#------------------------------------------------------------------------------
#$Date: 2016-03-23 22:07:42 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179468 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/65/4336565.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4336565
loop_
_publ_author_name
'Volodymyr Smetana'
'Gordon J. Miller'
'John D. Corbett'
_publ_section_title
;
 Polyclusters and Substitution Effects in the Na-Au-Ga System: Remarkable
 Sodium Bonding Characteristics in Polar Intermetallics
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              12502
_journal_page_last               12510
_journal_paper_doi               10.1021/ic401580y
_journal_volume                  52
_journal_year                    2013
_chemical_formula_sum            'Au2 Ga4 Na'
_chemical_formula_weight         695.80
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           62
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2ac 2n'
_symmetry_space_group_name_H-M   'P n m a'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   16.733(3)
_cell_length_b                   4.3330(9)
_cell_length_c                   7.3580(15)
_cell_measurement_reflns_used    8000
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      25.5
_cell_measurement_theta_min      3.02
_cell_volume                     533.49(18)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.958
_diffrn_measured_fraction_theta_max 0.958
_diffrn_measurement_device_type  'Bruker CCD'
_diffrn_measurement_method       w-scan
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0634
_diffrn_reflns_av_sigmaI/netI    0.0864
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       4
_diffrn_reflns_limit_k_min       -4
_diffrn_reflns_limit_l_max       7
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            541
_diffrn_reflns_theta_full        25.50
_diffrn_reflns_theta_max         25.50
_diffrn_reflns_theta_min         3.02
_exptl_absorpt_coefficient_mu    74.616
_exptl_absorpt_correction_T_max  0.19
_exptl_absorpt_correction_T_min  0.11
_exptl_absorpt_correction_type   numerical
_exptl_crystal_colour            silver
_exptl_crystal_density_diffrn    8.663
_exptl_crystal_description       'irregular fragment'
_exptl_crystal_F_000             1172
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.09
_refine_diff_density_max         2.181
_refine_diff_density_min         -1.927
_refine_diff_density_rms         0.510
_refine_ls_extinction_coef       0.0020(2)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.055
_refine_ls_matrix_type           full
_refine_ls_number_parameters     44
_refine_ls_number_reflns         367
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.055
_refine_ls_R_factor_all          0.0901
_refine_ls_R_factor_gt           0.0487
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0285P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0761
_refine_ls_wR_factor_ref         0.0833
_reflns_number_gt                248
_reflns_number_total             367
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic401580y_si_002_2.cif
_cod_data_source_block           NaAu2Ga4
_cod_original_cell_volume        533.49(19)
_cod_database_code               4336565
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z'
'x+1/2, -y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z'
'-x-1/2, y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Au1 Au 0.47695(11) 0.2500 0.7588(4) 0.0169(7) Uani 1 2 d S
Au2 Au 0.21916(11) 0.2500 0.5016(4) 0.0212(7) Uani 1 2 d S
Ga3 Ga 0.3156(3) 0.2500 0.8054(10) 0.0127(15) Uani 1 2 d S
Ga4 Ga 0.4358(3) -0.2500 0.9440(9) 0.0178(17) Uani 1 2 d S
Ga5 Ga 0.4521(3) -0.2500 0.5574(9) 0.0150(17) Uani 1 2 d S
Ga6 Ga 0.3009(3) -0.2500 0.5729(10) 0.0183(17) Uani 1 2 d S
Na1 Na 0.3760(12) 0.2500 0.256(4) 0.031(6) Uani 1 2 d S
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ga Ga 0.2307 1.6083 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ga5 Au1 Ga4 119.23(18) 5_656 5_657
Ga5 Au1 Ga4 125.17(13) 5_656 1_565
Ga4 Au1 Ga4 73.53(15) 5_657 1_565
Ga5 Au1 Ga4 125.17(13) 5_656 .
Ga4 Au1 Ga4 73.53(15) 5_657 .
Ga4 Au1 Ga4 109.7(3) 1_565 .
Ga5 Au1 Ga5 64.83(14) 5_656 .
Ga4 Au1 Ga5 123.42(12) 5_657 .
Ga4 Au1 Ga5 155.83(16) 1_565 .
Ga4 Au1 Ga5 65.14(18) . .
Ga5 Au1 Ga5 64.83(14) 5_656 1_565
Ga4 Au1 Ga5 123.42(12) 5_657 1_565
Ga4 Au1 Ga5 65.14(18) 1_565 1_565
Ga4 Au1 Ga5 155.83(16) . 1_565
Ga5 Au1 Ga5 109.2(3) . 1_565
Ga5 Au1 Ga3 124.3(2) 5_656 .
Ga4 Au1 Ga3 116.48(19) 5_657 .
Ga4 Au1 Ga3 71.19(13) 1_565 .
Ga4 Au1 Ga3 71.19(13) . .
Ga5 Au1 Ga3 85.11(15) . .
Ga5 Au1 Ga3 85.11(15) 1_565 .
Ga5 Au1 Na1 68.3(5) 5_656 5_666
Ga4 Au1 Na1 67.1(5) 5_657 5_666
Ga4 Au1 Na1 70.8(3) 1_565 5_666
Ga4 Au1 Na1 138.7(4) . 5_666
Ga5 Au1 Na1 129.6(4) . 5_666
Ga5 Au1 Na1 64.0(4) 1_565 5_666
Ga3 Au1 Na1 138.4(2) . 5_666
Ga5 Au1 Na1 68.3(5) 5_656 5_656
Ga4 Au1 Na1 67.1(5) 5_657 5_656
Ga4 Au1 Na1 138.7(4) 1_565 5_656
Ga4 Au1 Na1 70.8(3) . 5_656
Ga5 Au1 Na1 64.0(4) . 5_656
Ga5 Au1 Na1 129.6(4) 1_565 5_656
Ga3 Au1 Na1 138.4(2) . 5_656
Na1 Au1 Na1 82.7(5) 5_666 5_656
Ga6 Au2 Ga6 111.8(2) 1_565 .
Ga6 Au2 Ga4 123.28(10) 1_565 2_554
Ga6 Au2 Ga4 123.28(10) . 2_554
Ga6 Au2 Ga3 153.5(2) 1_565 2_554
Ga6 Au2 Ga3 63.24(16) . 2_554
Ga4 Au2 Ga3 72.39(14) 2_554 2_554
Ga6 Au2 Ga3 63.24(16) 1_565 2_564
Ga6 Au2 Ga3 153.5(2) . 2_564
Ga4 Au2 Ga3 72.39(14) 2_554 2_564
Ga3 Au2 Ga3 108.6(3) 2_554 2_564
Ga6 Au2 Ga3 62.05(15) 1_565 .
Ga6 Au2 Ga3 62.05(15) . .
Ga4 Au2 Ga3 135.1(2) 2_554 .
Ga3 Au2 Ga3 124.50(10) 2_554 .
Ga3 Au2 Ga3 124.50(10) 2_564 .
Ga6 Au2 Ga6 104.76(19) 1_565 2_554
Ga6 Au2 Ga6 104.76(19) . 2_554
Ga4 Au2 Ga6 74.62(18) 2_554 2_554
Ga3 Au2 Ga6 55.86(15) 2_554 2_554
Ga3 Au2 Ga6 55.86(15) 2_564 2_554
Ga3 Au2 Ga6 150.26(17) . 2_554
Ga6 Au2 Na1 71.5(3) 1_565 .
Ga6 Au2 Na1 71.5(3) . .
Ga4 Au2 Na1 136.1(5) 2_554 .
Ga3 Au2 Na1 82.7(3) 2_554 .
Ga3 Au2 Na1 82.7(3) 2_564 .
Ga3 Au2 Na1 88.7(5) . .
Ga6 Au2 Na1 61.5(5) 2_554 .
Ga6 Au2 Na1 65.9(3) 1_565 2_565
Ga6 Au2 Na1 133.5(5) . 2_565
Ga4 Au2 Na1 67.2(4) 2_554 2_565
Ga3 Au2 Na1 137.8(3) 2_554 2_565
Ga3 Au2 Na1 70.5(4) 2_564 2_565
Ga3 Au2 Na1 79.7(4) . 2_565
Ga6 Au2 Na1 121.1(4) 2_554 2_565
Na1 Au2 Na1 136.41(18) . 2_565
Ga6 Au2 Na1 133.5(5) 1_565 2
Ga6 Au2 Na1 65.9(3) . 2
Ga4 Au2 Na1 67.2(4) 2_554 2
Ga3 Au2 Na1 70.5(4) 2_554 2
Ga3 Au2 Na1 137.8(3) 2_564 2
Ga3 Au2 Na1 79.7(4) . 2
Ga6 Au2 Na1 121.1(4) 2_554 2
Na1 Au2 Na1 136.41(18) . 2
Na1 Au2 Na1 82.8(6) 2_565 2
Au2 Ga3 Au2 108.6(3) 2_565 2
Au2 Ga3 Au1 106.53(15) 2_565 .
Au2 Ga3 Au1 106.53(15) 2 .
Au2 Ga3 Au2 108.13(13) 2_565 .
Au2 Ga3 Au2 108.13(13) 2 .
Au1 Ga3 Au2 118.6(3) . .
Au2 Ga3 Ga6 57.46(13) 2_565 2
Au2 Ga3 Ga6 57.46(13) 2 2
Au1 Ga3 Ga6 142.0(3) . 2
Au2 Ga3 Ga6 99.4(2) . 2
Au2 Ga3 Ga6 161.7(2) 2_565 .
Au2 Ga3 Ga6 71.34(14) 2 .
Au1 Ga3 Ga6 90.56(17) . .
Au2 Ga3 Ga6 56.47(16) . .
Ga6 Ga3 Ga6 112.10(12) 2 .
Au2 Ga3 Ga6 71.34(14) 2_565 1_565
Au2 Ga3 Ga6 161.7(2) 2 1_565
Au1 Ga3 Ga6 90.56(17) . 1_565
Au2 Ga3 Ga6 56.47(16) . 1_565
Ga6 Ga3 Ga6 112.10(12) 2 1_565
Ga6 Ga3 Ga6 102.8(3) . 1_565
Au2 Ga3 Na1 63.0(2) 2_565 1_556
Au2 Ga3 Na1 63.0(2) 2 1_556
Au1 Ga3 Na1 80.3(4) . 1_556
Au2 Ga3 Na1 161.1(4) . 1_556
Ga6 Ga3 Na1 61.7(4) 2 1_556
Ga6 Ga3 Na1 128.05(17) . 1_556
Ga6 Ga3 Na1 128.05(17) 1_565 1_556
Au2 Ga4 Au1 114.4(3) 2 5_657
Au2 Ga4 Au1 109.83(14) 2 1_545
Au1 Ga4 Au1 106.47(15) 5_657 1_545
Au2 Ga4 Au1 109.83(14) 2 .
Au1 Ga4 Au1 106.47(15) 5_657 .
Au1 Ga4 Au1 109.7(3) 1_545 .
Au2 Ga4 Ga5 104.7(2) 2 .
Au1 Ga4 Ga5 140.8(2) 5_657 .
Au1 Ga4 Ga5 57.55(14) 1_545 .
Au1 Ga4 Ga5 57.55(14) . .
Au2 Ga4 Na1 65.8(3) 2 1_556
Au1 Ga4 Na1 65.9(4) 5_657 1_556
Au1 Ga4 Na1 165.9(4) 1_545 1_556
Au1 Ga4 Na1 84.3(3) . 1_556
Ga5 Ga4 Na1 135.9(4) . 1_556
Au2 Ga4 Na1 65.8(3) 2 1_546
Au1 Ga4 Na1 65.9(4) 5_657 1_546
Au1 Ga4 Na1 84.3(3) 1_545 1_546
Au1 Ga4 Na1 165.9(4) . 1_546
Ga5 Ga4 Na1 135.9(4) . 1_546
Na1 Ga4 Na1 81.7(6) 1_556 1_546
Au2 Ga4 Na1 164.3(5) 2 5_656
Au1 Ga4 Na1 81.3(5) 5_657 5_656
Au1 Ga4 Na1 63.1(2) 1_545 5_656
Au1 Ga4 Na1 63.1(2) . 5_656
Ga5 Ga4 Na1 59.5(5) . 5_656
Na1 Ga4 Na1 124.6(4) 1_556 5_656
Na1 Ga4 Na1 124.6(3) 1_546 5_656
Ga6 Ga5 Au1 119.6(3) . 5_656
Ga6 Ga5 Au1 97.56(18) . .
Au1 Ga5 Au1 115.17(14) 5_656 .
Ga6 Ga5 Au1 97.56(18) . 1_545
Au1 Ga5 Au1 115.17(14) 5_656 1_545
Au1 Ga5 Au1 109.2(3) . 1_545
Ga6 Ga5 Ga5 125.5(2) . 5_656
Au1 Ga5 Ga5 58.4(2) 5_656 5_656
Au1 Ga5 Ga5 56.81(13) . 5_656
Au1 Ga5 Ga5 134.7(3) 1_545 5_656
Ga6 Ga5 Ga5 125.5(2) . 5_646
Au1 Ga5 Ga5 58.4(2) 5_656 5_646
Au1 Ga5 Ga5 134.7(3) . 5_646
Au1 Ga5 Ga5 56.81(13) 1_545 5_646
Ga5 Ga5 Ga5 100.1(3) 5_656 5_646
Ga6 Ga5 Ga4 82.0(2) . .
Au1 Ga5 Ga4 158.4(3) 5_656 .
Au1 Ga5 Ga4 57.31(14) . .
Au1 Ga5 Ga4 57.31(14) 1_545 .
Ga5 Ga5 Ga4 110.6(3) 5_656 .
Ga5 Ga5 Ga4 110.6(3) 5_646 .
Ga6 Ga5 Na1 151.9(6) . 5_656
Au1 Ga5 Na1 88.5(5) 5_656 5_656
Au1 Ga5 Na1 67.6(3) . 5_656
Au1 Ga5 Na1 67.6(3) 1_545 5_656
Ga5 Ga5 Na1 67.4(3) 5_656 5_656
Ga5 Ga5 Na1 67.4(3) 5_646 5_656
Ga4 Ga5 Na1 69.9(5) . 5_656
Ga6 Ga5 Na1 69.5(4) . 1_545
Au1 Ga5 Na1 65.4(4) 5_656 1_545
Au1 Ga5 Na1 162.8(3) . 1_545
Au1 Ga5 Na1 84.4(3) 1_545 1_545
Ga5 Ga5 Na1 120.9(5) 5_656 1_545
Ga5 Ga5 Na1 61.5(3) 5_646 1_545
Ga4 Ga5 Na1 128.5(4) . 1_545
Na1 Ga5 Na1 128.9(4) 5_656 1_545
Ga6 Ga5 Na1 69.5(4) . .
Au1 Ga5 Na1 65.4(4) 5_656 .
Au1 Ga5 Na1 84.4(3) . .
Au1 Ga5 Na1 162.8(3) 1_545 .
Ga5 Ga5 Na1 61.5(3) 5_656 .
Ga5 Ga5 Na1 120.9(5) 5_646 .
Ga4 Ga5 Na1 128.5(4) . .
Na1 Ga5 Na1 128.9(4) 5_656 .
Na1 Ga5 Na1 80.5(6) 1_545 .
Ga5 Ga6 Au2 120.91(12) . 1_545
Ga5 Ga6 Au2 120.91(12) . .
Au2 Ga6 Au2 111.8(2) 1_545 .
Ga5 Ga6 Ga3 132.2(3) . 2_554
Au2 Ga6 Ga3 59.29(14) 1_545 2_554
Au2 Ga6 Ga3 59.29(14) . 2_554
Ga5 Ga6 Ga3 86.53(19) . .
Au2 Ga6 Ga3 144.8(3) 1_545 .
Au2 Ga6 Ga3 61.48(14) . .
Ga3 Ga6 Ga3 120.05(12) 2_554 .
Ga5 Ga6 Ga3 86.53(19) . 1_545
Au2 Ga6 Ga3 61.48(14) 1_545 1_545
Au2 Ga6 Ga3 144.8(3) . 1_545
Ga3 Ga6 Ga3 120.05(12) 2_554 1_545
Ga3 Ga6 Ga3 102.8(3) . 1_545
Ga5 Ga6 Au2 98.7(3) . 2
Au2 Ga6 Au2 98.27(17) 1_545 2
Au2 Ga6 Au2 98.27(17) . 2
Ga3 Ga6 Au2 129.2(2) 2_554 2
Ga3 Ga6 Au2 52.81(17) . 2
Ga3 Ga6 Au2 52.81(17) 1_545 2
Ga5 Ga6 Na1 158.1(6) . 2
Au2 Ga6 Na1 66.8(2) 1_545 2
Au2 Ga6 Na1 66.8(2) . 2
Ga3 Ga6 Na1 69.7(5) 2_554 2
Ga3 Ga6 Na1 79.9(3) . 2
Ga3 Ga6 Na1 79.9(3) 1_545 2
Au2 Ga6 Na1 59.5(5) 2 2
Ga5 Ga6 Na1 66.6(4) . 1_545
Au2 Ga6 Na1 62.0(3) 1_545 1_545
Au2 Ga6 Na1 125.4(4) . 1_545
Ga3 Ga6 Na1 76.9(4) 2_554 1_545
Ga3 Ga6 Na1 152.0(3) . 1_545
Ga3 Ga6 Na1 83.9(4) 1_545 1_545
Au2 Ga6 Na1 135.8(4) 2 1_545
Na1 Ga6 Na1 128.0(4) 2 1_545
Ga5 Ga6 Na1 66.6(4) . .
Au2 Ga6 Na1 125.4(4) 1_545 .
Au2 Ga6 Na1 62.0(3) . .
Ga3 Ga6 Na1 76.9(4) 2_554 .
Ga3 Ga6 Na1 83.9(4) . .
Ga3 Ga6 Na1 152.0(3) 1_545 .
Au2 Ga6 Na1 135.8(4) 2 .
Na1 Ga6 Na1 128.0(4) 2 .
Na1 Ga6 Na1 78.6(6) 1_545 .
Au2 Na1 Ga5 119.9(9) . 5_656
Au2 Na1 Ga6 59.0(4) . 2_554
Ga5 Na1 Ga6 178.9(9) 5_656 2_554
Au2 Na1 Au2 85.6(4) . 2_554
Ga5 Na1 Au2 133.2(4) 5_656 2_554
Ga6 Na1 Au2 47.2(3) 2_554 2_554
Au2 Na1 Au2 85.6(4) . 2_564
Ga5 Na1 Au2 133.2(4) 5_656 2_564
Ga6 Na1 Au2 47.2(3) 2_554 2_564
Au2 Na1 Au2 82.8(6) 2_554 2_564
Au2 Na1 Au1 129.5(6) . 5_666
Ga5 Na1 Au1 48.5(3) 5_656 5_666
Ga6 Na1 Au1 132.0(5) 2_554 5_666
Au2 Na1 Au1 141.5(9) 2_554 5_666
Au2 Na1 Au1 84.8(3) 2_564 5_666
Au2 Na1 Au1 129.5(6) . 5_656
Ga5 Na1 Au1 48.5(3) 5_656 5_656
Ga6 Na1 Au1 132.0(5) 2_554 5_656
Au2 Na1 Au1 84.8(3) 2_554 5_656
Au2 Na1 Au1 141.5(9) 2_564 5_656
Au1 Na1 Au1 82.7(5) 5_666 5_656
Au2 Na1 Ga4 130.0(4) . 1_554
Ga5 Na1 Ga4 91.5(4) 5_656 1_554
Ga6 Na1 Ga4 89.3(6) 2_554 1_554
Au2 Na1 Ga4 47.0(3) 2_554 1_554
Au2 Na1 Ga4 100.6(7) 2_564 1_554
Au1 Na1 Ga4 100.5(6) 5_666 1_554
Au1 Na1 Ga4 47.0(2) 5_656 1_554
Au2 Na1 Ga4 130.0(4) . 1_564
Ga5 Na1 Ga4 91.5(4) 5_656 1_564
Ga6 Na1 Ga4 89.3(6) 2_554 1_564
Au2 Na1 Ga4 100.6(7) 2_554 1_564
Au2 Na1 Ga4 47.0(3) 2_564 1_564
Au1 Na1 Ga4 47.0(2) 5_666 1_564
Au1 Na1 Ga4 100.5(6) 5_656 1_564
Ga4 Na1 Ga4 81.7(6) 1_554 1_564
Au2 Na1 Ga5 86.4(6) . 1_565
Ga5 Na1 Ga5 51.1(4) 5_656 1_565
Ga6 Na1 Ga5 128.3(4) 2_554 1_565
Au2 Na1 Ga5 171.9(8) 2_554 1_565
Au2 Na1 Ga5 97.76(10) 2_564 1_565
Au1 Na1 Ga5 46.4(2) 5_666 1_565
Au1 Na1 Ga5 99.4(6) 5_656 1_565
Ga4 Na1 Ga5 140.1(6) 1_554 1_565
Ga4 Na1 Ga5 85.5(2) 1_564 1_565
Au2 Na1 Ga5 86.4(6) . .
Ga5 Na1 Ga5 51.1(4) 5_656 .
Ga6 Na1 Ga5 128.3(4) 2_554 .
Au2 Na1 Ga5 97.76(10) 2_554 .
Au2 Na1 Ga5 171.9(8) 2_564 .
Au1 Na1 Ga5 99.4(6) 5_666 .
Au1 Na1 Ga5 46.4(2) 5_656 .
Ga4 Na1 Ga5 85.5(2) 1_554 .
Ga4 Na1 Ga5 140.1(6) 1_564 .
Ga5 Na1 Ga5 80.5(6) 1_565 .
Au2 Na1 Ga6 46.5(3) . 1_565
Ga5 Na1 Ga6 92.1(6) 5_656 1_565
Ga6 Na1 Ga6 87.0(4) 2_554 1_565
Au2 Na1 Ga6 129.0(6) 2_554 1_565
Au2 Na1 Ga6 78.0(3) 2_564 1_565
Au1 Na1 Ga6 83.1(3) 5_666 1_565
Au1 Na1 Ga6 135.7(8) 5_656 1_565
Ga4 Na1 Ga6 176.1(6) 1_554 1_565
Ga4 Na1 Ga6 99.73(11) 1_564 1_565
Ga5 Na1 Ga6 43.9(3) 1_565 1_565
Ga5 Na1 Ga6 95.6(7) . 1_565
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Au1 Ga5 2.612(7) 5_656
Au1 Ga4 2.629(7) 5_657
Au1 Ga4 2.650(4) 1_565
Au1 Ga4 2.650(4) .
Au1 Ga5 2.658(4) .
Au1 Ga5 2.658(4) 1_565
Au1 Ga3 2.722(5) .
Au1 Na1 3.281(15) 5_666
Au1 Na1 3.281(15) 5_656
Au2 Ga6 2.616(3) 1_565
Au2 Ga6 2.616(3) .
Au2 Ga4 2.628(5) 2_554
Au2 Ga3 2.668(5) 2_554
Au2 Ga3 2.668(5) 2_564
Au2 Ga3 2.757(7) .
Au2 Ga6 3.173(8) 2_554
Au2 Na1 3.19(2) .
Au2 Na1 3.275(19) 2_565
Au2 Na1 3.275(19) 2
Ga3 Au2 2.668(5) 2_565
Ga3 Au2 2.668(5) 2
Ga3 Ga6 2.770(9) 2
Ga3 Ga6 2.772(6) .
Ga3 Ga6 2.772(6) 1_565
Ga3 Na1 3.46(3) 1_556
Ga4 Au2 2.628(5) 2
Ga4 Au1 2.629(7) 5_657
Ga4 Au1 2.650(4) 1_545
Ga4 Ga5 2.857(9) .
Ga4 Na1 3.31(2) 1_556
Ga4 Na1 3.31(2) 1_546
Ga4 Na1 3.48(2) 5_656
Ga5 Ga6 2.531(7) .
Ga5 Au1 2.612(7) 5_656
Ga5 Au1 2.658(4) 1_545
Ga5 Ga5 2.825(7) 5_656
Ga5 Ga5 2.825(7) 5_646
Ga5 Na1 3.19(2) 5_656
Ga5 Na1 3.35(2) 1_545
Ga5 Na1 3.35(2) .
Ga6 Au2 2.616(3) 1_545
Ga6 Ga3 2.770(9) 2_554
Ga6 Ga3 2.772(6) 1_545
Ga6 Au2 3.173(8) 2
Ga6 Na1 3.25(2) 2
Ga6 Na1 3.42(2) 1_545
Ga6 Na1 3.42(2) .
Na1 Ga5 3.19(2) 5_656
Na1 Ga6 3.25(2) 2_554
Na1 Au2 3.275(19) 2_554
Na1 Au2 3.275(19) 2_564
Na1 Au1 3.281(15) 5_666
Na1 Au1 3.281(15) 5_656
Na1 Ga4 3.31(2) 1_554
Na1 Ga4 3.31(2) 1_564
Na1 Ga5 3.35(2) 1_565
Na1 Ga6 3.42(2) 1_565
