#------------------------------------------------------------------------------
#$Date: 2016-03-23 21:37:18 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179453 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/50/4335028.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4335028
loop_
_publ_author_name
'Shuangliu Zhou'
'Zhangshuan Wu'
'Lingmin Zhou'
'Shaowu Wang'
'Lijun Zhang'
'Xiancui Zhu'
'Yun Wei'
'Jinhua Zhai'
'Jie Wu'
_publ_contact_author_address
;College of Chemistry and Materials Science
Anhui Normal University
Wuhu, Anhui 241000 China
;
_publ_contact_author_email       swwang@mail.ahnu.edu.cn
_publ_contact_author_fax         0553-3883517
_publ_contact_author_name        'Shaowu Wang'
_publ_contact_author_phone       0553-3869310
_publ_section_title
;
 Controlled Synthesis of Racemic Indenyl Rare-Earth Metal Complexes via
 the Cooperation between the Intramolecular Coordination of Donor Atoms
 and a Bridge
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6417
_journal_page_last               6426
_journal_paper_doi               10.1021/ic4003109
_journal_volume                  52
_journal_year                    2013
_chemical_formula_sum            'C28 H35 N O Si Yb'
_chemical_formula_weight         602.70
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           62
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2ac 2n'
_symmetry_space_group_name_H-M   'P n m a'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   16.7214(18)
_cell_length_b                   10.5069(12)
_cell_length_c                   14.3848(16)
_cell_measurement_temperature    293(2)
_cell_volume                     2527.3(5)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0313
_diffrn_reflns_av_sigmaI/netI    0.0228
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            16574
_diffrn_reflns_theta_full        28.03
_diffrn_reflns_theta_max         28.03
_diffrn_reflns_theta_min         1.87
_exptl_absorpt_coefficient_mu    3.768
_exptl_absorpt_correction_T_max  0.5195
_exptl_absorpt_correction_T_min  0.3141
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_density_diffrn    1.584
_exptl_crystal_F_000             1208
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.704
_refine_diff_density_min         -1.544
_refine_diff_density_rms         0.190
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.310
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     268
_refine_ls_number_reflns         3216
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.310
_refine_ls_R_factor_all          0.0541
_refine_ls_R_factor_gt           0.0480
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0050P)²+41.1917P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1448
_refine_ls_wR_factor_ref         0.1472
_reflns_number_gt                2820
_reflns_number_total             3216
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic4003109_si_002_08.cif
_cod_data_source_block           15
_cod_database_code               4335028
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z'
'x+1/2, -y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z'
'-x-1/2, y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.8782(10) 0.3653(18) 0.3032(14) 0.039(4) Uani 0.50 1 d P
C5 C 0.8551(11) 0.391(2) 0.2093(14) 0.036(4) Uani 0.50 1 d P
C6 C 0.8482(12) 0.512(2) 0.1766(14) 0.045(4) Uani 0.50 1 d P
C7 C 0.8650(13) 0.616(2) 0.2313(19) 0.064(7) Uani 0.50 1 d P
C8 C 0.8886(14) 0.593(2) 0.3298(16) 0.054(5) Uani 0.50 1 d P
C9 C 0.8959(11) 0.473(2) 0.3639(14) 0.045(5) Uani 0.50 1 d P
C12 C 0.7182(12) 0.0220(19) 0.3782(17) 0.046(5) Uani 0.50 1 d P
C16 C 0.6372(13) 0.059(2) 0.3814(17) 0.050(5) Uani 0.50 1 d P
C17 C 0.5768(13) -0.015(2) 0.3340(17) 0.053(5) Uani 0.50 1 d P
C18 C 0.6012(17) -0.111(3) 0.275(2) 0.079(9) Uani 0.50 1 d P
C19 C 0.6829(15) -0.147(2) 0.268(2) 0.069(7) Uani 0.50 1 d P
C20 C 0.7405(14) -0.082(2) 0.3232(16) 0.054(5) Uani 0.50 1 d P
Yb1 Yb 0.72629(3) 0.2500 0.29321(4) 0.03231(17) Uani 1 2 d S
N1 N 0.6290(9) 0.4317(17) 0.3158(13) 0.045(4) Uani 0.50 1 d P
O1 O 0.6865(7) 0.2044(14) 0.1330(10) 0.056(4) Uani 0.50 1 d P
Si1 Si 0.8747(3) 0.1359(5) 0.4289(4) 0.0411(12) Uani 0.50 1 d P
C4 C 0.8474(8) 0.2500 0.1649(11) 0.054(4) Uani 1 2 d S
C2 C 0.8846(8) 0.2500 0.3201(10) 0.061(5) Uani 1 2 d S
C3 C 0.8681(12) 0.174(2) 0.2311(13) 0.037(4) Uani 0.50 1 d P
C10 C 0.9043(12) 0.2500 0.5370(13) 0.084(7) Uani 1 2 d S
C11 C 0.9305(12) -0.017(2) 0.4242(19) 0.061(7) Uani 0.50 1 d P
C21 C 0.8198(11) 0.2500 0.0675(10) 0.062(4) Uani 1 2 d S
C22 C 0.7336(13) 0.2500 0.0565(13) 0.124(12) Uani 1 2 d S
C23 C 0.6102(19) 0.153(4) 0.114(2) 0.111(13) Uani 0.50 1 d P
C13 C 0.7649(11) 0.1042(18) 0.4369(12) 0.040(4) Uani 0.50 1 d P
C15 C 0.6296(12) 0.169(2) 0.4416(14) 0.048(5) Uani 0.50 1 d P
C14 C 0.7094(10) 0.2006(18) 0.4760(12) 0.042(4) Uani 0.50 1 d P
C24 C 0.5532(11) 0.2500 0.4745(14) 0.075(6) Uani 1 2 d S
C25 C 0.5471(16) 0.373(4) 0.460(2) 0.089(10) Uani 0.50 1 d P
C26 C 0.5492(13) 0.418(3) 0.3551(18) 0.071(8) Uani 0.50 1 d P
C27 C 0.6120(18) 0.475(3) 0.213(2) 0.090(10) Uani 0.50 1 d P
C28 C 0.6794(15) 0.525(2) 0.3629(19) 0.056(6) Uani 0.50 1 d P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Yb Yb -0.3850 5.5486 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C3 C1 C2 81(2) 7_565 .
C3 C1 C5 33.1(14) 7_565 .
C2 C1 C5 113(2) . .
C3 C1 C9 150(2) 7_565 .
C2 C1 C9 128.3(18) . .
C5 C1 C9 118.3(18) . .
C3 C1 Si1 155.7(19) 7_565 7_565
C2 C1 Si1 78.4(12) . 7_565
C5 C1 Si1 159.4(15) . 7_565
C9 C1 Si1 54.0(11) . 7_565
C3 C1 Yb1 70.2(13) 7_565 .
C2 C1 Yb1 70.6(10) . .
C5 C1 Yb1 77.9(11) . .
C9 C1 Yb1 123.2(12) . .
Si1 C1 Yb1 91.1(7) 7_565 .
C3 C5 C6 168(3) 7_565 .
C3 C5 C1 52(2) 7_565 .
C6 C5 C1 121.8(19) . .
C3 C5 C4 52(2) 7_565 .
C6 C5 C4 135.4(18) . .
C1 C5 C4 102.7(17) . .
C3 C5 Yb1 66(2) 7_565 .
C6 C5 Yb1 124.2(13) . .
C1 C5 Yb1 73.0(11) . .
C4 C5 Yb1 68.5(9) . .
C7 C6 C5 121.8(19) . .
C6 C7 C8 118(2) . .
C9 C8 C7 121(2) . .
C9 C8 C11 41.5(13) . 7_565
C7 C8 C11 159(2) . 7_565
C11 C9 C8 86(2) 7_565 .
C11 C9 C1 151(2) 7_565 .
C8 C9 C1 119.0(19) . .
C11 C9 Si1 87.6(18) 7_565 7_565
C8 C9 Si1 154.0(19) . 7_565
C1 C9 Si1 75.0(13) . 7_565
C28 C12 C20 67(3) 7_565 .
C28 C12 C16 55(2) 7_565 .
C20 C12 C16 119(2) . .
C28 C12 C13 157(3) 7_565 .
C20 C12 C13 131(2) . .
C16 C12 C13 110(2) . .
C28 C12 N1 53(2) 7_565 7_565
C20 C12 N1 98.6(17) . 7_565
C16 C12 N1 31.7(11) . 7_565
C13 C12 N1 125.3(15) . 7_565
C28 C12 Yb1 116(2) 7_565 .
C20 C12 Yb1 115.0(15) . .
C16 C12 Yb1 79.6(12) . .
C13 C12 Yb1 72.8(10) . .
N1 C12 Yb1 65.0(8) 7_565 .
N1 C16 C28 87(3) 7_565 7_565
N1 C16 C12 98(2) 7_565 .
C28 C16 C12 36.8(15) 7_565 .
N1 C16 C15 119(3) 7_565 .
C28 C16 C15 143(3) 7_565 .
C12 C16 C15 109(2) . .
N1 C16 C17 59.5(19) 7_565 .
C28 C16 C17 85(2) 7_565 .
C12 C16 C17 121(2) . .
C15 C16 C17 131(2) . .
N1 C16 C26 66.7(19) 7_565 7_565
C28 C16 C26 130(3) 7_565 7_565
C12 C16 C26 163(2) . 7_565
C15 C16 C26 86.2(18) . 7_565
C17 C16 C26 45.9(14) . 7_565
N1 C16 C25 114(2) 7_565 7_565
C28 C16 C25 149(2) 7_565 7_565
C12 C16 C25 147(2) . 7_565
C15 C16 C25 46.7(13) . 7_565
C17 C16 C25 86.3(17) . 7_565
C26 C16 C25 50.7(14) 7_565 7_565
N1 C16 Yb1 63.6(15) 7_565 .
C28 C16 Yb1 96.7(16) 7_565 .
C12 C16 Yb1 70.8(11) . .
C15 C16 Yb1 75.3(11) . .
C17 C16 Yb1 122.9(15) . .
C26 C16 Yb1 106.3(16) 7_565 .
C25 C16 Yb1 113.3(14) 7_565 .
C26 C17 N1 73.4(18) 7_565 7_565
C26 C17 C18 157(3) 7_565 .
N1 C17 C18 100(2) 7_565 .
C26 C17 C16 71(2) 7_565 .
N1 C17 C16 40.7(12) 7_565 .
C18 C17 C16 119(2) . .
C26 C17 C28 112(2) 7_565 7_565
N1 C17 C28 54.5(14) 7_565 7_565
C18 C17 C28 79.5(18) . 7_565
C16 C17 C28 40.7(13) . 7_565
C26 C17 C27 99(2) 7_565 7_565
N1 C17 C27 55.8(14) 7_565 7_565
C18 C17 C27 60.3(17) . 7_565
C16 C17 C27 95.5(15) . 7_565
C28 C17 C27 85.8(15) 7_565 7_565
C17 C18 C19 121(2) . .
C17 C18 C27 74.7(18) . 7_565
C19 C18 C27 95(2) . 7_565
C17 C18 C28 58.6(15) . 7_565
C19 C18 C28 62.6(16) . 7_565
C27 C18 C28 83.1(15) 7_565 7_565
C18 C19 C20 119(3) . .
C18 C19 C28 75(2) . 7_565
C20 C19 C28 44.4(14) . 7_565
C28 C20 C12 36.1(13) 7_565 .
C28 C20 C19 86(2) 7_565 .
C12 C20 C19 121(2) . .
O1 Yb1 O1 22.6(7) 7_565 .
O1 Yb1 N1 95.4(6) 7_565 7_565
O1 Yb1 N1 78.4(5) . 7_565
O1 Yb1 N1 78.4(5) 7_565 .
O1 Yb1 N1 95.4(6) . .
N1 Yb1 N1 98.0(8) 7_565 .
O1 Yb1 C13 133.4(5) 7_565 7_565
O1 Yb1 C13 156.0(5) . 7_565
N1 Yb1 C13 119.5(6) 7_565 7_565
N1 Yb1 C13 67.7(6) . 7_565
O1 Yb1 C13 156.0(5) 7_565 .
O1 Yb1 C13 133.4(5) . .
N1 Yb1 C13 67.7(6) 7_565 .
N1 Yb1 C13 119.5(6) . .
C13 Yb1 C13 70.5(9) 7_565 .
O1 Yb1 C3 89.1(5) 7_565 .
O1 Yb1 C3 82.4(5) . .
N1 Yb1 C3 113.0(6) 7_565 .
N1 Yb1 C3 147.6(6) . .
C13 Yb1 C3 102.6(6) 7_565 .
C13 Yb1 C3 82.6(6) . .
O1 Yb1 C3 82.4(5) 7_565 7_565
O1 Yb1 C3 89.1(5) . 7_565
N1 Yb1 C3 147.6(6) 7_565 7_565
N1 Yb1 C3 113.0(6) . 7_565
C13 Yb1 C3 82.6(6) 7_565 7_565
C13 Yb1 C3 102.6(6) . 7_565
C3 Yb1 C3 35.0(10) . 7_565
O1 Yb1 C2 113.9(4) 7_565 .
O1 Yb1 C2 113.9(4) . .
N1 Yb1 C2 128.2(4) 7_565 .
N1 Yb1 C2 128.2(4) . .
C13 Yb1 C2 69.3(5) 7_565 .
C13 Yb1 C2 69.3(5) . .
C3 Yb1 C2 33.4(5) . .
C3 Yb1 C2 33.4(5) 7_565 .
O1 Yb1 C14 148.5(5) 7_565 7_565
O1 Yb1 C14 158.2(5) . 7_565
N1 Yb1 C14 87.3(6) 7_565 7_565
N1 Yb1 C14 70.2(6) . 7_565
C13 Yb1 C14 32.2(5) 7_565 7_565
C13 Yb1 C14 51.4(6) . 7_565
C3 Yb1 C14 118.6(6) . 7_565
C3 Yb1 C14 111.3(5) 7_565 7_565
C2 Yb1 C14 87.8(5) . 7_565
O1 Yb1 C14 158.2(5) 7_565 .
O1 Yb1 C14 148.5(5) . .
N1 Yb1 C14 70.2(6) 7_565 .
N1 Yb1 C14 87.3(6) . .
C13 Yb1 C14 51.4(6) 7_565 .
C13 Yb1 C14 32.2(5) . .
C3 Yb1 C14 111.3(5) . .
C3 Yb1 C14 118.6(6) 7_565 .
C2 Yb1 C14 87.8(5) . .
C14 Yb1 C14 22.2(8) 7_565 .
O1 Yb1 C12 103.9(6) 7_565 7_565
O1 Yb1 C12 126.0(6) . 7_565
N1 Yb1 C12 125.5(6) 7_565 7_565
N1 Yb1 C12 40.3(6) . 7_565
C13 Yb1 C12 31.2(6) 7_565 7_565
C13 Yb1 C12 99.9(7) . 7_565
C3 Yb1 C12 117.7(7) . 7_565
C3 Yb1 C12 86.0(7) 7_565 7_565
C2 Yb1 C12 89.1(5) . 7_565
C14 Yb1 C12 51.7(7) 7_565 7_565
C14 Yb1 C12 73.9(7) . 7_565
C16 N1 C17 80(2) 7_565 7_565
C16 N1 C28 52(2) 7_565 .
C17 N1 C28 80.5(18) 7_565 .
C16 N1 C26 76(2) 7_565 .
C17 N1 C26 50.2(16) 7_565 .
C28 N1 C26 115(2) . .
C16 N1 C27 157(3) 7_565 .
C17 N1 C27 82.5(18) 7_565 .
C28 N1 C27 110(2) . .
C26 N1 C27 103.2(18) . .
C16 N1 C12 50.6(18) 7_565 7_565
C17 N1 C12 106.2(18) 7_565 7_565
C28 N1 C12 27.4(11) . 7_565
C26 N1 C12 126.3(19) . 7_565
C27 N1 C12 122.5(18) . 7_565
C16 N1 Yb1 96.5(17) 7_565 .
C17 N1 Yb1 173.8(17) 7_565 .
C28 N1 Yb1 101.2(13) . .
C26 N1 Yb1 124.2(15) . .
C27 N1 Yb1 102.3(14) . .
C12 N1 Yb1 74.7(8) 7_565 .
O1 O1 C23 112.5(18) 7_565 .
O1 O1 C22 70.5(6) 7_565 .
C23 O1 C22 118(2) . .
O1 O1 Yb1 78.7(3) 7_565 .
C23 O1 Yb1 120.2(17) . .
C22 O1 Yb1 120.5(10) . .
C9 Si1 C1 51.0(10) 7_565 7_565
C9 Si1 C11 37.9(11) 7_565 .
C1 Si1 C11 86.7(11) 7_565 .
C9 Si1 C13 97.7(10) 7_565 .
C1 Si1 C13 95.3(8) 7_565 .
C11 Si1 C13 110.0(9) . .
C9 Si1 C2 87.0(9) 7_565 .
C1 Si1 C2 37.9(7) 7_565 .
C11 Si1 C2 117.0(9) . .
C13 Si1 C2 103.8(7) . .
C9 Si1 C10 149.6(10) 7_565 .
C1 Si1 C10 139.8(8) 7_565 .
C11 Si1 C10 114.7(9) . .
C13 Si1 C10 107.3(9) . .
C2 Si1 C10 103.2(5) . .
C9 Si1 Si1 138.7(8) 7_565 7_565
C1 Si1 Si1 90.4(6) 7_565 7_565
C11 Si1 Si1 149.8(7) . 7_565
C13 Si1 Si1 100.2(6) . 7_565
C2 Si1 Si1 52.7(3) . 7_565
C10 Si1 Si1 53.7(3) . 7_565
C3 C4 C3 77(2) 7_565 .
C3 C4 C21 141.7(12) 7_565 .
C3 C4 C21 141.7(12) . .
C3 C4 C5 28.4(10) 7_565 .
C3 C4 C5 104.7(18) . .
C21 C4 C5 113.6(9) . .
C3 C4 C5 104.7(18) 7_565 7_565
C3 C4 C5 28.4(10) . 7_565
C21 C4 C5 113.6(9) . 7_565
C5 C4 C5 132.5(18) . 7_565
C3 C4 Yb1 72.6(10) 7_565 .
C3 C4 Yb1 72.6(10) . .
C21 C4 Yb1 114.1(10) . .
C5 C4 Yb1 78.1(9) . .
C5 C4 Yb1 78.1(9) 7_565 .
C1 C2 C1 155(2) . 7_565
C1 C2 C3 46.5(13) . 7_565
C1 C2 C3 109.2(16) 7_565 7_565
C1 C2 C3 109.2(16) . .
C1 C2 C3 46.5(13) 7_565 .
C3 C2 C3 62.8(17) 7_565 .
C1 C2 Si1 63.7(11) . 7_565
C1 C2 Si1 137.8(14) 7_565 7_565
C3 C2 Si1 109.2(8) 7_565 7_565
C3 C2 Si1 163.9(11) . 7_565
C1 C2 Si1 137.8(14) . .
C1 C2 Si1 63.7(11) 7_565 .
C3 C2 Si1 163.9(11) 7_565 .
C3 C2 Si1 109.2(8) . .
Si1 C2 Si1 74.6(6) 7_565 .
C1 C2 Yb1 83.4(11) . .
C1 C2 Yb1 83.4(11) 7_565 .
C3 C2 Yb1 72.6(9) 7_565 .
C3 C2 Yb1 72.6(9) . .
Si1 C2 Yb1 91.8(5) 7_565 .
Si1 C2 Yb1 91.8(5) . .
C5 C3 C1 95(3) 7_565 7_565
C5 C3 C4 100(3) 7_565 .
C1 C3 C4 161(2) 7_565 .
C5 C3 C2 147(3) 7_565 .
C1 C3 C2 52.9(13) 7_565 .
C4 C3 C2 110.0(17) . .
C5 C3 C3 151(2) 7_565 7_565
C1 C3 C3 111.4(16) 7_565 7_565
C4 C3 C3 51.7(12) . 7_565
C2 C3 C3 58.6(8) . 7_565
C5 C3 Yb1 99(2) 7_565 .
C1 C3 Yb1 86.2(13) 7_565 .
C4 C3 Yb1 79.8(11) . .
C2 C3 Yb1 74.0(9) . .
C3 C3 Yb1 72.5(5) 7_565 .
Si1 C10 Si1 72.7(6) . 7_565
C9 C11 C8 52.1(16) 7_565 7_565
C9 C11 Si1 54.5(13) 7_565 .
C8 C11 Si1 103.0(12) 7_565 .
C22 C21 C4 114.5(14) . .
O1 C22 O1 39.0(13) 7_565 .
O1 C22 C21 117.5(15) 7_565 .
O1 C22 C21 117.5(15) . .
O1 C23 C27 96(2) . 7_565
C12 C13 C14 107.0(16) . .
C12 C13 Si1 127.1(15) . .
C14 C13 Si1 121.1(14) . .
C12 C13 Yb1 75.9(10) . .
C14 C13 Yb1 75.5(9) . .
Si1 C13 Yb1 95.1(7) . .
C16 C15 C14 107.8(17) . .
C16 C15 C25 87(2) . 7_565
C14 C15 C25 150(2) . 7_565
C16 C15 C24 132.0(18) . .
C14 C15 C24 120.2(18) . .
C25 C15 C24 50.2(16) 7_565 .
C16 C15 C15 142.8(11) . 7_565
C14 C15 C15 76.7(11) . 7_565
C25 C15 C15 107.2(18) 7_565 7_565
C24 C15 C15 57.9(8) . 7_565
C16 C15 C14 130.1(15) . 7_565
C14 C15 C14 30.7(13) . 7_565
C25 C15 C14 142(2) 7_565 7_565
C24 C15 C14 95.3(14) . 7_565
C15 C15 C14 46.0(8) 7_565 7_565
C16 C15 Yb1 74.8(11) . .
C14 C15 Yb1 70.3(9) . .
C25 C15 Yb1 140.0(17) 7_565 .
C24 C15 Yb1 121.2(11) . .
C15 C15 Yb1 72.3(5) 7_565 .
C14 C15 Yb1 65.8(7) 7_565 .
C14 C14 C15 103.3(11) 7_565 .
C14 C14 C13 133.0(10) 7_565 .
C15 C14 C13 106.6(17) . .
C14 C14 C15 46.0(8) 7_565 7_565
C15 C14 C15 57.2(15) . 7_565
C13 C14 C15 143.2(14) . 7_565
C14 C14 Yb1 78.9(4) 7_565 .
C15 C14 Yb1 79.0(10) . .
C13 C14 Yb1 72.3(9) . .
C15 C14 Yb1 72.1(8) 7_565 .
C25 C24 C25 160(4) . 7_565
C25 C24 C15 59.5(14) . 7_565
C25 C24 C15 122.6(18) 7_565 7_565
C25 C24 C15 122.6(18) . .
C25 C24 C15 59.5(14) 7_565 .
C15 C24 C15 64.2(16) 7_565 .
C24 C25 C15 70.3(18) . 7_565
C24 C25 C26 116(3) . .
C15 C25 C26 84.0(17) 7_565 .
C24 C25 C16 112.4(19) . 7_565
C15 C25 C16 45.9(13) 7_565 7_565
C26 C25 C16 48.8(13) . 7_565
C17 C26 N1 56.4(15) 7_565 .
C17 C26 C16 62.8(19) 7_565 7_565
N1 C26 C16 37.2(11) . 7_565
C17 C26 C25 121(3) 7_565 .
N1 C26 C25 115(2) . .
C16 C26 C25 80(2) 7_565 .
N1 C27 C18 76.8(19) . 7_565
N1 C27 C17 41.8(12) . 7_565
C18 C27 C17 45.0(15) 7_565 7_565
N1 C27 C23 119(2) . 7_565
C18 C27 C23 163(2) 7_565 7_565
C17 C27 C23 145(2) 7_565 7_565
C12 C28 C16 88(3) 7_565 7_565
C12 C28 C20 77(3) 7_565 7_565
C16 C28 C20 157(3) 7_565 7_565
C12 C28 N1 100(2) 7_565 .
C16 C28 N1 41.0(14) 7_565 .
C20 C28 N1 124(2) 7_565 .
C12 C28 C17 141(3) 7_565 7_565
C16 C28 C17 54.5(17) 7_565 7_565
C20 C28 C17 133(2) 7_565 7_565
N1 C28 C17 45.0(12) . 7_565
C12 C28 C19 125(3) 7_565 7_565
C16 C28 C19 135(3) 7_565 7_565
C20 C28 C19 49.4(15) 7_565 7_565
N1 C28 C19 98.2(18) . 7_565
C17 C28 C19 84.2(17) 7_565 7_565
C12 C28 C18 157(3) 7_565 7_565
C16 C28 C18 95(2) 7_565 7_565
C20 C28 C18 92(2) 7_565 7_565
N1 C28 C18 68.9(15) . 7_565
C17 C28 C18 41.9(13) 7_565 7_565
C19 C28 C18 42.4(13) 7_565 7_565
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 C3 1.13(3) 7_565
C1 C2 1.241(19) .
C1 C5 1.43(3) .
C1 C9 1.46(3) .
C1 Si1 1.81(2) 7_565
C1 Yb1 2.818(17) .
C5 C3 0.78(2) 7_565
C5 C6 1.36(3) .
C5 C4 1.62(2) .
C5 Yb1 2.88(2) .
C6 C7 1.37(3) .
C7 C8 1.49(3) .
C8 C9 1.36(3) .
C8 C11 1.72(3) 7_565
C9 C11 1.14(3) 7_565
C9 Si1 1.52(2) 7_565
C12 C28 0.84(3) 7_565
C12 C20 1.40(3) .
C12 C16 1.41(3) .
C12 C13 1.44(3) .
C12 N1 1.81(3) 7_565
C12 Yb1 2.693(18) .
C16 N1 0.96(2) 7_565
C16 C28 1.16(3) 7_565
C16 C15 1.45(3) .
C16 C17 1.45(3) .
C16 C26 1.54(3) 7_565
C16 C25 2.02(4) 7_565
C16 Yb1 2.80(2) .
C17 C26 1.17(3) 7_565
C17 N1 1.27(2) 7_565
C17 C18 1.38(4) .
C17 C28 1.77(3) 7_565
C17 C27 1.89(4) 7_565
C18 C19 1.42(4) .
C18 C27 1.70(4) 7_565
C18 C28 2.04(4) 7_565
C19 C20 1.42(3) .
C19 C28 1.87(4) 7_565
C20 C28 1.31(3) 7_565
Yb1 O1 2.446(13) 7_565
Yb1 O1 2.446(13) .
Yb1 N1 2.529(16) 7_565
Yb1 N1 2.529(16) .
Yb1 C13 2.653(16) 7_565
Yb1 C13 2.653(16) .
Yb1 C3 2.657(18) .
Yb1 C3 2.657(18) 7_565
Yb1 C2 2.676(13) .
Yb1 C14 2.695(17) 7_565
Yb1 C14 2.695(17) .
Yb1 C12 2.693(18) 7_565
N1 C16 0.96(2) 7_565
N1 C17 1.27(2) 7_565
N1 C28 1.46(3) .
N1 C26 1.46(3) .
N1 C27 1.57(3) .
N1 C12 1.81(3) 7_565
O1 O1 0.96(3) 7_565
O1 C23 1.41(3) .
O1 C22 1.44(2) .
Si1 C9 1.52(2) 7_565
Si1 C1 1.81(2) 7_565
Si1 C11 1.86(2) .
Si1 C13 1.870(19) .
Si1 C2 1.978(13) .
Si1 C10 2.024(15) .
Si1 Si1 2.398(11) 7_565
C4 C3 1.29(2) 7_565
C4 C3 1.29(2) .
C4 C21 1.47(2) .
C4 C5 1.62(2) 7_565
C2 C1 1.241(19) 7_565
C2 C3 1.53(2) 7_565
C2 C3 1.53(2) .
C2 Si1 1.978(13) 7_565
C3 C5 0.78(2) 7_565
C3 C1 1.13(3) 7_565
C3 C3 1.60(5) 7_565
C10 Si1 2.024(15) 7_565
C11 C9 1.14(3) 7_565
C11 C8 1.72(3) 7_565
C21 C22 1.45(3) .
C22 O1 1.44(2) 7_565
C23 C27 1.96(5) 7_565
C13 C14 1.48(3) .
C15 C14 1.46(3) .
C15 C25 1.47(3) 7_565
C15 C24 1.61(2) .
C15 C15 1.71(4) 7_565
C15 C14 1.98(3) 7_565
C14 C14 1.04(4) 7_565
C14 C15 1.98(3) 7_565
C24 C25 1.31(4) .
C24 C25 1.31(4) 7_565
C24 C15 1.61(2) 7_565
C25 C15 1.47(3) 7_565
C25 C26 1.58(4) .
C25 C16 2.02(4) 7_565
C26 C17 1.17(3) 7_565
C26 C16 1.54(3) 7_565
C27 C18 1.70(4) 7_565
C27 C17 1.89(4) 7_565
C27 C23 1.96(5) 7_565
C28 C12 0.84(3) 7_565
C28 C16 1.16(3) 7_565
C28 C20 1.31(3) 7_565
C28 C17 1.77(3) 7_565
C28 C19 1.87(4) 7_565
C28 C18 2.04(4) 7_565
