#------------------------------------------------------------------------------
#$Date: 2016-03-23 22:14:35 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179473 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/70/4337009.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4337009
loop_
_publ_author_name
'Chanel F. Leong'
'Bun Chan'
'Thomas B. Faust'
'Peter Turner'
'Deanna M. D'Alessandro'
_publ_section_title
;
 Electronic, Optical, and Computational Studies of a Redox-Active
 Napthalenediimide-Based Coordination Polymer
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              14246
_journal_page_last               14252
_journal_paper_doi               10.1021/ic402173z
_journal_volume                  52
_journal_year                    2013
_chemical_formula_moiety         'C22 H18 N4 O8 Zn'
_chemical_formula_sum            'C22 H18 N4 O8 Zn'
_chemical_formula_weight         531.77
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                92.283(2)
_cell_angle_beta                 94.663(2)
_cell_angle_gamma                97.343(2)
_cell_formula_units_Z            2
_cell_length_a                   7.5108(2)
_cell_length_b                   8.1831(2)
_cell_length_c                   17.6865(4)
_cell_measurement_reflns_used    13537
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      76
_cell_measurement_theta_min      5
_cell_volume                     1073.17(5)
_computing_cell_refinement
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.11 (release 16-05-2011 CrysAlis171 .NET)
(compiled May 16 2011,17:55:39)
;
_computing_data_collection
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.11 (release 16-05-2011 CrysAlis171 .NET)
(compiled May 16 2011,17:55:39)
;
_computing_data_reduction
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.11 (release 16-05-2011 CrysAlis171 .NET)
(compiled May 16 2011,17:55:39)
;
_computing_molecular_graphics
;
  xtal 3.6 (Hall,du Boulay, D.J. & Olthof-Hazekamp, R. 1999)
  ORTEPII  (Johnson,C.K., 1976). 
  WinGX (Farrugia, 1999)
  shelXle (Hubschke, 2011)
;
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SIR97 (Altomare, et. al. 1997)'
_diffrn_ambient_temperature      150(2)
_diffrn_crystal_treatment
;
attached with Exxon Paratone N, to a short length 
of fibre supported on a thin piece of copper wire 
inserted in a copper mounting pin.  The crystal was 
quenched in a cold nitrogen gas stream from an 
Oxford Cryosystems Cryostream. 
;
_diffrn_detector_area_resol_mean 10.5861
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_source         'SuperNova (Cu) x-ray Source'
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.5418
_diffrn_reflns_av_R_equivalents  0.0398
_diffrn_reflns_av_sigmaI/netI    0.0194
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            34241
_diffrn_reflns_theta_full        76.51
_diffrn_reflns_theta_max         76.51
_diffrn_reflns_theta_min         5.02
_exptl_absorpt_coefficient_mu    2.125
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.872
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies
 Version 1.171.36.21
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.646
_exptl_crystal_description       tablet
_exptl_crystal_F_000             544
_exptl_crystal_size_max          0.153
_exptl_crystal_size_mid          0.097
_exptl_crystal_size_min          0.026
_refine_diff_density_max         0.543
_refine_diff_density_min         -0.351
_refine_diff_density_rms         0.061
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.451
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     306
_refine_ls_number_reflns         4493
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.451
_refine_ls_R_factor_all          0.0381
_refine_ls_R_factor_gt           0.0336
_refine_ls_shift/su_max          0.009
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.05P)²P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0964
_refine_ls_wR_factor_ref         0.0993
_reflns_number_gt                4074
_reflns_number_total             4493
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic402173z_si_002.cif
_cod_data_source_block           (Zn(DMF)NO3)2(NDC)(DPMNI)
_cod_database_code               4337009
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Zn1 Zn 0.22158(3) 0.18379(3) 0.326980(13) 0.02833(10) Uani 1 1 d .
O1 O 0.2432(2) 0.00187(18) 0.24373(8) 0.0374(3) Uani 1 1 d .
O2 O 0.36888(19) 0.25089(17) 0.22432(8) 0.0341(3) Uani 1 1 d .
O7 O -0.1900(2) 1.02146(17) 0.21628(8) 0.0362(3) Uani 1 1 d .
O8 O -0.2324(2) 0.54514(16) 0.07250(8) 0.0353(3) Uani 1 1 d .
N1 N 0.0637(2) 0.36712(18) 0.30911(8) 0.0272(3) Uani 1 1 d .
N2 N -0.2019(2) 0.78230(18) 0.14566(8) 0.0272(3) Uani 1 1 d .
C1 C -0.1159(3) 0.3328(2) 0.30584(10) 0.0278(3) Uani 1 1 d .
H1 H -0.1667 0.2340 0.3267 0.033 Uiso 1 1 calc R
C2 C -0.2308(3) 0.4348(2) 0.27339(10) 0.0281(3) Uani 1 1 d .
H2 H -0.3576 0.4046 0.2710 0.034 Uiso 1 1 calc R
C3 C -0.1592(3) 0.5818(2) 0.24433(9) 0.0269(3) Uani 1 1 d .
C4 C 0.0274(3) 0.6239(2) 0.25262(11) 0.0310(4) Uani 1 1 d .
H4 H 0.0809 0.7273 0.2370 0.037 Uiso 1 1 calc R
C5 C 0.1336(3) 0.5134(2) 0.28385(11) 0.0308(4) Uani 1 1 d .
H5 H 0.2608 0.5413 0.2877 0.037 Uiso 1 1 calc R
C6 C -0.2851(3) 0.6892(2) 0.20565(11) 0.0308(4) Uani 1 1 d .
H6A H -0.3954 0.6188 0.1834 0.037 Uiso 1 1 calc R
H6B H -0.3210 0.7673 0.2440 0.037 Uiso 1 1 calc R
C7 C -0.1580(2) 0.9541(2) 0.15799(10) 0.0272(3) Uani 1 1 d .
C8 C -0.0734(2) 1.0440(2) 0.09591(10) 0.0258(3) Uani 1 1 d .
C9 C -0.0414(2) 0.9568(2) 0.02913(10) 0.0246(3) Uani 1 1 d .
C10 C -0.0928(2) 0.7843(2) 0.01854(10) 0.0253(3) Uani 1 1 d .
C11 C -0.1812(3) 0.6927(2) 0.07900(10) 0.0280(4) Uani 1 1 d .
C12 C -0.0247(3) 1.2132(2) 0.10463(10) 0.0277(3) Uani 1 1 d .
H12 H -0.0482 1.2713 0.1495 0.033 Uiso 1 1 calc R
C13 C -0.0594(3) 0.7012(2) -0.04710(10) 0.0280(4) Uani 1 1 d .
H13 H -0.0935 0.5853 -0.0535 0.034 Uiso 1 1 calc R
C14 C 0.3326(2) 0.1015(2) 0.20358(10) 0.0299(4) Uani 1 1 d .
C15 C 0.3895(2) 0.0372(2) 0.12989(10) 0.0288(4) Uani 1 1 d .
C16 C 0.4720(3) 0.1436(2) 0.08185(11) 0.0293(4) Uani 1 1 d .
H16 H 0.4978 0.2577 0.0965 0.035 Uiso 1 1 calc R
C17 C 0.5200(2) 0.0859(2) 0.01015(11) 0.0273(3) Uani 1 1 d .
C18 C 0.3973(3) -0.1943(2) 0.04072(11) 0.0303(4) Uani 1 1 d .
H18 H 0.3732 -0.3091 0.0275 0.036 Uiso 1 1 calc R
C19 C 0.3517(3) -0.1345(2) 0.10897(11) 0.0309(4) Uani 1 1 d .
H19 H 0.2945 -0.2080 0.1426 0.037 Uiso 1 1 calc R
O3 O 0.0319(2) 0.05071(17) 0.38275(8) 0.0339(3) Uani 1 1 d .
N3 N -0.1040(2) -0.18143(19) 0.42889(9) 0.0326(3) Uani 1 1 d .
C20 C 0.0390(3) -0.0860(2) 0.41098(10) 0.0312(4) Uani 1 1 d .
H20 H 0.1534 -0.1227 0.4199 0.037 Uiso 1 1 calc R
C21 C -0.0878(3) -0.3364(2) 0.46533(12) 0.0420(5) Uani 1 1 d .
H21A H 0.0373 -0.3592 0.4666 0.063 Uiso 1 1 calc R
H21B H -0.1668 -0.4262 0.4366 0.063 Uiso 1 1 calc R
H21C H -0.1232 -0.3278 0.5173 0.063 Uiso 1 1 calc R
C22 C -0.28366(11) -0.13561(13) 0.41496(12) 0.0436(5) Uani 1 1 d .
H22A H -0.3177 -0.0819 0.4611 0.065 Uiso 1 1 calc R
H22B H -0.3694 -0.2347 0.4007 0.065 Uiso 1 1 calc R
H22C H -0.2851 -0.0593 0.3737 0.065 Uiso 1 1 calc R
O4 O 0.42829(12) 0.14910(12) 0.40196(5) 0.0520(4) Uani 1 1 d R
O5 O 0.65146(12) 0.29434(12) 0.46780(5) 0.0526(4) Uani 1 1 d R
O6 O 0.45926(11) 0.41430(11) 0.39861(5) 0.0561(5) Uani 1 1 d R
N4 N 0.51726(12) 0.28904(11) 0.42400(5) 0.0415(4) Uani 1 1 d R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn -1.5491 0.6778 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O4 Zn1 O3 94.67(5) . .
O4 Zn1 N1 135.52(5) . .
O3 Zn1 N1 92.25(6) . .
O4 Zn1 O1 100.25(5) . .
O3 Zn1 O1 96.80(6) . .
N1 Zn1 O1 122.43(6) . .
O4 Zn1 O2 100.86(5) . .
O3 Zn1 O2 154.24(6) . .
N1 Zn1 O2 90.92(5) . .
O1 Zn1 O2 60.42(5) . .
O4 Zn1 C14 102.02(5) . .
O3 Zn1 C14 126.39(6) . .
N1 Zn1 C14 108.70(6) . .
O1 Zn1 C14 30.42(6) . .
O2 Zn1 C14 30.00(6) . .
C14 O1 Zn1 93.21(11) . .
C14 O2 Zn1 85.89(11) . .
C1 N1 C5 117.74(16) . .
C1 N1 Zn1 120.05(12) . .
C5 N1 Zn1 120.58(13) . .
C11 N2 C7 125.31(15) . .
C11 N2 C6 116.48(15) . .
C7 N2 C6 118.12(15) . .
N1 C1 C2 122.84(16) . .
N1 C1 H1 118.6 . .
C2 C1 H1 118.6 . .
C1 C2 C3 119.44(17) . .
C1 C2 H2 120.3 . .
C3 C2 H2 120.3 . .
C2 C3 C4 117.92(17) . .
C2 C3 C6 119.22(17) . .
C4 C3 C6 122.86(16) . .
C5 C4 C3 119.14(16) . .
C5 C4 H4 120.4 . .
C3 C4 H4 120.4 . .
N1 C5 C4 122.67(18) . .
N1 C5 H5 118.7 . .
C4 C5 H5 118.7 . .
N2 C6 C3 112.19(15) . .
N2 C6 H6A 109.2 . .
C3 C6 H6A 109.2 . .
N2 C6 H6B 109.2 . .
C3 C6 H6B 109.2 . .
H6A C6 H6B 107.9 . .
O7 C7 N2 120.29(16) . .
O7 C7 C8 123.24(16) . .
N2 C7 C8 116.48(15) . .
C12 C8 C9 120.48(16) . .
C12 C8 C7 119.55(16) . .
C9 C8 C7 119.97(15) . .
C8 C9 C10 121.39(16) . .
C8 C9 C9 119.50(19) . 2_575
C10 C9 C9 119.1(2) . 2_575
C13 C10 C9 120.45(16) . .
C13 C10 C11 119.99(15) . .
C9 C10 C11 119.56(15) . .
O8 C11 N2 120.20(17) . .
O8 C11 C10 122.66(16) . .
N2 C11 C10 117.13(15) . .
C8 C12 C13 120.02(16) . 2_575
C8 C12 H12 120.0 . .
C13 C12 H12 120.0 2_575 .
C10 C13 C12 120.44(16) . 2_575
C10 C13 H13 119.8 . .
C12 C13 H13 119.8 2_575 .
O2 C14 O1 120.48(17) . .
O2 C14 C15 120.95(17) . .
O1 C14 C15 118.55(17) . .
O2 C14 Zn1 64.11(10) . .
O1 C14 Zn1 56.37(9) . .
C15 C14 Zn1 174.86(14) . .
C16 C15 C19 120.11(17) . .
C16 C15 C14 120.17(17) . .
C19 C15 C14 119.69(17) . .
C15 C16 C17 120.98(17) . .
C15 C16 H16 119.5 . .
C17 C16 H16 119.5 . .
C18 C17 C17 120.0(2) 2_655 2_655
C18 C17 C16 121.79(16) 2_655 .
C17 C17 C16 118.2(2) 2_655 .
C19 C18 C17 120.32(17) . 2_655
C19 C18 H18 119.8 . .
C17 C18 H18 119.8 2_655 .
C18 C19 C15 120.37(17) . .
C18 C19 H19 119.8 . .
C15 C19 H19 119.8 . .
C20 O3 Zn1 128.00(14) . .
C20 N3 C22 121.51(15) . .
C20 N3 C21 121.18(18) . .
C22 N3 C21 117.29(16) . .
O3 C20 N3 123.24(19) . .
O3 C20 H20 118.4 . .
N3 C20 H20 118.4 . .
N3 C21 H21A 109.5 . .
N3 C21 H21B 109.5 . .
H21A C21 H21B 109.5 . .
N3 C21 H21C 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
N3 C22 H22A 109.5 . .
N3 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
N3 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
N4 O4 Zn1 109.2 . .
O5 N4 O6 123.5 . .
O5 N4 O4 119.4 . .
O6 N4 O4 117.0 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Zn1 O4 2.0144 .
Zn1 O3 2.0264(13) .
Zn1 N1 2.0463(15) .
Zn1 O1 2.0824(14) .
Zn1 O2 2.2523(14) .
Zn1 C14 2.4970(18) .
O1 C14 1.266(2) .
O2 C14 1.252(2) .
O7 C7 1.205(2) .
O8 C11 1.217(2) .
N1 C1 1.339(2) .
N1 C5 1.352(2) .
N2 C11 1.394(2) .
N2 C7 1.406(2) .
N2 C6 1.465(2) .
C1 C2 1.383(3) .
C1 H1 0.9500 .
C2 C3 1.389(2) .
C2 H2 0.9500 .
C3 C4 1.394(3) .
C3 C6 1.513(2) .
C4 C5 1.383(3) .
C4 H4 0.9500 .
C5 H5 0.9500 .
C6 H6A 0.9900 .
C6 H6B 0.9900 .
C7 C8 1.486(2) .
C8 C12 1.385(2) .
C8 C9 1.409(2) .
C9 C10 1.416(2) .
C9 C9 1.414(3) 2_575
C10 C13 1.379(2) .
C10 C11 1.483(2) .
C12 C13 1.405(3) 2_575
C12 H12 0.9500 .
C13 C12 1.405(3) 2_575
C13 H13 0.9500 .
C14 C15 1.500(2) .
C15 C16 1.368(3) .
C15 C19 1.426(3) .
C16 C17 1.425(3) .
C16 H16 0.9500 .
C17 C18 1.413(3) 2_655
C17 C17 1.424(3) 2_655
C18 C19 1.370(3) .
C18 C17 1.413(3) 2_655
C18 H18 0.9500 .
C19 H19 0.9500 .
O3 C20 1.248(2) .
N3 C20 1.313(3) .
N3 C22 1.451(2) .
N3 C21 1.459(2) .
C20 H20 0.9500 .
C21 H21A 0.9800 .
C21 H21B 0.9800 .
C21 H21C 0.9800 .
C22 H22A 0.9800 .
C22 H22B 0.9800 .
C22 H22C 0.9800 .
O4 N4 1.2792 .
O5 N4 1.2155 .
O6 N4 1.2494 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O4 Zn1 O1 C14 -96.32(12) . .
O3 Zn1 O1 C14 167.66(12) . .
N1 Zn1 O1 C14 70.62(13) . .
O2 Zn1 O1 C14 0.43(11) . .
O4 Zn1 O2 C14 95.28(11) . .
O3 Zn1 O2 C14 -30.76(19) . .
N1 Zn1 O2 C14 -127.86(12) . .
O1 Zn1 O2 C14 -0.43(11) . .
O4 Zn1 N1 C1 -125.71(12) . .
O3 Zn1 N1 C1 -26.71(14) . .
O1 Zn1 N1 C1 72.81(14) . .
O2 Zn1 N1 C1 127.72(13) . .
C14 Zn1 N1 C1 103.09(13) . .
O4 Zn1 N1 C5 69.16(16) . .
O3 Zn1 N1 C5 168.15(14) . .
O1 Zn1 N1 C5 -92.32(15) . .
O2 Zn1 N1 C5 -37.41(14) . .
C14 Zn1 N1 C5 -62.04(15) . .
C5 N1 C1 C2 4.4(3) . .
Zn1 N1 C1 C2 -161.13(13) . .
N1 C1 C2 C3 -1.6(3) . .
C1 C2 C3 C4 -3.1(3) . .
C1 C2 C3 C6 177.21(16) . .
C2 C3 C4 C5 4.9(3) . .
C6 C3 C4 C5 -175.44(17) . .
C1 N1 C5 C4 -2.5(3) . .
Zn1 N1 C5 C4 162.97(14) . .
C3 C4 C5 N1 -2.1(3) . .
C11 N2 C6 C3 73.1(2) . .
C7 N2 C6 C3 -110.01(18) . .
C2 C3 C6 N2 -149.25(16) . .
C4 C3 C6 N2 31.1(2) . .
C11 N2 C7 O7 176.01(17) . .
C6 N2 C7 O7 -0.6(3) . .
C11 N2 C7 C8 -3.6(3) . .
C6 N2 C7 C8 179.84(15) . .
O7 C7 C8 C12 1.2(3) . .
N2 C7 C8 C12 -179.22(16) . .
O7 C7 C8 C9 -179.54(18) . .
N2 C7 C8 C9 0.1(2) . .
C12 C8 C9 C10 -178.97(17) . .
C7 C8 C9 C10 1.8(3) . .
C12 C8 C9 C9 0.1(3) . 2_575
C7 C8 C9 C9 -179.12(19) . 2_575
C8 C9 C10 C13 -179.69(16) . .
C9 C9 C10 C13 1.2(3) 2_575 .
C8 C9 C10 C11 -0.4(3) . .
C9 C9 C10 C11 -179.48(19) 2_575 .
C7 N2 C11 O8 -175.97(18) . .
C6 N2 C11 O8 0.6(3) . .
C7 N2 C11 C10 5.0(3) . .
C6 N2 C11 C10 -178.42(15) . .
C13 C10 C11 O8 -2.5(3) . .
C9 C10 C11 O8 178.12(18) . .
C13 C10 C11 N2 176.49(16) . .
C9 C10 C11 N2 -2.8(3) . .
C9 C8 C12 C13 -0.8(3) . 2_575
C7 C8 C12 C13 178.42(16) . 2_575
C9 C10 C13 C12 -0.5(3) . 2_575
C11 C10 C13 C12 -179.83(16) . 2_575
Zn1 O2 C14 O1 0.72(18) . .
Zn1 O2 C14 C15 179.05(16) . .
Zn1 O1 C14 O2 -0.8(2) . .
Zn1 O1 C14 C15 -179.14(15) . .
O4 Zn1 C14 O2 -90.93(11) . .
O3 Zn1 C14 O2 163.97(10) . .
N1 Zn1 C14 O2 56.46(12) . .
O1 Zn1 C14 O2 179.26(19) . .
O4 Zn1 C14 O1 89.81(12) . .
O3 Zn1 C14 O1 -15.29(15) . .
N1 Zn1 C14 O1 -122.80(12) . .
O2 Zn1 C14 O1 -179.26(19) . .
O4 Zn1 C14 C15 98.2(15) . .
O3 Zn1 C14 C15 -6.9(16) . .
N1 Zn1 C14 C15 -114.4(15) . .
O1 Zn1 C14 C15 8.4(15) . .
O2 Zn1 C14 C15 -170.8(16) . .
O2 C14 C15 C16 -4.2(3) . .
O1 C14 C15 C16 174.14(18) . .
Zn1 C14 C15 C16 166.1(14) . .
O2 C14 C15 C19 177.87(18) . .
O1 C14 C15 C19 -3.8(3) . .
Zn1 C14 C15 C19 -11.8(16) . .
C19 C15 C16 C17 0.6(3) . .
C14 C15 C16 C17 -177.25(16) . .
C15 C16 C17 C18 179.00(17) . 2_655
C15 C16 C17 C17 -0.2(3) . 2_655
C17 C18 C19 C15 -0.9(3) 2_655 .
C16 C15 C19 C18 -0.1(3) . .
C14 C15 C19 C18 177.79(17) . .
O4 Zn1 O3 C20 -44.52(17) . .
N1 Zn1 O3 C20 179.45(17) . .
O1 Zn1 O3 C20 56.41(17) . .
O2 Zn1 O3 C20 82.7(2) . .
C14 Zn1 O3 C20 64.14(18) . .
Zn1 O3 C20 N3 -162.29(14) . .
C22 N3 C20 O3 1.7(3) . .
C21 N3 C20 O3 -176.85(18) . .
O3 Zn1 O4 N4 -127.36(4) . .
N1 Zn1 O4 N4 -29.34(7) . .
O1 Zn1 O4 N4 134.85(4) . .
O2 Zn1 O4 N4 73.29(4) . .
C14 Zn1 O4 N4 103.88(5) . .
Zn1 O4 N4 O5 -177.7 . .
Zn1 O4 N4 O6 2.4 . .
