#------------------------------------------------------------------------------
#$Date: 2016-03-23 23:55:35 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179518 $
#$URL: svn://www.crystallography.net/cod/cif/4/34/15/4341526.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4341526
loop_
_publ_author_name
'Liu, Bo'
'Pan, Shanfei'
'Liu, Bin'
'Chen, Wanzhi'
_publ_section_title
;
 Di-, tri-, and tetranuclear copper(i) complexes of phenanthroline-linked
 dicarbene ligands.
;
_journal_issue                   19
_journal_name_full               'Inorganic chemistry'
_journal_page_first              10485
_journal_page_last               10497
_journal_paper_doi               10.1021/ic501544d
_journal_volume                  53
_journal_year                    2014
_chemical_formula_sum            'C56 H52 Cu4 F24 N16 P4'
_chemical_formula_weight         1783.18
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 125.62(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   37.440(6)
_cell_length_b                   20.4871(8)
_cell_length_c                   22.563(8)
_cell_measurement_reflns_used    6497
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      29.5333
_cell_measurement_theta_min      2.8800
_cell_volume                     14069(9)
_computing_cell_refinement       'Bruker FRAMBO'
_computing_data_collection       'Bruker FRAMBO'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'multiwire proportional'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0405
_diffrn_reflns_av_sigmaI/netI    0.0626
_diffrn_reflns_limit_h_max       44
_diffrn_reflns_limit_h_min       -40
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            27446
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         2.89
_exptl_absorpt_coefficient_mu    1.398
_exptl_absorpt_correction_T_max  0.7213
_exptl_absorpt_correction_T_min  0.6404
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.684
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             7136
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.32
_exptl_crystal_size_min          0.25
_refine_diff_density_max         0.816
_refine_diff_density_min         -0.744
_refine_diff_density_rms         0.080
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.056
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     942
_refine_ls_number_reflns         12353
_refine_ls_number_restraints     245
_refine_ls_restrained_S_all      1.063
_refine_ls_R_factor_all          0.1015
_refine_ls_R_factor_gt           0.0589
_refine_ls_shift/su_max          0.016
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0300P)²+66.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1201
_refine_ls_wR_factor_ref         0.1399
_reflns_number_gt                7749
_reflns_number_total             12353
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic501544d_si_002.cif
_cod_data_source_block           6
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/current/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2827 2014-09-09 07:05:25Z andrius 
;
_cod_original_cell_volume        14068(6)
_cod_original_sg_symbol_H-M      'C2/c  '
_cod_database_code               4341526
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Cu1 Cu 0.19874(2) 0.73468(4) 0.55265(4) 0.0623(2) Uani 1 1 d .
Cu2 Cu 0.131011(19) 0.74760(3) 0.56469(3) 0.03908(16) Uani 1 1 d .
Cu3 Cu 0.10925(2) 0.76730(3) 0.65537(3) 0.04242(17) Uani 1 1 d .
Cu4 Cu 0.03809(3) 0.76733(4) 0.67201(5) 0.0778(3) Uani 1 1 d .
C1 C 0.21830(17) 0.6691(3) 0.6266(3) 0.0470(13) Uani 1 1 d .
C2 C 0.2596(2) 0.6072(3) 0.7271(4) 0.0711(18) Uani 1 1 d U
H2 H 0.2838 0.5928 0.7720 0.085 Uiso 1 1 calc R
C3 C 0.2206(2) 0.5793(3) 0.6880(4) 0.0659(17) Uani 1 1 d U
H3 H 0.2120 0.5416 0.6997 0.079 Uiso 1 1 calc R
C4 C 0.15080(17) 0.6020(2) 0.5682(3) 0.0452(13) Uani 1 1 d U
C5 C 0.1405(2) 0.5391(3) 0.5391(3) 0.0612(16) Uani 1 1 d U
H5 H 0.1622 0.5072 0.5582 0.073 Uiso 1 1 calc R
C6 C 0.0986(2) 0.5249(3) 0.4825(4) 0.0659(17) Uani 1 1 d U
H6 H 0.0915 0.4833 0.4624 0.079 Uiso 1 1 calc R
C7 C 0.06615(19) 0.5731(3) 0.4546(3) 0.0527(14) Uani 1 1 d U
C8 C 0.0211(2) 0.5623(3) 0.3956(3) 0.0600(16) Uani 1 1 d U
H8 H 0.0125 0.5219 0.3724 0.072 Uiso 1 1 calc R
C9 C -0.00909(19) 0.6098(3) 0.3731(3) 0.0578(15) Uani 1 1 d U
H9 H -0.0381 0.6015 0.3346 0.069 Uiso 1 1 calc R
C10 C 0.00238(17) 0.6724(3) 0.4070(3) 0.0456(13) Uani 1 1 d U
C11 C -0.02787(17) 0.7224(3) 0.3884(3) 0.0518(14) Uani 1 1 d U
H11 H -0.0573 0.7167 0.3499 0.062 Uiso 1 1 calc R
C12 C -0.01433(16) 0.7795(3) 0.4266(3) 0.0465(13) Uani 1 1 d U
H12 H -0.0343 0.8128 0.4152 0.056 Uiso 1 1 calc R
C13 C 0.03001(15) 0.7869(2) 0.4830(3) 0.0360(11) Uani 1 1 d U
C14 C 0.04636(16) 0.6846(2) 0.4640(3) 0.0384(11) Uani 1 1 d U
C15 C 0.07926(16) 0.6347(2) 0.4881(3) 0.0406(12) Uani 1 1 d U
C16 C 0.03152(19) 0.9068(3) 0.5013(3) 0.0540(15) Uani 1 1 d U
H16 H 0.0101 0.9195 0.4535 0.065 Uiso 1 1 calc R
C17 C 0.05495(19) 0.9457(3) 0.5587(4) 0.0577(16) Uani 1 1 d U
H17 H 0.0532 0.9909 0.5587 0.069 Uiso 1 1 calc R
C18 C 0.07737(16) 0.8430(2) 0.6009(3) 0.0403(12) Uani 1 1 d .
C19 C 0.02266(17) 0.6896(3) 0.6147(3) 0.0462(13) Uani 1 1 d .
C20 C -0.01341(19) 0.6091(3) 0.5330(3) 0.0570(15) Uani 1 1 d U
H20 H -0.0362 0.5860 0.4931 0.068 Uiso 1 1 calc R
C21 C 0.0274(2) 0.5881(3) 0.5798(3) 0.0551(15) Uani 1 1 d U
H21 H 0.0390 0.5480 0.5795 0.066 Uiso 1 1 calc R
C22 C 0.09296(18) 0.6336(3) 0.6943(3) 0.0483(13) Uani 1 1 d U
C23 C 0.1029(2) 0.5831(3) 0.7430(4) 0.0610(16) Uani 1 1 d U
H23 H 0.0818 0.5524 0.7329 0.073 Uiso 1 1 calc R
C24 C 0.1440(2) 0.5797(3) 0.8051(4) 0.0677(17) Uani 1 1 d U
H24 H 0.1509 0.5476 0.8394 0.081 Uiso 1 1 calc R
C25 C 0.1760(2) 0.6239(3) 0.8183(3) 0.0574(15) Uani 1 1 d U
C26 C 0.2207(2) 0.6223(4) 0.8803(3) 0.0724(18) Uani 1 1 d U
H26 H 0.2295 0.5908 0.9160 0.087 Uiso 1 1 calc R
C27 C 0.2503(2) 0.6645(3) 0.8885(3) 0.0695(18) Uani 1 1 d U
H27 H 0.2791 0.6619 0.9299 0.083 Uiso 1 1 calc R
C28 C 0.23889(18) 0.7135(3) 0.8356(3) 0.0539(14) Uani 1 1 d U
C29 C 0.26854(19) 0.7573(3) 0.8401(3) 0.0619(16) Uani 1 1 d U
H29 H 0.2977 0.7567 0.8804 0.074 Uiso 1 1 calc R
C30 C 0.25491(17) 0.8012(3) 0.7852(3) 0.0538(15) Uani 1 1 d U
H30 H 0.2746 0.8303 0.7871 0.065 Uiso 1 1 calc R
C31 C 0.21065(16) 0.8014(2) 0.7263(3) 0.0417(12) Uani 1 1 d U
C32 C 0.19494(17) 0.7172(3) 0.7743(3) 0.0430(12) Uani 1 1 d U
C33 C 0.16292(17) 0.6730(3) 0.7653(3) 0.0443(12) Uani 1 1 d U
C34 C 0.2081(2) 0.9089(3) 0.6717(4) 0.0592(16) Uani 1 1 d U
H34 H 0.2297 0.9307 0.7139 0.071 Uiso 1 1 calc R
C35 C 0.1839(2) 0.9331(3) 0.6049(4) 0.0631(17) Uani 1 1 d U
H35 H 0.1854 0.9753 0.5915 0.076 Uiso 1 1 calc R
C36 C 0.16221(16) 0.8285(2) 0.5954(3) 0.0386(12) Uani 1 1 d .
C37 C 0.2510(2) 0.8505(4) 0.5525(4) 0.0734(19) Uani 1 1 d U
C38 C 0.2745(3) 0.9078(4) 0.5523(5) 0.113(3) Uani 1 1 d U
H38A H 0.2705 0.9439 0.5750 0.169 Uiso 1 1 calc R
H38B H 0.2632 0.9189 0.5030 0.169 Uiso 1 1 calc R
H38C H 0.3053 0.8979 0.5789 0.169 Uiso 1 1 calc R
C39 C 0.1216(3) 0.7008(4) 0.3919(4) 0.082(2) Uani 1 1 d U
C40 C 0.0842(3) 0.6781(5) 0.3199(4) 0.131(4) Uani 1 1 d U
H40A H 0.0765 0.6345 0.3241 0.196 Uiso 1 1 calc R
H40B H 0.0922 0.6785 0.2865 0.196 Uiso 1 1 calc R
H40C H 0.0595 0.7066 0.3023 0.196 Uiso 1 1 calc R
C41 C 0.1208(3) 0.7804(4) 0.8350(4) 0.082(2) Uani 1 1 d U
C42 C 0.1601(3) 0.7812(5) 0.9100(4) 0.122(3) Uani 1 1 d U
H42A H 0.1785 0.7448 0.9177 0.183 Uiso 1 1 calc R
H42B H 0.1517 0.7783 0.9429 0.183 Uiso 1 1 calc R
H42C H 0.1759 0.8211 0.9188 0.183 Uiso 1 1 calc R
C43 C -0.0170(3) 0.8844(5) 0.6577(5) 0.149(5) Uani 1 1 d U
C44 C -0.0441(4) 0.9391(6) 0.6538(6) 0.209(7) Uani 1 1 d U
H44A H -0.0440 0.9739 0.6254 0.314 Uiso 1 1 calc R
H44B H -0.0322 0.9546 0.7021 0.314 Uiso 1 1 calc R
H44C H -0.0737 0.9244 0.6313 0.314 Uiso 1 1 calc R
C45 C 0.3629(3) 0.6780(5) 0.7248(6) 0.146(4) Uani 1 1 d U
H45A H 0.3804 0.6943 0.7721 0.175 Uiso 1 1 calc R
H45B H 0.3759 0.6607 0.7035 0.175 Uiso 1 1 calc R
C46 C 0.3237(2) 0.6793(4) 0.6914(5) 0.102(3) Uani 1 1 d U
H46 H 0.3084 0.6622 0.6445 0.122 Uiso 1 1 calc R
C47 C 0.29613(18) 0.7041(3) 0.7137(4) 0.0662(17) Uani 1 1 d U
H47A H 0.2856 0.7474 0.6933 0.079 Uiso 1 1 calc R
H47B H 0.3140 0.7079 0.7664 0.079 Uiso 1 1 calc R
C48 C 0.1140(2) 0.9317(3) 0.6919(4) 0.0673(17) Uani 1 1 d U
H48A H 0.1310 0.8957 0.7243 0.081 Uiso 1 1 calc R
H48B H 0.1342 0.9610 0.6915 0.081 Uiso 1 1 calc R
C49 C 0.0928(4) 0.9662(5) 0.7196(5) 0.122(3) Uani 1 1 d DU
H49 H 0.0833 0.9370 0.7392 0.146 Uiso 1 1 calc R
C50 C 0.0841(5) 1.0195(6) 0.7246(7) 0.194(5) Uani 1 1 d DU
H50A H 0.0916 1.0540 0.7072 0.232 Uiso 1 1 calc R
H50B H 0.0695 1.0276 0.7461 0.232 Uiso 1 1 calc R
C51 C 0.12375(18) 0.8928(3) 0.4809(3) 0.0585(15) Uani 1 1 d U
H51A H 0.1042 0.9283 0.4727 0.070 Uiso 1 1 calc R
H51B H 0.1062 0.8533 0.4611 0.070 Uiso 1 1 calc R
C52 C 0.1430(2) 0.9067(5) 0.4408(4) 0.099(3) Uani 1 1 d U
H52 H 0.1526 0.8700 0.4297 0.119 Uiso 1 1 calc R
C53 C 0.1486(3) 0.9572(5) 0.4201(5) 0.130(3) Uani 1 1 d U
H53A H 0.1399 0.9965 0.4290 0.156 Uiso 1 1 calc R
H53B H 0.1615 0.9571 0.3953 0.156 Uiso 1 1 calc R
C54 C -0.05757(19) 0.7065(3) 0.5201(3) 0.0640(16) Uani 1 1 d U
H54A H -0.0746 0.7020 0.4675 0.077 Uiso 1 1 calc R
H54B H -0.0513 0.7525 0.5318 0.077 Uiso 1 1 calc R
C55 C -0.0838(2) 0.6823(3) 0.5455(4) 0.0760(19) Uani 1 1 d U
H55 H -0.0714 0.6859 0.5950 0.091 Uiso 1 1 calc R
C56 C -0.1223(2) 0.6569(4) 0.5046(5) 0.101(3) Uani 1 1 d U
H56A H -0.1358 0.6525 0.4548 0.122 Uiso 1 1 calc R
H56B H -0.1367 0.6428 0.5248 0.122 Uiso 1 1 calc R
F1 F 0.3705(2) 0.4241(3) 0.3723(3) 0.154(2) Uani 1 1 d .
F2 F 0.39364(19) 0.3491(2) 0.5103(3) 0.1275(17) Uani 1 1 d .
F3 F 0.43066(16) 0.3792(3) 0.4693(4) 0.159(2) Uani 1 1 d .
F4 F 0.33466(17) 0.3953(4) 0.4152(5) 0.204(4) Uani 1 1 d .
F5 F 0.39543(18) 0.4538(2) 0.4820(3) 0.1242(17) Uani 1 1 d .
F6 F 0.3713(2) 0.3203(2) 0.4012(3) 0.163(3) Uani 1 1 d .
F7 F 0.17773(19) 0.5276(3) 0.2564(4) 0.162(3) Uani 1 1 d .
F8 F 0.1153(2) 0.6398(4) 0.1653(5) 0.206(4) Uani 1 1 d .
F9 F 0.16710(17) 0.5879(3) 0.1669(3) 0.1279(18) Uani 1 1 d .
F10 F 0.12439(16) 0.5748(3) 0.2518(3) 0.1210(17) Uani 1 1 d .
F11 F 0.1814(2) 0.6313(3) 0.2676(3) 0.150(2) Uani 1 1 d .
F12 F 0.1120(2) 0.5336(4) 0.1534(4) 0.202(4) Uani 1 1 d .
F13 F 0.27020(18) 0.9279(2) 0.8772(3) 0.1244(18) Uani 1 1 d .
F14 F 0.21924(15) 0.9306(3) 0.9494(3) 0.1177(17) Uani 1 1 d .
F15 F 0.28487(19) 0.9599(3) 0.9833(3) 0.152(2) Uani 1 1 d .
F16 F 0.20602(17) 0.8906(4) 0.8451(3) 0.164(3) Uani 1 1 d .
F17 F 0.26315(18) 0.8605(2) 0.9473(3) 0.1299(18) Uani 1 1 d .
F18 F 0.2254(3) 0.9966(3) 0.8795(4) 0.208(4) Uani 1 1 d .
F19 F -0.00764(18) 0.4189(2) 0.1734(2) 0.1154(17) Uani 1 1 d .
F20 F 0.0356(2) 0.3648(3) 0.2757(3) 0.153(2) Uani 1 1 d .
F21 F 0.03501(18) 0.4741(2) 0.2751(3) 0.1317(19) Uani 1 1 d .
F22 F 0.4574(2) 0.6587(4) 0.7418(6) 0.243(4) Uani 1 1 d .
F23 F 0.5150(4) 0.7087(5) 0.8039(6) 0.281(6) Uani 1 1 d .
F24 F 0.5165(3) 0.6031(6) 0.8008(6) 0.353(9) Uani 1 1 d .
N1 N 0.23272(17) 0.8075(3) 0.5525(3) 0.0711(15) Uani 1 1 d .
N2 N 0.1497(2) 0.7175(3) 0.4474(3) 0.0749(16) Uani 1 1 d .
N3 N 0.0034(2) 0.8435(3) 0.6610(4) 0.108(2) Uani 1 1 d .
N4 N 0.0909(2) 0.7782(3) 0.7773(3) 0.0824(17) Uani 1 1 d .
N5 N -0.01624(14) 0.6709(2) 0.5536(2) 0.0500(11) Uani 1 1 d .
N6 N 0.04940(14) 0.6387(2) 0.6296(3) 0.0484(11) Uani 1 1 d .
N7 N 0.12113(13) 0.6793(2) 0.7047(2) 0.0416(10) Uani 1 1 d .
N8 N 0.18055(12) 0.7624(2) 0.7200(2) 0.0394(10) Uani 1 1 d .
N9 N 0.19485(13) 0.8446(2) 0.6665(2) 0.0428(10) Uani 1 1 d .
N10 N 0.15614(14) 0.8844(2) 0.5589(2) 0.0455(11) Uani 1 1 d .
N11 N 0.25818(14) 0.6615(2) 0.6896(3) 0.0546(12) Uani 1 1 d .
N12 N 0.19487(14) 0.6174(2) 0.6260(2) 0.0472(11) Uani 1 1 d .
N13 N 0.12134(13) 0.64996(18) 0.5433(2) 0.0370(9) Uani 1 1 d .
N14 N 0.06029(12) 0.74213(18) 0.5007(2) 0.0348(9) Uani 1 1 d .
N15 N 0.04522(13) 0.84372(19) 0.5266(2) 0.0401(10) Uani 1 1 d .
N16 N 0.08249(14) 0.9065(2) 0.6184(3) 0.0482(11) Uani 1 1 d .
P1 P 0.38276(6) 0.38652(8) 0.44163(10) 0.0646(5) Uani 1 1 d .
P2 P 0.14559(6) 0.58316(10) 0.20922(11) 0.0739(5) Uani 1 1 d .
P3 P 0.24402(7) 0.92890(10) 0.91190(11) 0.0764(5) Uani 1 1 d .
P4 P 0.0000 0.41914(13) 0.2500 0.0806(8) Uani 1 2 d S
P4' P 0.5000 0.65511(17) 0.7500 0.0948(10) Uani 1 2 d S
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Cu1 N1 127.8(2) . .
C1 Cu1 N2 121.8(2) . .
N1 Cu1 N2 106.0(2) . .
C1 Cu1 Cu2 83.54(15) . .
N1 Cu1 Cu2 124.76(16) . .
N2 Cu1 Cu2 82.71(16) . .
C36 Cu2 N13 157.42(18) . .
C36 Cu2 N14 122.73(18) . .
N13 Cu2 N14 79.12(15) . .
C36 Cu2 Cu3 89.19(14) . .
N13 Cu2 Cu3 103.94(11) . .
N14 Cu2 Cu3 73.35(11) . .
C36 Cu2 Cu1 73.23(14) . .
N13 Cu2 Cu1 85.89(11) . .
N14 Cu2 Cu1 141.41(11) . .
Cu3 Cu2 Cu1 145.17(4) . .
C18 Cu3 N7 158.81(19) . .
C18 Cu3 N8 122.25(18) . .
N7 Cu3 N8 78.44(16) . .
C18 Cu3 Cu2 89.12(14) . .
N7 Cu3 Cu2 102.81(12) . .
N8 Cu3 Cu2 72.56(11) . .
C18 Cu3 Cu4 78.79(14) . .
N7 Cu3 Cu4 81.57(12) . .
N8 Cu3 Cu4 140.78(11) . .
Cu2 Cu3 Cu4 145.38(4) . .
C19 Cu4 N3 131.5(3) . .
C19 Cu4 N4 125.8(2) . .
N3 Cu4 N4 100.5(3) . .
C19 Cu4 Cu3 81.46(15) . .
N3 Cu4 Cu3 125.3(2) . .
N4 Cu4 Cu3 79.04(17) . .
N11 C1 N12 103.5(5) . .
N11 C1 Cu1 128.7(4) . .
N12 C1 Cu1 127.8(4) . .
C3 C2 N11 107.9(5) . .
C2 C3 N12 106.1(6) . .
N13 C4 C5 123.3(5) . .
N13 C4 N12 117.2(4) . .
C5 C4 N12 119.5(5) . .
C6 C5 C4 119.5(5) . .
C5 C6 C7 119.9(5) . .
C6 C7 C15 116.9(5) . .
C6 C7 C8 123.6(5) . .
C15 C7 C8 119.5(5) . .
C9 C8 C7 120.9(5) . .
C8 C9 C10 121.6(5) . .
C11 C10 C14 117.4(5) . .
C11 C10 C9 124.0(5) . .
C14 C10 C9 118.6(5) . .
C12 C11 C10 120.0(5) . .
C11 C12 C13 118.5(5) . .
N14 C13 C12 123.8(5) . .
N14 C13 N15 115.6(4) . .
C12 C13 N15 120.6(4) . .
N14 C14 C10 122.9(5) . .
N14 C14 C15 116.4(4) . .
C10 C14 C15 120.7(5) . .
N13 C15 C7 123.8(5) . .
N13 C15 C14 117.6(4) . .
C7 C15 C14 118.7(5) . .
C17 C16 N15 106.4(5) . .
C16 C17 N16 107.4(5) . .
N16 C18 N15 102.7(4) . .
N16 C18 Cu3 132.2(4) . .
N15 C18 Cu3 124.6(4) . .
N6 C19 N5 103.7(5) . .
N6 C19 Cu4 126.0(4) . .
N5 C19 Cu4 130.3(4) . .
C21 C20 N5 108.0(5) . .
C20 C21 N6 105.5(5) . .
N7 C22 C23 124.5(5) . .
N7 C22 N6 116.6(5) . .
C23 C22 N6 118.9(5) . .
C24 C23 C22 118.5(6) . .
C23 C24 C25 120.5(6) . .
C24 C25 C33 116.9(6) . .
C24 C25 C26 124.7(6) . .
C33 C25 C26 118.4(6) . .
C27 C26 C25 122.0(6) . .
C26 C27 C28 121.6(6) . .
C29 C28 C32 117.7(5) . .
C29 C28 C27 124.1(6) . .
C32 C28 C27 118.1(6) . .
C30 C29 C28 120.1(5) . .
C29 C30 C31 118.3(5) . .
N8 C31 C30 124.4(5) . .
N8 C31 N9 114.7(4) . .
C30 C31 N9 120.9(5) . .
N8 C32 C28 122.8(5) . .
N8 C32 C33 116.3(5) . .
C28 C32 C33 120.9(5) . .
N7 C33 C25 123.2(5) . .
N7 C33 C32 117.7(5) . .
C25 C33 C32 119.0(5) . .
C35 C34 N9 106.6(5) . .
C34 C35 N10 107.6(5) . .
N10 C36 N9 103.2(4) . .
N10 C36 Cu2 131.7(4) . .
N9 C36 Cu2 124.8(4) . .
N1 C37 C38 179.2(8) . .
N2 C39 C40 178.6(10) . .
N4 C41 C42 178.3(10) . .
N3 C43 C44 179.6(14) . .
C45 C46 C47 129.6(9) . .
C46 C47 N11 112.7(6) . .
C49 C48 N16 112.2(6) . .
C50 C49 C48 139.0(12) . .
N10 C51 C52 113.8(5) . .
C53 C52 C51 131.4(10) . .
N5 C54 C55 111.9(5) . .
C56 C55 C54 125.2(8) . .
C37 N1 Cu1 177.3(6) . .
C39 N2 Cu1 171.1(7) . .
C43 N3 Cu4 174.9(10) . .
C41 N4 Cu4 175.7(7) . .
C19 N5 C20 110.9(5) . .
C19 N5 C54 124.9(5) . .
C20 N5 C54 123.5(5) . .
C19 N6 C21 111.8(5) . .
C19 N6 C22 123.6(5) . .
C21 N6 C22 123.9(5) . .
C22 N7 C33 116.2(4) . .
C22 N7 Cu3 129.4(4) . .
C33 N7 Cu3 113.2(3) . .
C31 N8 C32 116.6(4) . .
C31 N8 Cu3 132.9(4) . .
C32 N8 Cu3 108.7(3) . .
C36 N9 C34 110.9(5) . .
C36 N9 C31 123.6(4) . .
C34 N9 C31 125.4(5) . .
C36 N10 C35 111.7(5) . .
C36 N10 C51 124.3(4) . .
C35 N10 C51 123.9(5) . .
C1 N11 C2 111.3(5) . .
C1 N11 C47 124.1(5) . .
C2 N11 C47 124.5(5) . .
C1 N12 C3 111.2(5) . .
C1 N12 C4 125.2(4) . .
C3 N12 C4 123.5(5) . .
C4 N13 C15 116.7(4) . .
C4 N13 Cu2 129.4(3) . .
C15 N13 Cu2 113.2(3) . .
C13 N14 C14 117.3(4) . .
C13 N14 Cu2 131.8(3) . .
C14 N14 Cu2 109.8(3) . .
C18 N15 C16 111.3(4) . .
C18 N15 C13 123.3(4) . .
C16 N15 C13 125.4(5) . .
C18 N16 C17 112.3(5) . .
C18 N16 C48 124.1(5) . .
C17 N16 C48 123.6(5) . .
F3 P1 F4 178.5(5) . .
F3 P1 F6 90.6(4) . .
F4 P1 F6 90.8(4) . .
F3 P1 F1 92.8(4) . .
F4 P1 F1 87.6(4) . .
F6 P1 F1 91.3(3) . .
F3 P1 F2 88.9(4) . .
F4 P1 F2 90.7(4) . .
F6 P1 F2 88.7(3) . .
F1 P1 F2 178.3(4) . .
F3 P1 F5 87.8(3) . .
F4 P1 F5 90.7(4) . .
F6 P1 F5 178.1(4) . .
F1 P1 F5 87.7(3) . .
F2 P1 F5 92.3(3) . .
F8 P2 F12 91.5(5) . .
F8 P2 F7 177.6(5) . .
F12 P2 F7 90.9(5) . .
F8 P2 F11 90.8(4) . .
F12 P2 F11 177.5(5) . .
F7 P2 F11 86.7(4) . .
F8 P2 F9 90.5(4) . .
F12 P2 F9 90.4(3) . .
F7 P2 F9 89.7(3) . .
F11 P2 F9 89.0(3) . .
F8 P2 F10 91.8(3) . .
F12 P2 F10 88.1(3) . .
F7 P2 F10 88.1(3) . .
F11 P2 F10 92.5(3) . .
F9 P2 F10 177.3(3) . .
F18 P3 F16 95.1(5) . .
F18 P3 F17 178.1(3) . .
F16 P3 F17 86.0(4) . .
F18 P3 F15 91.4(4) . .
F16 P3 F15 173.4(4) . .
F17 P3 F15 87.4(4) . .
F18 P3 F13 91.1(3) . .
F16 P3 F13 89.7(3) . .
F17 P3 F13 90.5(3) . .
F15 P3 F13 89.9(3) . .
F18 P3 F14 89.3(3) . .
F16 P3 F14 92.2(3) . .
F17 P3 F14 89.1(3) . .
F15 P3 F14 88.1(3) . .
F13 P3 F14 178.0(3) . .
F21 P4 F21 87.8(4) . 2
F21 P4 F20 179.2(4) . 2
F21 P4 F20 91.4(3) 2 2
F21 P4 F20 91.4(3) . .
F21 P4 F20 179.2(4) 2 .
F20 P4 F20 89.5(5) 2 .
F21 P4 F19 91.5(3) . 2
F21 P4 F19 88.8(3) 2 2
F20 P4 F19 88.6(3) 2 2
F20 P4 F19 91.1(3) . 2
F21 P4 F19 88.8(3) . .
F21 P4 F19 91.5(3) 2 .
F20 P4 F19 91.1(3) 2 .
F20 P4 F19 88.6(3) . .
F19 P4 F19 179.6(4) 2 .
F24 P4' F24 82.4(12) 2_656 .
F24 P4' F23 176.3(7) 2_656 .
F24 P4' F23 96.6(7) . .
F24 P4' F23 96.6(7) 2_656 2_656
F24 P4' F23 176.3(7) . 2_656
F23 P4' F23 84.7(10) . 2_656
F24 P4' F22 90.3(6) 2_656 .
F24 P4' F22 93.9(6) . .
F23 P4' F22 86.2(5) . .
F23 P4' F22 89.7(5) 2_656 .
F24 P4' F22 93.9(6) 2_656 2_656
F24 P4' F22 90.3(6) . 2_656
F23 P4' F22 89.7(5) . 2_656
F23 P4' F22 86.2(5) 2_656 2_656
F22 P4' F22 174.4(7) . 2_656
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Cu1 C1 1.925(6) .
Cu1 N1 1.963(6) .
Cu1 N2 2.014(6) .
Cu1 Cu2 2.7159(10) .
Cu2 C36 1.910(5) .
Cu2 N13 2.040(4) .
Cu2 N14 2.158(4) .
Cu2 Cu3 2.6371(11) .
Cu3 C18 1.905(5) .
Cu3 N7 2.027(4) .
Cu3 N8 2.174(4) .
Cu3 Cu4 2.8989(12) .
Cu4 C19 1.915(6) .
Cu4 N3 1.951(6) .
Cu4 N4 2.032(7) .
C1 N11 1.342(7) .
C1 N12 1.369(6) .
C2 C3 1.318(8) .
C2 N11 1.381(7) .
C3 N12 1.389(7) .
C4 N13 1.333(6) .
C4 C5 1.394(7) .
C4 N12 1.420(7) .
C5 C6 1.357(8) .
C6 C7 1.399(8) .
C7 C15 1.404(7) .
C7 C8 1.433(8) .
C8 C9 1.346(8) .
C9 C10 1.426(7) .
C10 C11 1.397(7) .
C10 C14 1.400(7) .
C11 C12 1.365(7) .
C12 C13 1.392(7) .
C13 N14 1.326(6) .
C13 N15 1.413(6) .
C14 N14 1.358(6) .
C14 C15 1.441(7) .
C15 N13 1.359(6) .
C16 C17 1.325(8) .
C16 N15 1.386(6) .
C17 N16 1.380(7) .
C18 N16 1.342(6) .
C18 N15 1.381(6) .
C19 N6 1.346(6) .
C19 N5 1.353(7) .
C20 C21 1.325(8) .
C20 N5 1.373(7) .
C21 N6 1.391(7) .
C22 N7 1.326(6) .
C22 C23 1.392(7) .
C22 N6 1.424(7) .
C23 C24 1.350(8) .
C24 C25 1.389(8) .
C25 C33 1.415(7) .
C25 C26 1.426(9) .
C26 C27 1.329(9) .
C27 C28 1.422(8) .
C28 C29 1.385(8) .
C28 C32 1.406(7) .
C29 C30 1.367(8) .
C30 C31 1.396(7) .
C31 N8 1.321(6) .
C31 N9 1.421(6) .
C32 N8 1.370(6) .
C32 C33 1.420(7) .
C33 N7 1.357(6) .
C34 C35 1.321(8) .
C34 N9 1.388(6) .
C35 N10 1.377(7) .
C36 N10 1.350(6) .
C36 N9 1.375(6) .
C37 N1 1.114(8) .
C37 C38 1.469(10) .
C39 N2 1.122(8) .
C39 C40 1.470(11) .
C41 N4 1.120(8) .
C41 C42 1.458(10) .
C43 N3 1.108(9) .
C43 C44 1.478(11) .
C45 C46 1.196(9) .
C46 C47 1.477(9) .
C47 N11 1.475(7) .
C48 C49 1.450(10) .
C48 N16 1.458(7) .
C49 C50 1.164(10) .
C51 N10 1.454(7) .
C51 C52 1.476(9) .
C52 C53 1.202(9) .
C54 N5 1.462(7) .
C54 C55 1.481(8) .
C55 C56 1.285(9) .
F1 P1 1.554(5) .
F2 P1 1.555(5) .
F3 P1 1.525(5) .
F4 P1 1.542(5) .
F5 P1 1.565(5) .
F6 P1 1.549(5) .
F7 P2 1.543(5) .
F8 P2 1.517(6) .
F9 P2 1.571(5) .
F10 P2 1.572(4) .
F11 P2 1.565(5) .
F12 P2 1.533(6) .
F13 P3 1.571(4) .
F14 P3 1.578(4) .
F15 P3 1.571(6) .
F16 P3 1.554(6) .
F17 P3 1.564(5) .
F18 P3 1.533(6) .
F19 P4 1.580(4) .
F20 P4 1.566(5) .
F21 P4 1.563(5) .
F22 P4' 1.497(6) .
F23 P4' 1.484(8) .
F24 P4' 1.416(8) .
P4 F21 1.563(5) 2
P4 F20 1.566(5) 2
P4 F19 1.580(4) 2
P4' F24 1.416(8) 2_656
P4' F23 1.484(8) 2_656
P4' F22 1.497(6) 2_656
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C1 Cu1 Cu2 C36 115.9(2)
N1 Cu1 Cu2 C36 -16.4(3)
N2 Cu1 Cu2 C36 -120.8(2)
C1 Cu1 Cu2 N13 -55.4(2)
N1 Cu1 Cu2 N13 172.3(2)
N2 Cu1 Cu2 N13 67.8(2)
C1 Cu1 Cu2 N14 -122.2(2)
N1 Cu1 Cu2 N14 105.5(3)
N2 Cu1 Cu2 N14 1.0(2)
C1 Cu1 Cu2 Cu3 53.22(17)
N1 Cu1 Cu2 Cu3 -79.0(2)
N2 Cu1 Cu2 Cu3 176.48(18)
C36 Cu2 Cu3 C18 63.2(2)
N13 Cu2 Cu3 C18 -135.39(19)
N14 Cu2 Cu3 C18 -61.48(19)
Cu1 Cu2 Cu3 C18 121.47(16)
C36 Cu2 Cu3 N7 -134.5(2)
N13 Cu2 Cu3 N7 26.94(17)
N14 Cu2 Cu3 N7 100.85(16)
Cu1 Cu2 Cu3 N7 -76.21(14)
C36 Cu2 Cu3 N8 -61.17(19)
N13 Cu2 Cu3 N8 100.27(16)
N14 Cu2 Cu3 N8 174.18(15)
Cu1 Cu2 Cu3 N8 -2.87(12)
C36 Cu2 Cu3 Cu4 131.80(16)
N13 Cu2 Cu3 Cu4 -66.77(13)
N14 Cu2 Cu3 Cu4 7.14(12)
Cu1 Cu2 Cu3 Cu4 -169.91(5)
C18 Cu3 Cu4 C19 113.2(2)
N7 Cu3 Cu4 C19 -58.8(2)
N8 Cu3 Cu4 C19 -118.6(2)
Cu2 Cu3 Cu4 C19 41.58(18)
C18 Cu3 Cu4 N3 -22.3(3)
N7 Cu3 Cu4 N3 165.7(3)
N8 Cu3 Cu4 N3 105.8(3)
Cu2 Cu3 Cu4 N3 -94.0(2)
C18 Cu3 Cu4 N4 -117.6(2)
N7 Cu3 Cu4 N4 70.4(2)
N8 Cu3 Cu4 N4 10.6(3)
Cu2 Cu3 Cu4 N4 170.78(19)
N1 Cu1 C1 N11 -0.8(6)
N2 Cu1 C1 N11 152.3(5)
Cu2 Cu1 C1 N11 -130.5(5)
N1 Cu1 C1 N12 -178.5(4)
N2 Cu1 C1 N12 -25.4(6)
Cu2 Cu1 C1 N12 51.9(4)
N11 C2 C3 N12 -0.4(7)
N13 C4 C5 C6 -0.1(9)
N12 C4 C5 C6 -178.2(6)
C4 C5 C6 C7 -0.6(10)
C5 C6 C7 C15 -0.5(9)
C5 C6 C7 C8 -179.4(6)
C6 C7 C8 C9 177.0(6)
C15 C7 C8 C9 -1.8(9)
C7 C8 C9 C10 -0.2(9)
C8 C9 C10 C11 -176.8(6)
C8 C9 C10 C14 1.3(8)
C14 C10 C11 C12 -1.9(8)
C9 C10 C11 C12 176.2(5)
C10 C11 C12 C13 1.2(8)
C11 C12 C13 N14 1.8(8)
C11 C12 C13 N15 -176.6(5)
C11 C10 C14 N14 -0.3(7)
C9 C10 C14 N14 -178.4(5)
C11 C10 C14 C15 177.8(5)
C9 C10 C14 C15 -0.3(7)
C6 C7 C15 N13 2.5(8)
C8 C7 C15 N13 -178.6(5)
C6 C7 C15 C14 -176.2(5)
C8 C7 C15 C14 2.7(8)
N14 C14 C15 N13 -2.3(7)
C10 C14 C15 N13 179.5(5)
N14 C14 C15 C7 176.6(5)
C10 C14 C15 C7 -1.7(7)
N15 C16 C17 N16 -0.3(6)
N7 Cu3 C18 N16 118.4(6)
N8 Cu3 C18 N16 -48.0(5)
Cu2 Cu3 C18 N16 -116.6(5)
Cu4 Cu3 C18 N16 96.0(5)
N7 Cu3 C18 N15 -71.2(7)
N8 Cu3 C18 N15 122.5(4)
Cu2 Cu3 C18 N15 53.8(4)
Cu4 Cu3 C18 N15 -93.6(4)
N3 Cu4 C19 N6 -177.2(5)
N4 Cu4 C19 N6 -17.3(6)
Cu3 Cu4 C19 N6 52.5(4)
N3 Cu4 C19 N5 -0.1(7)
N4 Cu4 C19 N5 159.9(4)
Cu3 Cu4 C19 N5 -130.4(5)
N5 C20 C21 N6 0.1(6)
N7 C22 C23 C24 -0.3(9)
N6 C22 C23 C24 -178.2(5)
C22 C23 C24 C25 -3.0(9)
C23 C24 C25 C33 2.2(9)
C23 C24 C25 C26 -176.6(6)
C24 C25 C26 C27 177.4(6)
C33 C25 C26 C27 -1.4(9)
C25 C26 C27 C28 -0.4(10)
C26 C27 C28 C29 -177.7(6)
C26 C27 C28 C32 1.3(9)
C32 C28 C29 C30 -1.4(8)
C27 C28 C29 C30 177.6(5)
C28 C29 C30 C31 1.3(8)
C29 C30 C31 N8 1.0(8)
C29 C30 C31 N9 -177.9(5)
C29 C28 C32 N8 -0.7(8)
C27 C28 C32 N8 -179.8(5)
C29 C28 C32 C33 178.5(5)
C27 C28 C32 C33 -0.5(8)
C24 C25 C33 N7 1.8(8)
C26 C25 C33 N7 -179.3(5)
C24 C25 C33 C32 -176.8(5)
C26 C25 C33 C32 2.1(8)
N8 C32 C33 N7 -0.6(7)
C28 C32 C33 N7 -179.9(5)
N8 C32 C33 C25 178.1(4)
C28 C32 C33 C25 -1.2(8)
N9 C34 C35 N10 -0.1(6)
N13 Cu2 C36 N10 117.0(6)
N14 Cu2 C36 N10 -47.0(5)
Cu3 Cu2 C36 N10 -116.6(5)
Cu1 Cu2 C36 N10 93.9(5)
N13 Cu2 C36 N9 -71.1(6)
N14 Cu2 C36 N9 124.8(4)
Cu3 Cu2 C36 N9 55.3(4)
Cu1 Cu2 C36 N9 -94.2(4)
C45 C46 C47 N11 -139.0(11)
N16 C48 C49 C50 -96.6(19)
N10 C51 C52 C53 -97.9(11)
N5 C54 C55 C56 -118.4(7)
C38 C37 N1 Cu1 -16(68)
C1 Cu1 N1 C37 -114(14)
N2 Cu1 N1 C37 90(14)
Cu2 Cu1 N1 C37 -3(14)
C40 C39 N2 Cu1 30(47)
C1 Cu1 N2 C39 10(4)
N1 Cu1 N2 C39 168(4)
Cu2 Cu1 N2 C39 -67(4)
C44 C43 N3 Cu4 74(100)
C19 Cu4 N3 C43 88(9)
N4 Cu4 N3 C43 -75(9)
Cu3 Cu4 N3 C43 -159(9)
C42 C41 N4 Cu4 -3(37)
C19 Cu4 N4 C41 6(9)
N3 Cu4 N4 C41 171(9)
Cu3 Cu4 N4 C41 -65(9)
N6 C19 N5 C20 1.6(6)
Cu4 C19 N5 C20 -176.0(4)
N6 C19 N5 C54 172.6(5)
Cu4 C19 N5 C54 -5.0(8)
C21 C20 N5 C19 -1.1(6)
C21 C20 N5 C54 -172.3(5)
C55 C54 N5 C19 -93.7(7)
C55 C54 N5 C20 76.3(7)
N5 C19 N6 C21 -1.5(6)
Cu4 C19 N6 C21 176.2(4)
N5 C19 N6 C22 -173.0(4)
Cu4 C19 N6 C22 4.8(7)
C20 C21 N6 C19 1.0(6)
C20 C21 N6 C22 172.3(5)
N7 C22 N6 C19 -61.8(7)
C23 C22 N6 C19 116.3(6)
N7 C22 N6 C21 127.8(5)
C23 C22 N6 C21 -54.1(7)
C23 C22 N7 C33 4.1(8)
N6 C22 N7 C33 -178.0(4)
C23 C22 N7 Cu3 -162.3(4)
N6 C22 N7 Cu3 15.7(7)
C25 C33 N7 C22 -4.8(7)
C32 C33 N7 C22 173.8(5)
C25 C33 N7 Cu3 163.7(4)
C32 C33 N7 Cu3 -17.7(6)
C18 Cu3 N7 C22 18.5(8)
N8 Cu3 N7 C22 -173.3(5)
Cu2 Cu3 N7 C22 -104.4(4)
Cu4 Cu3 N7 C22 40.6(4)
C18 Cu3 N7 C33 -148.2(5)
N8 Cu3 N7 C33 20.1(3)
Cu2 Cu3 N7 C33 88.9(3)
Cu4 Cu3 N7 C33 -126.0(3)
C30 C31 N8 C32 -2.9(7)
N9 C31 N8 C32 176.0(4)
C30 C31 N8 Cu3 159.8(4)
N9 C31 N8 Cu3 -21.3(6)
C28 C32 N8 C31 2.7(7)
C33 C32 N8 C31 -176.5(4)
C28 C32 N8 Cu3 -164.0(4)
C33 C32 N8 Cu3 16.8(5)
C18 Cu3 N8 C31 -8.5(5)
N7 Cu3 N8 C31 176.5(5)
Cu2 Cu3 N8 C31 69.0(4)
Cu4 Cu3 N8 C31 -122.7(4)
C18 Cu3 N8 C32 155.2(3)
N7 Cu3 N8 C32 -19.8(3)
Cu2 Cu3 N8 C32 -127.3(3)
Cu4 Cu3 N8 C32 41.0(4)
N10 C36 N9 C34 -0.5(5)
Cu2 C36 N9 C34 -174.3(4)
N10 C36 N9 C31 176.2(4)
Cu2 C36 N9 C31 2.4(6)
C35 C34 N9 C36 0.4(6)
C35 C34 N9 C31 -176.2(5)
N8 C31 N9 C36 -34.4(6)
C30 C31 N9 C36 144.5(5)
N8 C31 N9 C34 141.7(5)
C30 C31 N9 C34 -39.3(7)
N9 C36 N10 C35 0.4(5)
Cu2 C36 N10 C35 173.6(4)
N9 C36 N10 C51 -178.5(4)
Cu2 C36 N10 C51 -5.3(7)
C34 C35 N10 C36 -0.2(6)
C34 C35 N10 C51 178.7(5)
C52 C51 N10 C36 -116.9(6)
C52 C51 N10 C35 64.4(8)
N12 C1 N11 C2 -0.1(6)
Cu1 C1 N11 C2 -178.2(4)
N12 C1 N11 C47 177.1(5)
Cu1 C1 N11 C47 -1.0(8)
C3 C2 N11 C1 0.3(7)
C3 C2 N11 C47 -176.8(6)
C46 C47 N11 C1 -92.3(7)
C46 C47 N11 C2 84.5(8)
N11 C1 N12 C3 -0.1(6)
Cu1 C1 N12 C3 178.0(4)
N11 C1 N12 C4 -176.9(5)
Cu1 C1 N12 C4 1.2(7)
C2 C3 N12 C1 0.4(7)
C2 C3 N12 C4 177.2(5)
N13 C4 N12 C1 -50.6(7)
C5 C4 N12 C1 127.6(6)
N13 C4 N12 C3 133.0(5)
C5 C4 N12 C3 -48.8(8)
C5 C4 N13 C15 1.9(8)
N12 C4 N13 C15 -180.0(4)
C5 C4 N13 Cu2 -167.6(4)
N12 C4 N13 Cu2 10.5(7)
C7 C15 N13 C4 -3.2(7)
C14 C15 N13 C4 175.6(4)
C7 C15 N13 Cu2 168.0(4)
C14 C15 N13 Cu2 -13.2(5)
C36 Cu2 N13 C4 19.6(7)
N14 Cu2 N13 C4 -174.0(5)
Cu3 Cu2 N13 C4 -104.4(4)
Cu1 Cu2 N13 C4 41.7(4)
C36 Cu2 N13 C15 -150.2(5)
N14 Cu2 N13 C15 16.2(3)
Cu3 Cu2 N13 C15 85.8(3)
Cu1 Cu2 N13 C15 -128.1(3)
C12 C13 N14 C14 -3.8(7)
N15 C13 N14 C14 174.6(4)
C12 C13 N14 Cu2 162.9(4)
N15 C13 N14 Cu2 -18.7(6)
C10 C14 N14 C13 3.0(7)
C15 C14 N14 C13 -175.1(4)
C10 C14 N14 Cu2 -166.5(4)
C15 C14 N14 Cu2 15.4(5)
C36 Cu2 N14 C13 -10.7(5)
N13 Cu2 N14 C13 175.5(4)
Cu3 Cu2 N14 C13 67.2(4)
Cu1 Cu2 N14 C13 -115.5(4)
C36 Cu2 N14 C14 156.8(3)
N13 Cu2 N14 C14 -17.0(3)
Cu3 Cu2 N14 C14 -125.3(3)
Cu1 Cu2 N14 C14 52.0(4)
N16 C18 N15 C16 -0.5(5)
Cu3 C18 N15 C16 -173.2(4)
N16 C18 N15 C13 177.4(4)
Cu3 C18 N15 C13 4.6(6)
C17 C16 N15 C18 0.5(6)
C17 C16 N15 C13 -177.3(5)
N14 C13 N15 C18 -37.2(6)
C12 C13 N15 C18 141.3(5)
N14 C13 N15 C16 140.3(5)
C12 C13 N15 C16 -41.2(7)
N15 C18 N16 C17 0.3(5)
Cu3 C18 N16 C17 172.2(4)
N15 C18 N16 C48 -178.7(4)
Cu3 C18 N16 C48 -6.8(8)
C16 C17 N16 C18 0.0(6)
C16 C17 N16 C48 179.0(5)
C49 C48 N16 C18 -118.7(7)
C49 C48 N16 C17 62.4(8)
