#------------------------------------------------------------------------------
#$Date: 2016-03-23 22:14:35 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179473 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/70/4337078.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4337078
loop_
_publ_author_name
'Gao, Cunji'
'Kirillov, Alexander M.'
'Dou, Wei'
'Tang, Xiaoliang'
'Liu, Liangliang'
'Yan, Xuhuan'
'Xie, Yujie'
'Zang, Peixian'
'Liu, Weisheng'
'Tang, Yu'
_publ_section_title
;
 Self-Assembly Synthesis, Structural Features, and Photophysical
 Properties of Dilanthanide Complexes Derived from a Novel Amide Type
 Ligand: Energy Transfer from Tb(III) to Eu(III) in a Heterodinuclear
 Derivative.
;
_journal_issue                   2
_journal_name_full               'Inorganic chemistry'
_journal_page_first              935
_journal_page_last               942
_journal_paper_doi               10.1021/ic402338q
_journal_volume                  53
_journal_year                    2014
_chemical_formula_sum            'C74 H82 Eu N12 O32 Tb'
_chemical_formula_weight         1962.40
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 104.685(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   16.345(9)
_cell_length_b                   13.493(7)
_cell_length_c                   19.954(11)
_cell_measurement_reflns_used    5148
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      21.62
_cell_measurement_theta_min      2.40
_cell_volume                     4257(4)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0614
_diffrn_reflns_av_sigmaI/netI    0.0610
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            29461
_diffrn_reflns_theta_full        25.20
_diffrn_reflns_theta_max         25.20
_diffrn_reflns_theta_min         2.09
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.643
_exptl_absorpt_correction_T_max  0.685
_exptl_absorpt_correction_T_min  0.638
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.531
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1988
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.27
_exptl_crystal_size_min          0.23
_refine_diff_density_max         1.063
_refine_diff_density_min         -0.663
_refine_diff_density_rms         0.108
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.013
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     635
_refine_ls_number_reflns         7632
_refine_ls_number_restraints     957
_refine_ls_restrained_S_all      1.063
_refine_ls_R_factor_all          0.0833
_refine_ls_R_factor_gt           0.0515
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0705P)²+8.1433P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1243
_refine_ls_wR_factor_ref         0.1450
_reflns_number_gt                5331
_reflns_number_total             7632
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic402338q_si_004.cif
_cod_data_source_block           p21c
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/usr/data/users/saulius/automatic-downloads/current/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 
;
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               4337078
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C4 C 0.5923(5) 0.2197(6) -0.2408(4) 0.0509(18) Uani 1 1 d . A 2
C3 C 0.6543(5) 0.2074(7) -0.2729(4) 0.067(2) Uani 1 1 d . A 2
H3 H 0.6694 0.1487 -0.2910 0.080 Uiso 1 1 calc R A 2
C2 C 0.6932(6) 0.3032(8) -0.2738(5) 0.077(3) Uani 1 1 d . A 2
H2 H 0.7377 0.3185 -0.2932 0.092 Uiso 1 1 calc R A 2
C1 C 0.6535(7) 0.3641(8) -0.2421(5) 0.088(3) Uani 1 1 d . A 2
H1 H 0.6669 0.4308 -0.2342 0.105 Uiso 1 1 calc R A 2
C16 C 0.8867(4) 0.1766(6) -0.0822(4) 0.0978(19) Uani 0.50 1 d PGU B 1
C17 C 0.9177(5) 0.0940(6) -0.1094(5) 0.1001(19) Uani 0.50 1 d PGU B 1
H17 H 0.8815 0.0556 -0.1429 0.120 Uiso 0.50 1 calc PR B 1
C18 C 1.0026(5) 0.0688(6) -0.0865(5) 0.1003(19) Uani 0.50 1 d PGU B 1
H18 H 1.0233 0.0135 -0.1047 0.120 Uiso 0.50 1 calc PR B 1
C19 C 1.0567(4) 0.1262(6) -0.0364(5) 0.1003(19) Uani 0.50 1 d PGU B 1
H19 H 1.1135 0.1093 -0.0211 0.120 Uiso 0.50 1 calc PR B 1
C20 C 1.0257(4) 0.2087(5) -0.0091(4) 0.0999(19) Uani 0.50 1 d PGU B 1
H20 H 1.0619 0.2471 0.0244 0.120 Uiso 0.50 1 calc PR B 1
C21 C 0.9408(5) 0.2340(5) -0.0320(4) 0.0993(19) Uani 0.50 1 d PGU B 1
H21 H 0.9201 0.2892 -0.0138 0.119 Uiso 0.50 1 calc PR B 1
C16' C 0.8957(3) 0.1787(6) -0.0648(4) 0.0980(19) Uani 0.50 1 d PGU B 2
C17' C 0.9286(5) 0.0890(5) -0.0803(5) 0.0998(19) Uani 0.50 1 d PGU B 2
H17' H 0.8931 0.0422 -0.1072 0.120 Uiso 0.50 1 calc PR B 2
C18' C 1.0143(5) 0.0691(5) -0.0556(5) 0.1003(19) Uani 0.50 1 d PGU B 2
H18' H 1.0363 0.0091 -0.0660 0.120 Uiso 0.50 1 calc PR B 2
C19' C 1.0672(4) 0.1390(7) -0.0154(5) 0.1002(19) Uani 0.50 1 d PGU B 2
H19' H 1.1246 0.1258 0.0012 0.120 Uiso 0.50 1 calc PR B 2
C20' C 1.0343(5) 0.2288(6) 0.0001(4) 0.1003(19) Uani 0.50 1 d PGU B 2
H20' H 1.0698 0.2755 0.0270 0.120 Uiso 0.50 1 calc PR B 2
C21' C 0.9486(5) 0.2486(5) -0.0247(4) 0.0995(19) Uani 0.50 1 d PGU B 2
H21' H 0.9266 0.3086 -0.0143 0.119 Uiso 0.50 1 calc PR B 2
O6A O 0.9220(19) 0.551(2) 0.1815(16) 0.146(4) Uani 0.312(10) 1 d PDU C 1
C35A C 0.994(2) 0.502(2) 0.1950(16) 0.145(4) Uani 0.312(10) 1 d PDU C 1
H35A H 1.0232 0.4783 0.2382 0.174 Uiso 0.312(10) 1 calc PR C 1
C34A C 1.0165(19) 0.492(3) 0.137(2) 0.143(4) Uani 0.312(10) 1 d PDU C 1
H34A H 1.0648 0.4597 0.1317 0.171 Uiso 0.312(10) 1 calc PR C 1
C33A C 0.958(3) 0.535(3) 0.0877(15) 0.145(4) Uani 0.312(10) 1 d PDU C 1
H33A H 0.9585 0.5383 0.0412 0.174 Uiso 0.312(10) 1 calc PR C 1
C32A C 0.9007(19) 0.571(3) 0.1150(18) 0.142(4) Uani 0.312(10) 1 d PDU C 1
O6B O 0.9745(10) 0.6042(9) 0.1446(7) 0.148(4) Uani 0.688(10) 1 d PDU C 2
C35B C 1.0378(8) 0.5446(12) 0.1438(8) 0.145(4) Uani 0.688(10) 1 d PDU C 2
H35B H 1.0886 0.5407 0.1777 0.174 Uiso 0.688(10) 1 calc PR C 2
C34B C 1.0169(11) 0.4915(11) 0.0871(10) 0.146(4) Uani 0.688(10) 1 d PDU C 2
H34B H 1.0499 0.4432 0.0735 0.175 Uiso 0.688(10) 1 calc PR C 2
C33B C 0.9395(11) 0.5197(14) 0.0525(8) 0.146(4) Uani 0.688(10) 1 d PDU C 2
H33B H 0.9090 0.4950 0.0100 0.175 Uiso 0.688(10) 1 calc PR C 2
C32B C 0.9139(8) 0.5883(13) 0.0890(9) 0.139(4) Uani 0.688(10) 1 d PDU C 2
O1 O 0.5901(4) 0.3168(4) -0.2223(3) 0.0797(18) Uani 1 1 d . . .
C5 C 0.5268(5) 0.1530(7) -0.2266(4) 0.061(2) Uani 1 1 d . . .
H5A H 0.4714 0.1754 -0.2527 0.073 Uiso 1 1 calc R A 2
H5B H 0.5354 0.0866 -0.2421 0.073 Uiso 1 1 calc R A 2
C6 C 0.4600(4) 0.1551(5) -0.1301(4) 0.0412(16) Uani 1 1 d . . .
C7 C 0.4681(4) 0.1484(5) -0.0532(4) 0.0441(17) Uani 1 1 d . A .
C8 C 0.3971(5) 0.1742(6) -0.0302(4) 0.056(2) Uani 1 1 d . . .
H8 H 0.3484 0.1945 -0.0625 0.067 Uiso 1 1 calc R A .
C9 C 0.3966(6) 0.1707(6) 0.0384(5) 0.065(2) Uani 1 1 d . A .
H9 H 0.3489 0.1910 0.0520 0.079 Uiso 1 1 calc R . .
C10 C 0.4651(6) 0.1380(7) 0.0861(5) 0.071(2) Uani 1 1 d . . .
H10 H 0.4638 0.1334 0.1323 0.086 Uiso 1 1 calc R A .
C11 C 0.5360(6) 0.1119(6) 0.0670(4) 0.062(2) Uani 1 1 d . A .
H11 H 0.5831 0.0901 0.1004 0.075 Uiso 1 1 calc R . .
C12 C 0.5393(5) 0.1174(5) -0.0038(4) 0.0504(19) Uani 1 1 d . . .
C13 C 0.6891(5) 0.0846(6) 0.0230(5) 0.064(2) Uani 1 1 d . . .
H13A H 0.6971 0.0180 0.0419 0.077 Uiso 1 1 calc R A .
H13B H 0.6926 0.1307 0.0609 0.077 Uiso 1 1 calc R . .
C14 C 0.7545(5) 0.1074(6) -0.0133(5) 0.065(2) Uani 1 1 d . A .
H14A H 0.8089 0.1075 0.0205 0.078 Uiso 1 1 calc R . .
H14B H 0.7555 0.0542 -0.0458 0.078 Uiso 1 1 calc R . .
C15 C 0.7970(6) 0.1987(6) -0.1013(4) 0.066(2) Uani 1 1 d . . .
H15A H 0.7707 0.1513 -0.1368 0.079 Uiso 1 1 calc R B 1
H15B H 0.7907 0.2633 -0.1233 0.079 Uiso 1 1 calc R B 1
C22 C 0.7516(5) 0.2894(6) -0.0101(5) 0.063(2) Uani 1 1 d . . .
H22A H 0.7773 0.3413 -0.0316 0.075 Uiso 1 1 calc R B .
H22B H 0.7877 0.2775 0.0358 0.075 Uiso 1 1 calc R . .
C23 C 0.6664(5) 0.3235(6) -0.0041(5) 0.066(2) Uani 1 1 d . B .
H23A H 0.6290 0.3331 -0.0498 0.079 Uiso 1 1 calc R . .
H23B H 0.6416 0.2739 0.0200 0.079 Uiso 1 1 calc R . .
C24 C 0.6134(5) 0.4461(5) 0.0629(4) 0.0450(17) Uani 1 1 d . B .
C25 C 0.5376(5) 0.3965(5) 0.0547(4) 0.0503(18) Uani 1 1 d . . .
H25 H 0.5270 0.3401 0.0271 0.060 Uiso 1 1 calc R . .
C26 C 0.4777(5) 0.4293(5) 0.0868(4) 0.0524(19) Uani 1 1 d . . .
H26 H 0.4278 0.3937 0.0819 0.063 Uiso 1 1 calc R . .
C27 C 0.4905(5) 0.5130(6) 0.1254(4) 0.055(2) Uani 1 1 d . . .
H27 H 0.4491 0.5356 0.1461 0.066 Uiso 1 1 calc R . .
C28 C 0.5661(5) 0.5653(5) 0.1339(4) 0.0480(18) Uani 1 1 d . . .
H28 H 0.5753 0.6221 0.1612 0.058 Uiso 1 1 calc R . .
C29 C 0.6284(4) 0.5331(5) 0.1018(3) 0.0408(16) Uani 1 1 d . . .
C30 C 0.7058(4) 0.5963(5) 0.1136(4) 0.0432(16) Uani 1 1 d . . .
C31 C 0.8329(5) 0.6414(7) 0.0758(5) 0.072(2) Uani 1 1 d . . .
H31A H 0.8376 0.6911 0.1116 0.086 Uiso 1 1 calc R C 2
H31B H 0.8251 0.6763 0.0321 0.086 Uiso 1 1 calc R C 2
Eu1 Eu 0.2596(8) 0.2138(10) -0.2486(4) 0.0372(8) Uani 0.50 1 d P . .
Tb1 Tb 0.2634(8) 0.2183(10) -0.2357(4) 0.0372(8) Uani 0.50 1 d P . .
N1 N 0.5288(4) 0.1501(5) -0.1531(3) 0.0529(16) Uani 1 1 d . A .
H1A H 0.5770 0.1450 -0.1235 0.063 Uiso 1 1 calc R . .
N2 N 0.7457(4) 0.2001(4) -0.0507(3) 0.0524(16) Uani 1 1 d . A .
N3 N 0.7569(4) 0.5836(5) 0.0728(4) 0.0600(18) Uani 1 1 d . C .
H3A H 0.7444 0.5377 0.0420 0.072 Uiso 1 1 calc R . .
N4 N 0.3032(6) 0.3922(5) -0.3096(4) 0.069(2) Uani 1 1 d . A .
N5 N 0.2617(5) 0.1075(5) -0.3686(4) 0.0596(17) Uani 1 1 d . A .
N6 N 0.1986(4) 0.0466(5) -0.1785(4) 0.0555(17) Uani 1 1 d . A .
O3 O 0.6071(3) 0.0926(4) -0.0262(3) 0.0609(14) Uani 1 1 d . A .
O4 O 0.6770(3) 0.4146(4) 0.0336(3) 0.0585(14) Uani 1 1 d . . .
O5 O 0.7196(3) 0.6630(4) 0.1579(3) 0.0607(14) Uani 1 1 d . . .
O7 O 0.3556(4) 0.3232(4) -0.2882(3) 0.0632(15) Uani 1 1 d . A .
O8 O 0.3247(5) 0.4702(5) -0.3306(4) 0.105(2) Uani 1 1 d . . .
O9 O 0.2285(4) 0.3764(4) -0.3054(4) 0.0809(19) Uani 1 1 d . A .
O10 O 0.3242(3) 0.1067(4) -0.3170(3) 0.0576(14) Uani 1 1 d . A .
O11 O 0.2578(4) 0.0536(6) -0.4181(3) 0.098(2) Uani 1 1 d . . .
O12 O 0.2018(4) 0.1657(5) -0.3648(3) 0.0698(16) Uani 1 1 d . A .
O13 O 0.2134(4) 0.0437(4) -0.2378(3) 0.0629(14) Uani 1 1 d . A .
O14 O 0.1694(4) -0.0252(5) -0.1553(3) 0.0843(19) Uani 1 1 d . . .
O15 O 0.2164(4) 0.1266(4) -0.1450(3) 0.0663(15) Uani 1 1 d . A .
O2 O 0.3893(3) 0.1668(4) -0.1701(2) 0.0511(12) Uani 1 1 d . A .
O16 O 0.1156(4) 0.2396(5) -0.2594(3) 0.0785(16) Uani 0.561(15) 1 d PDU A 1
H16 H 0.1073 0.2044 -0.2263 0.094 Uiso 0.561(15) 1 d PRD A 1
C36 C 0.0357(7) 0.2503(15) -0.3071(7) 0.083(3) Uani 0.561(15) 1 d PDU A 1
H36A H 0.0323 0.2076 -0.3468 0.100 Uiso 0.561(15) 1 calc PR A 1
H36B H 0.0280 0.3183 -0.3233 0.100 Uiso 0.561(15) 1 calc PR A 1
C37 C -0.0321(9) 0.2230(17) -0.2720(11) 0.103(5) Uani 0.561(15) 1 d PDU A 1
H37A H -0.0154 0.1646 -0.2444 0.154 Uiso 0.561(15) 1 calc PR A 1
H37B H -0.0839 0.2102 -0.3064 0.154 Uiso 0.561(15) 1 calc PR A 1
H37C H -0.0404 0.2766 -0.2428 0.154 Uiso 0.561(15) 1 calc PR A 1
O16' O 0.1156(4) 0.2396(5) -0.2594(3) 0.0785(16) Uani 0.439(15) 1 d PDU A 2
H16' H 0.1080 0.2025 -0.2252 0.094 Uiso 0.439(15) 1 d PR A 2
C36' C 0.0442(8) 0.3075(11) -0.2745(11) 0.078(3) Uani 0.439(15) 1 d PDU A 2
H36C H 0.0503 0.3551 -0.3093 0.094 Uiso 0.439(15) 1 calc PR A 2
H36D H 0.0417 0.3433 -0.2329 0.094 Uiso 0.439(15) 1 calc PR A 2
C37' C -0.0341(10) 0.2487(19) -0.3002(13) 0.084(5) Uani 0.439(15) 1 d PDU A 2
H37D H -0.0324 0.2730 -0.3450 0.100 Uiso 0.439(15) 1 d PR A 2
H37E H -0.0848 0.2712 -0.2891 0.100 Uiso 0.439(15) 1 d PR A 2
H37F H -0.0332 0.1775 -0.3005 0.100 Uiso 0.439(15) 1 d PR A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Tb Tb -0.1723 4.1537 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C3 C4 O1 108.8(8) . .
C3 C4 C5 133.5(8) . .
O1 C4 C5 117.5(7) . .
C4 C3 C2 106.6(8) . .
C4 C3 H3 126.7 . .
C2 C3 H3 126.7 . .
C1 C2 C3 106.5(9) . .
C1 C2 H2 126.8 . .
C3 C2 H2 126.8 . .
C2 C1 O1 110.8(9) . .
C2 C1 H1 124.6 . .
O1 C1 H1 124.6 . .
C17 C16 C21 120.0 . .
C17 C16 C15 120.4(7) . .
C21 C16 C15 119.4(7) . .
C16 C17 C18 120.0 . .
C16 C17 H17 120.0 . .
C18 C17 H17 120.0 . .
C19 C18 C17 120.0 . .
C19 C18 H18 120.0 . .
C17 C18 H18 120.0 . .
C18 C19 C20 120.0 . .
C18 C19 H19 120.0 . .
C20 C19 H19 120.0 . .
C21 C20 C19 120.0 . .
C21 C20 H20 120.0 . .
C19 C20 H20 120.0 . .
C20 C21 C16 120.0 . .
C20 C21 H21 120.0 . .
C16 C21 H21 120.0 . .
C21' C16' C17' 120.0 . .
C21' C16' C15 123.4(6) . .
C17' C16' C15 116.3(6) . .
C18' C17' C16' 120.1 . .
C18' C17' H17' 120.0 . .
C16' C17' H17' 120.0 . .
C19' C18' C17' 119.9 . .
C19' C18' H18' 120.0 . .
C17' C18' H18' 120.0 . .
C18' C19' C20' 120.0 . .
C18' C19' H19' 120.0 . .
C20' C19' H19' 120.0 . .
C21' C20' C19' 120.1 . .
C21' C20' H20' 120.0 . .
C19' C20' H20' 120.0 . .
C16' C21' C20' 119.9 . .
C16' C21' H21' 120.0 . .
C20' C21' H21' 120.0 . .
C32A O6A C35A 107.8(6) . .
C34A C35A O6A 108.1(6) . .
C34A C35A H35A 125.9 . .
O6A C35A H35A 125.9 . .
C35A C34A C33A 107.5(6) . .
C35A C34A H34A 126.2 . .
C33A C34A H34A 126.2 . .
C32A C33A C34A 108.5(7) . .
C32A C33A H33A 125.8 . .
C34A C33A H33A 125.8 . .
C33A C32A O6A 108.1(7) . .
C32B O6B C35B 108.7(6) . .
C34B C35B O6B 108.1(6) . .
C34B C35B H35B 125.9 . .
O6B C35B H35B 125.9 . .
C35B C34B C33B 107.3(6) . .
C35B C34B H34B 126.4 . .
C33B C34B H34B 126.4 . .
C32B C33B C34B 108.0(6) . .
C32B C33B H33B 126.0 . .
C34B C33B H33B 126.0 . .
O6B C32B C33B 108.0(6) . .
O6B C32B C31 121.9(14) . .
C33B C32B C31 130.2(14) . .
C1 O1 C4 107.3(7) . .
N1 C5 C4 112.1(6) . .
N1 C5 H5A 109.2 . .
C4 C5 H5A 109.2 . .
N1 C5 H5B 109.2 . .
C4 C5 H5B 109.2 . .
H5A C5 H5B 107.9 . .
O2 C6 N1 121.4(7) . .
O2 C6 C7 119.4(6) . .
N1 C6 C7 119.2(6) . .
C12 C7 C8 117.3(7) . .
C12 C7 C6 125.7(7) . .
C8 C7 C6 117.0(6) . .
C9 C8 C7 122.4(8) . .
C9 C8 H8 118.8 . .
C7 C8 H8 118.8 . .
C10 C9 C8 120.2(9) . .
C10 C9 H9 119.9 . .
C8 C9 H9 119.9 . .
C9 C10 C11 120.2(9) . .
C9 C10 H10 119.9 . .
C11 C10 H10 119.9 . .
C10 C11 C12 121.0(8) . .
C10 C11 H11 119.5 . .
C12 C11 H11 119.5 . .
O3 C12 C7 117.1(7) . .
O3 C12 C11 124.0(7) . .
C7 C12 C11 118.9(8) . .
O3 C13 C14 108.3(7) . .
O3 C13 H13A 110.0 . .
C14 C13 H13A 110.0 . .
O3 C13 H13B 110.0 . .
C14 C13 H13B 110.0 . .
H13A C13 H13B 108.4 . .
N2 C14 C13 116.5(7) . .
N2 C14 H14A 108.2 . .
C13 C14 H14A 108.2 . .
N2 C14 H14B 108.2 . .
C13 C14 H14B 108.2 . .
H14A C14 H14B 107.3 . .
C16 C15 N2 122.6(7) . .
C16 C15 C16' 11.17(10) . .
N2 C15 C16' 111.9(7) . .
C16 C15 H15A 106.7 . .
N2 C15 H15A 106.7 . .
C16' C15 H15A 115.1 . .
C16 C15 H15B 106.7 . .
N2 C15 H15B 106.7 . .
C16' C15 H15B 109.4 . .
H15A C15 H15B 106.6 . .
N2 C22 C23 111.7(7) . .
N2 C22 H22A 109.3 . .
C23 C22 H22A 109.3 . .
N2 C22 H22B 109.3 . .
C23 C22 H22B 109.3 . .
H22A C22 H22B 107.9 . .
O4 C23 C22 108.3(7) . .
O4 C23 H23A 110.0 . .
C22 C23 H23A 110.0 . .
O4 C23 H23B 110.0 . .
C22 C23 H23B 110.0 . .
H23A C23 H23B 108.4 . .
C25 C24 O4 123.3(6) . .
C25 C24 C29 120.0(7) . .
O4 C24 C29 116.7(6) . .
C26 C25 C24 120.9(7) . .
C26 C25 H25 119.5 . .
C24 C25 H25 119.5 . .
C27 C26 C25 120.6(7) . .
C27 C26 H26 119.7 . .
C25 C26 H26 119.7 . .
C26 C27 C28 119.7(7) . .
C26 C27 H27 120.1 . .
C28 C27 H27 120.1 . .
C27 C28 C29 120.7(7) . .
C27 C28 H28 119.7 . .
C29 C28 H28 119.7 . .
C24 C29 C28 118.0(6) . .
C24 C29 C30 126.2(6) . .
C28 C29 C30 115.8(6) . .
O5 C30 N3 120.4(7) . .
O5 C30 C29 121.2(6) . .
N3 C30 C29 118.3(6) . .
N3 C31 C32B 117.9(10) . .
N3 C31 H31A 107.8 . .
C32B C31 H31A 107.8 . .
N3 C31 H31B 107.8 . .
C32B C31 H31B 107.8 . .
H31A C31 H31B 107.2 . .
O16 Eu1 O12 78.9(4) . .
O16 Eu1 O2 144.0(5) . .
O12 Eu1 O2 129.8(6) . .
O16 Eu1 O10 127.9(5) . .
O12 Eu1 O10 53.3(3) . .
O2 Eu1 O10 76.6(4) . .
O16 Eu1 O5 85.1(5) . 3_665
O12 Eu1 O5 150.4(6) . 3_665
O2 Eu1 O5 76.0(3) . 3_665
O10 Eu1 O5 147.0(6) . 3_665
O16 Eu1 O7 126.8(6) . .
O12 Eu1 O7 88.8(4) . .
O2 Eu1 O7 80.5(4) . .
O10 Eu1 O7 76.6(4) . .
O5 Eu1 O7 81.1(4) 3_665 .
O16 Eu1 O13 79.7(5) . .
O12 Eu1 O13 76.9(4) . .
O2 Eu1 O13 86.3(5) . .
O10 Eu1 O13 71.1(4) . .
O5 Eu1 O13 124.6(5) 3_665 .
O7 Eu1 O13 147.1(6) . .
O16 Eu1 O9 74.9(4) . .
O12 Eu1 O9 79.0(4) . .
O2 Eu1 O9 125.8(6) . .
O10 Eu1 O9 110.1(5) . .
O5 Eu1 O9 72.9(4) 3_665 .
O7 Eu1 O9 51.9(3) . .
O13 Eu1 O9 147.7(5) . .
O16 Eu1 O15 70.9(4) . .
O12 Eu1 O15 121.9(6) . .
O2 Eu1 O15 74.6(3) . .
O10 Eu1 O15 114.9(6) . .
O5 Eu1 O15 74.6(3) 3_665 .
O7 Eu1 O15 148.6(4) . .
O13 Eu1 O15 50.1(3) . .
O9 Eu1 O15 134.1(6) . .
O16 Eu1 N5 103.2(4) . .
O12 Eu1 N5 26.9(2) . .
O2 Eu1 N5 102.9(5) . .
O10 Eu1 N5 26.5(2) . .
O5 Eu1 N5 164.4(6) 3_665 .
O7 Eu1 N5 83.3(4) . .
O13 Eu1 N5 70.4(4) . .
O9 Eu1 N5 96.3(4) . .
O15 Eu1 N5 120.5(5) . .
O16 Eu1 N4 100.9(5) . .
O12 Eu1 N4 84.0(4) . .
O2 Eu1 N4 103.1(5) . .
O10 Eu1 N4 94.1(4) . .
O5 Eu1 N4 74.8(4) 3_665 .
O7 Eu1 N4 25.9(2) . .
O13 Eu1 N4 160.4(4) . .
O9 Eu1 N4 26.0(2) . .
O15 Eu1 N4 148.8(5) . .
N5 Eu1 N4 90.5(4) . .
O16 Eu1 H16 18.4 . .
O12 Eu1 H16 89.6 . .
O2 Eu1 H16 126.6 . .
O10 Eu1 H16 129.4 . .
O5 Eu1 H16 82.3 3_665 .
O7 Eu1 H16 143.0 . .
O13 Eu1 H16 67.3 . .
O9 Eu1 H16 91.5 . .
O15 Eu1 H16 52.6 . .
N5 Eu1 H16 109.7 . .
N4 Eu1 H16 117.3 . .
O16 Eu1 H16' 19.1 . .
O12 Eu1 H16' 89.9 . .
O2 Eu1 H16' 126.0 . .
O10 Eu1 H16' 129.2 . .
O5 Eu1 H16' 82.4 3_665 .
O7 Eu1 H16' 143.7 . .
O13 Eu1 H16' 66.7 . .
O9 Eu1 H16' 92.3 . .
O15 Eu1 H16' 51.9 . .
N5 Eu1 H16' 109.7 . .
N4 Eu1 H16' 118.0 . .
H16 Eu1 H16' 0.7 . .
O5 Tb1 O2 83.2(4) 3_665 .
O5 Tb1 O16 89.6(5) 3_665 .
O2 Tb1 O16 153.3(6) . .
O5 Tb1 O15 81.7(4) 3_665 .
O2 Tb1 O15 80.1(4) . .
O16 Tb1 O15 73.4(4) . .
O5 Tb1 O7 84.3(5) 3_665 .
O2 Tb1 O7 81.8(4) . .
O16 Tb1 O7 123.0(5) . .
O15 Tb1 O7 158.3(5) . .
O5 Tb1 O13 133.1(5) 3_665 .
O2 Tb1 O13 88.1(5) . .
O16 Tb1 O13 78.3(4) . .
O15 Tb1 O13 51.5(3) . .
O7 Tb1 O13 139.8(5) . .
O5 Tb1 O9 75.2(4) 3_665 .
O2 Tb1 O9 128.7(6) . .
O16 Tb1 O9 73.1(4) . .
O15 Tb1 O9 139.1(6) . .
O7 Tb1 O9 50.5(3) . .
O13 Tb1 O9 139.5(4) . .
O5 Tb1 O10 150.0(6) 3_665 .
O2 Tb1 O10 75.3(4) . .
O16 Tb1 O10 118.8(4) . .
O15 Tb1 O10 114.1(5) . .
O7 Tb1 O10 72.4(4) . .
O13 Tb1 O10 67.4(3) . .
O9 Tb1 O10 102.4(4) . .
O5 Tb1 O12 147.3(6) 3_665 .
O2 Tb1 O12 123.8(5) . .
O16 Tb1 O12 73.5(3) . .
O15 Tb1 O12 118.2(5) . .
O7 Tb1 O12 82.1(3) . .
O13 Tb1 O12 71.6(3) . .
O9 Tb1 O12 73.2(3) . .
O10 Tb1 O12 48.5(2) . .
O5 Tb1 N6 107.4(4) 3_665 .
O2 Tb1 N6 84.1(4) . .
O16 Tb1 N6 73.7(4) . .
O15 Tb1 N6 25.7(2) . .
O7 Tb1 N6 160.5(6) . .
O13 Tb1 N6 25.8(2) . .
O9 Tb1 N6 146.7(5) . .
O10 Tb1 N6 91.1(4) . .
O12 Tb1 N6 94.8(4) . .
O5 Tb1 N4 76.5(4) 3_665 .
O2 Tb1 N4 104.6(5) . .
O16 Tb1 N4 98.5(5) . .
O15 Tb1 N4 156.8(5) . .
O7 Tb1 N4 25.3(2) . .
O13 Tb1 N4 149.6(4) . .
O9 Tb1 N4 25.4(2) . .
O10 Tb1 N4 88.9(4) . .
O12 Tb1 N4 78.5(3) . .
N6 Tb1 N4 171.0(5) . .
C6 N1 C5 122.9(6) . .
C6 N1 H1A 118.5 . .
C5 N1 H1A 118.5 . .
C22 N2 C14 116.7(7) . .
C22 N2 C15 115.4(6) . .
C14 N2 C15 110.1(6) . .
C30 N3 C31 125.1(7) . .
C30 N3 H3A 117.5 . .
C31 N3 H3A 117.5 . .
O8 N4 O7 121.6(8) . .
O8 N4 O9 122.5(8) . .
O7 N4 O9 115.9(7) . .
O8 N4 Eu1 175.3(7) . .
O7 N4 Eu1 57.2(5) . .
O9 N4 Eu1 58.8(5) . .
O8 N4 Tb1 170.4(7) . .
O7 N4 Tb1 57.2(4) . .
O9 N4 Tb1 59.3(5) . .
Eu1 N4 Tb1 4.9(3) . .
O11 N5 O10 121.8(7) . .
O11 N5 O12 122.3(7) . .
O10 N5 O12 115.9(6) . .
O11 N5 Eu1 173.0(7) . .
O10 N5 Eu1 59.1(4) . .
O12 N5 Eu1 57.1(4) . .
O14 N6 O15 122.4(8) . .
O14 N6 O13 121.0(7) . .
O15 N6 O13 116.6(6) . .
O14 N6 Tb1 178.5(6) . .
O15 N6 Tb1 57.9(4) . .
O13 N6 Tb1 58.8(4) . .
O14 N6 Eu1 174.3(6) . .
O15 N6 Eu1 62.6(4) . .
O13 N6 Eu1 54.2(4) . .
Tb1 N6 Eu1 4.9(3) . .
C12 O3 C13 119.6(6) . .
C24 O4 C23 118.9(6) . .
C30 O5 Tb1 177.0(6) . 3_665
C30 O5 Eu1 176.0(6) . 3_665
Tb1 O5 Eu1 3.4(6) 3_665 3_665
N4 O7 Eu1 96.9(6) . .
N4 O7 Tb1 97.6(5) . .
Eu1 O7 Tb1 5.8(4) . .
N4 O9 Eu1 95.2(6) . .
N4 O9 Tb1 95.3(5) . .
Eu1 O9 Tb1 5.7(4) . .
N5 O10 Eu1 94.4(5) . .
N5 O10 Tb1 98.5(5) . .
Eu1 O10 Tb1 4.2(5) . .
N5 O12 Eu1 96.0(5) . .
N5 O12 Tb1 96.6(5) . .
Eu1 O12 Tb1 1.0(6) . .
N6 O13 Eu1 101.0(5) . .
N6 O13 Tb1 95.4(5) . .
Eu1 O13 Tb1 5.9(4) . .
N6 O15 Tb1 96.4(5) . .
N6 O15 Eu1 92.1(5) . .
Tb1 O15 Eu1 4.6(5) . .
C6 O2 Tb1 169.0(6) . .
C6 O2 Eu1 171.6(6) . .
Tb1 O2 Eu1 5.5(5) . .
C36 O16 Eu1 144.5(8) . .
C36 O16 Tb1 150.6(7) . .
Eu1 O16 Tb1 6.2(4) . .
C36 O16 H16 106.1 . .
Eu1 O16 H16 101.5 . .
Tb1 O16 H16 97.6 . .
C36 O16 H16' 107.0 . .
Eu1 O16 H16' 100.4 . .
Tb1 O16 H16' 96.5 . .
H16 O16 H16' 1.2 . .
O16 C36 C37 109.0(10) . .
O16 C36 H36A 109.9 . .
C37 C36 H36A 109.9 . .
O16 C36 H36B 109.9 . .
C37 C36 H36B 109.9 . .
H36A C36 H36B 108.3 . .
O16 C36 H37D 171.0 . .
C37 C36 H37D 71.6 . .
H36A C36 H37D 77.8 . .
H36B C36 H37D 62.2 . .
O16 C36 H37F 116.9 . .
C37 C36 H37F 32.0 . .
H36A C36 H37F 78.4 . .
H36B C36 H37F 127.0 . .
H37D C36 H37F 68.7 . .
C36 C37 H37E 109.5 . .
H37A C37 H37E 140.8 . .
H37B C37 H37E 52.1 . .
H37C C37 H37E 60.4 . .
C36 C37 H37F 75.8 . .
H37A C37 H37F 75.0 . .
H37B C37 H37F 61.2 . .
H37C C37 H37F 170.7 . .
H37E C37 H37F 110.9 . .
C37' C36' H36C 110.1 . .
C37' C36' H36D 110.1 . .
H36C C36' H36D 108.4 . .
C36' C37' H37D 85.0 . .
C36' C37' H37E 118.1 . .
H37D C37' H37E 109.6 . .
C36' C37' H37F 121.7 . .
H37D C37' H37F 109.5 . .
H37E C37' H37F 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C4 C3 1.340(11) .
C4 O1 1.365(9) .
C4 C5 1.480(11) .
C3 C2 1.441(12) .
C3 H3 0.9300 .
C2 C1 1.306(13) .
C2 H2 0.9300 .
C1 O1 1.359(11) .
C1 H1 0.9300 .
C16 C17 1.3900 .
C16 C21 1.3900 .
C16 C15 1.450(10) .
C17 C18 1.3900 .
C17 H17 0.9300 .
C18 C19 1.3900 .
C18 H18 0.9300 .
C19 C20 1.3900 .
C19 H19 0.9300 .
C20 C21 1.3900 .
C20 H20 0.9300 .
C21 H21 0.9300 .
C16' C21' 1.3886 .
C16' C17' 1.3906 .
C16' C15 1.616(10) .
C17' C18' 1.3887 .
C17' H17' 0.9300 .
C18' C19' 1.3886 .
C18' H18' 0.9300 .
C19' C20' 1.3907 .
C19' H19' 0.9300 .
C20' C21' 1.3889 .
C20' H20' 0.9300 .
C21' H21' 0.9300 .
O6A C32A 1.312(9) .
O6A C35A 1.314(9) .
C35A C34A 1.308(9) .
C35A H35A 0.9300 .
C34A C33A 1.318(9) .
C34A H34A 0.9300 .
C33A C32A 1.299(9) .
C33A H33A 0.9300 .
O6B C32B 1.303(9) .
O6B C35B 1.314(9) .
C35B C34B 1.309(9) .
C35B H35B 0.9300 .
C34B C33B 1.335(9) .
C34B H34B 0.9300 .
C33B C32B 1.309(9) .
C33B H33B 0.9300 .
C32B C31 1.469(14) .
C5 N1 1.458(9) .
C5 H5A 0.9700 .
C5 H5B 0.9700 .
C6 O2 1.237(8) .
C6 N1 1.321(9) .
C6 C7 1.509(10) .
C7 C12 1.385(10) .
C7 C8 1.397(10) .
C8 C9 1.370(11) .
C8 H8 0.9300 .
C9 C10 1.347(12) .
C9 H9 0.9300 .
C10 C11 1.354(12) .
C10 H10 0.9300 .
C11 C12 1.429(11) .
C11 H11 0.9300 .
C12 O3 1.338(9) .
C13 O3 1.450(9) .
C13 C14 1.469(11) .
C13 H13A 0.9700 .
C13 H13B 0.9700 .
C14 N2 1.445(9) .
C14 H14A 0.9700 .
C14 H14B 0.9700 .
C15 N2 1.466(10) .
C15 H15A 0.9700 .
C15 H15B 0.9700 .
C22 N2 1.442(9) .
C22 C23 1.500(10) .
C22 H22A 0.9700 .
C22 H22B 0.9700 .
C23 O4 1.428(8) .
C23 H23A 0.9700 .
C23 H23B 0.9700 .
C24 C25 1.381(10) .
C24 O4 1.383(8) .
C24 C29 1.394(9) .
C25 C26 1.371(10) .
C25 H25 0.9300 .
C26 C27 1.354(10) .
C26 H26 0.9300 .
C27 C28 1.396(10) .
C27 H27 0.9300 .
C28 C29 1.402(9) .
C28 H28 0.9300 .
C29 C30 1.494(9) .
C30 O5 1.242(8) .
C30 N3 1.316(9) .
C31 N3 1.456(9) .
C31 H31A 0.9700 .
C31 H31B 0.9700 .
Eu1 O16 2.335(14) .
Eu1 O12 2.362(10) .
Eu1 O2 2.380(12) .
Eu1 O10 2.408(13) .
Eu1 O5 2.417(11) 3_665
Eu1 O7 2.427(15) .
Eu1 O13 2.443(15) .
Eu1 O9 2.462(14) .
Eu1 O15 2.627(13) .
Eu1 N5 2.799(12) .
Eu1 N4 2.867(16) .
Eu1 H16 2.6402 .
Eu1 H16' 2.6396 .
Tb1 O5 2.198(11) 3_665
Tb1 O2 2.250(12) .
Tb1 O16 2.359(14) .
Tb1 O15 2.470(13) .
Tb1 O7 2.485(14) .
Tb1 O13 2.489(14) .
Tb1 O9 2.532(14) .
Tb1 O10 2.589(12) .
Tb1 O12 2.616(9) .
Tb1 N6 2.898(15) .
Tb1 N4 2.932(15) .
N1 H1A 0.8600 .
N3 H3A 0.8600 .
N4 O8 1.217(9) .
N4 O7 1.263(9) .
N4 O9 1.263(9) .
N5 O11 1.215(8) .
N5 O10 1.253(8) .
N5 O12 1.272(8) .
N6 O14 1.223(8) .
N6 O15 1.264(8) .
N6 O13 1.267(8) .
O5 Tb1 2.198(11) 3_665
O5 Eu1 2.417(11) 3_665
O16 C36 1.415(8) .
O16 H16 0.8517 .
O16 H16' 0.8801 .
C36 C37 1.499(10) .
C36 H36A 0.9700 .
C36 H36B 0.9700 .
C37 H37A 0.9600 .
C37 H37B 0.9600 .
C37 H37C 0.9600 .
C37 H37F 0.8329 .
C36' C37' 1.482(10) .
C36' H36C 0.9700 .
C36' H36D 0.9700 .
C37' H37D 0.9599 .
C37' H37E 0.9610 .
C37' H37F 0.9602 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O1 C4 C3 C2 0.3(9) . .
C5 C4 C3 C2 176.1(8) . .
C4 C3 C2 C1 0.9(11) . .
C3 C2 C1 O1 -1.8(12) . .
C21 C16 C17 C18 0.0 . .
C15 C16 C17 C18 -174.7(8) . .
C16 C17 C18 C19 0.0 . .
C17 C18 C19 C20 0.0 . .
C18 C19 C20 C21 0.0 . .
C19 C20 C21 C16 0.0 . .
C17 C16 C21 C20 0.0 . .
C15 C16 C21 C20 174.8(8) . .
C21' C16' C17' C18' 0.0 . .
C15 C16' C17' C18' 175.0(7) . .
C16' C17' C18' C19' 0.0 . .
C17' C18' C19' C20' 0.0 . .
C18' C19' C20' C21' 0.0 . .
C17' C16' C21' C20' 0.0 . .
C15 C16' C21' C20' -174.6(7) . .
C19' C20' C21' C16' 0.0 . .
C32A O6A C35A C34A -0.1(3) . .
O6A C35A C34A C33A -0.1(3) . .
C35A C34A C33A C32A 0.2(6) . .
C34A C33A C32A O6A -0.3(7) . .
C35A O6A C32A C33A 0.3(6) . .
C32B O6B C35B C34B 0.5(3) . .
O6B C35B C34B C33B 0.3(3) . .
C35B C34B C33B C32B -0.9(6) . .
C35B O6B C32B C33B -1.0(6) . .
C35B O6B C32B C31 177.9(16) . .
C34B C33B C32B O6B 1.2(7) . .
C34B C33B C32B C31 -177.6(17) . .
C2 C1 O1 C4 2.1(11) . .
C3 C4 O1 C1 -1.4(9) . .
C5 C4 O1 C1 -178.0(7) . .
C3 C4 C5 N1 125.6(9) . .
O1 C4 C5 N1 -58.9(9) . .
O2 C6 C7 C12 167.3(6) . .
N1 C6 C7 C12 -13.9(10) . .
O2 C6 C7 C8 -11.6(9) . .
N1 C6 C7 C8 167.2(6) . .
C12 C7 C8 C9 0.8(11) . .
C6 C7 C8 C9 179.8(7) . .
C7 C8 C9 C10 -2.6(12) . .
C8 C9 C10 C11 2.5(13) . .
C9 C10 C11 C12 -0.7(12) . .
C8 C7 C12 O3 179.9(6) . .
C6 C7 C12 O3 1.0(10) . .
C8 C7 C12 C11 1.0(10) . .
C6 C7 C12 C11 -177.9(6) . .
C10 C11 C12 O3 -179.9(7) . .
C10 C11 C12 C7 -1.1(11) . .
O3 C13 C14 N2 53.2(10) . .
C17 C16 C15 N2 117.4(8) . .
C21 C16 C15 N2 -57.3(10) . .
C17 C16 C15 C16' 134.9(6) . .
C21 C16 C15 C16' -39.8(3) . .
C21' C16' C15 C16 123.1(4) . .
C17' C16' C15 C16 -51.6(7) . .
C21' C16' C15 N2 -72.7(8) . .
C17' C16' C15 N2 112.6(6) . .
N2 C22 C23 O4 -177.0(7) . .
O4 C24 C25 C26 178.0(7) . .
C29 C24 C25 C26 -2.7(11) . .
C24 C25 C26 C27 2.2(12) . .
C25 C26 C27 C28 -1.4(12) . .
C26 C27 C28 C29 1.3(11) . .
C25 C24 C29 C28 2.5(10) . .
O4 C24 C29 C28 -178.2(6) . .
C25 C24 C29 C30 -178.1(7) . .
O4 C24 C29 C30 1.3(10) . .
C27 C28 C29 C24 -1.8(10) . .
C27 C28 C29 C30 178.7(7) . .
C24 C29 C30 O5 -168.0(7) . .
C28 C29 C30 O5 11.4(10) . .
C24 C29 C30 N3 16.1(10) . .
C28 C29 C30 N3 -164.5(7) . .
O6B C32B C31 N3 -116.3(13) . .
C33B C32B C31 N3 62.4(17) . .
O2 C6 N1 C5 -3.1(11) . .
C7 C6 N1 C5 178.1(7) . .
C4 C5 N1 C6 135.4(7) . .
C23 C22 N2 C14 -92.1(9) . .
C23 C22 N2 C15 136.2(8) . .
C13 C14 N2 C22 64.1(10) . .
C13 C14 N2 C15 -161.8(7) . .
C16 C15 N2 C22 80.5(10) . .
C16' C15 N2 C22 76.9(8) . .
C16 C15 N2 C14 -54.3(10) . .
C16' C15 N2 C14 -57.9(9) . .
O5 C30 N3 C31 1.7(12) . .
C29 C30 N3 C31 177.6(7) . .
C32B C31 N3 C30 120.5(11) . .
O16 Eu1 N4 O8 106(9) . .
O12 Eu1 N4 O8 -176(9) . .
O2 Eu1 N4 O8 -47(9) . .
O10 Eu1 N4 O8 -124(9) . .
O5 Eu1 N4 O8 24(9) 3_665 .
O7 Eu1 N4 O8 -77(9) . .
O13 Eu1 N4 O8 -164(8) . .
O9 Eu1 N4 O8 106(9) . .
O15 Eu1 N4 O8 35(10) . .
N5 Eu1 N4 O8 -150(9) . .
O16 Eu1 N4 O7 -177.1(6) . .
O12 Eu1 N4 O7 -99.6(6) . .
O2 Eu1 N4 O7 29.9(5) . .
O10 Eu1 N4 O7 -47.2(5) . .
O5 Eu1 N4 O7 101.2(5) 3_665 .
O13 Eu1 N4 O7 -87.1(18) . .
O9 Eu1 N4 O7 -176.8(8) . .
O15 Eu1 N4 O7 111.8(11) . .
N5 Eu1 N4 O7 -73.5(5) . .
O16 Eu1 N4 O9 -0.3(6) . .
O12 Eu1 N4 O9 77.2(6) . .
O2 Eu1 N4 O9 -153.3(7) . .
O10 Eu1 N4 O9 129.6(6) . .
O5 Eu1 N4 O9 -82.0(6) 3_665 .
O7 Eu1 N4 O9 176.8(8) . .
O13 Eu1 N4 O9 89.7(18) . .
O15 Eu1 N4 O9 -71.4(11) . .
N5 Eu1 N4 O9 103.3(6) . .
O16 Eu1 N4 Tb1 95(6) . .
O12 Eu1 N4 Tb1 172(6) . .
O2 Eu1 N4 Tb1 -58(6) . .
O10 Eu1 N4 Tb1 -135(6) . .
O5 Eu1 N4 Tb1 13(6) 3_665 .
O7 Eu1 N4 Tb1 -88(6) . .
O13 Eu1 N4 Tb1 -175(8) . .
O9 Eu1 N4 Tb1 95(6) . .
O15 Eu1 N4 Tb1 24(5) . .
N5 Eu1 N4 Tb1 -162(6) . .
O5 Tb1 N4 O8 20(5) 3_665 .
O2 Tb1 N4 O8 -59(5) . .
O16 Tb1 N4 O8 107(4) . .
O15 Tb1 N4 O8 40(5) . .
O7 Tb1 N4 O8 -86(4) . .
O13 Tb1 N4 O8 -171(4) . .
O9 Tb1 N4 O8 104(5) . .
O10 Tb1 N4 O8 -134(4) . .
O12 Tb1 N4 O8 178(4) . .
N6 Tb1 N4 O8 136(4) . .
O5 Tb1 N4 O7 105.5(6) 3_665 .
O2 Tb1 N4 O7 26.4(5) . .
O16 Tb1 N4 O7 -167.0(6) . .
O15 Tb1 N4 O7 125.6(13) . .
O13 Tb1 N4 O7 -85.6(12) . .
O9 Tb1 N4 O7 -170.7(8) . .
O10 Tb1 N4 O7 -48.0(5) . .
O12 Tb1 N4 O7 -95.8(5) . .
N6 Tb1 N4 O7 -138(3) . .
O5 Tb1 N4 O9 -83.8(6) 3_665 .
O2 Tb1 N4 O9 -162.9(6) . .
O16 Tb1 N4 O9 3.7(6) . .
O15 Tb1 N4 O9 -63.7(14) . .
O7 Tb1 N4 O9 170.7(8) . .
O13 Tb1 N4 O9 85.1(12) . .
O10 Tb1 N4 O9 122.7(6) . .
O12 Tb1 N4 O9 74.9(6) . .
N6 Tb1 N4 O9 33(3) . .
O5 Tb1 N4 Eu1 -166(6) 3_665 .
O2 Tb1 N4 Eu1 115(6) . .
O16 Tb1 N4 Eu1 -78(6) . .
O15 Tb1 N4 Eu1 -146(7) . .
O7 Tb1 N4 Eu1 89(6) . .
O13 Tb1 N4 Eu1 3(5) . .
O9 Tb1 N4 Eu1 -82(6) . .
O10 Tb1 N4 Eu1 41(6) . .
O12 Tb1 N4 Eu1 -7(6) . .
N6 Tb1 N4 Eu1 -49(4) . .
O16 Eu1 N5 O11 -61(6) . .
O12 Eu1 N5 O11 -87(6) . .
O2 Eu1 N5 O11 94(6) . .
O10 Eu1 N5 O11 99(6) . .
O5 Eu1 N5 O11 178(5) 3_665 .
O7 Eu1 N5 O11 172(6) . .
O13 Eu1 N5 O11 13(6) . .
O9 Eu1 N5 O11 -137(6) . .
O15 Eu1 N5 O11 14(6) . .
N4 Eu1 N5 O11 -163(6) . .
O16 Eu1 N5 O10 -160.5(7) . .
O12 Eu1 N5 O10 173.7(8) . .
O2 Eu1 N5 O10 -5.4(5) . .
O5 Eu1 N5 O10 79(2) 3_665 .
O7 Eu1 N5 O10 73.2(5) . .
O13 Eu1 N5 O10 -86.6(5) . .
O9 Eu1 N5 O10 123.6(6) . .
O15 Eu1 N5 O10 -85.0(6) . .
N4 Eu1 N5 O10 98.2(6) . .
O16 Eu1 N5 O12 25.8(5) . .
O2 Eu1 N5 O12 -179.1(7) . .
O10 Eu1 N5 O12 -173.7(8) . .
O5 Eu1 N5 O12 -95(2) 3_665 .
O7 Eu1 N5 O12 -100.5(6) . .
O13 Eu1 N5 O12 99.6(6) . .
O9 Eu1 N5 O12 -50.1(5) . .
O15 Eu1 N5 O12 101.2(7) . .
N4 Eu1 N5 O12 -75.5(5) . .
O5 Tb1 N6 O14 99(26) 3_665 .
O2 Tb1 N6 O14 -180(100) . .
O16 Tb1 N6 O14 15(26) . .
O15 Tb1 N6 O14 101(26) . .
O7 Tb1 N6 O14 -136(26) . .
O13 Tb1 N6 O14 -82(26) . .
O9 Tb1 N6 O14 10(27) . .
O10 Tb1 N6 O14 -105(26) . .
O12 Tb1 N6 O14 -56(27) . .
N4 Tb1 N6 O14 -15(28) . .
O5 Tb1 N6 O15 -1.4(5) 3_665 .
O2 Tb1 N6 O15 79.5(5) . .
O16 Tb1 N6 O15 -85.7(5) . .
O7 Tb1 N6 O15 123.3(12) . .
O13 Tb1 N6 O15 177.4(7) . .
O9 Tb1 N6 O15 -90.6(9) . .
O10 Tb1 N6 O15 154.6(6) . .
O12 Tb1 N6 O15 -157.0(6) . .
N4 Tb1 N6 O15 -116(3) . .
O5 Tb1 N6 O13 -178.8(7) 3_665 .
O2 Tb1 N6 O13 -97.9(5) . .
O16 Tb1 N6 O13 97.0(5) . .
O15 Tb1 N6 O13 -177.4(7) . .
O7 Tb1 N6 O13 -54.0(12) . .
O9 Tb1 N6 O13 92.0(8) . .
O10 Tb1 N6 O13 -22.8(4) . .
O12 Tb1 N6 O13 25.7(5) . .
N4 Tb1 N6 O13 67(3) . .
O5 Tb1 N6 Eu1 162(6) 3_665 .
O2 Tb1 N6 Eu1 -117(6) . .
O16 Tb1 N6 Eu1 78(6) . .
O15 Tb1 N6 Eu1 163(6) . .
O7 Tb1 N6 Eu1 -73(6) . .
O13 Tb1 N6 Eu1 -19(6) . .
O9 Tb1 N6 Eu1 73(6) . .
O10 Tb1 N6 Eu1 -42(6) . .
O12 Tb1 N6 Eu1 6(6) . .
N4 Tb1 N6 Eu1 48(4) . .
O16 Eu1 N6 O14 69(6) . .
O12 Eu1 N6 O14 -6(6) . .
O2 Eu1 N6 O14 -135(6) . .
O10 Eu1 N6 O14 -60(6) . .
O5 Eu1 N6 O14 151(6) 3_665 .
O7 Eu1 N6 O14 -118(6) . .
O13 Eu1 N6 O14 -34(6) . .
O9 Eu1 N6 O14 77(6) . .
O15 Eu1 N6 O14 151(6) . .
N5 Eu1 N6 O14 -33(6) . .
N4 Eu1 N6 O14 106(6) . .
O16 Eu1 N6 O15 -81.6(5) . .
O12 Eu1 N6 O15 -157.0(6) . .
O2 Eu1 N6 O15 73.9(4) . .
O10 Eu1 N6 O15 149.6(6) . .
O5 Eu1 N6 O15 0.0(5) 3_665 .
O7 Eu1 N6 O15 91.1(13) . .
O13 Eu1 N6 O15 175.5(7) . .
O9 Eu1 N6 O15 -73.5(9) . .
N5 Eu1 N6 O15 176.2(6) . .
N4 Eu1 N6 O15 -45(3) . .
O16 Eu1 N6 O13 102.9(5) . .
O12 Eu1 N6 O13 27.5(5) . .
O2 Eu1 N6 O13 -101.6(6) . .
O10 Eu1 N6 O13 -25.8(5) . .
O5 Eu1 N6 O13 -175.5(7) 3_665 .
O7 Eu1 N6 O13 -84.4(14) . .
O9 Eu1 N6 O13 111.1(9) . .
O15 Eu1 N6 O13 -175.5(7) . .
N5 Eu1 N6 O13 0.7(5) . .
N4 Eu1 N6 O13 139(3) . .
O16 Eu1 N6 Tb1 -98(6) . .
O12 Eu1 N6 Tb1 -173(6) . .
O2 Eu1 N6 Tb1 58(6) . .
O10 Eu1 N6 Tb1 134(6) . .
O5 Eu1 N6 Tb1 -16(6) 3_665 .
O7 Eu1 N6 Tb1 75(5) . .
O13 Eu1 N6 Tb1 159(6) . .
O9 Eu1 N6 Tb1 -89(6) . .
O15 Eu1 N6 Tb1 -16(6) . .
N5 Eu1 N6 Tb1 160(6) . .
N4 Eu1 N6 Tb1 -61(5) . .
C7 C12 O3 C13 164.0(6) . .
C11 C12 O3 C13 -17.2(10) . .
C14 C13 O3 C12 -151.5(7) . .
C25 C24 O4 C23 -3.6(11) . .
C29 C24 O4 C23 177.1(7) . .
C22 C23 O4 C24 -161.7(7) . .
N3 C30 O5 Tb1 148(11) . 3_665
C29 C30 O5 Tb1 -28(12) . 3_665
N3 C30 O5 Eu1 -157(8) . 3_665
C29 C30 O5 Eu1 27(9) . 3_665
O8 N4 O7 Eu1 174.6(8) . .
O9 N4 O7 Eu1 -3.0(8) . .
Tb1 N4 O7 Eu1 5.9(4) . .
O8 N4 O7 Tb1 168.8(8) . .
O9 N4 O7 Tb1 -8.9(8) . .
Eu1 N4 O7 Tb1 -5.9(4) . .
O16 Eu1 O7 N4 3.6(7) . .
O12 Eu1 O7 N4 78.7(6) . .
O2 Eu1 O7 N4 -150.5(5) . .
O10 Eu1 O7 N4 131.2(5) . .
O5 Eu1 O7 N4 -73.4(5) 3_665 .
O13 Eu1 O7 N4 141.9(8) . .
O9 Eu1 O7 N4 1.8(5) . .
O15 Eu1 O7 N4 -112.7(12) . .
N5 Eu1 O7 N4 105.1(5) . .
O16 Eu1 O7 Tb1 101(6) . .
O12 Eu1 O7 Tb1 176(6) . .
O2 Eu1 O7 Tb1 -53(6) . .
O10 Eu1 O7 Tb1 -132(6) . .
O5 Eu1 O7 Tb1 24(6) 3_665 .
O13 Eu1 O7 Tb1 -121(6) . .
O9 Eu1 O7 Tb1 99(6) . .
O15 Eu1 O7 Tb1 -16(5) . .
N5 Eu1 O7 Tb1 -158(6) . .
N4 Eu1 O7 Tb1 97(6) . .
O5 Tb1 O7 N4 -70.3(5) 3_665 .
O2 Tb1 O7 N4 -154.2(5) . .
O16 Tb1 O7 N4 15.4(7) . .
O15 Tb1 O7 N4 -120.1(16) . .
O13 Tb1 O7 N4 128.7(8) . .
O9 Tb1 O7 N4 5.2(5) . .
O10 Tb1 O7 N4 128.8(5) . .
O12 Tb1 O7 N4 79.9(5) . .
N6 Tb1 O7 N4 161.7(11) . .
O5 Tb1 O7 Eu1 -154(6) 3_665 .
O2 Tb1 O7 Eu1 122(6) . .
O16 Tb1 O7 Eu1 -68(6) . .
O15 Tb1 O7 Eu1 156(7) . .
O13 Tb1 O7 Eu1 45(5) . .
O9 Tb1 O7 Eu1 -79(6) . .
O10 Tb1 O7 Eu1 45(6) . .
O12 Tb1 O7 Eu1 -4(6) . .
N6 Tb1 O7 Eu1 78(6) . .
N4 Tb1 O7 Eu1 -84(6) . .
O8 N4 O9 Eu1 -174.7(8) . .
O7 N4 O9 Eu1 3.0(8) . .
Tb1 N4 O9 Eu1 -5.7(4) . .
O8 N4 O9 Tb1 -169.0(8) . .
O7 N4 O9 Tb1 8.7(8) . .
Eu1 N4 O9 Tb1 5.7(4) . .
O16 Eu1 O9 N4 179.7(6) . .
O12 Eu1 O9 N4 -98.9(6) . .
O2 Eu1 O9 N4 32.7(8) . .
O10 Eu1 O9 N4 -54.9(7) . .
O5 Eu1 O9 N4 90.3(6) 3_665 .
O7 Eu1 O9 N4 -1.8(5) . .
O13 Eu1 O9 N4 -141.1(10) . .
O15 Eu1 O9 N4 136.9(7) . .
N5 Eu1 O9 N4 -78.2(6) . .
O16 Eu1 O9 Tb1 89(6) . .
O12 Eu1 O9 Tb1 170(6) . .
O2 Eu1 O9 Tb1 -58(6) . .
O10 Eu1 O9 Tb1 -146(6) . .
O5 Eu1 O9 Tb1 -1(6) 3_665 .
O7 Eu1 O9 Tb1 -93(6) . .
O13 Eu1 O9 Tb1 128(7) . .
O15 Eu1 O9 Tb1 46(6) . .
N5 Eu1 O9 Tb1 -169(6) . .
N4 Eu1 O9 Tb1 -91(6) . .
O5 Tb1 O9 N4 89.7(6) 3_665 .
O2 Tb1 O9 N4 21.4(8) . .
O16 Tb1 O9 N4 -176.1(6) . .
O15 Tb1 O9 N4 147.4(7) . .
O7 Tb1 O9 N4 -5.1(5) . .
O13 Tb1 O9 N4 -129.1(9) . .
O10 Tb1 O9 N4 -59.5(6) . .
O12 Tb1 O9 N4 -98.7(6) . .
N6 Tb1 O9 N4 -171.2(8) . .
O5 Tb1 O9 Eu1 179(6) 3_665 .
O2 Tb1 O9 Eu1 111(6) . .
O16 Tb1 O9 Eu1 -86(6) . .
O15 Tb1 O9 Eu1 -123(7) . .
O7 Tb1 O9 Eu1 85(6) . .
O13 Tb1 O9 Eu1 -39(6) . .
O10 Tb1 O9 Eu1 30(6) . .
O12 Tb1 O9 Eu1 -9(6) . .
N6 Tb1 O9 Eu1 -81(6) . .
N4 Tb1 O9 Eu1 90(6) . .
O11 N5 O10 Eu1 -171.8(8) . .
O12 N5 O10 Eu1 5.9(7) . .
O11 N5 O10 Tb1 -170.9(7) . .
O12 N5 O10 Tb1 6.8(7) . .
Eu1 N5 O10 Tb1 1.0(6) . .
O16 Eu1 O10 N5 24.3(8) . .
O12 Eu1 O10 N5 -3.5(5) . .
O2 Eu1 O10 N5 174.6(5) . .
O5 Eu1 O10 N5 -151.0(11) 3_665 .
O7 Eu1 O10 N5 -102.2(5) . .
O13 Eu1 O10 N5 83.9(5) . .
O9 Eu1 O10 N5 -61.8(6) . .
O15 Eu1 O10 N5 108.9(6) . .
N4 Eu1 O10 N5 -82.9(5) . .
O16 Eu1 O10 Tb1 -142(9) . .
O12 Eu1 O10 Tb1 -170(9) . .
O2 Eu1 O10 Tb1 8(8) . .
O5 Eu1 O10 Tb1 42(8) 3_665 .
O7 Eu1 O10 Tb1 91(9) . .
O13 Eu1 O10 Tb1 -83(9) . .
O9 Eu1 O10 Tb1 132(9) . .
O15 Eu1 O10 Tb1 -58(8) . .
N5 Eu1 O10 Tb1 -166(9) . .
N4 Eu1 O10 Tb1 111(9) . .
O5 Tb1 O10 N5 -139.6(11) 3_665 .
O2 Tb1 O10 N5 175.0(5) . .
O16 Tb1 O10 N5 19.5(7) . .
O15 Tb1 O10 N5 103.2(6) . .
O7 Tb1 O10 N5 -99.0(5) . .
O13 Tb1 O10 N5 80.9(5) . .
O9 Tb1 O10 N5 -57.9(6) . .
O12 Tb1 O10 N5 -4.0(4) . .
N6 Tb1 O10 N5 91.4(5) . .
N4 Tb1 O10 N5 -79.6(5) . .
O5 Tb1 O10 Eu1 -126(9) 3_665 .
O2 Tb1 O10 Eu1 -171(9) . .
O16 Tb1 O10 Eu1 33(8) . .
O15 Tb1 O10 Eu1 117(9) . .
O7 Tb1 O10 Eu1 -85(9) . .
O13 Tb1 O10 Eu1 94(9) . .
O9 Tb1 O10 Eu1 -44(8) . .
O12 Tb1 O10 Eu1 10(9) . .
N6 Tb1 O10 Eu1 105(9) . .
N4 Tb1 O10 Eu1 -66(9) . .
O11 N5 O12 Eu1 171.7(8) . .
O10 N5 O12 Eu1 -6.0(8) . .
O11 N5 O12 Tb1 170.9(8) . .
O10 N5 O12 Tb1 -6.8(7) . .
Eu1 N5 O12 Tb1 -0.8(6) . .
O16 Eu1 O12 N5 -154.4(5) . .
O2 Eu1 O12 N5 1.1(9) . .
O10 Eu1 O12 N5 3.5(4) . .
O5 Eu1 O12 N5 147.1(13) 3_665 .
O7 Eu1 O12 N5 77.6(6) . .
O13 Eu1 O12 N5 -72.5(5) . .
O9 Eu1 O12 N5 129.0(5) . .
O15 Eu1 O12 N5 -95.4(7) . .
N4 Eu1 O12 N5 103.2(5) . .
O16 Eu1 O12 Tb1 -27(37) . .
O2 Eu1 O12 Tb1 129(38) . .
O10 Eu1 O12 Tb1 131(38) . .
O5 Eu1 O12 Tb1 -85(38) 3_665 .
O7 Eu1 O12 Tb1 -155(38) . .
O13 Eu1 O12 Tb1 55(38) . .
O9 Eu1 O12 Tb1 -103(38) . .
O15 Eu1 O12 Tb1 32(37) . .
N5 Eu1 O12 Tb1 128(38) . .
N4 Eu1 O12 Tb1 -129(38) . .
O5 Tb1 O12 N5 143.6(11) 3_665 .
O2 Tb1 O12 N5 2.7(8) . .
O16 Tb1 O12 N5 -154.7(5) . .
O15 Tb1 O12 N5 -94.4(7) . .
O7 Tb1 O12 N5 77.3(5) . .
O13 Tb1 O12 N5 -71.9(5) . .
O9 Tb1 O12 N5 128.4(5) . .
O10 Tb1 O12 N5 3.9(4) . .
N6 Tb1 O12 N5 -83.3(5) . .
N4 Tb1 O12 N5 102.7(5) . .
O5 Tb1 O12 Eu1 91(38) 3_665 .
O2 Tb1 O12 Eu1 -49(37) . .
O16 Tb1 O12 Eu1 153(38) . .
O15 Tb1 O12 Eu1 -147(38) . .
O7 Tb1 O12 Eu1 25(38) . .
O13 Tb1 O12 Eu1 -124(38) . .
O9 Tb1 O12 Eu1 76(38) . .
O10 Tb1 O12 Eu1 -48(38) . .
N6 Tb1 O12 Eu1 -136(38) . .
N4 Tb1 O12 Eu1 51(38) . .
O14 N6 O13 Eu1 176.3(6) . .
O15 N6 O13 Eu1 -4.5(7) . .
Tb1 N6 O13 Eu1 -2.0(6) . .
O14 N6 O13 Tb1 178.3(7) . .
O15 N6 O13 Tb1 -2.5(7) . .
Eu1 N6 O13 Tb1 2.0(6) . .
O16 Eu1 O13 N6 -71.2(5) . .
O12 Eu1 O13 N6 -152.1(5) . .
O2 Eu1 O13 N6 75.6(5) . .
O10 Eu1 O13 N6 152.6(5) . .
O5 Eu1 O13 N6 5.4(8) 3_665 .
O7 Eu1 O13 N6 141.6(8) . .
O9 Eu1 O13 N6 -109.5(10) . .
O15 Eu1 O13 N6 2.5(4) . .
N5 Eu1 O13 N6 -179.3(5) . .
N4 Eu1 O13 N6 -164.8(17) . .
O16 Eu1 O13 Tb1 -91(6) . .
O12 Eu1 O13 Tb1 -172(6) . .
O2 Eu1 O13 Tb1 56(6) . .
O10 Eu1 O13 Tb1 133(6) . .
O5 Eu1 O13 Tb1 -14(5) 3_665 .
O7 Eu1 O13 Tb1 122(6) . .
O9 Eu1 O13 Tb1 -129(7) . .
O15 Eu1 O13 Tb1 -17(6) . .
N5 Eu1 O13 Tb1 161(6) . .
N4 Eu1 O13 Tb1 175(8) . .
O5 Tb1 O13 N6 1.6(9) 3_665 .
O2 Tb1 O13 N6 80.4(5) . .
O16 Tb1 O13 N6 -76.6(5) . .
O15 Tb1 O13 N6 1.5(4) . .
O7 Tb1 O13 N6 155.3(7) . .
O9 Tb1 O13 N6 -122.3(8) . .
O10 Tb1 O13 N6 155.2(5) . .
O12 Tb1 O13 N6 -152.9(5) . .
N4 Tb1 O13 N6 -163.5(10) . .
O5 Tb1 O13 Eu1 162(7) 3_665 .
O2 Tb1 O13 Eu1 -119(6) . .
O16 Tb1 O13 Eu1 84(6) . .
O15 Tb1 O13 Eu1 162(6) . .
O7 Tb1 O13 Eu1 -44(5) . .
O9 Tb1 O13 Eu1 38(5) . .
O10 Tb1 O13 Eu1 -44(6) . .
O12 Tb1 O13 Eu1 7(6) . .
N6 Tb1 O13 Eu1 160(6) . .
N4 Tb1 O13 Eu1 -3(5) . .
O14 N6 O15 Tb1 -178.3(7) . .
O13 N6 O15 Tb1 2.5(7) . .
Eu1 N6 O15 Tb1 -1.6(6) . .
O14 N6 O15 Eu1 -176.7(7) . .
O13 N6 O15 Eu1 4.1(7) . .
Tb1 N6 O15 Eu1 1.6(6) . .
O5 Tb1 O15 N6 178.6(5) 3_665 .
O2 Tb1 O15 N6 -96.9(5) . .
O16 Tb1 O15 N6 86.6(5) . .
O7 Tb1 O15 N6 -131.1(16) . .
O13 Tb1 O15 N6 -1.5(4) . .
O9 Tb1 O15 N6 123.0(7) . .
O10 Tb1 O15 N6 -28.1(6) . .
O12 Tb1 O15 N6 26.3(7) . .
N4 Tb1 O15 N6 159.0(12) . .
O5 Tb1 O15 Eu1 158(8) 3_665 .
O2 Tb1 O15 Eu1 -117(7) . .
O16 Tb1 O15 Eu1 66(7) . .
O7 Tb1 O15 Eu1 -152(9) . .
O13 Tb1 O15 Eu1 -22(7) . .
O9 Tb1 O15 Eu1 103(7) . .
O10 Tb1 O15 Eu1 -48(7) . .
O12 Tb1 O15 Eu1 6(7) . .
N6 Tb1 O15 Eu1 -20(7) . .
N4 Tb1 O15 Eu1 139(8) . .
O16 Eu1 O15 N6 90.0(5) . .
O12 Eu1 O15 N6 27.0(7) . .
O2 Eu1 O15 N6 -100.6(5) . .
O10 Eu1 O15 N6 -33.8(6) . .
O5 Eu1 O15 N6 -180.0(5) 3_665 .
O7 Eu1 O15 N6 -139.5(11) . .
O13 Eu1 O15 N6 -2.5(4) . .
O9 Eu1 O15 N6 134.0(7) . .
N5 Eu1 O15 N6 -4.4(7) . .
N4 Eu1 O15 N6 169.4(10) . .
O16 Eu1 O15 Tb1 -110(7) . .
O12 Eu1 O15 Tb1 -173(8) . .
O2 Eu1 O15 Tb1 59(7) . .
O10 Eu1 O15 Tb1 126(8) . .
O5 Eu1 O15 Tb1 -20(7) 3_665 .
O7 Eu1 O15 Tb1 20(6) . .
O13 Eu1 O15 Tb1 157(7) . .
O9 Eu1 O15 Tb1 -66(7) . .
N5 Eu1 O15 Tb1 155(8) . .
N4 Eu1 O15 Tb1 -31(7) . .
N1 C6 O2 Tb1 -103(3) . .
C7 C6 O2 Tb1 76(3) . .
N1 C6 O2 Eu1 -74(4) . .
C7 C6 O2 Eu1 105(4) . .
O5 Tb1 O2 C6 -21(3) 3_665 .
O16 Tb1 O2 C6 -96(3) . .
O15 Tb1 O2 C6 -104(3) . .
O7 Tb1 O2 C6 64(3) . .
O13 Tb1 O2 C6 -155(3) . .
O9 Tb1 O2 C6 44(3) . .
O10 Tb1 O2 C6 138(3) . .
O12 Tb1 O2 C6 139(3) . .
N6 Tb1 O2 C6 -129(3) . .
N4 Tb1 O2 C6 53(3) . .
O5 Tb1 O2 Eu1 -152(7) 3_665 .
O16 Tb1 O2 Eu1 132(8) . .
O15 Tb1 O2 Eu1 125(7) . .
O7 Tb1 O2 Eu1 -67(7) . .
O13 Tb1 O2 Eu1 74(7) . .
O9 Tb1 O2 Eu1 -88(7) . .
O10 Tb1 O2 Eu1 7(7) . .
O12 Tb1 O2 Eu1 8(7) . .
N6 Tb1 O2 Eu1 99(7) . .
N4 Tb1 O2 Eu1 -78(7) . .
O16 Eu1 O2 C6 -112(4) . .
O12 Eu1 O2 C6 111(4) . .
O10 Eu1 O2 C6 109(4) . .
O5 Eu1 O2 C6 -52(4) 3_665 .
O7 Eu1 O2 C6 31(4) . .
O13 Eu1 O2 C6 -179(100) . .
O9 Eu1 O2 C6 4(4) . .
O15 Eu1 O2 C6 -130(4) . .
N5 Eu1 O2 C6 112(4) . .
N4 Eu1 O2 C6 18(4) . .
O16 Eu1 O2 Tb1 -35(6) . .
O12 Eu1 O2 Tb1 -171(8) . .
O10 Eu1 O2 Tb1 -173(7) . .
O5 Eu1 O2 Tb1 26(7) 3_665 .
O7 Eu1 O2 Tb1 109(7) . .
O13 Eu1 O2 Tb1 -101(7) . .
O9 Eu1 O2 Tb1 82(7) . .
O15 Eu1 O2 Tb1 -52(7) . .
N5 Eu1 O2 Tb1 -170(8) . .
N4 Eu1 O2 Tb1 96(7) . .
O12 Eu1 O16 C36 -16.3(17) . .
O2 Eu1 O16 C36 -163.5(16) . .
O10 Eu1 O16 C36 -38.7(19) . .
O5 Eu1 O16 C36 138.7(16) 3_665 .
O7 Eu1 O16 C36 63.7(18) . .
O13 Eu1 O16 C36 -94.8(16) . .
O9 Eu1 O16 C36 65.2(16) . .
O15 Eu1 O16 C36 -146.0(16) . .
N5 Eu1 O16 C36 -27.9(18) . .
N4 Eu1 O16 C36 65.3(17) . .
O12 Eu1 O16 Tb1 176(6) . .
O2 Eu1 O16 Tb1 28(5) . .
O10 Eu1 O16 Tb1 153(7) . .
O5 Eu1 O16 Tb1 -29(6) 3_665 .
O7 Eu1 O16 Tb1 -104(6) . .
O13 Eu1 O16 Tb1 97(6) . .
O9 Eu1 O16 Tb1 -103(6) . .
O15 Eu1 O16 Tb1 46(6) . .
N5 Eu1 O16 Tb1 164(6) . .
N4 Eu1 O16 Tb1 -103(6) . .
O5 Tb1 O16 C36 133.4(19) 3_665 .
O2 Tb1 O16 C36 -152.9(19) . .
O15 Tb1 O16 C36 -145.2(19) . .
O7 Tb1 O16 C36 50(2) . .
O13 Tb1 O16 C36 -92(2) . .
O9 Tb1 O16 C36 59(2) . .
O10 Tb1 O16 C36 -36(2) . .
O12 Tb1 O16 C36 -18(2) . .
N6 Tb1 O16 C36 -118.4(19) . .
N4 Tb1 O16 C36 57(2) . .
O5 Tb1 O16 Eu1 148(6) 3_665 .
O2 Tb1 O16 Eu1 -139(7) . .
O15 Tb1 O16 Eu1 -131(6) . .
O7 Tb1 O16 Eu1 65(6) . .
O13 Tb1 O16 Eu1 -78(6) . .
O9 Tb1 O16 Eu1 73(6) . .
O10 Tb1 O16 Eu1 -22(6) . .
O12 Tb1 O16 Eu1 -4(6) . .
N6 Tb1 O16 Eu1 -104(6) . .
N4 Tb1 O16 Eu1 71(6) . .
Eu1 O16 C36 C37 156.1(13) . .
Tb1 O16 C36 C37 158.8(14) . .
