#------------------------------------------------------------------------------
#$Date: 2016-03-23 21:14:58 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179445 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/42/4334275.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4334275
loop_
_publ_author_name
'Igor O. Koshevoy'
'Antti J. Karttunen'
'Ilya S. Kritchenkou'
'Dmitrii V. Krupenya'
'Stanislav I. Selivanov'
'Alexei S. Melnikov'
'Sergey P. Tunik'
'Matti Haukka'
'Tapani A. Pakkanen'
_publ_section_title
;
 Sky-Blue Luminescent AuI-AgI Alkynyl-Phosphine Clusters
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              3663
_journal_page_last               3673
_journal_paper_doi               10.1021/ic302105a
_journal_volume                  52
_journal_year                    2013
_chemical_formula_moiety
'2(C264 H228 Ag4 Au12 P12), 8(F6 P), 27(C3 H6 O)'
_chemical_formula_sum            'C611 H624 Ag8 Au24 F48 O28 P32'
_chemical_formula_weight         15908.30
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 117.1250(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   39.2864(4)
_cell_length_b                   32.6616(4)
_cell_length_c                   27.3632(3)
_cell_measurement_reflns_used    9883
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      28.65
_cell_measurement_theta_min      2.40
_cell_volume                     31249.5(7)
_computing_cell_refinement       'SAINT (Bruker AXS, 2009)'
_computing_data_collection       'APEX2 (Bruker AXS, 2010)'
_computing_data_reduction        'SAINT (Bruker AXS, 2009)'
_computing_molecular_graphics    'Diamond v.3.2g (Brandenburg, 2011)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 16
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device       '62mm x 62mm CCD camera on κ-goniostat'
_diffrn_measurement_device_type  'Bruker KAPPA APEX II CCD'
_diffrn_measurement_method       'φ scans and ω scans with κ offset'
_diffrn_radiation_monochromator  'horizontally mounted graphite crystal'
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0418
_diffrn_reflns_av_sigmaI/netI    0.0370
_diffrn_reflns_limit_h_max       47
_diffrn_reflns_limit_h_min       -47
_diffrn_reflns_limit_k_max       39
_diffrn_reflns_limit_k_min       -39
_diffrn_reflns_limit_l_max       33
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_number            121291
_diffrn_reflns_theta_full        25.50
_diffrn_reflns_theta_max         25.50
_diffrn_reflns_theta_min         2.09
_exptl_absorpt_coefficient_mu    6.003
_exptl_absorpt_correction_T_max  0.4285
_exptl_absorpt_correction_T_min  0.2940
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 2008)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.691
_exptl_crystal_description       block
_exptl_crystal_F_000             15396
_exptl_crystal_size_max          0.27
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.17
_refine_diff_density_max         2.828
_refine_diff_density_min         -1.584
_refine_diff_density_rms         0.157
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.051
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1700
_refine_ls_number_reflns         29073
_refine_ls_number_restraints     154
_refine_ls_restrained_S_all      1.052
_refine_ls_R_factor_all          0.0557
_refine_ls_R_factor_gt           0.0369
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0427P)²+439.7368P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0899
_refine_ls_wR_factor_ref         0.1000
_reflns_number_gt                23230
_reflns_number_total             29073
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic302105a_si_002_1.cif
_cod_data_source_block           1
_cod_original_cell_volume        31249.5(6)
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               4334275
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.7572(2) 0.3388(2) 0.8172(3) 0.0330(18) Uani 1 1 d . A .
C2 C 0.7699(2) 0.3607(2) 0.7930(3) 0.0344(18) Uani 1 1 d . A .
C3 C 0.7208(2) 0.2548(2) 0.8884(3) 0.0312(17) Uani 1 1 d . A .
C4 C 0.70858(19) 0.2281(2) 0.9072(3) 0.0277(16) Uani 1 1 d . A .
C5 C 0.7829(2) 0.2546(2) 0.7329(3) 0.0329(18) Uani 1 1 d . A .
C6 C 0.8076(2) 0.2694(2) 0.7244(3) 0.0297(17) Uani 1 1 d . . .
C7 C 0.7023(2) 0.1913(2) 0.7506(3) 0.0262(16) Uani 1 1 d . A .
C8 C 0.6749(2) 0.1714(3) 0.7449(3) 0.0322(18) Uani 1 1 d . . .
C11 C 0.7960(2) 0.1643(3) 0.8837(3) 0.0310(18) Uani 1 1 d . A .
C12 C 0.7803(2) 0.1315(3) 0.8784(3) 0.0332(18) Uani 1 1 d . . .
C13 C 0.7846(2) 0.3851(2) 0.7637(3) 0.0355(18) Uani 1 1 d . . .
C14 C 0.7644(3) 0.3894(3) 0.7070(4) 0.046(2) Uani 1 1 d . . .
H14 H 0.7398 0.3771 0.6876 0.056 Uiso 1 1 calc R . .
C15 C 0.7799(3) 0.4115(3) 0.6787(4) 0.057(3) Uani 1 1 d . . .
H15 H 0.7660 0.4141 0.6400 0.068 Uiso 1 1 calc R . .
C16 C 0.8146(3) 0.4294(3) 0.7054(4) 0.059(3) Uani 1 1 d . . .
H16 H 0.8250 0.4442 0.6855 0.070 Uiso 1 1 calc R . .
C17 C 0.8349(3) 0.4261(3) 0.7618(4) 0.052(2) Uani 1 1 d . . .
H17 H 0.8592 0.4389 0.7806 0.062 Uiso 1 1 calc R . .
C18 C 0.8202(2) 0.4044(3) 0.7910(4) 0.041(2) Uani 1 1 d . . .
H18 H 0.8343 0.4026 0.8298 0.049 Uiso 1 1 calc R . .
C19 C 0.6929(2) 0.1982(2) 0.9301(3) 0.0317(17) Uani 1 1 d . . .
C20 C 0.7002(2) 0.2009(2) 0.9852(3) 0.0315(17) Uani 1 1 d . . .
H20 H 0.7145 0.2232 1.0073 0.038 Uiso 1 1 calc R . .
C21 C 0.6863(2) 0.1707(3) 1.0071(4) 0.040(2) Uani 1 1 d . . .
H21 H 0.6912 0.1723 1.0444 0.048 Uiso 1 1 calc R . .
C22 C 0.6654(2) 0.1384(3) 0.9750(4) 0.045(2) Uani 1 1 d . . .
H22 H 0.6563 0.1175 0.9904 0.054 Uiso 1 1 calc R . .
C23 C 0.6576(2) 0.1364(3) 0.9205(4) 0.047(2) Uani 1 1 d . . .
H23 H 0.6430 0.1142 0.8984 0.056 Uiso 1 1 calc R . .
C24 C 0.6708(2) 0.1660(3) 0.8981(4) 0.041(2) Uani 1 1 d . . .
H24 H 0.6648 0.1646 0.8604 0.049 Uiso 1 1 calc R . .
C25 C 0.8386(2) 0.2829(3) 0.7142(3) 0.0356(18) Uani 1 1 d . . .
C26 C 0.8501(3) 0.3235(3) 0.7209(4) 0.051(2) Uani 1 1 d . . .
H26 H 0.8370 0.3432 0.7316 0.061 Uiso 1 1 calc R . .
C27 C 0.8806(3) 0.3354(3) 0.7120(4) 0.062(3) Uani 1 1 d . . .
H27 H 0.8885 0.3632 0.7166 0.074 Uiso 1 1 calc R . .
C28 C 0.8994(3) 0.3070(3) 0.6964(4) 0.059(3) Uani 1 1 d . . .
H28 H 0.9207 0.3151 0.6910 0.071 Uiso 1 1 calc R . .
C29 C 0.8878(3) 0.2669(3) 0.6885(3) 0.047(2) Uani 1 1 d . . .
H29 H 0.9008 0.2476 0.6771 0.056 Uiso 1 1 calc R . .
C30 C 0.8575(3) 0.2545(3) 0.6970(3) 0.040(2) Uani 1 1 d . . .
H30 H 0.8494 0.2268 0.6911 0.048 Uiso 1 1 calc R . .
C31 C 0.6414(2) 0.1478(3) 0.7345(3) 0.041(2) Uani 1 1 d . . .
C32 C 0.6069(3) 0.1674(3) 0.7227(4) 0.048(2) Uani 1 1 d . . .
H32 H 0.6056 0.1964 0.7224 0.058 Uiso 1 1 calc R . .
C33 C 0.5751(3) 0.1447(4) 0.7116(5) 0.073(3) Uani 1 1 d . . .
H33 H 0.5518 0.1581 0.7043 0.087 Uiso 1 1 calc R . .
C34 C 0.5761(4) 0.1037(5) 0.7109(7) 0.107(6) Uani 1 1 d . . .
H34 H 0.5537 0.0884 0.7036 0.129 Uiso 1 1 calc R . .
C35 C 0.6099(4) 0.0837(4) 0.7210(8) 0.114(6) Uani 1 1 d . . .
H35 H 0.6105 0.0547 0.7192 0.136 Uiso 1 1 calc R . .
C36 C 0.6421(3) 0.1061(3) 0.7336(6) 0.073(3) Uani 1 1 d . . .
H36 H 0.6655 0.0924 0.7419 0.088 Uiso 1 1 calc R . .
C9 C 0.8533(9) 0.2694(16) 0.8997(15) 0.032(3) Uani 0.625(6) 1 d P A 1
C10 C 0.8708(5) 0.3007(6) 0.9012(6) 0.032(3) Uani 0.625(6) 1 d P A 1
C37 C 0.8912(3) 0.3384(3) 0.9043(5) 0.0614(16) Uani 0.625(6) 1 d PG A 1
C38 C 0.8937(3) 0.3687(3) 0.9415(4) 0.0614(16) Uani 0.625(6) 1 d PG A 1
H38 H 0.8826 0.3645 0.9654 0.074 Uiso 0.625(6) 1 calc PR A 1
C39 C 0.9126(3) 0.4052(3) 0.9436(4) 0.0614(16) Uani 0.625(6) 1 d PG A 1
H39 H 0.9143 0.4259 0.9690 0.074 Uiso 0.625(6) 1 calc PR A 1
C40 C 0.9289(3) 0.4114(3) 0.9086(4) 0.0614(16) Uani 0.625(6) 1 d PG A 1
H40 H 0.9418 0.4363 0.9100 0.074 Uiso 0.625(6) 1 calc PR A 1
C41 C 0.9264(3) 0.3810(3) 0.8714(4) 0.0614(16) Uani 0.625(6) 1 d PG A 1
H41 H 0.9376 0.3853 0.8475 0.074 Uiso 0.625(6) 1 calc PR A 1
C42 C 0.9076(3) 0.3446(3) 0.8693(4) 0.0614(16) Uani 0.625(6) 1 d PG A 1
H42 H 0.9059 0.3238 0.8439 0.074 Uiso 0.625(6) 1 calc PR A 1
C148 C 1.0289(6) 0.6147(8) 0.4992(11) 0.105(6) Uani 0.625(6) 1 d PD A 1
H14P H 1.0243 0.5968 0.4682 0.158 Uiso 0.625(6) 1 calc PR A 1
H14Q H 1.0143 0.6401 0.4857 0.158 Uiso 0.625(6) 1 calc PR A 1
H14R H 1.0207 0.6009 0.5239 0.158 Uiso 0.625(6) 1 calc PR A 1
C149 C 1.0721(8) 0.6249(7) 0.5309(11) 0.105(6) Uani 0.625(6) 1 d PDU A 1
C150 C 1.0868(6) 0.6535(7) 0.5826(8) 0.087(7) Uani 0.625(6) 1 d PD A 1
H15A H 1.1146 0.6568 0.5980 0.131 Uiso 0.625(6) 1 calc PR A 1
H15B H 1.0805 0.6412 0.6102 0.131 Uiso 0.625(6) 1 calc PR A 1
H15C H 1.0744 0.6803 0.5718 0.131 Uiso 0.625(6) 1 calc PR A 1
O6 O 1.0944(5) 0.6120(4) 0.5154(5) 0.089(5) Uani 0.625(6) 1 d PD A 1
C9A C 0.8490(16) 0.271(3) 0.903(3) 0.032(3) Uani 0.375(6) 1 d PU A 2
C10A C 0.8648(8) 0.3024(11) 0.9133(11) 0.032(3) Uani 0.375(6) 1 d PU A 2
C42A C 0.9253(5) 0.3396(5) 0.9496(8) 0.0614(16) Uani 0.375(6) 1 d PG A 2
H42A H 0.9376 0.3145 0.9498 0.074 Uiso 0.375(6) 1 calc PR A 2
C41A C 0.9467(3) 0.3751(6) 0.9689(8) 0.0614(16) Uani 0.375(6) 1 d PG A 2
H41A H 0.9737 0.3744 0.9821 0.074 Uiso 0.375(6) 1 calc PR A 2
C40A C 0.9287(5) 0.4118(5) 0.9687(8) 0.0614(16) Uani 0.375(6) 1 d PGU A 2
H40A H 0.9434 0.4361 0.9818 0.074 Uiso 0.375(6) 1 calc PR A 2
C39A C 0.8893(5) 0.4129(5) 0.9493(8) 0.0614(16) Uani 0.375(6) 1 d PG A 2
H39A H 0.8770 0.4380 0.9491 0.074 Uiso 0.375(6) 1 calc PR A 2
C38A C 0.8679(3) 0.3773(6) 0.9300(8) 0.0614(16) Uani 0.375(6) 1 d PG A 2
H38A H 0.8409 0.3781 0.9168 0.074 Uiso 0.375(6) 1 calc PR A 2
C37A C 0.8859(5) 0.3406(5) 0.9302(8) 0.0614(16) Uani 0.375(6) 1 d PGU A 2
C156 C 1.0411(10) 0.5623(10) 0.5435(15) 0.093(7) Uani 0.375(6) 1 d PD A 2
H25D H 1.0279 0.5448 0.5111 0.140 Uiso 0.375(6) 1 calc PR A 2
H25E H 1.0242 0.5675 0.5603 0.140 Uiso 0.375(6) 1 calc PR A 2
H25F H 1.0643 0.5484 0.5701 0.140 Uiso 0.375(6) 1 calc PR A 2
O7 O 1.0400(7) 0.6074(8) 0.4726(10) 0.098(9) Uani 0.375(6) 1 d PD A 2
C157 C 1.0515(7) 0.6014(8) 0.5270(16) 0.093(7) Uani 0.375(6) 1 d PDU A 2
C158 C 1.0729(12) 0.6342(13) 0.5650(15) 0.093(7) Uani 0.375(6) 1 d PD A 2
H25G H 1.0763 0.6571 0.5444 0.140 Uiso 0.375(6) 1 calc PR A 2
H25H H 1.0980 0.6239 0.5916 0.140 Uiso 0.375(6) 1 calc PR A 2
H25I H 1.0587 0.6437 0.5845 0.140 Uiso 0.375(6) 1 calc PR A 2
C43 C 0.7636(2) 0.0914(2) 0.8753(3) 0.0365(19) Uani 1 1 d . . .
C44 C 0.7274(3) 0.0879(3) 0.8720(4) 0.048(2) Uani 1 1 d . . .
H44 H 0.7127 0.1119 0.8682 0.058 Uiso 1 1 calc R . .
C45 C 0.7124(3) 0.0499(4) 0.8741(5) 0.070(3) Uani 1 1 d . . .
H45 H 0.6877 0.0477 0.8722 0.084 Uiso 1 1 calc R . .
C46 C 0.7337(4) 0.0153(4) 0.8791(4) 0.068(3) Uani 1 1 d . . .
H46 H 0.7238 -0.0107 0.8818 0.082 Uiso 1 1 calc R . .
C47 C 0.7678(4) 0.0175(3) 0.8800(4) 0.060(3) Uani 1 1 d . . .
H47 H 0.7815 -0.0069 0.8820 0.072 Uiso 1 1 calc R . .
C48 C 0.7837(3) 0.0559(3) 0.8781(3) 0.051(2) Uani 1 1 d . . .
H48 H 0.8080 0.0573 0.8787 0.061 Uiso 1 1 calc R . .
C49 C 0.61038(19) 0.3755(2) 0.7174(3) 0.0247(15) Uani 1 1 d . . .
C50 C 0.6175(2) 0.3937(2) 0.6771(3) 0.0366(19) Uani 1 1 d . . .
H50 H 0.6352 0.3815 0.6668 0.044 Uiso 1 1 calc R . .
C51 C 0.5990(3) 0.4294(3) 0.6520(4) 0.057(3) Uani 1 1 d . . .
H51 H 0.6041 0.4419 0.6247 0.068 Uiso 1 1 calc R . .
C52 C 0.5726(3) 0.4471(3) 0.6671(4) 0.057(3) Uani 1 1 d . . .
H52 H 0.5594 0.4714 0.6496 0.069 Uiso 1 1 calc R . .
C53 C 0.5658(2) 0.4292(3) 0.7070(3) 0.041(2) Uani 1 1 d . . .
H53 H 0.5478 0.4411 0.7170 0.049 Uiso 1 1 calc R . .
C54 C 0.5847(2) 0.3943(2) 0.7326(3) 0.0313(17) Uani 1 1 d . . .
H54 H 0.5803 0.3826 0.7610 0.038 Uiso 1 1 calc R . .
C55 C 0.60380(19) 0.2956(2) 0.7601(3) 0.0235(15) Uani 1 1 d . . .
C56 C 0.5655(2) 0.2938(2) 0.7214(3) 0.0288(16) Uani 1 1 d . . .
H56 H 0.5558 0.3128 0.6919 0.035 Uiso 1 1 calc R . .
C57 C 0.5413(2) 0.2647(3) 0.7255(3) 0.0343(18) Uani 1 1 d . . .
H57 H 0.5151 0.2639 0.6990 0.041 Uiso 1 1 calc R . .
C58 C 0.5553(2) 0.2367(3) 0.7685(3) 0.0344(18) Uani 1 1 d . . .
H58 H 0.5388 0.2167 0.7716 0.041 Uiso 1 1 calc R . .
C59 C 0.5932(2) 0.2381(2) 0.8066(3) 0.0321(17) Uani 1 1 d . . .
H59 H 0.6030 0.2186 0.8356 0.039 Uiso 1 1 calc R . .
C60 C 0.6173(2) 0.2676(2) 0.8030(3) 0.0269(16) Uani 1 1 d . . .
H60 H 0.6433 0.2687 0.8301 0.032 Uiso 1 1 calc R . .
C61 C 0.73400(19) 0.2704(2) 0.5816(3) 0.0239(15) Uani 1 1 d . . .
C62 C 0.7363(2) 0.3126(3) 0.5798(4) 0.043(2) Uani 1 1 d . . .
H62 H 0.7183 0.3292 0.5849 0.052 Uiso 1 1 calc R . .
C63 C 0.7649(3) 0.3309(3) 0.5704(4) 0.056(3) Uani 1 1 d . . .
H63 H 0.7664 0.3598 0.5691 0.068 Uiso 1 1 calc R . .
C64 C 0.7912(2) 0.3066(3) 0.5629(3) 0.049(2) Uani 1 1 d . . .
H64 H 0.8108 0.3189 0.5567 0.058 Uiso 1 1 calc R . .
C65 C 0.7887(2) 0.2658(3) 0.5646(4) 0.050(2) Uani 1 1 d . . .
H65 H 0.8066 0.2492 0.5593 0.060 Uiso 1 1 calc R . .
C66 C 0.7605(2) 0.2475(3) 0.5738(3) 0.0387(19) Uani 1 1 d . . .
H66 H 0.7593 0.2185 0.5748 0.046 Uiso 1 1 calc R . .
C67 C 0.65754(19) 0.2362(2) 0.5250(3) 0.0271(16) Uani 1 1 d . . .
C68 C 0.6436(2) 0.2680(3) 0.4881(3) 0.0346(18) Uani 1 1 d . . .
H68 H 0.6560 0.2939 0.4972 0.042 Uiso 1 1 calc R . .
C69 C 0.6121(2) 0.2629(3) 0.4385(3) 0.047(2) Uani 1 1 d . . .
H69 H 0.6033 0.2851 0.4133 0.056 Uiso 1 1 calc R . .
C70 C 0.5933(2) 0.2262(4) 0.4248(3) 0.056(3) Uani 1 1 d . . .
H70 H 0.5712 0.2229 0.3905 0.068 Uiso 1 1 calc R . .
C71 C 0.6065(2) 0.1943(3) 0.4609(4) 0.051(2) Uani 1 1 d . . .
H71 H 0.5936 0.1687 0.4516 0.061 Uiso 1 1 calc R . .
C72 C 0.6389(2) 0.1991(3) 0.5114(3) 0.0386(19) Uani 1 1 d . . .
H72 H 0.6480 0.1768 0.5364 0.046 Uiso 1 1 calc R . .
C73 C 0.76824(19) 0.0977(2) 0.6277(3) 0.0232(14) Uani 1 1 d . . .
C74 C 0.7812(2) 0.1239(2) 0.6002(3) 0.0350(18) Uani 1 1 d . . .
H74 H 0.7793 0.1527 0.6036 0.042 Uiso 1 1 calc R . .
C75 C 0.7970(2) 0.1087(3) 0.5674(3) 0.040(2) Uani 1 1 d . . .
H75 H 0.8060 0.1269 0.5488 0.048 Uiso 1 1 calc R . .
C76 C 0.7995(2) 0.0666(3) 0.5623(3) 0.038(2) Uani 1 1 d . . .
H76 H 0.8097 0.0559 0.5395 0.046 Uiso 1 1 calc R . .
C77 C 0.7871(2) 0.0407(2) 0.5900(3) 0.0379(19) Uani 1 1 d . . .
H77 H 0.7894 0.0120 0.5870 0.045 Uiso 1 1 calc R . .
C78 C 0.7711(2) 0.0557(2) 0.6229(3) 0.0334(17) Uani 1 1 d . . .
H78 H 0.7622 0.0373 0.6416 0.040 Uiso 1 1 calc R . .
C79 C 0.7149(2) 0.0814(2) 0.6713(3) 0.0263(15) Uani 1 1 d . . .
C80 C 0.6789(2) 0.0784(3) 0.6255(3) 0.040(2) Uani 1 1 d . . .
H80 H 0.6721 0.0974 0.5962 0.048 Uiso 1 1 calc R . .
C81 C 0.6532(3) 0.0484(3) 0.6222(4) 0.049(2) Uani 1 1 d . . .
H81 H 0.6290 0.0465 0.5906 0.059 Uiso 1 1 calc R . .
C82 C 0.6629(3) 0.0212(3) 0.6653(4) 0.045(2) Uani 1 1 d . . .
H82 H 0.6451 0.0008 0.6635 0.054 Uiso 1 1 calc R . .
C83 C 0.6979(2) 0.0235(3) 0.7104(4) 0.040(2) Uani 1 1 d . . .
H83 H 0.7044 0.0045 0.7396 0.048 Uiso 1 1 calc R . .
C84 C 0.7237(2) 0.0533(2) 0.7135(3) 0.0339(18) Uani 1 1 d . . .
H84 H 0.7479 0.0546 0.7450 0.041 Uiso 1 1 calc R . .
C85 C 0.9471(2) 0.1460(3) 0.8818(3) 0.0344(18) Uani 1 1 d . . .
C86 C 0.9581(3) 0.1398(4) 0.8407(4) 0.065(3) Uani 1 1 d . . .
H86 H 0.9499 0.1586 0.8110 0.078 Uiso 1 1 calc R . .
C87 C 0.9806(4) 0.1068(4) 0.8427(6) 0.080(4) Uani 1 1 d . . .
H87 H 0.9874 0.1027 0.8138 0.096 Uiso 1 1 calc R . .
C88 C 0.9933(3) 0.0802(4) 0.8856(7) 0.083(4) Uani 1 1 d . . .
H88 H 1.0091 0.0579 0.8867 0.100 Uiso 1 1 calc R . .
C89 C 0.9833(3) 0.0855(4) 0.9277(6) 0.074(3) Uani 1 1 d . . .
H89 H 0.9923 0.0672 0.9579 0.089 Uiso 1 1 calc R . .
C90 C 0.9595(2) 0.1183(3) 0.9246(4) 0.047(2) Uani 1 1 d . . .
H90 H 0.9518 0.1217 0.9525 0.056 Uiso 1 1 calc R . .
C91 C 0.9464(3) 0.2341(4) 0.8827(4) 0.071(2) Uani 1 1 d . . .
C92 C 0.9439(3) 0.2531(4) 0.8375(4) 0.071(2) Uani 1 1 d . . .
H92 H 0.9261 0.2438 0.8021 0.085 Uiso 1 1 calc R . .
C93 C 0.9677(3) 0.2866(4) 0.8428(4) 0.071(2) Uani 1 1 d . . .
H93 H 0.9660 0.2995 0.8107 0.085 Uiso 1 1 calc R . .
C94 C 0.9932(3) 0.3010(4) 0.8935(4) 0.057(3) Uani 1 1 d . . .
H94 H 1.0081 0.3248 0.8971 0.069 Uiso 1 1 calc R . .
C95 C 0.9963(3) 0.2804(3) 0.9379(4) 0.053(3) Uani 1 1 d . . .
H95 H 1.0149 0.2886 0.9734 0.063 Uiso 1 1 calc R . .
C96 C 0.9728(2) 0.2472(3) 0.9324(3) 0.044(2) Uani 1 1 d . . .
H96 H 0.9753 0.2334 0.9644 0.053 Uiso 1 1 calc R . .
C97 C 0.93238(19) 0.2540(2) 1.0624(3) 0.0262(16) Uani 1 1 d . . .
C98 C 0.9143(2) 0.2897(2) 1.0647(3) 0.0378(19) Uani 1 1 d . . .
H98 H 0.8878 0.2895 1.0551 0.045 Uiso 1 1 calc R . .
C99 C 0.9350(3) 0.3258(3) 1.0812(4) 0.054(3) Uani 1 1 d . . .
H99 H 0.9225 0.3504 1.0824 0.065 Uiso 1 1 calc R . .
C100 C 0.9735(3) 0.3262(3) 1.0958(4) 0.050(2) Uani 1 1 d . . .
H100 H 0.9874 0.3511 1.1074 0.061 Uiso 1 1 calc R . .
C101 C 0.9919(2) 0.2911(3) 1.0937(3) 0.040(2) Uani 1 1 d . . .
H101 H 1.0184 0.2918 1.1037 0.047 Uiso 1 1 calc R . .
C102 C 0.9719(2) 0.2547(2) 1.0773(3) 0.0334(17) Uani 1 1 d . . .
H102 H 0.9847 0.2303 1.0759 0.040 Uiso 1 1 calc R . .
C103 C 0.93308(18) 0.1680(2) 1.0893(3) 0.0238(15) Uani 1 1 d . . .
C104 C 0.94394(19) 0.1768(3) 1.1441(3) 0.0285(16) Uani 1 1 d . . .
H104 H 0.9399 0.2034 1.1546 0.034 Uiso 1 1 calc R . .
C105 C 0.9607(2) 0.1466(3) 1.1833(3) 0.038(2) Uani 1 1 d . . .
H105 H 0.9679 0.1524 1.2208 0.046 Uiso 1 1 calc R . .
C106 C 0.9668(2) 0.1081(3) 1.1684(4) 0.046(2) Uani 1 1 d . . .
H106 H 0.9786 0.0876 1.1955 0.055 Uiso 1 1 calc R . .
C107 C 0.9560(3) 0.0994(3) 1.1142(4) 0.048(2) Uani 1 1 d . . .
H107 H 0.9599 0.0726 1.1040 0.058 Uiso 1 1 calc R . .
C108 C 0.9394(2) 0.1292(2) 1.0744(3) 0.0344(18) Uani 1 1 d . . .
H108 H 0.9325 0.1232 1.0370 0.041 Uiso 1 1 calc R . .
C109 C 0.7459(2) 0.4252(2) 0.9330(3) 0.0252(15) Uani 1 1 d . . .
C110 C 0.7565(2) 0.4283(3) 0.8918(3) 0.0346(18) Uani 1 1 d . . .
H110 H 0.7426 0.4137 0.8584 0.042 Uiso 1 1 calc R . .
C111 C 0.7875(3) 0.4526(3) 0.8984(4) 0.050(2) Uani 1 1 d . . .
H111 H 0.7946 0.4547 0.8696 0.059 Uiso 1 1 calc R . .
C112 C 0.8077(3) 0.4735(3) 0.9466(4) 0.053(2) Uani 1 1 d . . .
H112 H 0.8287 0.4902 0.9510 0.063 Uiso 1 1 calc R . .
C113 C 0.7978(3) 0.4704(3) 0.9887(4) 0.049(2) Uani 1 1 d . . .
H113 H 0.8120 0.4849 1.0220 0.059 Uiso 1 1 calc R . .
C114 C 0.7670(2) 0.4460(2) 0.9827(3) 0.0381(19) Uani 1 1 d . . .
H114 H 0.7604 0.4435 1.0119 0.046 Uiso 1 1 calc R . .
C115 C 0.66980(19) 0.4300(2) 0.9232(3) 0.0218(14) Uani 1 1 d . . .
C116 C 0.63836(19) 0.4396(2) 0.8735(3) 0.0255(15) Uani 1 1 d . . .
H116 H 0.6346 0.4259 0.8408 0.031 Uiso 1 1 calc R . .
C117 C 0.6123(2) 0.4696(2) 0.8719(3) 0.0354(18) Uani 1 1 d . . .
H117 H 0.5909 0.4763 0.8380 0.042 Uiso 1 1 calc R . .
C118 C 0.6174(2) 0.4894(2) 0.9190(3) 0.0326(17) Uani 1 1 d . . .
H118 H 0.5999 0.5099 0.9176 0.039 Uiso 1 1 calc R . .
C119 C 0.6481(2) 0.4794(2) 0.9683(3) 0.0333(18) Uani 1 1 d . . .
H119 H 0.6514 0.4928 1.0010 0.040 Uiso 1 1 calc R . .
C120 C 0.6741(2) 0.4500(2) 0.9707(3) 0.0299(16) Uani 1 1 d . . .
H120 H 0.6952 0.4434 1.0050 0.036 Uiso 1 1 calc R . .
C121 C 0.65885(17) 0.3061(2) 0.7173(3) 0.0210(14) Uani 1 1 d . . .
H12A H 0.6770 0.3251 0.7131 0.025 Uiso 1 1 calc R . .
H12B H 0.6736 0.2821 0.7384 0.025 Uiso 1 1 calc R . .
C122 C 0.62947(19) 0.2918(2) 0.6600(3) 0.0246(15) Uani 1 1 d . . .
H12C H 0.6078 0.2784 0.6629 0.029 Uiso 1 1 calc R . .
H12D H 0.6193 0.3159 0.6357 0.029 Uiso 1 1 calc R . .
C123 C 0.64653(18) 0.2617(2) 0.6341(3) 0.0213(14) Uani 1 1 d . . .
H12E H 0.6260 0.2523 0.5983 0.026 Uiso 1 1 calc R . .
H12F H 0.6563 0.2374 0.6582 0.026 Uiso 1 1 calc R . .
C124 C 0.67913(19) 0.2801(2) 0.6250(3) 0.0209(14) Uani 1 1 d . . .
H12G H 0.7001 0.2888 0.6607 0.025 Uiso 1 1 calc R . .
H12H H 0.6696 0.3047 0.6015 0.025 Uiso 1 1 calc R . .
C125 C 0.78774(19) 0.1197(2) 0.7393(3) 0.0242(15) Uani 1 1 d . . .
H12I H 0.7779 0.1266 0.7658 0.029 Uiso 1 1 calc R . .
H12J H 0.7992 0.0920 0.7486 0.029 Uiso 1 1 calc R . .
C126 C 0.81843(19) 0.1502(2) 0.7452(3) 0.0241(15) Uani 1 1 d . . .
H12K H 0.8070 0.1779 0.7359 0.029 Uiso 1 1 calc R . .
H12L H 0.8283 0.1432 0.7188 0.029 Uiso 1 1 calc R . .
C127 C 0.8517(2) 0.1508(2) 0.8032(3) 0.0290(16) Uani 1 1 d . . .
H12M H 0.8668 0.1254 0.8097 0.035 Uiso 1 1 calc R . .
H12N H 0.8415 0.1518 0.8303 0.035 Uiso 1 1 calc R . .
C128 C 0.8777(2) 0.1881(3) 0.8115(3) 0.0302(17) Uani 1 1 d . . .
H12O H 0.8625 0.2134 0.8055 0.036 Uiso 1 1 calc R . .
H12P H 0.8873 0.1873 0.7838 0.036 Uiso 1 1 calc R . .
C129 C 0.86146(19) 0.2116(2) 1.0389(3) 0.0222(14) Uani 1 1 d . . .
H12Q H 0.8658 0.2236 1.0745 0.027 Uiso 1 1 calc R . .
H12R H 0.8448 0.2304 1.0093 0.027 Uiso 1 1 calc R . .
C130 C 0.72200(19) 0.3639(2) 0.9867(3) 0.0232(15) Uani 1 1 d . . .
H13A H 0.7493 0.3573 0.9995 0.028 Uiso 1 1 calc R . .
H13B H 0.7201 0.3808 1.0154 0.028 Uiso 1 1 calc R . .
C131 C 0.69995(18) 0.3240(2) 0.9804(3) 0.0195(14) Uani 1 1 d . . .
H13C H 0.7005 0.3079 0.9501 0.023 Uiso 1 1 calc R . .
H13D H 0.7133 0.3078 1.0145 0.023 Uiso 1 1 calc R . .
C132 C 0.84138(18) 0.1702(2) 1.0313(3) 0.0219(14) Uani 1 1 d . . .
H13E H 0.8423 0.1553 1.0004 0.026 Uiso 1 1 calc R . .
H13F H 0.8549 0.1535 1.0649 0.026 Uiso 1 1 calc R . .
C133 C 0.8344(3) 0.9796(3) 0.7233(4) 0.051(2) Uani 1 1 d . . .
H13G H 0.8492 1.0027 0.7201 0.077 Uiso 1 1 calc R . .
H13H H 0.8138 0.9727 0.6869 0.077 Uiso 1 1 calc R . .
H13I H 0.8512 0.9559 0.7385 0.077 Uiso 1 1 calc R . .
C134 C 0.8176(2) 0.9911(3) 0.7601(3) 0.0377(19) Uani 1 1 d . . .
C135 C 0.7940(3) 0.9598(3) 0.7701(4) 0.056(3) Uani 1 1 d . . .
H13J H 0.7846 0.9711 0.7948 0.084 Uiso 1 1 calc R . .
H13K H 0.8096 0.9355 0.7869 0.084 Uiso 1 1 calc R . .
H13L H 0.7723 0.9522 0.7352 0.084 Uiso 1 1 calc R . .
C136 C 0.9088(3) 0.1114(4) 0.6357(4) 0.063(3) Uani 1 1 d . . .
H13M H 0.9160 0.1365 0.6230 0.094 Uiso 1 1 calc R . .
H13N H 0.8866 0.0989 0.6051 0.094 Uiso 1 1 calc R . .
H13O H 0.9303 0.0921 0.6492 0.094 Uiso 1 1 calc R . .
C137 C 0.8990(3) 0.1216(4) 0.6812(4) 0.063(3) Uani 1 1 d . . .
C138 C 0.8875(3) 0.0866(3) 0.7050(4) 0.064(3) Uani 1 1 d . . .
H13P H 0.8818 0.0965 0.7342 0.097 Uiso 1 1 calc R . .
H13Q H 0.9085 0.0667 0.7202 0.097 Uiso 1 1 calc R . .
H13R H 0.8647 0.0735 0.6763 0.097 Uiso 1 1 calc R . .
C139 C 0.5336(3) 0.3475(6) 0.5594(5) 0.103(6) Uani 1 1 d . . .
H13S H 0.5275 0.3407 0.5894 0.154 Uiso 1 1 calc R . .
H13T H 0.5111 0.3595 0.5288 0.154 Uiso 1 1 calc R . .
H13U H 0.5547 0.3672 0.5724 0.154 Uiso 1 1 calc R . .
C140 C 0.5449(3) 0.3101(6) 0.5406(5) 0.089(5) Uani 1 1 d . . .
C141 C 0.5549(3) 0.3157(4) 0.4944(5) 0.084(4) Uani 1 1 d . . .
H14A H 0.5617 0.2892 0.4845 0.126 Uiso 1 1 calc R . .
H14B H 0.5768 0.3344 0.5060 0.126 Uiso 1 1 calc R . .
H14C H 0.5330 0.3273 0.4626 0.126 Uiso 1 1 calc R . .
C142 C 0.8931(3) 0.0365(4) 0.9151(8) 0.121(7) Uani 1 1 d . . .
H14D H 0.8856 0.0653 0.9102 0.182 Uiso 1 1 calc R . .
H14E H 0.8715 0.0195 0.9113 0.182 Uiso 1 1 calc R . .
H14F H 0.9009 0.0285 0.8871 0.182 Uiso 1 1 calc R . .
C143 C 0.9253(4) 0.0305(3) 0.9699(6) 0.071(4) Uani 1 1 d . . .
C144 C 0.9409(3) -0.0101(4) 0.9863(5) 0.082(4) Uani 1 1 d . . .
H14G H 0.9616 -0.0093 1.0240 0.123 Uiso 1 1 calc R . .
H14H H 0.9510 -0.0198 0.9616 0.123 Uiso 1 1 calc R . .
H14I H 0.9208 -0.0287 0.9844 0.123 Uiso 1 1 calc R . .
C145 C 0.8156(6) 0.4137(5) 0.5123(6) 0.133(4) Uani 1 1 d . . .
H14J H 0.7927 0.4311 0.4965 0.200 Uiso 1 1 calc R . .
H14K H 0.8079 0.3849 0.5086 0.200 Uiso 1 1 calc R . .
H14L H 0.8309 0.4185 0.4928 0.200 Uiso 1 1 calc R . .
C146 C 0.8366(6) 0.4230(5) 0.5659(7) 0.133(4) Uani 1 1 d . . .
C147 C 0.8738(5) 0.4026(5) 0.6005(6) 0.133(4) Uani 1 1 d . . .
H14M H 0.8845 0.4133 0.6381 0.200 Uiso 1 1 calc R . .
H14N H 0.8916 0.4081 0.5853 0.200 Uiso 1 1 calc R . .
H14O H 0.8698 0.3730 0.6009 0.200 Uiso 1 1 calc R . .
C151 C 0.9716(7) 0.5953(8) 0.7010(10) 0.105(8) Uani 0.50 1 d PDU . .
H15D H 0.9571 0.6163 0.6740 0.157 Uiso 0.50 1 calc PR . .
H15E H 0.9541 0.5792 0.7101 0.157 Uiso 0.50 1 calc PR . .
H15F H 0.9841 0.5772 0.6857 0.157 Uiso 0.50 1 calc PR . .
C152 C 1.0000 0.6145(9) 0.7500 0.105(8) Uani 0.50 2 d SPDU . .
O8 O 1.0000 0.6509(7) 0.7500 0.097(9) Uani 0.50 2 d SPD . .
O1 O 0.8232(2) 1.0242(2) 0.7824(3) 0.067(2) Uani 1 1 d . . .
O2 O 0.8994(3) 0.1563(2) 0.6968(3) 0.096(3) Uani 1 1 d . . .
O3 O 0.5448(2) 0.2769(4) 0.5607(4) 0.100(4) Uani 1 1 d . . .
O4 O 0.9394(5) 0.0585(3) 0.9998(5) 0.163(6) Uani 1 1 d . . .
O5 O 0.8262(4) 0.4493(5) 0.5890(5) 0.152(5) Uani 1 1 d . . .
F1 F 0.61241(15) 0.39649(17) 0.5505(2) 0.0561(14) Uani 1 1 d . . .
F2 F 0.65520(17) 0.44768(15) 0.5845(2) 0.0576(14) Uani 1 1 d . . .
F3 F 0.63223(18) 0.42933(17) 0.4957(2) 0.0618(15) Uani 1 1 d . . .
F4 F 0.69384(16) 0.41498(19) 0.5564(2) 0.0653(16) Uani 1 1 d . . .
F5 F 0.65068(16) 0.36443(16) 0.5214(2) 0.0562(14) Uani 1 1 d . . .
F6 F 0.67303(15) 0.38219(16) 0.6099(2) 0.0528(13) Uani 1 1 d . . .
F7 F 0.5000 0.4713(2) 0.7500 0.056(2) Uani 1 2 d S . .
F8 F 0.52684(15) 0.52006(19) 0.8145(2) 0.0594(15) Uani 1 1 d . . .
F9 F 0.46346(13) 0.51980(16) 0.7607(2) 0.0494(13) Uani 1 1 d . . .
F10 F 0.5000 0.5684(2) 0.7500 0.062(2) Uani 1 2 d S . .
P9 P 0.9397(3) 0.4747(2) 0.7563(4) 0.113(3) Uani 0.50 1 d PD . .
F11 F 0.9574(5) 0.5185(4) 0.7739(8) 0.161(10) Uani 0.50 1 d PD . .
F12 F 0.9171(4) 0.4805(5) 0.7922(6) 0.128(6) Uani 0.50 1 d PDU . .
F13 F 0.9756(5) 0.4603(8) 0.8115(9) 0.183(10) Uani 0.50 1 d PDU . .
F14 F 0.9235(5) 0.4304(4) 0.7399(7) 0.141(7) Uani 0.50 1 d PDU . .
F15 F 0.9605(5) 0.4706(5) 0.7181(8) 0.170(10) Uani 0.50 1 d PD . .
F16 F 0.9028(4) 0.4940(5) 0.7047(6) 0.141(8) Uani 0.50 1 d PD . .
P1 P 0.63774(5) 0.33190(6) 0.75656(7) 0.0207(4) Uani 1 1 d . A .
P2 P 0.69772(5) 0.24392(6) 0.59275(7) 0.0203(4) Uani 1 1 d . A .
P3 P 0.74835(5) 0.11887(6) 0.67095(7) 0.0218(4) Uani 1 1 d . A .
P4 P 0.91790(5) 0.18931(6) 0.87959(7) 0.0274(4) Uani 1 1 d . A .
P5 P 0.90722(5) 0.20617(6) 1.03747(7) 0.0197(3) Uani 1 1 d . A .
P6 P 0.70504(5) 0.39389(6) 0.92370(7) 0.0205(4) Uani 1 1 d . A .
P7 P 0.65303(7) 0.40605(6) 0.55290(9) 0.0362(5) Uani 1 1 d . . .
P8 P 0.5000 0.51976(8) 0.7500 0.0265(6) Uani 1 2 d S . .
Ag1 Ag 0.798810(15) 0.285563(17) 0.81665(2) 0.02731(12) Uani 1 1 d . . .
Ag2 Ag 0.740300(15) 0.204859(18) 0.84472(2) 0.02896(13) Uani 1 1 d . . .
Au1 Au 0.679257(7) 0.356233(8) 0.843112(10) 0.02041(6) Uani 1 1 d . . .
Au2 Au 0.721857(7) 0.182725(8) 0.638585(10) 0.02138(6) Uani 1 1 d . . .
Au3 Au 0.904550(7) 0.193388(8) 0.953029(10) 0.02114(6) Uani 1 1 d . . .
Au4 Au 0.738695(8) 0.297849(9) 0.853796(11) 0.02903(7) Uani 1 1 d . A .
Au5 Au 0.742825(8) 0.223839(9) 0.743889(11) 0.02772(7) Uani 1 1 d . A .
Au6 Au 0.823612(8) 0.217069(10) 0.892610(11) 0.02951(7) Uani 1 1 d . A .
C154 C 0.9955(16) 0.7687(6) 0.2469(11) 0.094(9) Uani 0.50 1 d PDU . .
O9 O 0.9859(5) 0.7332(5) 0.2320(7) 0.090(6) Uani 0.50 1 d PDU . .
C153 C 0.9786(7) 0.8039(6) 0.2092(10) 0.075(7) Uani 0.50 1 d PDU . .
H15G H 0.9562 0.8180 0.1813 0.113 Uiso 0.50 1 calc PR . .
H15H H 1.0008 0.8221 0.2224 0.113 Uiso 0.50 1 calc PR . .
H15I H 0.9736 0.7961 0.2400 0.113 Uiso 0.50 1 calc PR . .
C155 C 1.0167(9) 0.7810(10) 0.3056(10) 0.104(10) Uani 0.50 1 d PDU . .
H15J H 1.0408 0.7667 0.3277 0.155 Uiso 0.50 1 calc PR . .
H15K H 0.9994 0.7630 0.2761 0.155 Uiso 0.50 1 calc PR . .
H15L H 1.0048 0.7888 0.3289 0.155 Uiso 0.50 1 calc PR . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C2 C1 Au4 173.5(7) . .
C2 C1 Ag1 88.3(5) . .
Au4 C1 Ag1 85.6(3) . .
C1 C2 C13 178.2(8) . .
C1 C2 Ag1 64.2(5) . .
C13 C2 Ag1 114.5(5) . .
C4 C3 Au4 177.2(7) . .
C4 C3 Ag2 90.1(5) . .
Au4 C3 Ag2 88.9(3) . .
C3 C4 C19 177.0(7) . .
C3 C4 Ag2 62.5(4) . .
C19 C4 Ag2 120.4(5) . .
C6 C5 Au5 173.4(7) . .
C6 C5 Ag1 98.0(6) . .
Au5 C5 Ag1 86.9(3) . .
C5 C6 C25 173.9(8) . .
C8 C7 Au5 168.6(6) . .
C8 C7 Ag2 109.1(5) . .
Au5 C7 Ag2 82.3(2) . .
C7 C8 C31 176.5(8) . .
C12 C11 Au6 177.7(6) . .
C12 C11 Ag2 97.2(5) . .
Au6 C11 Ag2 84.9(3) . .
C11 C12 C43 176.4(9) . .
C14 C13 C18 118.3(8) . .
C14 C13 C2 120.7(8) . .
C18 C13 C2 121.0(7) . .
C15 C14 C13 120.0(9) . .
C15 C14 H14 120.0 . .
C13 C14 H14 120.0 . .
C16 C15 C14 121.1(10) . .
C16 C15 H15 119.5 . .
C14 C15 H15 119.5 . .
C15 C16 C17 119.9(10) . .
C15 C16 H16 120.0 . .
C17 C16 H16 120.0 . .
C18 C17 C16 120.4(10) . .
C18 C17 H17 119.8 . .
C16 C17 H17 119.8 . .
C17 C18 C13 120.3(9) . .
C17 C18 H18 119.9 . .
C13 C18 H18 119.9 . .
C24 C19 C20 119.0(8) . .
C24 C19 C4 120.6(7) . .
C20 C19 C4 120.4(7) . .
C21 C20 C19 119.5(8) . .
C21 C20 H20 120.2 . .
C19 C20 H20 120.2 . .
C22 C21 C20 120.3(8) . .
C22 C21 H21 119.8 . .
C20 C21 H21 119.8 . .
C23 C22 C21 119.9(9) . .
C23 C22 H22 120.1 . .
C21 C22 H22 120.1 . .
C24 C23 C22 120.6(9) . .
C24 C23 H23 119.7 . .
C22 C23 H23 119.7 . .
C23 C24 C19 120.6(8) . .
C23 C24 H24 119.7 . .
C19 C24 H24 119.7 . .
C26 C25 C30 119.4(8) . .
C26 C25 C6 121.2(7) . .
C30 C25 C6 119.4(8) . .
C27 C26 C25 119.9(9) . .
C27 C26 H26 120.1 . .
C25 C26 H26 120.1 . .
C28 C27 C26 120.0(10) . .
C28 C27 H27 120.0 . .
C26 C27 H27 120.0 . .
C27 C28 C29 120.5(9) . .
C27 C28 H28 119.8 . .
C29 C28 H28 119.8 . .
C28 C29 C30 120.5(9) . .
C28 C29 H29 119.8 . .
C30 C29 H29 119.8 . .
C29 C30 C25 119.7(9) . .
C29 C30 H30 120.2 . .
C25 C30 H30 120.2 . .
C36 C31 C32 118.6(9) . .
C36 C31 C8 121.0(8) . .
C32 C31 C8 120.4(8) . .
C33 C32 C31 119.9(10) . .
C33 C32 H32 120.1 . .
C31 C32 H32 120.1 . .
C34 C33 C32 121.2(11) . .
C34 C33 H33 119.4 . .
C32 C33 H33 119.4 . .
C33 C34 C35 119.9(11) . .
C33 C34 H34 120.0 . .
C35 C34 H34 120.0 . .
C36 C35 C34 119.5(12) . .
C36 C35 H35 120.3 . .
C34 C35 H35 120.3 . .
C35 C36 C31 121.0(11) . .
C35 C36 H36 119.5 . .
C31 C36 H36 119.5 . .
C10 C9 Au6 177(3) . .
C10 C9 Ag1 96(2) . .
Au6 C9 Ag1 82.4(13) . .
C9 C10 C37 178.1(17) . .
C38 C37 C42 120.0 . .
C38 C37 C10 120.0(9) . .
C42 C37 C10 120.0(9) . .
C37 C38 C39 120.0 . .
C37 C38 H38 120.0 . .
C39 C38 H38 120.0 . .
C38 C39 C40 120.0 . .
C38 C39 H39 120.0 . .
C40 C39 H39 120.0 . .
C41 C40 C39 120.0 . .
C41 C40 H40 120.0 . .
C39 C40 H40 120.0 . .
C40 C41 C42 120.0 . .
C40 C41 H41 120.0 . .
C42 C41 H41 120.0 . .
C41 C42 C37 120.0 . .
C41 C42 H42 120.0 . .
C37 C42 H42 120.0 . .
C149 C148 H14P 109.5 . .
C149 C148 H14Q 109.5 . .
H14P C148 H14Q 109.5 . .
C149 C148 H14R 109.5 . .
H14P C148 H14R 109.5 . .
H14Q C148 H14R 109.5 . .
O6 C149 C148 121(3) . .
O6 C149 C150 120(2) . .
C148 C149 C150 119(3) . .
C149 C150 H15A 109.5 . .
C149 C150 H15B 109.5 . .
H15A C150 H15B 109.5 . .
C149 C150 H15C 109.5 . .
H15A C150 H15C 109.5 . .
H15B C150 H15C 109.5 . .
C10A C9A Au6 174(5) . .
C10A C9A Ag1 100(4) . .
Au6 C9A Ag1 84(2) . .
C9A C10A C37A 176(3) . .
C41A C42A C37A 120.0 . .
C41A C42A H42A 120.0 . .
C37A C42A H42A 120.0 . .
C40A C41A C42A 120.0 . .
C40A C41A H41A 120.0 . .
C42A C41A H41A 120.0 . .
C39A C40A C41A 120.0 . .
C39A C40A H40A 120.0 . .
C41A C40A H40A 120.0 . .
C40A C39A C38A 120.0 . .
C40A C39A H39A 120.0 . .
C38A C39A H39A 120.0 . .
C37A C38A C39A 120.0 . .
C37A C38A H38A 120.0 . .
C39A C38A H38A 120.0 . .
C38A C37A C42A 120.0 . .
C38A C37A C10A 121.6(16) . .
C42A C37A C10A 118.3(16) . .
C157 C156 H25D 109.5 . .
C157 C156 H25E 109.5 . .
H25D C156 H25E 109.5 . .
C157 C156 H25F 109.5 . .
H25D C156 H25F 109.5 . .
H25E C156 H25F 109.5 . .
O7 C157 C158 118(2) . .
O7 C157 C156 117(2) . .
C158 C157 C156 125(4) . .
C157 C158 H25G 109.5 . .
C157 C158 H25H 109.5 . .
H25G C158 H25H 109.5 . .
C157 C158 H25I 109.5 . .
H25G C158 H25I 109.5 . .
H25H C158 H25I 109.5 . .
C44 C43 C48 118.4(9) . .
C44 C43 C12 120.1(7) . .
C48 C43 C12 121.3(8) . .
C43 C44 C45 120.8(9) . .
C43 C44 H44 119.6 . .
C45 C44 H44 119.6 . .
C46 C45 C44 119.4(11) . .
C46 C45 H45 120.3 . .
C44 C45 H45 120.3 . .
C47 C46 C45 121.2(11) . .
C47 C46 H46 119.4 . .
C45 C46 H46 119.4 . .
C46 C47 C48 120.5(10) . .
C46 C47 H47 119.8 . .
C48 C47 H47 119.8 . .
C43 C48 C47 119.6(10) . .
C43 C48 H48 120.2 . .
C47 C48 H48 120.2 . .
C50 C49 C54 118.9(7) . .
C50 C49 P1 121.8(5) . .
C54 C49 P1 118.9(5) . .
C51 C50 C49 120.5(8) . .
C51 C50 H50 119.8 . .
C49 C50 H50 119.8 . .
C50 C51 C52 119.6(9) . .
C50 C51 H51 120.2 . .
C52 C51 H51 120.2 . .
C53 C52 C51 119.8(8) . .
C53 C52 H52 120.1 . .
C51 C52 H52 120.1 . .
C54 C53 C52 120.5(7) . .
C54 C53 H53 119.7 . .
C52 C53 H53 119.7 . .
C53 C54 C49 120.7(7) . .
C53 C54 H54 119.6 . .
C49 C54 H54 119.6 . .
C60 C55 C56 118.6(7) . .
C60 C55 P1 117.8(5) . .
C56 C55 P1 123.6(6) . .
C57 C56 C55 120.9(7) . .
C57 C56 H56 119.6 . .
C55 C56 H56 119.6 . .
C56 C57 C58 119.9(7) . .
C56 C57 H57 120.1 . .
C58 C57 H57 120.1 . .
C59 C58 C57 119.6(7) . .
C59 C58 H58 120.2 . .
C57 C58 H58 120.2 . .
C58 C59 C60 120.5(7) . .
C58 C59 H59 119.7 . .
C60 C59 H59 119.7 . .
C59 C60 C55 120.5(7) . .
C59 C60 H60 119.8 . .
C55 C60 H60 119.8 . .
C66 C61 C62 118.1(7) . .
C66 C61 P2 118.5(6) . .
C62 C61 P2 123.4(5) . .
C61 C62 C63 120.1(8) . .
C61 C62 H62 120.0 . .
C63 C62 H62 120.0 . .
C64 C63 C62 119.9(9) . .
C64 C63 H63 120.0 . .
C62 C63 H63 120.0 . .
C65 C64 C63 119.6(8) . .
C65 C64 H64 120.2 . .
C63 C64 H64 120.2 . .
C64 C65 C66 120.8(8) . .
C64 C65 H65 119.6 . .
C66 C65 H65 119.6 . .
C61 C66 C65 121.4(8) . .
C61 C66 H66 119.3 . .
C65 C66 H66 119.3 . .
C72 C67 C68 118.7(7) . .
C72 C67 P2 120.3(6) . .
C68 C67 P2 120.9(6) . .
C69 C68 C67 121.0(9) . .
C69 C68 H68 119.5 . .
C67 C68 H68 119.5 . .
C68 C69 C70 120.6(9) . .
C68 C69 H69 119.7 . .
C70 C69 H69 119.7 . .
C71 C70 C69 119.4(8) . .
C71 C70 H70 120.3 . .
C69 C70 H70 120.3 . .
C70 C71 C72 120.3(9) . .
C70 C71 H71 119.8 . .
C72 C71 H71 119.8 . .
C67 C72 C71 119.9(9) . .
C67 C72 H72 120.0 . .
C71 C72 H72 120.0 . .
C74 C73 C78 119.8(7) . .
C74 C73 P3 119.3(5) . .
C78 C73 P3 120.8(5) . .
C73 C74 C75 120.7(7) . .
C73 C74 H74 119.6 . .
C75 C74 H74 119.6 . .
C76 C75 C74 119.4(7) . .
C76 C75 H75 120.3 . .
C74 C75 H75 120.3 . .
C77 C76 C75 119.8(7) . .
C77 C76 H76 120.1 . .
C75 C76 H76 120.1 . .
C76 C77 C78 121.3(7) . .
C76 C77 H77 119.4 . .
C78 C77 H77 119.4 . .
C73 C78 C77 118.9(7) . .
C73 C78 H78 120.5 . .
C77 C78 H78 120.5 . .
C84 C79 C80 117.7(7) . .
C84 C79 P3 123.3(6) . .
C80 C79 P3 118.9(6) . .
C81 C80 C79 121.2(8) . .
C81 C80 H80 119.4 . .
C79 C80 H80 119.4 . .
C80 C81 C82 119.3(8) . .
C80 C81 H81 120.3 . .
C82 C81 H81 120.3 . .
C83 C82 C81 120.6(8) . .
C83 C82 H82 119.7 . .
C81 C82 H82 119.7 . .
C82 C83 C84 120.0(8) . .
C82 C83 H83 120.0 . .
C84 C83 H83 120.0 . .
C83 C84 C79 121.2(7) . .
C83 C84 H84 119.4 . .
C79 C84 H84 119.4 . .
C90 C85 C86 118.2(8) . .
C90 C85 P4 120.9(6) . .
C86 C85 P4 120.8(8) . .
C87 C86 C85 120.8(11) . .
C87 C86 H86 119.6 . .
C85 C86 H86 119.6 . .
C88 C87 C86 120.6(11) . .
C88 C87 H87 119.7 . .
C86 C87 H87 119.7 . .
C87 C88 C89 120.4(11) . .
C87 C88 H88 119.8 . .
C89 C88 H88 119.8 . .
C88 C89 C90 118.6(12) . .
C88 C89 H89 120.7 . .
C90 C89 H89 120.7 . .
C85 C90 C89 121.4(9) . .
C85 C90 H90 119.3 . .
C89 C90 H90 119.3 . .
C92 C91 C96 118.7(9) . .
C92 C91 P4 122.7(8) . .
C96 C91 P4 118.4(7) . .
C91 C92 C93 119.8(9) . .
C91 C92 H92 120.1 . .
C93 C92 H92 120.1 . .
C94 C93 C92 121.2(9) . .
C94 C93 H93 119.4 . .
C92 C93 H93 119.4 . .
C95 C94 C93 117.7(9) . .
C95 C94 H94 121.1 . .
C93 C94 H94 121.1 . .
C94 C95 C96 120.7(9) . .
C94 C95 H95 119.6 . .
C96 C95 H95 119.6 . .
C91 C96 C95 121.6(8) . .
C91 C96 H96 119.2 . .
C95 C96 H96 119.2 . .
C98 C97 C102 119.5(7) . .
C98 C97 P5 122.9(6) . .
C102 C97 P5 117.6(6) . .
C97 C98 C99 119.8(8) . .
C97 C98 H98 120.1 . .
C99 C98 H98 120.1 . .
C100 C99 C98 120.3(9) . .
C100 C99 H99 119.9 . .
C98 C99 H99 119.9 . .
C101 C100 C99 120.7(8) . .
C101 C100 H100 119.6 . .
C99 C100 H100 119.6 . .
C100 C101 C102 120.2(8) . .
C100 C101 H101 119.9 . .
C102 C101 H101 119.9 . .
C101 C102 C97 119.5(7) . .
C101 C102 H102 120.2 . .
C97 C102 H102 120.2 . .
C108 C103 C104 120.0(7) . .
C108 C103 P5 120.6(5) . .
C104 C103 P5 119.2(6) . .
C105 C104 C103 119.4(8) . .
C105 C104 H104 120.3 . .
C103 C104 H104 120.3 . .
C106 C105 C104 120.4(7) . .
C106 C105 H105 119.8 . .
C104 C105 H105 119.8 . .
C107 C106 C105 120.1(8) . .
C107 C106 H106 120.0 . .
C105 C106 H106 120.0 . .
C106 C107 C108 120.4(9) . .
C106 C107 H107 119.8 . .
C108 C107 H107 119.8 . .
C107 C108 C103 119.6(7) . .
C107 C108 H108 120.2 . .
C103 C108 H108 120.2 . .
C110 C109 C114 119.4(7) . .
C110 C109 P6 120.4(6) . .
C114 C109 P6 120.2(6) . .
C109 C110 C111 120.7(8) . .
C109 C110 H110 119.7 . .
C111 C110 H110 119.7 . .
C112 C111 C110 119.8(8) . .
C112 C111 H111 120.1 . .
C110 C111 H111 120.1 . .
C111 C112 C113 120.4(8) . .
C111 C112 H112 119.8 . .
C113 C112 H112 119.8 . .
C112 C113 C114 120.2(9) . .
C112 C113 H113 119.9 . .
C114 C113 H113 119.9 . .
C113 C114 C109 119.4(8) . .
C113 C114 H114 120.3 . .
C109 C114 H114 120.3 . .
C116 C115 C120 118.7(6) . .
C116 C115 P6 119.2(5) . .
C120 C115 P6 121.9(5) . .
C115 C116 C117 119.8(6) . .
C115 C116 H116 120.1 . .
C117 C116 H116 120.1 . .
C118 C117 C116 120.4(7) . .
C118 C117 H117 119.8 . .
C116 C117 H117 119.8 . .
C117 C118 C119 119.8(7) . .
C117 C118 H118 120.1 . .
C119 C118 H118 120.1 . .
C118 C119 C120 120.6(7) . .
C118 C119 H119 119.7 . .
C120 C119 H119 119.7 . .
C119 C120 C115 120.5(7) . .
C119 C120 H120 119.7 . .
C115 C120 H120 119.7 . .
C122 C121 P1 114.1(4) . .
C122 C121 H12A 108.7 . .
P1 C121 H12A 108.7 . .
C122 C121 H12B 108.7 . .
P1 C121 H12B 108.7 . .
H12A C121 H12B 107.6 . .
C123 C122 C121 112.6(5) . .
C123 C122 H12C 109.1 . .
C121 C122 H12C 109.1 . .
C123 C122 H12D 109.1 . .
C121 C122 H12D 109.1 . .
H12C C122 H12D 107.8 . .
C122 C123 C124 113.3(6) . .
C122 C123 H12E 108.9 . .
C124 C123 H12E 108.9 . .
C122 C123 H12F 108.9 . .
C124 C123 H12F 108.9 . .
H12E C123 H12F 107.7 . .
C123 C124 P2 111.9(5) . .
C123 C124 H12G 109.2 . .
P2 C124 H12G 109.2 . .
C123 C124 H12H 109.2 . .
P2 C124 H12H 109.2 . .
H12G C124 H12H 107.9 . .
C126 C125 P3 112.6(5) . .
C126 C125 H12I 109.1 . .
P3 C125 H12I 109.1 . .
C126 C125 H12J 109.1 . .
P3 C125 H12J 109.1 . .
H12I C125 H12J 107.8 . .
C125 C126 C127 112.4(6) . .
C125 C126 H12K 109.1 . .
C127 C126 H12K 109.1 . .
C125 C126 H12L 109.1 . .
C127 C126 H12L 109.1 . .
H12K C126 H12L 107.9 . .
C126 C127 C128 111.0(6) . .
C126 C127 H12M 109.4 . .
C128 C127 H12M 109.4 . .
C126 C127 H12N 109.4 . .
C128 C127 H12N 109.4 . .
H12M C127 H12N 108.0 . .
C127 C128 P4 112.2(5) . .
C127 C128 H12O 109.2 . .
P4 C128 H12O 109.2 . .
C127 C128 H12P 109.2 . .
P4 C128 H12P 109.2 . .
H12O C128 H12P 107.9 . .
C132 C129 P5 111.3(5) . .
C132 C129 H12Q 109.4 . .
P5 C129 H12Q 109.4 . .
C132 C129 H12R 109.4 . .
P5 C129 H12R 109.4 . .
H12Q C129 H12R 108.0 . .
C131 C130 P6 114.0(4) . .
C131 C130 H13A 108.8 . .
P6 C130 H13A 108.8 . .
C131 C130 H13B 108.8 . .
P6 C130 H13B 108.8 . .
H13A C130 H13B 107.6 . .
C132 C131 C130 114.5(6) 7_657 .
C132 C131 H13C 108.6 7_657 .
C130 C131 H13C 108.6 . .
C132 C131 H13D 108.6 7_657 .
C130 C131 H13D 108.6 . .
H13C C131 H13D 107.6 . .
C131 C132 C129 110.8(5) 7_657 .
C131 C132 H13E 109.5 7_657 .
C129 C132 H13E 109.5 . .
C131 C132 H13F 109.5 7_657 .
C129 C132 H13F 109.5 . .
H13E C132 H13F 108.1 . .
C134 C133 H13G 109.5 . .
C134 C133 H13H 109.5 . .
H13G C133 H13H 109.5 . .
C134 C133 H13I 109.5 . .
H13G C133 H13I 109.5 . .
H13H C133 H13I 109.5 . .
O1 C134 C133 122.1(9) . .
O1 C134 C135 120.4(8) . .
C133 C134 C135 117.5(8) . .
C134 C135 H13J 109.5 . .
C134 C135 H13K 109.5 . .
H13J C135 H13K 109.5 . .
C134 C135 H13L 109.5 . .
H13J C135 H13L 109.5 . .
H13K C135 H13L 109.5 . .
C137 C136 H13M 109.5 . .
C137 C136 H13N 109.5 . .
H13M C136 H13N 109.5 . .
C137 C136 H13O 109.5 . .
H13M C136 H13O 109.5 . .
H13N C136 H13O 109.5 . .
O2 C137 C138 121.7(10) . .
O2 C137 C136 122.3(11) . .
C138 C137 C136 116.0(10) . .
C137 C138 H13P 109.5 . .
C137 C138 H13Q 109.5 . .
H13P C138 H13Q 109.5 . .
C137 C138 H13R 109.5 . .
H13P C138 H13R 109.5 . .
H13Q C138 H13R 109.5 . .
C140 C139 H13S 109.5 . .
C140 C139 H13T 109.5 . .
H13S C139 H13T 109.5 . .
C140 C139 H13U 109.5 . .
H13S C139 H13U 109.5 . .
H13T C139 H13U 109.5 . .
O3 C140 C139 121.3(13) . .
O3 C140 C141 123.1(17) . .
C139 C140 C141 115.5(15) . .
C140 C141 H14A 109.5 . .
C140 C141 H14B 109.5 . .
H14A C141 H14B 109.5 . .
C140 C141 H14C 109.5 . .
H14A C141 H14C 109.5 . .
H14B C141 H14C 109.5 . .
C143 C142 H14D 109.5 . .
C143 C142 H14E 109.5 . .
H14D C142 H14E 109.5 . .
C143 C142 H14F 109.5 . .
H14D C142 H14F 109.5 . .
H14E C142 H14F 109.5 . .
O4 C143 C144 119.7(15) . .
O4 C143 C142 121.2(14) . .
C144 C143 C142 119.0(11) . .
C143 C144 H14G 109.5 . .
C143 C144 H14H 109.5 . .
H14G C144 H14H 109.5 . .
C143 C144 H14I 109.5 . .
H14G C144 H14I 109.5 . .
H14H C144 H14I 109.5 . .
C146 C145 H14J 109.5 . .
C146 C145 H14K 109.5 . .
H14J C145 H14K 109.5 . .
C146 C145 H14L 109.5 . .
H14J C145 H14L 109.5 . .
H14K C145 H14L 109.5 . .
O5 C146 C145 121.9(19) . .
O5 C146 C147 116.3(17) . .
C145 C146 C147 121.8(19) . .
C146 C147 H14M 109.5 . .
C146 C147 H14N 109.5 . .
H14M C147 H14N 109.5 . .
C146 C147 H14O 109.5 . .
H14M C147 H14O 109.5 . .
H14N C147 H14O 109.5 . .
C152 C151 H15D 109.5 . .
C152 C151 H15E 109.5 . .
H15D C151 H15E 109.5 . .
C152 C151 H15F 109.5 . .
H15D C151 H15F 109.5 . .
H15E C151 H15F 109.5 . .
O8 C152 C151 115.9(15) . .
O8 C152 C151 115.9(15) . 2_756
C151 C152 C151 128(3) . 2_756
F14 P9 F11 177.9(12) . .
F14 P9 F15 89.8(7) . .
F11 P9 F15 89.5(6) . .
F14 P9 F13 93.8(12) . .
F11 P9 F13 84.3(13) . .
F15 P9 F13 95.8(12) . .
F14 P9 F12 91.2(6) . .
F11 P9 F12 89.7(6) . .
F15 P9 F12 176.8(11) . .
F13 P9 F12 87.2(8) . .
F14 P9 F16 91.5(8) . .
F11 P9 F16 90.5(8) . .
F15 P9 F16 89.1(8) . .
F13 P9 F16 172.9(11) . .
F12 P9 F16 87.9(7) . .
C49 P1 C55 107.0(3) . .
C49 P1 C121 108.6(3) . .
C55 P1 C121 105.7(3) . .
C49 P1 Au1 106.6(2) . .
C55 P1 Au1 111.1(2) . .
C121 P1 Au1 117.4(2) . .
C61 P2 C124 107.1(3) . .
C61 P2 C67 106.2(3) . .
C124 P2 C67 103.3(3) . .
C61 P2 Au2 110.1(2) . .
C124 P2 Au2 117.0(2) . .
C67 P2 Au2 112.4(3) . .
C79 P3 C125 106.7(3) . .
C79 P3 C73 105.9(3) . .
C125 P3 C73 105.0(3) . .
C79 P3 Au2 114.4(2) . .
C125 P3 Au2 114.0(2) . .
C73 P3 Au2 110.1(2) . .
C85 P4 C128 105.0(4) . .
C85 P4 C91 105.1(5) . .
C128 P4 C91 107.2(4) . .
C85 P4 Au3 114.3(3) . .
C128 P4 Au3 117.4(2) . .
C91 P4 Au3 107.0(4) . .
C97 P5 C103 106.5(3) . .
C97 P5 C129 106.5(3) . .
C103 P5 C129 104.8(3) . .
C97 P5 Au3 107.6(2) . .
C103 P5 Au3 114.4(2) . .
C129 P5 Au3 116.4(2) . .
C115 P6 C109 104.9(3) . .
C115 P6 C130 107.8(3) . .
C109 P6 C130 104.5(3) . .
C115 P6 Au1 109.7(2) . .
C109 P6 Au1 114.0(2) . .
C130 P6 Au1 115.3(2) . .
F4 P7 F5 89.9(3) . .
F4 P7 F3 91.3(3) . .
F5 P7 F3 89.9(3) . .
F4 P7 F2 90.4(3) . .
F5 P7 F2 179.7(3) . .
F3 P7 F2 90.1(3) . .
F4 P7 F6 89.8(3) . .
F5 P7 F6 89.6(3) . .
F3 P7 F6 178.7(4) . .
F2 P7 F6 90.4(3) . .
F4 P7 F1 178.8(4) . .
F5 P7 F1 90.0(3) . .
F3 P7 F1 89.8(3) . .
F2 P7 F1 89.7(3) . .
F6 P7 F1 89.0(3) . .
F7 P8 F10 180.000(3) . .
F7 P8 F9 90.1(2) . .
F10 P8 F9 89.9(2) . .
F7 P8 F9 90.1(2) . 2_656
F10 P8 F9 89.9(2) . 2_656
F9 P8 F9 179.9(4) . 2_656
F7 P8 F8 90.3(2) . .
F10 P8 F8 89.7(2) . .
F9 P8 F8 89.6(3) . .
F9 P8 F8 90.4(3) 2_656 .
F7 P8 F8 90.3(2) . 2_656
F10 P8 F8 89.7(2) . 2_656
F9 P8 F8 90.4(3) . 2_656
F9 P8 F8 89.6(3) 2_656 2_656
F8 P8 F8 179.3(5) . 2_656
C5 Ag1 C9A 129.1(17) . .
C5 Ag1 C9 124.9(9) . .
C9A Ag1 C9 5(2) . .
C5 Ag1 C1 116.5(3) . .
C9A Ag1 C1 114.3(16) . .
C9 Ag1 C1 118.6(10) . .
C5 Ag1 C2 105.7(3) . .
C9A Ag1 C2 121(2) . .
C9 Ag1 C2 122.6(12) . .
C1 Ag1 C2 27.5(3) . .
C5 Ag1 Au6 102.9(2) . .
C9A Ag1 Au6 43(2) . .
C9 Ag1 Au6 43.9(12) . .
C1 Ag1 Au6 124.2(2) . .
C2 Ag1 Au6 148.50(17) . .
C5 Ag1 Au5 42.2(2) . .
C9A Ag1 Au5 124(2) . .
C9 Ag1 Au5 124.1(13) . .
C1 Ag1 Au5 101.38(19) . .
C2 Ag1 Au5 111.03(17) . .
Au6 Ag1 Au5 82.040(17) . .
C5 Ag1 Au4 119.7(2) . .
C9A Ag1 Au4 97.0(13) . .
C9 Ag1 Au4 102.3(7) . .
C1 Ag1 Au4 41.6(2) . .
C2 Ag1 Au4 69.08(18) . .
Au6 Ag1 Au4 85.375(17) . .
Au5 Ag1 Au4 82.023(16) . .
C3 Ag2 C7 119.7(2) . .
C3 Ag2 C11 127.7(3) . .
C7 Ag2 C11 112.6(2) . .
C3 Ag2 C4 27.4(3) . .
C7 Ag2 C4 120.6(2) . .
C11 Ag2 C4 118.8(2) . .
C3 Ag2 Au5 120.1(2) . .
C7 Ag2 Au5 43.41(19) . .
C11 Ag2 Au5 97.17(17) . .
C4 Ag2 Au5 142.32(16) . .
C3 Ag2 Au6 103.56(19) . .
C7 Ag2 Au6 122.28(18) . .
C11 Ag2 Au6 42.3(2) . .
C4 Ag2 Au6 115.39(15) . .
Au5 Ag2 Au6 83.116(17) . .
C3 Ag2 Au4 40.8(2) . .
C7 Ag2 Au4 104.48(18) . .
C11 Ag2 Au4 124.9(2) . .
C4 Ag2 Au4 68.16(18) . .
Au5 Ag2 Au4 82.784(17) . .
Au6 Ag2 Au4 83.627(17) . .
P6 Au1 P1 162.34(6) . .
P6 Au1 Au4 105.57(4) . .
P1 Au1 Au4 92.09(4) . .
P3 Au2 P2 169.42(6) . .
P3 Au2 Au5 99.22(4) . .
P2 Au2 Au5 89.95(4) . .
P4 Au3 P5 164.31(6) . .
P4 Au3 Au6 98.21(5) . .
P5 Au3 Au6 93.40(4) . .
C1 Au4 C3 177.2(3) . .
C1 Au4 Au1 88.2(2) . .
C3 Au4 Au1 93.9(2) . .
C1 Au4 Ag1 52.8(2) . .
C3 Au4 Ag1 124.8(2) . .
Au1 Au4 Ag1 140.452(16) . .
C1 Au4 Ag2 126.9(2) . .
C3 Au4 Ag2 50.3(2) . .
Au1 Au4 Ag2 133.340(16) . .
Ag1 Au4 Ag2 77.884(16) . .
C7 Au5 C5 176.5(3) . .
C7 Au5 Ag2 54.32(19) . .
C5 Au5 Ag2 128.7(2) . .
C7 Au5 Au2 88.20(19) . .
C5 Au5 Au2 88.3(2) . .
Ag2 Au5 Au2 136.605(17) . .
C7 Au5 Ag1 132.61(19) . .
C5 Au5 Ag1 50.9(2) . .
Ag2 Au5 Ag1 80.937(17) . .
Au2 Au5 Ag1 139.180(16) . .
C9A Au6 C11 176.9(16) . .
C9A Au6 C9 6(2) . .
C11 Au6 C9 176.9(9) . .
C9A Au6 Ag1 53.0(19) . .
C11 Au6 Ag1 126.4(2) . .
C9 Au6 Ag1 53.8(11) . .
C9A Au6 Au3 78.9(17) . .
C11 Au6 Au3 103.3(2) . .
C9 Au6 Au3 75.0(10) . .
Ag1 Au6 Au3 121.944(16) . .
C9A Au6 Ag2 124.8(17) . .
C11 Au6 Ag2 52.8(2) . .
C9 Au6 Ag2 129.1(10) . .
Ag1 Au6 Ag2 81.007(17) . .
Au3 Au6 Ag2 155.744(17) . .
C154 C154 O9 106(6) 2_755 .
C154 C154 O9 61(2) 2_755 2_755
O9 C154 O9 49.9(16) . 2_755
C154 C154 C155 110(10) 2_755 2_755
O9 C154 C155 91(2) . 2_755
O9 C154 C155 125(4) 2_755 2_755
C154 C154 C153 114(10) 2_755 .
O9 C154 C153 122(2) . .
O9 C154 C153 161(5) 2_755 .
C155 C154 C153 37.0(14) 2_755 .
C154 C154 C155 59(10) 2_755 .
O9 C154 C155 123(2) . .
O9 C154 C155 81.0(19) 2_755 .
C155 C154 C155 145(3) 2_755 .
C153 C154 C155 113(2) . .
C154 C154 C153 56(8) 2_755 2_755
O9 C154 C153 154(2) . 2_755
O9 C154 C153 105(2) 2_755 2_755
C155 C154 C153 112(3) 2_755 2_755
C153 C154 C153 84(2) . 2_755
C155 C154 C153 33.3(15) . 2_755
O9 O9 C154 70.8(19) 2_755 .
O9 O9 C154 59.3(15) 2_755 2_755
C154 O9 C154 13(5) . 2_755
O9 O9 C155 106.2(14) 2_755 2_755
C154 O9 C155 47(2) . 2_755
C154 O9 C155 52.7(11) 2_755 2_755
C155 C153 C154 64(3) 2_755 .
C155 C153 C154 64.2(16) 2_755 2_755
C154 C153 C154 10(4) . 2_755
C155 C153 C153 104(3) 2_755 2_755
C154 C153 C153 51.0(14) . 2_755
C154 C153 C153 44.8(12) 2_755 2_755
C155 C153 H15G 109.5 2_755 .
C154 C153 H15G 150.1 . .
C154 C153 H15G 160.2 2_755 .
C153 C153 H15G 146.2 2_755 .
C155 C153 H15H 109.5 2_755 .
C154 C153 H15H 99.9 . .
C154 C153 H15H 90.2 2_755 .
C153 C153 H15H 57.3 2_755 .
H15G C153 H15H 109.5 . .
C155 C153 H15I 109.5 2_755 .
C154 C153 H15I 53.4 . .
C154 C153 H15I 59.4 2_755 .
C153 C153 H15I 57.5 2_755 .
H15G C153 H15I 109.5 . .
H15H C153 H15I 109.5 . .
C153 C155 C154 79(3) 2_755 2_755
C153 C155 C154 82(2) 2_755 .
C154 C155 C154 12(5) 2_755 .
C153 C155 O9 115(3) 2_755 2_755
C154 C155 O9 41.8(10) 2_755 2_755
C154 C155 O9 46.3(13) . 2_755
C153 C155 H15J 109.5 2_755 .
C154 C155 H15J 106.8 2_755 .
C154 C155 H15J 116.5 . .
O9 C155 H15J 74.5 2_755 .
C153 C155 H15K 109.5 2_755 .
C154 C155 H15K 33.9 2_755 .
C154 C155 H15K 27.4 . .
O9 C155 H15K 36.1 2_755 .
H15J C155 H15K 109.5 . .
C153 C155 H15L 109.5 2_755 .
C154 C155 H15L 136.5 2_755 .
C154 C155 H15L 125.0 . .
O9 C155 H15L 131.2 2_755 .
H15J C155 H15L 109.5 . .
H15K C155 H15L 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 C2 1.225(11) .
C1 Au4 1.995(9) .
C1 Ag1 2.392(7) .
C2 C13 1.427(12) .
C2 Ag1 2.656(8) .
C3 C4 1.216(11) .
C3 Au4 1.994(9) .
C3 Ag2 2.347(7) .
C4 C19 1.440(11) .
C4 Ag2 2.646(7) .
C5 C6 1.198(11) .
C5 Au5 2.003(8) .
C5 Ag1 2.314(7) .
C6 C25 1.439(11) .
C7 C8 1.205(11) .
C7 Au5 1.993(8) .
C7 Ag2 2.355(7) .
C8 C31 1.434(12) .
C11 C12 1.213(11) .
C11 Au6 1.991(9) .
C11 Ag2 2.357(7) .
C12 C43 1.449(12) .
C13 C14 1.391(11) .
C13 C18 1.401(12) .
C14 C15 1.388(14) .
C14 H14 0.9500 .
C15 C16 1.349(15) .
C15 H15 0.9500 .
C16 C17 1.380(14) .
C16 H16 0.9500 .
C17 C18 1.375(12) .
C17 H17 0.9500 .
C18 H18 0.9500 .
C19 C24 1.391(11) .
C19 C20 1.404(11) .
C20 C21 1.390(11) .
C20 H20 0.9500 .
C21 C22 1.380(12) .
C21 H21 0.9500 .
C22 C23 1.380(13) .
C22 H22 0.9500 .
C23 C24 1.367(13) .
C23 H23 0.9500 .
C24 H24 0.9500 .
C25 C26 1.387(12) .
C25 C30 1.393(11) .
C26 C27 1.384(13) .
C26 H26 0.9500 .
C27 C28 1.370(14) .
C27 H27 0.9500 .
C28 C29 1.369(14) .
C28 H28 0.9500 .
C29 C30 1.375(12) .
C29 H29 0.9500 .
C30 H30 0.9500 .
C31 C36 1.365(14) .
C31 C32 1.397(12) .
C32 C33 1.363(13) .
C32 H32 0.9500 .
C33 C34 1.338(17) .
C33 H33 0.9500 .
C34 C35 1.390(18) .
C34 H34 0.9500 .
C35 C36 1.365(15) .
C35 H35 0.9500 .
C36 H36 0.9500 .
C9 C10 1.22(4) .
C9 Au6 2.03(5) .
C9 Ag1 2.36(4) .
C10 C37 1.45(2) .
C37 C38 1.3900 .
C37 C42 1.3900 .
C38 C39 1.3900 .
C38 H38 0.9500 .
C39 C40 1.3900 .
C39 H39 0.9500 .
C40 C41 1.3900 .
C40 H40 0.9500 .
C41 C42 1.3900 .
C41 H41 0.9500 .
C42 H42 0.9500 .
C148 C149 1.55(3) .
C148 H14P 0.9800 .
C148 H14Q 0.9800 .
C148 H14R 0.9800 .
C149 O6 1.21(3) .
C149 C150 1.57(4) .
C150 H15A 0.9800 .
C150 H15B 0.9800 .
C150 H15C 0.9800 .
C9A C10A 1.17(7) .
C9A Au6 1.97(9) .
C9A Ag1 2.33(6) .
C10A C37A 1.45(4) .
C42A C41A 1.3900 .
C42A C37A 1.3900 .
C42A H42A 0.9500 .
C41A C40A 1.3900 .
C41A H41A 0.9500 .
C40A C39A 1.3900 .
C40A H40A 0.9500 .
C39A C38A 1.3900 .
C39A H39A 0.9500 .
C38A C37A 1.3900 .
C38A H38A 0.9500 .
C156 C157 1.475(19) .
C156 H25D 0.9800 .
C156 H25E 0.9800 .
C156 H25F 0.9800 .
O7 C157 1.36(4) .
C157 C158 1.463(19) .
C158 H25G 0.9800 .
C158 H25H 0.9800 .
C158 H25I 0.9800 .
C43 C44 1.385(12) .
C43 C48 1.388(12) .
C44 C45 1.388(14) .
C44 H44 0.9500 .
C45 C46 1.374(16) .
C45 H45 0.9500 .
C46 C47 1.330(16) .
C46 H46 0.9500 .
C47 C48 1.412(15) .
C47 H47 0.9500 .
C48 H48 0.9500 .
C49 C50 1.388(10) .
C49 C54 1.397(9) .
C49 P1 1.811(7) .
C50 C51 1.379(12) .
C50 H50 0.9500 .
C51 C52 1.405(13) .
C51 H51 0.9500 .
C52 C53 1.368(13) .
C52 H52 0.9500 .
C53 C54 1.367(11) .
C53 H53 0.9500 .
C54 H54 0.9500 .
C55 C60 1.389(10) .
C55 C56 1.391(10) .
C55 P1 1.818(7) .
C56 C57 1.384(11) .
C56 H56 0.9500 .
C57 C58 1.392(11) .
C57 H57 0.9500 .
C58 C59 1.374(11) .
C58 H58 0.9500 .
C59 C60 1.387(10) .
C59 H59 0.9500 .
C60 H60 0.9500 .
C61 C66 1.373(10) .
C61 C62 1.385(11) .
C61 P2 1.808(7) .
C62 C63 1.398(11) .
C62 H62 0.9500 .
C63 C64 1.386(13) .
C63 H63 0.9500 .
C64 C65 1.341(14) .
C64 H64 0.9500 .
C65 C66 1.382(11) .
C65 H65 0.9500 .
C66 H66 0.9500 .
C67 C72 1.377(11) .
C67 C68 1.377(11) .
C67 P2 1.822(7) .
C68 C69 1.365(11) .
C68 H68 0.9500 .
C69 C70 1.369(14) .
C69 H69 0.9500 .
C70 C71 1.365(15) .
C70 H70 0.9500 .
C71 C72 1.396(11) .
C71 H71 0.9500 .
C72 H72 0.9500 .
C73 C74 1.381(10) .
C73 C78 1.388(10) .
C73 P3 1.827(7) .
C74 C75 1.394(10) .
C74 H74 0.9500 .
C75 C76 1.389(12) .
C75 H75 0.9500 .
C76 C77 1.366(11) .
C76 H76 0.9500 .
C77 C78 1.400(10) .
C77 H77 0.9500 .
C78 H78 0.9500 .
C79 C84 1.390(10) .
C79 C80 1.401(10) .
C79 P3 1.799(7) .
C80 C81 1.381(11) .
C80 H80 0.9500 .
C81 C82 1.384(13) .
C81 H81 0.9500 .
C82 C83 1.368(12) .
C82 H82 0.9500 .
C83 C84 1.382(11) .
C83 H83 0.9500 .
C84 H84 0.9500 .
C85 C90 1.379(12) .
C85 C86 1.388(11) .
C85 P4 1.807(8) .
C86 C87 1.381(15) .
C86 H86 0.9500 .
C87 C88 1.359(18) .
C87 H87 0.9500 .
C88 C89 1.388(17) .
C88 H88 0.9500 .
C89 C90 1.398(13) .
C89 H89 0.9500 .
C90 H90 0.9500 .
C91 C92 1.347(12) .
C91 C96 1.350(12) .
C91 P4 1.820(10) .
C92 C93 1.402(14) .
C92 H92 0.9500 .
C93 C94 1.373(13) .
C93 H93 0.9500 .
C94 C95 1.344(13) .
C94 H94 0.9500 .
C95 C96 1.388(12) .
C95 H95 0.9500 .
C96 H96 0.9500 .
C97 C98 1.382(11) .
C97 C102 1.415(10) .
C97 P5 1.807(8) .
C98 C99 1.386(12) .
C98 H98 0.9500 .
C99 C100 1.378(13) .
C99 H99 0.9500 .
C100 C101 1.369(12) .
C100 H100 0.9500 .
C101 C102 1.382(11) .
C101 H101 0.9500 .
C102 H102 0.9500 .
C103 C108 1.388(11) .
C103 C104 1.390(10) .
C103 P5 1.812(7) .
C104 C105 1.384(11) .
C104 H104 0.9500 .
C105 C106 1.377(13) .
C105 H105 0.9500 .
C106 C107 1.372(12) .
C106 H106 0.9500 .
C107 C108 1.384(11) .
C107 H107 0.9500 .
C108 H108 0.9500 .
C109 C110 1.375(10) .
C109 C114 1.403(11) .
C109 P6 1.819(7) .
C110 C111 1.394(11) .
C110 H110 0.9500 .
C111 C112 1.372(14) .
C111 H111 0.9500 .
C112 C113 1.378(13) .
C112 H112 0.9500 .
C113 C114 1.395(11) .
C113 H113 0.9500 .
C114 H114 0.9500 .
C115 C116 1.393(9) .
C115 C120 1.396(9) .
C115 P6 1.813(7) .
C116 C117 1.405(10) .
C116 H116 0.9500 .
C117 C118 1.372(11) .
C117 H117 0.9500 .
C118 C119 1.377(11) .
C118 H118 0.9500 .
C119 C120 1.382(10) .
C119 H119 0.9500 .
C120 H120 0.9500 .
C121 C122 1.535(9) .
C121 P1 1.835(6) .
C121 H12A 0.9900 .
C121 H12B 0.9900 .
C122 C123 1.535(9) .
C122 H12C 0.9900 .
C122 H12D 0.9900 .
C123 C124 1.536(9) .
C123 H12E 0.9900 .
C123 H12F 0.9900 .
C124 P2 1.815(6) .
C124 H12G 0.9900 .
C124 H12H 0.9900 .
C125 C126 1.515(9) .
C125 P3 1.804(7) .
C125 H12I 0.9900 .
C125 H12J 0.9900 .
C126 C127 1.529(9) .
C126 H12K 0.9900 .
C126 H12L 0.9900 .
C127 C128 1.537(10) .
C127 H12M 0.9900 .
C127 H12N 0.9900 .
C128 P4 1.814(7) .
C128 H12O 0.9900 .
C128 H12P 0.9900 .
C129 C132 1.530(10) .
C129 P5 1.825(6) .
C129 H12Q 0.9900 .
C129 H12R 0.9900 .
C130 C131 1.530(9) .
C130 P6 1.824(7) .
C130 H13A 0.9900 .
C130 H13B 0.9900 .
C131 C132 1.517(9) 7_657
C131 H13C 0.9900 .
C131 H13D 0.9900 .
C132 C131 1.517(9) 7_657
C132 H13E 0.9900 .
C132 H13F 0.9900 .
C133 C134 1.480(12) .
C133 H13G 0.9800 .
C133 H13H 0.9800 .
C133 H13I 0.9800 .
C134 O1 1.212(11) .
C134 C135 1.486(12) .
C135 H13J 0.9800 .
C135 H13K 0.9800 .
C135 H13L 0.9800 .
C136 C137 1.501(13) .
C136 H13M 0.9800 .
C136 H13N 0.9800 .
C136 H13O 0.9800 .
C137 O2 1.209(12) .
C137 C138 1.482(16) .
C138 H13P 0.9800 .
C138 H13Q 0.9800 .
C138 H13R 0.9800 .
C139 C140 1.47(2) .
C139 H13S 0.9800 .
C139 H13T 0.9800 .
C139 H13U 0.9800 .
C140 O3 1.216(18) .
C140 C141 1.497(16) .
C141 H14A 0.9800 .
C141 H14B 0.9800 .
C141 H14C 0.9800 .
C142 C143 1.468(19) .
C142 H14D 0.9800 .
C142 H14E 0.9800 .
C142 H14F 0.9800 .
C143 O4 1.183(14) .
C143 C144 1.445(16) .
C144 H14G 0.9800 .
C144 H14H 0.9800 .
C144 H14I 0.9800 .
C145 C146 1.35(2) .
C145 H14J 0.9800 .
C145 H14K 0.9800 .
C145 H14L 0.9800 .
C146 O5 1.24(2) .
C146 C147 1.49(2) .
C147 H14M 0.9800 .
C147 H14N 0.9800 .
C147 H14O 0.9800 .
C151 C152 1.440(15) .
C151 H15D 0.9800 .
C151 H15E 0.9800 .
C151 H15F 0.9800 .
C152 O8 1.189(19) .
C152 C151 1.440(15) 2_756
F1 P7 1.598(5) .
F2 P7 1.592(5) .
F3 P7 1.590(5) .
F4 P7 1.589(6) .
F5 P7 1.590(5) .
F6 P7 1.594(5) .
F7 P8 1.584(7) .
F8 P8 1.591(5) .
F9 P8 1.590(4) .
F10 P8 1.588(7) .
P9 F14 1.563(13) .
P9 F11 1.568(12) .
P9 F15 1.598(12) .
P9 F13 1.598(15) .
P9 F12 1.608(13) .
P9 F16 1.619(13) .
P1 Au1 2.3191(17) .
P2 Au2 2.3201(18) .
P3 Au2 2.3186(18) .
P4 Au3 2.3004(17) .
P5 Au3 2.3028(16) .
P6 Au1 2.3162(17) .
P8 F9 1.590(4) 2_656
P8 F8 1.591(5) 2_656
Ag1 Au6 2.9031(6) .
Ag1 Au5 2.9787(6) .
Ag1 Au4 2.9935(6) .
Ag2 Au5 2.8734(6) .
Ag2 Au6 2.9459(6) .
Ag2 Au4 3.0503(7) .
Au1 Au4 2.9244(4) .
Au2 Au5 2.9360(4) .
Au3 Au6 2.9409(4) .
C154 C154 0.32(11) 2_755
C154 O9 1.230(17) .
C154 O9 1.35(3) 2_755
C154 C155 1.35(4) 2_755
C154 C153 1.482(18) .
C154 C155 1.487(19) .
C154 C153 1.64(3) 2_755
O9 O9 1.10(3) 2_755
O9 C154 1.35(3) 2_755
O9 C155 1.85(3) 2_755
C153 C155 0.91(3) 2_755
C153 C154 1.64(3) 2_755
C153 C153 2.09(5) 2_755
C153 H15G 0.9800 .
C153 H15H 0.9800 .
C153 H15I 0.9800 .
C155 C153 0.91(3) 2_755
C155 C154 1.35(4) 2_755
C155 O9 1.85(3) 2_755
C155 H15J 0.9800 .
C155 H15K 0.9800 .
C155 H15L 0.9800 .
