C22 N3 C24 C25 -178.2(10) .
C23 N1 N2 Tb1 -168.9(6) .
C23 N1 N2 C22 -0.1(10) .
C23 C24 C25 C26A 29.8(16) .
C23 C24 C25 C26B 3(3) .
C23 C24 C25 C31 -104.8(12) .
C23 C24 C25 C32 142.6(13) .
C24 N3 C22 N2 -0.4(13) .
C24 N3 C22 C21 179.9(8) .
C24 C23 C28 C27A 27.8(16) .
C24 C23 C28 C27B 6(2) .
C24 C23 C28 C29 135.4(11) .
C24 C23 C28 C30 -105.7(12) .
C24 C25 C26A C27A -73.3(17) .
C24 C25 C26B C27B -3(4) .
C25 C26A C27A C28 97.8(16) .
C25 C26B C27B C28 5(5) .
C26A C25 C26B C27B -66(3) .
C26A C27A C28 C23 -76.4(18) .
C26A C27A C28 C27B 55(3) .
C26A C27A C28 C29 169.7(16) .
C26A C27A C28 C30 46(2) .
C26B C25 C26A C27A 53(2) .
C26B C27B C28 C23 -6(4) .
C26B C27B C28 C27A -62(4) .
C26B C27B C28 C29 -134(3) .
C26B C27B C28 C30 111(3) .
C28 C23 C24 N3 176.9(9) .
C28 C23 C24 C25 -4.3(17) .
C31 C25 C26A C27A 45.1(19) .
C31 C25 C26B C27B 107(3) .
C32 C25 C26A C27A 171.4(15) .
C32 C25 C26B C27B -140(3) .
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 0.342 0.065 0.220 165 32 ' '
2 0.342 -0.065 0.720 165 32 ' '
3 0.658 0.065 0.280 165 32 ' '
4 0.658 -0.065 0.780 165 32 ' '
5 0.158 0.435 0.780 165 32 ' '
6 0.842 0.435 0.720 165 32 ' '
7 0.158 0.565 0.280 165 32 ' '
8 0.842 0.565 0.220 165 32 ' '
