#------------------------------------------------------------------------------
#$Date: 2021-08-30 09:29:47 +0300 (Mon, 30 Aug 2021) $
#$Revision: 268283 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/34/32/4343234.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4343234
loop_
_publ_author_name
'Li, Xiao-Lei'
'Min, Fan-Yong'
'Wang, Chao'
'Lin, Shuang-Yan'
'Liu, Zhiliang'
'Tang, Jinkui'
_publ_section_title
;
 Utilizing 3d-4f magnetic interaction to slow the magnetic relaxation of
 heterometallic complexes.
;
_journal_issue                   9
_journal_name_full               'Inorganic chemistry'
_journal_page_first              4337
_journal_page_last               4344
_journal_paper_doi               10.1021/acs.inorgchem.5b00019
_journal_volume                  54
_journal_year                    2015
_chemical_formula_sum            'C70 H52 Dy2 Ni O20'
_chemical_formula_weight         1596.80
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 109.248(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   14.812(2)
_cell_length_b                   10.9693(16)
_cell_length_c                   20.281(3)
_cell_measurement_reflns_used    5326
_cell_measurement_temperature    273(2)
_cell_measurement_theta_max      25.50
_cell_measurement_theta_min      2.50
_cell_volume                     3111.0(8)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      273(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0578
_diffrn_reflns_av_sigmaI/netI    0.0678
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            15490
_diffrn_reflns_theta_full        24.99
_diffrn_reflns_theta_max         24.34
_diffrn_reflns_theta_min         2.36
_exptl_absorpt_coefficient_mu    2.755
_exptl_absorpt_correction_T_max  0.9347
_exptl_absorpt_correction_T_min  0.5545
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   crystalclear
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.705
_exptl_crystal_density_meas      1.703
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1584
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.05
_refine_diff_density_max         0.948
_refine_diff_density_min         -0.651
_refine_diff_density_rms         0.220
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.014
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     422
_refine_ls_number_reflns         5461
_refine_ls_number_restraints     126
_refine_ls_restrained_S_all      1.028
_refine_ls_R_factor_all          0.0736
_refine_ls_R_factor_gt           0.0430
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0587P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0980
_refine_ls_wR_factor_ref         0.1171
_reflns_number_gt                3870
_reflns_number_total             4649
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic5b00019_si_002.cif
_cod_data_source_block           Dy2Ni
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'multi_scan' changed to
'multi-scan' according to
/usr/data/users/saulius/crontab/automatic-downloads/current/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 3271 2015-04-21 07:52:19Z andrius 

2021-08-30
Z value and formula fixed to values more according to usual
chemical conventions.                 miguel
;
_cod_original_formula_sum            'C140 H104 Dy4 Ni2 O40'
_cod_original_formula_weight         3193.61
_cod_original_formula_units_Z            1
_cod_original_sg_symbol_H-M      P21/c
_cod_database_code               4343234
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C -0.0151(5) 0.3259(6) 0.1141(3) 0.0330(16) Uani 1 1 d .
C2 C -0.0990(5) 0.2659(7) 0.0743(4) 0.0417(18) Uani 1 1 d .
H2 H -0.1175 0.2692 0.0258 0.050 Uiso 1 1 calc R
C3 C -0.1541(6) 0.2033(8) 0.1045(5) 0.058(2) Uani 1 1 d .
H3 H -0.2091 0.1645 0.0762 0.070 Uiso 1 1 calc R
C4 C -0.1305(6) 0.1957(8) 0.1758(5) 0.062(2) Uani 1 1 d .
H4 H -0.1678 0.1500 0.1957 0.075 Uiso 1 1 calc R
C5 C -0.0523(6) 0.2555(8) 0.2167(4) 0.061(2) Uani 1 1 d .
H5 H -0.0371 0.2527 0.2650 0.073 Uiso 1 1 calc R
C6 C 0.0064(5) 0.3220(7) 0.1875(4) 0.0423(18) Uani 1 1 d .
C7 C 0.0819(6) 0.3914(9) 0.2339(4) 0.058(2) Uani 1 1 d .
H7 H 0.0858 0.3897 0.2806 0.070 Uiso 1 1 calc R
C8 C 0.3648(5) 0.2757(7) 0.2251(4) 0.0448(19) Uani 1 1 d .
C9 C 0.4447(6) 0.2683(9) 0.2873(4) 0.059(2) Uani 1 1 d .
H9 H 0.4628 0.3371 0.3155 0.071 Uiso 1 1 calc R
C10 C 0.4953(7) 0.1638(10) 0.3069(5) 0.073(3) Uani 1 1 d .
H10 H 0.5466 0.1614 0.3485 0.088 Uiso 1 1 calc R
C11 C 0.4713(7) 0.0611(10) 0.2657(5) 0.079(3) Uani 1 1 d .
H11 H 0.5074 -0.0096 0.2789 0.095 Uiso 1 1 calc R
C12 C 0.3958(7) 0.0627(8) 0.2061(5) 0.067(3) Uani 1 1 d .
H12 H 0.3789 -0.0077 0.1794 0.080 Uiso 1 1 calc R
C13 C 0.3422(6) 0.1702(7) 0.1842(4) 0.047(2) Uani 1 1 d .
C14 C 0.2649(6) 0.1669(7) 0.1205(4) 0.053(2) Uani 1 1 d .
H14 H 0.2539 0.0927 0.0970 0.063 Uiso 1 1 calc R
C15 C 0.0760(5) 0.7348(6) 0.0916(3) 0.0334(16) Uani 1 1 d .
C16 C -0.0075(6) 0.8013(7) 0.0558(4) 0.0429(19) Uani 1 1 d .
H16 H -0.0568 0.7628 0.0212 0.051 Uiso 1 1 calc R
C17 C -0.0175(6) 0.9190(8) 0.0707(4) 0.056(2) Uani 1 1 d .
H17 H -0.0734 0.9600 0.0461 0.068 Uiso 1 1 calc R
C18 C 0.0537(7) 0.9805(7) 0.1218(5) 0.065(3) Uani 1 1 d .
H18 H 0.0462 1.0623 0.1308 0.078 Uiso 1 1 calc R
C19 C 0.1345(7) 0.9198(8) 0.1583(4) 0.060(2) Uani 1 1 d .
H19 H 0.1815 0.9605 0.1934 0.072 Uiso 1 1 calc R
C20 C 0.1488(6) 0.7976(6) 0.1446(4) 0.0412(18) Uani 1 1 d .
C21 C 0.2360(6) 0.7420(7) 0.1841(4) 0.052(2) Uani 1 1 d .
H21 H 0.2796 0.7928 0.2157 0.063 Uiso 1 1 calc R
C22 C 0.1749(5) 0.4444(6) -0.0499(4) 0.0367(17) Uani 1 1 d .
C23 C 0.1186(5) 0.4203(7) -0.1187(4) 0.0413(18) Uani 1 1 d .
H23 H 0.0529 0.4120 -0.1292 0.050 Uiso 1 1 calc R
C24 C 0.1568(7) 0.4086(8) -0.1710(4) 0.054(2) Uani 1 1 d .
H24 H 0.1165 0.3934 -0.2162 0.065 Uiso 1 1 calc R
C25 C 0.2543(7) 0.4188(8) -0.1586(4) 0.060(2) Uani 1 1 d .
H25 H 0.2798 0.4086 -0.1945 0.072 Uiso 1 1 calc R
C26 C 0.3113(6) 0.4440(8) -0.0929(5) 0.064(3) Uani 1 1 d .
H26 H 0.3767 0.4532 -0.0839 0.077 Uiso 1 1 calc R
C27 C 0.2736(6) 0.4567(7) -0.0368(4) 0.0459(19) Uani 1 1 d .
C28 C 0.3400(6) 0.4890(9) 0.0292(4) 0.064(3) Uani 1 1 d .
H28 H 0.4027 0.5017 0.0306 0.076 Uiso 1 1 calc R
C29 C 0.3215(10) 0.4361(15) 0.3901(8) 0.126(5) Uani 1 1 d U
H29 H 0.2890 0.3777 0.3577 0.151 Uiso 1 1 calc R
C30 C 0.3266(11) 0.4167(15) 0.4573(9) 0.138(5) Uani 1 1 d U
H30 H 0.3022 0.3465 0.4709 0.166 Uiso 1 1 calc R
C31 C 0.3731(13) 0.5139(18) 0.5076(10) 0.149(6) Uani 1 1 d U
H31 H 0.3784 0.5095 0.5546 0.179 Uiso 1 1 calc R
C32 C 0.4060(10) 0.6061(16) 0.4819(9) 0.123(5) Uani 1 1 d U
C33 C 0.4016(11) 0.6203(16) 0.4121(9) 0.129(5) Uani 1 1 d U
C34 C 0.3623(10) 0.5400(13) 0.3628(9) 0.120(5) Uani 1 1 d U
H34 H 0.3603 0.5477 0.3167 0.144 Uiso 1 1 calc R
O9 O 0.4505(15) 0.7067(18) 0.5199(9) 0.271(8) Uani 1 1 d U
H9A H 0.4505 0.7007 0.5602 0.407 Uiso 1 1 calc R
Dy Dy 0.19541(2) 0.45733(3) 0.122313(16) 0.03443(13) Uani 1 1 d U
Ni Ni 0.0000 0.5000 0.0000 0.0293(3) Uani 1 2 d SU
O1 O 0.0387(3) 0.3858(4) 0.0854(2) 0.0355(11) Uani 1 1 d U
O2 O 0.1424(4) 0.4529(5) 0.2204(3) 0.0590(16) Uani 1 1 d U
O3 O 0.3166(4) 0.3752(5) 0.2090(3) 0.0524(14) Uani 1 1 d U
O4 O 0.2101(4) 0.2516(5) 0.0923(3) 0.0564(15) Uani 1 1 d U
O5 O 0.0855(3) 0.6195(4) 0.0780(2) 0.0335(11) Uani 1 1 d U
O6 O 0.2625(4) 0.6361(5) 0.1826(3) 0.0544(15) Uani 1 1 d U
O7 O 0.1366(3) 0.4568(4) 0.0000(2) 0.0333(11) Uani 1 1 d U
O8 O 0.3249(4) 0.5020(6) 0.0839(3) 0.0650(17) Uani 1 1 d U
C35 C 0.4420(13) 0.7269(18) 0.3768(10) 0.170(7) Uani 1 1 d U
H35 H 0.4408 0.7382 0.3310 0.204 Uiso 1 1 calc R
O10 O 0.4789(12) 0.7959(15) 0.4348(9) 0.245(7) Uani 1 1 d U
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ni Ni 0.3393 1.1124 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 C1 C2 122.3(6) . .
O1 C1 C6 121.6(6) . .
C2 C1 C6 116.1(7) . .
C3 C2 C1 121.9(7) . .
C3 C2 H2 119.1 . .
C1 C2 H2 119.1 . .
C2 C3 C4 121.6(8) . .
C2 C3 H3 119.2 . .
C4 C3 H3 119.2 . .
C5 C4 C3 119.1(8) . .
C5 C4 H4 120.5 . .
C3 C4 H4 120.5 . .
C4 C5 C6 121.1(8) . .
C4 C5 H5 119.5 . .
C6 C5 H5 119.5 . .
C5 C6 C1 120.2(7) . .
C5 C6 C7 117.2(7) . .
C1 C6 C7 122.3(7) . .
O2 C7 C6 128.3(7) . .
O2 C7 H7 115.8 . .
C6 C7 H7 115.8 . .
O3 C8 C13 123.1(7) . .
O3 C8 C9 120.3(8) . .
C13 C8 C9 116.5(7) . .
C10 C9 C8 121.8(9) . .
C10 C9 H9 119.1 . .
C8 C9 H9 119.1 . .
C9 C10 C11 120.4(9) . .
C9 C10 H10 119.8 . .
C11 C10 H10 119.8 . .
C12 C11 C10 120.3(9) . .
C12 C11 H11 119.9 . .
C10 C11 H11 119.9 . .
C11 C12 C13 120.6(9) . .
C11 C12 H12 119.7 . .
C13 C12 H12 119.7 . .
C8 C13 C12 120.4(7) . .
C8 C13 C14 121.7(7) . .
C12 C13 C14 117.9(8) . .
O4 C14 C13 127.5(7) . .
O4 C14 H14 116.2 . .
C13 C14 H14 116.2 . .
O5 C15 C16 121.8(6) . .
O5 C15 C20 121.2(6) . .
C16 C15 C20 117.0(6) . .
C17 C16 C15 121.5(7) . .
C17 C16 H16 119.2 . .
C15 C16 H16 119.2 . .
C16 C17 C18 121.5(8) . .
C16 C17 H17 119.3 . .
C18 C17 H17 119.3 . .
C19 C18 C17 119.1(8) . .
C19 C18 H18 120.4 . .
C17 C18 H18 120.4 . .
C18 C19 C20 121.7(8) . .
C18 C19 H19 119.1 . .
C20 C19 H19 119.1 . .
C19 C20 C21 118.1(7) . .
C19 C20 C15 119.1(7) . .
C21 C20 C15 122.8(7) . .
O6 C21 C20 129.2(7) . .
O6 C21 H21 115.4 . .
C20 C21 H21 115.4 . .
O7 C22 C23 121.3(6) . .
O7 C22 C27 122.0(6) . .
C23 C22 C27 116.7(7) . .
C24 C23 C22 122.1(7) . .
C24 C23 H23 119.0 . .
C22 C23 H23 119.0 . .
C23 C24 C25 121.8(8) . .
C23 C24 H24 119.1 . .
C25 C24 H24 119.1 . .
C26 C25 C24 118.0(8) . .
C26 C25 H25 121.0 . .
C24 C25 H25 121.0 . .
C25 C26 C27 121.6(8) . .
C25 C26 H26 119.2 . .
C27 C26 H26 119.2 . .
C22 C27 C28 123.8(7) . .
C22 C27 C26 119.7(7) . .
C28 C27 C26 116.3(8) . .
O8 C28 C27 127.8(8) . .
O8 C28 H28 116.1 . .
C27 C28 H28 116.1 . .
C30 C29 C34 127.0(16) . .
C30 C29 H29 116.5 . .
C34 C29 H29 116.5 . .
C29 C30 C31 116.1(17) . .
C29 C30 H30 122.0 . .
C31 C30 H30 122.0 . .
C32 C31 C30 115.7(17) . .
C32 C31 H31 122.1 . .
C30 C31 H31 122.1 . .
C31 C32 O9 125(2) . .
C31 C32 C33 126.1(18) . .
O9 C32 C33 109.1(19) . .
C34 C33 C32 123.6(18) . .
C34 C33 C35 106.7(16) . .
C32 C33 C35 129.6(18) . .
C33 C34 C29 111.4(16) . .
C33 C34 H34 124.3 . .
C29 C34 H34 124.3 . .
C32 O9 H9A 109.5 . .
O3 Dy O1 124.85(18) . .
O3 Dy O7 138.61(18) . .
O1 Dy O7 71.04(15) . .
O3 Dy O8 79.3(2) . .
O1 Dy O8 143.19(17) . .
O7 Dy O8 73.04(17) . .
O3 Dy O6 80.58(18) . .
O1 Dy O6 130.85(18) . .
O7 Dy O6 119.89(17) . .
O8 Dy O6 75.3(2) . .
O3 Dy O4 72.58(17) . .
O1 Dy O4 76.25(17) . .
O7 Dy O4 76.07(16) . .
O8 Dy O4 87.7(2) . .
O6 Dy O4 150.52(18) . .
O3 Dy O2 74.6(2) . .
O1 Dy O2 72.04(17) . .
O7 Dy O2 141.16(18) . .
O8 Dy O2 144.8(2) . .
O6 Dy O2 77.3(2) . .
O4 Dy O2 106.3(2) . .
O3 Dy O5 150.09(17) . .
O1 Dy O5 69.20(15) . .
O7 Dy O5 68.42(15) . .
O8 Dy O5 104.50(19) . .
O6 Dy O5 72.04(16) . .
O4 Dy O5 136.54(15) . .
O2 Dy O5 87.57(18) . .
O3 Dy Ni 164.00(13) . .
O1 Dy Ni 40.57(10) . .
O7 Dy Ni 41.01(11) . .
O8 Dy Ni 110.17(14) . .
O6 Dy Ni 113.86(13) . .
O4 Dy Ni 94.45(12) . .
O2 Dy Ni 100.99(14) . .
O5 Dy Ni 42.10(10) . .
O1 Ni O1 180.0 3_565 .
O1 Ni O7 98.04(17) 3_565 .
O1 Ni O7 81.96(17) . .
O1 Ni O7 81.96(17) 3_565 3_565
O1 Ni O7 98.04(17) . 3_565
O7 Ni O7 180.0 . 3_565
O1 Ni O5 79.45(17) 3_565 3_565
O1 Ni O5 100.55(17) . 3_565
O7 Ni O5 101.58(17) . 3_565
O7 Ni O5 78.42(17) 3_565 3_565
O1 Ni O5 100.55(17) 3_565 .
O1 Ni O5 79.44(17) . .
O7 Ni O5 78.42(17) . .
O7 Ni O5 101.58(17) 3_565 .
O5 Ni O5 180.0 3_565 .
O1 Ni Dy 132.69(13) 3_565 .
O1 Ni Dy 47.31(13) . .
O7 Ni Dy 47.73(12) . .
O7 Ni Dy 132.27(12) 3_565 .
O5 Ni Dy 131.27(11) 3_565 .
O5 Ni Dy 48.73(11) . .
O1 Ni Dy 47.31(13) 3_565 3_565
O1 Ni Dy 132.69(13) . 3_565
O7 Ni Dy 132.27(12) . 3_565
O7 Ni Dy 47.73(12) 3_565 3_565
O5 Ni Dy 48.73(11) 3_565 3_565
O5 Ni Dy 131.27(11) . 3_565
Dy Ni Dy 180.0 . 3_565
C1 O1 Ni 129.6(4) . .
C1 O1 Dy 135.7(4) . .
Ni O1 Dy 92.12(17) . .
C7 O2 Dy 132.1(5) . .
C8 O3 Dy 140.7(5) . .
C14 O4 Dy 134.2(5) . .
C15 O5 Ni 132.3(4) . .
C15 O5 Dy 138.5(4) . .
Ni O5 Dy 89.17(15) . .
C21 O6 Dy 135.9(5) . .
C22 O7 Ni 133.5(4) . .
C22 O7 Dy 135.0(4) . .
Ni O7 Dy 91.26(17) . .
C28 O8 Dy 134.3(6) . .
O10 C35 C33 97.1(16) . .
O10 C35 H35 131.5 . .
C33 C35 H35 131.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 O1 1.307(8) .
C1 C2 1.403(9) .
C1 C6 1.416(9) .
C2 C3 1.357(10) .
C2 H2 0.9300 .
C3 C4 1.375(11) .
C3 H3 0.9300 .
C4 C5 1.351(12) .
C4 H4 0.9300 .
C5 C6 1.408(11) .
C5 H5 0.9300 .
C6 C7 1.423(11) .
C7 O2 1.223(10) .
C7 H7 0.9300 .
C8 O3 1.286(8) .
C8 C13 1.398(10) .
C8 C9 1.419(10) .
C9 C10 1.356(12) .
C9 H9 0.9300 .
C10 C11 1.379(13) .
C10 H10 0.9300 .
C11 C12 1.348(12) .
C11 H11 0.9300 .
C12 C13 1.409(11) .
C12 H12 0.9300 .
C13 C14 1.417(10) .
C14 O4 1.242(8) .
C14 H14 0.9300 .
C15 O5 1.311(8) .
C15 C16 1.413(9) .
C15 C20 1.425(9) .
C16 C17 1.344(10) .
C16 H16 0.9300 .
C17 C18 1.385(11) .
C17 H17 0.9300 .
C18 C19 1.356(12) .
C18 H18 0.9300 .
C19 C20 1.400(10) .
C19 H19 0.9300 .
C20 C21 1.414(10) .
C21 O6 1.229(9) .
C21 H21 0.9300 .
C22 O7 1.321(8) .
C22 C23 1.395(9) .
C22 C27 1.403(10) .
C23 C24 1.364(10) .
C23 H23 0.9300 .
C24 C25 1.386(11) .
C24 H24 0.9300 .
C25 C26 1.350(12) .
C25 H25 0.9300 .
C26 C27 1.430(11) .
C26 H26 0.9300 .
C27 C28 1.421(11) .
C28 O8 1.209(9) .
C28 H28 0.9300 .
C29 C30 1.357(18) .
C29 C34 1.480(19) .
C29 H29 0.9300 .
C30 C31 1.48(2) .
C30 H30 0.9300 .
C31 C32 1.30(2) .
C31 H31 0.9300 .
C32 O9 1.383(18) .
C32 C33 1.40(2) .
C33 C34 1.316(18) .
C33 C35 1.59(2) .
C34 H34 0.9300 .
O9 H9A 0.8200 .
Dy O3 2.245(5) .
Dy O1 2.328(5) .
Dy O7 2.343(4) .
Dy O8 2.348(6) .
Dy O6 2.351(5) .
Dy O4 2.366(5) .
Dy O2 2.367(5) .
Dy O5 2.379(4) .
Dy Ni 3.1648(4) .
Ni O1 2.060(4) 3_565
Ni O1 2.060(4) .
Ni O7 2.077(5) .
Ni O7 2.077(4) 3_565
Ni O5 2.122(4) 3_565
Ni O5 2.122(4) .
Ni Dy 3.1649(4) 3_565
C35 O10 1.35(2) .
C35 H35 0.9300 .
