#------------------------------------------------------------------------------
#$Date: 2016-02-13 14:50:18 +0200 (Sat, 13 Feb 2016) $
#$Revision: 176428 $
#$URL: svn://www.crystallography.net/cod/cif/4/34/34/4343466.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4343466
loop_
_publ_author_name
'Wächtler, Erik'
'Privér, Steven H'
'Wagler, Jörg'
'Heine, Thomas'
'Zhechkov, Lyuben'
'Bennett, Martin A.'
'Bhargava, Suresh K.'
_publ_contact_author
;
 Wächtler, Erik 
 Institut für Anorganische Chemie  
 Technische Universität Bergakademie Freiberg
 Leipziger Str. 29 
 09596 Freiberg 
 Bundesrepublik Deutschland
;
_publ_section_title
;
 Metallophilic Contacts in 2-C6F4PPh2 Bridged Heterobinuclear Complexes: A
 Crystallographic and Computational Study.
;
_journal_issue                   14
_journal_name_full               'Inorganic chemistry'
_journal_page_first              6947
_journal_page_last               6957
_journal_paper_doi               10.1021/acs.inorgchem.5b00939
_journal_volume                  54
_journal_year                    2015
_chemical_formula_moiety         'C42 H38 Au Cl F8 P4 Pd'
_chemical_formula_sum            'C42 H38 Au Cl F8 P4 Pd'
_chemical_formula_weight         1157.42
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           62
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2ac 2n'
_symmetry_space_group_name_H-M   'P n m a'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   12.1772(10)
_cell_length_b                   24.117(2)
_cell_length_c                   14.2573(12)
_cell_measurement_reflns_used    3896
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      29.49
_cell_measurement_theta_min      2.36
_cell_volume                     4187.0(6)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0608
_diffrn_reflns_av_sigmaI/netI    0.0553
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       33
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            23299
_diffrn_reflns_theta_full        30.00
_diffrn_reflns_theta_max         30.00
_diffrn_reflns_theta_min         1.66
_exptl_absorpt_coefficient_mu    4.213
_exptl_absorpt_correction_T_max  0.7463
_exptl_absorpt_correction_T_min  0.6101
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.836
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       piece
_exptl_crystal_F_000             2256
_exptl_crystal_size_max          0.11
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.05
_refine_diff_density_max         0.906
_refine_diff_density_min         -1.479
_refine_diff_density_rms         0.150
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.010
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     271
_refine_ls_number_reflns         6229
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.010
_refine_ls_R_factor_all          0.0527
_refine_ls_R_factor_gt           0.0337
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0250P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0613
_refine_ls_wR_factor_ref         0.0650
_reflns_number_gt                4979
_reflns_number_total             6229
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic5b00939_si_002.cif
_cod_data_source_block           16
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Orthorhombic' changed to
'orthorhombic' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

'_exptl_absorpt_correction_type' value 'MULTI-SCAN' changed to
'multi-scan' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 3271 2015-04-21 07:52:19Z andrius 

 Adding full bibliography for 4343462--4343474.cif.
;
_cod_original_sg_symbol_Hall     -P2ac2n
_cod_original_sg_symbol_H-M      'Pnma '
_cod_database_code               4343466
#BEGIN Tags that were not found in dictionaries:
#END Tags that were not found in dictionaries
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z'
'x+1/2, -y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z'
'-x-1/2, y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Au1 Au 0.017996(15) 0.7500 0.871219(12) 0.01444(5) Uani 1 2 d S
Pd1 Pd 0.15501(3) 0.7500 1.03623(2) 0.01118(7) Uani 1 2 d S
Cl1 Cl 0.10836(10) 0.7500 0.70118(8) 0.0216(3) Uani 1 2 d S
P1 P -0.00313(7) 0.84429(4) 0.90551(6) 0.01417(17) Uani 1 1 d .
P2 P 0.30230(10) 0.7500 0.93294(8) 0.0142(2) Uani 1 2 d S
P3 P 0.03748(10) 0.7500 1.16492(8) 0.0166(3) Uani 1 2 d S
F1 F 0.08166(19) 0.96603(9) 0.92266(16) 0.0323(6) Uani 1 1 d .
F2 F 0.2459(2) 1.00354(9) 1.02943(16) 0.0367(6) Uani 1 1 d .
F3 F 0.35384(18) 0.93435(10) 1.14707(15) 0.0334(6) Uani 1 1 d .
F4 F 0.30228(16) 0.82675(9) 1.15496(13) 0.0233(5) Uani 1 1 d .
C1 C 0.1666(3) 0.83529(14) 1.0346(2) 0.0144(6) Uani 1 1 d .
C2 C 0.1104(3) 0.87261(14) 0.9751(2) 0.0151(6) Uani 1 1 d .
C3 C 0.1363(3) 0.92846(15) 0.9757(2) 0.0201(7) Uani 1 1 d .
C4 C 0.2192(3) 0.94937(14) 1.0315(2) 0.0226(8) Uani 1 1 d .
C5 C 0.2743(3) 0.91410(16) 1.0916(2) 0.0221(8) Uani 1 1 d .
C6 C 0.2455(3) 0.85885(15) 1.0928(2) 0.0181(7) Uani 1 1 d .
C7 C -0.0238(3) 0.89067(14) 0.8061(2) 0.0163(6) Uani 1 1 d .
C8 C 0.0576(3) 0.89386(16) 0.7372(3) 0.0243(8) Uani 1 1 d .
H8 H 0.1217 0.8716 0.7421 0.029 Uiso 1 1 calc R
C9 C 0.0451(3) 0.92931(17) 0.6619(3) 0.0284(9) Uani 1 1 d .
H9 H 0.1017 0.9319 0.6162 0.034 Uiso 1 1 calc R
C10 C -0.0488(3) 0.96118(17) 0.6519(3) 0.0305(9) Uani 1 1 d .
H10 H -0.0568 0.9853 0.5997 0.037 Uiso 1 1 calc R
C11 C -0.1312(3) 0.95752(17) 0.7193(3) 0.0315(9) Uani 1 1 d .
H11 H -0.1963 0.9789 0.7127 0.038 Uiso 1 1 calc R
C12 C -0.1182(3) 0.92267(16) 0.7960(3) 0.0244(8) Uani 1 1 d .
H12 H -0.1744 0.9206 0.8421 0.029 Uiso 1 1 calc R
C13 C -0.1225(3) 0.85751(14) 0.9786(2) 0.0171(7) Uani 1 1 d .
C14 C -0.2219(3) 0.83242(16) 0.9524(3) 0.0236(8) Uani 1 1 d .
H14 H -0.2240 0.8080 0.9002 0.028 Uiso 1 1 calc R
C15 C -0.3165(3) 0.84331(18) 1.0024(3) 0.0318(9) Uani 1 1 d .
H15 H -0.3838 0.8265 0.9843 0.038 Uiso 1 1 calc R
C16 C -0.3137(3) 0.87882(18) 1.0790(3) 0.0341(10) Uani 1 1 d .
H16 H -0.3794 0.8867 1.1125 0.041 Uiso 1 1 calc R
C17 C -0.2158(3) 0.90278(17) 1.1069(3) 0.0306(9) Uani 1 1 d .
H17 H -0.2137 0.9259 1.1608 0.037 Uiso 1 1 calc R
C18 C -0.1205(3) 0.89295(15) 1.0562(2) 0.0209(7) Uani 1 1 d .
H18 H -0.0538 0.9104 1.0742 0.025 Uiso 1 1 calc R
C19 C 0.4278(4) 0.7500 1.0015(4) 0.0274(13) Uani 1 2 d S
H19A H 0.4279 0.7180 1.0438 0.041 Uiso 0.50 1 d PR
H19B H 0.4320 0.7842 1.0383 0.041 Uiso 0.50 1 d PR
H19C H 0.4912 0.7500 0.9593 0.041 Uiso 1 2 d SR
C20 C 0.3215(3) 0.80822(15) 0.8543(2) 0.0215(8) Uani 1 1 d .
H20A H 0.3219 0.8428 0.8905 0.032 Uiso 1 1 calc R
H20B H 0.2614 0.8092 0.8086 0.032 Uiso 1 1 calc R
H20C H 0.3916 0.8042 0.8212 0.032 Uiso 1 1 calc R
C21 C 0.0575(3) 0.80839(18) 1.2432(3) 0.0318(10) Uani 1 1 d .
H21A H 0.0108 0.8039 1.2987 0.048 Uiso 1 1 calc R
H21B H 0.0378 0.8428 1.2107 0.048 Uiso 1 1 calc R
H21C H 0.1346 0.8100 1.2626 0.048 Uiso 1 1 calc R
C22 C -0.1117(4) 0.7500 1.1497(3) 0.0200(10) Uani 1 2 d S
H22A H -0.1361 0.7871 1.1306 0.030 Uiso 0.50 1 calc PR
H22B H -0.1471 0.7399 1.2090 0.030 Uiso 0.50 1 calc PR
H22C H -0.1319 0.7231 1.1012 0.030 Uiso 0.50 1 calc PR
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
P1 Au1 P1 152.69(4) 7_575 .
P1 Au1 Cl1 103.63(2) 7_575 .
P1 Au1 Cl1 103.63(2) . .
P1 Au1 Pd1 83.87(2) 7_575 .
P1 Au1 Pd1 83.87(2) . .
Cl1 Au1 Pd1 120.24(3) . .
C1 Pd1 C1 172.02(17) . 7_575
C1 Pd1 P2 86.56(8) . .
C1 Pd1 P2 86.56(8) 7_575 .
C1 Pd1 P3 92.92(8) . .
C1 Pd1 P3 92.92(8) 7_575 .
P2 Pd1 P3 167.34(4) . .
C1 Pd1 Au1 91.76(9) . .
C1 Pd1 Au1 91.76(9) 7_575 .
P2 Pd1 Au1 85.96(3) . .
P3 Pd1 Au1 106.70(3) . .
C13 P1 C7 103.19(15) . .
C13 P1 C2 103.15(15) . .
C7 P1 C2 107.21(15) . .
C13 P1 Au1 112.23(12) . .
C7 P1 Au1 116.69(11) . .
C2 P1 Au1 113.08(11) . .
C20 P2 C20 101.6(2) 7_575 .
C20 P2 C19 102.99(15) 7_575 .
C20 P2 C19 102.99(15) . .
C20 P2 Pd1 119.49(12) 7_575 .
C20 P2 Pd1 119.49(12) . .
C19 P2 Pd1 108.01(17) . .
C21 P3 C21 101.9(3) . 7_575
C21 P3 C22 101.92(16) . .
C21 P3 C22 101.92(16) 7_575 .
C21 P3 Pd1 113.76(13) . .
C21 P3 Pd1 113.76(13) 7_575 .
C22 P3 Pd1 121.12(16) . .
C6 C1 C2 115.6(3) . .
C6 C1 Pd1 116.7(2) . .
C2 C1 Pd1 127.5(2) . .
C3 C2 C1 120.4(3) . .
C3 C2 P1 122.6(3) . .
C1 C2 P1 116.9(3) . .
F1 C3 C4 115.9(3) . .
F1 C3 C2 122.3(3) . .
C4 C3 C2 121.7(3) . .
F2 C4 C3 121.2(3) . .
F2 C4 C5 119.6(3) . .
C3 C4 C5 119.2(3) . .
F3 C5 C6 121.9(3) . .
F3 C5 C4 119.5(3) . .
C6 C5 C4 118.6(3) . .
F4 C6 C5 115.3(3) . .
F4 C6 C1 120.4(3) . .
C5 C6 C1 124.3(3) . .
C12 C7 C8 118.8(3) . .
C12 C7 P1 122.3(3) . .
C8 C7 P1 118.9(3) . .
C9 C8 C7 120.2(4) . .
C9 C8 H8 119.9 . .
C7 C8 H8 119.9 . .
C8 C9 C10 120.9(4) . .
C8 C9 H9 119.5 . .
C10 C9 H9 119.5 . .
C9 C10 C11 119.3(3) . .
C9 C10 H10 120.4 . .
C11 C10 H10 120.4 . .
C12 C11 C10 120.0(4) . .
C12 C11 H11 120.0 . .
C10 C11 H11 120.0 . .
C11 C12 C7 120.7(3) . .
C11 C12 H12 119.6 . .
C7 C12 H12 119.6 . .
C18 C13 C14 119.3(3) . .
C18 C13 P1 123.2(3) . .
C14 C13 P1 117.4(3) . .
C15 C14 C13 120.0(4) . .
C15 C14 H14 120.0 . .
C13 C14 H14 120.0 . .
C14 C15 C16 120.2(4) . .
C14 C15 H15 119.9 . .
C16 C15 H15 119.9 . .
C17 C16 C15 120.3(4) . .
C17 C16 H16 119.8 . .
C15 C16 H16 119.8 . .
C16 C17 C18 120.0(4) . .
C16 C17 H17 120.0 . .
C18 C17 H17 120.0 . .
C17 C18 C13 120.2(4) . .
C17 C18 H18 119.9 . .
C13 C18 H18 119.9 . .
P2 C19 H19A 109.5 . .
P2 C19 H19B 109.5 . .
H19A C19 H19B 109.5 . .
P2 C19 H19C 109.5 . .
H19A C19 H19C 112.2 . .
H19B C19 H19C 106.7 . .
P2 C20 H20A 109.5 . .
P2 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
P2 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
P3 C21 H21A 109.5 . .
P3 C21 H21B 109.5 . .
H21A C21 H21B 109.5 . .
P3 C21 H21C 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
P3 C22 H22A 109.5 . .
P3 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
P3 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Au1 P1 2.3401(9) 7_575
Au1 P1 2.3401(9) .
Au1 Cl1 2.6623(12) .
Au1 Pd1 2.8842(4) .
Pd1 C1 2.062(3) .
Pd1 C1 2.062(3) 7_575
Pd1 P2 2.3207(12) .
Pd1 P3 2.3270(12) .
P1 C13 1.817(3) .
P1 C7 1.822(3) .
P1 C2 1.834(3) .
P2 C20 1.812(3) 7_575
P2 C20 1.812(3) .
P2 C19 1.813(5) .
P3 C21 1.814(4) .
P3 C21 1.814(4) 7_575
P3 C22 1.830(5) .
F1 C3 1.355(4) .
F2 C4 1.347(4) .
F3 C5 1.342(4) .
F4 C6 1.365(4) .
C1 C6 1.390(4) .
C1 C2 1.414(4) .
C2 C3 1.383(5) .
C3 C4 1.380(5) .
C4 C5 1.381(5) .
C5 C6 1.378(5) .
C7 C12 1.393(5) .
C7 C8 1.398(5) .
C8 C9 1.381(5) .
C8 H8 0.9500 .
C9 C10 1.385(6) .
C9 H9 0.9500 .
C10 C11 1.392(5) .
C10 H10 0.9500 .
C11 C12 1.388(5) .
C11 H11 0.9500 .
C12 H12 0.9500 .
C13 C18 1.398(5) .
C13 C14 1.404(5) .
C14 C15 1.381(5) .
C14 H14 0.9500 .
C15 C16 1.389(6) .
C15 H15 0.9500 .
C16 C17 1.384(6) .
C16 H16 0.9500 .
C17 C18 1.387(5) .
C17 H17 0.9500 .
C18 H18 0.9500 .
C19 H19A 0.9800 .
C19 H19B 0.9800 .
C19 H19C 0.9785 .
C20 H20A 0.9800 .
C20 H20B 0.9800 .
C20 H20C 0.9800 .
C21 H21A 0.9800 .
C21 H21B 0.9800 .
C21 H21C 0.9800 .
C22 H22A 0.9800 .
C22 H22B 0.9800 .
C22 H22C 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
P1 Au1 Pd1 C1 -171.35(9) 7_575 .
P1 Au1 Pd1 C1 -15.80(9) . .
Cl1 Au1 Pd1 C1 86.42(8) . .
P1 Au1 Pd1 C1 15.80(9) 7_575 7_575
P1 Au1 Pd1 C1 171.35(9) . 7_575
Cl1 Au1 Pd1 C1 -86.42(8) . 7_575
P1 Au1 Pd1 P2 102.22(2) 7_575 .
P1 Au1 Pd1 P2 -102.22(2) . .
Cl1 Au1 Pd1 P2 0.0 . .
P1 Au1 Pd1 P3 -77.78(2) 7_575 .
P1 Au1 Pd1 P3 77.78(2) . .
Cl1 Au1 Pd1 P3 180.0 . .
P1 Au1 P1 C13 -28.43(16) 7_575 .
Cl1 Au1 P1 C13 148.13(12) . .
Pd1 Au1 P1 C13 -92.19(12) . .
P1 Au1 P1 C7 -147.20(13) 7_575 .
Cl1 Au1 P1 C7 29.36(13) . .
Pd1 Au1 P1 C7 149.04(13) . .
P1 Au1 P1 C2 87.76(14) 7_575 .
Cl1 Au1 P1 C2 -95.68(12) . .
Pd1 Au1 P1 C2 24.00(11) . .
C1 Pd1 P2 C20 -154.93(17) . 7_575
C1 Pd1 P2 C20 29.10(16) 7_575 7_575
P3 Pd1 P2 C20 117.09(14) . 7_575
Au1 Pd1 P2 C20 -62.91(14) . 7_575
C1 Pd1 P2 C20 -29.10(16) . .
C1 Pd1 P2 C20 154.93(17) 7_575 .
P3 Pd1 P2 C20 -117.09(14) . .
Au1 Pd1 P2 C20 62.91(14) . .
C1 Pd1 P2 C19 87.98(9) . .
C1 Pd1 P2 C19 -87.98(9) 7_575 .
P3 Pd1 P2 C19 0.000(1) . .
Au1 Pd1 P2 C19 180.0 . .
C1 Pd1 P3 C21 -29.25(19) . .
C1 Pd1 P3 C21 145.31(18) 7_575 .
P2 Pd1 P3 C21 58.03(16) . .
Au1 Pd1 P3 C21 -121.97(16) . .
C1 Pd1 P3 C21 -145.31(18) . 7_575
C1 Pd1 P3 C21 29.25(19) 7_575 7_575
P2 Pd1 P3 C21 -58.03(16) . 7_575
Au1 Pd1 P3 C21 121.97(16) . 7_575
C1 Pd1 P3 C22 92.72(9) . .
C1 Pd1 P3 C22 -92.72(9) 7_575 .
P2 Pd1 P3 C22 180.0 . .
Au1 Pd1 P3 C22 0.000(1) . .
P2 Pd1 C1 C6 -81.7(2) . .
P3 Pd1 C1 C6 85.6(2) . .
Au1 Pd1 C1 C6 -167.6(2) . .
P2 Pd1 C1 C2 92.1(3) . .
P3 Pd1 C1 C2 -100.5(3) . .
Au1 Pd1 C1 C2 6.3(3) . .
C6 C1 C2 C3 1.2(5) . .
Pd1 C1 C2 C3 -172.8(3) . .
C6 C1 C2 P1 -174.3(2) . .
Pd1 C1 C2 P1 11.7(4) . .
C13 P1 C2 C3 -82.0(3) . .
C7 P1 C2 C3 26.5(3) . .
Au1 P1 C2 C3 156.6(3) . .
C13 P1 C2 C1 93.4(3) . .
C7 P1 C2 C1 -158.1(2) . .
Au1 P1 C2 C1 -28.1(3) . .
C1 C2 C3 F1 -177.3(3) . .
P1 C2 C3 F1 -2.1(5) . .
C1 C2 C3 C4 2.0(5) . .
P1 C2 C3 C4 177.2(3) . .
F1 C3 C4 F2 -2.7(5) . .
C2 C3 C4 F2 177.9(3) . .
F1 C3 C4 C5 176.3(3) . .
C2 C3 C4 C5 -3.1(6) . .
F2 C4 C5 F3 0.0(5) . .
C3 C4 C5 F3 -179.0(3) . .
F2 C4 C5 C6 179.9(3) . .
C3 C4 C5 C6 0.8(6) . .
F3 C5 C6 F4 0.9(5) . .
C4 C5 C6 F4 -179.0(3) . .
F3 C5 C6 C1 -177.6(3) . .
C4 C5 C6 C1 2.5(6) . .
C2 C1 C6 F4 178.1(3) . .
Pd1 C1 C6 F4 -7.3(4) . .
C2 C1 C6 C5 -3.5(5) . .
Pd1 C1 C6 C5 171.1(3) . .
C13 P1 C7 C12 -4.4(3) . .
C2 P1 C7 C12 -112.9(3) . .
Au1 P1 C7 C12 119.1(3) . .
C13 P1 C7 C8 176.2(3) . .
C2 P1 C7 C8 67.7(3) . .
Au1 P1 C7 C8 -60.2(3) . .
C12 C7 C8 C9 1.7(5) . .
P1 C7 C8 C9 -178.9(3) . .
C7 C8 C9 C10 -1.6(6) . .
C8 C9 C10 C11 0.4(6) . .
C9 C10 C11 C12 0.8(6) . .
C10 C11 C12 C7 -0.7(6) . .
C8 C7 C12 C11 -0.6(6) . .
P1 C7 C12 C11 -179.9(3) . .
C7 P1 C13 C18 -98.3(3) . .
C2 P1 C13 C18 13.3(3) . .
Au1 P1 C13 C18 135.3(3) . .
C7 P1 C13 C14 78.9(3) . .
C2 P1 C13 C14 -169.6(3) . .
Au1 P1 C13 C14 -47.6(3) . .
C18 C13 C14 C15 0.7(5) . .
P1 C13 C14 C15 -176.6(3) . .
C13 C14 C15 C16 -0.3(6) . .
C14 C15 C16 C17 -1.2(6) . .
C15 C16 C17 C18 2.3(6) . .
C16 C17 C18 C13 -2.0(6) . .
C14 C13 C18 C17 0.5(5) . .
P1 C13 C18 C17 177.6(3) . .
