#------------------------------------------------------------------------------
#$Date: 2016-03-23 23:40:49 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179511 $
#$URL: svn://www.crystallography.net/cod/cif/4/34/08/4340875.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4340875
loop_
_publ_author_name
'Powers, David C.'
'Hwang, Seung Jun'
'Zheng, Shao-Liang'
'Nocera, Daniel G.'
_publ_section_title
;
 Halide-Bridged Binuclear HX-Splitting Catalysts.
;
_journal_issue                   17
_journal_name_full               'Inorganic chemistry'
_journal_page_first              9122
_journal_page_last               9128
_journal_paper_doi               10.1021/ic501136m
_journal_volume                  53
_journal_year                    2014
_chemical_formula_sum            'C25 H24 Br4 F25 N3 O8 P4 Rh2'
_chemical_formula_weight         1618.81
_chemical_name_common            Rh2Br4(tfepma)2(4-F-C6H4NC)
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           8
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'C -2y'
_symmetry_space_group_name_H-M   'C 1 m 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 124.859(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   14.074(2)
_cell_length_b                   21.280(3)
_cell_length_c                   9.6086(15)
_cell_measurement_reflns_used    11145
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      25.72
_cell_measurement_theta_min      1.91
_cell_volume                     2361.3(6)
_computing_cell_refinement       'SAINT 7.46A (Bruker-AXS, 2009)'
_computing_data_collection       'APEX2 v2009.3.0 (Bruker-AXS, 2009)'
_computing_data_reduction        'SAINT 7.46A (Bruker-AXS, 2009)'
_computing_molecular_graphics    'Bruker SHELXTL (Sheldrick, 2008)'
_computing_publication_material  'Bruker SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXT-2014 (Sheldrick, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1013
_diffrn_reflns_av_sigmaI/netI    0.1372
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_number            10524
_diffrn_reflns_theta_full        25.02
_diffrn_reflns_theta_max         25.02
_diffrn_reflns_theta_min         1.91
_exptl_absorpt_coefficient_mu    4.364
_exptl_absorpt_correction_T_max  0.5605
_exptl_absorpt_correction_T_min  0.2742
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    2.277
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1548
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.15
_refine_diff_density_max         0.940
_refine_diff_density_min         -1.040
_refine_diff_density_rms         0.174
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.000(18)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.973
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     287
_refine_ls_number_reflns         4181
_refine_ls_number_restraints     33
_refine_ls_restrained_S_all      0.968
_refine_ls_R_factor_all          0.0913
_refine_ls_R_factor_gt           0.0544
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0117P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0792
_refine_ls_wR_factor_ref         0.0897
_reflns_number_gt                3038
_reflns_number_total             4181
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic501136m_si_002.cif
_cod_data_source_block           Rh2Br4(tfepma)2(4-F-C6H4NC)
_cod_depositor_comments
'Adding full bibliography for 4340872--4340876.cif.'
_cod_original_sg_symbol_H-M      Cm
_cod_database_code               4340875
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'x, -y, z'
'x+1/2, y+1/2, z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.5501(12) 0.2833(5) 0.3615(18) 0.030(3) Uani 1 1 d .
H1A H 0.4708 0.2677 0.3064 0.045 Uiso 1 1 calc R
H1B H 0.5982 0.2679 0.4786 0.045 Uiso 1 1 calc R
H1C H 0.5817 0.2682 0.2994 0.045 Uiso 1 1 calc R
C2 C 0.2736(9) 0.3782(6) 0.2583(14) 0.022(2) Uani 1 1 d .
H2 H 0.3022 0.4080 0.3474 0.027 Uiso 1 1 calc R
C3 C 0.1596(11) 0.3416(6) 0.1722(16) 0.022(2) Uani 1 1 d .
C4 C 0.3266(10) 0.3622(6) -0.1214(14) 0.025(3) Uani 1 1 d .
H4A H 0.3099 0.4065 -0.1595 0.030 Uiso 1 1 calc R
H4B H 0.2593 0.3447 -0.1269 0.030 Uiso 1 1 calc R
C5 C 0.3495(11) 0.3248(7) -0.2309(17) 0.032(4) Uani 1 1 d .
C6 C 0.6660(10) 0.3782(6) 0.7841(15) 0.024(2) Uani 1 1 d .
H6A H 0.5814 0.3721 0.7228 0.029 Uiso 1 1 calc R
H6B H 0.6837 0.4232 0.8141 0.029 Uiso 1 1 calc R
C7 C 0.7284(11) 0.3390(7) 0.9398(16) 0.024(2) Uani 1 1 d .
C8 C 0.8810(8) 0.3594(6) 0.6152(15) 0.020(3) Uani 1 1 d .
H8A H 0.8966 0.3400 0.7199 0.024 Uiso 1 1 calc R
H8B H 0.9130 0.4026 0.6418 0.024 Uiso 1 1 calc R
C9 C 0.9327(10) 0.3219(6) 0.5463(16) 0.021(3) Uani 1 1 d .
C10 C 0.7510(13) 0.5000 0.4110(19) 0.0177(14) Uani 1 2 d S
C11 C 0.9194(14) 0.5000 0.380(2) 0.0177(14) Uani 1 2 d S
C12 C 1.0238(12) 0.5000 0.539(2) 0.0177(14) Uani 1 2 d SU
H12 H 1.0261 0.5000 0.6394 0.021 Uiso 1 2 calc SR
C13 C 1.1240(13) 0.5000 0.5451(19) 0.0177(14) Uani 1 2 d SU
H13 H 1.1976 0.5000 0.6509 0.021 Uiso 1 2 calc SR
C14 C 1.1157(14) 0.5000 0.399(2) 0.0177(14) Uani 1 2 d SU
C15 C 1.0163(12) 0.5000 0.243(2) 0.0177(14) Uani 1 2 d SU
H15 H 1.0159 0.5000 0.1435 0.021 Uiso 1 2 calc SR
C16 C 0.9106(13) 0.5000 0.233(2) 0.0177(14) Uani 1 2 d SU
H16 H 0.8372 0.5000 0.1274 0.021 Uiso 1 2 calc SR
N1 N 0.5494(10) 0.3535(4) 0.3615(14) 0.019(2) Uani 1 1 d .
N2 N 0.8162(11) 0.5000 0.3814(16) 0.0177(14) Uani 1 2 d S
O1 O 0.3278(7) 0.3589(4) 0.1797(9) 0.0200(10) Uani 1 1 d .
O2 O 0.4283(6) 0.3582(4) 0.0470(10) 0.0200(10) Uani 1 1 d .
O3 O 0.7028(6) 0.3596(3) 0.6809(10) 0.0200(10) Uani 1 1 d .
O4 O 0.7587(6) 0.3605(4) 0.4846(10) 0.0200(10) Uani 1 1 d .
F1 F 0.1090(6) 0.3557(3) 0.2490(9) 0.036(2) Uani 1 1 d .
F2 F 0.1740(6) 0.2803(3) 0.1779(10) 0.038(2) Uani 1 1 d .
F3 F 0.0903(6) 0.3590(4) 0.0109(9) 0.049(2) Uani 1 1 d .
F4 F 0.3771(9) 0.2659(4) -0.1825(11) 0.062(3) Uani 1 1 d .
F5 F 0.2540(6) 0.3240(4) -0.3920(9) 0.049(3) Uani 1 1 d .
F6 F 0.4321(7) 0.3486(4) -0.2398(10) 0.045(2) Uani 1 1 d .
F7 F 0.7024(7) 0.2792(4) 0.9061(10) 0.046(2) Uani 1 1 d .
F8 F 0.6990(6) 0.3574(4) 1.0428(9) 0.044(2) Uani 1 1 d .
F9 F 0.8417(6) 0.3442(4) 1.0224(10) 0.046(2) Uani 1 1 d .
F10 F 0.9005(6) 0.2627(3) 0.5184(10) 0.0323(19) Uani 1 1 d .
F11 F 1.0502(5) 0.3214(4) 0.6633(9) 0.040(2) Uani 1 1 d .
F12 F 0.9174(6) 0.3448(3) 0.4076(9) 0.0337(19) Uani 1 1 d .
F13 F 1.2176(8) 0.5000 0.4057(13) 0.041(3) Uani 1 2 d S
P1 P 0.4358(3) 0.39298(14) 0.1989(4) 0.0142(8) Uani 1 1 d .
P2 P 0.6664(3) 0.39254(14) 0.5065(4) 0.0166(8) Uani 1 1 d .
Br1 Br 0.49681(14) 0.5000 0.0073(2) 0.0213(4) Uani 1 2 d S
Br2 Br 0.22615(13) 0.5000 -0.01138(19) 0.0182(4) Uani 1 2 d S
Br3 Br 0.48033(13) 0.5000 0.50185(19) 0.0160(4) Uani 1 2 d S
Br4 Br 0.84413(14) 0.5000 0.7972(2) 0.0221(4) Uani 1 2 d S
Rh1 Rh 0.44464(10) 0.5000 0.21304(14) 0.0130(3) Uani 1 2 d S
Rh2 Rh 0.65720(10) 0.5000 0.49515(15) 0.0133(3) Uani 1 2 d S
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 C2 C3 106.5(10) . .
F2 C3 F1 108.8(10) . .
F2 C3 F3 108.5(11) . .
F1 C3 F3 108.6(10) . .
F2 C3 C2 113.0(11) . .
F1 C3 C2 108.5(10) . .
F3 C3 C2 109.4(10) . .
O2 C4 C5 106.7(10) . .
F6 C5 F4 107.2(11) . .
F6 C5 F5 105.5(10) . .
F4 C5 F5 107.0(11) . .
F6 C5 C4 113.3(12) . .
F4 C5 C4 113.4(11) . .
F5 C5 C4 109.9(11) . .
O3 C6 C7 107.9(10) . .
F7 C7 F9 107.5(11) . .
F7 C7 F8 107.8(10) . .
F9 C7 F8 108.1(10) . .
F7 C7 C6 112.0(11) . .
F9 C7 C6 112.1(11) . .
F8 C7 C6 109.2(11) . .
O4 C8 C9 105.7(9) . .
F10 C9 F12 108.1(11) . .
F10 C9 F11 106.0(10) . .
F12 C9 F11 104.9(10) . .
F10 C9 C8 114.2(10) . .
F12 C9 C8 114.7(10) . .
F11 C9 C8 108.1(10) . .
N2 C10 Rh2 171.8(14) . .
C16 C11 C12 123.9(16) . .
C16 C11 N2 121.0(15) . .
C12 C11 N2 115.1(14) . .
C13 C12 C11 117.7(16) . .
C14 C13 C12 118.7(16) . .
C15 C14 C13 125.4(17) . .
C15 C14 F13 116.1(15) . .
C13 C14 F13 118.5(14) . .
C14 C15 C16 116.7(16) . .
C11 C16 C15 117.6(15) . .
C1 N1 P2 120.0(9) . .
C1 N1 P1 120.0(9) . .
P2 N1 P1 119.4(5) . .
C10 N2 C11 168.2(16) . .
C2 O1 P1 125.4(7) . .
C4 O2 P1 120.9(7) . .
C6 O3 P2 125.7(7) . .
C8 O4 P2 123.7(7) . .
O2 P1 O1 97.1(4) . .
O2 P1 N1 98.6(5) . .
O1 P1 N1 102.5(5) . .
O2 P1 Rh1 119.6(3) . .
O1 P1 Rh1 118.4(3) . .
N1 P1 Rh1 116.8(3) . .
O4 P2 O3 98.8(4) . .
O4 P2 N1 99.7(5) . .
O3 P2 N1 103.3(5) . .
O4 P2 Rh2 116.9(3) . .
O3 P2 Rh2 117.5(3) . .
N1 P2 Rh2 117.5(3) . .
Rh1 Br3 Rh2 63.35(5) . .
P1 Rh1 P1 173.90(17) 2_565 .
P1 Rh1 Br1 89.05(8) 2_565 .
P1 Rh1 Br1 89.05(8) . .
P1 Rh1 Br3 92.03(8) 2_565 .
P1 Rh1 Br3 92.03(8) . .
Br1 Rh1 Br3 156.48(7) . .
P1 Rh1 Br2 87.20(9) 2_565 .
P1 Rh1 Br2 87.20(9) . .
Br1 Rh1 Br2 95.13(7) . .
Br3 Rh1 Br2 108.39(6) . .
P1 Rh1 Rh2 93.00(9) 2_565 .
P1 Rh1 Rh2 93.00(9) . .
Br1 Rh1 Rh2 98.07(6) . .
Br3 Rh1 Rh2 58.41(5) . .
Br2 Rh1 Rh2 166.80(7) . .
C10 Rh2 P2 89.22(9) . 2_565
C10 Rh2 P2 89.22(9) . .
P2 Rh2 P2 174.40(17) 2_565 .
C10 Rh2 Br3 160.8(5) . .
P2 Rh2 Br3 91.62(9) 2_565 .
P2 Rh2 Br3 91.62(9) . .
C10 Rh2 Br4 88.2(5) . .
P2 Rh2 Br4 87.29(9) 2_565 .
P2 Rh2 Br4 87.29(9) . .
Br3 Rh2 Br4 111.00(7) . .
C10 Rh2 Rh1 102.5(5) . .
P2 Rh2 Rh1 92.80(9) 2_565 .
P2 Rh2 Rh1 92.80(9) . .
Br3 Rh2 Rh1 58.24(5) . .
Br4 Rh2 Rh1 169.24(7) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 N1 1.494(12) .
C2 O1 1.406(13) .
C2 C3 1.532(16) .
C3 F2 1.317(13) .
C3 F1 1.319(13) .
C3 F3 1.327(14) .
C4 O2 1.423(13) .
C4 C5 1.492(16) .
C5 F6 1.316(13) .
C5 F4 1.316(15) .
C5 F5 1.351(14) .
C6 O3 1.412(13) .
C6 C7 1.483(16) .
C7 F7 1.313(15) .
C7 F9 1.317(14) .
C7 F8 1.332(13) .
C8 O4 1.438(12) .
C8 C9 1.469(15) .
C9 F10 1.313(13) .
C9 F12 1.315(13) .
C9 F11 1.369(12) .
C10 N2 1.106(18) .
C10 Rh2 1.902(16) .
C11 C16 1.34(2) .
C11 C12 1.39(2) .
C11 N2 1.46(2) .
C12 C13 1.38(2) .
C13 C14 1.34(2) .
C14 C15 1.343(19) .
C14 F13 1.397(17) .
C15 C16 1.44(2) .
N1 P2 1.650(11) .
N1 P1 1.688(11) .
O1 P1 1.596(9) .
O2 P1 1.585(9) .
O3 P2 1.606(9) .
O4 P2 1.585(8) .
P1 Rh1 2.281(3) .
P2 Rh2 2.289(3) .
Br1 Rh1 2.471(2) .
Br2 Rh1 2.5546(19) .
Br3 Rh1 2.522(2) .
Br3 Rh2 2.527(2) .
Br4 Rh2 2.572(2) .
Rh1 P1 2.280(3) 2_565
Rh1 Rh2 2.6509(16) .
Rh2 P2 2.289(3) 2_565
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O1 C2 C3 F2 55.8(13) . .
O1 C2 C3 F1 176.5(9) . .
O1 C2 C3 F3 -65.2(13) . .
O2 C4 C5 F6 -65.2(15) . .
O2 C4 C5 F4 57.4(14) . .
O2 C4 C5 F5 177.0(10) . .
O3 C6 C7 F7 -63.2(13) . .
O3 C6 C7 F9 57.7(15) . .
O3 C6 C7 F8 177.4(9) . .
O4 C8 C9 F10 -64.6(13) . .
O4 C8 C9 F12 61.0(13) . .
O4 C8 C9 F11 177.6(9) . .
C16 C11 C12 C13 0.000(6) . .
N2 C11 C12 C13 180.000(3) . .
C11 C12 C13 C14 0.000(5) . .
C12 C13 C14 C15 0.000(4) . .
C12 C13 C14 F13 180.000(3) . .
C13 C14 C15 C16 0.000(5) . .
F13 C14 C15 C16 180.000(3) . .
C12 C11 C16 C15 0.000(5) . .
N2 C11 C16 C15 180.000(3) . .
C14 C15 C16 C11 0.000(4) . .
Rh2 C10 N2 C11 0.00(2) . .
C16 C11 N2 C10 180.000(11) . .
C12 C11 N2 C10 0.000(13) . .
C3 C2 O1 P1 167.2(8) . .
C5 C4 O2 P1 179.6(8) . .
C7 C6 O3 P2 -174.8(8) . .
C9 C8 O4 P2 176.4(8) . .
C4 O2 P1 O1 58.9(9) . .
C4 O2 P1 N1 162.7(9) . .
C4 O2 P1 Rh1 -69.7(9) . .
C2 O1 P1 O2 -166.6(8) . .
C2 O1 P1 N1 92.9(9) . .
C2 O1 P1 Rh1 -37.3(10) . .
C1 N1 P1 O2 -50.5(10) . .
P2 N1 P1 O2 121.4(7) . .
C1 N1 P1 O1 48.8(10) . .
P2 N1 P1 O1 -139.3(7) . .
C1 N1 P1 Rh1 -180.0(8) . .
P2 N1 P1 Rh1 -8.0(9) . .
C8 O4 P2 O3 -51.7(9) . .
C8 O4 P2 N1 -156.9(9) . .
C8 O4 P2 Rh2 75.4(9) . .
C6 O3 P2 O4 166.9(9) . .
C6 O3 P2 N1 -90.8(10) . .
C6 O3 P2 Rh2 40.3(10) . .
C1 N1 P2 O4 52.4(11) . .
P1 N1 P2 O4 -119.6(7) . .
C1 N1 P2 O3 -49.2(10) . .
P1 N1 P2 O3 138.9(7) . .
C1 N1 P2 Rh2 179.7(8) . .
P1 N1 P2 Rh2 7.7(9) . .
O2 P1 Rh1 P1 55.6(18) . 2_565
O1 P1 Rh1 P1 -62.4(17) . 2_565
N1 P1 Rh1 P1 174.2(16) . 2_565
O2 P1 Rh1 Br1 -16.3(4) . .
O1 P1 Rh1 Br1 -134.3(4) . .
N1 P1 Rh1 Br1 102.3(5) . .
O2 P1 Rh1 Br3 -172.8(4) . .
O1 P1 Rh1 Br3 69.2(4) . .
N1 P1 Rh1 Br3 -54.2(5) . .
O2 P1 Rh1 Br2 78.9(4) . .
O1 P1 Rh1 Br2 -39.1(4) . .
N1 P1 Rh1 Br2 -162.5(5) . .
O2 P1 Rh1 Rh2 -114.3(4) . .
O1 P1 Rh1 Rh2 127.7(4) . .
N1 P1 Rh1 Rh2 4.3(5) . .
Rh2 Br3 Rh1 P1 -92.28(9) . 2_565
Rh2 Br3 Rh1 P1 92.28(9) . .
Rh2 Br3 Rh1 Br1 0.0 . .
Rh2 Br3 Rh1 Br2 180.0 . .
N2 C10 Rh2 P2 87.31(9) . 2_565
N2 C10 Rh2 P2 -87.31(9) . .
N2 C10 Rh2 Br3 180.00(2) . .
N2 C10 Rh2 Br4 0.00(2) . .
N2 C10 Rh2 Rh1 180.00(2) . .
O4 P2 Rh2 C10 12.3(6) . .
O3 P2 Rh2 C10 129.5(6) . .
N1 P2 Rh2 C10 -106.2(7) . .
O4 P2 Rh2 P2 -62(2) . 2_565
O3 P2 Rh2 P2 56(2) . 2_565
N1 P2 Rh2 P2 180(100) . 2_565
O4 P2 Rh2 Br3 173.1(4) . .
O3 P2 Rh2 Br3 -69.7(3) . .
N1 P2 Rh2 Br3 54.6(5) . .
O4 P2 Rh2 Br4 -76.0(4) . .
O3 P2 Rh2 Br4 41.3(3) . .
N1 P2 Rh2 Br4 165.6(5) . .
O4 P2 Rh2 Rh1 114.8(4) . .
O3 P2 Rh2 Rh1 -127.9(3) . .
N1 P2 Rh2 Rh1 -3.7(5) . .
Rh1 Br3 Rh2 C10 0.000(6) . .
Rh1 Br3 Rh2 P2 92.28(9) . 2_565
Rh1 Br3 Rh2 P2 -92.28(9) . .
Rh1 Br3 Rh2 Br4 180.0 . .
P1 Rh1 Rh2 C10 -89.47(9) 2_565 .
P1 Rh1 Rh2 C10 89.47(9) . .
Br1 Rh1 Rh2 C10 0.000(2) . .
Br3 Rh1 Rh2 C10 180.000(1) . .
Br2 Rh1 Rh2 C10 180.000(2) . .
P1 Rh1 Rh2 P2 0.35(11) 2_565 2_565
P1 Rh1 Rh2 P2 179.29(14) . 2_565
Br1 Rh1 Rh2 P2 89.82(9) . 2_565
Br3 Rh1 Rh2 P2 -90.18(9) . 2_565
Br2 Rh1 Rh2 P2 -90.18(9) . 2_565
P1 Rh1 Rh2 P2 -179.29(14) 2_565 .
P1 Rh1 Rh2 P2 -0.36(11) . .
Br1 Rh1 Rh2 P2 -89.82(9) . .
Br3 Rh1 Rh2 P2 90.18(9) . .
Br2 Rh1 Rh2 P2 90.18(9) . .
P1 Rh1 Rh2 Br3 90.53(9) 2_565 .
P1 Rh1 Rh2 Br3 -90.53(9) . .
Br1 Rh1 Rh2 Br3 180.0 . .
Br2 Rh1 Rh2 Br3 0.0 . .
P1 Rh1 Rh2 Br4 90.53(9) 2_565 .
P1 Rh1 Rh2 Br4 -90.53(9) . .
Br1 Rh1 Rh2 Br4 180.000(2) . .
Br3 Rh1 Rh2 Br4 0.000(2) . .
Br2 Rh1 Rh2 Br4 0.000(1) . .
