#------------------------------------------------------------------------------
#$Date: 2016-03-23 23:28:34 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179503 $
#$URL: svn://www.crystallography.net/cod/cif/4/34/00/4340089.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4340089
loop_
_publ_author_name
'Handke, Marcel'
'Weber, Hanna'
'Lange, Marcus'
'Möllmer, Jens'
'Lincke, Jörg'
'Gläser, Roger'
'Staudt, Reiner'
'Krautscheid, Harald'
_publ_section_title
;
 Network Flexibility: Control of Gate Opening in an Isostructural Series
 of Ag-MOFs by Linker Substitution.
;
_journal_issue                   14
_journal_name_full               'Inorganic chemistry'
_journal_page_first              7599
_journal_page_last               7607
_journal_paper_doi               10.1021/ic500908r
_journal_volume                  53
_journal_year                    2014
_chemical_formula_moiety         'C40 H38 Ag2 N8 O6'
_chemical_formula_sum            'C40 H38 Ag2 N8 O6'
_chemical_formula_weight         942.52
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           45
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      45
_symmetry_space_group_name_Hall  'I 2 -2c'
_symmetry_space_group_name_H-M   'I b a 2'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            16
_cell_length_a                   23.3024(5)
_cell_length_b                   29.3223(8)
_cell_length_c                   29.7087(9)
_cell_measurement_reflns_used    57104
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      28.35
_cell_measurement_theta_min      1.77
_cell_volume                     20299.4(9)
_computing_cell_refinement       'STOE X-AREA'
_computing_data_collection       'STOE X-AREA'
_computing_data_reduction        'STOE X-AREA, STOE X-RED'
_computing_molecular_graphics    'DIAMOND 3.2e'
_computing_publication_material  'WinGX publication routines (Farrugia, 1999)'
_computing_structure_refinement
'SHELXL-97 Sheldrick, G. M. (2008) Acta Cryst.'
_computing_structure_solution
'SHELXS-97 Sheldrick, G. M. (2008) Acta Cryst.'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 6.67
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'STOE IPDS-2T'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0297
_diffrn_reflns_av_sigmaI/netI    0.0349
_diffrn_reflns_limit_h_max       25
_diffrn_reflns_limit_h_min       -29
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_k_min       -37
_diffrn_reflns_limit_l_max       36
_diffrn_reflns_limit_l_min       -37
_diffrn_reflns_number            34571
_diffrn_reflns_theta_full        27.00
_diffrn_reflns_theta_max         27.00
_diffrn_reflns_theta_min         1.77
_diffrn_standards_number         none
_exptl_absorpt_coefficient_mu    0.816
_exptl_absorpt_correction_T_max  0.9134
_exptl_absorpt_correction_T_min  0.8473
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'STOE X-RED'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.234
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             7616
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.19
_exptl_crystal_size_min          0.19
_refine_diff_density_max         0.852
_refine_diff_density_min         -0.825
_refine_diff_density_rms         0.076
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.026(16)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.029
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1025
_refine_ls_number_reflns         19986
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.029
_refine_ls_R_factor_all          0.0373
_refine_ls_R_factor_gt           0.0323
_refine_ls_shift/su_max          0.011
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0641P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0879
_refine_ls_wR_factor_ref         0.0958
_reflns_number_gt                17853
_reflns_number_total             19986
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic500908r_si_002.cif
_cod_data_source_block           compound_4
_cod_depositor_comments
'Adding full bibliography for 4340086--4340098.cif.'
_cod_original_sg_symbol_H-M      Iba2
_cod_database_code               4340089
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z'
'-x, y, z+1/2'
'x, -y, z+1/2'
'x+1/2, y+1/2, z+1/2'
'-x+1/2, -y+1/2, z+1/2'
'-x+1/2, y+1/2, z+1'
'x+1/2, -y+1/2, z+1'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.72709(19) 0.37617(17) 0.37478(16) 0.0355(10) Uani 1 1 d . . .
C2 C 0.72631(17) 0.33842(15) 0.34073(15) 0.0298(9) Uani 1 1 d . . .
C3 C 0.77667(18) 0.32442(15) 0.31996(15) 0.0294(9) Uani 1 1 d . . .
H3 H 0.8120 0.3394 0.3260 0.035 Uiso 1 1 calc R . .
C4 C 0.77411(17) 0.28843(14) 0.29057(14) 0.0260(8) Uani 1 1 d . . .
C5 C 0.72361(17) 0.26646(15) 0.27926(13) 0.0259(8) Uani 1 1 d . . .
H5 H 0.7234 0.2418 0.2585 0.031 Uiso 1 1 calc R . .
C6 C 0.67300(16) 0.28165(14) 0.29938(14) 0.0261(8) Uani 1 1 d . . .
C7 C 0.67532(18) 0.31820(16) 0.33002(15) 0.0315(9) Uani 1 1 d . . .
H7 H 0.6409 0.3290 0.3435 0.038 Uiso 1 1 calc R . .
C8 C 0.84304(18) 0.34006(16) 0.21989(16) 0.0329(9) Uani 1 1 d . . .
H8A H 0.8668 0.3464 0.1934 0.049 Uiso 1 1 calc R . .
H8B H 0.8499 0.3635 0.2428 0.049 Uiso 1 1 calc R . .
H8C H 0.8025 0.3403 0.2112 0.049 Uiso 1 1 calc R . .
C9 C 0.85805(17) 0.29487(14) 0.23834(13) 0.0252(8) Uani 1 1 d . . .
C10 C 0.85544(17) 0.23243(14) 0.27905(13) 0.0242(8) Uani 1 1 d . . .
C11 C 0.83708(19) 0.19861(15) 0.31260(15) 0.0318(9) Uani 1 1 d . . .
H11A H 0.8050 0.1808 0.3005 0.048 Uiso 1 1 calc R . .
H11B H 0.8248 0.2143 0.3401 0.048 Uiso 1 1 calc R . .
H11C H 0.8692 0.1782 0.3196 0.048 Uiso 1 1 calc R . .
C12 C 0.60741(18) 0.22171(16) 0.27180(14) 0.0299(9) Uani 1 1 d . . .
C13 C 0.54922(19) 0.20142(15) 0.28077(15) 0.0290(8) Uani 1 1 d . . .
C14 C 0.51359(18) 0.21591(15) 0.31638(15) 0.0294(8) Uani 1 1 d . . .
H14 H 0.5231 0.2428 0.3325 0.035 Uiso 1 1 calc R . .
C15 C 0.46505(18) 0.19150(16) 0.32817(15) 0.0323(9) Uani 1 1 d . . .
C16 C 0.45216(19) 0.15227(17) 0.30394(16) 0.0355(10) Uani 1 1 d . . .
H16 H 0.4194 0.1349 0.3124 0.043 Uiso 1 1 calc R . .
C17 C 0.48571(18) 0.13717(16) 0.26740(16) 0.0314(9) Uani 1 1 d . . .
C18 C 0.53424(17) 0.16259(15) 0.25615(15) 0.0294(9) Uani 1 1 d . . .
H18 H 0.5574 0.1534 0.2314 0.035 Uiso 1 1 calc R . .
C19 C 0.4294(2) 0.20680(18) 0.36748(17) 0.0390(11) Uani 1 1 d . . .
H19A H 0.3926 0.1907 0.3672 0.059 Uiso 1 1 calc R . .
H19B H 0.4227 0.2397 0.3654 0.059 Uiso 1 1 calc R . .
H19C H 0.4498 0.2000 0.3955 0.059 Uiso 1 1 calc R . .
C20 C 0.4713(2) 0.09463(17) 0.2424(2) 0.0435(12) Uani 1 1 d . . .
H20A H 0.4328 0.0844 0.2509 0.065 Uiso 1 1 calc R . .
H20B H 0.4993 0.0708 0.2498 0.065 Uiso 1 1 calc R . .
H20C H 0.4724 0.1007 0.2100 0.065 Uiso 1 1 calc R . .
C21 C 0.75802(17) 0.59690(15) 0.58223(13) 0.0267(8) Uani 1 1 d . . .
C22 C 0.74950(18) 0.64054(16) 0.60860(14) 0.0290(9) Uani 1 1 d . . .
C23 C 0.69787(18) 0.64987(15) 0.62927(14) 0.0288(8) Uani 1 1 d . . .
H23 H 0.6678 0.6280 0.6291 0.035 Uiso 1 1 calc R . .
C24 C 0.69042(18) 0.69115(15) 0.65013(15) 0.0308(9) Uani 1 1 d . . .
C25 C 0.73345(19) 0.72397(16) 0.65333(15) 0.0317(9) Uani 1 1 d . . .
H25 H 0.7277 0.7517 0.6692 0.038 Uiso 1 1 calc R . .
C26 C 0.78604(18) 0.71414(15) 0.63184(15) 0.0301(9) Uani 1 1 d . . .
C27 C 0.79332(18) 0.67301(15) 0.61013(14) 0.0296(9) Uani 1 1 d . . .
H27 H 0.8289 0.6666 0.5959 0.035 Uiso 1 1 calc R . .
C28 C 0.62240(19) 0.63569(16) 0.72158(14) 0.0319(9) Uani 1 1 d . . .
H28A H 0.6218 0.6101 0.7003 0.048 Uiso 1 1 calc R . .
H28B H 0.5969 0.6289 0.7470 0.048 Uiso 1 1 calc R . .
H28C H 0.6616 0.6402 0.7327 0.048 Uiso 1 1 calc R . .
C29 C 0.60259(18) 0.67762(15) 0.69860(14) 0.0284(8) Uani 1 1 d . . .
C30 C 0.6012(2) 0.73909(16) 0.65648(16) 0.0375(11) Uani 1 1 d . . .
C31 C 0.6190(3) 0.7752(2) 0.6241(2) 0.0580(17) Uani 1 1 d . . .
H31A H 0.5855 0.7935 0.6156 0.087 Uiso 1 1 calc R . .
H31B H 0.6355 0.7610 0.5972 0.087 Uiso 1 1 calc R . .
H31C H 0.6477 0.7950 0.6383 0.087 Uiso 1 1 calc R . .
C32 C 0.8374(2) 0.78729(16) 0.64997(16) 0.0341(9) Uani 1 1 d . . .
C33 C 0.8908(2) 0.81341(17) 0.63923(17) 0.0379(10) Uani 1 1 d . . .
C34 C 0.9262(3) 0.8012(2) 0.6036(2) 0.0563(15) Uani 1 1 d . A .
H34 H 0.9180 0.7747 0.5863 0.068 Uiso 1 1 calc R . .
C35 C 0.9742(3) 0.8280(2) 0.5933(3) 0.070(2) Uani 1 1 d . . .
C36 C 0.9860(3) 0.8669(2) 0.6188(2) 0.0572(15) Uani 1 1 d . A .
H36 H 1.0187 0.8849 0.6118 0.069 Uiso 1 1 calc R . .
C37 C 0.9506(2) 0.87958(17) 0.65410(18) 0.0433(11) Uani 1 1 d . . .
C38 C 0.9026(2) 0.85269(17) 0.66365(17) 0.0400(11) Uani 1 1 d . A .
H38 H 0.8775 0.8615 0.6873 0.048 Uiso 1 1 calc R . .
C39A C 1.0225(6) 0.8110(5) 0.5631(5) 0.049(4) Uiso 0.48(3) 1 d P A 1
H39A H 1.0097 0.7838 0.5468 0.074 Uiso 0.48(3) 1 calc PR A 1
H39B H 1.0560 0.8034 0.5816 0.074 Uiso 0.48(3) 1 calc PR A 1
H39C H 1.0329 0.8349 0.5416 0.074 Uiso 0.48(3) 1 calc PR A 1
C39B C 1.0029(8) 0.8194(5) 0.5459(6) 0.064(5) Uiso 0.52(3) 1 d P A 2
H39D H 0.9992 0.8469 0.5273 0.096 Uiso 0.52(3) 1 calc PR A 2
H39E H 0.9837 0.7938 0.5309 0.096 Uiso 0.52(3) 1 calc PR A 2
H39F H 1.0437 0.8122 0.5500 0.096 Uiso 0.52(3) 1 calc PR A 2
C40 C 0.9637(3) 0.9220(2) 0.6798(2) 0.0637(16) Uani 1 1 d . A .
H40A H 0.9432 0.9214 0.7086 0.096 Uiso 1 1 calc R . .
H40B H 0.9514 0.9486 0.6623 0.096 Uiso 1 1 calc R . .
H40C H 1.0051 0.9239 0.6853 0.096 Uiso 1 1 calc R . .
C41 C 1.02728(18) 0.34546(15) 0.60974(14) 0.0283(8) Uani 1 1 d . . .
C42 C 1.02173(17) 0.37905(15) 0.57159(14) 0.0273(8) Uani 1 1 d . . .
C43 C 0.96668(17) 0.39591(14) 0.56023(14) 0.0262(8) Uani 1 1 d . . .
H43 H 0.9337 0.3878 0.5773 0.031 Uiso 1 1 calc R . .
C44 C 0.96270(17) 0.42466(15) 0.52330(13) 0.0258(8) Uani 1 1 d . . .
C45 C 1.01095(16) 0.43874(13) 0.49825(13) 0.0246(8) Uani 1 1 d . . .
H45 H 1.0071 0.4590 0.4734 0.029 Uiso 1 1 calc R . .
C46 C 1.06433(15) 0.42201(14) 0.51111(12) 0.0230(8) Uani 1 1 d . . .
C47 C 1.06890(17) 0.39210(14) 0.54746(13) 0.0262(8) Uani 1 1 d . . .
H47 H 1.1056 0.3806 0.5556 0.031 Uiso 1 1 calc R . .
C48 C 0.8968(2) 0.4011(2) 0.43619(17) 0.0467(13) Uani 1 1 d . . .
H48A H 0.9222 0.4193 0.4170 0.070 Uiso 1 1 calc R . .
H48B H 0.8643 0.3900 0.4183 0.070 Uiso 1 1 calc R . .
H48C H 0.9180 0.3751 0.4485 0.070 Uiso 1 1 calc R . .
C49 C 0.87511(17) 0.42977(15) 0.47361(14) 0.0282(8) Uani 1 1 d . . .
C50 C 0.87146(16) 0.46830(13) 0.53675(14) 0.0243(7) Uani 1 1 d . . .
C51 C 0.88806(18) 0.48897(16) 0.58018(14) 0.0303(9) Uani 1 1 d . . .
H51A H 0.8834 0.4665 0.6043 0.045 Uiso 1 1 calc R . .
H51B H 0.8636 0.5154 0.5863 0.045 Uiso 1 1 calc R . .
H51C H 0.9282 0.4987 0.5788 0.045 Uiso 1 1 calc R . .
C52 C 1.12318(18) 0.45278(14) 0.44814(13) 0.0257(8) Uani 1 1 d . . .
C53 C 1.18017(16) 0.44485(14) 0.42578(13) 0.0259(8) Uani 1 1 d . . .
C54 C 1.19252(18) 0.47108(16) 0.38717(14) 0.0300(9) Uani 1 1 d . . .
H54 H 1.1681 0.4957 0.3790 0.036 Uiso 1 1 calc R . .
C55 C 1.24058(19) 0.46102(18) 0.36085(15) 0.0343(10) Uani 1 1 d . . .
C56 C 1.2755(2) 0.42491(17) 0.37362(15) 0.0347(10) Uani 1 1 d . . .
H56 H 1.3080 0.4179 0.3556 0.042 Uiso 1 1 calc R . .
C57 C 1.26489(18) 0.39867(15) 0.41163(15) 0.0309(9) Uani 1 1 d . . .
C58 C 1.21648(17) 0.40979(15) 0.43790(14) 0.0290(8) Uani 1 1 d . . .
H58 H 1.2087 0.3928 0.4645 0.035 Uiso 1 1 calc R . .
C59 C 1.2532(2) 0.4885(2) 0.3190(2) 0.0470(13) Uani 1 1 d . . .
H59A H 1.2826 0.4729 0.3011 0.071 Uiso 1 1 calc R . .
H59B H 1.2672 0.5188 0.3276 0.071 Uiso 1 1 calc R . .
H59C H 1.2181 0.4917 0.3011 0.071 Uiso 1 1 calc R . .
C60 C 1.3027(2) 0.35906(18) 0.42396(18) 0.0433(11) Uani 1 1 d . . .
H60A H 1.3066 0.3575 0.4568 0.065 Uiso 1 1 calc R . .
H60B H 1.3406 0.3631 0.4103 0.065 Uiso 1 1 calc R . .
H60C H 1.2854 0.3307 0.4129 0.065 Uiso 1 1 calc R . .
C61 C 0.49834(16) 0.64148(15) 0.33347(14) 0.0274(8) Uani 1 1 d . . .
C62 C 0.49887(17) 0.61554(14) 0.37770(14) 0.0281(8) Uani 1 1 d . . .
C63 C 0.54641(16) 0.58937(15) 0.39054(14) 0.0273(8) Uani 1 1 d . . .
H63 H 0.5788 0.5871 0.3713 0.033 Uiso 1 1 calc R . .
C64 C 0.54594(17) 0.56744(14) 0.43021(15) 0.0293(8) Uani 1 1 d . . .
C65 C 0.49858(16) 0.56804(16) 0.45944(15) 0.0304(9) Uani 1 1 d . . .
H65 H 0.4990 0.5512 0.4868 0.036 Uiso 1 1 calc R . .
C66 C 0.45089(18) 0.59399(16) 0.44734(16) 0.0342(10) Uani 1 1 d . . .
C67 C 0.45214(18) 0.61770(16) 0.40633(15) 0.0330(9) Uani 1 1 d . . .
H67 H 0.4200 0.6358 0.3980 0.040 Uiso 1 1 calc R . .
C68 C 0.6078(2) 0.48978(16) 0.37838(16) 0.0360(10) Uani 1 1 d . . .
H68A H 0.5660 0.4859 0.3774 0.054 Uiso 1 1 calc R . .
H68B H 0.6264 0.4602 0.3739 0.054 Uiso 1 1 calc R . .
H68C H 0.6197 0.5108 0.3545 0.054 Uiso 1 1 calc R . .
C69 C 0.62482(17) 0.50872(15) 0.42303(14) 0.0292(9) Uani 1 1 d . . .
C70 C 0.62675(17) 0.55058(15) 0.48453(14) 0.0278(8) Uani 1 1 d . . .
C71 C 0.6126(2) 0.58547(18) 0.51800(16) 0.0399(11) Uani 1 1 d . . .
H71A H 0.5801 0.5751 0.5363 0.060 Uiso 1 1 calc R . .
H71B H 0.6024 0.6139 0.5027 0.060 Uiso 1 1 calc R . .
H71C H 0.6459 0.5907 0.5375 0.060 Uiso 1 1 calc R . .
C72 C 0.39090(19) 0.57860(17) 0.51449(15) 0.0334(9) Uani 1 1 d . . .
C73 C 0.33428(19) 0.58993(18) 0.53605(18) 0.0400(10) Uani 1 1 d . . .
C74 C 0.2951(2) 0.62075(18) 0.51938(18) 0.0437(11) Uani 1 1 d . . .
H74 H 0.3025 0.6359 0.4917 0.052 Uiso 1 1 calc R . .
C75 C 0.2446(2) 0.62992(19) 0.5428(2) 0.0542(15) Uani 1 1 d . . .
C76 C 0.2336(2) 0.6079(2) 0.5832(2) 0.0489(13) Uani 1 1 d . . .
H76 H 0.1994 0.6146 0.5994 0.059 Uiso 1 1 calc R . .
C77 C 0.2725(2) 0.5756(2) 0.60041(17) 0.0442(12) Uani 1 1 d . . .
C78 C 0.3219(2) 0.56683(18) 0.57644(15) 0.0377(10) Uani 1 1 d . . .
H78 H 0.3482 0.5447 0.5874 0.045 Uiso 1 1 calc R . .
C79 C 0.2011(3) 0.6645(2) 0.5240(3) 0.070(2) Uani 1 1 d . . .
H79A H 0.2108 0.6952 0.5347 0.105 Uiso 1 1 calc R . .
H79B H 0.1624 0.6565 0.5343 0.105 Uiso 1 1 calc R . .
H79C H 0.2022 0.6639 0.4910 0.105 Uiso 1 1 calc R . .
C80 C 0.2596(3) 0.5524(2) 0.6448(2) 0.0588(16) Uani 1 1 d . . .
H80A H 0.2931 0.5547 0.6646 0.088 Uiso 1 1 calc R . .
H80B H 0.2507 0.5202 0.6395 0.088 Uiso 1 1 calc R . .
H80C H 0.2266 0.5673 0.6591 0.088 Uiso 1 1 calc R . .
Ag1 Ag 0.744706(13) 0.452517(12) 0.433898(11) 0.03352(8) Uani 1 1 d . . .
Ag2 Ag 0.744338(12) 0.512312(11) 0.533764(10) 0.02840(7) Uani 1 1 d . . .
Ag3 Ag 0.978095(12) 0.184230(11) 0.247873(11) 0.02812(7) Uani 1 1 d . . .
Ag4 Ag 0.976688(14) 0.283863(12) 0.183975(12) 0.03504(8) Uani 1 1 d . . .
N1 N 0.90159(14) 0.23065(11) 0.25358(12) 0.0239(7) Uani 1 1 d . . .
N2 N 0.90254(14) 0.26992(11) 0.22770(12) 0.0256(7) Uani 1 1 d . . .
N3 N 0.82685(14) 0.27222(12) 0.27002(12) 0.0255(7) Uani 1 1 d . . .
N4 N 0.61813(14) 0.26229(12) 0.29224(12) 0.0272(7) Uani 1 1 d . . .
H4 H 0.5883 0.2779 0.3019 0.033 Uiso 1 1 calc R . .
N5 N 0.55157(15) 0.73604(13) 0.67727(13) 0.0326(8) Uani 1 1 d . . .
N6 N 0.55310(15) 0.69780(12) 0.70400(12) 0.0268(7) Uani 1 1 d . . .
N7 N 0.63493(15) 0.70284(13) 0.66868(12) 0.0298(8) Uani 1 1 d . . .
N8 N 0.83351(16) 0.74413(13) 0.63174(13) 0.0338(8) Uani 1 1 d . . .
H8 H 0.8646 0.7339 0.6183 0.041 Uiso 1 1 calc R . .
N9 N 0.82229(14) 0.47333(12) 0.51658(11) 0.0249(7) Uani 1 1 d . . .
N10 N 0.82452(15) 0.44854(13) 0.47653(12) 0.0298(8) Uani 1 1 d . . .
N11 N 0.90704(14) 0.44165(12) 0.51135(10) 0.0234(7) Uani 1 1 d . . .
N12 N 1.11576(14) 0.43135(13) 0.48853(12) 0.0269(7) Uani 1 1 d . . .
H12 H 1.1473 0.4222 0.5021 0.032 Uiso 1 1 calc R . .
N13 N 0.67089(14) 0.52284(13) 0.48559(11) 0.0258(7) Uani 1 1 d . . .
N14 N 0.66904(14) 0.49663(13) 0.44667(11) 0.0272(7) Uani 1 1 d . . .
N15 N 0.59645(14) 0.54297(12) 0.44555(12) 0.0273(7) Uani 1 1 d . . .
N16 N 0.40100(17) 0.59727(17) 0.47307(14) 0.0422(10) Uani 1 1 d . . .
H16A H 0.3727 0.6132 0.4613 0.051 Uiso 1 1 calc R . .
O1 O 0.76947(14) 0.40373(13) 0.37460(12) 0.0417(8) Uani 1 1 d . . .
O2 O 0.68644(14) 0.37850(12) 0.40291(11) 0.0402(8) Uani 1 1 d . . .
O3 O 0.64321(13) 0.20168(12) 0.24864(13) 0.0412(8) Uani 1 1 d . . .
O4 O 0.72656(14) 0.56308(12) 0.59225(11) 0.0354(7) Uani 1 1 d . . .
O5 O 0.79414(13) 0.59713(12) 0.55097(10) 0.0363(7) Uani 1 1 d . . .
O6 O 0.79942(15) 0.80299(12) 0.67422(13) 0.0422(8) Uani 1 1 d . . .
O7 O 0.99030(13) 0.34600(11) 0.64077(10) 0.0319(6) Uani 1 1 d . . .
O8 O 1.06873(14) 0.31767(11) 0.60794(11) 0.0377(7) Uani 1 1 d . . .
O9 O 1.08422(12) 0.47500(11) 0.43025(10) 0.0323(6) Uani 1 1 d . . .
O10 O 0.53265(14) 0.62923(13) 0.30331(11) 0.0414(8) Uani 1 1 d . . .
O11 O 0.46219(14) 0.67345(12) 0.32957(12) 0.0376(7) Uani 1 1 d . . .
O12 O 0.42556(16) 0.55407(16) 0.53172(13) 0.0581(11) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O2 C1 O1 123.2(4) . .
O2 C1 C2 118.4(4) . .
O1 C1 C2 118.3(4) . .
C7 C2 C3 120.2(4) . .
C7 C2 C1 119.2(4) . .
C3 C2 C1 120.5(4) . .
C4 C3 C2 118.3(4) . .
C4 C3 H3 120.9 . .
C2 C3 H3 120.9 . .
C3 C4 C5 123.4(4) . .
C3 C4 N3 118.9(4) . .
C5 C4 N3 117.7(4) . .
C4 C5 C6 117.8(4) . .
C4 C5 H5 121.1 . .
C6 C5 H5 121.1 . .
C5 C6 C7 119.2(4) . .
C5 C6 N4 124.8(4) . .
C7 C6 N4 115.9(3) . .
C2 C7 C6 121.0(4) . .
C2 C7 H7 119.5 . .
C6 C7 H7 119.5 . .
C9 C8 H8A 109.5 . .
C9 C8 H8B 109.5 . .
H8A C8 H8B 109.5 . .
C9 C8 H8C 109.5 . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
N2 C9 N3 108.5(4) . .
N2 C9 C8 126.9(4) . .
N3 C9 C8 124.6(4) . .
N1 C10 N3 108.6(3) . .
N1 C10 C11 126.9(4) . .
N3 C10 C11 124.5(3) . .
C10 C11 H11A 109.5 . .
C10 C11 H11B 109.5 . .
H11A C11 H11B 109.5 . .
C10 C11 H11C 109.5 . .
H11A C11 H11C 109.5 . .
H11B C11 H11C 109.5 . .
O3 C12 N4 122.9(4) . .
O3 C12 C13 121.4(4) . .
N4 C12 C13 115.6(4) . .
C18 C13 C14 119.4(4) . .
C18 C13 C12 117.0(4) . .
C14 C13 C12 123.0(4) . .
C15 C14 C13 121.0(4) . .
C15 C14 H14 119.5 . .
C13 C14 H14 119.5 . .
C14 C15 C16 118.3(4) . .
C14 C15 C19 119.6(4) . .
C16 C15 C19 122.1(4) . .
C15 C16 C17 122.6(4) . .
C15 C16 H16 118.7 . .
C17 C16 H16 118.7 . .
C18 C17 C16 117.8(4) . .
C18 C17 C20 120.7(4) . .
C16 C17 C20 121.5(4) . .
C17 C18 C13 120.8(4) . .
C17 C18 H18 119.6 . .
C13 C18 H18 119.6 . .
C15 C19 H19A 109.5 . .
C15 C19 H19B 109.5 . .
H19A C19 H19B 109.5 . .
C15 C19 H19C 109.5 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
C17 C20 H20A 109.5 . .
C17 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
C17 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
O5 C21 O4 124.5(4) . .
O5 C21 C22 117.8(4) . .
O4 C21 C22 117.6(4) . .
C23 C22 C27 119.2(4) . .
C23 C22 C21 120.9(4) . .
C27 C22 C21 119.8(4) . .
C24 C23 C22 119.2(4) . .
C24 C23 H23 120.4 . .
C22 C23 H23 120.4 . .
C23 C24 C25 123.3(4) . .
C23 C24 N7 119.7(4) . .
C25 C24 N7 117.0(4) . .
C24 C25 C26 116.9(4) . .
C24 C25 H25 121.5 . .
C26 C25 H25 121.5 . .
C27 C26 C25 119.8(4) . .
C27 C26 N8 116.6(4) . .
C25 C26 N8 123.6(4) . .
C26 C27 C22 121.4(4) . .
C26 C27 H27 119.3 . .
C22 C27 H27 119.3 . .
C29 C28 H28A 109.5 . .
C29 C28 H28B 109.5 . .
H28A C28 H28B 109.5 . .
C29 C28 H28C 109.5 . .
H28A C28 H28C 109.5 . .
H28B C28 H28C 109.5 . .
N6 C29 N7 108.6(4) . .
N6 C29 C28 126.5(4) . .
N7 C29 C28 124.9(4) . .
N5 C30 N7 109.1(4) . .
N5 C30 C31 126.6(4) . .
N7 C30 C31 124.2(4) . .
C30 C31 H31A 109.5 . .
C30 C31 H31B 109.5 . .
H31A C31 H31B 109.5 . .
C30 C31 H31C 109.5 . .
H31A C31 H31C 109.5 . .
H31B C31 H31C 109.5 . .
O6 C32 N8 121.7(4) . .
O6 C32 C33 122.1(4) . .
N8 C32 C33 116.2(4) . .
C38 C33 C34 119.6(5) . .
C38 C33 C32 118.6(4) . .
C34 C33 C32 121.7(5) . .
C33 C34 C35 119.7(6) . .
C33 C34 H34 120.2 . .
C35 C34 H34 120.2 . .
C36 C35 C34 119.9(6) . .
C36 C35 C39A 116.2(7) . .
C34 C35 C39A 122.3(7) . .
C36 C35 C39B 122.0(7) . .
C34 C35 C39B 116.3(8) . .
C39A C35 C39B 27.1(6) . .
C37 C36 C35 120.8(6) . .
C37 C36 H36 119.6 . .
C35 C36 H36 119.6 . .
C36 C37 C38 118.6(5) . .
C36 C37 C40 119.3(5) . .
C38 C37 C40 122.0(5) . .
C33 C38 C37 121.4(5) . .
C33 C38 H38 119.3 . .
C37 C38 H38 119.3 . .
C35 C39A H39A 109.5 . .
C35 C39A H39B 109.5 . .
H39A C39A H39B 109.5 . .
C35 C39A H39C 109.5 . .
H39A C39A H39C 109.5 . .
H39B C39A H39C 109.5 . .
C35 C39B H39D 109.5 . .
C35 C39B H39E 109.5 . .
H39D C39B H39E 109.5 . .
C35 C39B H39F 109.5 . .
H39D C39B H39F 109.5 . .
H39E C39B H39F 109.5 . .
C37 C40 H40A 109.5 . .
C37 C40 H40B 109.5 . .
H40A C40 H40B 109.5 . .
C37 C40 H40C 109.5 . .
H40A C40 H40C 109.5 . .
H40B C40 H40C 109.5 . .
O7 C41 O8 124.1(4) . .
O7 C41 C42 118.9(4) . .
O8 C41 C42 117.0(4) . .
C47 C42 C43 120.4(4) . .
C47 C42 C41 120.6(3) . .
C43 C42 C41 119.0(4) . .
C44 C43 C42 117.5(4) . .
C44 C43 H43 121.3 . .
C42 C43 H43 121.3 . .
C43 C44 C45 122.8(3) . .
C43 C44 N11 117.9(4) . .
C45 C44 N11 119.3(3) . .
C46 C45 C44 117.7(4) . .
C46 C45 H45 121.1 . .
C44 C45 H45 121.1 . .
C45 C46 C47 120.2(4) . .
C45 C46 N12 124.4(4) . .
C47 C46 N12 115.4(3) . .
C42 C47 C46 121.4(4) . .
C42 C47 H47 119.3 . .
C46 C47 H47 119.3 . .
C49 C48 H48A 109.5 . .
C49 C48 H48B 109.5 . .
H48A C48 H48B 109.5 . .
C49 C48 H48C 109.5 . .
H48A C48 H48C 109.5 . .
H48B C48 H48C 109.5 . .
N10 C49 N11 108.9(3) . .
N10 C49 C48 126.6(4) . .
N11 C49 C48 124.4(4) . .
N9 C50 N11 110.2(3) . .
N9 C50 C51 125.9(4) . .
N11 C50 C51 123.9(3) . .
C50 C51 H51A 109.5 . .
C50 C51 H51B 109.5 . .
H51A C51 H51B 109.5 . .
C50 C51 H51C 109.5 . .
H51A C51 H51C 109.5 . .
H51B C51 H51C 109.5 . .
O9 C52 N12 121.8(4) . .
O9 C52 C53 122.7(4) . .
N12 C52 C53 115.4(3) . .
C58 C53 C54 119.6(4) . .
C58 C53 C52 122.8(4) . .
C54 C53 C52 117.1(4) . .
C55 C54 C53 120.2(4) . .
C55 C54 H54 119.9 . .
C53 C54 H54 119.9 . .
C56 C55 C54 118.6(4) . .
C56 C55 C59 121.1(4) . .
C54 C55 C59 120.3(4) . .
C55 C56 C57 122.7(4) . .
C55 C56 H56 118.6 . .
C57 C56 H56 118.6 . .
C56 C57 C58 117.7(4) . .
C56 C57 C60 121.5(4) . .
C58 C57 C60 120.8(4) . .
C53 C58 C57 121.2(4) . .
C53 C58 H58 119.4 . .
C57 C58 H58 119.4 . .
C55 C59 H59A 109.5 . .
C55 C59 H59B 109.5 . .
H59A C59 H59B 109.5 . .
C55 C59 H59C 109.5 . .
H59A C59 H59C 109.5 . .
H59B C59 H59C 109.5 . .
C57 C60 H60A 109.5 . .
C57 C60 H60B 109.5 . .
H60A C60 H60B 109.5 . .
C57 C60 H60C 109.5 . .
H60A C60 H60C 109.5 . .
H60B C60 H60C 109.5 . .
O10 C61 O11 124.8(4) . .
O10 C61 C62 118.0(3) . .
O11 C61 C62 117.1(4) . .
C67 C62 C63 118.7(4) . .
C67 C62 C61 120.2(4) . .
C63 C62 C61 121.1(4) . .
C64 C63 C62 119.7(4) . .
C64 C63 H63 120.2 . .
C62 C63 H63 120.2 . .
C63 C64 C65 122.9(4) . .
C63 C64 N15 120.4(4) . .
C65 C64 N15 116.7(4) . .
C66 C65 C64 118.3(4) . .
C66 C65 H65 120.9 . .
C64 C65 H65 120.9 . .
C65 C66 N16 124.1(4) . .
C65 C66 C67 118.5(4) . .
N16 C66 C67 117.3(4) . .
C62 C67 C66 121.8(4) . .
C62 C67 H67 119.1 . .
C66 C67 H67 119.1 . .
C69 C68 H68A 109.5 . .
C69 C68 H68B 109.5 . .
H68A C68 H68B 109.5 . .
C69 C68 H68C 109.5 . .
H68A C68 H68C 109.5 . .
H68B C68 H68C 109.5 . .
N14 C69 N15 108.6(4) . .
N14 C69 C68 126.2(4) . .
N15 C69 C68 125.2(4) . .
N13 C70 N15 108.8(4) . .
N13 C70 C71 126.4(4) . .
N15 C70 C71 124.7(4) . .
C70 C71 H71A 109.5 . .
C70 C71 H71B 109.5 . .
H71A C71 H71B 109.5 . .
C70 C71 H71C 109.5 . .
H71A C71 H71C 109.5 . .
H71B C71 H71C 109.5 . .
O12 C72 N16 120.6(4) . .
O12 C72 C73 122.9(4) . .
N16 C72 C73 116.5(4) . .
C74 C73 C78 119.1(4) . .
C74 C73 C72 125.0(5) . .
C78 C73 C72 115.9(4) . .
C73 C74 C75 120.5(5) . .
C73 C74 H74 119.8 . .
C75 C74 H74 119.8 . .
C76 C75 C74 119.9(5) . .
C76 C75 C79 120.0(5) . .
C74 C75 C79 120.1(6) . .
C75 C76 C77 120.6(5) . .
C75 C76 H76 119.7 . .
C77 C76 H76 119.7 . .
C78 C77 C76 118.5(5) . .
C78 C77 C80 122.1(5) . .
C76 C77 C80 119.4(5) . .
C77 C78 C73 121.4(5) . .
C77 C78 H78 119.3 . .
C73 C78 H78 119.3 . .
C75 C79 H79A 109.5 . .
C75 C79 H79B 109.5 . .
H79A C79 H79B 109.5 . .
C75 C79 H79C 109.5 . .
H79A C79 H79C 109.5 . .
H79B C79 H79C 109.5 . .
C77 C80 H80A 109.5 . .
C77 C80 H80B 109.5 . .
H80A C80 H80B 109.5 . .
C77 C80 H80C 109.5 . .
H80A C80 H80C 109.5 . .
H80B C80 H80C 109.5 . .
N14 Ag1 N10 126.15(12) . .
N14 Ag1 O1 132.87(12) . .
N10 Ag1 O1 100.83(12) . .
N9 Ag2 N13 123.34(12) . .
N9 Ag2 O4 130.64(12) . .
N13 Ag2 O4 104.58(12) . .
N6 Ag3 N1 124.11(12) 5_544 .
N6 Ag3 O10 128.89(13) 5_544 7_644
N1 Ag3 O10 106.36(13) . 7_644
N2 Ag4 N5 123.11(12) . 5_544
N2 Ag4 O7 136.17(11) . 3_754
N5 Ag4 O7 100.40(12) 5_544 3_754
C10 N1 N2 107.4(3) . .
C10 N1 Ag3 135.6(3) . .
N2 N1 Ag3 116.7(2) . .
C9 N2 N1 108.6(3) . .
C9 N2 Ag4 131.4(3) . .
N1 N2 Ag4 119.7(2) . .
C9 N3 C10 106.9(3) . .
C9 N3 C4 125.6(4) . .
C10 N3 C4 127.4(3) . .
C12 N4 C6 125.8(3) . .
C12 N4 H4 117.1 . .
C6 N4 H4 117.1 . .
C30 N5 N6 107.7(3) . .
C30 N5 Ag4 133.0(3) . 5_455
N6 N5 Ag4 118.5(2) . 5_455
C29 N6 N5 108.8(3) . .
C29 N6 Ag3 133.4(3) . 5_455
N5 N6 Ag3 117.8(2) . 5_455
C30 N7 C29 105.8(3) . .
C30 N7 C24 126.6(4) . .
C29 N7 C24 127.3(4) . .
C32 N8 C26 128.4(4) . .
C32 N8 H8 115.8 . .
C26 N8 H8 115.8 . .
C50 N9 N10 107.5(3) . .
C50 N9 Ag2 132.6(3) . .
N10 N9 Ag2 119.9(2) . .
C49 N10 N9 108.1(3) . .
C49 N10 Ag1 137.0(3) . .
N9 N10 Ag1 114.9(2) . .
C50 N11 C49 105.3(3) . .
C50 N11 C44 127.6(3) . .
C49 N11 C44 126.7(3) . .
C52 N12 C46 128.3(3) . .
C52 N12 H12 115.9 . .
C46 N12 H12 115.9 . .
C70 N13 N14 107.4(3) . .
C70 N13 Ag2 134.1(3) . .
N14 N13 Ag2 118.5(2) . .
C69 N14 N13 108.9(3) . .
C69 N14 Ag1 134.3(3) . .
N13 N14 Ag1 116.1(2) . .
C70 N15 C69 106.3(3) . .
C70 N15 C64 126.9(4) . .
C69 N15 C64 126.7(3) . .
C72 N16 C66 127.5(4) . .
C72 N16 H16A 116.2 . .
C66 N16 H16A 116.2 . .
C1 O1 Ag1 101.1(3) . .
C21 O4 Ag2 102.8(3) . .
C41 O7 Ag4 99.5(2) . 3_755
C61 O10 Ag3 103.9(3) . 7_654
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 O2 1.265(6) .
C1 O1 1.276(6) .
C1 C2 1.500(6) .
C2 C7 1.366(6) .
C2 C3 1.388(6) .
C3 C4 1.371(6) .
C3 H3 0.9500 .
C4 C5 1.383(6) .
C4 N3 1.452(5) .
C5 C6 1.395(5) .
C5 H5 0.9500 .
C6 C7 1.407(6) .
C6 N4 1.415(5) .
C7 H7 0.9500 .
C8 C9 1.476(6) .
C8 H8A 0.9800 .
C8 H8B 0.9800 .
C8 H8C 0.9800 .
C9 N2 1.308(5) .
C9 N3 1.362(5) .
C10 N1 1.316(5) .
C10 N3 1.370(5) .
C10 C11 1.470(6) .
C11 H11A 0.9800 .
C11 H11B 0.9800 .
C11 H11C 0.9800 .
C12 O3 1.230(5) .
C12 N4 1.359(6) .
C12 C13 1.504(6) .
C13 C18 1.398(6) .
C13 C14 1.410(6) .
C14 C15 1.384(6) .
C14 H14 0.9500 .
C15 C16 1.390(7) .
C15 C19 1.501(6) .
C16 C17 1.409(7) .
C16 H16 0.9500 .
C17 C18 1.395(6) .
C17 C20 1.490(6) .
C18 H18 0.9500 .
C19 H19A 0.9800 .
C19 H19B 0.9800 .
C19 H19C 0.9800 .
C20 H20A 0.9800 .
C20 H20B 0.9800 .
C20 H20C 0.9800 .
C21 O5 1.253(5) .
C21 O4 1.269(6) .
C21 C22 1.513(6) .
C22 C23 1.378(5) .
C22 C27 1.397(6) .
C23 C24 1.371(6) .
C23 H23 0.9500 .
C24 C25 1.393(7) .
C24 N7 1.447(5) .
C25 C26 1.412(6) .
C25 H25 0.9500 .
C26 C27 1.378(6) .
C26 N8 1.413(6) .
C27 H27 0.9500 .
C28 C29 1.480(6) .
C28 H28A 0.9800 .
C28 H28B 0.9800 .
C28 H28C 0.9800 .
C29 N6 1.306(5) .
C29 N7 1.380(5) .
C30 N5 1.314(6) .
C30 N7 1.371(6) .
C30 C31 1.490(7) .
C31 H31A 0.9800 .
C31 H31B 0.9800 .
C31 H31C 0.9800 .
C32 O6 1.231(6) .
C32 N8 1.380(6) .
C32 C33 1.495(7) .
C33 C38 1.389(7) .
C33 C34 1.390(7) .
C34 C35 1.401(8) .
C34 H34 0.9500 .
C35 C36 1.396(10) .
C35 C39A 1.523(14) .
C35 C39B 1.581(16) .
C36 C37 1.385(8) .
C36 H36 0.9500 .
C37 C38 1.398(7) .
C37 C40 1.491(8) .
C38 H38 0.9500 .
C39A H39A 0.9800 .
C39A H39B 0.9800 .
C39A H39C 0.9800 .
C39B H39D 0.9800 .
C39B H39E 0.9800 .
C39B H39F 0.9800 .
C40 H40A 0.9800 .
C40 H40B 0.9800 .
C40 H40C 0.9800 .
C41 O7 1.262(5) .
C41 O8 1.265(5) .
C41 C42 1.507(5) .
C42 C47 1.367(6) .
C42 C43 1.416(5) .
C43 C44 1.387(6) .
C43 H43 0.9500 .
C44 C45 1.410(6) .
C44 N11 1.434(5) .
C45 C46 1.391(5) .
C45 H45 0.9500 .
C46 C47 1.395(5) .
C46 N12 1.400(5) .
C47 H47 0.9500 .
C48 C49 1.482(6) .
C48 H48A 0.9800 .
C48 H48B 0.9800 .
C48 H48C 0.9800 .
C49 N10 1.304(5) .
C49 N11 1.390(5) .
C50 N9 1.301(5) .
C50 N11 1.367(5) .
C50 C51 1.477(6) .
C51 H51A 0.9800 .
C51 H51B 0.9800 .
C51 H51C 0.9800 .
C52 O9 1.237(5) .
C52 N12 1.366(5) .
C52 C53 1.503(6) .
C53 C58 1.379(6) .
C53 C54 1.411(6) .
C54 C55 1.397(6) .
C54 H54 0.9500 .
C55 C56 1.388(7) .
C55 C59 1.510(7) .
C56 C57 1.389(7) .
C56 H56 0.9500 .
C57 C58 1.410(6) .
C57 C60 1.503(6) .
C58 H58 0.9500 .
C59 H59A 0.9800 .
C59 H59B 0.9800 .
C59 H59C 0.9800 .
C60 H60A 0.9800 .
C60 H60B 0.9800 .
C60 H60C 0.9800 .
C61 O10 1.253(5) .
C61 O11 1.266(5) .
C61 C62 1.518(6) .
C62 C67 1.383(6) .
C62 C63 1.401(5) .
C63 C64 1.343(6) .
C63 H63 0.9500 .
C64 C65 1.404(6) .
C64 N15 1.452(5) .
C65 C66 1.394(6) .
C65 H65 0.9500 .
C66 N16 1.395(6) .
C66 C67 1.403(6) .
C67 H67 0.9500 .
C68 C69 1.492(6) .
C68 H68A 0.9800 .
C68 H68B 0.9800 .
C68 H68C 0.9800 .
C69 N14 1.296(5) .
C69 N15 1.376(6) .
C70 N13 1.312(5) .
C70 N15 1.374(5) .
C70 C71 1.464(6) .
C71 H71A 0.9800 .
C71 H71B 0.9800 .
C71 H71C 0.9800 .
C72 O12 1.197(6) .
C72 N16 1.367(6) .
C72 C73 1.504(6) .
C73 C74 1.377(7) .
C73 C78 1.408(7) .
C74 C75 1.394(7) .
C74 H74 0.9500 .
C75 C76 1.387(9) .
C75 C79 1.539(9) .
C76 C77 1.405(9) .
C76 H76 0.9500 .
C77 C78 1.378(7) .
C77 C80 1.515(8) .
C78 H78 0.9500 .
C79 H79A 0.9800 .
C79 H79B 0.9800 .
C79 H79C 0.9800 .
C80 H80A 0.9800 .
C80 H80B 0.9800 .
C80 H80C 0.9800 .
Ag1 N14 2.219(3) .
Ag1 N10 2.253(3) .
Ag1 O1 2.342(3) .
Ag2 N9 2.206(3) .
Ag2 N13 2.252(3) .
Ag2 O4 2.325(3) .
Ag3 N6 2.216(3) 5_544
Ag3 N1 2.249(3) .
Ag3 O10 2.319(3) 7_644
Ag4 N2 2.200(3) .
Ag4 N5 2.247(3) 5_544
Ag4 O7 2.358(3) 3_754
N1 N2 1.385(5) .
N4 H4 0.8800 .
N5 N6 1.375(5) .
N5 Ag4 2.247(3) 5_455
N6 Ag3 2.216(3) 5_455
N8 H8 0.8800 .
N9 N10 1.395(5) .
N12 H12 0.8800 .
N13 N14 1.389(5) .
N16 H16A 0.8800 .
O7 Ag4 2.358(3) 3_755
O10 Ag3 2.319(3) 7_654
