#------------------------------------------------------------------------------
#$Date: 2017-07-25 02:22:46 +0300 (Tue, 25 Jul 2017) $
#$Revision: 198943 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/34/59/4345910.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4345910
loop_
_publ_author_name
'Schneider, Leon'
'Sivchik, Vasily'
'Chung, Kun-You'
'Chen, Yi-Ting'
'Karttunen, Antti J.'
'Chou, Pi-Tai'
'Koshevoy, Igor O.'
_publ_section_title
;
 Cyclometalated Platinum(II) Cyanometallates: Luminescent Blocks for
 Coordination Self-Assembly.
;
_journal_name_full               'Inorganic chemistry'
_journal_paper_doi               10.1021/acs.inorgchem.7b00006
_journal_year                    2017
_chemical_formula_moiety         'C98 H76 Cu2 N6 P4 Pt2'
_chemical_formula_sum            'C98 H76 Cu2 N6 P4 Pt2'
_chemical_formula_weight         1978.78
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_cell_angle_alpha                98.9770(10)
_cell_angle_beta                 99.1600(10)
_cell_angle_gamma                114.7450(10)
_cell_formula_units_Z            1
_cell_length_a                   11.4119(3)
_cell_length_b                   12.5448(3)
_cell_length_c                   16.9820(4)
_cell_measurement_reflns_used    9653
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      32.30
_cell_measurement_theta_min      2.36
_cell_volume                     2111.47(9)
_computing_cell_refinement       'SAINT (Bruker AXS, 2009)'
_computing_data_collection       'APEX2 (Bruker AXS, 2010)'
_computing_data_reduction        'SAINT (Bruker AXS, 2009)'
_computing_molecular_graphics    'Diamond v.4.03 (Brandenburg, 2014)'
_computing_publication_material  'SHELXL-2014 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-2014 (Sheldrick, 2014)'
_diffrn_ambient_temperature      150(2)
_diffrn_detector_area_resol_mean 16
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device
'62mm x 62mm CCD camera on three-circle goniostat'
_diffrn_measurement_device_type  'Bruker SMART APEX II CCD'
_diffrn_measurement_method       'φ scans and ω scans'
_diffrn_radiation_monochromator  'flat graphite crystal'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0324
_diffrn_reflns_av_unetI/netI     0.0263
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            109141
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         34.996
_diffrn_reflns_theta_min         1.254
_exptl_absorpt_coefficient_mu    3.926
_exptl_absorpt_correction_T_max  0.568
_exptl_absorpt_correction_T_min  0.255
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'SADABS (Sheldrick, 2008)'
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    1.556
_exptl_crystal_description       block
_exptl_crystal_F_000             980
_exptl_crystal_size_max          0.370
_exptl_crystal_size_mid          0.324
_exptl_crystal_size_min          0.144
_refine_diff_density_max         1.686
_refine_diff_density_min         -1.097
_refine_diff_density_rms         0.093
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.031
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     579
_refine_ls_number_reflns         18586
_refine_ls_number_restraints     36
_refine_ls_restrained_S_all      1.033
_refine_ls_R_factor_all          0.0338
_refine_ls_R_factor_gt           0.0247
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0243P)²+0.6480P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0496
_refine_ls_wR_factor_ref         0.0521
_reflns_Friedel_coverage         0.000
_reflns_number_gt                16180
_reflns_number_total             18586
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ic7b00006_si_003.cif
_cod_data_source_block           1
_cod_original_cell_volume        2111.46(9)
_cod_database_code               4345910
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.324
_shelx_estimated_absorpt_t_max   0.602
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C2 C 0.12838(17) 0.42211(15) 0.10020(9) 0.0234(3) Uani 1 1 d . . . . .
C1 C 0.02611(17) 0.29139(15) -0.06786(10) 0.0239(3) Uani 1 1 d . . . . .
C3 C 0.22050(16) 0.24789(14) 0.13449(9) 0.0213(3) Uani 1 1 d . . . . .
C4 C 0.26120(19) 0.31410(18) 0.21576(11) 0.0317(4) Uani 1 1 d . . . . .
H4 H 0.2473 0.3837 0.2288 0.038 Uiso 1 1 calc R U . . .
C5 C 0.3218(2) 0.2811(2) 0.27850(12) 0.0410(5) Uani 1 1 d . . . . .
H5 H 0.3483 0.3274 0.3338 0.049 Uiso 1 1 calc R U . . .
C6 C 0.3433(3) 0.1806(2) 0.26021(13) 0.0480(6) Uani 1 1 d . . . . .
H6 H 0.3862 0.1585 0.3028 0.058 Uiso 1 1 calc R U . . .
C7 C 0.3026(2) 0.1124(2) 0.18030(13) 0.0380(4) Uani 1 1 d . . . . .
H7 H 0.3163 0.0427 0.1678 0.046 Uiso 1 1 calc R U . . .
C8 C 0.24110(17) 0.14570(15) 0.11766(10) 0.0248(3) Uani 1 1 d . . . . .
C9 C 0.19370(16) 0.07814(14) 0.03115(10) 0.0237(3) Uani 1 1 d . . . . .
C10 C 0.20511(19) -0.02587(16) 0.00112(12) 0.0317(4) Uani 1 1 d . . . . .
H10 H 0.2451 -0.0582 0.0377 0.038 Uiso 1 1 calc R U . . .
C11 C 0.1582(2) -0.08206(17) -0.08189(14) 0.0366(4) Uani 1 1 d . . . . .
H11 H 0.1655 -0.1532 -0.1028 0.044 Uiso 1 1 calc R U . . .
C12 C 0.1006(2) -0.03378(17) -0.13425(12) 0.0356(4) Uani 1 1 d . . . . .
H12 H 0.0681 -0.0714 -0.1916 0.043 Uiso 1 1 calc R U . . .
C13 C 0.09044(19) 0.06955(16) -0.10282(12) 0.0308(4) Uani 1 1 d . . . . .
H13 H 0.0515 0.1028 -0.1392 0.037 Uiso 1 1 calc R U . . .
C14 C -0.4071(11) 0.1352(11) -0.2943(10) 0.0197(16) Uani 0.47(6) 1 d . . P A 1
C15 C -0.4525(14) 0.1810(13) -0.2341(10) 0.0339(19) Uani 0.47(6) 1 d . . P A 1
H15 H -0.4043 0.2643 -0.2059 0.041 Uiso 0.47(6) 1 calc R U P A 1
C16 C -0.5687(12) 0.1072(14) -0.2133(8) 0.0331(17) Uani 0.47(6) 1 d . . P A 1
H16 H -0.6005 0.1409 -0.1727 0.040 Uiso 0.47(6) 1 calc R U P A 1
C17 C -0.6355(10) -0.0128(11) -0.2516(8) 0.0328(18) Uani 0.47(6) 1 d . . P A 1
H17 H -0.7134 -0.0631 -0.2368 0.039 Uiso 0.47(6) 1 calc R U P A 1
C18 C -0.5921(11) -0.0622(11) -0.3113(8) 0.0300(17) Uani 0.47(6) 1 d . . P A 1
H18 H -0.6389 -0.1463 -0.3376 0.036 Uiso 0.47(6) 1 calc R U P A 1
C19 C -0.4777(10) 0.0133(8) -0.3332(8) 0.0203(16) Uani 0.47(6) 1 d . . P A 1
H19 H -0.4482 -0.0200 -0.3755 0.024 Uiso 0.47(6) 1 calc R U P A 1
C14A C -0.4048(10) 0.1456(12) -0.2841(10) 0.023(2) Uani 0.53(6) 1 d G . P A 2
C15A C -0.4473(10) 0.2030(17) -0.2266(8) 0.029(2) Uani 0.53(6) 1 d G . P A 2
H15A H -0.3947 0.2868 -0.2006 0.035 Uiso 0.53(6) 1 calc R U P A 2
C16A C -0.5666(10) 0.138(2) -0.2070(7) 0.046(3) Uani 0.53(6) 1 d G . P A 2
H16A H -0.5957 0.1771 -0.1676 0.056 Uiso 0.53(6) 1 calc R U P A 2
C17A C -0.6435(10) 0.015(2) -0.2449(8) 0.051(3) Uani 0.53(6) 1 d G . P A 2
H17A H -0.7251 -0.0294 -0.2315 0.062 Uiso 0.53(6) 1 calc R U P A 2
C18A C -0.6010(12) -0.0422(17) -0.3024(10) 0.046(3) Uani 0.53(6) 1 d G . P A 2
H18A H -0.6535 -0.1260 -0.3283 0.055 Uiso 0.53(6) 1 calc R U P A 2
C19A C -0.4816(12) 0.0230(12) -0.3220(11) 0.037(3) Uani 0.53(6) 1 d G . P A 2
H19A H -0.4526 -0.0163 -0.3613 0.044 Uiso 0.53(6) 1 calc R U P A 2
C20 C -0.21252(16) 0.13099(14) -0.37271(11) 0.0248(3) Uani 1 1 d . . . . .
C21 C -0.1531(3) 0.0778(2) -0.32520(16) 0.0503(6) Uani 1 1 d . . . . .
H21 H -0.1377 0.0984 -0.2670 0.060 Uiso 1 1 calc R U . . .
C22 C -0.1161(3) -0.0061(3) -0.3633(2) 0.0706(9) Uani 1 1 d . . . . .
H22 H -0.0764 -0.0429 -0.3307 0.085 Uiso 1 1 calc R U . . .
C23 C -0.1363(3) -0.0358(2) -0.4469(2) 0.0607(8) Uani 1 1 d . . . . .
H23 H -0.1084 -0.0913 -0.4720 0.073 Uiso 1 1 calc R U . . .
C24 C -0.1967(2) 0.01456(18) -0.49438(16) 0.0456(5) Uani 1 1 d . . . . .
H24 H -0.2125 -0.0072 -0.5526 0.055 Uiso 1 1 calc R U . . .
C25 C -0.23521(19) 0.09785(16) -0.45744(12) 0.0307(4) Uani 1 1 d . . . . .
H25 H -0.2775 0.1322 -0.4908 0.037 Uiso 1 1 calc R U . . .
C26 C -0.32599(15) 0.29532(13) -0.39520(9) 0.0188(3) Uani 1 1 d . . . . .
C27 C -0.44706(17) 0.22149(16) -0.45362(10) 0.0260(3) Uani 1 1 d . . . . .
H27 H -0.4954 0.1387 -0.4536 0.031 Uiso 1 1 calc R U . . .
C28 C -0.49684(19) 0.26869(18) -0.51158(11) 0.0335(4) Uani 1 1 d . . . . .
H28 H -0.5790 0.2179 -0.5512 0.040 Uiso 1 1 calc R U . . .
C29 C -0.4275(2) 0.38923(19) -0.51199(12) 0.0347(4) Uani 1 1 d . . . . .
H29 H -0.4616 0.4210 -0.5520 0.042 Uiso 1 1 calc R U . . .
C30 C -0.3088(2) 0.46305(17) -0.45405(12) 0.0349(4) Uani 1 1 d . . . . .
H30 H -0.2611 0.5459 -0.4541 0.042 Uiso 1 1 calc R U . . .
C31 C -0.25885(17) 0.41648(15) -0.39554(11) 0.0275(3) Uani 1 1 d . . . . .
H31 H -0.1777 0.4682 -0.3553 0.033 Uiso 1 1 calc R U . . .
C32 C 0.2084(3) 0.4301(2) -0.2748(2) 0.0278(14) Uani 0.562(5) 1 d G . P B 1
C33 C 0.1532(2) 0.3061(2) -0.2815(2) 0.0456(12) Uani 0.562(5) 1 d G . P B 1
H33 H 0.0714 0.2660 -0.2671 0.055 Uiso 0.562(5) 1 calc R U P B 1
C34 C 0.2177(3) 0.24075(18) -0.3093(3) 0.0623(17) Uani 0.562(5) 1 d G . P B 1
H34 H 0.1799 0.1560 -0.3139 0.075 Uiso 0.562(5) 1 calc R U P B 1
C35 C 0.3374(3) 0.2994(3) -0.3304(2) 0.0405(12) Uani 0.562(5) 1 d G . P B 1
H35 H 0.3815 0.2548 -0.3494 0.049 Uiso 0.562(5) 1 calc R U P B 1
C36 C 0.3926(3) 0.4235(3) -0.3237(2) 0.0486(13) Uani 0.562(5) 1 d G . P B 1
H36 H 0.4744 0.4636 -0.3381 0.058 Uiso 0.562(5) 1 calc R U P B 1
C37 C 0.3281(3) 0.4888(2) -0.2959(3) 0.0497(13) Uani 0.562(5) 1 d G . P B 1
H37 H 0.3658 0.5736 -0.2913 0.060 Uiso 0.562(5) 1 calc R U P B 1
C32A C 0.2058(4) 0.2845(5) -0.3745(3) 0.075(3) Uani 0.438(5) 1 d G U P B 2
H32A H 0.1585 0.2160 -0.4202 0.091 Uiso 0.438(5) 1 calc R U P B 2
C33A C 0.1397(3) 0.3440(4) -0.3405(3) 0.058(2) Uani 0.438(5) 1 d G U P B 2
H33A H 0.0473 0.3161 -0.3631 0.070 Uiso 0.438(5) 1 calc R U P B 2
C34A C 0.2089(4) 0.4442(4) -0.2736(2) 0.0221(15) Uani 0.438(5) 1 d G U P B 2
C37A C 0.3441(4) 0.4849(4) -0.2407(3) 0.060(2) Uani 0.438(5) 1 d G U P B 2
H37A H 0.3914 0.5534 -0.1949 0.072 Uiso 0.438(5) 1 calc R U P B 2
C36A C 0.4102(3) 0.4254(5) -0.2746(3) 0.068(2) Uani 0.438(5) 1 d G U P B 2
H36A H 0.5026 0.4533 -0.2520 0.081 Uiso 0.438(5) 1 calc R U P B 2
C35A C 0.3410(4) 0.3252(4) -0.3415(3) 0.0485(19) Uani 0.438(5) 1 d G U P B 2
H35A H 0.3862 0.2846 -0.3647 0.058 Uiso 0.438(5) 1 calc R U P B 2
C38 C 0.09506(16) 0.59869(14) -0.30756(10) 0.0233(3) Uani 1 1 d . . . . .
C39 C 0.1251(2) 0.5884(2) -0.38374(12) 0.0359(4) Uani 1 1 d . . . . .
H39 H 0.1653 0.5381 -0.3986 0.043 Uiso 1 1 calc R U . . .
C40 C 0.0966(2) 0.6517(2) -0.43845(13) 0.0429(5) Uani 1 1 d . . . . .
H40 H 0.1181 0.6445 -0.4902 0.052 Uiso 1 1 calc R U . . .
C41 C 0.0377(2) 0.72392(18) -0.41820(12) 0.0384(4) Uani 1 1 d . . . . .
H41 H 0.0178 0.7661 -0.4559 0.046 Uiso 1 1 calc R U . . .
C42 C 0.0073(2) 0.73525(16) -0.34214(12) 0.0347(4) Uani 1 1 d . . . . .
H42 H -0.0331 0.7856 -0.3278 0.042 Uiso 1 1 calc R U . . .
C43 C 0.03585(19) 0.67317(15) -0.28722(11) 0.0286(3) Uani 1 1 d . . . . .
H43 H 0.0150 0.6814 -0.2353 0.034 Uiso 1 1 calc R U . . .
C44 C 0.22925(16) 0.62955(14) -0.14434(10) 0.0242(3) Uani 1 1 d . . . . .
C45 C 0.33668(18) 0.73242(16) -0.15136(12) 0.0306(4) Uani 1 1 d . . . . .
H45 H 0.3509 0.7413 -0.2041 0.037 Uiso 1 1 calc R U . . .
C46 C 0.4226(2) 0.82164(17) -0.08120(13) 0.0378(4) Uani 1 1 d . . . . .
H46 H 0.4958 0.8913 -0.0861 0.045 Uiso 1 1 calc R U . . .
C47 C 0.4023(2) 0.80989(18) -0.00451(13) 0.0401(5) Uani 1 1 d . . . . .
H47 H 0.4620 0.8711 0.0432 0.048 Uiso 1 1 calc R U . . .
C48 C 0.2952(2) 0.70921(18) 0.00326(12) 0.0385(4) Uani 1 1 d . . . . .
H48 H 0.2809 0.7018 0.0562 0.046 Uiso 1 1 calc R U . . .
C49 C 0.20832(18) 0.61864(16) -0.06667(10) 0.0303(4) Uani 1 1 d . . . . .
H49 H 0.1349 0.5495 -0.0614 0.036 Uiso 1 1 calc R U . . .
N2 N 0.13227(15) 0.50564(13) 0.14248(9) 0.0260(3) Uani 1 1 d . . . . .
N1 N -0.02991(15) 0.30193(13) -0.12686(8) 0.0264(3) Uani 1 1 d . . . . .
N3 N 0.13518(15) 0.12517(13) -0.02043(9) 0.0264(3) Uani 1 1 d . . . . .
Cu1 Cu -0.08511(2) 0.38024(2) -0.21083(2) 0.01803(3) Uani 1 1 d . . . . .
Pt1 Pt 0.12472(2) 0.27700(2) 0.03486(2) 0.02007(2) Uani 1 1 d . . . . .
P1 P -0.25507(4) 0.24053(3) -0.31603(2) 0.01769(7) Uani 1 1 d . . . . .
P2 P 0.11241(4) 0.50929(4) -0.23480(2) 0.02046(7) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N2 C2 Pt1 176.28(14) . .
N1 C1 Pt1 178.79(14) . .
C4 C3 C8 117.75(14) . .
C4 C3 Pt1 127.70(12) . .
C8 C3 Pt1 114.48(11) . .
C3 C4 C5 121.54(18) . .
C3 C4 H4 119.2 . .
C5 C4 H4 119.2 . .
C6 C5 C4 119.73(19) . .
C6 C5 H5 120.1 . .
C4 C5 H5 120.1 . .
C7 C6 C5 119.98(18) . .
C7 C6 H6 120.0 . .
C5 C6 H6 120.0 . .
C6 C7 C8 120.00(18) . .
C6 C7 H7 120.0 . .
C8 C7 H7 120.0 . .
C3 C8 C7 120.98(16) . .
C3 C8 C9 115.29(14) . .
C7 C8 C9 123.73(16) . .
N3 C9 C10 120.85(16) . .
N3 C9 C8 114.59(14) . .
C10 C9 C8 124.56(15) . .
C11 C10 C9 119.93(17) . .
C11 C10 H10 120.0 . .
C9 C10 H10 120.0 . .
C10 C11 C12 119.30(17) . .
C10 C11 H11 120.4 . .
C12 C11 H11 120.4 . .
C11 C12 C13 119.59(18) . .
C11 C12 H12 120.2 . .
C13 C12 H12 120.2 . .
N3 C13 C12 121.58(18) . .
N3 C13 H13 119.2 . .
C12 C13 H13 119.2 . .
C15 C14 C19 118.2(6) . .
C15 C14 P1 117.1(8) . .
C19 C14 P1 124.7(8) . .
C14 C15 C16 121.3(7) . .
C14 C15 H15 119.4 . .
C16 C15 H15 119.4 . .
C17 C16 C15 119.5(7) . .
C17 C16 H16 120.2 . .
C15 C16 H16 120.2 . .
C16 C17 C18 120.9(6) . .
C16 C17 H17 119.6 . .
C18 C17 H17 119.6 . .
C17 C18 C19 119.1(7) . .
C17 C18 H18 120.5 . .
C19 C18 H18 120.5 . .
C14 C19 C18 121.0(7) . .
C14 C19 H19 119.5 . .
C18 C19 H19 119.5 . .
C15A C14A C19A 120.0 . .
C15A C14A P1 117.9(5) . .
C19A C14A P1 121.8(5) . .
C14A C15A C16A 120.0 . .
C14A C15A H15A 120.0 . .
C16A C15A H15A 120.0 . .
C15A C16A C17A 120.0 . .
C15A C16A H16A 120.0 . .
C17A C16A H16A 120.0 . .
C18A C17A C16A 120.0 . .
C18A C17A H17A 120.0 . .
C16A C17A H17A 120.0 . .
C17A C18A C19A 120.0 . .
C17A C18A H18A 120.0 . .
C19A C18A H18A 120.0 . .
C18A C19A C14A 120.0 . .
C18A C19A H19A 120.0 . .
C14A C19A H19A 120.0 . .
C25 C20 C21 118.68(18) . .
C25 C20 P1 125.42(13) . .
C21 C20 P1 115.90(15) . .
C20 C21 C22 119.8(2) . .
C20 C21 H21 120.1 . .
C22 C21 H21 120.1 . .
C23 C22 C21 120.9(2) . .
C23 C22 H22 119.5 . .
C21 C22 H22 119.5 . .
C22 C23 C24 119.8(2) . .
C22 C23 H23 120.1 . .
C24 C23 H23 120.1 . .
C23 C24 C25 120.1(2) . .
C23 C24 H24 120.0 . .
C25 C24 H24 120.0 . .
C20 C25 C24 120.7(2) . .
C20 C25 H25 119.6 . .
C24 C25 H25 119.6 . .
C31 C26 C27 118.63(14) . .
C31 C26 P1 118.47(11) . .
C27 C26 P1 122.86(12) . .
C28 C27 C26 120.25(16) . .
C28 C27 H27 119.9 . .
C26 C27 H27 119.9 . .
C29 C28 C27 120.41(16) . .
C29 C28 H28 119.8 . .
C27 C28 H28 119.8 . .
C30 C29 C28 119.75(16) . .
C30 C29 H29 120.1 . .
C28 C29 H29 120.1 . .
C29 C30 C31 120.11(17) . .
C29 C30 H30 119.9 . .
C31 C30 H30 119.9 . .
C26 C31 C30 120.83(16) . .
C26 C31 H31 119.6 . .
C30 C31 H31 119.6 . .
C33 C32 C37 120.0 . .
C33 C32 P2 116.01(14) . .
C37 C32 P2 123.99(14) . .
C34 C33 C32 120.0 . .
C34 C33 H33 120.0 . .
C32 C33 H33 120.0 . .
C35 C34 C33 120.0 . .
C35 C34 H34 120.0 . .
C33 C34 H34 120.0 . .
C34 C35 C36 120.0 . .
C34 C35 H35 120.0 . .
C36 C35 H35 120.0 . .
C37 C36 C35 120.0 . .
C37 C36 H36 120.0 . .
C35 C36 H36 120.0 . .
C36 C37 C32 120.0 . .
C36 C37 H37 120.0 . .
C32 C37 H37 120.0 . .
C33A C32A C35A 120.0 . .
C33A C32A H32A 120.0 . .
C35A C32A H32A 120.0 . .
C34A C33A C32A 120.0 . .
C34A C33A H33A 120.0 . .
C32A C33A H33A 120.0 . .
C33A C34A C37A 120.0 . .
C33A C34A P2 115.5(2) . .
C37A C34A P2 124.5(2) . .
C36A C37A C34A 120.0 . .
C36A C37A H37A 120.0 . .
C34A C37A H37A 120.0 . .
C35A C36A C37A 120.0 . .
C35A C36A H36A 120.0 . .
C37A C36A H36A 120.0 . .
C36A C35A C32A 120.0 . .
C36A C35A H35A 120.0 . .
C32A C35A H35A 120.0 . .
C39 C38 C43 118.69(16) . .
C39 C38 P2 124.42(14) . .
C43 C38 P2 116.60(12) . .
C38 C39 C40 120.33(19) . .
C38 C39 H39 119.8 . .
C40 C39 H39 119.8 . .
C41 C40 C39 120.58(19) . .
C41 C40 H40 119.7 . .
C39 C40 H40 119.7 . .
C40 C41 C42 119.72(18) . .
C40 C41 H41 120.1 . .
C42 C41 H41 120.1 . .
C43 C42 C41 120.12(19) . .
C43 C42 H42 119.9 . .
C41 C42 H42 119.9 . .
C42 C43 C38 120.55(17) . .
C42 C43 H43 119.7 . .
C38 C43 H43 119.7 . .
C49 C44 C45 119.43(15) . .
C49 C44 P2 118.77(13) . .
C45 C44 P2 121.79(13) . .
C46 C45 C44 119.91(18) . .
C46 C45 H45 120.0 . .
C44 C45 H45 120.0 . .
C47 C46 C45 120.46(18) . .
C47 C46 H46 119.8 . .
C45 C46 H46 119.8 . .
C46 C47 C48 120.24(17) . .
C46 C47 H47 119.9 . .
C48 C47 H47 119.9 . .
C47 C48 C49 119.93(19) . .
C47 C48 H48 120.0 . .
C49 C48 H48 120.0 . .
C44 C49 C48 120.02(17) . .
C44 C49 H49 120.0 . .
C48 C49 H49 120.0 . .
C2 N2 Cu1 164.04(15) . 2_565
C1 N1 Cu1 160.36(14) . .
C9 N3 C13 118.74(15) . .
C9 N3 Pt1 115.41(11) . .
C13 N3 Pt1 125.85(12) . .
N2 Cu1 N1 101.77(6) 2_565 .
N2 Cu1 P1 114.14(4) 2_565 .
N1 Cu1 P1 111.21(4) . .
N2 Cu1 P2 102.61(5) 2_565 .
N1 Cu1 P2 104.26(5) . .
P1 Cu1 P2 120.726(16) . .
C2 Pt1 C1 91.84(6) . .
C2 Pt1 C3 92.73(6) . .
C1 Pt1 C3 175.23(6) . .
C2 Pt1 N3 172.90(6) . .
C1 Pt1 N3 95.24(6) . .
C3 Pt1 N3 80.20(6) . .
C14 P1 C26 100.1(5) . .
C14 P1 C20 99.1(4) . .
C26 P1 C20 104.79(7) . .
C26 P1 C14A 101.6(5) . .
C20 P1 C14A 104.1(5) . .
C14 P1 Cu1 119.5(5) . .
C26 P1 Cu1 117.55(5) . .
C20 P1 Cu1 113.11(5) . .
C14A P1 Cu1 114.1(5) . .
C34A P2 C44 104.20(13) . .
C34A P2 C38 103.37(16) . .
C44 P2 C38 100.96(7) . .
C44 P2 C32 105.80(11) . .
C38 P2 C32 106.17(11) . .
C34A P2 Cu1 117.38(15) . .
C44 P2 Cu1 114.33(6) . .
C38 P2 Cu1 114.64(5) . .
C32 P2 Cu1 113.72(8) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C2 N2 1.154(2) .
C2 Pt1 1.9590(16) .
C1 N1 1.157(2) .
C1 Pt1 1.9963(16) .
C3 C4 1.388(2) .
C3 C8 1.393(2) .
C3 Pt1 2.0320(14) .
C4 C5 1.389(3) .
C4 H4 0.9500 .
C5 C6 1.381(3) .
C5 H5 0.9500 .
C6 C7 1.376(3) .
C6 H6 0.9500 .
C7 C8 1.394(2) .
C7 H7 0.9500 .
C8 C9 1.464(2) .
C9 N3 1.366(2) .
C9 C10 1.391(2) .
C10 C11 1.380(3) .
C10 H10 0.9500 .
C11 C12 1.380(3) .
C11 H11 0.9500 .
C12 C13 1.381(2) .
C12 H12 0.9500 .
C13 N3 1.369(2) .
C13 H13 0.9500 .
C14 C15 1.370(9) .
C14 C19 1.382(8) .
C14 P1 1.824(9) .
C15 C16 1.401(9) .
C15 H15 0.9500 .
C16 C17 1.358(11) .
C16 H16 0.9500 .
C17 C18 1.371(11) .
C17 H17 0.9500 .
C18 C19 1.403(7) .
C18 H18 0.9500 .
C19 H19 0.9500 .
C14A C15A 1.3900 .
C14A C19A 1.3900 .
C14A P1 1.850(7) .
C15A C16A 1.3900 .
C15A H15A 0.9500 .
C16A C17A 1.3900 .
C16A H16A 0.9500 .
C17A C18A 1.3900 .
C17A H17A 0.9500 .
C18A C19A 1.3900 .
C18A H18A 0.9500 .
C19A H19A 0.9500 .
C20 C25 1.384(3) .
C20 C21 1.389(3) .
C20 P1 1.8290(16) .
C21 C22 1.396(3) .
C21 H21 0.9500 .
C22 C23 1.366(5) .
C22 H22 0.9500 .
C23 C24 1.368(4) .
C23 H23 0.9500 .
C24 C25 1.395(3) .
C24 H24 0.9500 .
C25 H25 0.9500 .
C26 C31 1.388(2) .
C26 C27 1.399(2) .
C26 P1 1.8283(15) .
C27 C28 1.388(2) .
C27 H27 0.9500 .
C28 C29 1.384(3) .
C28 H28 0.9500 .
C29 C30 1.379(3) .
C29 H29 0.9500 .
C30 C31 1.391(2) .
C30 H30 0.9500 .
C31 H31 0.9500 .
C32 C33 1.3900 .
C32 C37 1.3900 .
C32 P2 1.8926(19) .
C33 C34 1.3900 .
C33 H33 0.9500 .
C34 C35 1.3900 .
C34 H34 0.9500 .
C35 C36 1.3900 .
C35 H35 0.9500 .
C36 C37 1.3900 .
C36 H36 0.9500 .
C37 H37 0.9500 .
C32A C33A 1.3900 .
C32A C35A 1.3900 .
C32A H32A 0.9500 .
C33A C34A 1.3900 .
C33A H33A 0.9500 .
C34A C37A 1.3900 .
C34A P2 1.769(3) .
C37A C36A 1.3900 .
C37A H37A 0.9500 .
C36A C35A 1.3900 .
C36A H36A 0.9500 .
C35A H35A 0.9500 .
C38 C39 1.391(2) .
C38 C43 1.397(2) .
C38 P2 1.8340(16) .
C39 C40 1.397(3) .
C39 H39 0.9500 .
C40 C41 1.370(3) .
C40 H40 0.9500 .
C41 C42 1.391(3) .
C41 H41 0.9500 .
C42 C43 1.387(2) .
C42 H42 0.9500 .
C43 H43 0.9500 .
C44 C49 1.395(2) .
C44 C45 1.397(2) .
C44 P2 1.8315(16) .
C45 C46 1.388(3) .
C45 H45 0.9500 .
C46 C47 1.378(3) .
C46 H46 0.9500 .
C47 C48 1.385(3) .
C47 H47 0.9500 .
C48 C49 1.395(2) .
C48 H48 0.9500 .
C49 H49 0.9500 .
N2 Cu1 2.0030(14) 2_565
N1 Cu1 2.0161(14) .
N3 Pt1 2.0473(14) .
Cu1 N2 2.0030(14) 2_565
Cu1 P1 2.2581(4) .
Cu1 P2 2.3044(4) .
