#------------------------------------------------------------------------------
#$Date: 2016-03-23 22:28:48 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179482 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/79/4337902.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4337902
loop_
_publ_author_name
'Schwamm, Ryan J.'
'Day, Benjamin M.'
'Coles, Martyn P.'
'Fitchett, Christopher M.'
_publ_section_title
;
 Low-Coordinate Bismuth Cations.
;
_journal_issue                   7
_journal_name_full               'Inorganic chemistry'
_journal_page_first              3778
_journal_paper_doi               10.1021/ic500113g
_journal_volume                  53
_journal_year                    2014
_chemical_formula_moiety         '4(C32 H45 Bi N2 Si), C7'
_chemical_formula_sum            'C135 H180 Bi4 N8 Si4'
_chemical_formula_weight         2863.15
_chemical_name_systematic
;
 ?
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     iterative
_audit_creation_date             2013-10-25
_audit_creation_method
;
Olex2 1.2
(compiled 2013.09.17 svn.r2790 for OlexSys, GUI svn.r4601)
;
_cell_angle_alpha                108.940(2)
_cell_angle_beta                 93.6783(18)
_cell_angle_gamma                100.2794(18)
_cell_formula_units_Z            1
_cell_length_a                   12.9068(2)
_cell_length_b                   15.6323(4)
_cell_length_c                   17.3240(5)
_cell_measurement_reflns_used    32723
_cell_measurement_temperature    120.0(1)
_cell_measurement_theta_max      37.2900
_cell_measurement_theta_min      3.1700
_cell_volume                     3224.93(14)
_computing_cell_refinement
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
;
_computing_data_collection
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
;
_computing_data_reduction
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
;
_computing_molecular_graphics
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_publication_material
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_structure_refinement
'L.J. Bourhis, O.V. Dolomanov, R.J. Gildea, J.A.K. Howard, H. Puschmann, in preparation (2013)'
_computing_structure_solution
'L.J. Bourhis, O.V. Dolomanov, R.J. Gildea, J.A.K. Howard, H. Puschmann, in preparation (2013)'
_diffrn_ambient_temperature      120.02(10)
_diffrn_detector_area_resol_mean 5.3250
_diffrn_measured_fraction_theta_full 0.9995
_diffrn_measured_fraction_theta_max 0.9486
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      0.0173947000
_diffrn_orient_matrix_UB_12      0.0023846000
_diffrn_orient_matrix_UB_13      -0.0374067000
_diffrn_orient_matrix_UB_21      0.0065963000
_diffrn_orient_matrix_UB_22      0.0488446000
_diffrn_orient_matrix_UB_23      0.0154519000
_diffrn_orient_matrix_UB_31      0.0531788000
_diffrn_orient_matrix_UB_32      0.0041379000
_diffrn_orient_matrix_UB_33      0.0163868000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.0354
_diffrn_reflns_av_unetI/netI     0.0336
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            66037
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        26.000
_diffrn_reflns_theta_max         30.000
_diffrn_reflns_theta_min         2.664
_diffrn_source                   'SuperNova (Mo) X-ray Source'
_exptl_absorpt_coefficient_mu    5.528
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.56171
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            yellow
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.474
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1434
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.05
_refine_diff_density_max         1.824
_refine_diff_density_min         -0.966
_refine_diff_density_rms         0.104
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.036
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     714
_refine_ls_number_reflns         18799
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.036
_refine_ls_R_factor_all          0.0332
_refine_ls_R_factor_gt           0.0237
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;
 w=1/[σ²(Fo²)+(0.0216P)²+2.3857P]
 where P=(Fo²+2Fc²)/3
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0527
_refine_ls_wR_factor_ref         0.0558
_reflns_Friedel_coverage         0.000
_reflns_number_gt                15967
_reflns_number_total             18799
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ic500113g_si_002.cif
_cod_data_source_block           (4)
_cod_depositor_comments
'Adding full bibliography for 4337900--4337903.cif.'
_cod_original_cell_volume        3224.91(14)
_cod_database_code               4337902
#BEGIN Tags that were not found in dictionaries:
_shelxl_version_number           2013-2
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_reflns_odcompleteness_completeness 99.95
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     36.23
_olex2_refinement_description
;
1. Others
 Fixed Sof: C71(0.5) C73(0.5) C74(0.5)
 Fixed Uiso: H1Da(0.032) H1Db(0.032) H1Dc(0.032) H1Ua(0.032) H1Ub(0.032)
 H1Uc(0.032) H3(0.032) H4(0.036) H5(0.031) H7(0.028) H8a(0.057) H8b(0.057)
 H8c(0.057) H9a(0.065) H9b(0.065) H9c(0.065) H10(0.029) H11a(0.061) H11b(0.061)
 H11c(0.061) H12a(0.064) H12b(0.064) H12c(0.064) H15(0.026) H16(0.027)
 H17(0.026) H19(0.024) H20a(0.048) H20b(0.048) H20c(0.048) H21a(0.047)
 H21b(0.047) H21c(0.047) H22(0.034) H23a(0.074) H23b(0.074) H23c(0.074)
 H24a(0.076) H24b(0.076) H24c(0.076) H25a(0.04) H25b(0.04) H25c(0.04)
 H26a(0.047) H26b(0.047) H26c(0.047) H28(0.029) H29(0.036) H30(0.036)
 H31(0.037) H32(0.031) H36(0.025) H37(0.028) H38(0.027) H40(0.021) H41a(0.043)
 H41b(0.043) H41c(0.043) H42a(0.047) H42b(0.047) H42c(0.047) H43(0.025)
 H44a(0.041) H44b(0.041) H44c(0.041) H45a(0.054) H45b(0.054) H45c(0.054)
 H48(0.031) H49(0.037) H50(0.029) H52(0.023) H53a(0.041) H53b(0.041)
 H53c(0.041) H54a(0.042) H54b(0.042) H54c(0.042) H55(0.022) H56a(0.046)
 H56b(0.046) H56c(0.046) H57a(0.047) H57b(0.047) H57c(0.047) H59(0.032)
 H60(0.039) H61(0.039) H62(0.039) H63(0.031)
 Fixed X: H1Da(0.8695) H1Db(0.8861) H1Dc(0.7795) H1Ua(0.664) H1Ub(0.7751)
 H1Uc(0.6938) H3(0.255) H4(0.1988) H5(0.3213) H7(0.5235) H8a(0.3344)
 H8b(0.4348) H8c(0.4401) H9a(0.4253) H9b(0.4384) H9c(0.3305) H10(0.603)
 H11a(0.5396) H11b(0.5753) H11c(0.4543) H12a(0.446) H12b(0.5687) H12c(0.5179)
 H15(1.1276) H16(1.1965) H17(1.0861) H19(0.8558) H20a(0.913) H20b(0.9152)
 H20c(1.0211) H21a(1.0545) H21b(0.9428) H21c(0.9819) H22(0.8064) H23a(0.9774)
 H23b(0.8578) H23c(0.8969) H24a(0.8837) H24b(0.8441) H24c(0.9654) H25a(0.6266)
 H25b(0.7507) H25c(0.6817) H26a(0.7135) H26b(0.7732) H26c(0.6492) H28(0.6317)
 H29(0.6015) H30(0.6239) H31(0.6725) H32(0.7011) H36(0.3406) H37(0.3162)
 H38(0.461) H40(0.5878) H41a(0.4081) H41b(0.4961) H41c(0.5235) H42a(0.4693)
 H42b(0.4648) H42c(0.375) H43(0.7331) H44a(0.6828) H44b(0.736) H44c(0.6121)
 H45a(0.6023) H45b(0.7265) H45c(0.6586) H48(0.9472) H49(1.1213) H50(1.1749)
 H52(0.7399) H53a(0.7944) H53b(0.6916) H53c(0.8023) H54a(0.7711) H54b(0.6602)
 H54c(0.742) H55(1.0211) H56a(1.2334) H56b(1.1969) H56c(1.162) H57a(1.0344)
 H57b(1.1171) H57c(1.1543) H59(0.9747) H60(1.0856) H61(1.0612) H62(0.9261)
 H63(0.8175)
 Fixed Y: H1Da(0.2483) H1Db(0.3548) H1Dc(0.301) H1Ua(0.3784) H1Ub(0.4295)
 H1Uc(0.367) H3(0.7052) H4(0.6196) H5(0.5853) H7(0.7913) H8a(0.7011) H8b(0.756)
 H8c(0.6646) H9a(0.8983) H9b(0.9038) H9c(0.8528) H10(0.6561) H11a(0.499)
 H11b(0.512) H11c(0.4935) H12a(0.64) H12b(0.6595) H12c(0.7344) H15(0.9063)
 H16(0.8544) H17(0.761) H19(0.8714) H20a(0.7471) H20b(0.8264) H20c(0.8126)
 H21a(0.9785) H21b(0.9947) H21c(1.0146) H22(0.6855) H23a(0.5977) H23b(0.5537)
 H23c(0.5722) H24a(0.7918) H24b(0.6919) H24c(0.7295) H25a(0.9452) H25b(0.9698)
 H25c(0.9054) H26a(0.812) H26b(0.9095) H26c(0.8875) H28(0.4933) H29(0.4846)
 H30(0.6186) H31(0.7611) H32(0.7703) H36(0.1111) H37(0.0299) H38(0.0099)
 H40(0.2175) H41a(0.091) H41b(0.1509) H41c(0.0723) H42a(0.3072) H42b(0.2969)
 H42c(0.2377) H43(0.1001) H44a(-0.0588) H44b(-0.0406) H44c(-0.0703)
 H45a(0.0737) H45b(0.1034) H45c(0.1713) H48(0.364) H49(0.4226) H50(0.416)
 H52(0.2542) H53a(0.1567) H53b(0.1879) H53c(0.2341) H54a(0.3911) H54b(0.3428)
 H54c(0.4093) H55(0.3012) H56a(0.3382) H56b(0.2976) H56c(0.2386) H57a(0.462)
 H57b(0.4348) H57c(0.477) H59(0.1492) H60(0.0734) H61(-0.0848) H62(-0.1697)
 H63(-0.0942)
 Fixed Z: H1Da(0.3773) H1Db(0.4252) H1Dc(0.3678) H1Ua(0.5109) H1Ub(0.5625)
 H1Uc(0.5956) H3(0.9229) H4(0.786) H5(0.6963) H7(1.0171) H8a(1.0553)
 H8b(1.1197) H8c(1.0489) H9a(0.9961) H9b(1.0883) H9c(1.0318) H10(0.745)
 H11a(0.7206) H11b(0.6396) H11c(0.6495) H12a(0.6168) H12b(0.6133) H12c(0.6734)
 H15(1.0409) H16(0.9193) H17(0.801) H19(1.0685) H20a(1.0925) H20b(1.1763)
 H20c(1.1392) H21a(1.1542) H21b(1.1786) H21c(1.1011) H22(0.7806) H23a(0.7357)
 H23b(0.7002) H23c(0.7928) H24a(0.7185) H24b(0.654) H24c(0.6866) H25a(0.9883)
 H25b(1.0094) H25c(1.0483) H26a(0.7747) H26b(0.8353) H26c(0.8151) H28(0.9972)
 H29(1.1256) H30(1.2377) H31(1.2223) H32(1.0938) H36(0.446) H37(0.3066)
 H38(0.2373) H40(0.573) H41a(0.5835) H41b(0.6573) H41c(0.5836) H42a(0.5504)
 H42b(0.6372) H42c(0.5645) H43(0.3227) H44a(0.2946) H44b(0.2209) H44c(0.2134)
 H45a(0.1758) H45b(0.1893) H45c(0.2383) H48(0.8337) H49(0.8261) H50(0.7004)
 H52(0.667) H53a(0.7323) H53b(0.7644) H53c(0.8182) H54a(0.8254) H54b(0.7724)
 H54c(0.7436) H55(0.5046) H56a(0.5788) H56b(0.4836) H56c(0.539) H57a(0.5521)
 H57b(0.4909) H57c(0.5859) H59(0.4311) H60(0.3461) H61(0.3049) H62(0.3477)
 H63(0.436)
;
#END Tags that were not found in dictionaries
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_occupancy
Bi1 Bi 0.69465(2) 0.62780(2) 0.90371(2) 0.01612(3) Uani 1 1 d .
Bi2 Bi 0.78226(2) 0.10375(2) 0.53455(2) 0.01393(2) Uani 1 1 d .
Si1 Si 0.69728(5) 0.81937(5) 0.91116(4) 0.01616(13) Uani 1 1 d .
Si2 Si 0.77749(5) 0.27230(5) 0.49380(4) 0.01318(12) Uani 1 1 d .
N1 N 0.59744(16) 0.72413(14) 0.89305(13) 0.0163(4) Uani 1 1 d .
N2 N 0.79551(16) 0.76387(14) 0.92935(12) 0.0157(4) Uani 1 1 d .
N3 N 0.69418(15) 0.16485(14) 0.46238(12) 0.0139(4) Uani 1 1 d .
N4 N 0.86358(16) 0.24591(14) 0.55922(12) 0.0138(4) Uani 1 1 d .
C1 C 0.48799(18) 0.69837(17) 0.86258(15) 0.0159(5) Uani 1 1 d .
C1D C 0.8351(2) 0.29711(19) 0.40529(16) 0.0211(5) Uani 1 1 d .
H1DA H 0.8695 0.2483 0.3773 0.032 Uiso 1 1 calc .
H1DB H 0.8861 0.3548 0.4252 0.032 Uiso 1 1 calc .
H1DC H 0.7795 0.3010 0.3678 0.032 Uiso 1 1 calc .
C1U C 0.7207(2) 0.37418(18) 0.54720(16) 0.0217(5) Uani 1 1 d .
H1UA H 0.6640 0.3784 0.5109 0.032 Uiso 1 1 calc .
H1UB H 0.7751 0.4295 0.5625 0.032 Uiso 1 1 calc .
H1UC H 0.6938 0.3670 0.5956 0.032 Uiso 1 1 calc .
C2 C 0.4126(2) 0.71986(18) 0.91740(16) 0.0194(5) Uani 1 1 d .
C3 C 0.3050(2) 0.6905(2) 0.88713(19) 0.0266(6) Uani 1 1 d .
H3 H 0.2550 0.7052 0.9229 0.032 Uiso 1 1 calc .
C4 C 0.2711(2) 0.6398(2) 0.8051(2) 0.0301(6) Uani 1 1 d .
H4 H 0.1988 0.6196 0.7860 0.036 Uiso 1 1 calc .
C5 C 0.3447(2) 0.61959(19) 0.75151(18) 0.0256(6) Uani 1 1 d .
H5 H 0.3213 0.5853 0.6963 0.031 Uiso 1 1 calc .
C6 C 0.4534(2) 0.64922(18) 0.77799(16) 0.0190(5) Uani 1 1 d .
C7 C 0.4457(2) 0.77507(19) 1.00813(17) 0.0230(5) Uani 1 1 d .
H7 H 0.5235 0.7913 1.0171 0.028 Uiso 1 1 calc .
C8 C 0.4105(3) 0.7190(3) 1.0631(2) 0.0382(8) Uani 1 1 d .
H8A H 0.3344 0.7011 1.0553 0.057 Uiso 1 1 calc .
H8B H 0.4348 0.7560 1.1197 0.057 Uiso 1 1 calc .
H8C H 0.4401 0.6646 1.0489 0.057 Uiso 1 1 calc .
C9 C 0.4063(3) 0.8660(2) 1.0335(2) 0.0430(9) Uani 1 1 d .
H9A H 0.4253 0.8983 0.9961 0.065 Uiso 1 1 calc .
H9B H 0.4384 0.9038 1.0883 0.065 Uiso 1 1 calc .
H9C H 0.3305 0.8528 1.0318 0.065 Uiso 1 1 calc .
C10 C 0.5312(2) 0.6277(2) 0.71576(16) 0.0239(5) Uani 1 1 d .
H10 H 0.6030 0.6561 0.7450 0.029 Uiso 1 1 calc .
C11 C 0.5245(3) 0.5233(2) 0.6778(2) 0.0410(8) Uani 1 1 d .
H11A H 0.5396 0.4990 0.7206 0.061 Uiso 1 1 calc .
H11B H 0.5753 0.5120 0.6396 0.061 Uiso 1 1 calc .
H11C H 0.4543 0.4935 0.6495 0.061 Uiso 1 1 calc .
C12 C 0.5144(3) 0.6693(3) 0.6486(2) 0.0427(8) Uani 1 1 d .
H12A H 0.4460 0.6400 0.6168 0.064 Uiso 1 1 calc .
H12B H 0.5687 0.6595 0.6133 0.064 Uiso 1 1 calc .
H12C H 0.5179 0.7344 0.6734 0.064 Uiso 1 1 calc .
C13 C 0.90612(19) 0.78704(17) 0.92557(15) 0.0163(5) Uani 1 1 d .
C14 C 0.97436(19) 0.84413(18) 0.99803(15) 0.0173(5) Uani 1 1 d .
C15 C 1.0824(2) 0.86836(19) 0.99353(17) 0.0216(5) Uani 1 1 d .
H15 H 1.1276 0.9063 1.0409 0.026 Uiso 1 1 calc .
C16 C 1.1240(2) 0.83753(19) 0.92076(17) 0.0223(5) Uani 1 1 d .
H16 H 1.1965 0.8544 0.9193 0.027 Uiso 1 1 calc .
C17 C 1.0576(2) 0.78150(19) 0.85004(17) 0.0219(5) Uani 1 1 d .
H17 H 1.0861 0.7610 0.8010 0.026 Uiso 1 1 calc .
C18 C 0.9490(2) 0.75506(19) 0.85052(15) 0.0192(5) Uani 1 1 d .
C19 C 0.9322(2) 0.87541(19) 1.07983(15) 0.0200(5) Uani 1 1 d .
H19 H 0.8558 0.8714 1.0685 0.024 Uiso 1 1 calc .
C20 C 0.9467(3) 0.8092(2) 1.12628(18) 0.0317(7) Uani 1 1 d .
H20A H 0.9130 0.7471 1.0925 0.048 Uiso 1 1 calc .
H20B H 0.9152 0.8264 1.1763 0.048 Uiso 1 1 calc .
H20C H 1.0211 0.8126 1.1392 0.048 Uiso 1 1 calc .
C21 C 0.9825(3) 0.9751(2) 1.13341(18) 0.0314(6) Uani 1 1 d .
H21A H 1.0545 0.9785 1.1542 0.047 Uiso 1 1 calc .
H21B H 0.9428 0.9947 1.1786 0.047 Uiso 1 1 calc .
H21C H 0.9819 1.0146 1.1011 0.047 Uiso 1 1 calc .
C22 C 0.8809(2) 0.6909(2) 0.77106(17) 0.0286(6) Uani 1 1 d .
H22 H 0.8064 0.6855 0.7806 0.034 Uiso 1 1 calc .
C23 C 0.9055(3) 0.5948(3) 0.7478(2) 0.0496(10) Uani 1 1 d .
H23A H 0.9774 0.5977 0.7357 0.074 Uiso 1 1 calc .
H23B H 0.8578 0.5537 0.7002 0.074 Uiso 1 1 calc .
H23C H 0.8969 0.5722 0.7928 0.074 Uiso 1 1 calc .
C24 C 0.8948(3) 0.7296(3) 0.7010(2) 0.0509(11) Uani 1 1 d .
H24A H 0.8837 0.7918 0.7185 0.076 Uiso 1 1 calc .
H24B H 0.8441 0.6919 0.6540 0.076 Uiso 1 1 calc .
H24C H 0.9654 0.7295 0.6866 0.076 Uiso 1 1 calc .
C25 C 0.6880(2) 0.92243(19) 1.00008(18) 0.0269(6) Uani 1 1 d .
H25A H 0.6266 0.9452 0.9883 0.040 Uiso 1 1 calc .
H25B H 0.7507 0.9698 1.0094 0.040 Uiso 1 1 calc .
H25C H 0.6817 0.9054 1.0483 0.040 Uiso 1 1 calc .
C26 C 0.7098(2) 0.8623(2) 0.82349(19) 0.0310(7) Uani 1 1 d .
H26A H 0.7135 0.8120 0.7747 0.047 Uiso 1 1 calc .
H26B H 0.7732 0.9095 0.8353 0.047 Uiso 1 1 calc .
H26C H 0.6492 0.8875 0.8151 0.047 Uiso 1 1 calc .
C27 C 0.6690(2) 0.63278(19) 1.03236(16) 0.0198(5) Uani 1 1 d .
C28 C 0.6396(2) 0.5473(2) 1.04233(18) 0.0243(6) Uani 1 1 d .
H28 H 0.6317 0.4933 0.9972 0.029 Uiso 1 1 calc .
C29 C 0.6219(2) 0.5419(2) 1.11939(19) 0.0301(6) Uani 1 1 d .
H29 H 0.6015 0.4846 1.1256 0.036 Uiso 1 1 calc .
C30 C 0.6349(2) 0.6219(2) 1.18611(19) 0.0302(6) Uani 1 1 d .
H30 H 0.6239 0.6186 1.2377 0.036 Uiso 1 1 calc .
C31 C 0.6642(2) 0.7073(2) 1.17695(19) 0.0310(6) Uani 1 1 d .
H31 H 0.6725 0.7611 1.2223 0.037 Uiso 1 1 calc .
C32 C 0.6814(2) 0.7128(2) 1.09983(18) 0.0256(6) Uani 1 1 d .
H32 H 0.7011 0.7703 1.0938 0.031 Uiso 1 1 calc .
C34 C 0.59032(18) 0.12841(16) 0.41937(14) 0.0137(4) Uani 1 1 d .
C35 C 0.50090(19) 0.13951(17) 0.46224(15) 0.0154(5) Uani 1 1 d .
C36 C 0.3995(2) 0.10282(18) 0.41839(17) 0.0209(5) Uani 1 1 d .
H36 H 0.3406 0.1111 0.4460 0.025 Uiso 1 1 calc .
C37 C 0.3844(2) 0.05449(19) 0.33482(17) 0.0236(6) Uani 1 1 d .
H37 H 0.3162 0.0299 0.3066 0.028 Uiso 1 1 calc .
C38 C 0.4716(2) 0.04304(19) 0.29352(16) 0.0223(5) Uani 1 1 d .
H38 H 0.4610 0.0099 0.2373 0.027 Uiso 1 1 calc .
C39 C 0.5750(2) 0.07961(17) 0.33349(15) 0.0170(5) Uani 1 1 d .
C40 C 0.51258(19) 0.18837(18) 0.55448(15) 0.0176(5) Uani 1 1 d .
H40 H 0.5878 0.2175 0.5730 0.021 Uiso 1 1 calc .
C41 C 0.4822(2) 0.1192(2) 0.59883(17) 0.0286(6) Uani 1 1 d .
H41A H 0.4081 0.0910 0.5835 0.043 Uiso 1 1 calc .
H41B H 0.4961 0.1509 0.6573 0.043 Uiso 1 1 calc .
H41C H 0.5235 0.0723 0.5836 0.043 Uiso 1 1 calc .
C42 C 0.4496(2) 0.2646(2) 0.57888(19) 0.0316(7) Uani 1 1 d .
H42A H 0.4693 0.3072 0.5504 0.047 Uiso 1 1 calc .
H42B H 0.4648 0.2969 0.6372 0.047 Uiso 1 1 calc .
H42C H 0.3750 0.2377 0.5645 0.047 Uiso 1 1 calc .
C43 C 0.6680(2) 0.06638(18) 0.28485(15) 0.0210(5) Uani 1 1 d .
H43 H 0.7331 0.1001 0.3227 0.025 Uiso 1 1 calc .
C44 C 0.6754(2) -0.0353(2) 0.25020(18) 0.0273(6) Uani 1 1 d .
H44A H 0.6828 -0.0588 0.2946 0.041 Uiso 1 1 calc .
H44B H 0.7360 -0.0406 0.2209 0.041 Uiso 1 1 calc .
H44C H 0.6121 -0.0703 0.2134 0.041 Uiso 1 1 calc .
C45 C 0.6634(3) 0.1076(2) 0.21559(18) 0.0358(7) Uani 1 1 d .
H45A H 0.6023 0.0737 0.1758 0.054 Uiso 1 1 calc .
H45B H 0.7265 0.1034 0.1893 0.054 Uiso 1 1 calc .
H45C H 0.6586 0.1713 0.2383 0.054 Uiso 1 1 calc .
C46 C 0.93136(18) 0.30077(16) 0.63347(15) 0.0143(4) Uani 1 1 d .
C47 C 0.89608(19) 0.31297(18) 0.71134(15) 0.0181(5) Uani 1 1 d .
C48 C 0.9693(2) 0.3583(2) 0.78248(16) 0.0257(6) Uani 1 1 d .
H48 H 0.9472 0.3640 0.8337 0.031 Uiso 1 1 calc .
C49 C 1.0732(2) 0.3944(2) 0.77827(18) 0.0306(7) Uani 1 1 d .
H49 H 1.1213 0.4226 0.8261 0.037 Uiso 1 1 calc .
C50 C 1.1057(2) 0.3884(2) 0.70273(17) 0.0245(6) Uani 1 1 d .
H50 H 1.1749 0.4160 0.7004 0.029 Uiso 1 1 calc .
C51 C 1.03685(19) 0.34196(17) 0.62998(15) 0.0170(5) Uani 1 1 d .
C52 C 0.7808(2) 0.28172(19) 0.72203(15) 0.0192(5) Uani 1 1 d .
H52 H 0.7399 0.2542 0.6670 0.023 Uiso 1 1 calc .
C53 C 0.7659(2) 0.2083(2) 0.76303(18) 0.0271(6) Uani 1 1 d .
H53A H 0.7944 0.1567 0.7323 0.041 Uiso 1 1 calc .
H53B H 0.6916 0.1879 0.7644 0.041 Uiso 1 1 calc .
H53C H 0.8023 0.2341 0.8182 0.041 Uiso 1 1 calc .
C54 C 0.7341(2) 0.3639(2) 0.77038(18) 0.0283(6) Uani 1 1 d .
H54A H 0.7711 0.3911 0.8254 0.042 Uiso 1 1 calc .
H54B H 0.6602 0.3428 0.7724 0.042 Uiso 1 1 calc .
H54C H 0.7420 0.4093 0.7436 0.042 Uiso 1 1 calc .
C55 C 1.07708(19) 0.34052(18) 0.54930(16) 0.0183(5) Uani 1 1 d .
H55 H 1.0211 0.3012 0.5046 0.022 Uiso 1 1 calc .
C56 C 1.1766(2) 0.2999(2) 0.53647(19) 0.0309(7) Uani 1 1 d .
H56A H 1.2334 0.3382 0.5788 0.046 Uiso 1 1 calc .
H56B H 1.1969 0.2976 0.4836 0.046 Uiso 1 1 calc .
H56C H 1.1620 0.2386 0.5390 0.046 Uiso 1 1 calc .
C57 C 1.0976(2) 0.4376(2) 0.5440(2) 0.0311(7) Uani 1 1 d .
H57A H 1.0344 0.4620 0.5521 0.047 Uiso 1 1 calc .
H57B H 1.1171 0.4348 0.4909 0.047 Uiso 1 1 calc .
H57C H 1.1543 0.4770 0.5859 0.047 Uiso 1 1 calc .
C58 C 0.8831(2) 0.03533(18) 0.44176(15) 0.0191(5) Uani 1 1 d .
C59 C 0.9646(2) 0.0851(2) 0.41480(17) 0.0266(6) Uani 1 1 d .
H59 H 0.9747 0.1492 0.4311 0.032 Uiso 1 1 calc .
C60 C 1.0311(3) 0.0397(2) 0.36372(19) 0.0329(7) Uani 1 1 d .
H60 H 1.0856 0.0734 0.3461 0.039 Uiso 1 1 calc .
C61 C 1.0166(3) -0.0548(2) 0.33920(17) 0.0326(7) Uani 1 1 d .
H61 H 1.0612 -0.0848 0.3049 0.039 Uiso 1 1 calc .
C62 C 0.9363(3) -0.1056(2) 0.36500(19) 0.0326(7) Uani 1 1 d .
H62 H 0.9261 -0.1697 0.3477 0.039 Uiso 1 1 calc .
C63 C 0.8704(2) -0.0602(2) 0.41728(18) 0.0261(6) Uani 1 1 d .
H63 H 0.8175 -0.0942 0.4360 0.031 Uiso 1 1 calc .
C70 C 0.9393(3) 0.3801(3) 0.0326(2) 0.0411(8) Uani 1 1 d .
C71 C 0.8751(5) 0.4448(4) 0.0202(4) 0.0295(12) Uani 0.5 1 d P
C72 C 0.9135(2) 0.5176(2) -0.00037(17) 0.0259(6) Uani 1 1 d .
C73 C 1.0197(4) 0.5438(4) -0.0111(3) 0.0221(11) Uani 0.5 1 d P
C74 C 0.9509(5) 0.5905(5) -0.0201(4) 0.0315(13) Uani 0.5 1 d P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Bi Bi -4.1077 10.2566 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Bi1 Si1 35.10(6) . .
N1 Bi1 N2 70.50(7) . .
N1 Bi1 C27 98.02(9) . .
N2 Bi1 Si1 35.46(5) . .
N2 Bi1 C27 100.50(9) . .
C27 Bi1 Si1 102.92(7) . .
N3 Bi2 Si2 35.31(5) . .
N3 Bi2 C58 100.32(8) . .
N4 Bi2 Si2 35.55(5) . .
N4 Bi2 N3 70.86(7) . .
N4 Bi2 C58 97.44(9) . .
C58 Bi2 Si2 100.45(7) . .
N1 Si1 Bi1 46.69(7) . .
N1 Si1 N2 93.65(10) . .
N1 Si1 C25 115.14(12) . .
N1 Si1 C26 114.57(12) . .
N2 Si1 Bi1 47.05(7) . .
N2 Si1 C25 113.91(12) . .
N2 Si1 C26 115.13(13) . .
C25 Si1 Bi1 129.70(10) . .
C26 Si1 Bi1 125.53(11) . .
C26 Si1 C25 104.77(15) . .
N3 Si2 Bi2 47.06(6) . .
N3 Si2 N4 93.90(10) . .
N3 Si2 C1D 111.30(11) . .
N3 Si2 C1U 117.49(12) . .
N4 Si2 Bi2 46.86(7) . .
N4 Si2 C1D 115.40(11) . .
N4 Si2 C1U 113.12(11) . .
C1D Si2 Bi2 124.77(9) . .
C1U Si2 Bi2 129.44(9) . .
C1U Si2 C1D 105.79(12) . .
Si1 N1 Bi1 98.21(9) . .
C1 N1 Bi1 124.30(16) . .
C1 N1 Si1 136.22(17) . .
Si1 N2 Bi1 97.49(9) . .
C13 N2 Bi1 128.66(16) . .
C13 N2 Si1 128.79(17) . .
Si2 N3 Bi2 97.63(9) . .
C34 N3 Bi2 127.17(15) . .
C34 N3 Si2 133.90(16) . .
Si2 N4 Bi2 97.59(9) . .
C46 N4 Bi2 123.55(15) . .
C46 N4 Si2 132.73(16) . .
N1 C1 C6 120.5(2) . .
C2 C1 N1 119.7(2) . .
C2 C1 C6 119.8(2) . .
C1 C2 C7 121.7(2) . .
C3 C2 C1 119.0(2) . .
C3 C2 C7 119.2(2) . .
C4 C3 C2 121.2(3) . .
C5 C4 C3 119.6(3) . .
C4 C5 C6 121.6(3) . .
C1 C6 C10 121.9(2) . .
C5 C6 C1 118.7(3) . .
C5 C6 C10 119.4(2) . .
C2 C7 C8 112.4(2) . .
C2 C7 C9 111.7(2) . .
C8 C7 C9 110.7(3) . .
C6 C10 C11 111.5(2) . .
C6 C10 C12 111.4(3) . .
C12 C10 C11 110.6(3) . .
C14 C13 N2 119.0(2) . .
C14 C13 C18 119.6(2) . .
C18 C13 N2 121.4(2) . .
C13 C14 C19 121.0(2) . .
C15 C14 C13 118.8(2) . .
C15 C14 C19 120.2(2) . .
C16 C15 C14 121.7(2) . .
C15 C16 C17 119.7(2) . .
C16 C17 C18 121.4(3) . .
C13 C18 C22 122.4(2) . .
C17 C18 C13 118.9(2) . .
C17 C18 C22 118.7(2) . .
C14 C19 C20 109.5(2) . .
C14 C19 C21 113.7(2) . .
C21 C19 C20 110.4(2) . .
C18 C22 C23 110.4(2) . .
C18 C22 C24 111.6(3) . .
C23 C22 C24 111.0(3) . .
C28 C27 Bi1 115.6(2) . .
C32 C27 Bi1 125.04(19) . .
C32 C27 C28 119.4(3) . .
C27 C28 C29 120.6(3) . .
C30 C29 C28 119.5(3) . .
C29 C30 C31 120.4(3) . .
C30 C31 C32 120.2(3) . .
C27 C32 C31 119.9(3) . .
N3 C34 C35 120.1(2) . .
N3 C34 C39 120.2(2) . .
C39 C34 C35 119.6(2) . .
C34 C35 C40 121.9(2) . .
C36 C35 C34 119.0(2) . .
C36 C35 C40 119.1(2) . .
C37 C36 C35 121.4(2) . .
C38 C37 C36 119.4(2) . .
C37 C38 C39 121.9(2) . .
C34 C39 C43 121.6(2) . .
C38 C39 C34 118.6(2) . .
C38 C39 C43 119.8(2) . .
C35 C40 C41 110.9(2) . .
C35 C40 C42 112.9(2) . .
C42 C40 C41 110.5(2) . .
C39 C43 C44 112.0(2) . .
C39 C43 C45 111.4(2) . .
C44 C43 C45 110.5(2) . .
C47 C46 N4 121.3(2) . .
C51 C46 N4 119.7(2) . .
C51 C46 C47 119.0(2) . .
C46 C47 C52 123.2(2) . .
C48 C47 C46 119.0(2) . .
C48 C47 C52 117.8(2) . .
C49 C48 C47 121.4(3) . .
C48 C49 C50 119.6(2) . .
C49 C50 C51 121.3(3) . .
C46 C51 C55 122.1(2) . .
C50 C51 C46 119.5(2) . .
C50 C51 C55 118.4(2) . .
C47 C52 C53 113.0(2) . .
C47 C52 C54 111.4(2) . .
C53 C52 C54 109.7(2) . .
C51 C55 C56 112.5(2) . .
C51 C55 C57 110.4(2) . .
C57 C55 C56 110.5(2) . .
C59 C58 Bi2 122.8(2) . .
C63 C58 Bi2 118.1(2) . .
C63 C58 C59 118.7(3) . .
C60 C59 C58 120.4(3) . .
C61 C60 C59 120.1(3) . .
C60 C61 C62 120.5(3) . .
C61 C62 C63 119.5(3) . .
C58 C63 C62 120.7(3) . .
C73 C70 C71 56.9(4) 2_765 .
C73 C70 C74 53.3(4) 2_765 2_765
C74 C70 C71 110.1(4) 2_765 .
C72 C71 C70 123.5(5) . .
C72 C71 C73 65.2(4) . 2_765
C73 C71 C70 58.3(4) 2_765 .
C71 C72 C73 124.5(4) . .
C71 C72 C73 58.7(4) . 2_765
C73 C72 C73 65.8(4) . 2_765
C74 C72 C71 179.3(5) . .
C74 C72 C73 56.1(4) . .
C74 C72 C73 121.9(4) . 2_765
C70 C73 C72 124.9(4) 2_765 .
C70 C73 C72 120.9(4) 2_765 2_765
C70 C73 C73 176.3(7) 2_765 2_765
C71 C73 C70 64.8(4) 2_765 2_765
C71 C73 C72 56.1(4) 2_765 2_765
C71 C73 C72 170.2(5) 2_765 .
C71 C73 C73 111.7(6) 2_765 2_765
C72 C73 C72 114.2(4) . 2_765
C72 C73 C73 58.6(4) . 2_765
C72 C73 C73 55.6(3) 2_765 2_765
C74 C73 C70 66.4(4) . 2_765
C74 C73 C71 131.2(6) . 2_765
C74 C73 C72 58.5(4) . .
C74 C73 C72 172.6(6) . 2_765
C74 C73 C73 117.1(7) . 2_765
C72 C74 C70 125.8(5) . 2_765
C73 C74 C70 60.3(4) . 2_765
C73 C74 C72 65.4(4) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Bi1 Si1 2.9493(7) .
Bi1 N1 2.168(2) .
Bi1 N2 2.177(2) .
Bi1 C27 2.253(3) .
Bi2 Si2 2.9504(6) .
Bi2 N3 2.1790(19) .
Bi2 N4 2.172(2) .
Bi2 C58 2.252(3) .
Si1 N1 1.713(2) .
Si1 N2 1.726(2) .
Si1 C25 1.861(3) .
Si1 C26 1.854(3) .
Si2 N3 1.721(2) .
Si2 N4 1.731(2) .
Si2 C1D 1.867(3) .
Si2 C1U 1.864(3) .
N1 C1 1.414(3) .
N2 C13 1.420(3) .
N3 C34 1.414(3) .
N4 C46 1.424(3) .
C1 C2 1.411(4) .
C1 C6 1.414(4) .
C2 C3 1.392(4) .
C2 C7 1.516(4) .
C3 C4 1.381(4) .
C4 C5 1.376(4) .
C5 C6 1.394(4) .
C6 C10 1.519(4) .
C7 C8 1.529(4) .
C7 C9 1.535(4) .
C10 C11 1.532(4) .
C10 C12 1.528(4) .
C13 C14 1.414(3) .
C13 C18 1.419(4) .
C14 C15 1.392(4) .
C14 C19 1.513(4) .
C15 C16 1.376(4) .
C16 C17 1.379(4) .
C17 C18 1.391(4) .
C18 C22 1.519(4) .
C19 C20 1.531(4) .
C19 C21 1.527(4) .
C22 C23 1.522(5) .
C22 C24 1.529(4) .
C27 C28 1.391(4) .
C27 C32 1.383(4) .
C28 C29 1.395(4) .
C29 C30 1.375(5) .
C30 C31 1.383(4) .
C31 C32 1.396(4) .
C34 C35 1.418(3) .
C34 C39 1.416(3) .
C35 C36 1.393(3) .
C35 C40 1.515(3) .
C36 C37 1.381(4) .
C37 C38 1.379(4) .
C38 C39 1.392(3) .
C39 C43 1.517(4) .
C40 C41 1.530(4) .
C40 C42 1.524(4) .
C43 C44 1.528(4) .
C43 C45 1.537(4) .
C46 C47 1.416(3) .
C46 C51 1.412(3) .
C47 C48 1.399(3) .
C47 C52 1.523(3) .
C48 C49 1.375(4) .
C49 C50 1.379(4) .
C50 C51 1.392(3) .
C51 C55 1.517(4) .
C52 C53 1.525(4) .
C52 C54 1.536(4) .
C55 C56 1.529(4) .
C55 C57 1.526(4) .
C58 C59 1.392(4) .
C58 C63 1.388(4) .
C59 C60 1.389(4) .
C60 C61 1.371(5) .
C61 C62 1.379(5) .
C62 C63 1.394(4) .
C70 C71 1.473(7) .
C70 C73 1.386(6) 2_765
C70 C74 1.461(7) 2_765
C71 C72 1.325(7) .
C71 C73 1.364(8) 2_765
C72 C73 1.449(6) 2_765
C72 C73 1.401(6) .
C72 C74 1.313(7) .
C73 C70 1.386(6) 2_765
C73 C71 1.364(8) 2_765
C73 C72 1.449(6) 2_765
C73 C73 1.549(11) 2_765
C73 C74 1.278(8) .
C74 C70 1.462(7) 2_765
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
Bi1 Si1 N1 C1 -166.8(3) . .
Bi1 Si1 N2 C13 156.1(3) . .
Bi1 N1 C1 C2 107.4(2) . .
Bi1 N1 C1 C6 -71.0(3) . .
Bi1 N2 C13 C14 -118.5(2) . .
Bi1 N2 C13 C18 62.3(3) . .
Bi1 C27 C28 C29 179.8(2) . .
Bi1 C27 C32 C31 -179.4(2) . .
Bi2 Si2 N3 C34 167.2(3) . .
Bi2 Si2 N4 C46 -151.9(3) . .
Bi2 N3 C34 C35 80.4(3) . .
Bi2 N3 C34 C39 -98.8(2) . .
Bi2 N4 C46 C47 -53.8(3) . .
Bi2 N4 C46 C51 124.4(2) . .
Bi2 C58 C59 C60 173.6(2) . .
Bi2 C58 C63 C62 -175.0(2) . .
Si1 N1 C1 C2 -88.5(3) . .
Si1 N1 C1 C6 93.1(3) . .
Si1 N2 C13 C14 92.5(3) . .
Si1 N2 C13 C18 -86.7(3) . .
Si2 N3 C34 C35 -83.6(3) . .
Si2 N3 C34 C39 97.3(3) . .
Si2 N4 C46 C47 92.1(3) . .
Si2 N4 C46 C51 -89.6(3) . .
N1 Si1 N2 Bi1 3.22(10) . .
N1 Si1 N2 C13 159.3(2) . .
N1 C1 C2 C3 -177.2(2) . .
N1 C1 C2 C7 3.6(4) . .
N1 C1 C6 C5 175.6(2) . .
N1 C1 C6 C10 -4.1(4) . .
N2 Si1 N1 Bi1 -3.24(10) . .
N2 Si1 N1 C1 -170.0(3) . .
N2 C13 C14 C15 -178.5(2) . .
N2 C13 C14 C19 3.9(3) . .
N2 C13 C18 C17 178.7(2) . .
N2 C13 C18 C22 -3.0(4) . .
N3 Si2 N4 Bi2 0.97(10) . .
N3 Si2 N4 C46 -150.9(2) . .
N3 C34 C35 C36 -179.9(2) . .
N3 C34 C35 C40 -1.2(3) . .
N3 C34 C39 C38 178.7(2) . .
N3 C34 C39 C43 -1.2(3) . .
N4 Si2 N3 Bi2 -0.97(10) . .
N4 Si2 N3 C34 166.2(2) . .
N4 C46 C47 C48 172.5(2) . .
N4 C46 C47 C52 -9.4(4) . .
N4 C46 C51 C50 -174.2(2) . .
N4 C46 C51 C55 8.2(3) . .
C1 C2 C3 C4 0.9(4) . .
C1 C2 C7 C8 -116.2(3) . .
C1 C2 C7 C9 118.6(3) . .
C1 C6 C10 C11 115.1(3) . .
C1 C6 C10 C12 -120.7(3) . .
C1D Si2 N3 Bi2 118.25(11) . .
C1D Si2 N3 C34 -74.6(3) . .
C1D Si2 N4 Bi2 -114.84(12) . .
C1D Si2 N4 C46 93.3(2) . .
C1U Si2 N3 Bi2 -119.60(11) . .
C1U Si2 N3 C34 47.6(3) . .
C1U Si2 N4 Bi2 123.13(11) . .
C1U Si2 N4 C46 -28.8(3) . .
C2 C1 C6 C5 -2.8(4) . .
C2 C1 C6 C10 177.5(2) . .
C2 C3 C4 C5 -1.4(4) . .
C3 C2 C7 C8 64.5(3) . .
C3 C2 C7 C9 -60.6(4) . .
C3 C4 C5 C6 -0.2(4) . .
C4 C5 C6 C1 2.3(4) . .
C4 C5 C6 C10 -178.0(3) . .
C5 C6 C10 C11 -64.6(3) . .
C5 C6 C10 C12 59.5(3) . .
C6 C1 C2 C3 1.2(4) . .
C6 C1 C2 C7 -178.0(2) . .
C7 C2 C3 C4 -179.8(3) . .
C13 C14 C15 C16 -0.6(4) . .
C13 C14 C19 C20 94.6(3) . .
C13 C14 C19 C21 -141.4(2) . .
C13 C18 C22 C23 -109.3(3) . .
C13 C18 C22 C24 126.7(3) . .
C14 C13 C18 C17 -0.5(4) . .
C14 C13 C18 C22 177.8(2) . .
C14 C15 C16 C17 0.3(4) . .
C15 C14 C19 C20 -82.9(3) . .
C15 C14 C19 C21 41.1(3) . .
C15 C16 C17 C18 -0.1(4) . .
C16 C17 C18 C13 0.2(4) . .
C16 C17 C18 C22 -178.2(3) . .
C17 C18 C22 C23 69.1(3) . .
C17 C18 C22 C24 -54.9(4) . .
C18 C13 C14 C15 0.7(4) . .
C18 C13 C14 C19 -176.9(2) . .
C19 C14 C15 C16 177.0(2) . .
C25 Si1 N1 Bi1 -121.83(12) . .
C25 Si1 N1 C1 71.4(3) . .
C25 Si1 N2 Bi1 122.82(12) . .
C25 Si1 N2 C13 -81.1(2) . .
C26 Si1 N1 Bi1 116.56(13) . .
C26 Si1 N1 C1 -50.2(3) . .
C26 Si1 N2 Bi1 -116.12(13) . .
C26 Si1 N2 C13 39.9(3) . .
C27 C28 C29 C30 -0.7(4) . .
C28 C27 C32 C31 -0.1(4) . .
C28 C29 C30 C31 0.7(5) . .
C29 C30 C31 C32 -0.3(5) . .
C30 C31 C32 C27 0.0(4) . .
C32 C27 C28 C29 0.4(4) . .
C34 C35 C36 C37 1.4(4) . .
C34 C35 C40 C41 -107.2(3) . .
C34 C35 C40 C42 128.2(3) . .
C34 C39 C43 C44 114.3(3) . .
C34 C39 C43 C45 -121.3(3) . .
C35 C34 C39 C38 -0.5(3) . .
C35 C34 C39 C43 179.6(2) . .
C35 C36 C37 C38 -0.7(4) . .
C36 C35 C40 C41 71.6(3) . .
C36 C35 C40 C42 -53.1(3) . .
C36 C37 C38 C39 -0.6(4) . .
C37 C38 C39 C34 1.2(4) . .
C37 C38 C39 C43 -179.0(2) . .
C38 C39 C43 C44 -65.5(3) . .
C38 C39 C43 C45 58.9(3) . .
C39 C34 C35 C36 -0.7(3) . .
C39 C34 C35 C40 178.0(2) . .
C40 C35 C36 C37 -177.4(2) . .
C46 C47 C48 C49 2.8(4) . .
C46 C47 C52 C53 117.7(3) . .
C46 C47 C52 C54 -118.2(3) . .
C46 C51 C55 C56 -125.4(3) . .
C46 C51 C55 C57 110.6(3) . .
C47 C46 C51 C50 4.1(4) . .
C47 C46 C51 C55 -173.5(2) . .
C47 C48 C49 C50 1.9(5) . .
C48 C47 C52 C53 -64.2(3) . .
C48 C47 C52 C54 59.9(3) . .
C48 C49 C50 C51 -3.6(5) . .
C49 C50 C51 C46 0.6(4) . .
C49 C50 C51 C55 178.3(3) . .
C50 C51 C55 C56 57.0(3) . .
C50 C51 C55 C57 -67.0(3) . .
C51 C46 C47 C48 -5.8(4) . .
C51 C46 C47 C52 172.3(2) . .
C52 C47 C48 C49 -175.4(3) . .
C58 C59 C60 C61 0.3(4) . .
C59 C58 C63 C62 -1.6(4) . .
C59 C60 C61 C62 -0.2(4) . .
C60 C61 C62 C63 -0.8(4) . .
C61 C62 C63 C58 1.7(4) . .
C63 C58 C59 C60 0.6(4) . .
C70 C71 C72 C73 -1.6(8) . .
C70 C71 C72 C73 0.0(4) . 2_765
C70 C73 C74 C72 179.5(5) 2_765 .
C71 C72 C73 C70 -180.0(5) . 2_765
C71 C72 C73 C72 1.5(6) . 2_765
C71 C72 C73 C73 1.5(6) . 2_765
C71 C72 C73 C74 -179.4(6) . .
C71 C73 C74 C70 -1.3(7) 2_765 2_765
C71 C73 C74 C72 178.2(7) 2_765 .
C72 C73 C74 C70 -179.5(5) . 2_765
C73 C70 C71 C72 0.0(5) 2_765 .
C73 C71 C72 C73 -1.6(6) 2_765 .
C73 C72 C73 C70 178.6(8) 2_765 2_765
C73 C72 C73 C72 0.004(0) 2_765 2_765
C73 C72 C73 C74 179.1(6) 2_765 .
C73 C72 C74 C70 -0.4(8) 2_765 2_765
C73 C72 C74 C70 0.5(5) . 2_765
C73 C72 C74 C73 -1.0(7) 2_765 .
C73 C73 C74 C70 -178.7(7) 2_765 2_765
C73 C73 C74 C72 0.9(6) 2_765 .
C74 C70 C71 C72 0.9(7) 2_765 .
C74 C70 C71 C73 0.9(5) 2_765 2_765
C74 C72 C73 C70 -0.5(5) . 2_765
C74 C72 C73 C72 -179.1(6) . 2_765
C74 C72 C73 C73 -179.1(6) . 2_765
