#------------------------------------------------------------------------------
#$Date: 2016-03-23 22:10:53 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179470 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/67/4336707.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4336707
loop_
_publ_author_name
'Femke F. B. J. Janssen'
'Laurens C. J. M. Peters'
'Paul P. J. Schlebos'
'Jan M. M. Smits'
'René de Gelder'
'Alan E. Rowan'
_publ_contact_author
;
        F.F.B.J. Janssen
        Institute for Molecules and Materials
        Radboud University Nijmegen
        Heyendaalseweg 135
        6525 AJ  Nijmegen
        The Netherlands
;
_publ_contact_author_email       femke.janssen@science.ru.nl
_publ_contact_author_fax         '031 024 3553450'
_publ_contact_author_phone       '031 024 3652022'
_publ_section_title
;
 Uncorrelated Dynamical Processes in Tetranuclear Carboxylate Clusters
 Studied by Variable-Temperature 1H NMR Spectroscopy.
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              13004
_journal_page_last               13013
_journal_paper_doi               10.1021/ic401522v
_journal_volume                  52
_journal_year                    2013
_chemical_formula_sum            'C64 H72 Cl6 N6 O14 Zn4'
_chemical_formula_weight         1623.46
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yab'
_symmetry_space_group_name_H-M   'P 1 21/a 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             2006-07-27
_audit_creation_method           'SHELXL, adapted and expanded'
_cell_angle_alpha                90.00
_cell_angle_beta                 104.473(6)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   14.5599(6)
_cell_length_b                   15.9732(7)
_cell_length_c                   15.5271(16)
_cell_measurement_reflns_used    642
_cell_measurement_temperature    208(2)
_cell_measurement_theta_max      27.500
_cell_measurement_theta_min      2.140
_cell_volume                     3496.5(4)
_computing_data_collection
;
Nonius "Collect" program suite (Nonius, 1999)
;
_computing_data_reduction
;
Nonius "EvalCCD" program suite (Duisenberg, 1998)
;
_computing_molecular_graphics
;
PLATON (Spek, 2003)
;
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution
;
DIRDIF (Beurskens et al., 1996),
PATTY (Beurskens et al., 1987)
;
_diffrn_ambient_temperature      208(2)
_diffrn_detector_area_resol_mean 18.4
_diffrn_measured_fraction_theta_full 0.952
_diffrn_measured_fraction_theta_max 0.950
_diffrn_measurement_device       'Nonius KappaCCD'
_diffrn_measurement_method       'area detector φ and ω scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0440
_diffrn_reflns_av_sigmaI/netI    0.0344
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            73661
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         2.14
_diffrn_standards_decay_%        0.000
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.651
_exptl_absorpt_correction_T_max  0.921
_exptl_absorpt_correction_T_min  0.735
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS multi-scan (Sheldrick, 1996)'
_exptl_crystal_colour            'translucent red-brown'
_exptl_crystal_density_diffrn    1.542
_exptl_crystal_description       'regular platelet'
_exptl_crystal_F_000             1664
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.05
_refine_diff_density_max         1.218
_refine_diff_density_min         -1.530
_refine_diff_density_rms         0.124
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_all   1.031
_refine_ls_goodness_of_fit_ref   1.031
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     426
_refine_ls_number_reflns         7888
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.031
_refine_ls_R_factor_all          0.0854
_refine_ls_R_factor_gt           0.0605
_refine_ls_R_factor_obs          0.0605
_refine_ls_shift/esd_max         0.000
_refine_ls_shift/esd_mean        0.000
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;
w=1/[σ²(Fo²)+(0.0762P)²+15.6542P] where P=(Fo²+2Fc²)/3
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.1676
_refine_ls_wR_factor_gt          0.1500
_refine_ls_wR_factor_obs         0.1500
_refine_ls_wR_factor_ref         0.1676
_reflns_number_gt                5976
_reflns_number_observed          5976
_reflns_number_total             7888
_reflns_observed_criterion       >2sigma(I)
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic401522v_si_001_5.cif
_cod_data_source_block           FJ004
_cod_original_sg_symbol_H-M      'P 21/a'
_cod_database_code               4336707
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x-1/2, -y-1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
Zn1 Zn 0.09557(3) 0.01889(3) 0.09504(3) 0.01946(14) Uani 1 d .
Zn2 Zn 0.09348(4) -0.16107(3) 0.02167(3) 0.02116(14) Uani 1 d .
C1 C -0.1115(3) 0.0235(3) 0.0975(3) 0.0212(8) Uani 1 d .
C2 C -0.1253(3) 0.0673(3) 0.1700(3) 0.0256(9) Uani 1 d .
H2 H -0.1018 0.1221 0.1806 0.031 Uiso 1 calc R
C3 C -0.1732(3) 0.0314(3) 0.2272(3) 0.0291(10) Uani 1 d .
H3 H -0.1794 0.0617 0.2773 0.035 Uiso 1 calc R
C4 C -0.2125(3) -0.0484(3) 0.2127(3) 0.0263(9) Uani 1 d .
C5 C -0.2441(4) -0.1819(4) 0.2864(5) 0.0546(17) Uani 1 d .
H5A H -0.1771 -0.1880 0.3149 0.082 Uiso 1 calc R
H5B H -0.2584 -0.2098 0.2291 0.082 Uiso 1 calc R
H5C H -0.2812 -0.2068 0.3236 0.082 Uiso 1 calc R
C6 C -0.2494(6) -0.0448(6) 0.3638(4) 0.076(3) Uani 1 d .
H6A H -0.1826 -0.0497 0.3936 0.114 Uiso 1 calc R
H6B H -0.2870 -0.0710 0.3998 0.114 Uiso 1 calc R
H6C H -0.2663 0.0139 0.3555 0.114 Uiso 1 calc R
C7 C -0.3740(4) -0.0797(4) 0.2287(4) 0.0437(13) Uani 1 d .
H7A H -0.4106 -0.1044 0.2665 0.066 Uiso 1 calc R
H7B H -0.3884 -0.1082 0.1717 0.066 Uiso 1 calc R
H7C H -0.3900 -0.0208 0.2196 0.066 Uiso 1 calc R
C8 C -0.2687(4) -0.0883(3) 0.2730(3) 0.0348(11) Uani 1 d .
C9 C -0.2033(3) -0.0900(3) 0.1374(3) 0.0283(10) Uani 1 d .
H9 H -0.2317 -0.1428 0.1242 0.034 Uiso 1 calc R
C10 C 0.1531(3) 0.0559(3) -0.0804(3) 0.0217(8) Uani 1 d .
C11 C 0.1641(3) 0.1723(3) 0.0168(3) 0.0271(10) Uani 1 d .
H11 H 0.1844 0.2081 -0.0227 0.033 Uiso 1 calc R
C12 C 0.1556(3) 0.2015(3) 0.1041(3) 0.0258(9) Uani 1 d .
C13 C 0.1739(4) 0.2829(3) 0.1354(4) 0.0361(11) Uani 1 d .
H13 H 0.1938 0.3243 0.1010 0.043 Uiso 1 calc R
C14 C 0.1620(4) 0.3006(3) 0.2185(4) 0.0425(13) Uani 1 d .
H14 H 0.1721 0.3554 0.2408 0.051 Uiso 1 calc R
C15 C 0.1354(4) 0.2389(3) 0.2696(4) 0.0362(11) Uani 1 d .
H15 H 0.1271 0.2510 0.3264 0.043 Uiso 1 calc R
C16 C 0.1213(3) 0.1589(3) 0.2351(3) 0.0277(10) Uani 1 d .
C17 C 0.0983(3) 0.0848(3) 0.2811(3) 0.0284(10) Uani 1 d .
H17 H 0.0904 0.0879 0.3393 0.034 Uiso 1 calc R
C18 C 0.0685(3) -0.0623(3) 0.2677(3) 0.0231(9) Uani 1 d .
C19 C 0.0682(3) -0.0830(3) 0.3548(3) 0.0270(9) Uani 1 d .
H19 H 0.0812 -0.0411 0.3987 0.032 Uiso 1 calc R
C20 C 0.0493(3) -0.1638(3) 0.3784(3) 0.0269(9) Uani 1 d .
C21 C 0.0598(4) -0.1892(3) 0.4756(3) 0.0361(11) Uani 1 d .
C22 C 0.1634(6) -0.2074(7) 0.5166(5) 0.099(4) Uani 1 d .
H22A H 0.2010 -0.1587 0.5103 0.148 Uiso 1 calc R
H22B H 0.1833 -0.2548 0.4866 0.148 Uiso 1 calc R
H22C H 0.1724 -0.2203 0.5792 0.148 Uiso 1 calc R
C23 C 0.0299(8) -0.1190(5) 0.5287(5) 0.086(3) Uani 1 d .
H23A H 0.0666 -0.0692 0.5247 0.129 Uiso 1 calc R
H23B H 0.0409 -0.1358 0.5905 0.129 Uiso 1 calc R
H23C H -0.0370 -0.1072 0.5049 0.129 Uiso 1 calc R
C24 C -0.0009(8) -0.2633(6) 0.4842(5) 0.107(4) Uani 1 d .
H24A H 0.0077 -0.2768 0.5466 0.160 Uiso 1 calc R
H24B H 0.0173 -0.3109 0.4535 0.160 Uiso 1 calc R
H24C H -0.0670 -0.2499 0.4581 0.160 Uiso 1 calc R
C25 C 0.0282(3) -0.2224(3) 0.3097(3) 0.0289(10) Uani 1 d .
H25 H 0.0138 -0.2774 0.3233 0.035 Uiso 1 calc R
C26 C 0.0275(3) -0.2037(3) 0.2229(3) 0.0256(9) Uani 1 d .
H26 H 0.0121 -0.2455 0.1790 0.031 Uiso 1 calc R
C27 C 0.0496(3) -0.1229(3) 0.1997(3) 0.0200(8) Uani 1 d .
C28 C 0.2753(3) -0.0937(3) 0.1059(3) 0.0270(9) Uani 1 d .
C29 C 0.3811(4) -0.1031(3) 0.1383(4) 0.0458(14) Uani 1 d .
H29A H 0.4087 -0.0502 0.1623 0.069 Uiso 1 calc R
H29B H 0.4072 -0.1196 0.0891 0.069 Uiso 1 calc R
H29C H 0.3956 -0.1456 0.1843 0.069 Uiso 1 calc R
C30 C 0.0689(4) -0.3048(3) -0.0391(4) 0.0374(12) Uani 1 d .
C31 C 0.0608(5) -0.3964(3) -0.0611(5) 0.0566(17) Uani 1 d .
H31A H -0.0021 -0.4082 -0.0981 0.085 Uiso 1 calc R
H31B H 0.0713 -0.4287 -0.0066 0.085 Uiso 1 calc R
H31C H 0.1079 -0.4115 -0.0928 0.085 Uiso 1 calc R
N1 N 0.1424(2) 0.0958(2) -0.0029(2) 0.0220(7) Uani 1 d .
N2 N 0.1294(3) 0.1424(2) 0.1529(2) 0.0238(8) Uani 1 d .
N3 N 0.0895(3) 0.0162(2) 0.2385(2) 0.0231(7) Uani 1 d .
O1 O -0.0569(2) 0.05348(17) 0.04521(19) 0.0201(6) Uani 1 d .
O2 O 0.0512(2) -0.10195(17) 0.11773(19) 0.0210(6) Uani 1 d .
O3 O 0.2323(2) -0.1548(2) 0.0615(2) 0.0344(8) Uani 1 d .
O4 O 0.2375(2) -0.02842(19) 0.1259(2) 0.0282(7) Uani 1 d .
O5 O 0.0501(4) -0.2804(2) 0.0307(3) 0.0567(12) Uani 1 d .
O6 O 0.0939(4) -0.2543(3) -0.0877(3) 0.0616(13) Uani 1 d .
C32 C 0.3563(9) 0.0318(10) 0.3343(7) 0.136(5) Uani 1 d .
H32 H 0.3169 -0.0080 0.2918 0.163 Uiso 1 calc R
Cl1 Cl 0.4708(3) 0.0029(3) 0.3623(3) 0.188(2) Uani 1 d .
Cl2 Cl 0.3070(2) 0.0551(2) 0.41697(18) 0.1219(11) Uani 1 d .
Cl3 Cl 0.3721(3) 0.1402(4) 0.2761(3) 0.1762(19) Uani 1 d .
O7 O 0.3213(9) -0.1045(9) 0.3488(8) 0.205(5) Uani 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O2 Zn1 O4 87.59(12) . . y
O2 Zn1 N2 144.61(13) . . y
O4 Zn1 N2 96.99(13) . . y
O2 Zn1 N1 142.78(12) . . y
O4 Zn1 N1 84.44(13) . . y
N2 Zn1 N1 72.56(14) . . y
O2 Zn1 O1 87.96(11) . . y
O4 Zn1 O1 170.88(11) . . y
N2 Zn1 O1 91.24(12) . . y
N1 Zn1 O1 94.34(12) . . y
O2 Zn1 N3 74.10(12) . . y
O4 Zn1 N3 92.63(13) . . y
N2 Zn1 N3 70.65(13) . . y
N1 Zn1 N3 142.44(13) . . y
O1 Zn1 N3 93.80(12) . . y
O2 Zn1 O1 72.36(10) . 3 y
O4 Zn1 O1 91.57(11) . 3 y
N2 Zn1 O1 142.05(12) . 3 y
N1 Zn1 O1 71.59(11) . 3 y
O1 Zn1 O1 79.49(11) . 3 y
N3 Zn1 O1 145.97(11) . 3 y
O2 Zn1 Zn2 39.56(8) . . y
O4 Zn1 Zn2 70.97(8) . . y
N2 Zn1 Zn2 167.87(10) . . y
N1 Zn1 Zn2 104.00(10) . . y
O1 Zn1 Zn2 100.68(7) . . y
N3 Zn1 Zn2 110.37(9) . . y
O1 Zn1 Zn2 40.56(7) 3 . y
O3 Zn2 O2 103.11(13) . . y
O3 Zn2 O1 103.79(13) . 3 y
O2 Zn2 O1 83.68(11) . 3 y
O3 Zn2 O5 109.89(18) . . y
O2 Zn2 O5 103.57(14) . . y
O1 Zn2 O5 142.60(17) 3 . y
O3 Zn2 O6 94.27(17) . . y
O2 Zn2 O6 159.41(15) . . y
O1 Zn2 O6 103.00(14) 3 . y
O5 Zn2 O6 59.42(16) . . y
O3 Zn2 C30 101.92(16) . . y
O2 Zn2 C30 133.19(15) . . y
O1 Zn2 C30 127.03(15) 3 . y
O5 Zn2 C30 30.07(17) . . y
O6 Zn2 C30 29.46(16) . . y
O3 Zn2 Zn1 85.53(9) . . y
O2 Zn2 Zn1 42.09(8) . . y
O1 Zn2 Zn1 51.08(8) 3 . y
O5 Zn2 Zn1 145.61(12) . . y
O6 Zn2 Zn1 152.69(11) . . y
C30 Zn2 Zn1 172.43(13) . . y
O1 C1 C2 122.3(4) . . y
O1 C1 C10 119.7(4) . 3 y
C2 C1 C10 117.9(4) . 3 y
C1 C2 C3 120.8(4) . . y
C2 C3 C4 121.8(4) . . y
C9 C4 C3 117.1(4) . . y
C9 C4 C8 119.9(4) . . y
C3 C4 C8 122.9(4) . . y
C7 C8 C4 108.6(4) . . y
C7 C8 C6 107.9(5) . . y
C4 C8 C6 111.8(4) . . y
C7 C8 C5 108.9(5) . . y
C4 C8 C5 110.2(4) . . y
C6 C8 C5 109.5(5) . . y
C4 C9 C10 121.9(4) . 3 y
C9 C10 C1 120.3(4) 3 3 y
C9 C10 N1 123.7(4) 3 . y
C1 C10 N1 116.0(4) 3 . y
N1 C11 C12 117.0(4) . . y
N2 C12 C13 121.6(4) . . y
N2 C12 C11 113.8(4) . . y
C13 C12 C11 124.7(4) . . y
C14 C13 C12 117.6(5) . . y
C13 C14 C15 120.8(5) . . y
C14 C15 C16 118.3(5) . . y
N2 C16 C15 120.8(4) . . y
N2 C16 C17 113.1(4) . . y
C15 C16 C17 126.1(4) . . y
N3 C17 C16 116.7(4) . . y
C19 C18 N3 125.7(4) . . y
C19 C18 C27 121.2(4) . . y
N3 C18 C27 113.1(4) . . y
C20 C19 C18 121.7(4) . . y
C19 C20 C25 116.2(4) . . y
C19 C20 C21 122.0(4) . . y
C25 C20 C21 121.6(4) . . y
C24 C21 C22 111.0(7) . . y
C24 C21 C23 106.1(7) . . y
C22 C21 C23 107.7(6) . . y
C24 C21 C20 112.4(5) . . y
C22 C21 C20 108.0(5) . . y
C23 C21 C20 111.5(5) . . y
C26 C25 C20 123.3(4) . . y
C25 C26 C27 120.4(4) . . y
O2 C27 C26 122.8(4) . . y
O2 C27 C18 120.1(4) . . y
C26 C27 C18 117.1(4) . . y
O4 C28 O3 126.0(4) . . y
O4 C28 C29 118.5(4) . . y
O3 C28 C29 115.5(4) . . y
O6 C30 O5 119.7(5) . . y
O6 C30 C31 121.5(5) . . y
O5 C30 C31 118.8(5) . . y
O6 C30 Zn2 65.5(3) . . y
O5 C30 Zn2 54.5(3) . . y
C31 C30 Zn2 170.9(4) . . y
C11 N1 C10 124.5(4) . . y
C11 N1 Zn1 118.0(3) . . y
C10 N1 Zn1 117.3(3) . . y
C12 N2 C16 120.8(4) . . y
C12 N2 Zn1 118.6(3) . . y
C16 N2 Zn1 120.6(3) . . y
C17 N3 C18 127.5(4) . . y
C17 N3 Zn1 118.4(3) . . y
C18 N3 Zn1 113.9(3) . . y
C1 O1 Zn2 119.4(2) . 3 y
C1 O1 Zn1 112.7(2) . . y
Zn2 O1 Zn1 120.21(13) 3 . y
C1 O1 Zn1 109.4(2) . 3 y
Zn2 O1 Zn1 88.36(10) 3 3 y
Zn1 O1 Zn1 100.51(11) . 3 y
C27 O2 Zn2 133.3(3) . . y
C27 O2 Zn1 118.4(2) . . y
Zn2 O2 Zn1 98.35(12) . . y
C28 O3 Zn2 122.7(3) . . y
C28 O4 Zn1 134.2(3) . . y
C30 O5 Zn2 95.4(3) . . y
C30 O6 Zn2 85.1(3) . . y
Cl2 C32 Cl1 117.0(7) . . y
Cl2 C32 Cl3 106.1(7) . . y
Cl1 C32 Cl3 97.8(8) . . y
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Zn1 O2 2.093(3) . y
Zn1 O4 2.140(3) . y
Zn1 N2 2.172(4) . y
Zn1 N1 2.193(4) . y
Zn1 O1 2.230(3) . y
Zn1 N3 2.252(4) . y
Zn1 O1 2.405(3) 3 y
Zn1 Zn2 3.0894(7) . y
Zn2 O3 1.963(3) . y
Zn2 O2 1.989(3) . y
Zn2 O1 2.010(3) 3 y
Zn2 O5 2.024(4) . y
Zn2 O6 2.260(5) . y
Zn2 C30 2.475(5) . y
C1 O1 1.357(5) . y
C1 C2 1.382(6) . y
C1 C10 1.401(6) 3 y
C2 C3 1.384(6) . y
C3 C4 1.392(7) . y
C4 C9 1.379(7) . y
C4 C8 1.529(6) . y
C5 C8 1.538(8) . y
C6 C8 1.534(8) . y
C7 C8 1.521(7) . y
C9 C10 1.392(6) 3 y
C10 C9 1.392(6) 3 y
C10 C1 1.401(6) 3 y
C10 N1 1.404(5) . y
C11 N1 1.279(6) . y
C11 C12 1.466(7) . y
C12 N2 1.326(6) . y
C12 C13 1.390(6) . y
C13 C14 1.372(8) . y
C14 C15 1.380(7) . y
C15 C16 1.380(6) . y
C16 N2 1.337(6) . y
C16 C17 1.464(6) . y
C17 N3 1.270(6) . y
C18 C19 1.392(6) . y
C18 N3 1.394(6) . y
C18 C27 1.408(6) . y
C19 C20 1.388(6) . y
C20 C25 1.395(6) . y
C20 C21 1.533(6) . y
C21 C24 1.502(9) . y
C21 C22 1.512(9) . y
C21 C23 1.520(9) . y
C25 C26 1.378(6) . y
C26 C27 1.399(6) . y
C27 O2 1.322(5) . y
C28 O4 1.253(5) . y
C28 O3 1.267(6) . y
C28 C29 1.504(7) . y
C30 O6 1.222(7) . y
C30 O5 1.246(7) . y
C30 C31 1.499(7) . y
O1 Zn2 2.010(3) 3 y
O1 Zn1 2.405(3) 3 y
C32 Cl2 1.662(10) . y
C32 Cl1 1.679(12) . y
C32 Cl3 1.992(16) . y
