#------------------------------------------------------------------------------
#$Date: 2016-03-23 22:32:00 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179484 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/81/4338173.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4338173
loop_
_publ_author_name
'Dau, Minh Thuy'
'Shakirova, Julia R.'
'Karttunen, Antti J.'
'Grachova, Elena V.'
'Tunik, Sergey P.'
'Melnikov, Alexey S.'
'Pakkanen, Tapani A.'
'Koshevoy, Igor O.'
_publ_section_title
;
 Coinage metal complexes supported by the tri- and tetraphosphine ligands.
;
_journal_issue                   9
_journal_name_full               'Inorganic chemistry'
_journal_page_first              4705
_journal_page_last               4715
_journal_paper_doi               10.1021/ic500402m
_journal_volume                  53
_journal_year                    2014
_chemical_formula_moiety
'C64 H62 Au Cu2 O2 P6, 3(F6 P), 2(C4 H10 O), 2(C H2 Cl2)'
_chemical_formula_sum            'C74 H86 Au Cl4 Cu2 F18 O4 P9'
_chemical_formula_weight         2126.00
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                114.4110(10)
_cell_angle_beta                 104.1270(10)
_cell_angle_gamma                106.1380(10)
_cell_formula_units_Z            1
_cell_length_a                   13.4925(2)
_cell_length_b                   13.9213(2)
_cell_length_c                   14.0484(3)
_cell_measurement_reflns_used    9424
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      35.00
_cell_measurement_theta_min      2.48
_cell_volume                     2104.89(7)
_computing_cell_refinement       'SAINT (Bruker AXS, 2009)'
_computing_data_collection       'APEX2 (Bruker AXS, 2010)'
_computing_data_reduction        'SAINT (Bruker AXS, 2009)'
_computing_molecular_graphics    'Diamond v.3.2g (Brandenburg, 2011)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SUPERFLIP (Palatinus & Chapuis, 2007)'
_diffrn_ambient_temperature      120(2)
_diffrn_detector_area_resol_mean 16
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device
'62mm x 62mm CCD camera on three-circle goniostat'
_diffrn_measurement_device_type  'Bruker SMART APEX II CCD'
_diffrn_measurement_method       'φ scans and ω scans'
_diffrn_radiation_monochromator  'flat graphite crystal'
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0177
_diffrn_reflns_av_sigmaI/netI    0.0138
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            40544
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         1.72
_exptl_absorpt_coefficient_mu    2.624
_exptl_absorpt_correction_T_max  0.5270
_exptl_absorpt_correction_T_min  0.4355
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'SADABS (Sheldrick, 2008)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.677
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1064
_exptl_crystal_size_max          0.38
_exptl_crystal_size_mid          0.31
_exptl_crystal_size_min          0.28
_refine_diff_density_max         3.577
_refine_diff_density_min         -1.229
_refine_diff_density_rms         0.079
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.083
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     564
_refine_ls_number_reflns         8275
_refine_ls_number_restraints     28
_refine_ls_restrained_S_all      1.082
_refine_ls_R_factor_all          0.0255
_refine_ls_R_factor_gt           0.0253
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0260P)²+4.5801P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0627
_refine_ls_wR_factor_ref         0.0628
_reflns_number_gt                8192
_reflns_number_total             8275
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic500402m_si_003.cif
_cod_data_source_block           2
_cod_depositor_comments
'Adding full bibliography for 4338172--4338179.cif.'
_cod_original_cell_volume        2104.89(6)
_cod_database_code               4338173
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.6672(2) 0.2320(2) 0.0013(2) 0.0174(5) Uani 1 1 d . . .
C2 C 0.5854(2) 0.1196(3) -0.0437(3) 0.0255(6) Uani 1 1 d . . .
H2 H 0.6056 0.0560 -0.0640 0.031 Uiso 1 1 calc R . .
C3 C 0.4747(3) 0.1006(3) -0.0588(3) 0.0325(7) Uani 1 1 d . . .
H3 H 0.4194 0.0241 -0.0889 0.039 Uiso 1 1 calc R . .
C4 C 0.4444(3) 0.1927(3) -0.0303(3) 0.0303(7) Uani 1 1 d . . .
H4 H 0.3686 0.1794 -0.0402 0.036 Uiso 1 1 calc R . .
C5 C 0.5242(3) 0.3036(3) 0.0123(3) 0.0264(6) Uani 1 1 d . . .
H5 H 0.5033 0.3667 0.0313 0.032 Uiso 1 1 calc R . .
C6 C 0.6352(2) 0.3233(3) 0.0275(2) 0.0215(6) Uani 1 1 d . . .
H6 H 0.6897 0.3998 0.0561 0.026 Uiso 1 1 calc R . .
C7 C 0.8321(2) 0.1497(2) 0.0531(2) 0.0181(5) Uani 1 1 d . . .
C8 C 0.8664(3) 0.0690(3) -0.0094(3) 0.0285(7) Uani 1 1 d . . .
H8 H 0.8810 0.0687 -0.0723 0.034 Uiso 1 1 calc R . .
C9 C 0.8794(3) -0.0118(3) 0.0207(4) 0.0403(9) Uani 1 1 d . . .
H9 H 0.9020 -0.0679 -0.0226 0.048 Uiso 1 1 calc R . .
C10 C 0.8598(3) -0.0110(3) 0.1124(4) 0.0411(9) Uani 1 1 d . . .
H10 H 0.8689 -0.0664 0.1322 0.049 Uiso 1 1 calc R . .
C11 C 0.8269(3) 0.0697(3) 0.1758(3) 0.0346(8) Uani 1 1 d . . .
H11 H 0.8142 0.0705 0.2397 0.042 Uiso 1 1 calc R . .
C12 C 0.8124(2) 0.1498(3) 0.1463(3) 0.0248(6) Uani 1 1 d . . .
H12 H 0.7889 0.2049 0.1895 0.030 Uiso 1 1 calc R . .
C13 C 1.1187(2) 0.3959(2) 0.1623(2) 0.0174(5) Uani 1 1 d . . .
C14 C 1.1840(2) 0.3862(3) 0.0987(2) 0.0225(6) Uani 1 1 d . . .
H14 H 1.1763 0.4122 0.0458 0.027 Uiso 1 1 calc R . .
C15 C 1.2599(3) 0.3387(3) 0.1125(3) 0.0321(7) Uani 1 1 d . . .
H15 H 1.3052 0.3334 0.0700 0.039 Uiso 1 1 calc R . .
C16 C 1.2701(3) 0.2992(3) 0.1879(3) 0.0383(8) Uani 1 1 d . . .
H16 H 1.3226 0.2669 0.1975 0.046 Uiso 1 1 calc R . .
C17 C 1.2039(3) 0.3064(3) 0.2496(3) 0.0388(8) Uani 1 1 d . . .
H17 H 1.2105 0.2778 0.3006 0.047 Uiso 1 1 calc R . .
C18 C 1.1282(3) 0.3548(3) 0.2378(3) 0.0269(6) Uani 1 1 d . . .
H18 H 1.0832 0.3599 0.2806 0.032 Uiso 1 1 calc R . .
C19 C 0.6729(2) 0.3237(2) -0.2947(2) 0.0175(5) Uani 1 1 d . . .
C20 C 0.6188(2) 0.3221(3) -0.2223(3) 0.0226(6) Uani 1 1 d . . .
H20 H 0.6430 0.2990 -0.1693 0.027 Uiso 1 1 calc R . .
C21 C 0.5295(3) 0.3542(3) -0.2271(3) 0.0296(7) Uani 1 1 d . . .
H21 H 0.4927 0.3528 -0.1777 0.036 Uiso 1 1 calc R . .
C22 C 0.4946(3) 0.3879(3) -0.3039(3) 0.0311(7) Uani 1 1 d . . .
H22 H 0.4334 0.4093 -0.3077 0.037 Uiso 1 1 calc R . .
C23 C 0.5486(3) 0.3906(3) -0.3757(3) 0.0292(7) Uani 1 1 d . . .
H23 H 0.5245 0.4146 -0.4279 0.035 Uiso 1 1 calc R . .
C24 C 0.6372(2) 0.3586(3) -0.3720(2) 0.0233(6) Uani 1 1 d . . .
H24 H 0.6737 0.3603 -0.4216 0.028 Uiso 1 1 calc R . .
C25 C 0.7362(2) 0.1519(2) -0.4294(2) 0.0169(5) Uani 1 1 d . . .
C26 C 0.6223(3) 0.0895(3) -0.5025(3) 0.0262(6) Uani 1 1 d . . .
H26 H 0.5685 0.1126 -0.4788 0.031 Uiso 1 1 calc R . .
C27 C 0.5865(3) -0.0067(3) -0.6105(3) 0.0340(7) Uani 1 1 d . . .
H27 H 0.5083 -0.0491 -0.6602 0.041 Uiso 1 1 calc R . .
C28 C 0.6636(3) -0.0408(3) -0.6458(3) 0.0287(7) Uani 1 1 d . . .
H28 H 0.6388 -0.1063 -0.7199 0.034 Uiso 1 1 calc R . .
C29 C 0.7771(3) 0.0200(3) -0.5737(3) 0.0284(7) Uani 1 1 d . . .
H29 H 0.8303 -0.0037 -0.5982 0.034 Uiso 1 1 calc R . .
C30 C 0.8139(3) 0.1158(3) -0.4655(3) 0.0238(6) Uani 1 1 d . . .
H30 H 0.8921 0.1569 -0.4158 0.029 Uiso 1 1 calc R . .
C31 C 0.8983(2) 0.3953(2) 0.1518(2) 0.0162(5) Uani 1 1 d . . .
H31A H 0.8563 0.4443 0.1628 0.019 Uiso 1 1 calc R . .
H31B H 0.9128 0.3808 0.2161 0.019 Uiso 1 1 calc R . .
C32 C 0.8998(2) 0.3870(2) -0.2874(2) 0.0152(5) Uani 1 1 d . . .
H32A H 0.9572 0.3577 -0.3003 0.018 Uiso 1 1 calc R . .
H32B H 0.8678 0.3976 -0.3518 0.018 Uiso 1 1 calc R . .
Au1 Au 1.0000 0.5000 0.0000 0.01385(5) Uani 1 2 d S . .
Cu1 Cu 0.84427(3) 0.25385(3) -0.13527(2) 0.01515(7) Uani 1 1 d . . .
F1 F 1.1450(2) 0.3866(2) -0.14453(19) 0.0454(5) Uani 1 1 d . . .
F2 F 1.1718(2) 0.2270(2) -0.1696(2) 0.0527(6) Uani 1 1 d . . .
F3 F 1.26530(19) 0.2482(2) -0.2791(2) 0.0541(6) Uani 1 1 d . . .
F4 F 1.32005(19) 0.3968(2) -0.0994(2) 0.0513(6) Uani 1 1 d . . .
F5 F 1.2384(2) 0.40804(19) -0.25215(19) 0.0479(6) Uani 1 1 d . . .
F6 F 1.08985(18) 0.2366(2) -0.3227(2) 0.0522(6) Uani 1 1 d . . .
F7 F 0.9437(2) 0.37069(18) 0.39187(17) 0.0455(5) Uani 1 1 d . . .
F8 F 1.11092(18) 0.5273(2) 0.47510(18) 0.0455(5) Uani 1 1 d . . .
F9 F 1.05297(18) 0.45748(19) 0.58112(17) 0.0394(5) Uani 1 1 d . . .
O1 O 0.9426(2) 0.1597(2) -0.1794(2) 0.0328(5) Uani 1 1 d . . .
H2O1 H 0.9153 0.0795 -0.2364 0.049 Uiso 1 1 d R . .
H1O1 H 1.0165 0.1920 -0.1734 0.049 Uiso 1 1 d R . .
P1 P 0.81138(6) 0.25487(6) 0.01539(6) 0.01410(13) Uani 1 1 d . . .
P2 P 1.03215(5) 0.47261(6) 0.15366(5) 0.01322(13) Uani 1 1 d . . .
P3 P 0.78614(5) 0.27795(6) -0.28650(6) 0.01435(13) Uani 1 1 d . . .
P4 P 1.20636(7) 0.31684(7) -0.21227(7) 0.02462(16) Uani 1 1 d . . .
P5 P 1.0000 0.5000 0.5000 0.0273(2) Uani 1 2 d S . .
O2 O 0.8448(4) -0.0640(3) -0.3433(3) 0.0339(10) Uani 0.779(8) 1 d P A 1
C34 C 0.6674(5) -0.0858(6) -0.3318(6) 0.0470(16) Uani 0.779(8) 1 d P A 1
H34A H 0.5853 -0.1299 -0.3754 0.071 Uiso 0.779(8) 1 calc PR A 1
H34B H 0.6885 -0.0027 -0.3038 0.071 Uiso 0.779(8) 1 calc PR A 1
H34C H 0.6907 -0.0966 -0.2666 0.071 Uiso 0.779(8) 1 calc PR A 1
C35 C 0.7251(6) -0.1288(5) -0.4077(5) 0.0397(14) Uani 0.779(8) 1 d P A 1
H35A H 0.7036 -0.2129 -0.4369 0.048 Uiso 0.779(8) 1 calc PR A 1
H35B H 0.7014 -0.1186 -0.4740 0.048 Uiso 0.779(8) 1 calc PR A 1
C36 C 0.9101(5) -0.0955(5) -0.4085(5) 0.0409(15) Uani 0.779(8) 1 d P A 1
H36A H 0.9882 -0.0329 -0.3665 0.049 Uiso 0.779(8) 1 calc PR A 1
H36B H 0.8767 -0.1016 -0.4830 0.049 Uiso 0.779(8) 1 calc PR A 1
C37 C 0.9142(4) -0.2110(5) -0.4303(4) 0.0401(13) Uani 0.779(8) 1 d P A 1
H37A H 0.9602 -0.2279 -0.4737 0.060 Uiso 0.779(8) 1 calc PR A 1
H37B H 0.8372 -0.2739 -0.4742 0.060 Uiso 0.779(8) 1 calc PR A 1
H37C H 0.9477 -0.2053 -0.3568 0.060 Uiso 0.779(8) 1 calc PR A 1
C136 C 0.8149(18) -0.169(2) -0.4525(18) 0.056(4) Uani 0.221(8) 1 d P A 2
H13A H 0.7772 -0.2513 -0.4733 0.067 Uiso 0.221(8) 1 calc PR A 2
H13B H 0.7852 -0.1635 -0.5208 0.067 Uiso 0.221(8) 1 calc PR A 2
C135 C 0.673(3) -0.122(3) -0.382(2) 0.056(4) Uani 0.221(8) 1 d PU A 2
H13C H 0.6402 -0.1091 -0.4444 0.067 Uiso 0.221(8) 1 calc PR A 2
H13D H 0.6347 -0.2061 -0.4097 0.067 Uiso 0.221(8) 1 calc PR A 2
C134 C 0.653(2) -0.059(3) -0.289(2) 0.056(4) Uani 0.221(8) 1 d PU A 2
H13E H 0.5715 -0.0846 -0.3113 0.083 Uiso 0.221(8) 1 calc PR A 2
H13F H 0.6893 0.0241 -0.2625 0.083 Uiso 0.221(8) 1 calc PR A 2
H13G H 0.6848 -0.0722 -0.2273 0.083 Uiso 0.221(8) 1 calc PR A 2
O12 O 0.7931(19) -0.0861(19) -0.3505(19) 0.055(5) Uani 0.221(8) 1 d PU A 2
C137 C 0.928(2) -0.132(3) -0.414(2) 0.056(4) Uani 0.221(8) 1 d PU A 2
H13H H 0.9465 -0.1799 -0.4754 0.083 Uiso 0.221(8) 1 calc PR A 2
H13I H 0.9559 -0.1405 -0.3479 0.083 Uiso 0.221(8) 1 calc PR A 2
H13J H 0.9643 -0.0503 -0.3917 0.083 Uiso 0.221(8) 1 calc PR A 2
C33 C 0.3461(10) 0.6663(9) 0.6952(10) 0.043(2) Uani 0.572(10) 1 d PD B 3
H33A H 0.3737 0.6903 0.7772 0.051 Uiso 0.572(10) 1 calc PR B 3
H33B H 0.2649 0.6117 0.6574 0.051 Uiso 0.572(10) 1 calc PR B 3
Cl1 Cl 0.3615(3) 0.7897(3) 0.6836(3) 0.0601(10) Uani 0.572(10) 1 d PD B 3
Cl2 Cl 0.4200(7) 0.5957(8) 0.6331(8) 0.102(2) Uani 0.572(10) 1 d PD B 3
Cl12 Cl 0.3637(5) 0.5272(5) 0.5675(4) 0.0582(13) Uani 0.428(10) 1 d PD B 4
Cl11 Cl 0.4000(6) 0.7615(5) 0.7215(6) 0.100(3) Uani 0.428(10) 1 d PD B 4
C133 C 0.3421(14) 0.6154(10) 0.6841(11) 0.053(4) Uani 0.428(10) 1 d PD B 4
H13K H 0.3774 0.6089 0.7505 0.063 Uiso 0.428(10) 1 calc PR B 4
H13L H 0.2599 0.5878 0.6646 0.063 Uiso 0.428(10) 1 calc PR B 4
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C6 C1 C2 119.0(3) . .
C6 C1 P1 121.3(2) . .
C2 C1 P1 119.6(2) . .
C3 C2 C1 120.1(3) . .
C3 C2 H2 120.0 . .
C1 C2 H2 120.0 . .
C4 C3 C2 120.3(3) . .
C4 C3 H3 119.8 . .
C2 C3 H3 119.8 . .
C5 C4 C3 119.9(3) . .
C5 C4 H4 120.0 . .
C3 C4 H4 120.0 . .
C4 C5 C6 120.1(3) . .
C4 C5 H5 120.0 . .
C6 C5 H5 120.0 . .
C5 C6 C1 120.6(3) . .
C5 C6 H6 119.7 . .
C1 C6 H6 119.7 . .
C8 C7 C12 119.5(3) . .
C8 C7 P1 121.1(2) . .
C12 C7 P1 119.4(2) . .
C7 C8 C9 119.5(3) . .
C7 C8 H8 120.3 . .
C9 C8 H8 120.3 . .
C10 C9 C8 120.5(3) . .
C10 C9 H9 119.7 . .
C8 C9 H9 119.7 . .
C9 C10 C11 120.4(3) . .
C9 C10 H10 119.8 . .
C11 C10 H10 119.8 . .
C10 C11 C12 119.9(3) . .
C10 C11 H11 120.1 . .
C12 C11 H11 120.1 . .
C11 C12 C7 120.2(3) . .
C11 C12 H12 119.9 . .
C7 C12 H12 119.9 . .
C14 C13 C18 119.7(3) . .
C14 C13 P2 118.9(2) . .
C18 C13 P2 121.2(2) . .
C15 C14 C13 120.2(3) . .
C15 C14 H14 119.9 . .
C13 C14 H14 119.9 . .
C16 C15 C14 120.1(3) . .
C16 C15 H15 120.0 . .
C14 C15 H15 120.0 . .
C15 C16 C17 120.1(3) . .
C15 C16 H16 119.9 . .
C17 C16 H16 119.9 . .
C16 C17 C18 120.6(3) . .
C16 C17 H17 119.7 . .
C18 C17 H17 119.7 . .
C17 C18 C13 119.3(3) . .
C17 C18 H18 120.3 . .
C13 C18 H18 120.3 . .
C20 C19 C24 119.4(3) . .
C20 C19 P3 118.3(2) . .
C24 C19 P3 122.3(2) . .
C19 C20 C21 120.5(3) . .
C19 C20 H20 119.8 . .
C21 C20 H20 119.8 . .
C22 C21 C20 119.7(3) . .
C22 C21 H21 120.2 . .
C20 C21 H21 120.2 . .
C21 C22 C23 120.2(3) . .
C21 C22 H22 119.9 . .
C23 C22 H22 119.9 . .
C24 C23 C22 120.6(3) . .
C24 C23 H23 119.7 . .
C22 C23 H23 119.7 . .
C23 C24 C19 119.6(3) . .
C23 C24 H24 120.2 . .
C19 C24 H24 120.2 . .
C26 C25 C30 119.0(3) . .
C26 C25 P3 121.5(2) . .
C30 C25 P3 119.5(2) . .
C25 C26 C27 120.3(3) . .
C25 C26 H26 119.9 . .
C27 C26 H26 119.9 . .
C28 C27 C26 120.3(3) . .
C28 C27 H27 119.8 . .
C26 C27 H27 119.8 . .
C27 C28 C29 120.0(3) . .
C27 C28 H28 120.0 . .
C29 C28 H28 120.0 . .
C28 C29 C30 120.3(3) . .
C28 C29 H29 119.8 . .
C30 C29 H29 119.8 . .
C29 C30 C25 120.1(3) . .
C29 C30 H30 120.0 . .
C25 C30 H30 120.0 . .
P2 C31 P1 111.24(14) . .
P2 C31 H31A 109.4 . .
P1 C31 H31A 109.4 . .
P2 C31 H31B 109.4 . .
P1 C31 H31B 109.4 . .
H31A C31 H31B 108.0 . .
P2 C32 P3 112.09(13) 2_765 .
P2 C32 H32A 109.2 2_765 .
P3 C32 H32A 109.2 . .
P2 C32 H32B 109.2 2_765 .
P3 C32 H32B 109.2 . .
H32A C32 H32B 107.9 . .
P2 Au1 P2 180.0 2_765 .
P2 Au1 Cu1 85.291(17) 2_765 2_765
P2 Au1 Cu1 94.708(17) . 2_765
P2 Au1 Cu1 94.709(17) 2_765 .
P2 Au1 Cu1 85.292(17) . .
Cu1 Au1 Cu1 180.0 2_765 .
O1 Cu1 P1 110.48(7) . .
O1 Cu1 P3 102.72(7) . .
P1 Cu1 P3 144.92(3) . .
O1 Cu1 Au1 106.58(7) . .
P1 Cu1 Au1 92.926(19) . .
P3 Cu1 Au1 88.143(19) . .
Cu1 O1 H2O1 127.1 . .
Cu1 O1 H1O1 125.4 . .
H2O1 O1 H1O1 102.4 . .
C7 P1 C1 102.81(12) . .
C7 P1 C31 102.82(12) . .
C1 P1 C31 102.75(12) . .
C7 P1 Cu1 118.90(10) . .
C1 P1 Cu1 113.83(9) . .
C31 P1 Cu1 113.78(9) . .
C13 P2 C31 108.65(12) . .
C13 P2 C32 107.37(12) . 2_765
C31 P2 C32 105.14(12) . 2_765
C13 P2 Au1 115.24(9) . .
C31 P2 Au1 109.86(9) . .
C32 P2 Au1 110.07(9) 2_765 .
C19 P3 C25 104.16(12) . .
C19 P3 C32 105.47(12) . .
C25 P3 C32 100.96(12) . .
C19 P3 Cu1 114.42(9) . .
C25 P3 Cu1 117.06(9) . .
C32 P3 Cu1 113.23(9) . .
F3 P4 F4 91.61(14) . .
F3 P4 F5 90.67(13) . .
F4 P4 F5 90.42(13) . .
F3 P4 F6 90.05(13) . .
F4 P4 F6 177.92(14) . .
F5 P4 F6 90.81(14) . .
F3 P4 F2 91.34(14) . .
F4 P4 F2 89.56(14) . .
F5 P4 F2 177.99(13) . .
F6 P4 F2 89.16(14) . .
F3 P4 F1 179.56(16) . .
F4 P4 F1 88.83(13) . .
F5 P4 F1 89.34(12) . .
F6 P4 F1 89.51(13) . .
F2 P4 F1 88.65(13) . .
F7 P5 F7 179.998(2) . 2_766
F7 P5 F9 89.47(11) . 2_766
F7 P5 F9 90.53(11) 2_766 2_766
F7 P5 F9 90.53(11) . .
F7 P5 F9 89.47(11) 2_766 .
F9 P5 F9 179.999(1) 2_766 .
F7 P5 F8 89.85(12) . .
F7 P5 F8 90.16(12) 2_766 .
F9 P5 F8 89.91(11) 2_766 .
F9 P5 F8 90.09(11) . .
F7 P5 F8 90.16(12) . 2_766
F7 P5 F8 89.84(12) 2_766 2_766
F9 P5 F8 90.09(11) 2_766 2_766
F9 P5 F8 89.91(11) . 2_766
F8 P5 F8 180.0 . 2_766
C35 O2 C36 114.3(4) . .
C35 C34 H34A 109.5 . .
C35 C34 H34B 109.5 . .
H34A C34 H34B 109.5 . .
C35 C34 H34C 109.5 . .
H34A C34 H34C 109.5 . .
H34B C34 H34C 109.5 . .
O2 C35 C34 109.0(4) . .
O2 C35 H35A 109.9 . .
C34 C35 H35A 109.9 . .
O2 C35 H35B 109.9 . .
C34 C35 H35B 109.9 . .
H35A C35 H35B 108.3 . .
O2 C36 C37 112.6(4) . .
O2 C36 H36A 109.1 . .
C37 C36 H36A 109.1 . .
O2 C36 H36B 109.1 . .
C37 C36 H36B 109.1 . .
H36A C36 H36B 107.8 . .
C36 C37 H37A 109.5 . .
C36 C37 H37B 109.5 . .
H37A C37 H37B 109.5 . .
C36 C37 H37C 109.5 . .
H37A C37 H37C 109.5 . .
H37B C37 H37C 109.5 . .
C137 C136 O12 106(2) . .
C137 C136 H13A 110.5 . .
O12 C136 H13A 110.5 . .
C137 C136 H13B 110.5 . .
O12 C136 H13B 110.5 . .
H13A C136 H13B 108.7 . .
C134 C135 O12 110(2) . .
C134 C135 H13C 109.6 . .
O12 C135 H13C 109.6 . .
C134 C135 H13D 109.6 . .
O12 C135 H13D 109.6 . .
H13C C135 H13D 108.1 . .
C135 C134 H13E 109.5 . .
C135 C134 H13F 109.5 . .
H13E C134 H13F 109.5 . .
C135 C134 H13G 109.5 . .
H13E C134 H13G 109.5 . .
H13F C134 H13G 109.5 . .
C135 O12 C136 110(2) . .
C136 C137 H13H 109.5 . .
C136 C137 H13I 109.5 . .
H13H C137 H13I 109.5 . .
C136 C137 H13J 109.5 . .
H13H C137 H13J 109.5 . .
H13I C137 H13J 109.5 . .
Cl2 C33 Cl1 111.8(5) . .
Cl2 C33 H33A 109.3 . .
Cl1 C33 H33A 109.3 . .
Cl2 C33 H33B 109.3 . .
Cl1 C33 H33B 109.3 . .
H33A C33 H33B 107.9 . .
Cl12 C133 Cl11 111.3(6) . .
Cl12 C133 H13K 109.4 . .
Cl11 C133 H13K 109.4 . .
Cl12 C133 H13L 109.4 . .
Cl11 C133 H13L 109.4 . .
H13K C133 H13L 108.0 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 C6 1.390(4) .
C1 C2 1.396(4) .
C1 P1 1.827(3) .
C2 C3 1.388(4) .
C2 H2 0.9500 .
C3 C4 1.385(5) .
C3 H3 0.9500 .
C4 C5 1.378(5) .
C4 H4 0.9500 .
C5 C6 1.390(4) .
C5 H5 0.9500 .
C6 H6 0.9500 .
C7 C8 1.386(4) .
C7 C12 1.397(4) .
C7 P1 1.817(3) .
C8 C9 1.392(5) .
C8 H8 0.9500 .
C9 C10 1.374(6) .
C9 H9 0.9500 .
C10 C11 1.376(6) .
C10 H10 0.9500 .
C11 C12 1.384(4) .
C11 H11 0.9500 .
C12 H12 0.9500 .
C13 C14 1.394(4) .
C13 C18 1.395(4) .
C13 P2 1.802(3) .
C14 C15 1.381(4) .
C14 H14 0.9500 .
C15 C16 1.377(5) .
C15 H15 0.9500 .
C16 C17 1.384(5) .
C16 H16 0.9500 .
C17 C18 1.385(5) .
C17 H17 0.9500 .
C18 H18 0.9500 .
C19 C20 1.392(4) .
C19 C24 1.399(4) .
C19 P3 1.809(3) .
C20 C21 1.393(4) .
C20 H20 0.9500 .
C21 C22 1.378(5) .
C21 H21 0.9500 .
C22 C23 1.388(5) .
C22 H22 0.9500 .
C23 C24 1.384(4) .
C23 H23 0.9500 .
C24 H24 0.9500 .
C25 C26 1.386(4) .
C25 C30 1.396(4) .
C25 P3 1.826(3) .
C26 C27 1.390(4) .
C26 H26 0.9500 .
C27 C28 1.372(5) .
C27 H27 0.9500 .
C28 C29 1.379(5) .
C28 H28 0.9500 .
C29 C30 1.386(4) .
C29 H29 0.9500 .
C30 H30 0.9500 .
C31 P2 1.815(3) .
C31 P1 1.844(3) .
C31 H31A 0.9900 .
C31 H31B 0.9900 .
C32 P2 1.822(3) 2_765
C32 P3 1.840(3) .
C32 H32A 0.9900 .
C32 H32B 0.9900 .
Au1 P2 2.3041(6) 2_765
Au1 P2 2.3041(6) .
Au1 Cu1 2.9042(3) 2_765
Au1 Cu1 2.9042(3) .
Cu1 O1 2.136(2) .
Cu1 P1 2.2615(7) .
Cu1 P3 2.2723(7) .
F1 P4 1.613(2) .
F2 P4 1.605(2) .
F3 P4 1.572(2) .
F4 P4 1.585(2) .
F5 P4 1.586(2) .
F6 P4 1.589(2) .
F7 P5 1.594(2) .
F8 P5 1.599(2) .
F9 P5 1.5984(19) .
O1 H2O1 0.9541 .
O1 H1O1 0.9387 .
P2 C32 1.822(3) 2_765
P5 F7 1.594(2) 2_766
P5 F9 1.5984(19) 2_766
P5 F8 1.599(2) 2_766
O2 C35 1.429(7) .
O2 C36 1.444(7) .
C34 C35 1.494(8) .
C34 H34A 0.9800 .
C34 H34B 0.9800 .
C34 H34C 0.9800 .
C35 H35A 0.9900 .
C35 H35B 0.9900 .
C36 C37 1.527(7) .
C36 H36A 0.9900 .
C36 H36B 0.9900 .
C37 H37A 0.9800 .
C37 H37B 0.9800 .
C37 H37C 0.9800 .
C136 C137 1.35(3) .
C136 O12 1.58(3) .
C136 H13A 0.9900 .
C136 H13B 0.9900 .
C135 C134 1.37(3) .
C135 O12 1.45(3) .
C135 H13C 0.9900 .
C135 H13D 0.9900 .
C134 H13E 0.9800 .
C134 H13F 0.9800 .
C134 H13G 0.9800 .
C137 H13H 0.9800 .
C137 H13I 0.9800 .
C137 H13J 0.9800 .
C33 Cl2 1.728(9) .
C33 Cl1 1.751(7) .
C33 H33A 0.9900 .
C33 H33B 0.9900 .
Cl12 C133 1.744(9) .
Cl11 C133 1.749(8) .
C133 H13K 0.9900 .
C133 H13L 0.9900 .
