#------------------------------------------------------------------------------
#$Date: 2016-03-23 21:24:02 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179448 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/45/4334592.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4334592
loop_
_publ_author_name
'Sebastian C. Peter'
'Christos D. Malliakas'
'Mercouri G. Kanatzidis'
_publ_section_title
;
 Structure and Unusual Magnetic Properties of YbMn0.17Si1.88
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4909
_journal_page_last               4915
_journal_paper_doi               10.1021/ic3024925
_journal_volume                  52
_journal_year                    2013
_chemical_formula_sum            'Mn0.67 Si7.55 Yb4'
_chemical_formula_weight         940.77
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           4
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 97.97(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            1
_cell_length_a                   4.0107(8)
_cell_length_b                   3.8380(8)
_cell_length_c                   14.458(3)
_cell_measurement_reflns_used    2115
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      29.10
_cell_measurement_theta_min      2.85
_cell_volume                     220.40(8)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'stoe ipds 2'
_diffrn_measurement_method       rotation
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0408
_diffrn_reflns_av_sigmaI/netI    0.0252
_diffrn_reflns_limit_h_max       5
_diffrn_reflns_limit_h_min       -5
_diffrn_reflns_limit_k_max       5
_diffrn_reflns_limit_k_min       -5
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            2115
_diffrn_reflns_theta_full        29.10
_diffrn_reflns_theta_max         29.10
_diffrn_reflns_theta_min         2.85
_exptl_absorpt_coefficient_mu    43.902
_exptl_absorpt_correction_T_max  0.1271
_exptl_absorpt_correction_T_min  0.0966
_exptl_absorpt_correction_type   empirical
_exptl_crystal_colour            grey
_exptl_crystal_density_diffrn    7.088
_exptl_crystal_description       plate
_exptl_crystal_F_000             402
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.08
_refine_diff_density_max         2.320
_refine_diff_density_min         -3.053
_refine_diff_density_rms         0.525
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.49(6)
_refine_ls_extinction_coef       0.0047(7)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.143
_refine_ls_matrix_type           full
_refine_ls_number_parameters     68
_refine_ls_number_reflns         1188
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.143
_refine_ls_R_factor_all          0.0337
_refine_ls_R_factor_gt           0.0296
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0449P)²+1.3738P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0720
_refine_ls_wR_factor_ref         0.0742
_reflns_number_gt                1082
_reflns_number_total             1188
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic3024925_si_001.cif
_cod_data_source_block           p2(1)
_cod_database_code               4334592
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Yb1 Yb 0.94036(7) 0.4508(3) 0.88059(3) 0.00217(14) Uani 1 1 d .
Yb2 Yb 0.82894(8) 0.9512(2) 0.65780(3) 0.00248(14) Uani 1 1 d .
Mn1 Mn 0.2755(11) 0.461(4) 0.5536(3) 0.0030(13) Uani 0.337(8) 1 d P
Si1 Si 0.5127(11) 0.5236(15) 0.0265(4) 0.018(2) Uani 0.777(19) 1 d P
Si2 Si 0.5941(6) 0.459(2) 0.1872(2) 0.0064(6) Uani 1 1 d .
Si3 Si 0.3572(6) 0.454(2) 0.7140(2) 0.0055(5) Uani 1 1 d .
Si4 Si 0.2510(12) 0.952(4) 0.5017(2) 0.0327(12) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mn Mn 0.3368 0.7283 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Yb Yb -0.3850 5.5486 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Si1 Yb1 Si1 101.53(12) 1_656 2_646
Si1 Yb1 Si1 87.14(14) 1_656 1_556
Si1 Yb1 Si1 41.53(7) 2_646 1_556
Si1 Yb1 Si1 41.53(8) 1_656 2_746
Si1 Yb1 Si1 87.05(15) 2_646 2_746
Si1 Yb1 Si1 101.63(12) 1_556 2_746
Si1 Yb1 Si2 80.12(12) 1_656 2_746
Si1 Yb1 Si2 105.1(2) 2_646 2_746
Si1 Yb1 Si2 140.75(19) 1_556 2_746
Si1 Yb1 Si2 46.77(14) 2_746 2_746
Si1 Yb1 Si2 140.8(2) 1_656 2_646
Si1 Yb1 Si2 46.77(14) 2_646 2_646
Si1 Yb1 Si2 80.01(12) 1_556 2_646
Si1 Yb1 Si2 105.2(2) 2_746 2_646
Si2 Yb1 Si2 86.78(19) 2_746 2_646
Si1 Yb1 Si2 72.93(13) 1_656 2_756
Si1 Yb1 Si2 170.76(14) 2_646 2_756
Si1 Yb1 Si2 129.70(16) 1_556 2_756
Si1 Yb1 Si2 93.14(15) 2_746 2_756
Si2 Yb1 Si2 81.52(7) 2_746 2_756
Si2 Yb1 Si2 141.41(14) 2_646 2_756
Si1 Yb1 Si2 129.70(16) 1_656 2_656
Si1 Yb1 Si2 93.13(14) 2_646 2_656
Si1 Yb1 Si2 72.83(13) 1_556 2_656
Si1 Yb1 Si2 170.77(14) 2_746 2_656
Si2 Yb1 Si2 141.41(13) 2_746 2_656
Si2 Yb1 Si2 81.41(7) 2_646 2_656
Si2 Yb1 Si2 85.2(2) 2_756 2_656
Si1 Yb1 Si3 173.13(19) 1_656 .
Si1 Yb1 Si3 84.81(14) 2_646 .
Si1 Yb1 Si3 96.04(11) 1_556 .
Si1 Yb1 Si3 142.7(2) 2_746 .
Si2 Yb1 Si3 100.94(16) 2_746 .
Si2 Yb1 Si3 46.06(19) 2_646 .
Si2 Yb1 Si3 100.44(14) 2_756 .
Si2 Yb1 Si3 46.40(17) 2_656 .
Si1 Yb1 Si3 96.10(11) 1_656 1_655
Si1 Yb1 Si3 142.7(2) 2_646 1_655
Si1 Yb1 Si3 173.1(2) 1_556 1_655
Si1 Yb1 Si3 84.75(16) 2_746 1_655
Si2 Yb1 Si3 46.07(19) 2_746 1_655
Si2 Yb1 Si3 101.00(14) 2_646 1_655
Si2 Yb1 Si3 46.42(16) 2_756 1_655
Si2 Yb1 Si3 100.50(15) 2_656 1_655
Si3 Yb1 Si3 80.10(7) . 1_655
Si1 Yb1 Si1 93.75(14) 1_656 2_656
Si1 Yb1 Si1 76.73(12) 2_646 2_656
Si1 Yb1 Si1 38.57(10) 1_556 2_656
Si1 Yb1 Si1 128.10(18) 2_746 2_656
Si2 Yb1 Si1 173.82(10) 2_746 2_656
Si2 Yb1 Si1 98.56(13) 2_646 2_656
Si2 Yb1 Si1 96.03(16) 2_756 2_656
Si2 Yb1 Si1 43.36(11) 2_656 2_656
Si3 Yb1 Si1 85.06(17) . 2_656
Si3 Yb1 Si1 134.8(2) 1_655 2_656
Si1 Yb1 Si1 38.56(10) 1_656 2_756
Si1 Yb1 Si1 128.11(18) 2_646 2_756
Si1 Yb1 Si1 93.85(15) 1_556 2_756
Si1 Yb1 Si1 76.64(11) 2_746 2_756
Si2 Yb1 Si1 98.57(12) 2_746 2_756
Si2 Yb1 Si1 173.82(10) 2_646 2_756
Si2 Yb1 Si1 43.35(11) 2_756 2_756
Si2 Yb1 Si1 96.13(17) 2_656 2_756
Si3 Yb1 Si1 134.9(2) . 2_756
Si3 Yb1 Si1 85.01(15) 1_655 2_756
Si1 Yb1 Si1 75.94(13) 2_656 2_756
Si3 Yb2 Si3 88.2(2) . 1_655
Si3 Yb2 Si3 83.24(7) . 1_565
Si3 Yb2 Si3 147.67(11) 1_655 1_565
Si3 Yb2 Si3 147.67(12) . 1_665
Si3 Yb2 Si3 83.20(7) 1_655 1_665
Si3 Yb2 Si3 87.6(3) 1_565 1_665
Si3 Yb2 Si4 77.8(3) . 2_646
Si3 Yb2 Si4 77.8(2) 1_655 2_646
Si3 Yb2 Si4 129.85(11) 1_565 2_646
Si3 Yb2 Si4 129.87(16) 1_665 2_646
Si3 Yb2 Si4 129.75(16) . 2_656
Si3 Yb2 Si4 129.77(10) 1_655 2_656
Si3 Yb2 Si4 77.47(18) 1_565 2_656
Si3 Yb2 Si4 77.5(2) 1_665 2_656
Si4 Yb2 Si4 80.06(9) 2_646 2_656
Si3 Yb2 Si2 105.43(15) . 2_756
Si3 Yb2 Si2 48.19(17) 1_655 2_756
Si3 Yb2 Si2 104.51(14) 1_565 2_756
Si3 Yb2 Si2 47.40(18) 1_665 2_756
Si4 Yb2 Si2 125.15(17) 2_646 2_756
Si4 Yb2 Si2 124.1(2) 2_656 2_756
Si3 Yb2 Si2 48.18(17) . 2_656
Si3 Yb2 Si2 105.49(15) 1_655 2_656
Si3 Yb2 Si2 47.39(18) 1_565 2_656
Si3 Yb2 Si2 104.56(15) 1_665 2_656
Si4 Yb2 Si2 125.1(2) 2_646 2_656
Si4 Yb2 Si2 124.08(19) 2_656 2_656
Si2 Yb2 Si2 84.21(9) 2_756 2_656
Si3 Yb2 Si4 75.16(17) . .
Si3 Yb2 Si4 132.3(3) 1_655 .
Si3 Yb2 Si4 75.2(2) 1_565 .
Si3 Yb2 Si4 131.9(3) 1_665 .
Si4 Yb2 Si4 55.26(18) 2_646 .
Si4 Yb2 Si4 55.22(10) 2_656 .
Si2 Yb2 Si4 179.3(3) 2_756 .
Si2 Yb2 Si4 95.96(11) 2_656 .
Si3 Yb2 Si4 132.3(3) . 1_655
Si3 Yb2 Si4 75.1(2) 1_655 1_655
Si3 Yb2 Si4 131.9(3) 1_565 1_655
Si3 Yb2 Si4 75.14(17) 1_665 1_655
Si4 Yb2 Si4 55.30(10) 2_646 1_655
Si4 Yb2 Si4 55.26(18) 2_656 1_655
Si2 Yb2 Si4 96.01(10) 2_756 1_655
Si2 Yb2 Si4 179.3(3) 2_656 1_655
Si4 Yb2 Si4 83.81(9) . 1_655
Si3 Yb2 Mn1 106.8(2) . 2_656
Si3 Yb2 Mn1 106.6(2) 1_655 2_656
Si3 Yb2 Mn1 105.7(2) 1_565 2_656
Si3 Yb2 Mn1 105.6(2) 1_665 2_656
Si4 Yb2 Mn1 40.7(4) 2_646 2_656
Si4 Yb2 Mn1 39.4(4) 2_656 2_656
Si2 Yb2 Mn1 137.81(9) 2_756 2_656
Si2 Yb2 Mn1 137.93(10) 2_656 2_656
Si4 Yb2 Mn1 42.00(11) . 2_656
Si4 Yb2 Mn1 41.82(11) 1_655 2_656
Si3 Yb2 Mn1 100.4(2) . 1_655
Si3 Yb2 Mn1 44.72(11) 1_655 1_655
Si3 Yb2 Mn1 167.60(13) 1_565 1_655
Si3 Yb2 Mn1 95.2(3) 1_665 1_655
Si4 Yb2 Mn1 41.19(15) 2_646 1_655
Si4 Yb2 Mn1 91.3(2) 2_656 1_655
Si2 Yb2 Mn1 86.09(13) 2_756 1_655
Si2 Yb2 Mn1 142.1(3) 2_656 1_655
Si4 Yb2 Mn1 94.2(2) . 1_655
Si4 Yb2 Mn1 38.6(4) 1_655 1_655
Mn1 Yb2 Mn1 61.90(18) 2_656 1_655
Si4 Mn1 Si4 137.7(3) . 1_545
Si4 Mn1 Si4 83.2(5) . 2_546
Si4 Mn1 Si4 81.8(5) 1_545 2_546
Si4 Mn1 Si4 82.9(4) . 2_646
Si4 Mn1 Si4 81.5(6) 1_545 2_646
Si4 Mn1 Si4 136.8(3) 2_546 2_646
Si4 Mn1 Si3 112.1(7) . .
Si4 Mn1 Si3 110.2(7) 1_545 .
Si4 Mn1 Si3 111.8(2) 2_546 .
Si4 Mn1 Si3 111.3(2) 2_646 .
Si4 Mn1 Yb2 69.2(2) . 2_646
Si4 Mn1 Yb2 68.5(2) 1_545 2_646
Si4 Mn1 Yb2 68.47(17) 2_546 2_646
Si4 Mn1 Yb2 68.38(16) 2_646 2_646
Si3 Mn1 Yb2 178.7(7) . 2_646
Si4 Mn1 Yb2 67.4(4) . 1_455
Si4 Mn1 Yb2 137.3(3) 1_545 1_455
Si4 Mn1 Yb2 65.8(3) 2_546 1_455
Si4 Mn1 Yb2 141.2(7) 2_646 1_455
Si3 Mn1 Yb2 62.0(3) . 1_455
Yb2 Mn1 Yb2 119.0(3) 2_646 1_455
Si4 Mn1 Yb2 67.3(4) . .
Si4 Mn1 Yb2 136.8(3) 1_545 .
Si4 Mn1 Yb2 141.4(7) 2_546 .
Si4 Mn1 Yb2 65.6(4) 2_646 .
Si3 Mn1 Yb2 61.9(3) . .
Yb2 Mn1 Yb2 118.8(3) 2_646 .
Yb2 Mn1 Yb2 79.7(3) 1_455 .
Si4 Mn1 Mn1 112.8(3) . 2_546
Si4 Mn1 Mn1 42.49(17) 1_545 2_546
Si4 Mn1 Mn1 39.3(6) 2_546 2_546
Si4 Mn1 Mn1 113.5(5) 2_646 2_546
Si3 Mn1 Mn1 118.7(4) . 2_546
Yb2 Mn1 Mn1 60.6(3) 2_646 2_546
Yb2 Mn1 Mn1 101.2(2) 1_455 2_546
Yb2 Mn1 Mn1 179.1(3) . 2_546
Si4 Mn1 Mn1 42.27(14) . 2_556
Si4 Mn1 Mn1 113.3(3) 1_545 2_556
Si4 Mn1 Mn1 41.0(6) 2_546 2_556
Si4 Mn1 Mn1 114.7(4) 2_646 2_556
Si3 Mn1 Mn1 119.5(4) . 2_556
Yb2 Mn1 Mn1 61.5(2) 2_646 2_556
Yb2 Mn1 Mn1 57.53(15) 1_455 2_556
Yb2 Mn1 Mn1 105.7(2) . 2_556
Mn1 Mn1 Mn1 74.6(2) 2_546 2_556
Si4 Mn1 Yb2 138.4(3) . 1_445
Si4 Mn1 Yb2 66.0(3) 1_545 1_445
Si4 Mn1 Yb2 65.0(4) 2_546 1_445
Si4 Mn1 Yb2 138.6(7) 2_646 1_445
Si3 Mn1 Yb2 61.6(3) . 1_445
Yb2 Mn1 Yb2 117.7(3) 2_646 1_445
Yb2 Mn1 Yb2 75.13(10) 1_455 1_445
Yb2 Mn1 Yb2 123.48(16) . 1_445
Mn1 Mn1 Yb2 57.10(14) 2_546 1_445
Mn1 Mn1 Yb2 101.8(2) 2_556 1_445
Si4 Mn1 Yb2 138.0(3) . 1_545
Si4 Mn1 Yb2 65.8(4) 1_545 1_545
Si4 Mn1 Yb2 138.8(7) 2_546 1_545
Si4 Mn1 Yb2 64.8(3) 2_646 1_545
Si3 Mn1 Yb2 61.5(3) . 1_545
Yb2 Mn1 Yb2 117.5(3) 2_646 1_545
Yb2 Mn1 Yb2 123.48(16) 1_455 1_545
Yb2 Mn1 Yb2 74.93(10) . 1_545
Mn1 Mn1 Yb2 104.7(2) 2_546 1_545
Mn1 Mn1 Yb2 178.9(3) 2_556 1_545
Yb2 Mn1 Yb2 78.4(3) 1_445 1_545
Si1 Si1 Si1 136.8(5) 2_655 2_645
Si1 Si1 Si2 117.7(4) 2_655 .
Si1 Si1 Si2 105.5(4) 2_645 .
Si1 Si1 Yb1 80.0(3) 2_655 1_454
Si1 Si1 Yb1 69.4(3) 2_645 1_454
Si2 Si1 Yb1 134.9(2) . 1_454
Si1 Si1 Yb1 69.3(2) 2_655 2_656
Si1 Si1 Yb1 133.9(3) 2_645 2_656
Si2 Si1 Yb1 66.85(19) . 2_656
Yb1 Si1 Yb1 84.74(12) 1_454 2_656
Si1 Si1 Yb1 79.8(3) 2_655 1_554
Si1 Si1 Yb1 69.2(3) 2_645 1_554
Si2 Si1 Yb1 134.6(2) . 1_554
Yb1 Si1 Yb1 87.14(14) 1_454 1_554
Yb1 Si1 Yb1 149.0(2) 2_656 1_554
Si1 Si1 Yb1 69.1(2) 2_655 2_756
Si1 Si1 Yb1 133.6(3) 2_645 2_756
Si2 Si1 Yb1 66.71(19) . 2_756
Yb1 Si1 Yb1 149.0(2) 1_454 2_756
Yb1 Si1 Yb1 87.05(15) 2_656 2_756
Yb1 Si1 Yb1 84.63(13) 1_554 2_756
Si1 Si1 Yb1 141.2(3) 2_655 2_646
Si1 Si1 Yb1 61.6(2) 2_645 2_646
Si2 Si1 Yb1 61.5(2) . 2_646
Yb1 Si1 Yb1 78.76(12) 1_454 2_646
Yb1 Si1 Yb1 76.73(11) 2_656 2_646
Yb1 Si1 Yb1 130.7(2) 1_554 2_646
Yb1 Si1 Yb1 128.10(18) 2_756 2_646
Si1 Si1 Yb1 140.9(3) 2_655 2_746
Si1 Si1 Yb1 61.4(2) 2_645 2_746
Si2 Si1 Yb1 61.4(2) . 2_746
Yb1 Si1 Yb1 130.7(2) 1_454 2_746
Yb1 Si1 Yb1 128.11(18) 2_656 2_746
Yb1 Si1 Yb1 78.67(12) 1_554 2_746
Yb1 Si1 Yb1 76.64(11) 2_756 2_746
Yb1 Si1 Yb1 75.94(13) 2_646 2_746
Si1 Si2 Si3 120.6(3) . 2_656
Si1 Si2 Si3 132.2(4) . 2_646
Si3 Si2 Si3 107.22(18) 2_656 2_646
Si1 Si2 Yb1 66.52(16) . 2_756
Si3 Si2 Yb1 71.4(2) 2_656 2_756
Si3 Si2 Yb1 135.99(14) 2_646 2_756
Si1 Si2 Yb1 66.38(16) . 2_656
Si3 Si2 Yb1 71.3(2) 2_656 2_656
Si3 Si2 Yb1 135.79(13) 2_646 2_656
Yb1 Si2 Yb1 86.78(19) 2_756 2_656
Si1 Si2 Yb1 75.2(2) . 2_746
Si3 Si2 Yb1 136.52(15) 2_656 2_746
Si3 Si2 Yb1 70.22(19) 2_646 2_746
Yb1 Si2 Yb1 81.52(7) 2_756 2_746
Yb1 Si2 Yb1 141.41(14) 2_656 2_746
Si1 Si2 Yb1 75.10(19) . 2_646
Si3 Si2 Yb1 136.32(16) 2_656 2_646
Si3 Si2 Yb1 70.1(2) 2_646 2_646
Yb1 Si2 Yb1 141.41(13) 2_756 2_646
Yb1 Si2 Yb1 81.41(7) 2_656 2_646
Yb1 Si2 Yb1 85.2(2) 2_746 2_646
Si1 Si2 Yb2 137.77(17) . 2_746
Si3 Si2 Yb2 64.29(17) 2_656 2_746
Si3 Si2 Yb2 63.56(14) 2_646 2_746
Yb1 Si2 Yb2 78.11(11) 2_756 2_746
Yb1 Si2 Yb2 135.6(3) 2_656 2_746
Yb1 Si2 Yb2 77.47(9) 2_746 2_746
Yb1 Si2 Yb2 133.6(2) 2_646 2_746
Si1 Si2 Yb2 137.48(16) . 2_646
Si3 Si2 Yb2 64.21(19) 2_656 2_646
Si3 Si2 Yb2 63.49(12) 2_646 2_646
Yb1 Si2 Yb2 135.6(3) 2_756 2_646
Yb1 Si2 Yb2 78.01(11) 2_656 2_646
Yb1 Si2 Yb2 133.6(2) 2_746 2_646
Yb1 Si2 Yb2 77.38(10) 2_646 2_646
Yb2 Si2 Yb2 84.21(9) 2_746 2_646
Mn1 Si3 Si2 127.2(6) . 2_646
Mn1 Si3 Si2 125.5(6) . 2_656
Si2 Si3 Si2 107.22(18) 2_646 2_656
Mn1 Si3 Yb2 73.5(3) . .
Si2 Si3 Yb2 134.30(15) 2_646 .
Si2 Si3 Yb2 68.3(2) 2_656 .
Mn1 Si3 Yb2 73.3(3) . 1_455
Si2 Si3 Yb2 134.14(13) 2_646 1_455
Si2 Si3 Yb2 68.2(2) 2_656 1_455
Yb2 Si3 Yb2 88.2(2) . 1_455
Mn1 Si3 Yb2 74.4(3) . 1_545
Si2 Si3 Yb2 68.4(2) 2_646 1_545
Si2 Si3 Yb2 134.66(13) 2_656 1_545
Yb2 Si3 Yb2 83.24(8) . 1_545
Yb2 Si3 Yb2 147.67(12) 1_455 1_545
Mn1 Si3 Yb2 74.2(4) . 1_445
Si2 Si3 Yb2 68.3(2) 2_646 1_445
Si2 Si3 Yb2 134.51(17) 2_656 1_445
Yb2 Si3 Yb2 147.67(12) . 1_445
Yb2 Si3 Yb2 83.20(7) 1_455 1_445
Yb2 Si3 Yb2 87.6(3) 1_545 1_445
Mn1 Si3 Yb1 140.11(14) . .
Si2 Si3 Yb1 62.62(13) 2_646 .
Si2 Si3 Yb1 63.46(17) 2_656 .
Yb2 Si3 Yb1 76.65(10) . .
Yb2 Si3 Yb1 131.6(3) 1_455 .
Yb2 Si3 Yb1 76.37(12) 1_545 .
Yb2 Si3 Yb1 130.9(3) 1_445 .
Mn1 Si3 Yb1 139.78(14) . 1_455
Si2 Si3 Yb1 62.53(12) 2_646 1_455
Si2 Si3 Yb1 63.37(18) 2_656 1_455
Yb2 Si3 Yb1 131.6(3) . 1_455
Yb2 Si3 Yb1 76.62(13) 1_455 1_455
Yb2 Si3 Yb1 130.9(3) 1_545 1_455
Yb2 Si3 Yb1 76.35(9) 1_445 1_455
Yb1 Si3 Yb1 80.10(7) . 1_455
Mn1 Si4 Mn1 137.7(3) . 1_565
Mn1 Si4 Mn1 98.4(6) . 2_556
Mn1 Si4 Mn1 96.5(7) 1_565 2_556
Mn1 Si4 Mn1 98.7(7) . 2_656
Mn1 Si4 Mn1 96.8(6) 1_565 2_656
Mn1 Si4 Mn1 136.8(3) 2_556 2_656
Mn1 Si4 Si4 50.60(15) . 2_646
Mn1 Si4 Si4 130.9(3) 1_565 2_646
Mn1 Si4 Si4 132.5(5) 2_556 2_646
Mn1 Si4 Si4 48.1(6) 2_656 2_646
Mn1 Si4 Si4 130.7(3) . 2_656
Mn1 Si4 Si4 50.37(15) 1_565 2_656
Mn1 Si4 Si4 130.8(6) 2_556 2_656
Mn1 Si4 Si4 46.5(5) 2_656 2_656
Si4 Si4 Si4 87.5(3) 2_646 2_656
Mn1 Si4 Si4 50.32(16) . 2_546
Mn1 Si4 Si4 130.6(3) 1_565 2_546
Mn1 Si4 Si4 48.1(5) 2_556 2_546
Mn1 Si4 Si4 132.5(6) 2_656 2_546
Si4 Si4 Si4 92.502(18) 2_646 2_546
Si4 Si4 Si4 177.9(3) 2_656 2_546
Mn1 Si4 Si4 130.3(3) . 2_556
Mn1 Si4 Si4 50.09(14) 1_565 2_556
Mn1 Si4 Si4 46.5(6) 2_556 2_556
Mn1 Si4 Si4 130.9(5) 2_656 2_556
Si4 Si4 Si4 177.9(3) 2_646 2_556
Si4 Si4 Si4 92.501(18) 2_656 2_556
Si4 Si4 Si4 87.4(3) 2_546 2_556
Mn1 Si4 Yb2 151.5(5) . 2_656
Mn1 Si4 Yb2 70.9(4) 1_565 2_656
Mn1 Si4 Yb2 73.0(4) 2_556 2_656
Mn1 Si4 Yb2 73.1(4) 2_656 2_656
Si4 Si4 Yb2 115.5(3) 2_646 2_656
Si4 Si4 Yb2 62.75(14) 2_656 2_656
Si4 Si4 Yb2 115.5(2) 2_546 2_656
Si4 Si4 Yb2 62.74(14) 2_556 2_656
Mn1 Si4 Yb2 71.4(4) . 2_646
Mn1 Si4 Yb2 150.9(4) 1_565 2_646
Mn1 Si4 Yb2 74.2(4) 2_556 2_646
Mn1 Si4 Yb2 74.3(4) 2_656 2_646
Si4 Si4 Yb2 62.70(17) 2_646 2_646
Si4 Si4 Yb2 115.6(2) 2_656 2_646
Si4 Si4 Yb2 62.69(17) 2_546 2_646
Si4 Si4 Yb2 115.5(3) 2_556 2_646
Yb2 Si4 Yb2 80.06(9) 2_656 2_646
Mn1 Si4 Yb2 74.2(3) . .
Mn1 Si4 Yb2 74.8(2) 1_565 .
Mn1 Si4 Yb2 153.5(2) 2_556 .
Mn1 Si4 Yb2 69.63(17) 2_656 .
Si4 Si4 Yb2 62.0(3) 2_646 .
Si4 Si4 Yb2 62.1(2) 2_656 .
Si4 Si4 Yb2 119.7(3) 2_546 .
Si4 Si4 Yb2 119.8(3) 2_556 .
Yb2 Si4 Yb2 124.8(3) 2_656 .
Yb2 Si4 Yb2 124.7(4) 2_646 .
Mn1 Si4 Yb2 74.0(2) . 1_455
Mn1 Si4 Yb2 74.6(3) 1_565 1_455
Mn1 Si4 Yb2 69.71(18) 2_556 1_455
Mn1 Si4 Yb2 153.4(2) 2_656 1_455
Si4 Si4 Yb2 119.7(2) 2_646 1_455
Si4 Si4 Yb2 119.8(3) 2_656 1_455
Si4 Si4 Yb2 61.96(19) 2_546 1_455
Si4 Si4 Yb2 62.1(3) 2_556 1_455
Yb2 Si4 Yb2 124.8(4) 2_656 1_455
Yb2 Si4 Yb2 124.6(3) 2_646 1_455
Yb2 Si4 Yb2 83.81(9) . 1_455
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Yb1 Si1 2.908(5) 1_656
Yb1 Si1 2.910(5) 2_646
Yb1 Si1 2.911(5) 1_556
Yb1 Si1 2.913(5) 2_746
Yb1 Si2 2.917(5) 2_746
Yb1 Si2 2.921(5) 2_646
Yb1 Si2 2.961(7) 2_756
Yb1 Si2 2.964(7) 2_656
Yb1 Si3 3.116(3) .
Yb1 Si3 3.117(3) 1_655
Yb1 Si1 3.258(5) 2_656
Yb1 Si1 3.261(6) 2_756
Yb2 Si3 2.881(6) .
Yb2 Si3 2.882(7) 1_655
Yb2 Si3 2.898(8) 1_565
Yb2 Si3 2.899(6) 1_665
Yb2 Si4 2.981(9) 2_646
Yb2 Si4 2.985(10) 2_656
Yb2 Si2 2.989(3) 2_756
Yb2 Si2 2.992(3) 2_656
Yb2 Si4 3.002(4) .
Yb2 Si4 3.003(4) 1_655
Yb2 Mn1 3.028(5) 2_656
Yb2 Mn1 3.125(10) 1_655
Mn1 Si4 2.03(2) .
Mn1 Si4 2.09(2) 1_545
Mn1 Si4 2.152(6) 2_546
Mn1 Si4 2.161(6) 2_646
Mn1 Si3 2.296(5) .
Mn1 Yb2 3.028(5) 2_646
Mn1 Yb2 3.125(10) 1_455
Mn1 Mn1 3.165(7) 2_546
Mn1 Mn1 3.165(7) 2_556
Mn1 Yb2 3.170(10) 1_445
Mn1 Yb2 3.177(9) 1_545
Si1 Si1 2.064(4) 2_655
Si1 Si1 2.064(4) 2_645
Si1 Si2 2.314(6) .
Si1 Yb1 2.908(5) 1_454
Si1 Yb1 2.910(5) 2_656
Si1 Yb1 2.911(5) 1_554
Si1 Yb1 2.913(5) 2_756
Si1 Yb1 3.258(5) 2_646
Si1 Yb1 3.261(5) 2_746
Si2 Si3 2.368(10) 2_656
Si2 Si3 2.399(9) 2_646
Si2 Yb1 2.917(5) 2_756
Si2 Yb1 2.921(5) 2_656
Si2 Yb1 2.961(7) 2_746
Si2 Yb1 2.964(7) 2_646
Si2 Yb2 2.989(3) 2_746
Si2 Yb2 2.992(3) 2_646
Si3 Si2 2.368(10) 2_646
Si3 Si2 2.399(9) 2_656
Si3 Yb2 2.882(7) 1_455
Si3 Yb2 2.898(8) 1_545
Si3 Yb2 2.899(6) 1_445
Si3 Yb1 3.117(3) 1_455
Si4 Mn1 2.09(2) 1_565
Si4 Mn1 2.152(6) 2_556
Si4 Mn1 2.161(6) 2_656
Si4 Si4 2.775(7) 2_646
Si4 Si4 2.775(7) 2_656
Si4 Si4 2.777(7) 2_546
Si4 Si4 2.777(7) 2_556
Si4 Yb2 2.981(9) 2_656
Si4 Yb2 2.985(10) 2_646
Si4 Yb2 3.003(4) 1_455
