#------------------------------------------------------------------------------
#$Date: 2016-02-16 22:30:59 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176467 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/66/4336614.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4336614
loop_
_publ_author_name
'Nian-Tzu Suen'
'Svilen Bobev'
_publ_section_title
;
 Synthesis and Structural Characterization of RE7Zn21Tt2 (RE = La-Nd; Tt =
 Ge, Sn, and Pb): New Structure Type Among the Polar Intermetallic Phases
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              12731
_journal_page_last               12740
_journal_paper_doi               10.1021/ic4019844
_journal_volume                  52
_journal_year                    2013
_chemical_formula_moiety         Pr7Zn21.30Ge1.70
_chemical_formula_sum            'Ge1.7 Pr7 Zn21.3'
_chemical_formula_weight         2502.15
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           55
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2 2ab'
_symmetry_space_group_name_H-M   'P b a m'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   15.437(2)
_cell_length_b                   17.075(3)
_cell_length_c                   4.4537(7)
_cell_measurement_reflns_used    1762
_cell_measurement_temperature    200(2)
_cell_measurement_theta_max      29.00
_cell_measurement_theta_min      5.16
_cell_volume                     1173.9(3)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      200(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0655
_diffrn_reflns_av_sigmaI/netI    0.0292
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       5
_diffrn_reflns_limit_l_min       -5
_diffrn_reflns_number            13921
_diffrn_reflns_theta_full        26.36
_diffrn_reflns_theta_max         26.36
_diffrn_reflns_theta_min         1.78
_exptl_absorpt_coefficient_mu    37.592
_exptl_absorpt_correction_T_max  0.6025
_exptl_absorpt_correction_T_min  0.4192
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            silver
_exptl_crystal_density_diffrn    7.078
_exptl_crystal_description       irregular
_exptl_crystal_F_000             2213
_exptl_crystal_size_max          0.03
_exptl_crystal_size_mid          0.02
_exptl_crystal_size_min          0.02
_refine_diff_density_max         1.561
_refine_diff_density_min         -1.681
_refine_diff_density_rms         0.304
_refine_ls_extinction_coef       0.000226(19)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.083
_refine_ls_matrix_type           full
_refine_ls_number_parameters     94
_refine_ls_number_reflns         1364
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.083
_refine_ls_R_factor_all          0.0363
_refine_ls_R_factor_gt           0.0236
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0097P)²+4.4167P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0370
_refine_ls_wR_factor_ref         0.0410
_reflns_number_gt                1103
_reflns_number_total             1364
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic4019844_si_002_02.cif
_cod_data_source_block           PrZnGe
_cod_original_cell_volume        1174.0(3)
_cod_original_formula_sum        'Ge1.70 Pr7 Zn21.30'
_cod_database_code               4336614
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z'
'-x+1/2, y+1/2, -z'
'x+1/2, -y+1/2, -z'
'-x, -y, -z'
'x, y, -z'
'x-1/2, -y-1/2, z'
'-x-1/2, y-1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Pr1 Pr 0.16563(4) 0.18077(3) 0.5000 0.00756(13) Uani 1 2 d S
Pr2 Pr 0.41784(4) 0.25966(3) 0.5000 0.01187(14) Uani 1 2 d S
Pr3 Pr 0.16446(4) 0.45469(3) 0.0000 0.00767(13) Uani 1 2 d S
Pr4 Pr 0.0000 0.0000 0.5000 0.01114(19) Uani 1 4 d S
Ge1 Ge 0.01994(7) 0.14149(6) 0.0000 0.0102(2) Uani 0.85 2 d SP
Zn1 Zn 0.01994(7) 0.14149(6) 0.0000 0.0102(2) Uani 0.15 2 d SP
Zn2 Zn 0.07286(8) 0.35919(7) 0.5000 0.0127(3) Uani 1 2 d S
Zn3 Zn 0.24859(8) 0.35344(7) 0.5000 0.0126(3) Uani 1 2 d S
Zn4 Zn 0.29954(8) 0.49449(7) 0.5000 0.0129(3) Uani 1 2 d S
Zn5 Zn 0.35243(8) 0.08089(7) 0.5000 0.0136(3) Uani 1 2 d S
Zn6 Zn 0.07485(8) 0.28371(7) 0.0000 0.0099(3) Uani 1 2 d S
Zn7 Zn 0.15147(8) 0.05199(6) 0.0000 0.0096(3) Uani 1 2 d S
Zn8 Zn 0.25674(8) 0.28141(6) 0.0000 0.0097(3) Uani 1 2 d S
Zn9 Zn 0.30358(8) 0.14159(6) 0.0000 0.0101(3) Uani 1 2 d S
Zn10 Zn 0.36311(7) 0.40091(7) 0.0000 0.0116(3) Uani 1 2 d S
Zn11 Zn 0.46564(8) 0.09838(7) 0.0000 0.0124(3) Uani 1 2 d S
Zn12 Zn 0.0000 0.5000 0.5000 0.0137(4) Uani 1 4 d S
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pr Pr -0.2180 2.8214 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Zn7 Pr1 Zn7 90.44(3) . 1_556
Zn7 Pr1 Zn8 84.93(2) . .
Zn7 Pr1 Zn8 156.46(4) 1_556 .
Zn7 Pr1 Zn8 156.46(4) . 1_556
Zn7 Pr1 Zn8 84.93(2) 1_556 1_556
Zn8 Pr1 Zn8 90.16(3) . 1_556
Zn7 Pr1 Zn9 52.91(3) . .
Zn7 Pr1 Zn9 113.55(3) 1_556 .
Zn8 Pr1 Zn9 46.67(3) . .
Zn8 Pr1 Zn9 108.30(3) 1_556 .
Zn7 Pr1 Zn9 113.55(3) . 1_556
Zn7 Pr1 Zn9 52.92(3) 1_556 1_556
Zn8 Pr1 Zn9 108.30(3) . 1_556
Zn8 Pr1 Zn9 46.67(3) 1_556 1_556
Zn9 Pr1 Zn9 89.86(4) . 1_556
Zn7 Pr1 Zn6 81.89(3) . .
Zn7 Pr1 Zn6 149.10(4) 1_556 .
Zn8 Pr1 Zn6 52.86(3) . .
Zn8 Pr1 Zn6 113.13(3) 1_556 .
Zn9 Pr1 Zn6 85.41(2) . .
Zn9 Pr1 Zn6 156.07(3) 1_556 .
Zn7 Pr1 Zn6 149.10(4) . 1_556
Zn7 Pr1 Zn6 81.89(3) 1_556 1_556
Zn8 Pr1 Zn6 113.13(3) . 1_556
Zn8 Pr1 Zn6 52.86(3) 1_556 1_556
Zn9 Pr1 Zn6 156.07(3) . 1_556
Zn9 Pr1 Zn6 85.41(2) 1_556 1_556
Zn6 Pr1 Zn6 89.46(3) . 1_556
Zn7 Pr1 Zn3 132.12(2) . .
Zn7 Pr1 Zn3 132.12(2) 1_556 .
Zn8 Pr1 Zn3 47.205(18) . .
Zn8 Pr1 Zn3 47.204(18) 1_556 .
Zn9 Pr1 Zn3 85.73(3) . .
Zn9 Pr1 Zn3 85.73(3) 1_556 .
Zn6 Pr1 Zn3 70.55(3) . .
Zn6 Pr1 Zn3 70.55(3) 1_556 .
Zn7 Pr1 Zn4 47.194(19) . 3_546
Zn7 Pr1 Zn4 47.194(19) 1_556 3_546
Zn8 Pr1 Zn4 117.66(3) . 3_546
Zn8 Pr1 Zn4 117.66(3) 1_556 3_546
Zn9 Pr1 Zn4 71.23(3) . 3_546
Zn9 Pr1 Zn4 71.22(3) 1_556 3_546
Zn6 Pr1 Zn4 128.43(2) . 3_546
Zn6 Pr1 Zn4 128.43(2) 1_556 3_546
Zn3 Pr1 Zn4 146.92(4) . 3_546
Zn7 Pr1 Zn1 107.15(3) . 1_556
Zn7 Pr1 Zn1 46.97(3) 1_556 1_556
Zn8 Pr1 Zn1 155.72(3) . 1_556
Zn8 Pr1 Zn1 86.38(2) 1_556 1_556
Zn9 Pr1 Zn1 155.73(3) . 1_556
Zn9 Pr1 Zn1 86.53(2) 1_556 1_556
Zn6 Pr1 Zn1 106.96(3) . 1_556
Zn6 Pr1 Zn1 47.38(3) 1_556 1_556
Zn3 Pr1 Zn1 117.85(3) . 1_556
Zn4 Pr1 Zn1 84.92(3) 3_546 1_556
Zn7 Pr1 Ge1 107.15(3) . 1_556
Zn7 Pr1 Ge1 46.97(3) 1_556 1_556
Zn8 Pr1 Ge1 155.72(3) . 1_556
Zn8 Pr1 Ge1 86.38(2) 1_556 1_556
Zn9 Pr1 Ge1 155.73(3) . 1_556
Zn9 Pr1 Ge1 86.53(2) 1_556 1_556
Zn6 Pr1 Ge1 106.96(3) . 1_556
Zn6 Pr1 Ge1 47.38(3) 1_556 1_556
Zn3 Pr1 Ge1 117.85(3) . 1_556
Zn4 Pr1 Ge1 84.92(3) 3_546 1_556
Zn1 Pr1 Ge1 0.00(5) 1_556 1_556
Zn3 Pr2 Zn2 171.21(4) . 7_665
Zn3 Pr2 Zn1 98.27(3) . 7_666
Zn2 Pr2 Zn1 88.03(3) 7_665 7_666
Zn3 Pr2 Ge1 98.27(3) . 7_666
Zn2 Pr2 Ge1 88.03(3) 7_665 7_666
Zn1 Pr2 Ge1 0.00(3) 7_666 7_666
Zn3 Pr2 Zn1 98.27(3) . 7_665
Zn2 Pr2 Zn1 88.03(3) 7_665 7_665
Zn1 Pr2 Zn1 87.91(3) 7_666 7_665
Ge1 Pr2 Zn1 87.91(3) 7_666 7_665
Zn3 Pr2 Ge1 98.27(3) . 7_665
Zn2 Pr2 Ge1 88.03(3) 7_665 7_665
Zn1 Pr2 Ge1 87.91(3) 7_666 7_665
Ge1 Pr2 Ge1 87.91(3) 7_666 7_665
Zn1 Pr2 Ge1 0.00(3) 7_665 7_665
Zn3 Pr2 Zn5 103.20(4) . .
Zn2 Pr2 Zn5 68.01(4) 7_665 .
Zn1 Pr2 Zn5 130.83(2) 7_666 .
Ge1 Pr2 Zn5 130.83(2) 7_666 .
Zn1 Pr2 Zn5 130.83(2) 7_665 .
Ge1 Pr2 Zn5 130.83(2) 7_665 .
Zn3 Pr2 Zn8 46.44(2) . 1_556
Zn2 Pr2 Zn8 129.51(2) 7_665 1_556
Zn1 Pr2 Zn8 81.11(3) 7_666 1_556
Ge1 Pr2 Zn8 81.11(3) 7_666 1_556
Zn1 Pr2 Zn8 139.97(3) 7_665 1_556
Ge1 Pr2 Zn8 139.97(3) 7_665 1_556
Zn5 Pr2 Zn8 82.67(3) . 1_556
Zn3 Pr2 Zn8 46.442(19) . .
Zn2 Pr2 Zn8 129.51(2) 7_665 .
Zn1 Pr2 Zn8 139.97(3) 7_666 .
Ge1 Pr2 Zn8 139.97(3) 7_666 .
Zn1 Pr2 Zn8 81.11(3) 7_665 .
Ge1 Pr2 Zn8 81.11(3) 7_665 .
Zn5 Pr2 Zn8 82.67(3) . .
Zn8 Pr2 Zn8 83.05(3) 1_556 .
Zn3 Pr2 Zn6 136.655(18) . 7_666
Zn2 Pr2 Zn6 46.38(2) 7_665 7_666
Zn1 Pr2 Zn6 45.92(3) 7_666 7_666
Ge1 Pr2 Zn6 45.92(3) 7_666 7_666
Zn1 Pr2 Zn6 102.75(3) 7_665 7_666
Ge1 Pr2 Zn6 102.75(3) 7_665 7_666
Zn5 Pr2 Zn6 90.99(3) . 7_666
Zn8 Pr2 Zn6 96.81(2) 1_556 7_666
Zn8 Pr2 Zn6 173.63(3) . 7_666
Zn3 Pr2 Zn6 136.655(18) . 7_665
Zn2 Pr2 Zn6 46.38(2) 7_665 7_665
Zn1 Pr2 Zn6 102.75(3) 7_666 7_665
Ge1 Pr2 Zn6 102.75(3) 7_666 7_665
Zn1 Pr2 Zn6 45.92(3) 7_665 7_665
Ge1 Pr2 Zn6 45.92(3) 7_665 7_665
Zn5 Pr2 Zn6 90.99(3) . 7_665
Zn8 Pr2 Zn6 173.63(3) 1_556 7_665
Zn8 Pr2 Zn6 96.81(2) . 7_665
Zn6 Pr2 Zn6 82.61(3) 7_666 7_665
Zn3 Pr2 Zn10 54.24(2) . 1_556
Zn2 Pr2 Zn10 130.56(2) 7_665 1_556
Zn1 Pr2 Zn10 44.93(3) 7_666 1_556
Ge1 Pr2 Zn10 44.93(3) 7_666 1_556
Zn1 Pr2 Zn10 101.77(3) 7_665 1_556
Ge1 Pr2 Zn10 101.77(3) 7_665 1_556
Zn5 Pr2 Zn10 126.68(3) . 1_556
Zn8 Pr2 Zn10 45.67(3) 1_556 1_556
Zn8 Pr2 Zn10 99.92(3) . 1_556
Zn6 Pr2 Zn10 84.35(2) 7_666 1_556
Zn6 Pr2 Zn10 140.25(3) 7_665 1_556
Zn2 Pr3 Zn2 91.79(4) . 1_554
Zn2 Pr3 Zn3 51.89(3) . .
Zn2 Pr3 Zn3 114.40(3) 1_554 .
Zn2 Pr3 Zn3 114.40(3) . 1_554
Zn2 Pr3 Zn3 51.88(3) 1_554 1_554
Zn3 Pr3 Zn3 91.68(4) . 1_554
Zn2 Pr3 Zn5 79.16(3) . 3_556
Zn2 Pr3 Zn5 147.18(4) 1_554 3_556
Zn3 Pr3 Zn5 84.68(3) . 3_556
Zn3 Pr3 Zn5 159.19(4) 1_554 3_556
Zn2 Pr3 Zn5 147.18(4) . 3
Zn2 Pr3 Zn5 79.16(3) 1_554 3
Zn3 Pr3 Zn5 159.19(4) . 3
Zn3 Pr3 Zn5 84.68(3) 1_554 3
Zn5 Pr3 Zn5 91.47(4) 3_556 3
Zn2 Pr3 Zn4 158.46(4) . 1_554
Zn2 Pr3 Zn4 84.66(3) 1_554 1_554
Zn3 Pr3 Zn4 110.68(4) . 1_554
Zn3 Pr3 Zn4 48.00(3) 1_554 1_554
Zn5 Pr3 Zn4 114.55(3) 3_556 1_554
Zn5 Pr3 Zn4 52.78(3) 3 1_554
Zn2 Pr3 Zn4 84.66(3) . .
Zn2 Pr3 Zn4 158.46(4) 1_554 .
Zn3 Pr3 Zn4 48.00(3) . .
Zn3 Pr3 Zn4 110.68(4) 1_554 .
Zn5 Pr3 Zn4 52.78(3) 3_556 .
Zn5 Pr3 Zn4 114.55(3) 3 .
Zn4 Pr3 Zn4 90.87(4) 1_554 .
Zn2 Pr3 Zn11 96.78(3) . 3
Zn2 Pr3 Zn11 96.78(3) 1_554 3
Zn3 Pr3 Zn11 134.110(18) . 3
Zn3 Pr3 Zn11 134.111(18) 1_554 3
Zn5 Pr3 Zn11 53.89(2) 3_556 3
Zn5 Pr3 Zn11 53.89(2) 3 3
Zn4 Pr3 Zn11 104.73(3) 1_554 3
Zn4 Pr3 Zn11 104.73(3) . 3
Zn2 Pr3 Zn11 54.11(2) . 7_565
Zn2 Pr3 Zn11 54.11(2) 1_554 7_565
Zn3 Pr3 Zn11 104.10(3) . 7_565
Zn3 Pr3 Zn11 104.10(3) 1_554 7_565
Zn5 Pr3 Zn11 96.65(3) 3_556 7_565
Zn5 Pr3 Zn11 96.65(3) 3 7_565
Zn4 Pr3 Zn11 134.541(19) 1_554 7_565
Zn4 Pr3 Zn11 134.542(18) . 7_565
Zn11 Pr3 Zn11 67.15(4) 3 7_565
Zn2 Pr3 Zn10 106.62(3) . .
Zn2 Pr3 Zn10 106.62(3) 1_554 .
Zn3 Pr3 Zn10 55.90(3) . .
Zn3 Pr3 Zn10 55.90(3) 1_554 .
Zn5 Pr3 Zn10 106.21(3) 3_556 .
Zn5 Pr3 Zn10 106.21(3) 3 .
Zn4 Pr3 Zn10 54.78(2) 1_554 .
Zn4 Pr3 Zn10 54.78(2) . .
Zn11 Pr3 Zn10 145.97(4) 3 .
Zn11 Pr3 Zn10 146.88(3) 7_565 .
Zn2 Pr3 Zn9 126.11(2) . 3
Zn2 Pr3 Zn9 126.11(2) 1_554 3
Zn3 Pr3 Zn9 119.11(3) . 3
Zn3 Pr3 Zn9 119.11(3) 1_554 3
Zn5 Pr3 Zn9 47.778(19) 3_556 3
Zn5 Pr3 Zn9 47.778(19) 3 3
Zn4 Pr3 Zn9 71.53(3) 1_554 3
Zn4 Pr3 Zn9 71.53(3) . 3
Zn11 Pr3 Zn9 48.09(3) 3 3
Zn11 Pr3 Zn9 115.24(3) 7_565 3
Zn10 Pr3 Zn9 97.88(3) . 3
Zn4 Pr4 Zn4 180.0 7_565 3_546
Zn4 Pr4 Zn1 85.93(3) 7_565 5
Zn4 Pr4 Zn1 94.07(3) 3_546 5
Zn4 Pr4 Zn1 94.07(3) 7_565 1_556
Zn4 Pr4 Zn1 85.93(3) 3_546 1_556
Zn1 Pr4 Zn1 180.00(4) 5 1_556
Zn4 Pr4 Ge1 85.93(3) 7_565 5
Zn4 Pr4 Ge1 94.07(3) 3_546 5
Zn1 Pr4 Ge1 0.00(2) 5 5
Zn1 Pr4 Ge1 180.0 1_556 5
Zn4 Pr4 Ge1 94.07(3) 7_565 1_556
Zn4 Pr4 Ge1 85.93(3) 3_546 1_556
Zn1 Pr4 Ge1 180.00(4) 5 1_556
Zn1 Pr4 Ge1 0.0 1_556 1_556
Ge1 Pr4 Ge1 180.00(4) 5 1_556
Zn4 Pr4 Zn1 85.93(3) 7_565 5_556
Zn4 Pr4 Zn1 94.07(3) 3_546 5_556
Zn1 Pr4 Zn1 84.88(3) 5 5_556
Zn1 Pr4 Zn1 95.12(3) 1_556 5_556
Ge1 Pr4 Zn1 84.88(3) 5 5_556
Ge1 Pr4 Zn1 95.12(3) 1_556 5_556
Zn4 Pr4 Ge1 85.93(3) 7_565 5_556
Zn4 Pr4 Ge1 94.07(3) 3_546 5_556
Zn1 Pr4 Ge1 84.88(3) 5 5_556
Zn1 Pr4 Ge1 95.12(3) 1_556 5_556
Ge1 Pr4 Ge1 84.88(3) 5 5_556
Ge1 Pr4 Ge1 95.12(3) 1_556 5_556
Zn1 Pr4 Ge1 0.00(4) 5_556 5_556
Zn4 Pr4 Ge1 94.07(3) 7_565 .
Zn4 Pr4 Ge1 85.93(3) 3_546 .
Zn1 Pr4 Ge1 95.12(3) 5 .
Zn1 Pr4 Ge1 84.88(3) 1_556 .
Ge1 Pr4 Ge1 95.12(3) 5 .
Ge1 Pr4 Ge1 84.88(3) 1_556 .
Zn1 Pr4 Ge1 180.0 5_556 .
Ge1 Pr4 Ge1 180.0 5_556 .
Zn4 Pr4 Zn7 46.380(18) 7_565 5
Zn4 Pr4 Zn7 133.620(18) 3_546 5
Zn1 Pr4 Zn7 44.93(3) 5 5
Zn1 Pr4 Zn7 135.07(3) 1_556 5
Ge1 Pr4 Zn7 44.93(3) 5 5
Ge1 Pr4 Zn7 135.07(3) 1_556 5
Zn1 Pr4 Zn7 100.92(2) 5_556 5
Ge1 Pr4 Zn7 100.92(2) 5_556 5
Ge1 Pr4 Zn7 79.08(2) . 5
Zn4 Pr4 Zn7 133.620(18) 7_565 1_556
Zn4 Pr4 Zn7 46.380(18) 3_546 1_556
Zn1 Pr4 Zn7 135.07(3) 5 1_556
Zn1 Pr4 Zn7 44.93(3) 1_556 1_556
Ge1 Pr4 Zn7 135.07(3) 5 1_556
Ge1 Pr4 Zn7 44.93(3) 1_556 1_556
Zn1 Pr4 Zn7 79.08(2) 5_556 1_556
Ge1 Pr4 Zn7 79.08(2) 5_556 1_556
Ge1 Pr4 Zn7 100.92(2) . 1_556
Zn7 Pr4 Zn7 180.0 5 1_556
Zn10 Ge1 Zn7 126.39(6) 7_565 .
Zn10 Ge1 Zn6 125.89(5) 7_565 .
Zn7 Ge1 Zn6 107.72(5) . .
Zn10 Ge1 Pr2 71.34(3) 7_565 7_565
Zn7 Ge1 Pr2 135.149(18) . 7_565
Zn6 Ge1 Pr2 70.44(3) . 7_565
Zn10 Ge1 Pr2 71.34(3) 7_565 7_564
Zn7 Ge1 Pr2 135.149(18) . 7_564
Zn6 Ge1 Pr2 70.44(3) . 7_564
Pr2 Ge1 Pr2 87.91(3) 7_565 7_564
Zn10 Ge1 Pr1 136.505(16) 7_565 .
Zn7 Ge1 Pr1 64.48(3) . .
Zn6 Ge1 Pr1 64.86(3) . .
Pr2 Ge1 Pr1 75.800(19) 7_565 .
Pr2 Ge1 Pr1 135.25(4) 7_564 .
Zn10 Ge1 Pr1 136.506(16) 7_565 1_554
Zn7 Ge1 Pr1 64.48(3) . 1_554
Zn6 Ge1 Pr1 64.86(3) . 1_554
Pr2 Ge1 Pr1 135.25(4) 7_565 1_554
Pr2 Ge1 Pr1 75.800(19) 7_564 1_554
Pr1 Ge1 Pr1 86.99(3) . 1_554
Zn10 Ge1 Pr4 72.60(3) 7_565 1_554
Zn7 Ge1 Pr4 68.55(3) . 1_554
Zn6 Ge1 Pr4 136.214(17) . 1_554
Pr2 Ge1 Pr4 143.88(4) 7_565 1_554
Pr2 Ge1 Pr4 82.589(17) 7_564 1_554
Pr1 Ge1 Pr4 132.93(4) . 1_554
Pr1 Ge1 Pr4 75.652(16) 1_554 1_554
Zn10 Ge1 Pr4 72.60(3) 7_565 .
Zn7 Ge1 Pr4 68.55(3) . .
Zn6 Ge1 Pr4 136.214(17) . .
Pr2 Ge1 Pr4 82.589(17) 7_565 .
Pr2 Ge1 Pr4 143.88(4) 7_564 .
Pr1 Ge1 Pr4 75.651(16) . .
Pr1 Ge1 Pr4 132.93(4) 1_554 .
Pr4 Ge1 Pr4 84.88(3) 1_554 .
Zn6 Zn2 Zn6 119.86(6) 1_556 .
Zn6 Zn2 Zn12 117.31(3) 1_556 .
Zn6 Zn2 Zn12 117.31(3) . .
Zn6 Zn2 Zn3 88.28(4) 1_556 .
Zn6 Zn2 Zn3 88.28(4) . .
Zn12 Zn2 Zn3 117.15(5) . .
Zn6 Zn2 Zn11 143.65(6) 1_556 7_565
Zn6 Zn2 Zn11 57.41(3) . 7_565
Zn12 Zn2 Zn11 61.75(3) . 7_565
Zn3 Zn2 Zn11 125.87(3) . 7_565
Zn6 Zn2 Zn11 57.41(3) 1_556 7_566
Zn6 Zn2 Zn11 143.65(6) . 7_566
Zn12 Zn2 Zn11 61.74(3) . 7_566
Zn3 Zn2 Zn11 125.87(3) . 7_566
Zn11 Zn2 Zn11 101.89(5) 7_565 7_566
Zn6 Zn2 Pr3 151.57(6) 1_556 .
Zn6 Zn2 Pr3 68.69(3) . .
Zn12 Zn2 Pr3 73.56(3) . .
Zn3 Zn2 Pr3 64.11(3) . .
Zn11 Zn2 Pr3 64.71(3) 7_565 .
Zn11 Zn2 Pr3 133.47(5) 7_566 .
Zn6 Zn2 Pr3 68.69(3) 1_556 1_556
Zn6 Zn2 Pr3 151.57(6) . 1_556
Zn12 Zn2 Pr3 73.56(3) . 1_556
Zn3 Zn2 Pr3 64.11(3) . 1_556
Zn11 Zn2 Pr3 133.47(5) 7_565 1_556
Zn11 Zn2 Pr3 64.71(3) 7_566 1_556
Pr3 Zn2 Pr3 91.79(4) . 1_556
Zn6 Zn2 Pr2 71.65(4) 1_556 7_565
Zn6 Zn2 Pr2 71.65(4) . 7_565
Zn12 Zn2 Pr2 105.22(4) . 7_565
Zn3 Zn2 Pr2 137.63(5) . 7_565
Zn11 Zn2 Pr2 73.92(4) 7_565 7_565
Zn11 Zn2 Pr2 73.92(4) 7_566 7_565
Pr3 Zn2 Pr2 133.46(2) . 7_565
Pr3 Zn2 Pr2 133.46(2) 1_556 7_565
Zn6 Zn2 Pr1 62.72(3) 1_556 .
Zn6 Zn2 Pr1 62.71(3) . .
Zn12 Zn2 Pr1 179.90(5) . .
Zn3 Zn2 Pr1 62.75(4) . .
Zn11 Zn2 Pr1 118.30(3) 7_565 .
Zn11 Zn2 Pr1 118.30(3) 7_566 .
Pr3 Zn2 Pr1 106.37(3) . .
Pr3 Zn2 Pr1 106.37(3) 1_556 .
Pr2 Zn2 Pr1 74.88(3) 7_565 .
Zn4 Zn3 Zn8 116.34(4) . 1_556
Zn4 Zn3 Zn8 116.34(4) . .
Zn8 Zn3 Zn8 121.92(6) 1_556 .
Zn4 Zn3 Zn2 106.01(5) . .
Zn8 Zn3 Zn2 93.83(4) 1_556 .
Zn8 Zn3 Zn2 93.83(4) . .
Zn4 Zn3 Zn10 63.50(3) . .
Zn8 Zn3 Zn10 139.59(6) 1_556 .
Zn8 Zn3 Zn10 56.25(3) . .
Zn2 Zn3 Zn10 125.99(3) . .
Zn4 Zn3 Zn10 63.50(3) . 1_556
Zn8 Zn3 Zn10 56.24(3) 1_556 1_556
Zn8 Zn3 Zn10 139.59(6) . 1_556
Zn2 Zn3 Zn10 125.99(3) . 1_556
Zn10 Zn3 Zn10 97.73(5) . 1_556
Zn4 Zn3 Pr2 103.42(5) . .
Zn8 Zn3 Pr2 72.88(4) 1_556 .
Zn8 Zn3 Pr2 72.88(4) . .
Zn2 Zn3 Pr2 150.57(5) . .
Zn10 Zn3 Pr2 68.50(3) . .
Zn10 Zn3 Pr2 68.50(3) 1_556 .
Zn4 Zn3 Pr3 66.45(3) . .
Zn8 Zn3 Pr3 156.47(6) 1_556 .
Zn8 Zn3 Pr3 70.27(3) . .
Zn2 Zn3 Pr3 64.00(3) . .
Zn10 Zn3 Pr3 63.71(3) . .
Zn10 Zn3 Pr3 129.63(5) 1_556 .
Pr2 Zn3 Pr3 130.38(3) . .
Zn4 Zn3 Pr3 66.45(3) . 1_556
Zn8 Zn3 Pr3 70.27(3) 1_556 1_556
Zn8 Zn3 Pr3 156.47(6) . 1_556
Zn2 Zn3 Pr3 64.00(3) . 1_556
Zn10 Zn3 Pr3 129.63(5) . 1_556
Zn10 Zn3 Pr3 63.71(3) 1_556 1_556
Pr2 Zn3 Pr3 130.38(3) . 1_556
Pr3 Zn3 Pr3 91.68(4) . 1_556
Zn4 Zn3 Pr1 174.60(6) . .
Zn8 Zn3 Pr1 64.96(3) 1_556 .
Zn8 Zn3 Pr1 64.96(3) . .
Zn2 Zn3 Pr1 68.59(4) . .
Zn10 Zn3 Pr1 119.32(3) . .
Zn10 Zn3 Pr1 119.32(3) 1_556 .
Pr2 Zn3 Pr1 81.97(3) . .
Pr3 Zn3 Pr1 110.13(3) . .
Pr3 Zn3 Pr1 110.13(3) 1_556 .
Zn3 Zn4 Zn7 117.28(3) . 3_556
Zn3 Zn4 Zn7 117.28(3) . 3
Zn7 Zn4 Zn7 121.80(6) 3_556 3
Zn3 Zn4 Zn5 104.08(6) . 3_556
Zn7 Zn4 Zn5 92.65(4) 3_556 3_556
Zn7 Zn4 Zn5 92.65(4) 3 3_556
Zn3 Zn4 Zn10 65.35(4) . .
Zn7 Zn4 Zn10 141.24(6) 3_556 .
Zn7 Zn4 Zn10 56.15(3) 3 .
Zn5 Zn4 Zn10 125.28(3) 3_556 .
Zn3 Zn4 Zn10 65.35(4) . 1_556
Zn7 Zn4 Zn10 56.15(3) 3_556 1_556
Zn7 Zn4 Zn10 141.24(6) 3 1_556
Zn5 Zn4 Zn10 125.28(3) 3_556 1_556
Zn10 Zn4 Zn10 99.80(5) . 1_556
Zn3 Zn4 Pr4 109.82(5) . 3_556
Zn7 Zn4 Pr4 72.04(4) 3_556 3_556
Zn7 Zn4 Pr4 72.04(4) 3 3_556
Zn5 Zn4 Pr4 146.10(5) 3_556 3_556
Zn10 Zn4 Pr4 71.32(3) . 3_556
Zn10 Zn4 Pr4 71.32(3) 1_556 3_556
Zn3 Zn4 Pr3 65.56(3) . 1_556
Zn7 Zn4 Pr3 70.08(3) 3_556 1_556
Zn7 Zn4 Pr3 154.73(5) 3 1_556
Zn5 Zn4 Pr3 63.32(3) 3_556 1_556
Zn10 Zn4 Pr3 130.58(5) . 1_556
Zn10 Zn4 Pr3 63.93(3) 1_556 1_556
Pr4 Zn4 Pr3 132.33(2) 3_556 1_556
Zn3 Zn4 Pr3 65.56(3) . .
Zn7 Zn4 Pr3 154.73(5) 3_556 .
Zn7 Zn4 Pr3 70.08(3) 3 .
Zn5 Zn4 Pr3 63.32(3) 3_556 .
Zn10 Zn4 Pr3 63.93(3) . .
Zn10 Zn4 Pr3 130.58(5) 1_556 .
Pr4 Zn4 Pr3 132.33(2) 3_556 .
Pr3 Zn4 Pr3 90.87(4) 1_556 .
Zn3 Zn4 Pr1 171.51(6) . 3_556
Zn7 Zn4 Pr1 64.57(3) 3_556 3_556
Zn7 Zn4 Pr1 64.57(3) 3 3_556
Zn5 Zn4 Pr1 67.43(4) 3_556 3_556
Zn10 Zn4 Pr1 119.01(3) . 3_556
Zn10 Zn4 Pr1 119.01(3) 1_556 3_556
Pr4 Zn4 Pr1 78.66(3) 3_556 3_556
Pr3 Zn4 Pr1 109.00(3) 1_556 3_556
Pr3 Zn4 Pr1 109.00(3) . 3_556
Zn9 Zn5 Zn9 120.15(6) 1_556 .
Zn9 Zn5 Zn12 117.39(3) 1_556 3_546
Zn9 Zn5 Zn12 117.39(3) . 3_546
Zn9 Zn5 Zn4 88.07(4) 1_556 3_546
Zn9 Zn5 Zn4 88.07(4) . 3_546
Zn12 Zn5 Zn4 116.61(5) 3_546 3_546
Zn9 Zn5 Zn11 57.30(3) 1_556 1_556
Zn9 Zn5 Zn11 144.67(6) . 1_556
Zn12 Zn5 Zn11 61.93(3) 3_546 1_556
Zn4 Zn5 Zn11 125.14(3) 3_546 1_556
Zn9 Zn5 Zn11 144.67(6) 1_556 .
Zn9 Zn5 Zn11 57.30(3) . .
Zn12 Zn5 Zn11 61.93(3) 3_546 .
Zn4 Zn5 Zn11 125.14(3) 3_546 .
Zn11 Zn5 Zn11 102.95(5) 1_556 .
Zn9 Zn5 Pr3 151.11(5) 1_556 3_545
Zn9 Zn5 Pr3 68.55(3) . 3_545
Zn12 Zn5 Pr3 73.29(3) 3_546 3_545
Zn4 Zn5 Pr3 63.91(3) 3_546 3_545
Zn11 Zn5 Pr3 133.19(5) 1_556 3_545
Zn11 Zn5 Pr3 64.15(3) . 3_545
Zn9 Zn5 Pr3 68.55(3) 1_556 3_546
Zn9 Zn5 Pr3 151.11(5) . 3_546
Zn12 Zn5 Pr3 73.29(3) 3_546 3_546
Zn4 Zn5 Pr3 63.91(3) 3_546 3_546
Zn11 Zn5 Pr3 64.15(3) 1_556 3_546
Zn11 Zn5 Pr3 133.19(5) . 3_546
Pr3 Zn5 Pr3 91.47(4) 3_545 3_546
Zn9 Zn5 Pr2 73.09(4) 1_556 .
Zn9 Zn5 Pr2 73.09(4) . .
Zn12 Zn5 Pr2 102.92(4) 3_546 .
Zn4 Zn5 Pr2 140.47(5) 3_546 .
Zn11 Zn5 Pr2 72.99(3) 1_556 .
Zn11 Zn5 Pr2 72.99(3) . .
Pr3 Zn5 Pr2 133.17(2) 3_545 .
Pr3 Zn5 Pr2 133.17(2) 3_546 .
Zn9 Zn5 Pr1 62.74(3) 1_556 .
Zn9 Zn5 Pr1 62.74(3) . .
Zn12 Zn5 Pr1 179.38(5) 3_546 .
Zn4 Zn5 Pr1 62.77(4) 3_546 .
Zn11 Zn5 Pr1 118.36(3) 1_556 .
Zn11 Zn5 Pr1 118.36(3) . .
Pr3 Zn5 Pr1 106.30(3) 3_545 .
Pr3 Zn5 Pr1 106.30(3) 3_546 .
Pr2 Zn5 Pr1 77.70(3) . .
Ge1 Zn6 Zn2 117.97(3) . 1_554
Ge1 Zn6 Zn2 117.97(3) . .
Zn2 Zn6 Zn2 119.86(6) 1_554 .
Ge1 Zn6 Zn11 120.81(6) . 7_565
Zn2 Zn6 Zn11 66.94(4) 1_554 7_565
Zn2 Zn6 Zn11 66.94(4) . 7_565
Ge1 Zn6 Zn8 108.44(5) . .
Zn2 Zn6 Zn8 91.08(4) 1_554 .
Zn2 Zn6 Zn8 91.08(4) . .
Zn11 Zn6 Zn8 130.74(6) 7_565 .
Ge1 Zn6 Pr1 67.76(3) . 1_554
Zn2 Zn6 Pr1 71.00(3) 1_554 1_554
Zn2 Zn6 Pr1 153.20(5) . 1_554
Zn11 Zn6 Pr1 135.253(17) 7_565 1_554
Zn8 Zn6 Pr1 63.22(3) . 1_554
Ge1 Zn6 Pr1 67.76(3) . .
Zn2 Zn6 Pr1 153.20(5) 1_554 .
Zn2 Zn6 Pr1 71.00(3) . .
Zn11 Zn6 Pr1 135.253(17) 7_565 .
Zn8 Zn6 Pr1 63.22(3) . .
Pr1 Zn6 Pr1 89.46(3) 1_554 .
Ge1 Zn6 Pr3 173.89(5) . .
Zn2 Zn6 Pr3 63.41(3) 1_554 .
Zn2 Zn6 Pr3 63.41(3) . .
Zn11 Zn6 Pr3 65.30(4) 7_565 .
Zn8 Zn6 Pr3 65.45(4) . .
Pr1 Zn6 Pr3 108.20(3) 1_554 .
Pr1 Zn6 Pr3 108.20(3) . .
Ge1 Zn6 Pr2 63.64(3) . 7_564
Zn2 Zn6 Pr2 61.98(3) 1_554 7_564
Zn2 Zn6 Pr2 132.27(5) . 7_564
Zn11 Zn6 Pr2 72.96(3) 7_565 7_564
Zn8 Zn6 Pr2 135.67(2) . 7_564
Pr1 Zn6 Pr2 74.44(2) 1_554 7_564
Pr1 Zn6 Pr2 131.36(4) . 7_564
Pr3 Zn6 Pr2 120.39(3) . 7_564
Ge1 Zn6 Pr2 63.64(3) . 7_565
Zn2 Zn6 Pr2 132.27(5) 1_554 7_565
Zn2 Zn6 Pr2 61.98(3) . 7_565
Zn11 Zn6 Pr2 72.96(3) 7_565 7_565
Zn8 Zn6 Pr2 135.67(2) . 7_565
Pr1 Zn6 Pr2 131.36(4) 1_554 7_565
Pr1 Zn6 Pr2 74.44(2) . 7_565
Pr3 Zn6 Pr2 120.39(3) . 7_565
Pr2 Zn6 Pr2 82.61(3) 7_564 7_565
Ge1 Zn7 Zn4 117.96(3) . 3_545
Ge1 Zn7 Zn4 117.96(3) . 3_546
Zn4 Zn7 Zn4 121.80(6) 3_545 3_546
Ge1 Zn7 Zn10 121.98(6) . 3_545
Zn4 Zn7 Zn10 69.02(4) 3_545 3_545
Zn4 Zn7 Zn10 69.02(4) 3_546 3_545
Ge1 Zn7 Zn9 109.95(5) . .
Zn4 Zn7 Zn9 87.80(4) 3_545 .
Zn4 Zn7 Zn9 87.80(4) 3_546 .
Zn10 Zn7 Zn9 128.07(6) 3_545 .
Ge1 Zn7 Pr1 68.54(3) . .
Zn4 Zn7 Pr1 150.41(5) 3_545 .
Zn4 Zn7 Pr1 68.23(3) 3_546 .
Zn10 Zn7 Pr1 134.776(17) 3_545 .
Zn9 Zn7 Pr1 63.83(3) . .
Ge1 Zn7 Pr1 68.54(3) . 1_554
Zn4 Zn7 Pr1 68.23(3) 3_545 1_554
Zn4 Zn7 Pr1 150.41(5) 3_546 1_554
Zn10 Zn7 Pr1 134.777(16) 3_545 1_554
Zn9 Zn7 Pr1 63.83(3) . 1_554
Pr1 Zn7 Pr1 90.44(3) . 1_554
Ge1 Zn7 Pr3 173.35(5) . 3_545
Zn4 Zn7 Pr3 63.21(3) 3_545 3_545
Zn4 Zn7 Pr3 63.21(3) 3_546 3_545
Zn10 Zn7 Pr3 64.67(4) 3_545 3_545
Zn9 Zn7 Pr3 63.40(4) . 3_545
Pr1 Zn7 Pr3 107.08(3) . 3_545
Pr1 Zn7 Pr3 107.08(3) 1_554 3_545
Ge1 Zn7 Pr4 66.52(3) . 1_554
Zn4 Zn7 Pr4 61.58(3) 3_545 1_554
Zn4 Zn7 Pr4 133.32(5) 3_546 1_554
Zn10 Zn7 Pr4 71.05(3) 3_545 1_554
Zn9 Zn7 Pr4 136.866(17) . 1_554
Pr1 Zn7 Pr4 134.95(4) . 1_554
Pr1 Zn7 Pr4 76.260(17) 1_554 1_554
Pr3 Zn7 Pr4 117.97(3) 3_545 1_554
Ge1 Zn7 Pr4 66.52(3) . .
Zn4 Zn7 Pr4 133.32(5) 3_545 .
Zn4 Zn7 Pr4 61.58(3) 3_546 .
Zn10 Zn7 Pr4 71.05(3) 3_545 .
Zn9 Zn7 Pr4 136.866(17) . .
Pr1 Zn7 Pr4 76.259(17) . .
Pr1 Zn7 Pr4 134.95(4) 1_554 .
Pr3 Zn7 Pr4 117.97(3) 3_545 .
Pr4 Zn7 Pr4 83.36(3) 1_554 .
Zn9 Zn8 Zn3 118.45(3) . 1_554
Zn9 Zn8 Zn3 118.45(3) . .
Zn3 Zn8 Zn3 121.92(6) 1_554 .
Zn9 Zn8 Zn10 124.32(6) . .
Zn3 Zn8 Zn10 69.80(4) 1_554 .
Zn3 Zn8 Zn10 69.80(4) . .
Zn9 Zn8 Zn6 107.65(5) . .
Zn3 Zn8 Zn6 86.79(4) 1_554 .
Zn3 Zn8 Zn6 86.78(4) . .
Zn10 Zn8 Zn6 128.03(6) . .
Zn9 Zn8 Pr1 66.84(3) . 1_554
Zn3 Zn8 Pr1 67.83(3) 1_554 1_554
Zn3 Zn8 Pr1 149.41(5) . 1_554
Zn10 Zn8 Pr1 134.917(17) . 1_554
Zn6 Zn8 Pr1 63.92(3) . 1_554
Zn9 Zn8 Pr1 66.84(3) . .
Zn3 Zn8 Pr1 149.41(5) 1_554 .
Zn3 Zn8 Pr1 67.83(3) . .
Zn10 Zn8 Pr1 134.918(17) . .
Zn6 Zn8 Pr1 63.92(3) . .
Pr1 Zn8 Pr1 90.16(3) 1_554 .
Zn9 Zn8 Pr3 171.14(5) . .
Zn3 Zn8 Pr3 62.84(3) 1_554 .
Zn3 Zn8 Pr3 62.84(3) . .
Zn10 Zn8 Pr3 64.53(4) . .
Zn6 Zn8 Pr3 63.49(4) . .
Pr1 Zn8 Pr3 107.36(3) 1_554 .
Pr1 Zn8 Pr3 107.36(3) . .
Zn9 Zn8 Pr2 71.31(3) . 1_554
Zn3 Zn8 Pr2 60.68(3) 1_554 1_554
Zn3 Zn8 Pr2 132.04(5) . 1_554
Zn10 Zn8 Pr2 67.79(3) . 1_554
Zn6 Zn8 Pr2 137.893(17) . 1_554
Pr1 Zn8 Pr2 78.54(2) 1_554 1_554
Pr1 Zn8 Pr2 137.74(4) . 1_554
Pr3 Zn8 Pr2 114.89(3) . 1_554
Zn9 Zn8 Pr2 71.31(3) . .
Zn3 Zn8 Pr2 132.04(5) 1_554 .
Zn3 Zn8 Pr2 60.68(3) . .
Zn10 Zn8 Pr2 67.79(3) . .
Zn6 Zn8 Pr2 137.893(17) . .
Pr1 Zn8 Pr2 137.74(4) 1_554 .
Pr1 Zn8 Pr2 78.536(19) . .
Pr3 Zn8 Pr2 114.89(3) . .
Pr2 Zn8 Pr2 83.05(3) 1_554 .
Zn8 Zn9 Zn5 118.11(3) . .
Zn8 Zn9 Zn5 118.11(3) . 1_554
Zn5 Zn9 Zn5 120.15(6) . 1_554
Zn8 Zn9 Zn11 123.28(6) . .
Zn5 Zn9 Zn11 66.70(4) . .
Zn5 Zn9 Zn11 66.70(4) 1_554 .
Zn8 Zn9 Zn7 106.23(5) . .
Zn5 Zn9 Zn7 91.47(4) . .
Zn5 Zn9 Zn7 91.47(4) 1_554 .
Zn11 Zn9 Zn7 130.49(6) . .
Zn8 Zn9 Pr1 66.49(3) . 1_554
Zn5 Zn9 Pr1 153.63(5) . 1_554
Zn5 Zn9 Pr1 70.84(3) 1_554 1_554
Zn11 Zn9 Pr1 135.061(18) . 1_554
Zn7 Zn9 Pr1 63.25(3) . 1_554
Zn8 Zn9 Pr1 66.49(3) . .
Zn5 Zn9 Pr1 70.84(3) . .
Zn5 Zn9 Pr1 153.63(5) 1_554 .
Zn11 Zn9 Pr1 135.061(18) . .
Zn7 Zn9 Pr1 63.25(3) . .
Pr1 Zn9 Pr1 89.86(4) 1_554 .
Zn8 Zn9 Pr3 171.94(6) . 3_545
Zn5 Zn9 Pr3 63.67(3) . 3_545
Zn5 Zn9 Pr3 63.67(3) 1_554 3_545
Zn11 Zn9 Pr3 64.78(4) . 3_545
Zn7 Zn9 Pr3 65.70(4) . 3_545
Pr1 Zn9 Pr3 108.24(3) 1_554 3_545
Pr1 Zn9 Pr3 108.24(3) . 3_545
Zn8 Zn9 Pr2 65.98(3) . 1_554
Zn5 Zn9 Pr2 129.71(5) . 1_554
Zn5 Zn9 Pr2 62.02(3) 1_554 1_554
Zn11 Zn9 Pr2 71.22(3) . 1_554
Zn7 Zn9 Pr2 137.75(2) . 1_554
Pr1 Zn9 Pr2 76.57(2) 1_554 1_554
Pr1 Zn9 Pr2 132.12(4) . 1_554
Pr3 Zn9 Pr2 119.64(3) 3_545 1_554
Zn8 Zn9 Pr2 65.98(3) . .
Zn5 Zn9 Pr2 62.02(3) . .
Zn5 Zn9 Pr2 129.71(5) 1_554 .
Zn11 Zn9 Pr2 71.22(3) . .
Zn7 Zn9 Pr2 137.75(2) . .
Pr1 Zn9 Pr2 132.11(4) 1_554 .
Pr1 Zn9 Pr2 76.57(2) . .
Pr3 Zn9 Pr2 119.64(3) 3_545 .
Pr2 Zn9 Pr2 79.47(3) 1_554 .
Zn1 Zn10 Ge1 0.00(4) 7_665 7_665
Zn1 Zn10 Zn7 111.63(6) 7_665 3
Ge1 Zn10 Zn7 111.63(6) 7_665 3
Zn1 Zn10 Zn8 112.18(6) 7_665 .
Ge1 Zn10 Zn8 112.18(6) 7_665 .
Zn7 Zn10 Zn8 136.19(6) 3 .
Zn1 Zn10 Zn4 118.70(4) 7_665 1_554
Ge1 Zn10 Zn4 118.70(4) 7_665 1_554
Zn7 Zn10 Zn4 54.82(3) 3 1_554
Zn8 Zn10 Zn4 102.49(4) . 1_554
Zn1 Zn10 Zn4 118.70(4) 7_665 .
Ge1 Zn10 Zn4 118.70(4) 7_665 .
Zn7 Zn10 Zn4 54.82(3) 3 .
Zn8 Zn10 Zn4 102.49(4) . .
Zn4 Zn10 Zn4 99.80(5) 1_554 .
Zn1 Zn10 Zn3 119.62(4) 7_665 1_554
Ge1 Zn10 Zn3 119.62(4) 7_665 1_554
Zn7 Zn10 Zn3 102.78(4) 3 1_554
Zn8 Zn10 Zn3 53.95(3) . 1_554
Zn4 Zn10 Zn3 51.16(3) 1_554 1_554
Zn4 Zn10 Zn3 121.67(5) . 1_554
Zn1 Zn10 Zn3 119.63(4) 7_665 .
Ge1 Zn10 Zn3 119.63(4) 7_665 .
Zn7 Zn10 Zn3 102.78(4) 3 .
Zn8 Zn10 Zn3 53.95(3) . .
Zn4 Zn10 Zn3 121.67(5) 1_554 .
Zn4 Zn10 Zn3 51.16(3) . .
Zn3 Zn10 Zn3 97.74(5) 1_554 .
Zn1 Zn10 Pr3 179.98(5) 7_665 .
Ge1 Zn10 Pr3 179.98(5) 7_665 .
Zn7 Zn10 Pr3 68.35(4) 3 .
Zn8 Zn10 Pr3 67.84(4) . .
Zn4 Zn10 Pr3 61.29(3) 1_554 .
Zn4 Zn10 Pr3 61.29(3) . .
Zn3 Zn10 Pr3 60.39(3) 1_554 .
Zn3 Zn10 Pr3 60.39(3) . .
Zn1 Zn10 Pr2 63.73(3) 7_665 .
Ge1 Zn10 Pr2 63.73(3) 7_665 .
Zn7 Zn10 Pr2 136.93(2) 3 .
Zn8 Zn10 Pr2 66.54(3) . .
Zn4 Zn10 Pr2 167.71(4) 1_554 .
Zn4 Zn10 Pr2 88.40(2) . .
Zn3 Zn10 Pr2 116.66(4) 1_554 .
Zn3 Zn10 Pr2 57.26(3) . .
Pr3 Zn10 Pr2 116.29(3) . .
Zn1 Zn10 Pr2 63.73(3) 7_665 1_554
Ge1 Zn10 Pr2 63.73(3) 7_665 1_554
Zn7 Zn10 Pr2 136.93(2) 3 1_554
Zn8 Zn10 Pr2 66.54(3) . 1_554
Zn4 Zn10 Pr2 88.40(2) 1_554 1_554
Zn4 Zn10 Pr2 167.71(4) . 1_554
Zn3 Zn10 Pr2 57.26(3) 1_554 1_554
Zn3 Zn10 Pr2 116.66(4) . 1_554
Pr3 Zn10 Pr2 116.29(3) . 1_554
Pr2 Zn10 Pr2 82.13(3) . 1_554
Zn1 Zn10 Pr4 63.94(3) 7_665 3_556
Ge1 Zn10 Pr4 63.94(3) 7_665 3_556
Zn7 Zn10 Pr4 64.63(3) 3 3_556
Zn8 Zn10 Pr4 138.939(18) . 3_556
Zn4 Zn10 Pr4 115.10(4) 1_554 3_556
Zn4 Zn10 Pr4 56.80(3) . 3_556
Zn3 Zn10 Pr4 166.24(4) 1_554 3_556
Zn3 Zn10 Pr4 90.82(2) . 3_556
Pr3 Zn10 Pr4 116.05(3) . 3_556
Pr2 Zn10 Pr4 77.048(18) . 3_556
Pr2 Zn10 Pr4 127.63(4) 1_554 3_556
Zn9 Zn11 Zn6 113.51(6) . 7_665
Zn9 Zn11 Zn12 110.28(3) . 3_545
Zn6 Zn11 Zn12 109.49(3) 7_665 3_545
Zn9 Zn11 Zn12 110.28(3) . 3_546
Zn6 Zn11 Zn12 109.49(3) 7_665 3_546
Zn12 Zn11 Zn12 103.30(4) 3_545 3_546
Zn9 Zn11 Zn5 56.00(3) . 1_554
Zn6 Zn11 Zn5 118.34(4) 7_665 1_554
Zn12 Zn11 Zn5 55.88(3) 3_545 1_554
Zn12 Zn11 Zn5 131.77(5) 3_546 1_554
Zn9 Zn11 Zn5 56.00(3) . .
Zn6 Zn11 Zn5 118.34(4) 7_665 .
Zn12 Zn11 Zn5 131.77(5) 3_545 .
Zn12 Zn11 Zn5 55.88(3) 3_546 .
Zn5 Zn11 Zn5 102.95(5) 1_554 .
Zn9 Zn11 Zn2 118.83(4) . 7_665
Zn6 Zn11 Zn2 55.65(3) 7_665 7_665
Zn12 Zn11 Zn2 130.59(5) 3_545 7_665
Zn12 Zn11 Zn2 55.43(3) 3_546 7_665
Zn5 Zn11 Zn2 171.27(6) 1_554 7_665
Zn5 Zn11 Zn2 76.90(3) . 7_665
Zn9 Zn11 Zn2 118.83(4) . 7_664
Zn6 Zn11 Zn2 55.65(3) 7_665 7_664
Zn12 Zn11 Zn2 55.43(3) 3_545 7_664
Zn12 Zn11 Zn2 130.59(5) 3_546 7_664
Zn5 Zn11 Zn2 76.90(3) 1_554 7_664
Zn5 Zn11 Zn2 171.27(6) . 7_664
Zn2 Zn11 Zn2 101.89(5) 7_665 7_664
Zn9 Zn11 Pr3 67.13(4) . 3_545
Zn6 Zn11 Pr3 179.36(6) 7_665 3_545
Zn12 Zn11 Pr3 70.15(2) 3_545 3_545
Zn12 Zn11 Pr3 70.15(2) 3_546 3_545
Zn5 Zn11 Pr3 61.96(3) 1_554 3_545
Zn5 Zn11 Pr3 61.96(3) . 3_545
Zn2 Zn11 Pr3 124.13(3) 7_665 3_545
Zn2 Zn11 Pr3 124.13(3) 7_664 3_545
Zn9 Zn11 Pr3 179.98(5) . 7_665
Zn6 Zn11 Pr3 66.51(4) 7_665 7_665
Zn12 Zn11 Pr3 69.71(2) 3_545 7_665
Zn12 Zn11 Pr3 69.71(2) 3_546 7_665
Zn5 Zn11 Pr3 123.99(3) 1_554 7_665
Zn5 Zn11 Pr3 123.99(3) . 7_665
Zn2 Zn11 Pr3 61.18(3) 7_665 7_665
Zn2 Zn11 Pr3 61.18(3) 7_664 7_665
Pr3 Zn11 Pr3 112.85(4) 3_545 7_665
Zn9 Zn11 Pr2 65.73(3) . 1_554
Zn6 Zn11 Pr2 63.09(3) 7_665 1_554
Zn12 Zn11 Pr2 90.328(15) 3_545 1_554
Zn12 Zn11 Pr2 166.23(3) 3_546 1_554
Zn5 Zn11 Pr2 58.20(3) 1_554 1_554
Zn5 Zn11 Pr2 115.86(4) . 1_554
Zn2 Zn11 Pr2 113.79(4) 7_665 1_554
Zn2 Zn11 Pr2 56.46(3) 7_664 1_554
Pr3 Zn11 Pr2 117.38(3) 3_545 1_554
Pr3 Zn11 Pr2 114.28(3) 7_665 1_554
Zn9 Zn11 Pr2 65.74(3) . .
Zn6 Zn11 Pr2 63.09(3) 7_665 .
Zn12 Zn11 Pr2 166.23(3) 3_545 .
Zn12 Zn11 Pr2 90.328(14) 3_546 .
Zn5 Zn11 Pr2 115.86(4) 1_554 .
Zn5 Zn11 Pr2 58.20(3) . .
Zn2 Zn11 Pr2 56.46(3) 7_665 .
Zn2 Zn11 Pr2 113.79(4) 7_664 .
Pr3 Zn11 Pr2 117.38(3) 3_545 .
Pr3 Zn11 Pr2 114.28(3) 7_665 .
Pr2 Zn11 Pr2 75.99(3) 1_554 .
Zn2 Zn12 Zn2 180.0 . 5_566
Zn2 Zn12 Zn5 83.84(4) . 7_565
Zn2 Zn12 Zn5 96.16(4) 5_566 7_565
Zn2 Zn12 Zn5 96.16(4) . 3_556
Zn2 Zn12 Zn5 83.84(4) 5_566 3_556
Zn5 Zn12 Zn5 180.00(4) 7_565 3_556
Zn2 Zn12 Zn11 62.82(3) . 7_565
Zn2 Zn12 Zn11 117.18(3) 5_566 7_565
Zn5 Zn12 Zn11 62.19(2) 7_565 7_565
Zn5 Zn12 Zn11 117.81(2) 3_556 7_565
Zn2 Zn12 Zn11 117.18(3) . 3_556
Zn2 Zn12 Zn11 62.82(3) 5_566 3_556
Zn5 Zn12 Zn11 117.81(2) 7_565 3_556
Zn5 Zn12 Zn11 62.19(2) 3_556 3_556
Zn11 Zn12 Zn11 180.00(4) 7_565 3_556
Zn2 Zn12 Zn11 62.82(3) . 7_566
Zn2 Zn12 Zn11 117.18(3) 5_566 7_566
Zn5 Zn12 Zn11 62.19(2) 7_565 7_566
Zn5 Zn12 Zn11 117.81(2) 3_556 7_566
Zn11 Zn12 Zn11 103.30(4) 7_565 7_566
Zn11 Zn12 Zn11 76.70(4) 3_556 7_566
Zn2 Zn12 Zn11 117.18(3) . 3
Zn2 Zn12 Zn11 62.82(3) 5_566 3
Zn5 Zn12 Zn11 117.81(2) 7_565 3
Zn5 Zn12 Zn11 62.19(2) 3_556 3
Zn11 Zn12 Zn11 76.70(4) 7_565 3
Zn11 Zn12 Zn11 103.30(4) 3_556 3
Zn11 Zn12 Zn11 180.00(4) 7_566 3
Zn2 Zn12 Pr3 120.850(19) . 5_565
Zn2 Zn12 Pr3 59.150(19) 5_566 5_565
Zn5 Zn12 Pr3 59.28(2) 7_565 5_565
Zn5 Zn12 Pr3 120.72(2) 3_556 5_565
Zn11 Zn12 Pr3 59.41(2) 7_565 5_565
Zn11 Zn12 Pr3 120.59(2) 3_556 5_565
Zn11 Zn12 Pr3 119.95(2) 7_566 5_565
Zn11 Zn12 Pr3 60.05(2) 3 5_565
Zn2 Zn12 Pr3 59.150(19) . 1_556
Zn2 Zn12 Pr3 120.850(19) 5_566 1_556
Zn5 Zn12 Pr3 120.72(2) 7_565 1_556
Zn5 Zn12 Pr3 59.28(2) 3_556 1_556
Zn11 Zn12 Pr3 120.59(2) 7_565 1_556
Zn11 Zn12 Pr3 59.41(2) 3_556 1_556
Zn11 Zn12 Pr3 60.05(2) 7_566 1_556
Zn11 Zn12 Pr3 119.95(2) 3 1_556
Pr3 Zn12 Pr3 180.0 5_565 1_556
Zn2 Zn12 Pr3 120.850(19) . 5_566
Zn2 Zn12 Pr3 59.15(2) 5_566 5_566
Zn5 Zn12 Pr3 59.28(2) 7_565 5_566
Zn5 Zn12 Pr3 120.72(2) 3_556 5_566
Zn11 Zn12 Pr3 119.95(2) 7_565 5_566
Zn11 Zn12 Pr3 60.05(2) 3_556 5_566
Zn11 Zn12 Pr3 59.41(2) 7_566 5_566
Zn11 Zn12 Pr3 120.59(2) 3 5_566
Pr3 Zn12 Pr3 79.995(17) 5_565 5_566
Pr3 Zn12 Pr3 100.005(17) 1_556 5_566
Zn2 Zn12 Pr3 59.149(19) . .
Zn2 Zn12 Pr3 120.851(19) 5_566 .
Zn5 Zn12 Pr3 120.72(2) 7_565 .
Zn5 Zn12 Pr3 59.28(2) 3_556 .
Zn11 Zn12 Pr3 60.05(2) 7_565 .
Zn11 Zn12 Pr3 119.95(2) 3_556 .
Zn11 Zn12 Pr3 120.59(2) 7_566 .
Zn11 Zn12 Pr3 59.41(2) 3 .
Pr3 Zn12 Pr3 100.006(17) 5_565 .
Pr3 Zn12 Pr3 79.994(17) 1_556 .
Pr3 Zn12 Pr3 179.999(1) 5_566 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pr1 Zn7 3.1372(9) .
Pr1 Zn7 3.1373(9) 1_556
Pr1 Zn8 3.1449(9) .
Pr1 Zn8 3.1449(9) 1_556
Pr1 Zn9 3.1531(10) .
Pr1 Zn9 3.1532(10) 1_556
Pr1 Zn6 3.1642(9) .
Pr1 Zn6 3.1642(9) 1_556
Pr1 Zn3 3.2145(14) .
Pr1 Zn4 3.2260(14) 3_546
Pr1 Zn1 3.2353(10) 1_556
Pr1 Ge1 3.2353(10) 1_556
Pr2 Zn3 3.0645(14) .
Pr2 Zn2 3.1379(14) 7_665
Pr2 Zn1 3.2082(9) 7_666
Pr2 Ge1 3.2082(9) 7_666
Pr2 Zn1 3.2082(9) 7_665
Pr2 Ge1 3.2082(9) 7_665
Pr2 Zn5 3.2153(14) .
Pr2 Zn8 3.3588(10) 1_556
Pr2 Zn8 3.3589(10) .
Pr2 Zn6 3.3738(10) 7_666
Pr2 Zn6 3.3738(10) 7_665
Pr2 Zn10 3.3898(10) 1_556
Pr3 Zn2 3.1012(9) .
Pr3 Zn2 3.1012(9) 1_554
Pr3 Zn3 3.1040(10) .
Pr3 Zn3 3.1040(10) 1_554
Pr3 Zn5 3.1097(9) 3_556
Pr3 Zn5 3.1097(9) 3
Pr3 Zn4 3.1255(10) 1_554
Pr3 Zn4 3.1255(10) .
Pr3 Zn11 3.1708(13) 3
Pr3 Zn11 3.2004(14) 7_565
Pr3 Zn10 3.2011(14) .
Pr3 Zn9 3.2292(13) 3
Pr4 Zn4 3.0961(13) 7_565
Pr4 Zn4 3.0961(13) 3_546
Pr4 Zn1 3.3001(8) 5
Pr4 Zn1 3.3001(8) 1_556
Pr4 Ge1 3.3001(8) 5
Pr4 Ge1 3.3001(8) 1_556
Pr4 Zn1 3.3001(8) 5_556
Pr4 Ge1 3.3001(8) 5_556
Pr4 Ge1 3.3001(8) .
Pr4 Zn7 3.3488(9) 5
Pr4 Zn7 3.3488(9) 1_556
Ge1 Zn10 2.5270(16) 7_565
Ge1 Zn7 2.5414(16) .
Ge1 Zn6 2.5721(16) .
Ge1 Pr2 3.2082(9) 7_565
Ge1 Pr2 3.2082(9) 7_564
Ge1 Pr1 3.2354(10) 1_554
Ge1 Pr4 3.3001(8) 1_554
Zn2 Zn6 2.5732(9) 1_556
Zn2 Zn6 2.5732(9) .
Zn2 Zn12 2.6544(12) .
Zn2 Zn3 2.7146(17) .
Zn2 Zn11 2.8677(11) 7_565
Zn2 Zn11 2.8677(11) 7_566
Zn2 Pr3 3.1012(9) 1_556
Zn2 Pr2 3.1379(14) 7_565
Zn3 Zn4 2.5337(17) .
Zn3 Zn8 2.5470(8) 1_556
Zn3 Zn8 2.5470(8) .
Zn3 Zn10 2.9566(12) .
Zn3 Zn10 2.9566(12) 1_556
Zn3 Pr3 3.1040(10) 1_556
Zn4 Zn7 2.5485(9) 3_556
Zn4 Zn7 2.5485(9) 3
Zn4 Zn5 2.7712(18) 3_556
Zn4 Zn10 2.9112(11) .
Zn4 Zn10 2.9113(11) 1_556
Zn4 Pr4 3.0961(13) 3_556
Zn4 Pr3 3.1255(10) 1_556
Zn4 Pr1 3.2260(14) 3_556
Zn5 Zn9 2.5694(8) 1_556
Zn5 Zn9 2.5694(8) .
Zn5 Zn12 2.6641(12) 3_546
Zn5 Zn4 2.7713(18) 3_546
Zn5 Zn11 2.8465(11) 1_556
Zn5 Zn11 2.8465(11) .
Zn5 Pr3 3.1097(9) 3_545
Zn5 Pr3 3.1097(9) 3_546
Zn6 Zn2 2.5732(9) 1_554
Zn6 Zn11 2.6260(17) 7_565
Zn6 Zn8 2.8081(16) .
Zn6 Pr1 3.1641(9) 1_554
Zn6 Pr2 3.3738(10) 7_564
Zn6 Pr2 3.3738(10) 7_565
Zn7 Zn4 2.5485(9) 3_545
Zn7 Zn4 2.5485(8) 3_546
Zn7 Zn10 2.5896(16) 3_545
Zn7 Zn9 2.8026(17) .
Zn7 Pr1 3.1373(9) 1_554
Zn7 Pr3 3.2916(13) 3_545
Zn7 Pr4 3.3489(9) 1_554
Zn8 Zn9 2.4948(16) .
Zn8 Zn3 2.5470(8) 1_554
Zn8 Zn10 2.6192(16) .
Zn8 Pr1 3.1448(9) 1_554
Zn8 Pr2 3.3589(10) 1_554
Zn9 Zn5 2.5694(8) 1_554
Zn9 Zn11 2.6082(17) .
Zn9 Pr1 3.1531(10) 1_554
Zn9 Pr3 3.2292(13) 3_545
Zn9 Pr2 3.4834(10) 1_554
Zn10 Zn1 2.5270(16) 7_665
Zn10 Ge1 2.5270(16) 7_665
Zn10 Zn7 2.5895(16) 3
Zn10 Zn4 2.9112(11) 1_554
Zn10 Zn3 2.9566(12) 1_554
Zn10 Pr2 3.3898(10) 1_554
Zn10 Pr4 3.5054(9) 3_556
Zn11 Zn6 2.6261(17) 7_665
Zn11 Zn12 2.8395(8) 3_545
Zn11 Zn12 2.8394(8) 3_546
Zn11 Zn5 2.8465(11) 1_554
Zn11 Zn2 2.8677(11) 7_665
Zn11 Zn2 2.8677(11) 7_664
Zn11 Pr3 3.1708(13) 3_545
Zn11 Pr3 3.2003(14) 7_665
Zn11 Pr2 3.6176(11) 1_554
Zn12 Zn2 2.6545(12) 5_566
Zn12 Zn5 2.6641(13) 7_565
Zn12 Zn5 2.6641(13) 3_556
Zn12 Zn11 2.8395(8) 7_565
Zn12 Zn11 2.8395(8) 3_556
Zn12 Zn11 2.8395(8) 7_566
Zn12 Zn11 2.8395(8) 3
Zn12 Pr3 3.4646(6) 5_565
Zn12 Pr3 3.4646(6) 1_556
Zn12 Pr3 3.4646(6) 5_566
