#------------------------------------------------------------------------------
#$Date: 2015-06-05 05:59:40 +0300 (Fri, 05 Jun 2015) $
#$Revision: 138151 $
#$URL: svn://www.crystallography.net/cod/cif/4/34/28/4342856.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4342856
loop_
_publ_author_name
'Morrison, Gregory'
'Ramanantoanina, Harry'
'Urland, Werner'
'Smith, Mark D.'
'Zur Loye, Hans-Conrad'
_publ_section_title
;
 Flux Synthesis, Structure, Properties, and Theoretical Magnetic Study of
 Uranium(IV)-Containing A2USi6O15 (A = K, Rb) with an Intriguing
 Green-to-Purple, Crystal-to-Crystal Structural Transition in the K
 Analogue.
;
_journal_issue                   11
_journal_name_full               'Inorganic chemistry'
_journal_page_first              5504
_journal_page_last               5511
_journal_paper_doi               10.1021/acs.inorgchem.5b00556
_journal_volume                  54
_journal_year                    2015
_chemical_formula_moiety         'K2 O15 Si6 U'
_chemical_formula_sum            'K2 O15 Si6 U'
_chemical_formula_weight         724.77
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_audit_creation_method           SHELXL-2014/6
_cell_angle_alpha                99.514(2)
_cell_angle_beta                 91.002(2)
_cell_angle_gamma                106.116(2)
_cell_formula_units_Z            4
_cell_length_a                   7.2196(5)
_cell_length_b                   12.0518(8)
_cell_length_c                   17.1967(12)
_cell_measurement_reflns_used    9676
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      37.454
_cell_measurement_theta_min      2.325
_cell_volume                     1414.52(17)
_computing_cell_refinement       'SAINT-Plus Version 6.45 (Bruker, 2001)'
_computing_data_collection       'SMART Version 5.631 (Bruker, 2001)'
_computing_data_reduction        'SAINT-Plus Version 6.45 (Bruker, 2001)'
_computing_molecular_graphics    various
_computing_publication_material  various
_computing_structure_refinement  'SHELXL-2014/6 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.929
_diffrn_measurement_device_type  'Bruker SMART APEX CCD diffractometer'
_diffrn_measurement_method       'omega and phi scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0350
_diffrn_reflns_av_unetI/netI     0.0370
_diffrn_reflns_laue_measured_fraction_full 1.000
_diffrn_reflns_laue_measured_fraction_max 0.929
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            43979
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.929
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         35.033
_diffrn_reflns_theta_min         1.203
_diffrn_source                   'sealed tube'
_exptl_absorpt_coefficient_mu    12.654
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.6532
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS Version 2.05 (Bruker, 2001)'
_exptl_crystal_colour            'light purple'
_exptl_crystal_density_diffrn    3.403
_exptl_crystal_description       irregular
_exptl_crystal_F_000             1336
_exptl_crystal_size_max          0.120
_exptl_crystal_size_mid          0.100
_exptl_crystal_size_min          0.080
_refine_diff_density_max         2.894
_refine_diff_density_min         -1.233
_refine_diff_density_rms         0.247
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.047
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     433
_refine_ls_number_reflns         11604
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.047
_refine_ls_R_factor_all          0.0351
_refine_ls_R_factor_gt           0.0294
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0267P)²+2.8824P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0604
_refine_ls_wR_factor_ref         0.0624
_reflns_number_gt                10408
_reflns_number_total             11604
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ic5b00556_si_004.cif
_cod_data_source_block           kusiolts
_cod_depositor_comments
'Adding full bibliography for 4342855--4342857.cif.'
_cod_database_code               4342856
_shelx_space_group_comment
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;
_shelx_estimated_absorpt_t_min   0.312
_shelx_estimated_absorpt_t_max   0.431
_shelxl_version_number           2014/6
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
U1 U 0.10689(2) 0.22522(2) 0.86405(2) 0.00546(3) Uani 1 1 d
U2 U 0.12330(2) 0.26080(2) 0.39049(2) 0.00536(3) Uani 1 1 d
K1 K 0.29833(11) 0.62371(7) 0.51851(4) 0.01249(13) Uani 1 1 d
K2 K 0.35663(11) 0.67577(6) 0.03772(4) 0.01001(12) Uani 1 1 d
K3 K 0.38397(12) 0.79487(7) 0.24957(5) 0.01791(16) Uani 1 1 d
K4 K 0.60529(12) 0.24057(7) 0.26015(5) 0.01854(16) Uani 1 1 d
Si1 Si 0.03070(13) 0.49356(8) 0.30717(5) 0.00582(15) Uani 1 1 d
Si2 Si 0.05588(13) 0.10377(8) 0.65840(5) 0.00588(15) Uani 1 1 d
Si3 Si 0.06896(13) 0.51217(8) 0.86554(5) 0.00605(15) Uani 1 1 d
Si4 Si 0.07706(13) 0.16098(8) 0.17234(5) 0.00578(15) Uani 1 1 d
Si5 Si 0.16096(13) 0.33393(8) 0.59641(5) 0.00581(15) Uani 1 1 d
Si6 Si 0.19117(13) 0.35941(8) 0.06808(5) 0.00590(15) Uani 1 1 d
Si7 Si 0.26624(13) 0.97804(8) 0.07748(5) 0.00631(15) Uani 1 1 d
Si8 Si 0.30531(13) 0.05941(8) 0.43563(5) 0.00575(15) Uani 1 1 d
Si9 Si 0.44922(13) 0.51052(8) 0.33207(5) 0.00615(15) Uani 1 1 d
Si10 Si 0.55068(13) 0.51967(8) 0.16515(5) 0.00593(15) Uani 1 1 d
Si11 Si 0.68479(13) 0.02842(8) 0.39945(5) 0.00577(15) Uani 1 1 d
Si12 Si 0.69323(13) 0.01074(8) 0.10567(5) 0.00615(15) Uani 1 1 d
O1 O 0.0150(3) 0.8503(2) 0.25850(14) 0.0087(4) Uani 1 1 d
O2 O 0.0300(3) 0.6107(2) 0.64399(14) 0.0085(4) Uani 1 1 d
O3 O 0.0304(3) 0.6245(2) 0.13965(14) 0.0081(4) Uani 1 1 d
O4 O 0.0344(4) 0.5606(2) 0.78540(14) 0.0095(4) Uani 1 1 d
O5 O 0.0679(3) 0.4029(2) 0.66679(14) 0.0090(4) Uani 1 1 d
O6 O 0.0764(3) 0.1952(2) 0.59774(14) 0.0085(4) Uani 1 1 d
O7 O 0.0957(3) 0.01923(19) 0.38609(13) 0.0061(4) Uani 1 1 d
O8 O 0.1083(3) 0.3610(2) 0.51224(14) 0.0086(4) Uani 1 1 d
O9 O 0.1275(3) 0.0439(2) 0.12785(14) 0.0084(4) Uani 1 1 d
O10 O 0.1513(3) 0.1951(2) 0.26313(14) 0.0094(4) Uani 1 1 d
O11 O 0.1759(4) 0.2659(2) 0.12605(14) 0.0100(4) Uani 1 1 d
O12 O 0.1849(3) 0.8431(2) 0.08498(15) 0.0100(4) Uani 1 1 d
O13 O 0.2609(3) 0.0718(2) 0.66565(13) 0.0076(4) Uani 1 1 d
O14 O 0.2631(3) 0.5591(2) 0.31677(15) 0.0098(4) Uani 1 1 d
O15 O 0.2871(3) 0.0006(2) 0.51350(14) 0.0089(4) Uani 1 1 d
O16 O 0.3031(3) 0.1079(2) 0.86565(14) 0.0091(4) Uani 1 1 d
O17 O 0.3517(3) 0.4805(2) 0.10994(14) 0.0076(4) Uani 1 1 d
O18 O 0.3598(3) 0.1988(2) 0.44811(14) 0.0084(4) Uani 1 1 d
O19 O 0.3935(3) 0.3749(2) 0.61906(14) 0.0085(4) Uani 1 1 d
O20 O 0.3995(3) 0.4051(2) 0.38020(14) 0.0088(4) Uani 1 1 d
O21 O 0.4531(3) 0.0063(2) 0.37964(14) 0.0076(4) Uani 1 1 d
O22 O 0.4850(3) 0.0384(2) 0.11763(14) 0.0089(4) Uani 1 1 d
O23 O 0.5213(3) 0.4657(2) 0.24649(13) 0.0082(4) Uani 1 1 d
O24 O 0.6274(3) 0.6594(2) 0.18169(14) 0.0083(4) Uani 1 1 d
O25 O 0.6968(3) 0.4558(2) 0.11605(14) 0.0076(4) Uani 1 1 d
O26 O 0.7369(4) 0.0029(2) 0.01336(14) 0.0108(5) Uani 1 1 d
O27 O 0.7515(3) 0.6873(2) 0.01735(14) 0.0091(4) Uani 1 1 d
O28 O 0.8061(3) 0.1580(2) 0.39214(14) 0.0089(4) Uani 1 1 d
O29 O 0.8413(3) 0.1280(2) 0.15912(14) 0.0082(4) Uani 1 1 d
O30 O 0.9943(3) 0.4008(2) 0.06321(14) 0.0086(4) Uani 1 1 d
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
U U -9.6767 9.6646 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 U1 O27 174.99(9) 2_566 2_666
O1 U1 O16 95.04(9) 2_566 .
O27 U1 O16 85.18(9) 2_666 .
O1 U1 O24 90.55(9) 2_566 2_666
O27 U1 O24 84.53(9) 2_666 2_666
O16 U1 O24 81.46(8) . 2_666
O1 U1 O12 92.22(9) 2_566 2_566
O27 U1 O12 92.26(9) 2_666 2_566
O16 U1 O12 114.07(8) . 2_566
O24 U1 O12 163.89(9) 2_666 2_566
O1 U1 O3 88.51(9) 2_566 2_566
O27 U1 O3 90.25(9) 2_666 2_566
O16 U1 O3 167.42(9) . 2_566
O24 U1 O3 86.45(8) 2_666 2_566
O12 U1 O3 77.76(8) 2_566 2_566
O1 U1 Si7 86.81(6) 2_566 2_566
O27 U1 Si7 98.19(6) 2_666 2_566
O16 U1 Si7 91.46(6) . 2_566
O24 U1 Si7 172.21(6) 2_666 2_566
O12 U1 Si7 23.82(6) 2_566 2_566
O3 U1 Si7 100.79(6) 2_566 2_566
O1 U1 K3 46.93(6) 2_566 2_566
O27 U1 K3 134.81(6) 2_666 2_566
O16 U1 K3 136.05(6) . 2_566
O24 U1 K3 114.14(6) 2_666 2_566
O12 U1 K3 58.19(6) 2_566 2_566
O3 U1 K3 53.05(6) 2_566 2_566
Si7 U1 K3 68.97(2) 2_566 2_566
O1 U1 K2 132.48(6) 2_566 2_666
O27 U1 K2 44.26(6) 2_666 2_666
O16 U1 K2 54.41(6) . 2_666
O24 U1 K2 53.36(6) 2_666 2_666
O12 U1 K2 131.46(6) 2_566 2_666
O3 U1 K2 114.96(6) 2_566 2_666
Si7 U1 K2 124.457(19) 2_566 2_666
K3 U1 K2 165.535(17) 2_566 2_666
O1 U1 K2 100.55(6) 2_566 2_566
O27 U1 K2 81.81(6) 2_666 2_566
O16 U1 K2 146.24(6) . 2_566
O24 U1 K2 127.70(6) 2_666 2_566
O12 U1 K2 36.23(6) 2_566 2_566
O3 U1 K2 43.64(6) 2_566 2_566
Si7 U1 K2 60.050(19) 2_566 2_566
K3 U1 K2 53.831(16) 2_566 2_566
K2 U1 K2 125.310(19) 2_666 2_566
O1 U1 K3 79.57(6) 2_566 2_666
O27 U1 K3 97.09(6) 2_666 2_666
O16 U1 K3 46.38(6) . 2_666
O24 U1 K3 38.94(6) 2_666 2_666
O12 U1 K3 156.95(6) 2_566 2_666
O3 U1 K3 123.03(6) 2_566 2_666
Si7 U1 K3 133.28(2) 2_566 2_666
K3 U1 K3 123.75(2) 2_566 2_666
K2 U1 K3 52.920(16) 2_666 2_666
K2 U1 K3 166.394(16) 2_566 2_666
O10 U2 O8 169.11(8) . .
O10 U2 O2 90.45(9) . 2_566
O8 U2 O2 81.22(8) . 2_566
O10 U2 O28 95.74(9) . 1_455
O8 U2 O28 89.45(9) . 1_455
O2 U2 O28 78.36(8) 2_566 1_455
O10 U2 O20 85.09(9) . .
O8 U2 O20 87.14(9) . .
O2 U2 O20 84.48(8) 2_566 .
O28 U2 O20 162.81(9) 1_455 .
O10 U2 O18 99.96(9) . .
O8 U2 O18 85.68(8) . .
O2 U2 O18 157.85(8) 2_566 .
O28 U2 O18 119.47(8) 1_455 .
O20 U2 O18 77.07(8) . .
O10 U2 O7 76.57(8) . .
O8 U2 O7 114.23(7) . .
O2 U2 O7 144.89(8) 2_566 .
O28 U2 O7 70.85(7) 1_455 .
O20 U2 O7 125.71(8) . .
O18 U2 O7 57.20(7) . .
O10 U2 Si8 88.55(6) . .
O8 U2 Si8 100.37(6) . .
O2 U2 Si8 174.87(6) 2_566 .
O28 U2 Si8 96.74(6) 1_455 .
O20 U2 Si8 100.45(6) . .
O18 U2 Si8 27.09(6) . .
O7 U2 Si8 30.10(5) . .
O10 U2 K1 127.16(6) . 2_566
O8 U2 K1 50.31(6) . 2_566
O2 U2 K1 47.43(6) 2_566 2_566
O28 U2 K1 52.16(6) 1_455 2_566
O20 U2 K1 114.32(6) . 2_566
O18 U2 K1 131.36(6) . 2_566
O7 U2 K1 117.50(5) . 2_566
Si8 U2 K1 130.291(19) . 2_566
O10 U2 K1 102.19(6) . 2_666
O8 U2 K1 76.56(6) . 2_666
O2 U2 K1 121.11(6) 2_566 2_666
O28 U2 K1 152.96(6) 1_455 2_666
O20 U2 K1 41.11(6) . 2_666
O18 U2 K1 37.65(6) . 2_666
O7 U2 K1 93.69(5) . 2_666
Si8 U2 K1 64.016(19) . 2_666
K1 U2 K1 125.18(2) 2_566 2_666
O10 U2 K4 47.65(6) . .
O8 U2 K4 130.17(6) . .
O2 U2 K4 114.11(6) 2_566 .
O28 U2 K4 138.76(6) 1_455 .
O20 U2 K4 50.75(6) . .
O18 U2 K4 62.43(6) . .
O7 U2 K4 80.90(5) . .
Si8 U2 K4 68.63(2) . .
K1 U2 K4 160.632(16) 2_566 .
K1 U2 K4 54.541(16) 2_666 .
O10 U2 K4 71.48(6) . 1_455
O8 U2 K4 106.16(6) . 1_455
O2 U2 K4 43.06(6) 2_566 1_455
O28 U2 K4 45.45(6) 1_455 1_455
O20 U2 K4 119.87(6) . 1_455
O18 U2 K4 159.09(6) . 1_455
O7 U2 K4 101.92(5) . 1_455
Si8 U2 K4 132.01(2) . 1_455
K1 U2 K4 56.045(16) 2_566 1_455
K1 U2 K4 160.975(16) 2_666 1_455
K4 U2 K4 117.01(2) . 1_455
O18 K1 O20 60.78(7) 2_666 2_666
O18 K1 O2 115.30(7) 2_666 .
O20 K1 O2 92.43(7) 2_666 .
O18 K1 O8 129.41(7) 2_666 2_566
O20 K1 O8 151.87(7) 2_666 2_566
O2 K1 O8 59.46(7) . 2_566
O18 K1 O8 144.47(7) 2_666 .
O20 K1 O8 85.75(7) 2_666 .
O2 K1 O8 74.88(7) . .
O8 K1 O8 85.70(7) 2_566 .
O18 K1 O28 73.44(7) 2_666 2_666
O20 K1 O28 104.49(7) 2_666 2_666
O2 K1 O28 57.10(6) . 2_666
O8 K1 O28 62.71(6) 2_566 2_666
O8 K1 O28 130.92(7) . 2_666
O18 K1 O19 65.46(7) 2_666 2_666
O20 K1 O19 85.08(7) 2_666 2_666
O2 K1 O19 176.57(7) . 2_666
O8 K1 O19 122.95(6) 2_566 2_666
O8 K1 O19 102.54(6) . 2_666
O28 K1 O19 125.82(6) 2_666 2_666
O18 K1 O14 103.17(7) 2_666 .
O20 K1 O14 125.25(7) 2_666 .
O2 K1 O14 136.38(7) . .
O8 K1 O14 80.71(6) 2_566 .
O8 K1 O14 85.87(6) . .
O28 K1 O14 121.18(6) 2_666 .
O19 K1 O14 44.80(6) 2_666 .
O18 K1 Si9 92.27(6) 2_666 .
O20 K1 Si9 98.34(5) 2_666 .
O2 K1 Si9 152.18(6) . .
O8 K1 Si9 106.56(5) 2_566 .
O8 K1 Si9 80.39(5) . .
O28 K1 Si9 141.82(5) 2_666 .
O19 K1 Si9 26.81(4) 2_666 .
O14 K1 Si9 26.99(4) . .
O18 K1 Si5 127.03(6) 2_666 .
O20 K1 Si5 66.26(5) 2_666 .
O2 K1 Si5 64.55(5) . .
O8 K1 Si5 97.54(5) 2_566 .
O8 K1 Si5 23.65(5) . .
O28 K1 Si5 120.52(5) 2_666 .
O19 K1 Si5 112.20(5) 2_666 .
O14 K1 Si5 107.91(5) . .
Si9 K1 Si5 96.54(3) . .
O18 K1 K4 66.77(5) 2_666 2_666
O20 K1 K4 56.07(5) 2_666 2_666
O2 K1 K4 50.65(5) . 2_666
O8 K1 K4 100.97(5) 2_566 2_666
O8 K1 K4 105.69(5) . 2_666
O28 K1 K4 51.72(5) 2_666 2_666
O19 K1 K4 128.92(5) 2_666 2_666
O14 K1 K4 168.38(5) . 2_666
Si9 K1 K4 152.21(3) . 2_666
Si5 K1 K4 83.36(2) . 2_666
O18 K1 Si9 81.20(5) 2_666 2_666
O20 K1 Si9 20.80(5) 2_666 2_666
O2 K1 Si9 79.24(5) . 2_666
O8 K1 Si9 135.49(5) 2_566 2_666
O8 K1 Si9 66.92(5) . 2_666
O28 K1 Si9 109.52(5) 2_666 2_666
O19 K1 Si9 97.71(5) 2_666 2_666
O14 K1 Si9 128.34(5) . 2_666
Si9 K1 Si9 102.71(3) . 2_666
Si5 K1 Si9 45.89(2) . 2_666
K4 K1 Si9 57.81(2) 2_666 2_666
O12 K2 O25 123.60(8) . 2_665
O12 K2 O17 127.01(7) . .
O25 K2 O17 93.62(7) 2_665 .
O12 K2 O27 131.45(8) . .
O25 K2 O27 83.01(7) 2_665 .
O17 K2 O27 84.50(7) . .
O12 K2 O30 77.47(7) . 2_665
O25 K2 O30 53.38(7) 2_665 2_665
O17 K2 O30 104.13(7) . 2_665
O27 K2 O30 135.59(7) . 2_665
O12 K2 O3 61.39(7) . .
O25 K2 O3 116.96(7) 2_665 .
O17 K2 O3 68.69(7) . .
O27 K2 O3 146.67(7) . .
O30 K2 O3 72.51(7) 2_665 .
O12 K2 O24 108.75(7) . .
O25 K2 O24 127.64(7) 2_665 .
O17 K2 O24 50.82(6) . .
O27 K2 O24 59.75(6) . .
O30 K2 O24 153.25(7) 2_665 .
O3 K2 O24 87.46(6) . .
O12 K2 O16 75.38(7) . 2_666
O25 K2 O16 134.91(7) 2_665 2_666
O17 K2 O16 105.67(7) . 2_666
O27 K2 O16 59.51(7) . 2_666
O30 K2 O16 147.96(7) 2_665 2_666
O3 K2 O16 108.02(7) . 2_666
O24 K2 O16 54.86(6) . 2_666
O12 K2 Si3 102.85(6) . 1_554
O25 K2 Si3 26.87(5) 2_665 1_554
O17 K2 Si3 95.97(5) . 1_554
O27 K2 Si3 109.88(5) . 1_554
O30 K2 Si3 27.05(5) 2_665 1_554
O3 K2 Si3 92.82(5) . 1_554
O24 K2 Si3 143.93(5) . 1_554
O16 K2 Si3 154.12(5) 2_666 1_554
O12 K2 Si10 125.72(6) . .
O25 K2 Si10 107.83(5) 2_665 .
O17 K2 Si10 25.63(5) . .
O27 K2 Si10 66.24(5) . .
O30 K2 Si10 129.74(5) 2_665 .
O3 K2 Si10 81.73(5) . .
O24 K2 Si10 26.20(4) . .
O16 K2 Si10 80.71(5) 2_666 .
Si3 K2 Si10 118.30(3) 1_554 .
O12 K2 K3 61.61(6) . .
O25 K2 K3 169.30(5) 2_665 .
O17 K2 K3 76.62(5) . .
O27 K2 K3 100.14(5) . .
O30 K2 K3 124.27(5) 2_665 .
O3 K2 K3 55.64(5) . .
O24 K2 K3 48.57(5) . .
O16 K2 K3 53.66(4) 2_666 .
Si3 K2 K3 148.31(3) 1_554 .
Si10 K2 K3 64.88(2) . .
O12 K2 Si6 126.70(6) . .
O25 K2 Si6 75.82(5) 2_665 .
O17 K2 Si6 23.27(5) . .
O27 K2 Si6 97.04(5) . .
O30 K2 Si6 81.46(5) 2_665 .
O3 K2 Si6 65.69(5) . .
O24 K2 Si6 74.07(4) . .
O16 K2 Si6 128.93(5) 2_666 .
Si3 K2 Si6 73.30(2) 1_554 .
Si10 K2 Si6 48.45(2) . .
K3 K2 Si6 93.61(3) . .
O13 K3 O24 81.01(7) 2_666 .
O13 K3 O1 126.65(7) 2_666 .
O24 K3 O1 152.14(7) . .
O13 K3 O21 52.08(7) 2_666 1_565
O24 K3 O21 132.97(7) . 1_565
O1 K3 O21 74.88(7) . 1_565
O13 K3 O16 68.87(7) 2_666 2_666
O24 K3 O16 58.98(6) . 2_666
O1 K3 O16 123.03(7) . 2_666
O21 K3 O16 100.62(7) 1_565 2_666
O13 K3 O14 105.27(7) 2_666 .
O24 K3 O14 74.14(7) . .
O1 K3 O14 98.35(7) . .
O21 K3 O14 111.56(7) 1_565 .
O16 K3 O14 133.11(7) 2_666 .
O13 K3 O3 170.81(7) 2_666 .
O24 K3 O3 89.88(7) . .
O1 K3 O3 62.38(7) . .
O21 K3 O3 137.08(7) 1_565 .
O16 K3 O3 105.40(7) 2_666 .
O14 K3 O3 73.05(6) . .
O13 K3 O12 127.96(7) 2_666 .
O24 K3 O12 100.21(7) . .
O1 K3 O12 61.72(6) . .
O21 K3 O12 110.62(6) 1_565 .
O16 K3 O12 68.02(6) 2_666 .
O14 K3 O12 125.33(6) . .
O3 K3 O12 52.38(6) . .
O13 K3 Si11 25.71(5) 2_666 1_565
O24 K3 Si11 106.59(5) . 1_565
O1 K3 Si11 101.21(5) . 1_565
O21 K3 Si11 26.39(5) 1_565 1_565
O16 K3 Si11 84.88(5) 2_666 1_565
O14 K3 Si11 109.60(5) . 1_565
O3 K3 Si11 163.47(5) . 1_565
O12 K3 Si11 123.54(5) . 1_565
O13 K3 K2 122.02(5) 2_666 .
O24 K3 K2 56.98(5) . .
O1 K3 K2 99.39(5) . .
O21 K3 K2 148.66(5) 1_565 .
O16 K3 K2 56.08(5) 2_666 .
O14 K3 K2 99.73(5) . .
O3 K3 K2 50.53(5) . .
O12 K3 K2 44.44(4) . .
Si11 K3 K2 140.93(3) 1_565 .
O13 K3 Si10 96.81(5) 2_666 .
O24 K3 Si10 20.71(5) . .
O1 K3 Si10 135.60(6) . .
O21 K3 Si10 145.27(5) 1_565 .
O16 K3 Si10 77.32(5) 2_666 .
O14 K3 Si10 56.72(5) . .
O3 K3 Si10 74.62(5) . .
O12 K3 Si10 100.79(5) . .
Si11 K3 Si10 120.92(3) 1_565 .
K2 K3 Si10 56.82(2) . .
O13 K3 U1 151.04(5) 2_666 2_566
O24 K3 U1 119.97(5) . 2_566
O1 K3 U1 33.62(5) . 2_566
O21 K3 U1 105.32(5) 1_565 2_566
O16 K3 U1 103.35(5) 2_666 2_566
O14 K3 U1 100.02(5) . 2_566
O3 K3 U1 35.70(4) . 2_566
O12 K3 U1 35.33(4) . 2_566
Si11 K3 U1 130.04(3) 1_565 2_566
K2 K3 U1 65.949(18) . 2_566
Si10 K3 U1 108.89(2) . 2_566
O29 K4 O23 126.22(7) . .
O29 K4 O2 88.36(7) . 2_666
O23 K4 O2 86.46(7) . 2_666
O29 K4 O22 50.15(7) . .
O23 K4 O22 117.85(7) . .
O2 K4 O22 138.44(7) 2_666 .
O29 K4 O28 83.03(7) . .
O23 K4 O28 133.57(7) . .
O2 K4 O28 56.13(6) 2_666 .
O22 K4 O28 108.57(7) . .
O29 K4 O10 132.09(7) . .
O23 K4 O10 72.76(7) . .
O2 K4 O10 139.39(7) 2_666 .
O22 K4 O10 81.95(7) . .
O28 K4 O10 116.68(7) . .
O29 K4 O4 71.17(7) . 2_666
O23 K4 O4 65.39(6) . 2_666
O2 K4 O4 49.20(6) 2_666 2_666
O22 K4 O4 108.16(7) . 2_666
O28 K4 O4 100.06(6) . 2_666
O10 K4 O4 136.82(7) . 2_666
O29 K4 O20 170.74(7) . .
O23 K4 O20 49.11(6) . .
O2 K4 O20 83.45(7) 2_666 .
O22 K4 O20 138.10(7) . .
O28 K4 O20 95.88(6) . .
O10 K4 O20 56.48(6) . .
O4 K4 O20 100.07(6) 2_666 .
O29 K4 Si1 87.10(5) . 1_655
O23 K4 Si1 67.29(5) . 1_655
O2 K4 Si1 25.49(5) 2_666 1_655
O22 K4 Si1 132.38(5) . 1_655
O28 K4 Si1 81.26(5) . 1_655
O10 K4 Si1 136.35(5) . 1_655
O4 K4 Si1 26.47(4) 2_666 1_655
O20 K4 Si1 83.65(5) . 1_655
O29 K4 Si12 25.08(5) . .
O23 K4 Si12 130.37(5) . .
O2 K4 Si12 112.70(5) 2_666 .
O22 K4 Si12 25.86(5) . .
O28 K4 Si12 92.09(5) . .
O10 K4 Si12 107.28(5) . .
O4 K4 Si12 92.42(5) 2_666 .
O20 K4 Si12 163.75(5) . .
Si1 K4 Si12 111.62(3) 1_655 .
O29 K4 Si9 148.79(6) . .
O23 K4 Si9 24.66(5) . .
O2 K4 Si9 80.83(5) 2_666 .
O22 K4 Si9 134.92(5) . .
O28 K4 Si9 113.63(5) . .
O10 K4 Si9 65.66(5) . .
O4 K4 Si9 79.74(5) 2_666 .
O20 K4 Si9 24.95(4) . .
Si1 K4 Si9 70.70(3) 1_655 .
Si12 K4 Si9 153.99(3) . .
O29 K4 K1 128.39(6) . 2_666
O23 K4 K1 83.65(5) . 2_666
O2 K4 K1 48.40(5) 2_666 2_666
O22 K4 K1 155.16(5) . 2_666
O28 K4 K1 51.64(5) . 2_666
O10 K4 K1 93.94(5) . 2_666
O4 K4 K1 91.64(5) 2_666 2_666
O20 K4 K1 47.07(4) . 2_666
Si1 K4 K1 65.32(2) 1_655 2_666
Si12 K4 K1 143.61(3) . 2_666
Si9 K4 K1 62.00(2) . 2_666
O2 Si1 O5 114.05(13) 2_566 2_566
O2 Si1 O4 108.00(13) 2_566 2_566
O5 Si1 O4 107.80(13) 2_566 2_566
O2 Si1 O14 112.75(13) 2_566 .
O5 Si1 O14 104.61(13) 2_566 .
O4 Si1 O14 109.47(13) 2_566 .
O2 Si1 K4 54.71(9) 2_566 1_455
O5 Si1 K4 100.94(10) 2_566 1_455
O4 Si1 K4 61.95(9) 2_566 1_455
O14 Si1 K4 154.45(10) . 1_455
O1 Si2 O6 112.88(13) 2_566 .
O1 Si2 O7 111.53(13) 2_566 2_556
O6 Si2 O7 106.15(13) . 2_556
O1 Si2 O13 113.31(13) 2_566 .
O6 Si2 O13 108.35(13) . .
O7 Si2 O13 104.01(12) 2_556 .
O3 Si3 O4 113.78(13) 2_566 .
O3 Si3 O30 116.16(13) 2_566 2_666
O4 Si3 O30 105.30(13) . 2_666
O3 Si3 O25 110.87(13) 2_566 2_666
O4 Si3 O25 107.06(13) . 2_666
O30 Si3 O25 102.72(13) 2_666 2_666
O3 Si3 K2 119.62(9) 2_566 1_556
O4 Si3 K2 126.50(10) . 1_556
O30 Si3 K2 53.30(9) 2_666 1_556
O25 Si3 K2 50.79(9) 2_666 1_556
O3 Si3 K2 44.65(9) 2_566 2_566
O4 Si3 K2 121.23(10) . 2_566
O30 Si3 K2 72.26(9) 2_666 2_566
O25 Si3 K2 131.23(9) 2_666 2_566
K2 Si3 K2 99.55(3) 1_556 2_566
O10 Si4 O11 110.44(14) . .
O10 Si4 O9 112.67(13) . .
O11 Si4 O9 107.20(13) . .
O10 Si4 O29 112.81(13) . 1_455
O11 Si4 O29 109.58(13) . 1_455
O9 Si4 O29 103.81(13) . 1_455
O10 Si4 K4 52.55(9) . .
O11 Si4 K4 80.34(10) . .
O9 Si4 K4 82.80(9) . .
O29 Si4 K4 165.23(9) 1_455 .
O8 Si5 O5 111.65(13) . .
O8 Si5 O6 110.00(13) . .
O5 Si5 O6 107.32(13) . .
O8 Si5 O19 112.51(13) . .
O5 Si5 O19 105.92(13) . .
O6 Si5 O19 109.22(13) . .
O8 Si5 K1 50.32(9) . .
O5 Si5 K1 85.49(9) . .
O6 Si5 K1 160.16(9) . .
O19 Si5 K1 80.60(9) . .
O27 Si6 O11 111.94(13) 2_665 .
O27 Si6 O17 111.22(13) 2_665 .
O11 Si6 O17 107.09(13) . .
O27 Si6 O30 111.40(13) 2_665 1_455
O11 Si6 O30 112.13(13) . 1_455
O17 Si6 O30 102.60(13) . 1_455
O27 Si6 K2 92.15(9) 2_665 .
O11 Si6 K2 148.66(10) . .
O17 Si6 K2 43.11(8) . .
O30 Si6 K2 74.39(9) 1_455 .
O27 Si6 K2 40.66(9) 2_665 2_665
O11 Si6 K2 99.45(10) . 2_665
O17 Si6 K2 79.46(9) . 2_665
O30 Si6 K2 145.71(9) 1_455 2_665
K2 Si6 K2 85.70(2) . 2_665
O12 Si7 O26 112.19(14) . 2_665
O12 Si7 O9 105.40(13) . 1_565
O26 Si7 O9 110.87(13) 2_665 1_565
O12 Si7 O22 112.97(13) . 1_565
O26 Si7 O22 108.56(13) 2_665 1_565
O9 Si7 O22 106.70(13) 1_565 1_565
O12 Si7 U1 35.33(9) . 2_566
O26 Si7 U1 118.99(10) 2_665 2_566
O9 Si7 U1 70.75(9) 1_565 2_566
O22 Si7 U1 130.06(9) 1_565 2_566
O12 Si7 K2 34.51(9) . .
O26 Si7 K2 96.90(10) 2_665 .
O9 Si7 K2 139.26(9) 1_565 .
O22 Si7 K2 91.06(9) 1_565 .
U1 Si7 K2 69.83(2) 2_566 .
O18 Si8 O15 117.28(13) . .
O18 Si8 O7 102.63(12) . .
O15 Si8 O7 109.44(13) . .
O18 Si8 O21 112.45(13) . .
O15 Si8 O21 107.42(13) . .
O7 Si8 O21 107.11(13) . .
O18 Si8 U2 41.44(9) . .
O15 Si8 U2 129.96(10) . .
O7 Si8 U2 61.19(8) . .
O21 Si8 U2 122.48(9) . .
O20 Si9 O19 111.70(13) . 2_666
O20 Si9 O23 108.95(13) . .
O19 Si9 O23 112.05(13) 2_666 .
O20 Si9 O14 112.80(13) . .
O19 Si9 O14 103.16(13) 2_666 .
O23 Si9 O14 108.06(13) . .
O20 Si9 K1 73.84(9) . .
O19 Si9 K1 65.96(9) 2_666 .
O23 Si9 K1 177.16(9) . .
O14 Si9 K1 70.89(9) . .
O20 Si9 K4 60.58(9) . .
O19 Si9 K4 118.66(9) 2_666 .
O23 Si9 K4 49.90(9) . .
O14 Si9 K4 137.32(10) . .
K1 Si9 K4 132.65(3) . .
O20 Si9 K1 40.32(9) . 2_666
O19 Si9 K1 77.55(9) 2_666 2_666
O23 Si9 K1 104.45(9) . 2_666
O14 Si9 K1 144.21(9) . 2_666
K1 Si9 K1 77.29(3) . 2_666
K4 Si9 K1 60.20(2) . 2_666
O24 Si10 O17 108.41(13) . .
O24 Si10 O23 112.31(13) . .
O17 Si10 O23 111.45(13) . .
O24 Si10 O25 113.75(13) . .
O17 Si10 O25 105.53(13) . .
O23 Si10 O25 105.21(13) . .
O24 Si10 K2 62.19(9) . .
O17 Si10 K2 49.16(8) . .
O23 Si10 K2 144.29(10) . .
O25 Si10 K2 108.97(9) . .
O24 Si10 K3 39.30(9) . .
O17 Si10 K3 84.56(9) . .
O23 Si10 K3 94.23(9) . .
O25 Si10 K3 152.47(9) . .
K2 Si10 K3 58.31(2) . .
O28 Si11 O15 112.32(13) . 2_656
O28 Si11 O21 111.67(13) . .
O15 Si11 O21 107.89(13) 2_656 .
O28 Si11 O13 112.44(13) . 2_656
O15 Si11 O13 108.46(13) 2_656 2_656
O21 Si11 O13 103.58(12) . 2_656
O28 Si11 K3 129.71(10) . 1_545
O15 Si11 K3 117.90(10) 2_656 1_545
O21 Si11 K3 54.96(9) . 1_545
O13 Si11 K3 48.70(8) 2_656 1_545
O28 Si11 K4 48.62(9) . .
O15 Si11 K4 151.07(10) 2_656 .
O21 Si11 K4 69.95(8) . .
O13 Si11 K4 99.85(9) 2_656 .
K3 Si11 K4 85.29(3) 1_545 .
O16 Si12 O26 110.05(13) 2_656 .
O16 Si12 O22 112.03(13) 2_656 .
O26 Si12 O22 108.81(13) . .
O16 Si12 O29 113.31(13) 2_656 .
O26 Si12 O29 110.82(13) . .
O22 Si12 O29 101.50(13) . .
O16 Si12 K4 115.38(10) 2_656 .
O26 Si12 K4 134.54(10) . .
O22 Si12 K4 55.11(9) . .
O29 Si12 K4 48.47(9) . .
Si2 O1 U1 138.74(14) 2_566 2_566
Si2 O1 K3 120.41(12) 2_566 .
U1 O1 K3 99.45(8) 2_566 .
Si1 O2 U2 133.13(14) 2_566 2_566
Si1 O2 K1 125.21(12) 2_566 .
U2 O2 K1 97.42(8) 2_566 .
Si1 O2 K4 99.80(11) 2_566 2_666
U2 O2 K4 105.88(8) 2_566 2_666
K1 O2 K4 80.95(6) . 2_666
Si3 O3 U1 129.97(14) 2_566 2_566
Si3 O3 K2 113.08(12) 2_566 .
U1 O3 K2 103.75(8) 2_566 .
Si3 O3 K3 130.16(12) 2_566 .
U1 O3 K3 91.25(7) 2_566 .
K2 O3 K3 73.83(6) . .
Si3 O4 Si1 137.56(16) . 2_566
Si3 O4 K4 115.55(12) . 2_666
Si1 O4 K4 91.58(10) 2_566 2_666
Si1 O5 Si5 146.37(16) 2_566 .
Si5 O6 Si2 140.01(16) . .
Si8 O7 Si2 136.92(15) . 2_556
Si8 O7 U2 88.70(9) . .
Si2 O7 U2 133.93(12) 2_556 .
Si5 O8 U2 129.05(13) . .
Si5 O8 K1 117.27(12) . 2_566
U2 O8 K1 94.78(8) . 2_566
Si5 O8 K1 106.03(11) . .
U2 O8 K1 110.01(8) . .
K1 O8 K1 94.30(7) 2_566 .
Si7 O9 Si4 152.37(16) 1_545 .
Si4 O10 U2 153.20(15) . .
Si4 O10 K4 103.99(11) . .
U2 O10 K4 100.96(8) . .
Si6 O11 Si4 158.40(18) . .
Si7 O12 U1 120.85(13) . 2_566
Si7 O12 K2 125.71(13) . .
U1 O12 K2 113.41(9) 2_566 .
Si7 O12 K3 109.84(12) . .
U1 O12 K3 86.48(7) 2_566 .
K2 O12 K3 73.95(6) . .
Si2 O13 Si11 122.01(15) . 2_656
Si2 O13 K3 129.93(12) . 2_666
Si11 O13 K3 105.59(11) 2_656 2_666
Si1 O14 Si9 131.61(16) . .
Si1 O14 K3 114.15(11) . .
Si9 O14 K3 111.87(11) . .
Si1 O14 K1 96.37(10) . .
Si9 O14 K1 82.12(9) . .
K3 O14 K1 108.95(7) . .
Si8 O15 Si11 164.91(18) . 2_656
Si12 O16 U1 139.71(14) 2_656 .
Si12 O16 K3 117.21(12) 2_656 2_666
U1 O16 K3 102.13(8) . 2_666
Si12 O16 K2 109.60(12) 2_656 2_666
U1 O16 K2 90.87(7) . 2_666
K3 O16 K2 70.26(5) 2_666 2_666
Si10 O17 Si6 138.51(16) . .
Si10 O17 K2 105.21(11) . .
Si6 O17 K2 113.62(11) . .
Si8 O18 U2 111.47(12) . .
Si8 O18 K1 134.08(13) . 2_666
U2 O18 K1 111.55(9) . 2_666
Si9 O19 Si5 136.84(16) 2_666 .
Si9 O19 K1 87.23(10) 2_666 2_666
Si5 O19 K1 121.01(11) . 2_666
Si9 O20 U2 133.45(14) . .
Si9 O20 K1 118.88(12) . 2_666
U2 O20 K1 107.67(8) . 2_666
Si9 O20 K4 94.46(10) . .
U2 O20 K4 96.66(8) . .
K1 O20 K4 76.86(6) 2_666 .
Si8 O21 Si11 126.67(15) . .
Si8 O21 K3 131.97(12) . 1_545
Si11 O21 K3 98.65(10) . 1_545
Si7 O22 Si12 134.88(16) 1_545 .
Si7 O22 K4 125.87(12) 1_545 .
Si12 O22 K4 99.03(11) . .
Si9 O23 Si10 132.91(16) . .
Si9 O23 K4 105.44(11) . .
Si10 O23 K4 121.65(12) . .
Si10 O24 U1 127.81(13) . 2_666
Si10 O24 K3 119.98(12) . .
U1 O24 K3 111.04(9) 2_666 .
Si10 O24 K2 91.61(10) . .
U1 O24 K2 91.80(7) 2_666 .
K3 O24 K2 74.45(6) . .
Si10 O25 Si3 126.07(15) . 2_666
Si10 O25 K2 129.25(12) . 2_665
Si3 O25 K2 102.33(11) 2_666 2_665
Si12 O26 Si7 161.22(18) . 2_665
Si6 O27 U1 139.17(14) 2_665 2_666
Si6 O27 K2 118.01(12) 2_665 .
U1 O27 K2 102.73(9) 2_666 .
Si11 O28 U2 137.69(14) . 1_655
Si11 O28 K1 121.40(12) . 2_666
U2 O28 K1 92.33(8) 1_655 2_666
Si11 O28 K4 108.80(12) . .
U2 O28 K4 102.99(8) 1_655 .
K1 O28 K4 76.65(6) 2_666 .
Si12 O29 Si4 128.16(15) . 1_655
Si12 O29 K4 106.44(11) . .
Si4 O29 K4 123.67(12) 1_655 .
Si3 O30 Si6 123.85(15) 2_666 1_655
Si3 O30 K2 99.64(11) 2_666 2_665
Si6 O30 K2 135.37(13) 1_655 2_665
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
U1 O1 2.214(2) 2_566
U1 O27 2.221(2) 2_666
U1 O16 2.265(2) .
U1 O24 2.273(2) 2_666
U1 O12 2.286(2) 2_566
U1 O3 2.302(2) 2_566
U1 Si7 3.3932(9) 2_566
U1 K3 3.9446(9) 2_566
U1 K2 3.9772(8) 2_666
U1 K2 4.1502(8) 2_566
U1 K3 4.2400(9) 2_666
U2 O10 2.235(2) .
U2 O8 2.258(2) .
U2 O2 2.282(2) 2_566
U2 O28 2.285(2) 1_455
U2 O20 2.285(2) .
U2 O18 2.313(2) .
U2 O7 2.851(2) .
U2 Si8 3.2524(9) .
U2 K1 3.9307(8) 2_566
U2 K1 4.2008(8) 2_666
U2 K4 4.2137(9) .
U2 K4 4.2532(9) 1_455
K1 O18 2.759(2) 2_666
K1 O20 2.899(3) 2_666
K1 O2 2.919(2) .
K1 O8 3.035(3) 2_566
K1 O8 3.065(2) .
K1 O28 3.107(3) 2_666
K1 O19 3.275(2) 2_666
K1 O14 3.416(3) .
K1 Si9 3.5817(12) .
K1 Si5 3.8269(11) .
K1 K4 3.8555(12) 2_666
K1 Si9 3.9229(12) 2_666
K2 O12 2.673(3) .
K2 O25 2.810(2) 2_665
K2 O17 2.829(2) .
K2 O27 2.846(3) .
K2 O30 2.881(2) 2_665
K2 O3 2.949(2) .
K2 O24 3.193(2) .
K2 O16 3.235(3) 2_666
K2 Si3 3.5425(12) 1_554
K2 Si10 3.6087(11) .
K2 K3 3.6689(11) .
K2 Si6 3.7931(11) .
K3 O13 2.844(2) 2_666
K3 O24 2.855(3) .
K3 O1 2.921(3) .
K3 O21 3.020(2) 1_565
K3 O16 3.140(2) 2_666
K3 O14 3.149(3) .
K3 O3 3.153(3) .
K3 O12 3.359(3) .
K3 Si11 3.6462(12) 1_565
K3 Si10 3.9041(12) .
K3 U1 3.9446(9) 2_566
K4 O29 2.893(2) .
K4 O23 2.984(3) .
K4 O2 3.019(3) 2_666
K4 O22 3.078(3) .
K4 O28 3.110(3) .
K4 O10 3.172(3) .
K4 O4 3.218(3) 2_666
K4 O20 3.285(3) .
K4 Si1 3.6445(12) 1_655
K4 Si12 3.7062(12) .
K4 Si9 3.7600(12) .
K4 K1 3.8555(12) 2_666
Si1 O2 1.591(2) 2_566
Si1 O5 1.608(3) 2_566
Si1 O4 1.625(3) 2_566
Si1 O14 1.636(3) .
Si1 K4 3.6445(12) 1_455
Si2 O1 1.591(3) 2_566
Si2 O6 1.619(2) .
Si2 O7 1.636(2) 2_556
Si2 O13 1.637(3) .
Si3 O3 1.590(2) 2_566
Si3 O4 1.624(2) .
Si3 O30 1.634(3) 2_666
Si3 O25 1.639(3) 2_666
Si3 K2 3.5425(12) 1_556
Si3 K2 3.8599(11) 2_566
Si4 O10 1.591(2) .
Si4 O11 1.611(2) .
Si4 O9 1.626(2) .
Si4 O29 1.639(3) 1_455
Si5 O8 1.597(2) .
Si5 O5 1.616(3) .
Si5 O6 1.617(2) .
Si5 O19 1.633(3) .
Si6 O27 1.589(3) 2_665
Si6 O11 1.607(2) .
Si6 O17 1.635(2) .
Si6 O30 1.637(3) 1_455
Si6 K2 3.8561(12) 2_665
Si7 O12 1.596(2) .
Si7 O26 1.617(3) 2_665
Si7 O9 1.622(3) 1_565
Si7 O22 1.630(3) 1_565
Si7 U1 3.3932(9) 2_566
Si8 O18 1.592(2) .
Si8 O15 1.607(2) .
Si8 O7 1.632(2) .
Si8 O21 1.639(3) .
Si9 O20 1.591(2) .
Si9 O19 1.617(3) 2_666
Si9 O23 1.627(2) .
Si9 O14 1.641(3) .
Si9 K1 3.9229(12) 2_666
Si10 O24 1.594(2) .
Si10 O17 1.618(2) .
Si10 O23 1.631(2) .
Si10 O25 1.639(3) .
Si11 O28 1.591(2) .
Si11 O15 1.614(2) 2_656
Si11 O21 1.640(3) .
Si11 O13 1.642(3) 2_656
Si11 K3 3.6462(12) 1_545
Si12 O16 1.594(2) 2_656
Si12 O26 1.616(3) .
Si12 O22 1.637(3) .
Si12 O29 1.638(2) .
O1 Si2 1.591(3) 2_566
O1 U1 2.214(2) 2_566
O2 Si1 1.592(2) 2_566
O2 U2 2.282(2) 2_566
O2 K4 3.019(3) 2_666
O3 Si3 1.590(2) 2_566
O3 U1 2.302(2) 2_566
O4 Si1 1.625(3) 2_566
O4 K4 3.218(3) 2_666
O5 Si1 1.608(3) 2_566
O7 Si2 1.636(2) 2_556
O8 K1 3.035(3) 2_566
O9 Si7 1.622(3) 1_545
O12 U1 2.286(2) 2_566
O13 Si11 1.643(3) 2_656
O13 K3 2.844(2) 2_666
O15 Si11 1.614(2) 2_656
O16 Si12 1.594(2) 2_656
O16 K3 3.140(2) 2_666
O16 K2 3.235(3) 2_666
O18 K1 2.759(2) 2_666
O19 Si9 1.617(2) 2_666
O19 K1 3.275(2) 2_666
O20 K1 2.899(2) 2_666
O21 K3 3.020(2) 1_545
O22 Si7 1.630(3) 1_545
O24 U1 2.273(2) 2_666
O25 Si3 1.639(2) 2_666
O25 K2 2.810(2) 2_665
O26 Si7 1.617(3) 2_665
O27 Si6 1.589(3) 2_665
O27 U1 2.221(2) 2_666
O28 U2 2.285(2) 1_655
O28 K1 3.107(3) 2_666
O29 Si4 1.639(2) 1_655
O30 Si3 1.634(3) 2_666
O30 Si6 1.637(3) 1_655
O30 K2 2.881(2) 2_665
