#------------------------------------------------------------------------------
#$Date: 2016-03-23 22:16:12 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179474 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/71/4337136.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4337136
loop_
_publ_author_name
'Smart, Katharine A.'
'Grellier, Mary'
'Coppel, Yannick'
'Vendier, Laure'
'Mason, Sax A.'
'Capelli, Silvia C.'
'Albinati, Alberto'
'Montiel-Palma, Virginia'
'Muñoz-Hernández, Miguel A'
'Sabo-Etienne, Sylviane'
_publ_section_title
;
 Nature of si-h interactions in a series of ruthenium silazane complexes
 using multinuclear solid-state NMR and neutron diffraction.
;
_journal_issue                   2
_journal_name_full               'Inorganic chemistry'
_journal_page_first              1156
_journal_page_last               1165
_journal_paper_doi               10.1021/ic4027199
_journal_volume                  53
_journal_year                    2014
_chemical_formula_moiety         'C27 H34 N6 Ru Si3, 0.5(C6H14)'
_chemical_formula_sum            'C30 H41 N6 Ru Si3'
_chemical_formula_weight         671.03
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                95.782(2)
_cell_angle_beta                 98.830(2)
_cell_angle_gamma                105.106(2)
_cell_formula_units_Z            2
_cell_length_a                   9.4948(13)
_cell_length_b                   9.6324(13)
_cell_length_c                   18.339(2)
_cell_measurement_temperature    173(2)
_cell_volume                     1582.6(4)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0341
_diffrn_reflns_av_sigmaI/netI    0.0406
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            15429
_diffrn_reflns_theta_full        25.05
_diffrn_reflns_theta_max         25.05
_diffrn_reflns_theta_min         1.14
_exptl_absorpt_coefficient_mu    0.639
_exptl_absorpt_correction_T_max  0.9330
_exptl_absorpt_correction_T_min  0.8882
_exptl_absorpt_correction_type   numerical
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.408
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       rectangular
_exptl_crystal_F_000             698
_exptl_crystal_size_max          0.19
_exptl_crystal_size_mid          0.14
_exptl_crystal_size_min          0.11
_refine_diff_density_max         0.983
_refine_diff_density_min         -0.304
_refine_diff_density_rms         0.075
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.048
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     371
_refine_ls_number_reflns         5578
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.048
_refine_ls_R_factor_all          0.0379
_refine_ls_R_factor_gt           0.0336
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0364P)²+1.0014P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0795
_refine_ls_wR_factor_ref         0.0816
_reflns_number_gt                5063
_reflns_number_total             5578
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic4027199_si_002.cif
_cod_data_source_block           3BHEX(vic1107)
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/automatic-downloads/current/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 
;
_cod_original_cell_volume        1582.6(3)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4337136
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ru1 Ru 0.18181(2) 0.72145(2) 0.286765(12) 0.02131(8) Uani 1 1 d .
H100 H 0.214(3) 0.774(3) 0.3641(15) 0.026 Uiso 1 1 d .
Si1 Si 0.40220(8) 0.88044(8) 0.27199(4) 0.02684(18) Uani 1 1 d .
Si2 Si 0.10218(8) 0.90976(9) 0.34363(4) 0.02763(18) Uani 1 1 d .
Si3 Si 0.29293(8) 0.61487(9) 0.38168(4) 0.02545(18) Uani 1 1 d .
N1 N 0.4566(2) 0.7566(2) 0.20605(13) 0.0285(5) Uani 1 1 d .
N2 N 0.2408(2) 0.5675(2) 0.20911(12) 0.0226(5) Uani 1 1 d .
N3 N 0.0249(2) 0.9712(2) 0.26011(13) 0.0266(5) Uani 1 1 d .
N4 N 0.0625(2) 0.7749(2) 0.18390(12) 0.0230(5) Uani 1 1 d .
N5 N 0.1235(2) 0.4888(2) 0.39646(12) 0.0255(5) Uani 1 1 d .
N6 N -0.0215(2) 0.5527(2) 0.29444(12) 0.0243(5) Uani 1 1 d .
C1 C 0.5767(3) 0.7654(3) 0.17072(18) 0.0350(7) Uani 1 1 d .
H1 H 0.6569 0.8507 0.1752 0.042 Uiso 1 1 calc R
C2 C 0.5658(3) 0.6373(3) 0.12896(18) 0.0366(7) Uani 1 1 d .
H2 H 0.6345 0.6181 0.0995 0.044 Uiso 1 1 calc R
C3 C 0.4315(3) 0.5368(3) 0.13759(16) 0.0284(6) Uani 1 1 d .
C4 C 0.3688(3) 0.6180(3) 0.18503(15) 0.0247(6) Uani 1 1 d .
C5 C 0.1715(3) 0.4257(3) 0.18536(15) 0.0275(6) Uani 1 1 d .
H5 H 0.0805 0.3845 0.2007 0.033 Uiso 1 1 calc R
C6 C 0.2255(3) 0.3369(3) 0.13987(16) 0.0322(7) Uani 1 1 d .
H6 H 0.1721 0.2373 0.1256 0.039 Uiso 1 1 calc R
C7 C 0.3563(3) 0.3913(3) 0.11479(16) 0.0342(7) Uani 1 1 d .
H7 H 0.3933 0.3308 0.0830 0.041 Uiso 1 1 calc R
C8 C 0.5734(3) 0.9483(3) 0.34715(18) 0.0388(8) Uani 1 1 d .
H8A H 0.5949 0.8660 0.3694 0.058 Uiso 1 1 calc R
H8B H 0.5566 1.0171 0.3857 0.058 Uiso 1 1 calc R
H8C H 0.6577 0.9971 0.3254 0.058 Uiso 1 1 calc R
C9 C 0.3993(3) 1.0398(3) 0.21992(18) 0.0358(7) Uani 1 1 d .
H9A H 0.4970 1.0792 0.2072 0.054 Uiso 1 1 calc R
H9B H 0.3752 1.1154 0.2515 0.054 Uiso 1 1 calc R
H9C H 0.3241 1.0074 0.1741 0.054 Uiso 1 1 calc R
C10 C -0.0429(3) 1.0799(3) 0.24669(18) 0.0335(7) Uani 1 1 d .
H10 H -0.0499 1.1519 0.2843 0.040 Uiso 1 1 calc R
C11 C -0.0976(3) 1.0702(3) 0.17326(17) 0.0333(7) Uani 1 1 d .
H11 H -0.1481 1.1328 0.1509 0.040 Uiso 1 1 calc R
C12 C -0.0653(3) 0.9485(3) 0.13572(16) 0.0263(6) Uani 1 1 d .
C13 C 0.0106(3) 0.8915(3) 0.19268(15) 0.0239(6) Uani 1 1 d .
C14 C 0.0359(3) 0.7092(3) 0.11344(15) 0.0290(6) Uani 1 1 d .
H14 H 0.0699 0.6260 0.1038 0.035 Uiso 1 1 calc R
C15 C -0.0382(3) 0.7551(3) 0.05365(16) 0.0345(7) Uani 1 1 d .
H15 H -0.0542 0.7026 0.0050 0.041 Uiso 1 1 calc R
C16 C -0.0890(3) 0.8761(3) 0.06373(16) 0.0334(7) Uani 1 1 d .
H16 H -0.1387 0.9087 0.0227 0.040 Uiso 1 1 calc R
C17 C 0.2323(4) 1.0775(4) 0.40205(19) 0.0471(9) Uani 1 1 d .
H17A H 0.3153 1.1151 0.3770 0.071 Uiso 1 1 calc R
H17B H 0.2703 1.0543 0.4507 0.071 Uiso 1 1 calc R
H17C H 0.1794 1.1513 0.4091 0.071 Uiso 1 1 calc R
C18 C -0.0588(4) 0.8592(4) 0.39273(18) 0.0444(8) Uani 1 1 d .
H18A H -0.0940 0.9446 0.4040 0.067 Uiso 1 1 calc R
H18B H -0.0275 0.8245 0.4393 0.067 Uiso 1 1 calc R
H18C H -0.1393 0.7821 0.3606 0.067 Uiso 1 1 calc R
C19 C 0.0911(3) 0.3913(3) 0.44632(16) 0.0324(7) Uani 1 1 d .
H19 H 0.1625 0.3779 0.4853 0.039 Uiso 1 1 calc R
C20 C -0.0544(3) 0.3177(3) 0.43262(17) 0.0343(7) Uani 1 1 d .
H20 H -0.1018 0.2453 0.4594 0.041 Uiso 1 1 calc R
C21 C -0.1237(3) 0.3693(3) 0.37023(16) 0.0290(6) Uani 1 1 d .
C22 C -0.0078(3) 0.4748(3) 0.35063(15) 0.0244(6) Uani 1 1 d .
C23 C -0.1599(3) 0.5230(3) 0.25475(16) 0.0300(6) Uani 1 1 d .
H23 H -0.1757 0.5744 0.2141 0.036 Uiso 1 1 calc R
C24 C -0.2807(3) 0.4215(3) 0.26990(17) 0.0353(7) Uani 1 1 d .
H24 H -0.3758 0.4054 0.2397 0.042 Uiso 1 1 calc R
C25 C -0.2647(3) 0.3435(3) 0.32810(17) 0.0346(7) Uani 1 1 d .
H25 H -0.3475 0.2745 0.3390 0.042 Uiso 1 1 calc R
C26 C 0.3872(3) 0.7124(4) 0.47752(16) 0.0396(8) Uani 1 1 d .
H26A H 0.3349 0.7819 0.4935 0.059 Uiso 1 1 calc R
H26B H 0.4903 0.7644 0.4766 0.059 Uiso 1 1 calc R
H26C H 0.3857 0.6417 0.5125 0.059 Uiso 1 1 calc R
C27 C 0.4134(3) 0.4967(4) 0.35726(18) 0.0409(8) Uani 1 1 d .
H27A H 0.4351 0.4450 0.3991 0.061 Uiso 1 1 calc R
H27B H 0.5066 0.5575 0.3472 0.061 Uiso 1 1 calc R
H27C H 0.3614 0.4262 0.3128 0.061 Uiso 1 1 calc R
C28 C 0.7167(4) 0.3244(4) 0.0369(2) 0.0529(9) Uani 1 1 d .
H28A H 0.6408 0.3732 0.0216 0.079 Uiso 1 1 calc R
H28B H 0.8102 0.3748 0.0228 0.079 Uiso 1 1 calc R
H28C H 0.7319 0.3261 0.0911 0.079 Uiso 1 1 calc R
C29 C 0.6658(4) 0.1674(4) -0.00169(19) 0.0426(8) Uani 1 1 d .
H29A H 0.6506 0.1669 -0.0564 0.051 Uiso 1 1 calc R
H29B H 0.7455 0.1207 0.0120 0.051 Uiso 1 1 calc R
C30 C 0.5252(4) 0.0791(3) 0.01784(19) 0.0436(8) Uani 1 1 d .
H30A H 0.4450 0.1245 0.0026 0.052 Uiso 1 1 calc R
H30B H 0.5395 0.0831 0.0727 0.052 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N2 Ru1 N6 90.31(8) . .
N2 Ru1 N4 84.34(8) . .
N6 Ru1 N4 89.86(8) . .
N2 Ru1 Si1 83.99(6) . .
N6 Ru1 Si1 174.24(6) . .
N4 Ru1 Si1 90.40(6) . .
N2 Ru1 Si2 166.06(6) . .
N6 Ru1 Si2 93.09(6) . .
N4 Ru1 Si2 82.15(6) . .
Si1 Ru1 Si2 92.65(3) . .
N2 Ru1 Si3 85.71(6) . .
N6 Ru1 Si3 83.38(6) . .
N4 Ru1 Si3 167.93(6) . .
Si1 Ru1 Si3 95.34(3) . .
Si2 Ru1 Si3 108.11(3) . .
N2 Ru1 H100 138.8(11) . .
N6 Ru1 H100 93.5(11) . .
N4 Ru1 H100 136.7(11) . .
Si1 Ru1 H100 90.3(11) . .
Si2 Ru1 H100 54.5(11) . .
Si3 Ru1 H100 54.1(11) . .
N1 Si1 C8 102.57(13) . .
N1 Si1 C9 102.69(13) . .
C8 Si1 C9 104.79(14) . .
N1 Si1 Ru1 97.94(8) . .
C8 Si1 Ru1 124.16(11) . .
C9 Si1 Ru1 120.38(10) . .
N3 Si2 C17 104.96(14) . .
N3 Si2 C18 103.42(13) . .
C17 Si2 C18 105.30(16) . .
N3 Si2 Ru1 98.78(8) . .
C17 Si2 Ru1 123.29(11) . .
C18 Si2 Ru1 118.11(12) . .
N3 Si2 H100 135.3(8) . .
C17 Si2 H100 99.5(8) . .
C18 Si2 H100 105.4(8) . .
Ru1 Si2 H100 37.0(8) . .
N5 Si3 C26 104.26(12) . .
N5 Si3 C27 104.83(13) . .
C26 Si3 C27 103.93(15) . .
N5 Si3 Ru1 97.38(7) . .
C26 Si3 Ru1 124.65(11) . .
C27 Si3 Ru1 118.78(10) . .
N5 Si3 H100 97.7(8) . .
C26 Si3 H100 89.4(8) . .
C27 Si3 H100 149.8(8) . .
Ru1 Si3 H100 36.9(8) . .
C4 N1 C1 105.4(2) . .
C4 N1 Si1 119.19(18) . .
C1 N1 Si1 135.4(2) . .
C4 N2 C5 114.8(2) . .
C4 N2 Ru1 116.06(17) . .
C5 N2 Ru1 129.00(18) . .
C13 N3 C10 106.0(2) . .
C13 N3 Si2 119.10(18) . .
C10 N3 Si2 134.5(2) . .
C14 N4 C13 114.2(2) . .
C14 N4 Ru1 129.55(18) . .
C13 N4 Ru1 116.23(17) . .
C22 N5 C19 105.6(2) . .
C22 N5 Si3 119.94(18) . .
C19 N5 Si3 134.4(2) . .
C23 N6 C22 114.7(2) . .
C23 N6 Ru1 129.67(19) . .
C22 N6 Ru1 115.39(17) . .
C2 C1 N1 111.6(3) . .
C2 C1 H1 124.2 . .
N1 C1 H1 124.2 . .
C1 C2 C3 107.0(3) . .
C1 C2 H2 126.5 . .
C3 C2 H2 126.5 . .
C7 C3 C4 117.2(3) . .
C7 C3 C2 138.1(3) . .
C4 C3 C2 104.6(3) . .
N2 C4 N1 122.8(2) . .
N2 C4 C3 125.8(3) . .
N1 C4 C3 111.4(2) . .
N2 C5 C6 123.6(3) . .
N2 C5 H5 118.2 . .
C6 C5 H5 118.2 . .
C5 C6 C7 120.9(3) . .
C5 C6 H6 119.6 . .
C7 C6 H6 119.6 . .
C6 C7 C3 117.7(3) . .
C6 C7 H7 121.1 . .
C3 C7 H7 121.1 . .
Si1 C8 H8A 109.5 . .
Si1 C8 H8B 109.5 . .
H8A C8 H8B 109.5 . .
Si1 C8 H8C 109.5 . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
Si1 C9 H9A 109.5 . .
Si1 C9 H9B 109.5 . .
H9A C9 H9B 109.5 . .
Si1 C9 H9C 109.5 . .
H9A C9 H9C 109.5 . .
H9B C9 H9C 109.5 . .
C11 C10 N3 111.3(3) . .
C11 C10 H10 124.4 . .
N3 C10 H10 124.4 . .
C10 C11 C12 107.2(3) . .
C10 C11 H11 126.4 . .
C12 C11 H11 126.4 . .
C16 C12 C13 116.6(3) . .
C16 C12 C11 138.4(3) . .
C13 C12 C11 105.0(2) . .
N4 C13 N3 122.9(2) . .
N4 C13 C12 126.6(3) . .
N3 C13 C12 110.5(2) . .
N4 C14 C15 124.0(3) . .
N4 C14 H14 118.0 . .
C15 C14 H14 118.0 . .
C16 C15 C14 120.9(3) . .
C16 C15 H15 119.5 . .
C14 C15 H15 119.5 . .
C15 C16 C12 117.8(3) . .
C15 C16 H16 121.1 . .
C12 C16 H16 121.1 . .
Si2 C17 H17A 109.5 . .
Si2 C17 H17B 109.5 . .
H17A C17 H17B 109.5 . .
Si2 C17 H17C 109.5 . .
H17A C17 H17C 109.5 . .
H17B C17 H17C 109.5 . .
Si2 C18 H18A 109.5 . .
Si2 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
Si2 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
C20 C19 N5 111.6(3) . .
C20 C19 H19 124.2 . .
N5 C19 H19 124.2 . .
C19 C20 C21 107.0(3) . .
C19 C20 H20 126.5 . .
C21 C20 H20 126.5 . .
C25 C21 C22 117.3(3) . .
C25 C21 C20 137.9(3) . .
C22 C21 C20 104.8(2) . .
N6 C22 N5 123.3(2) . .
N6 C22 C21 125.8(2) . .
N5 C22 C21 110.9(2) . .
N6 C23 C24 123.5(3) . .
N6 C23 H23 118.2 . .
C24 C23 H23 118.2 . .
C25 C24 C23 120.9(3) . .
C25 C24 H24 119.6 . .
C23 C24 H24 119.6 . .
C24 C25 C21 117.7(3) . .
C24 C25 H25 121.1 . .
C21 C25 H25 121.1 . .
Si3 C26 H26A 109.5 . .
Si3 C26 H26B 109.5 . .
H26A C26 H26B 109.5 . .
Si3 C26 H26C 109.5 . .
H26A C26 H26C 109.5 . .
H26B C26 H26C 109.5 . .
Si3 C27 H27A 109.5 . .
Si3 C27 H27B 109.5 . .
H27A C27 H27B 109.5 . .
Si3 C27 H27C 109.5 . .
H27A C27 H27C 109.5 . .
H27B C27 H27C 109.5 . .
C29 C28 H28A 109.5 . .
C29 C28 H28B 109.5 . .
H28A C28 H28B 109.5 . .
C29 C28 H28C 109.5 . .
H28A C28 H28C 109.5 . .
H28B C28 H28C 109.5 . .
C30 C29 C28 113.8(3) . .
C30 C29 H29A 108.8 . .
C28 C29 H29A 108.8 . .
C30 C29 H29B 108.8 . .
C28 C29 H29B 108.8 . .
H29A C29 H29B 107.7 . .
C29 C30 C30 114.8(3) . 2_655
C29 C30 H30A 108.6 . .
C30 C30 H30A 108.6 2_655 .
C29 C30 H30B 108.6 . .
C30 C30 H30B 108.6 2_655 .
H30A C30 H30B 107.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ru1 N2 2.190(2) .
Ru1 N6 2.209(2) .
Ru1 N4 2.225(2) .
Ru1 Si1 2.3205(8) .
Ru1 Si2 2.3505(8) .
Ru1 Si3 2.3575(8) .
Ru1 H100 1.42(3) .
Si1 N1 1.837(2) .
Si1 C8 1.883(3) .
Si1 C9 1.892(3) .
Si2 N3 1.816(2) .
Si2 C17 1.868(3) .
Si2 C18 1.873(3) .
Si2 H100 1.91(3) .
Si3 N5 1.822(2) .
Si3 C26 1.876(3) .
Si3 C27 1.881(3) .
Si3 H100 1.91(3) .
N1 C4 1.357(3) .
N1 C1 1.384(3) .
N2 C4 1.345(3) .
N2 C5 1.346(3) .
N3 C13 1.356(3) .
N3 C10 1.388(3) .
N4 C14 1.336(3) .
N4 C13 1.344(3) .
N5 C22 1.359(3) .
N5 C19 1.386(4) .
N6 C23 1.344(3) .
N6 C22 1.344(3) .
C1 C2 1.356(4) .
C1 H1 0.9500 .
C2 C3 1.427(4) .
C2 H2 0.9500 .
C3 C7 1.385(4) .
C3 C4 1.410(4) .
C5 C6 1.380(4) .
C5 H5 0.9500 .
C6 C7 1.383(4) .
C6 H6 0.9500 .
C7 H7 0.9500 .
C8 H8A 0.9800 .
C8 H8B 0.9800 .
C8 H8C 0.9800 .
C9 H9A 0.9800 .
C9 H9B 0.9800 .
C9 H9C 0.9800 .
C10 C11 1.351(4) .
C10 H10 0.9500 .
C11 C12 1.425(4) .
C11 H11 0.9500 .
C12 C16 1.386(4) .
C12 C13 1.415(4) .
C14 C15 1.384(4) .
C14 H14 0.9500 .
C15 C16 1.379(4) .
C15 H15 0.9500 .
C16 H16 0.9500 .
C17 H17A 0.9800 .
C17 H17B 0.9800 .
C17 H17C 0.9800 .
C18 H18A 0.9800 .
C18 H18B 0.9800 .
C18 H18C 0.9800 .
C19 C20 1.350(4) .
C19 H19 0.9500 .
C20 C21 1.429(4) .
C20 H20 0.9500 .
C21 C25 1.386(4) .
C21 C22 1.409(4) .
C23 C24 1.384(4) .
C23 H23 0.9500 .
C24 C25 1.377(4) .
C24 H24 0.9500 .
C25 H25 0.9500 .
C26 H26A 0.9800 .
C26 H26B 0.9800 .
C26 H26C 0.9800 .
C27 H27A 0.9800 .
C27 H27B 0.9800 .
C27 H27C 0.9800 .
C28 C29 1.522(5) .
C28 H28A 0.9800 .
C28 H28B 0.9800 .
C28 H28C 0.9800 .
C29 C30 1.500(5) .
C29 H29A 0.9900 .
C29 H29B 0.9900 .
C30 C30 1.518(6) 2_655
C30 H30A 0.9900 .
C30 H30B 0.9900 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_4
N2 Ru1 Si1 N1 0.49(9) .
N6 Ru1 Si1 N1 8.7(6) .
N4 Ru1 Si1 N1 -83.78(10) .
Si2 Ru1 Si1 N1 -165.94(8) .
Si3 Ru1 Si1 N1 85.59(8) .
N2 Ru1 Si1 C8 -110.62(14) .
N6 Ru1 Si1 C8 -102.4(6) .
N4 Ru1 Si1 C8 165.11(14) .
Si2 Ru1 Si1 C8 82.95(13) .
Si3 Ru1 Si1 C8 -25.52(13) .
N2 Ru1 Si1 C9 110.31(13) .
N6 Ru1 Si1 C9 118.5(6) .
N4 Ru1 Si1 C9 26.04(13) .
Si2 Ru1 Si1 C9 -56.12(12) .
Si3 Ru1 Si1 C9 -164.60(12) .
N2 Ru1 Si2 N3 7.5(3) .
N6 Ru1 Si2 N3 -96.36(10) .
N4 Ru1 Si2 N3 -6.93(9) .
Si1 Ru1 Si2 N3 83.10(8) .
Si3 Ru1 Si2 N3 179.60(8) .
N2 Ru1 Si2 C17 -107.0(3) .
N6 Ru1 Si2 C17 149.19(16) .
N4 Ru1 Si2 C17 -121.38(16) .
Si1 Ru1 Si2 C17 -31.35(15) .
Si3 Ru1 Si2 C17 65.15(15) .
N2 Ru1 Si2 C18 117.9(3) .
N6 Ru1 Si2 C18 14.05(13) .
N4 Ru1 Si2 C18 103.48(13) .
Si1 Ru1 Si2 C18 -166.48(12) .
Si3 Ru1 Si2 C18 -69.99(12) .
N2 Ru1 Si3 N5 -96.95(9) .
N6 Ru1 Si3 N5 -6.14(9) .
N4 Ru1 Si3 N5 -62.4(3) .
Si1 Ru1 Si3 N5 179.51(8) .
Si2 Ru1 Si3 N5 84.95(8) .
N2 Ru1 Si3 C26 150.01(14) .
N6 Ru1 Si3 C26 -119.18(14) .
N4 Ru1 Si3 C26 -175.5(3) .
Si1 Ru1 Si3 C26 66.46(13) .
Si2 Ru1 Si3 C26 -28.09(13) .
N2 Ru1 Si3 C27 14.49(14) .
N6 Ru1 Si3 C27 105.30(14) .
N4 Ru1 Si3 C27 49.0(3) .
Si1 Ru1 Si3 C27 -69.05(13) .
Si2 Ru1 Si3 C27 -163.61(13) .
C8 Si1 N1 C4 126.5(2) .
C9 Si1 N1 C4 -124.9(2) .
Ru1 Si1 N1 C4 -1.2(2) .
C8 Si1 N1 C1 -50.3(3) .
C9 Si1 N1 C1 58.2(3) .
Ru1 Si1 N1 C1 -178.1(3) .
N6 Ru1 N2 C4 -179.07(18) .
N4 Ru1 N2 C4 91.10(18) .
Si1 Ru1 N2 C4 0.11(17) .
Si2 Ru1 N2 C4 76.7(3) .
Si3 Ru1 N2 C4 -95.73(18) .
N6 Ru1 N2 C5 -3.6(2) .
N4 Ru1 N2 C5 -93.5(2) .
Si1 Ru1 N2 C5 175.5(2) .
Si2 Ru1 N2 C5 -107.8(3) .
Si3 Ru1 N2 C5 79.7(2) .
C17 Si2 N3 C13 137.2(2) .
C18 Si2 N3 C13 -112.6(2) .
Ru1 Si2 N3 C13 9.2(2) .
C17 Si2 N3 C10 -51.4(3) .
C18 Si2 N3 C10 58.8(3) .
Ru1 Si2 N3 C10 -179.4(3) .
N2 Ru1 N4 C14 8.5(2) .
N6 Ru1 N4 C14 -81.8(2) .
Si1 Ru1 N4 C14 92.4(2) .
Si2 Ru1 N4 C14 -175.0(2) .
Si3 Ru1 N4 C14 -26.1(4) .
N2 Ru1 N4 C13 -170.39(19) .
N6 Ru1 N4 C13 99.29(18) .
Si1 Ru1 N4 C13 -86.47(18) .
Si2 Ru1 N4 C13 6.15(17) .
Si3 Ru1 N4 C13 155.0(2) .
C26 Si3 N5 C22 135.0(2) .
C27 Si3 N5 C22 -116.0(2) .
Ru1 Si3 N5 C22 6.4(2) .
C26 Si3 N5 C19 -46.9(3) .
C27 Si3 N5 C19 62.0(3) .
Ru1 Si3 N5 C19 -175.5(3) .
N2 Ru1 N6 C23 -92.7(2) .
N4 Ru1 N6 C23 -8.3(2) .
Si1 Ru1 N6 C23 -100.9(6) .
Si2 Ru1 N6 C23 73.8(2) .
Si3 Ru1 N6 C23 -178.3(2) .
N2 Ru1 N6 C22 92.77(19) .
N4 Ru1 N6 C22 177.10(19) .
Si1 Ru1 N6 C22 84.6(6) .
Si2 Ru1 N6 C22 -100.76(18) .
Si3 Ru1 N6 C22 7.13(17) .
C4 N1 C1 C2 -0.1(3) .
Si1 N1 C1 C2 177.1(2) .
N1 C1 C2 C3 -0.7(4) .
C1 C2 C3 C7 -176.6(3) .
C1 C2 C3 C4 1.1(3) .
C5 N2 C4 N1 -177.1(2) .
Ru1 N2 C4 N1 -1.0(3) .
C5 N2 C4 C3 1.1(4) .
Ru1 N2 C4 C3 177.2(2) .
C1 N1 C4 N2 179.3(2) .
Si1 N1 C4 N2 1.6(3) .
C1 N1 C4 C3 0.9(3) .
Si1 N1 C4 C3 -176.86(18) .
C7 C3 C4 N2 -1.3(4) .
C2 C3 C4 N2 -179.6(3) .
C7 C3 C4 N1 177.1(2) .
C2 C3 C4 N1 -1.2(3) .
C4 N2 C5 C6 0.1(4) .
Ru1 N2 C5 C6 -175.4(2) .
N2 C5 C6 C7 -1.0(4) .
C5 C6 C7 C3 0.7(4) .
C4 C3 C7 C6 0.3(4) .
C2 C3 C7 C6 177.9(3) .
C13 N3 C10 C11 -0.4(3) .
Si2 N3 C10 C11 -172.6(2) .
N3 C10 C11 C12 0.3(3) .
C10 C11 C12 C16 178.8(3) .
C10 C11 C12 C13 0.0(3) .
C14 N4 C13 N3 179.1(2) .
Ru1 N4 C13 N3 -1.9(3) .
C14 N4 C13 C12 -0.6(4) .
Ru1 N4 C13 C12 178.4(2) .
C10 N3 C13 N4 -179.4(2) .
Si2 N3 C13 N4 -5.8(3) .
C10 N3 C13 C12 0.3(3) .
Si2 N3 C13 C12 173.96(17) .
C16 C12 C13 N4 0.4(4) .
C11 C12 C13 N4 179.5(2) .
C16 C12 C13 N3 -179.3(2) .
C11 C12 C13 N3 -0.2(3) .
C13 N4 C14 C15 0.1(4) .
Ru1 N4 C14 C15 -178.8(2) .
N4 C14 C15 C16 0.7(5) .
C14 C15 C16 C12 -0.9(4) .
C13 C12 C16 C15 0.4(4) .
C11 C12 C16 C15 -178.4(3) .
C22 N5 C19 C20 0.3(3) .
Si3 N5 C19 C20 -177.9(2) .
N5 C19 C20 C21 -0.3(3) .
C19 C20 C21 C25 -179.7(3) .
C19 C20 C21 C22 0.2(3) .
C23 N6 C22 N5 179.5(2) .
Ru1 N6 C22 N5 -5.1(3) .
C23 N6 C22 C21 -0.4(4) .
Ru1 N6 C22 C21 175.0(2) .
C19 N5 C22 N6 179.9(2) .
Si3 N5 C22 N6 -1.6(4) .
C19 N5 C22 C21 -0.2(3) .
Si3 N5 C22 C21 178.34(18) .
C25 C21 C22 N6 -0.2(4) .
C20 C21 C22 N6 179.9(3) .
C25 C21 C22 N5 179.9(2) .
C20 C21 C22 N5 0.0(3) .
C22 N6 C23 C24 0.5(4) .
Ru1 N6 C23 C24 -174.1(2) .
N6 C23 C24 C25 0.0(5) .
C23 C24 C25 C21 -0.7(4) .
C22 C21 C25 C24 0.7(4) .
C20 C21 C25 C24 -179.5(3) .
C28 C29 C30 C30 -178.0(4) 2_655
