#------------------------------------------------------------------------------
#$Date: 2015-08-05 21:43:43 +0300 (Wed, 05 Aug 2015) $
#$Revision: 152825 $
#$URL: svn://www.crystallography.net/cod/cif/4/34/34/4343452.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4343452
loop_
_publ_author_name
'Huang, Chun-Zuo'
'Liu, Biao'
'Wen, Lei'
'Zhuang, Rong-Chuan'
'Zhao, Jing-Tai'
'Pan, Yuanming'
'Mi, Jin-Xiao'
'Huang, Ya-Xi'
_publ_section_title
;
 Dimensional Reduction From 2D Layer to 1D Band for Germanophosphates
 Induced by the "Tailor Effect" of Fluoride.
;
_journal_issue                   14
_journal_name_full               'Inorganic chemistry'
_journal_page_first              6978
_journal_page_last               6985
_journal_paper_doi               10.1021/acs.inorgchem.5b00973
_journal_volume                  54
_journal_year                    2015
_chemical_formula_sum            'Co F2 Ge2 H8 K4 O20 P4'
_chemical_formula_weight         850.45
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   difmap
_audit_creation_method           SHELXL-2014/7
_cell_angle_alpha                90
_cell_angle_beta                 116.19(3)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   9.946(4)
_cell_length_b                   16.132(7)
_cell_length_c                   12.653(4)
_cell_measurement_reflns_used    4371
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      28.804
_cell_measurement_theta_min      2.194
_cell_volume                     1821.7(13)
_computing_cell_refinement       'SAINT (Bruker, 2001)'
_computing_data_collection       'SAINT (Bruker, 2001)'
_computing_data_reduction        'SAINT (Bruker, 2001)'
_computing_molecular_graphics    'DIAMOND (Brandenburg, 2005) '
_computing_publication_material
'SHELXL-2014/7 (Sheldrick, 2014) and WinGX (Farrugia, 2014)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.920
_diffrn_measurement_device_type  'Bruker Diffraction CCD area-detector'
_diffrn_measurement_method
'1265 images,φ=0, 90, 180 degree, and Δω=0.3 degree, χ= 54.74 degree'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0412
_diffrn_reflns_av_unetI/netI     0.0578
_diffrn_reflns_laue_measured_fraction_full 0.998
_diffrn_reflns_laue_measured_fraction_max 0.920
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            11253
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.920
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.804
_diffrn_reflns_theta_min         2.194
_exptl_absorpt_coefficient_mu    5.570
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SMART (Bruker, 2001)'
_exptl_crystal_colour            pink
_exptl_crystal_density_diffrn    3.101
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       rod
_exptl_crystal_F_000             1652
_exptl_crystal_size_max          0.100
_exptl_crystal_size_mid          0.050
_exptl_crystal_size_min          0.030
_exptl_transmission_factor_max   0.846
_exptl_transmission_factor_min   0.723
_refine_diff_density_max         1.328
_refine_diff_density_min         -0.788
_refine_diff_density_rms         0.197
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.037
_refine_ls_hydrogen_treatment    refxyz
_refine_ls_matrix_type           full
_refine_ls_number_parameters     325
_refine_ls_number_reflns         4373
_refine_ls_number_restraints     14
_refine_ls_restrained_S_all      1.036
_refine_ls_R_factor_all          0.0567
_refine_ls_R_factor_gt           0.0419
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0462P)²+2.7673P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0970
_refine_ls_wR_factor_ref         0.1025
_reflns_Friedel_coverage         0.000
_reflns_number_gt                3492
_reflns_number_total             4373
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ic5b00973_si_005.cif
_cod_data_source_block           P21/c
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'multi scan' changed to
'multi-scan' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 3271 2015-04-21 07:52:19Z andrius 

 Adding full bibliography for 4343450--4343453.cif.
;
_cod_original_cell_volume        1821.6(13)
_cod_database_code               4343452
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.606
_shelx_estimated_absorpt_t_max   0.851
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Ge1 Ge 0.49408(6) 0.46609(3) 0.22463(4) 0.00567(13) Uani 1 1 d . . .
Ge2 Ge 0.00636(6) 0.41952(3) 0.24146(4) 0.00556(13) Uani 1 1 d . . .
Co1 Co 0.5000 0.5000 0.5000 0.0069(2) Uani 1 2 d S . P
Co2 Co 0.0000 0.5000 0.5000 0.0062(2) Uani 1 2 d S . P
P1 P 0.32596(14) 0.34307(8) 0.32629(11) 0.0069(3) Uani 1 1 d . . .
P2 P 0.22969(14) 0.56177(8) 0.24116(11) 0.0064(3) Uani 1 1 d . . .
P3 P 0.77754(14) 0.56441(8) 0.23382(11) 0.0057(3) Uani 1 1 d . . .
P4 P 0.78071(14) 0.34852(8) 0.32905(11) 0.0062(3) Uani 1 1 d . . .
F1 F -0.0797(3) 0.38079(17) 0.0920(2) 0.0094(6) Uani 1 1 d . . .
F2 F 0.4076(3) 0.44766(18) 0.0688(2) 0.0101(6) Uani 1 1 d . . .
O1 O 0.3883(4) 0.3895(2) 0.4412(3) 0.0105(7) Uani 1 1 d . . .
O2 O 0.5847(4) 0.4901(2) 0.3805(3) 0.0071(7) Uani 1 1 d D . .
H2 H 0.668(4) 0.469(4) 0.409(6) 0.050 Uiso 1 1 d D U .
O3 O 0.3051(4) 0.5613(2) 0.3745(3) 0.0103(7) Uani 1 1 d . . .
O4 O 0.0904(4) 0.4575(2) 0.3924(3) 0.0087(7) Uani 1 1 d D U .
H4 H 0.179(3) 0.469(4) 0.413(6) 0.050 Uiso 1 1 d D U .
O5 O 0.8596(4) 0.5778(2) 0.3651(3) 0.0090(7) Uani 1 1 d . . .
O6 O 0.8400(4) 0.4026(2) 0.4369(3) 0.0097(7) Uani 1 1 d . . .
O7 O 0.3639(4) 0.3854(2) 0.2330(3) 0.0080(7) Uani 1 1 d . . .
O8 O 0.6320(4) 0.3837(2) 0.2333(3) 0.0080(7) Uani 1 1 d . . .
O9 O 0.3492(4) 0.5509(2) 0.1940(3) 0.0083(7) Uani 1 1 d . . .
O10 O 0.6102(4) 0.5498(2) 0.1936(3) 0.0079(7) Uani 1 1 d . . .
O11 O 0.1528(4) 0.3363(2) 0.2731(3) 0.0068(7) Uani 1 1 d . . .
O12 O 0.1123(4) 0.4918(2) 0.1888(3) 0.0072(7) Uani 1 1 d . . .
O13 O 0.8933(4) 0.3398(2) 0.2753(3) 0.0073(7) Uani 1 1 d . . .
O14 O 0.8431(4) 0.4939(2) 0.1892(3) 0.0080(7) Uani 1 1 d . . .
O15 O 0.3846(4) 0.2539(2) 0.3426(3) 0.0105(7) Uani 1 1 d . . .
O16 O 0.1455(4) 0.6425(2) 0.1922(3) 0.0113(7) Uani 1 1 d . . .
O17 O 0.7897(4) 0.6431(2) 0.1688(3) 0.0096(7) Uani 1 1 d D . .
H17 H 0.731(7) 0.682(3) 0.159(6) 0.050 Uiso 1 1 d D U .
O18 O 0.7490(4) 0.2613(2) 0.3601(3) 0.0114(8) Uani 1 1 d D . .
H18 H 0.789(8) 0.219(3) 0.352(7) 0.050 Uiso 1 1 d D U .
OW1 O 0.1496(5) 0.2776(2) 0.5154(3) 0.0179(9) Uani 1 1 d D . .
HW1A H 0.121(8) 0.291(5) 0.448(3) 0.050 Uiso 1 1 d D U .
HW1B H 0.160(9) 0.324(2) 0.544(6) 0.050 Uiso 1 1 d D U .
OW2 O 0.6393(5) 0.2259(3) 0.0587(4) 0.0240(9) Uani 1 1 d D . .
HW2A H 0.659(9) 0.1754(18) 0.077(7) 0.050 Uiso 1 1 d D U .
HW2B H 0.583(7) 0.226(5) -0.014(2) 0.050 Uiso 1 1 d D U .
K1 K 0.12244(13) 0.10313(8) 0.50198(9) 0.0139(2) Uani 1 1 d . . .
K2 K 0.62515(13) 0.39194(7) 0.01057(10) 0.0135(2) Uani 1 1 d . . .
K3 K 0.94052(13) 0.21229(7) 0.13227(10) 0.0151(3) Uani 1 1 d . . .
K4 K 0.45504(15) 0.19692(10) 0.16674(12) 0.0299(3) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
F2 Ge1 O2 176.93(15) . .
F2 Ge1 O7 86.47(14) . .
O2 Ge1 O7 96.38(15) . .
F2 Ge1 O8 86.03(14) . .
O2 Ge1 O8 95.05(15) . .
O7 Ge1 O8 90.58(15) . .
F2 Ge1 O9 86.72(14) . .
O2 Ge1 O9 92.05(15) . .
O7 Ge1 O9 91.79(15) . .
O8 Ge1 O9 172.21(14) . .
F2 Ge1 O10 86.09(13) . .
O2 Ge1 O10 91.01(15) . .
O7 Ge1 O10 172.24(14) . .
O8 Ge1 O10 91.11(15) . .
O9 Ge1 O10 85.57(15) . .
F2 Ge1 K2 50.18(10) . 3_665
O2 Ge1 K2 126.96(12) . 3_665
O7 Ge1 K2 121.13(11) . 3_665
O8 Ge1 K2 118.33(10) . 3_665
O9 Ge1 K2 54.32(10) . 3_665
O10 Ge1 K2 51.70(10) . 3_665
F2 Ge1 K2 44.95(9) . .
O2 Ge1 K2 134.60(11) . .
O7 Ge1 K2 107.07(10) . .
O8 Ge1 K2 47.71(10) . .
O9 Ge1 K2 124.53(10) . .
O10 Ge1 K2 68.84(10) . .
K2 Ge1 K2 71.72(4) 3_665 .
F2 Ge1 K1 43.85(9) . 4_565
O2 Ge1 K1 138.07(11) . 4_565
O7 Ge1 K1 49.36(10) . 4_565
O8 Ge1 K1 106.85(11) . 4_565
O9 Ge1 K1 69.43(11) . 4_565
O10 Ge1 K1 122.97(10) . 4_565
K2 Ge1 K1 72.65(4) 3_665 4_565
K2 Ge1 K1 84.31(4) . 4_565
F2 Ge1 K4 117.87(10) . 2_655
O2 Ge1 K4 59.38(11) . 2_655
O7 Ge1 K4 128.75(11) . 2_655
O8 Ge1 K4 132.30(11) . 2_655
O9 Ge1 K4 49.95(11) . 2_655
O10 Ge1 K4 53.86(10) . 2_655
K2 Ge1 K4 67.79(4) 3_665 2_655
K2 Ge1 K4 122.18(3) . 2_655
K1 Ge1 K4 119.00(3) 4_565 2_655
F1 Ge2 O4 178.94(14) . .
F1 Ge2 O13 86.95(14) . 1_455
O4 Ge2 O13 92.02(15) . 1_455
F1 Ge2 O12 85.67(14) . .
O4 Ge2 O12 95.36(15) . .
O13 Ge2 O12 172.45(14) 1_455 .
F1 Ge2 O14 85.18(14) . 1_455
O4 Ge2 O14 94.53(16) . 1_455
O13 Ge2 O14 90.33(15) 1_455 1_455
O12 Ge2 O14 90.65(15) . 1_455
F1 Ge2 O11 86.63(14) . .
O4 Ge2 O11 93.61(15) . .
O13 Ge2 O11 87.04(15) 1_455 .
O12 Ge2 O11 90.92(15) . .
O14 Ge2 O11 171.52(14) 1_455 .
F1 Ge2 K3 49.43(9) . 1_455
O4 Ge2 K3 130.03(12) . 1_455
O13 Ge2 K3 54.58(10) 1_455 1_455
O12 Ge2 K3 118.70(10) . 1_455
O14 Ge2 K3 118.51(11) 1_455 1_455
O11 Ge2 K3 53.74(10) . 1_455
F1 Ge2 K2 43.61(9) . 1_455
O4 Ge2 K2 135.58(11) . 1_455
O13 Ge2 K2 65.42(11) 1_455 1_455
O12 Ge2 K2 109.77(11) . 1_455
O14 Ge2 K2 50.82(11) 1_455 1_455
O11 Ge2 K2 120.95(11) . 1_455
K3 Ge2 K2 68.13(3) 1_455 1_455
F1 Ge2 K1 44.41(9) . 4_565
O4 Ge2 K1 136.61(11) . 4_565
O13 Ge2 K1 123.57(10) 1_455 4_565
O12 Ge2 K1 49.14(10) . 4_565
O14 Ge2 K1 107.84(10) 1_455 4_565
O11 Ge2 K1 67.31(10) . 4_565
K3 Ge2 K1 70.18(3) 1_455 4_565
K2 Ge2 K1 85.53(4) 1_455 4_565
O2 Co1 O2 180.0 3_666 .
O2 Co1 O1 89.87(14) 3_666 3_666
O2 Co1 O1 90.13(14) . 3_666
O2 Co1 O1 90.13(14) 3_666 .
O2 Co1 O1 89.87(14) . .
O1 Co1 O1 180.0 3_666 .
O2 Co1 O3 88.75(13) 3_666 .
O2 Co1 O3 91.25(13) . .
O1 Co1 O3 92.05(14) 3_666 .
O1 Co1 O3 87.95(14) . .
O2 Co1 O3 91.25(13) 3_666 3_666
O2 Co1 O3 88.75(13) . 3_666
O1 Co1 O3 87.95(14) 3_666 3_666
O1 Co1 O3 92.05(14) . 3_666
O3 Co1 O3 180.0 . 3_666
O2 Co1 K4 58.97(10) 3_666 4_566
O2 Co1 K4 121.03(10) . 4_566
O1 Co1 K4 132.40(10) 3_666 4_566
O1 Co1 K4 47.60(10) . 4_566
O3 Co1 K4 119.44(10) . 4_566
O3 Co1 K4 60.56(10) 3_666 4_566
O2 Co1 K4 121.03(10) 3_666 2_655
O2 Co1 K4 58.97(10) . 2_655
O1 Co1 K4 47.60(10) 3_666 2_655
O1 Co1 K4 132.40(10) . 2_655
O3 Co1 K4 60.56(10) . 2_655
O3 Co1 K4 119.44(10) 3_666 2_655
K4 Co1 K4 180.0 4_566 2_655
O4 Co2 O4 180.00(14) . 3_566
O4 Co2 O5 90.65(14) . 3_666
O4 Co2 O5 89.35(14) 3_566 3_666
O4 Co2 O5 89.35(14) . 1_455
O4 Co2 O5 90.65(14) 3_566 1_455
O5 Co2 O5 180.0(2) 3_666 1_455
O4 Co2 O6 91.23(13) . 3_666
O4 Co2 O6 88.77(13) 3_566 3_666
O5 Co2 O6 91.02(14) 3_666 3_666
O5 Co2 O6 88.99(14) 1_455 3_666
O4 Co2 O6 88.77(13) . 1_455
O4 Co2 O6 91.23(13) 3_566 1_455
O5 Co2 O6 88.98(14) 3_666 1_455
O5 Co2 O6 91.01(14) 1_455 1_455
O6 Co2 O6 180.0 3_666 1_455
O4 Co2 K3 100.50(10) . 4_466
O4 Co2 K3 79.50(10) 3_566 4_466
O5 Co2 K3 45.97(10) 3_666 4_466
O5 Co2 K3 134.03(10) 1_455 4_466
O6 Co2 K3 134.89(9) 3_666 4_466
O6 Co2 K3 45.11(9) 1_455 4_466
O4 Co2 K3 79.50(10) . 2_655
O4 Co2 K3 100.50(10) 3_566 2_655
O5 Co2 K3 134.03(10) 3_666 2_655
O5 Co2 K3 45.97(10) 1_455 2_655
O6 Co2 K3 45.11(9) 3_666 2_655
O6 Co2 K3 134.89(9) 1_455 2_655
K3 Co2 K3 180.000(17) 4_466 2_655
O1 P1 O15 111.5(2) . .
O1 P1 O7 112.48(19) . .
O15 P1 O7 108.1(2) . .
O1 P1 O11 111.0(2) . .
O15 P1 O11 106.03(19) . .
O7 P1 O11 107.35(19) . .
O1 P1 K4 138.90(15) . .
O15 P1 K4 43.01(13) . .
O7 P1 K4 66.60(14) . .
O11 P1 K4 107.83(13) . .
O1 P1 K1 136.71(15) . 4_565
O15 P1 K1 110.54(14) . 4_565
O7 P1 K1 42.82(13) . 4_565
O11 P1 K1 65.58(13) . 4_565
K4 P1 K1 72.66(4) . 4_565
O3 P2 O16 111.7(2) . .
O3 P2 O12 112.5(2) . .
O16 P2 O12 105.9(2) . .
O3 P2 O9 109.9(2) . .
O16 P2 O9 108.41(19) . .
O12 P2 O9 108.26(19) . .
O3 P2 K1 141.12(15) . 2
O16 P2 K1 48.26(14) . 2
O12 P2 K1 59.83(13) . 2
O9 P2 K1 108.44(14) . 2
O3 P2 K4 72.99(15) . 2_655
O16 P2 K4 81.74(15) . 2_655
O12 P2 K4 167.05(14) . 2_655
O9 P2 K4 58.95(14) . 2_655
K1 P2 K4 123.76(5) 2 2_655
O3 P2 K3 67.49(14) . 2_655
O16 P2 K3 48.81(13) . 2_655
O12 P2 K3 105.11(13) . 2_655
O9 P2 K3 144.20(14) . 2_655
K1 P2 K3 77.74(4) 2 2_655
K4 P2 K3 87.80(5) 2_655 2_655
O3 P2 K1 135.15(15) . 4_565
O16 P2 K1 111.29(15) . 4_565
O12 P2 K1 42.00(12) . 4_565
O9 P2 K1 67.09(13) . 4_565
K1 P2 K1 67.71(4) 2 4_565
K4 P2 K1 125.72(5) 2_655 4_565
K3 P2 K1 141.24(5) 2_655 4_565
O5 P3 O10 111.69(19) . .
O5 P3 O14 113.5(2) . .
O10 P3 O14 109.8(2) . .
O5 P3 O17 109.7(2) . .
O10 P3 O17 106.2(2) . .
O14 P3 O17 105.50(19) . .
O5 P3 K3 55.97(14) . 2_755
O10 P3 K3 142.10(14) . 2_755
O14 P3 K3 107.67(14) . 2_755
O17 P3 K3 57.54(14) . 2_755
O5 P3 K1 132.54(15) . 2_655
O10 P3 K1 114.22(14) . 2_655
O14 P3 K1 60.38(13) . 2_655
O17 P3 K1 45.59(13) . 2_655
K3 P3 K1 80.04(4) 2_755 2_655
O5 P3 K4 70.33(14) . 2_655
O10 P3 K4 57.18(13) . 2_655
O14 P3 K4 165.73(14) . 2_655
O17 P3 K4 85.12(14) . 2_655
K3 P3 K4 85.99(5) 2_755 2_655
K1 P3 K4 128.12(5) 2_655 2_655
O5 P3 K2 140.64(14) . .
O10 P3 K2 67.55(13) . .
O14 P3 K2 43.50(13) . .
O17 P3 K2 107.90(14) . .
K3 P3 K2 146.81(5) 2_755 .
K1 P3 K2 70.94(4) 2_655 .
K4 P3 K2 124.60(5) 2_655 .
O6 P4 O18 110.1(2) . .
O6 P4 O8 110.7(2) . .
O18 P4 O8 107.7(2) . .
O6 P4 O13 112.4(2) . .
O18 P4 O13 107.43(19) . .
O8 P4 O13 108.36(19) . .
O6 P4 K3 51.37(14) . 4_566
O18 P4 K3 61.14(15) . 4_566
O8 P4 K3 139.29(13) . 4_566
O13 P4 K3 112.33(14) . 4_566
O6 P4 K2 133.50(14) . .
O18 P4 K2 114.86(15) . .
O8 P4 K2 43.98(12) . .
O13 P4 K2 64.81(13) . .
K3 P4 K2 174.70(5) 4_566 .
O6 P4 K4 138.89(14) . .
O18 P4 K4 48.16(15) . .
O8 P4 K4 61.79(14) . .
O13 P4 K4 107.97(14) . .
K3 P4 K4 105.58(5) 4_566 .
K2 P4 K4 71.91(4) . .
Ge2 F1 K2 108.35(12) . 1_455
Ge2 F1 K1 107.93(13) . 4_565
K2 F1 K1 136.45(11) 1_455 4_565
Ge2 F1 K3 100.68(12) . 1_455
K2 F1 K3 96.71(10) 1_455 1_455
K1 F1 K3 99.43(9) 4_565 1_455
Ge1 F2 K1 108.80(12) . 4_565
Ge1 F2 K2 107.38(13) . .
K1 F2 K2 131.53(12) 4_565 .
Ge1 F2 K2 99.67(12) . 3_665
K1 F2 K2 103.46(10) 4_565 3_665
K2 F2 K2 101.06(10) . 3_665
P1 O1 Co1 135.0(2) . .
P1 O1 K4 121.06(18) . 4_566
Co1 O1 K4 101.69(13) . 4_566
Ge1 O2 Co1 130.94(19) . .
Ge1 O2 K4 93.16(13) . 2_655
Co1 O2 K4 89.98(11) . 2_655
Ge1 O2 H2 109(5) . .
Co1 O2 H2 112(5) . .
K4 O2 H2 120(5) 2_655 .
P2 O3 Co1 132.3(2) . .
P2 O3 K3 88.39(15) . 2_655
Co1 O3 K3 138.89(14) . 2_655
Ge2 O4 Co2 132.54(19) . .
Ge2 O4 H4 110(5) . .
Co2 O4 H4 116(5) . .
P3 O5 Co2 131.2(2) . 1_655
P3 O5 K3 98.80(16) . 2_755
Co2 O5 K3 103.35(14) 1_655 2_755
P4 O6 Co2 134.3(2) . 1_655
P4 O6 K3 104.66(17) . 4_566
Co2 O6 K3 103.52(13) 1_655 4_566
P1 O7 Ge1 139.2(2) . .
P1 O7 K1 115.54(17) . 4_565
Ge1 O7 K1 100.80(13) . 4_565
P1 O7 K4 88.56(15) . .
Ge1 O7 K4 110.11(14) . .
K1 O7 K4 90.06(9) 4_565 .
P4 O8 Ge1 136.6(2) . .
P4 O8 K2 113.38(17) . .
Ge1 O8 K2 102.44(13) . .
P4 O8 K4 94.59(15) . .
Ge1 O8 K4 109.10(14) . .
K2 O8 K4 90.73(9) . .
P2 O9 Ge1 129.9(2) . .
P2 O9 K2 134.25(18) . 3_665
Ge1 O9 K2 93.08(12) . 3_665
P2 O9 K4 95.28(15) . 2_655
Ge1 O9 K4 101.77(14) . 2_655
K2 O9 K4 89.12(10) 3_665 2_655
P3 O10 Ge1 134.7(2) . .
P3 O10 K2 127.21(18) . 3_665
Ge1 O10 K2 95.29(13) . 3_665
P3 O10 K4 99.08(16) . 2_655
Ge1 O10 K4 96.98(12) . 2_655
K2 O10 K4 88.24(10) 3_665 2_655
P1 O11 Ge2 130.3(2) . .
P1 O11 K3 133.34(18) . 1_455
Ge2 O11 K3 94.38(13) . 1_455
P2 O12 Ge2 137.4(2) . .
P2 O12 K1 116.76(17) . 4_565
Ge2 O12 K1 100.99(14) . 4_565
P2 O12 K1 94.49(16) . 2
Ge2 O12 K1 106.83(14) . 2
K1 O12 K1 87.47(10) 4_565 2
P4 O13 Ge2 131.2(2) . 1_655
P4 O13 K3 133.00(18) . .
Ge2 O13 K3 93.72(12) 1_655 .
P4 O13 K2 90.33(15) . .
Ge2 O13 K2 83.82(11) 1_655 .
K3 O13 K2 80.27(9) . .
P3 O14 Ge2 141.3(2) . 1_655
P3 O14 K2 114.78(18) . .
Ge2 O14 K2 98.42(14) 1_655 .
P3 O14 K1 94.34(15) . 2_655
Ge2 O14 K1 104.94(13) 1_655 2_655
K2 O14 K1 90.94(10) . 2_655
P1 O15 K4 114.80(18) . .
P1 O15 K2 149.93(19) . 4_566
K4 O15 K2 85.06(10) . 4_566
P2 O16 K1 107.65(18) . 2
P2 O16 K3 108.18(17) . 2_655
K1 O16 K3 105.67(12) 2 2_655
P3 O17 K1 110.65(17) . 2_655
P3 O17 K3 96.39(16) . 2_755
K1 O17 K3 105.87(12) 2_655 2_755
P3 O17 H17 119(5) . .
K1 O17 H17 121(5) 2_655 .
K3 O17 H17 99(5) 2_755 .
P4 O18 K4 109.88(19) . .
P4 O18 K3 93.60(17) . 4_566
K4 O18 K3 145.91(13) . 4_566
P4 O18 H18 124(5) . .
K4 O18 H18 88(6) . .
K3 O18 H18 99(5) 4_566 .
K4 OW1 K1 103.41(13) 4_566 .
K4 OW1 K3 115.17(14) 4_566 4_466
K1 OW1 K3 90.84(12) . 4_466
K4 OW1 HW1A 117(6) 4_566 .
K1 OW1 HW1A 103(6) . .
K3 OW1 HW1A 120(6) 4_466 .
K4 OW1 HW1B 71(6) 4_566 .
K1 OW1 HW1B 158(5) . .
K3 OW1 HW1B 73(5) 4_466 .
HW1A OW1 HW1B 98(7) . .
K3 OW2 K2 95.48(14) . .
K3 OW2 K4 133.27(17) . .
K2 OW2 K4 107.14(16) . .
K3 OW2 HW2A 75(6) . .
K2 OW2 HW2A 171(6) . .
K4 OW2 HW2A 80(5) . .
K3 OW2 HW2B 119(5) . .
K2 OW2 HW2B 79(5) . .
K4 OW2 HW2B 106(5) . .
HW2A OW2 HW2B 106(7) . .
F2 K1 F1 139.76(9) 4_566 4_566
F2 K1 O17 70.30(10) 4_566 2_645
F1 K1 O17 149.04(11) 4_566 2_645
F2 K1 O16 143.88(10) 4_566 2_545
F1 K1 O16 75.65(10) 4_566 2_545
O17 K1 O16 76.39(11) 2_645 2_545
F2 K1 OW1 102.93(11) 4_566 .
F1 K1 OW1 87.06(11) 4_566 .
O17 K1 OW1 75.97(11) 2_645 .
O16 K1 OW1 81.64(12) 2_545 .
F2 K1 O7 53.63(9) 4_566 4_566
F1 K1 O7 90.48(10) 4_566 4_566
O17 K1 O7 112.02(11) 2_645 4_566
O16 K1 O7 158.94(11) 2_545 4_566
OW1 K1 O7 81.89(11) . 4_566
F2 K1 O12 89.65(10) 4_566 4_566
F1 K1 O12 53.35(9) 4_566 4_566
O17 K1 O12 156.73(11) 2_645 4_566
O16 K1 O12 118.87(11) 2_545 4_566
OW1 K1 O12 121.48(11) . 4_566
O7 K1 O12 60.57(10) 4_566 4_566
F2 K1 O12 113.28(10) 4_566 2_545
F1 K1 O12 86.52(9) 4_566 2_545
O17 K1 O12 85.11(10) 2_645 2_545
O16 K1 O12 49.01(10) 2_545 2_545
OW1 K1 O12 130.22(11) . 2_545
O7 K1 O12 147.42(10) 4_566 2_545
O12 K1 O12 92.53(10) 4_566 2_545
F2 K1 O14 67.29(9) 4_566 2_645
F1 K1 O14 136.78(10) 4_566 2_645
O17 K1 O14 48.87(10) 2_645 2_645
O16 K1 O14 80.52(10) 2_545 2_645
OW1 K1 O14 124.54(11) . 2_645
O7 K1 O14 119.86(10) 4_566 2_645
O12 K1 O14 113.14(10) 4_566 2_645
O12 K1 O14 51.05(9) 2_545 2_645
F2 K1 P2 135.21(8) 4_566 2_545
F1 K1 P2 75.71(7) 4_566 2_545
O17 K1 P2 84.10(9) 2_645 2_545
O16 K1 P2 24.09(8) 2_545 2_545
OW1 K1 P2 105.68(9) . 2_545
O7 K1 P2 163.65(8) 4_566 2_545
O12 K1 P2 103.53(8) 4_566 2_545
O12 K1 P2 25.68(7) 2_545 2_545
O14 K1 P2 68.18(7) 2_645 2_545
F2 K1 P3 64.56(7) 4_566 2_645
F1 K1 P3 152.82(7) 4_566 2_645
O17 K1 P3 23.76(8) 2_645 2_645
O16 K1 P3 79.33(8) 2_545 2_645
OW1 K1 P3 99.73(9) . 2_645
O7 K1 P3 116.45(8) 4_566 2_645
O12 K1 P3 135.90(8) 4_566 2_645
O12 K1 P3 68.93(7) 2_545 2_645
O14 K1 P3 25.27(6) 2_645 2_645
P2 K1 P3 77.12(5) 2_545 2_645
F2 K1 Ge1 27.36(6) 4_566 4_566
F1 K1 Ge1 112.60(7) 4_566 4_566
O17 K1 Ge1 96.46(9) 2_645 4_566
O16 K1 Ge1 170.69(8) 2_545 4_566
OW1 K1 Ge1 102.61(9) . 4_566
O7 K1 Ge1 29.83(7) 4_566 4_566
O12 K1 Ge1 66.16(7) 4_566 4_566
O12 K1 Ge1 125.26(8) 2_545 4_566
O14 K1 Ge1 90.29(7) 2_645 4_566
P2 K1 Ge1 150.93(5) 2_545 4_566
P3 K1 Ge1 91.73(5) 2_645 4_566
F1 K2 F2 142.26(10) 1_655 .
F1 K2 OW2 84.71(12) 1_655 .
F2 K2 OW2 103.38(12) . .
F1 K2 F2 97.95(9) 1_655 3_665
F2 K2 F2 78.94(10) . 3_665
OW2 K2 F2 172.31(11) . 3_665
F1 K2 O10 135.95(10) 1_655 3_665
F2 K2 O10 72.31(10) . 3_665
OW2 K2 O10 118.57(12) . 3_665
F2 K2 O10 54.84(9) 3_665 3_665
F1 K2 O8 94.28(10) 1_655 .
F2 K2 O8 53.97(9) . .
OW2 K2 O8 75.71(12) . .
F2 K2 O8 111.15(10) 3_665 .
O10 K2 O8 126.20(11) 3_665 .
F1 K2 O14 53.81(9) 1_655 .
F2 K2 O14 90.69(10) . .
OW2 K2 O14 116.12(12) . .
F2 K2 O14 70.92(10) 3_665 .
O10 K2 O14 125.05(11) 3_665 .
O8 K2 O14 63.74(10) . .
F1 K2 O9 81.27(10) 1_655 3_665
F2 K2 O9 122.43(10) . 3_665
OW2 K2 O9 119.98(12) . 3_665
F2 K2 O9 53.75(9) 3_665 3_665
O10 K2 O9 54.86(10) 3_665 3_665
O8 K2 O9 162.87(11) . 3_665
O14 K2 O9 100.97(10) . 3_665
F1 K2 O13 48.44(8) 1_655 .
F2 K2 O13 100.91(9) . .
OW2 K2 O13 65.83(11) . .
F2 K2 O13 121.21(9) 3_665 .
O10 K2 O13 172.37(10) 3_665 .
O8 K2 O13 47.36(9) . .
O14 K2 O13 50.30(9) . .
O9 K2 O13 129.60(10) 3_665 .
F1 K2 O15 123.72(9) 1_655 4_565
F2 K2 O15 88.47(9) . 4_565
OW2 K2 O15 53.67(11) . 4_565
F2 K2 O15 119.52(9) 3_665 4_565
O10 K2 O15 64.90(10) 3_665 4_565
O8 K2 O15 107.37(10) . 4_565
O14 K2 O15 169.07(10) . 4_565
O9 K2 O15 88.64(10) 3_665 4_565
O13 K2 O15 119.25(9) . 4_565
F1 K2 Ge1 105.94(7) 1_655 3_665
F2 K2 Ge1 90.16(7) . 3_665
OW2 K2 Ge1 142.17(10) . 3_665
F2 K2 Ge1 30.15(6) 3_665 3_665
O10 K2 Ge1 33.01(7) 3_665 3_665
O8 K2 Ge1 137.16(8) . 3_665
O14 K2 Ge1 98.57(8) . 3_665
O9 K2 Ge1 32.60(7) 3_665 3_665
O13 K2 Ge1 146.47(7) . 3_665
O15 K2 Ge1 92.33(7) 4_565 3_665
F1 K2 Ge2 28.04(6) 1_655 1_655
F2 K2 Ge2 114.27(7) . 1_655
OW2 K2 Ge2 90.46(10) . 1_655
F2 K2 Ge2 95.25(7) 3_665 1_655
O10 K2 Ge2 148.76(8) 3_665 1_655
O8 K2 Ge2 69.14(8) . 1_655
O14 K2 Ge2 30.76(7) . 1_655
O9 K2 Ge2 102.04(8) 3_665 1_655
O13 K2 Ge2 30.76(6) . 1_655
O15 K2 Ge2 142.15(7) 4_565 1_655
Ge1 K2 Ge2 116.13(4) 3_665 1_655
F1 K2 HW2B 93.9(14) 1_655 .
F2 K2 HW2B 104.7(16) . .
OW2 K2 HW2B 17.8(5) . .
F2 K2 HW2B 154.6(5) 3_665 .
O10 K2 HW2B 101.7(7) 3_665 .
O8 K2 HW2B 90.1(10) . .
O14 K2 HW2B 133.2(7) . .
O9 K2 HW2B 106.6(11) 3_665 .
O13 K2 HW2B 83.2(6) . .
O15 K2 HW2B 37.2(8) 4_565 .
Ge1 K2 HW2B 124.7(5) 3_665 .
Ge2 K2 HW2B 105.5(10) 1_655 .
OW2 K3 F1 82.99(11) . 1_655
OW2 K3 O11 123.37(12) . 1_655
F1 K3 O11 53.40(9) 1_655 1_655
OW2 K3 O6 81.15(12) . 4_565
F1 K3 O6 120.30(10) 1_655 4_565
O11 K3 O6 148.82(10) 1_655 4_565
OW2 K3 O13 72.60(12) . .
F1 K3 O13 53.09(9) 1_655 .
O11 K3 O13 53.18(10) 1_655 .
O6 K3 O13 153.41(11) 4_565 .
OW2 K3 O5 134.46(12) . 2_745
F1 K3 O5 136.52(10) 1_655 2_745
O11 K3 O5 101.47(11) 1_655 2_745
O6 K3 O5 60.82(10) 4_565 2_745
O13 K3 O5 144.11(10) . 2_745
OW2 K3 O16 69.24(12) . 2_645
F1 K3 O16 119.75(10) 1_655 2_645
O11 K3 O16 100.19(10) 1_655 2_645
O6 K3 O16 107.14(11) 4_565 2_645
O13 K3 O16 67.64(10) . 2_645
O5 K3 O16 97.48(10) 2_745 2_645
OW2 K3 O17 139.96(12) . 2_745
F1 K3 O17 119.48(10) 1_655 2_745
O11 K3 O17 66.15(10) 1_655 2_745
O6 K3 O17 109.02(11) 4_565 2_745
O13 K3 O17 94.13(10) . 2_745
O5 K3 O17 50.07(10) 2_745 2_745
O16 K3 O17 70.77(10) 2_645 2_745
OW2 K3 OW1 135.55(13) . 4_665
F1 K3 OW1 82.38(10) 1_655 4_665
O11 K3 OW1 78.01(10) 1_655 4_665
O6 K3 OW1 70.81(10) 4_565 4_665
O13 K3 OW1 126.65(11) . 4_665
O5 K3 OW1 55.93(10) 2_745 4_665
O16 K3 OW1 151.51(11) 2_645 4_665
O17 K3 OW1 82.89(11) 2_745 4_665
OW2 K3 O18 64.63(11) . 4_565
F1 K3 O18 72.80(9) 1_655 4_565
O11 K3 O18 120.49(10) 1_655 4_565
O6 K3 O18 48.45(10) 4_565 4_565
O13 K3 O18 113.52(10) . 4_565
O5 K3 O18 101.11(10) 2_745 4_565
O16 K3 O18 130.02(11) 2_645 4_565
O17 K3 O18 149.72(10) 2_745 4_565
OW1 K3 O18 70.96(11) 4_665 4_565
OW2 K3 O3 51.98(11) . 2_645
F1 K3 O3 134.73(10) 1_655 2_645
O11 K3 O3 145.97(9) 1_655 2_645
O6 K3 O3 63.19(9) 4_565 2_645
O13 K3 O3 102.07(9) . 2_645
O5 K3 O3 86.92(10) 2_745 2_645
O16 K3 O3 45.80(9) 2_645 2_645
O17 K3 O3 97.00(10) 2_745 2_645
OW1 K3 O3 131.23(10) 4_665 2_645
O18 K3 O3 89.33(9) 4_565 2_645
OW2 K3 P3 138.22(10) . 2_745
F1 K3 P3 137.71(8) 1_655 2_745
O11 K3 P3 87.83(8) 1_655 2_745
O6 K3 P3 82.97(8) 4_565 2_745
O13 K3 P3 119.72(8) . 2_745
O5 K3 P3 25.23(7) 2_745 2_745
O16 K3 P3 79.11(8) 2_645 2_745
O17 K3 P3 26.07(7) 2_745 2_745
OW1 K3 P3 72.42(9) 4_665 2_745
O18 K3 P3 126.29(8) 4_565 2_745
O3 K3 P3 86.42(8) 2_645 2_745
OW2 K3 HW2A 18.0(4) . .
F1 K3 HW2A 101.0(5) 1_655 .
O11 K3 HW2A 136.2(13) 1_655 .
O6 K3 HW2A 72.8(15) 4_565 .
O13 K3 HW2A 83.1(13) . .
O5 K3 HW2A 118.1(8) 2_745 .
O16 K3 HW2A 58.9(14) 2_645 .
O17 K3 HW2A 126.6(10) 2_745 .
OW1 K3 HW2A 139.3(16) 4_665 .
O18 K3 HW2A 71.5(15) 4_565 .
O3 K3 HW2A 34.0(5) 2_645 .
P3 K3 HW2A 120.3(5) 2_745 .
OW2 K4 O15 143.04(13) . .
OW2 K4 OW1 112.97(13) . 4_565
O15 K4 OW1 85.33(12) . 4_565
OW2 K4 O1 61.39(11) . 4_565
O15 K4 O1 153.88(12) . 4_565
OW1 K4 O1 72.49(11) 4_565 4_565
OW2 K4 O18 74.31(12) . .
O15 K4 O18 74.64(11) . .
OW1 K4 O18 149.38(12) 4_565 .
O1 K4 O18 131.15(11) 4_565 .
OW2 K4 O9 91.28(12) . 2_645
O15 K4 O9 96.59(10) . 2_645
OW1 K4 O9 136.32(12) 4_565 2_645
O1 K4 O9 90.43(10) 4_565 2_645
O18 K4 O9 70.12(10) . 2_645
OW2 K4 O10 137.70(12) . 2_645
O15 K4 O10 67.44(10) . 2_645
OW1 K4 O10 93.62(11) 4_565 2_645
O1 K4 O10 99.72(10) 4_565 2_645
O18 K4 O10 99.56(10) . 2_645
O9 K4 O10 48.99(9) 2_645 2_645
OW2 K4 O7 106.21(12) . .
O15 K4 O7 46.53(9) . .
OW1 K4 O7 73.19(10) 4_565 .
O1 K4 O7 133.47(10) 4_565 .
O18 K4 O7 76.22(10) . .
O9 K4 O7 136.00(10) 2_645 .
O10 K4 O7 112.91(9) 2_645 .
OW2 K4 O2 97.47(11) . 2_645
O15 K4 O2 114.73(10) . 2_645
OW1 K4 O2 90.97(11) 4_565 2_645
O1 K4 O2 53.77(9) 4_565 2_645
O18 K4 O2 118.27(10) . 2_645
O9 K4 O2 48.64(9) 2_645 2_645
O10 K4 O2 47.77(9) 2_645 2_645
O7 K4 O2 155.18(9) . 2_645
OW2 K4 O8 65.79(11) . .
O15 K4 O8 78.11(10) . .
OW1 K4 O8 108.91(11) 4_565 .
O1 K4 O8 121.62(10) 4_565 .
O18 K4 O8 44.91(9) . .
O9 K4 O8 114.19(10) 2_645 .
O10 K4 O8 136.95(9) 2_645 .
O7 K4 O8 46.25(9) . .
O2 K4 O8 157.62(9) 2_645 .
OW2 K4 P2 65.55(10) . 2_645
O15 K4 P2 115.98(9) . 2_645
OW1 K4 P2 147.18(10) 4_565 2_645
O1 K4 P2 79.56(8) 4_565 2_645
O18 K4 P2 63.43(8) . 2_645
O9 K4 P2 25.77(6) 2_645 2_645
O10 K4 P2 74.26(8) 2_645 2_645
O7 K4 P2 139.62(8) . 2_645
O2 K4 P2 58.12(7) 2_645 2_645
O8 K4 P2 100.15(8) . 2_645
OW2 K4 P1 129.04(11) . .
O15 K4 P1 22.19(7) . .
OW1 K4 P1 75.35(9) 4_565 .
O1 K4 P1 147.26(8) 4_565 .
O18 K4 P1 77.58(8) . .
O9 K4 P1 117.58(8) 2_645 .
O10 K4 P1 88.13(7) 2_645 .
O7 K4 P1 24.84(6) . .
O2 K4 P1 133.36(7) 2_645 .
O8 K4 P1 64.21(7) . .
P2 K4 P1 132.93(5) 2_645 .
OW2 K4 HW2A 17.6(5) . .
O15 K4 HW2A 150.3(17) . .
OW1 K4 HW2A 120.6(16) 4_565 .
O1 K4 HW2A 55.8(16) 4_565 .
O18 K4 HW2A 75.7(17) . .
O9 K4 HW2A 75.1(8) 2_645 .
O10 K4 HW2A 120.1(5) 2_645 .
O7 K4 HW2A 122.9(8) . .
O2 K4 HW2A 81.5(9) 2_645 .
O8 K4 HW2A 79.6(11) . .
P2 K4 HW2A 49.8(9) 2_645 .
P1 K4 HW2A 143.7(11) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ge1 F2 1.794(3) .
Ge1 O2 1.812(3) .
Ge1 O7 1.871(3) .
Ge1 O8 1.878(3) .
Ge1 O9 1.899(3) .
Ge1 O10 1.926(3) .
Ge1 K2 3.5202(16) 3_665
Ge1 K2 3.6855(15) .
Ge1 K1 3.695(2) 4_565
Ge1 K4 3.924(2) 2_655
Ge2 F1 1.808(3) .
Ge2 O4 1.820(3) .
Ge2 O13 1.878(3) 1_455
Ge2 O12 1.880(3) .
Ge2 O14 1.888(3) 1_455
Ge2 O11 1.889(3) .
Ge2 K3 3.5659(18) 1_455
Ge2 K2 3.651(2) 1_455
Ge2 K1 3.7063(16) 4_565
Co1 O2 2.035(3) 3_666
Co1 O2 2.035(3) .
Co1 O1 2.058(3) 3_666
Co1 O1 2.058(3) .
Co1 O3 2.131(4) .
Co1 O3 2.131(4) 3_666
Co1 K4 3.9466(19) 4_566
Co1 K4 3.9466(19) 2_655
Co2 O4 2.052(3) .
Co2 O4 2.052(3) 3_566
Co2 O5 2.082(3) 3_666
Co2 O5 2.082(3) 1_455
Co2 O6 2.125(4) 3_666
Co2 O6 2.125(4) 1_455
Co2 K3 3.9690(17) 4_466
Co2 K3 3.9690(17) 2_655
P1 O1 1.504(3) .
P1 O15 1.532(4) .
P1 O7 1.548(3) .
P1 O11 1.552(4) .
P1 K4 3.684(2) .
P1 K1 3.789(2) 4_565
P2 O3 1.514(4) .
P2 O16 1.524(4) .
P2 O12 1.547(4) .
P2 O9 1.557(4) .
P2 K1 3.558(2) 2
P2 K4 3.566(2) 2_655
P2 K3 3.7041(19) 2_655
P2 K1 3.811(2) 4_565
P3 O5 1.508(3) .
P3 O10 1.529(4) .
P3 O14 1.538(4) .
P3 O17 1.547(4) .
P3 K3 3.497(2) 2_755
P3 K1 3.5918(19) 2_655
P3 K4 3.751(2) 2_655
P3 K2 3.773(2) .
P4 O6 1.503(3) .
P4 O18 1.531(4) .
P4 O8 1.547(4) .
P4 O13 1.552(3) .
P4 K3 3.581(2) 4_566
P4 K2 3.690(2) .
P4 K4 3.849(2) .
F1 K2 2.653(3) 1_455
F1 K1 2.726(3) 4_565
F1 K3 2.756(3) 1_455
F2 K1 2.704(3) 4_565
F2 K2 2.728(3) .
F2 K2 2.743(3) 3_665
O1 K4 2.976(4) 4_566
O2 K4 3.382(4) 2_655
O2 H2 0.82(2) .
O3 K3 3.423(4) 2_655
O4 H4 0.82(2) .
O5 Co2 2.082(3) 1_655
O5 K3 2.933(4) 2_755
O6 Co2 2.125(3) 1_655
O6 K3 2.892(4) 4_566
O7 K1 2.854(4) 4_565
O7 K4 3.382(4) .
O8 K2 2.792(3) .
O8 K4 3.403(4) .
O9 K2 2.864(3) 3_665
O9 K4 3.068(4) 2_655
O10 K2 2.774(4) 3_665
O10 K4 3.193(4) 2_655
O11 K3 2.884(4) 1_455
O12 K1 2.856(3) 4_565
O12 K1 3.086(4) 2
O13 Ge2 1.878(3) 1_655
O13 K3 2.912(3) .
O13 K2 3.339(4) .
O14 Ge2 1.888(3) 1_655
O14 K2 2.861(4) .
O14 K1 3.132(4) 2_655
O15 K4 2.768(4) .
O15 K2 3.359(4) 4_566
O16 K1 2.786(4) 2
O16 K3 2.934(4) 2_655
O17 K1 2.742(4) 2_655
O17 K3 2.969(4) 2_755
O17 H17 0.83(2) .
O18 K4 3.049(4) .
O18 K3 3.143(4) 4_566
O18 H18 0.83(2) .
OW1 K4 2.816(5) 4_566
OW1 K1 2.826(4) .
OW1 K3 3.042(4) 4_466
OW1 HW1A 0.81(2) .
OW1 HW1B 0.82(2) .
OW2 K3 2.725(5) .
OW2 K2 2.737(5) .
OW2 K4 2.767(5) .
OW2 HW2A 0.84(2) .
OW2 HW2B 0.84(2) .
K1 F2 2.704(3) 4_566
K1 F1 2.726(3) 4_566
K1 O17 2.742(4) 2_645
K1 O16 2.786(4) 2_545
K1 O7 2.854(4) 4_566
K1 O12 2.856(3) 4_566
K1 O12 3.086(4) 2_545
K1 O14 3.132(4) 2_645
K1 P2 3.559(2) 2_545
K1 P3 3.5918(19) 2_645
K1 Ge1 3.695(2) 4_566
K2 F1 2.653(3) 1_655
K2 F2 2.743(3) 3_665
K2 O10 2.774(4) 3_665
K2 O9 2.864(3) 3_665
K2 O15 3.359(4) 4_565
K2 Ge1 3.5202(16) 3_665
K2 Ge2 3.651(2) 1_655
K2 HW2B 2.70(8) .
K3 F1 2.756(3) 1_655
K3 O11 2.884(4) 1_655
K3 O6 2.892(4) 4_565
K3 O5 2.933(4) 2_745
K3 O16 2.934(4) 2_645
K3 O17 2.969(4) 2_745
K3 OW1 3.042(4) 4_665
K3 O18 3.143(4) 4_565
K3 O3 3.423(4) 2_645
K3 P3 3.497(2) 2_745
K3 HW2A 2.64(8) .
K4 OW1 2.816(5) 4_565
K4 O1 2.976(4) 4_565
K4 O9 3.068(4) 2_645
K4 O10 3.193(4) 2_645
K4 O2 3.382(4) 2_645
K4 P2 3.566(2) 2_645
K4 HW2A 2.74(8) .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O2 H2 O6 0.82(2) 1.92(3) 2.711(5) 164(8) .
O4 H4 O1 0.82(2) 2.34(6) 2.958(5) 133(6) .
O4 H4 O3 0.82(2) 2.14(5) 2.800(5) 137(7) .
O17 H17 O15 0.83(2) 1.62(2) 2.448(5) 172(8) 2_655
O18 H18 O16 0.83(2) 1.60(3) 2.413(5) 168(8) 2_645
OW1 HW1A O11 0.81(2) 2.47(4) 3.221(5) 155(7) .
OW1 HW1A O13 0.81(2) 2.48(5) 3.146(5) 141(7) 1_455
OW1 HW1B O5 0.82(2) 2.02(3) 2.804(5) 162(8) 3_666
OW2 HW2A O3 0.84(2) 1.92(2) 2.766(6) 176(8) 2_645
OW2 HW2B O15 0.84(2) 2.03(4) 2.808(6) 154(7) 4_565
