#------------------------------------------------------------------------------
#$Date: 2019-11-23 12:16:39 +0200 (Sat, 23 Nov 2019) $
#$Revision: 233252 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/34/86/4348672.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4348672
loop_
_publ_author_name
'Al-Balushi, Rayya A'
'Haque, Ashanul'
'Jayapal, Maharaja'
'Al-Suti, Mohammed K'
'Husband, John'
'Khan, Muhammad S.'
'Skelton, Jonathan M.'
'Molloy, Kieran C.'
'Raithby, Paul R.'
_publ_section_title
;
 Impact of the Alkyne Substitution Pattern and Metalation on the
 Photoisomerization of Azobenzene-Based Platinum(II) Diynes and Polyynes.
;
_journal_issue                   21
_journal_name_full               'Inorganic chemistry'
_journal_page_first              10955
_journal_page_last               10967
_journal_paper_doi               10.1021/acs.inorgchem.6b01509
_journal_volume                  55
_journal_year                    2016
_chemical_formula_moiety         'C52 H78 N2 P4 Pt2'
_chemical_formula_sum            'C52 H78 N2 P4 Pt2'
_chemical_formula_weight         1245.22
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_conform_dict_location     ftp://ftp.iucr.org/pub/cif_core.dic
_audit_conform_dict_name         cif_core.dic
_audit_conform_dict_version      2.4
_audit_creation_date             2011-12-20T18:04:47-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                92.353(3)
_cell_angle_beta                 93.954(3)
_cell_angle_gamma                94.633(3)
_cell_formula_units_Z            1
_cell_length_a                   8.9899(3)
_cell_length_b                   9.6169(3)
_cell_length_c                   15.8333(7)
_cell_measurement_reflns_used    8700
_cell_measurement_temperature    250(2)
_cell_measurement_theta_max      30.4383
_cell_measurement_theta_min      2.9786
_cell_volume                     1359.65(9)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      250(2)
_diffrn_detector_area_resol_mean 10.3795
_diffrn_measured_fraction_theta_full 0.99
_diffrn_measured_fraction_theta_max 0.935
_diffrn_measurement_device_type  'Xcalibur, Atlas, Gemini ultra'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0363
_diffrn_reflns_av_unetI/netI     0.0433
_diffrn_reflns_Laue_measured_fraction_full 0.99
_diffrn_reflns_Laue_measured_fraction_max 0.935
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            23252
_diffrn_reflns_point_group_measured_fraction_full 0.99
_diffrn_reflns_point_group_measured_fraction_max 0.935
_diffrn_reflns_theta_full        25.0
_diffrn_reflns_theta_max         30.51
_diffrn_reflns_theta_min         2.98
_exptl_absorpt_coefficient_mu    5.29
_exptl_absorpt_correction_T_max  0.791
_exptl_absorpt_correction_T_min  0.308
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.11 (release 16-05-2011 CrysAlis171 .NET)
(compiled May 16 2011,17:55:39)
Analytical numeric absorption correction using a multifaceted crystal
			model based on expressions derived by R.C. Clark & J.S. Reid.
(Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
;
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.521
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             620
_exptl_crystal_size_max          0.3393
_exptl_crystal_size_mid          0.1903
_exptl_crystal_size_min          0.0443
_refine_diff_density_max         1.736
_refine_diff_density_min         -1.754
_refine_diff_density_rms         0.119
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.042
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     334
_refine_ls_number_reflns         8278
_refine_ls_number_restraints     51
_refine_ls_restrained_S_all      1.039
_refine_ls_R_factor_all          0.0545
_refine_ls_R_factor_gt           0.0397
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0379P)²+1.1281P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0809
_refine_ls_wR_factor_ref         0.0879
_reflns_number_gt                6846
_reflns_number_total             8278
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic6b01509_si_003.cif
_cod_data_source_block           136
_cod_database_code               4348672
_olex2_refinement_description
;
1. Others
 Fixed Uiso: H4(0.053) H5(0.052) H7(0.058) H8(0.057) H10(0.076) H11(0.088)
 H12(0.077) H13(0.068) H14(0.056) H15A(0.117) H15B(0.117) H16A(0.183)
 H16B(0.183) H16C(0.183) H17A(0.111) H17B(0.111) H18A(0.168) H18B(0.168)
 H18C(0.168) H19A(0.162) H19B(0.162) H20A(0.268) H20B(0.268) H20C(0.268)
 H21A(0.097) H21B(0.097) H21C(0.097) H21D(0.097) H22A(0.153) H22B(0.153)
 H22C(0.153) H22D(0.135) H22E(0.135) H22F(0.135) H23A(0.128) H23B(0.128)
 H23C(0.125) H23D(0.125) H24A(0.249) H24B(0.249) H24C(0.249) H24D(0.238)
 H24E(0.238) H24F(0.238) H25A(0.098) H25B(0.098) H25C(0.098) H25D(0.098)
 H26A(0.155) H26B(0.155) H26C(0.155) H26D(0.129) H26E(0.129) H26F(0.129)
 Fixed X: H4(0.825) H5(0.971) H7(0.7493) H8(0.6084) H10(0.3987) H11(0.2622)
 H12(0.0622) H13(0.0015) H14(0.1375) H15A(0.7909) H15B(0.8105) H16A(0.6842)
 H16B(0.792) H16C(0.6203) H17A(0.5961) H17B(0.4511) H18A(0.3209) H18B(0.4047)
 H18C(0.4671) H19A(0.6076) H19B(0.756) H20A(0.8212) H20B(0.8054) H20C(0.6773)
 H21A(0.0497) H21B(0.1573) H21C(0.0807) H21D(0.2179) H22A(0.0701) H22B(-0.0462)
 H22C(-0.0585) H22D(0.126) H22E(0.0045) H22F(-0.0108) H23A(0.444) H23B(0.317)
 H23C(0.3899) H23D(0.2553) H24A(0.4185) H24B(0.5371) H24C(0.5471) H24D(0.4813)
 H24E(0.5304) H24F(0.395) H25A(0.1397) H25B(0.2535) H25C(0.0605) H25D(0.0276)
 H26A(0.0832) H26B(0.0206) H26C(-0.0333) H26D(0.1861) H26E(0.0713) H26F(0.2369)
 Fixed Y: H4(0.7465) H5(0.9078) H7(0.7758) H8(0.6097) H10(0.225) H11(0.0669)
 H12(-0.0724) H13(-0.0488) H14(0.1095) H15A(0.2917) H15B(0.1306) H16A(0.1189)
 H16B(0.2579) H16C(0.2657) H17A(-0.0748) H17B(-0.0447) H18A(-0.0182) H18B(-
 0.1555) H18C(-0.0146) H19A(0.0982) H19B(0.0696) H20A(0.3011) H20B(0.2371)
 H20C(0.323) H21A(0.3814) H21B(0.4341) H21C(0.3881) H21D(0.4452) H22A(0.6649)
 H22B(0.5531) H22C(0.5868) H22D(0.6665) H22E(0.5519) H22F(0.6112) H23A(0.69)
 H23B(0.7274) H23C(0.7164) H23D(0.7382) H24A(0.5903) H24B(0.7112) H24C(0.5566)
 H24D(0.7854) H24E(0.6353) H24F(0.6505) H25A(0.6637) H25B(0.59) H25C(0.4126)
 H25D(0.5612) H26A(0.384) H26B(0.5102) H26C(0.4755) H26D(0.6719) H26E(0.5655)
 H26F(0.5267)
 Fixed Z: H4(0.214) H5(0.1443) H7(-0.0779) H8(-0.0095) H10(0.4298) H11(0.5055)
 H12(0.4389) H13(0.2964) H14(0.2204) H15A(0.1975) H15B(0.184) H16A(0.0546)
 H16B(0.056) H16C(0.0706) H17A(0.2163) H17B(0.2624) H18A(0.139) H18B(0.1268)
 H18C(0.0885) H19A(0.3819) H19B(0.3383) H20A(0.3459) H20B(0.4358) H20C(0.3956)
 H21A(0.3225) H21B(0.4022) H21C(0.3541) H21D(0.4166) H22A(0.3801) H22B(0.4152)
 H22C(0.3181) H22D(0.4222) H22E(0.4497) H22F(0.3579) H23A(0.2799) H23B(0.3393)
 H23C(0.2574) H23D(0.3149) H24A(0.4433) H24B(0.4204) H24C(0.3839) H24D(0.3981)
 H24E(0.3736) H24F(0.4313) H25A(0.1977) H25B(0.1422) H25C(0.1818) H25D(0.2194)
 H26A(0.1352) H26B(0.0866) H26C(0.1771) H26D(0.1283) H26E(0.073) H26F(0.0953)
;
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 'x, y, z'
2 '-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.5381(5) 0.4697(4) 0.1877(3) 0.0441(10) Uani 1 1 d . . .
C2 C 0.6112(5) 0.5583(4) 0.1532(3) 0.0449(10) Uani 1 1 d . . .
C3 C 0.6997(5) 0.6601(4) 0.1093(3) 0.0404(9) Uani 1 1 d . . .
C4 C 0.8100(5) 0.7515(4) 0.1549(3) 0.0440(10) Uani 1 1 d . . .
H4 H 0.825 0.7465 0.214 0.053 Uiso 1 1 calc R . .
C5 C 0.8964(5) 0.8485(4) 0.1135(3) 0.0435(10) Uani 1 1 d . . .
H5 H 0.971 0.9078 0.1443 0.052 Uiso 1 1 calc R . .
C6 C 0.8736(4) 0.8589(4) 0.0260(3) 0.0394(9) Uani 1 1 d . . .
C7 C 0.7653(5) 0.7694(5) -0.0189(3) 0.0487(11) Uani 1 1 d . . .
H7 H 0.7493 0.7758 -0.0779 0.058 Uiso 1 1 calc R . .
C8 C 0.6804(5) 0.6707(5) 0.0221(3) 0.0474(10) Uani 1 1 d . . .
H8 H 0.6084 0.6097 -0.0095 0.057 Uiso 1 1 calc R . .
C9 C 0.2881(5) 0.1870(4) 0.3157(3) 0.0383(8) Uani 1 1 d . . .
C10 C 0.3183(6) 0.1696(6) 0.4013(3) 0.0631(14) Uani 1 1 d . . .
H10 H 0.3987 0.225 0.4298 0.076 Uiso 1 1 calc R . .
C11 C 0.2364(7) 0.0747(6) 0.4474(4) 0.0731(17) Uani 1 1 d . . .
H11 H 0.2622 0.0669 0.5055 0.088 Uiso 1 1 calc R . .
C12 C 0.1181(7) -0.0075(5) 0.4083(4) 0.0639(14) Uani 1 1 d . . .
H12 H 0.0622 -0.0724 0.4389 0.077 Uiso 1 1 calc R . .
C13 C 0.0828(6) 0.0068(5) 0.3239(3) 0.0563(12) Uani 1 1 d . . .
H13 H 0.0015 -0.0488 0.2964 0.068 Uiso 1 1 calc R . .
C14 C 0.1651(5) 0.1019(5) 0.2782(3) 0.0468(10) Uani 1 1 d . . .
H14 H 0.1375 0.1095 0.2204 0.056 Uiso 1 1 calc R . .
C15 C 0.7405(8) 0.2024(9) 0.1748(6) 0.097(2) Uani 1 1 d . . .
H15A H 0.7909 0.2917 0.1975 0.117 Uiso 1 1 calc R . .
H15B H 0.8105 0.1306 0.184 0.117 Uiso 1 1 calc R . .
C16 C 0.7062(11) 0.2121(10) 0.0806(5) 0.122(3) Uani 1 1 d . . .
H16A H 0.6842 0.1189 0.0546 0.183 Uiso 1 1 calc R . .
H16B H 0.792 0.2579 0.056 0.183 Uiso 1 1 calc R . .
H16C H 0.6203 0.2657 0.0706 0.183 Uiso 1 1 calc R . .
C17 C 0.5104(9) -0.0179(7) 0.2150(6) 0.093(2) Uani 1 1 d . . .
H17A H 0.5961 -0.0748 0.2163 0.111 Uiso 1 1 calc R . .
H17B H 0.4511 -0.0447 0.2624 0.111 Uiso 1 1 calc R . .
C18 C 0.4178(11) -0.0547(9) 0.1355(6) 0.112(3) Uani 1 1 d . . .
H18A H 0.3209 -0.0182 0.139 0.168 Uiso 1 1 calc R . .
H18B H 0.4047 -0.1555 0.1268 0.168 Uiso 1 1 calc R . .
H18C H 0.4671 -0.0146 0.0885 0.168 Uiso 1 1 calc R . .
C19 C 0.6814(11) 0.1374(12) 0.3447(7) 0.135(4) Uani 1 1 d . . .
H19A H 0.6076 0.0982 0.3819 0.162 Uiso 1 1 calc R . .
H19B H 0.756 0.0696 0.3383 0.162 Uiso 1 1 calc R . .
C20 C 0.7515(11) 0.2586(17) 0.3833(7) 0.179(7) Uani 1 1 d . . .
H20A H 0.8212 0.3011 0.3459 0.268 Uiso 1 1 calc R . .
H20B H 0.8054 0.2371 0.4358 0.268 Uiso 1 1 calc R . .
H20C H 0.6773 0.323 0.3956 0.268 Uiso 1 1 calc R . .
C21 C 0.1125(18) 0.462(2) 0.3480(10) 0.081(5) Uani 0.709(10) 1 d PDU A 1
H21A H 0.0497 0.3814 0.3225 0.097 Uiso 0.709(10) 1 calc PR A 1
H21B H 0.1573 0.4341 0.4022 0.097 Uiso 0.709(10) 1 calc PR A 1
C21A C 0.151(6) 0.470(5) 0.369(3) 0.081(7) Uani 0.291(10) 1 d PDU A 2
H21C H 0.0807 0.3881 0.3541 0.097 Uiso 0.291(10) 1 calc PR A 2
H21D H 0.2179 0.4452 0.4166 0.097 Uiso 0.291(10) 1 calc PR A 2
C22 C 0.010(2) 0.577(2) 0.3671(10) 0.102(5) Uani 0.709(10) 1 d PD A 1
H22A H 0.0701 0.6649 0.3801 0.153 Uiso 0.709(10) 1 calc PR A 1
H22B H -0.0462 0.5531 0.4152 0.153 Uiso 0.709(10) 1 calc PR A 1
H22C H -0.0585 0.5868 0.3181 0.153 Uiso 0.709(10) 1 calc PR A 1
C22A C 0.059(5) 0.586(5) 0.403(3) 0.090(8) Uani 0.291(10) 1 d PDU A 2
H22D H 0.126 0.6665 0.4222 0.135 Uiso 0.291(10) 1 calc PR A 2
H22E H 0.0045 0.5519 0.4497 0.135 Uiso 0.291(10) 1 calc PR A 2
H22F H -0.0108 0.6112 0.3579 0.135 Uiso 0.291(10) 1 calc PR A 2
C23 C 0.381(3) 0.6543(11) 0.3237(16) 0.107(6) Uani 0.709(10) 1 d PDU A 1
H23A H 0.444 0.69 0.2799 0.128 Uiso 0.709(10) 1 calc PR A 1
H23B H 0.317 0.7274 0.3393 0.128 Uiso 0.709(10) 1 calc PR A 1
C23A C 0.338(7) 0.680(2) 0.305(4) 0.104(8) Uani 0.291(10) 1 d PDU A 2
H23C H 0.3899 0.7164 0.2574 0.125 Uiso 0.291(10) 1 calc PR A 2
H23D H 0.2553 0.7382 0.3149 0.125 Uiso 0.291(10) 1 calc PR A 2
C24 C 0.480(4) 0.626(2) 0.3994(18) 0.166(9) Uani 0.709(10) 1 d PU A 1
H24A H 0.4185 0.5903 0.4433 0.249 Uiso 0.709(10) 1 calc PR A 1
H24B H 0.5371 0.7112 0.4204 0.249 Uiso 0.709(10) 1 calc PR A 1
H24C H 0.5471 0.5566 0.3839 0.249 Uiso 0.709(10) 1 calc PR A 1
C24A C 0.446(11) 0.689(6) 0.384(4) 0.159(13) Uani 0.291(10) 1 d PDU A 2
H24D H 0.4813 0.7854 0.3981 0.238 Uiso 0.291(10) 1 calc PR A 2
H24E H 0.5304 0.6353 0.3736 0.238 Uiso 0.291(10) 1 calc PR A 2
H24F H 0.395 0.6505 0.4313 0.238 Uiso 0.291(10) 1 calc PR A 2
C25 C 0.1771(11) 0.5736(10) 0.1827(7) 0.081(3) Uani 0.709(10) 1 d PDU A 1
H25A H 0.1397 0.6637 0.1977 0.098 Uiso 0.709(10) 1 calc PR A 1
H25B H 0.2535 0.59 0.1422 0.098 Uiso 0.709(10) 1 calc PR A 1
C25A C 0.105(2) 0.508(3) 0.1962(13) 0.081(3) Uani 0.291(10) 1 d PDU A 2
H25C H 0.0605 0.4126 0.1818 0.098 Uiso 0.291(10) 1 calc PR A 2
H25D H 0.0276 0.5612 0.2194 0.098 Uiso 0.291(10) 1 calc PR A 2
C26 C 0.0507(13) 0.4774(13) 0.1418(8) 0.104(4) Uani 0.709(10) 1 d PU A 1
H26A H 0.0832 0.384 0.1352 0.155 Uiso 0.709(10) 1 calc PR A 1
H26B H 0.0206 0.5102 0.0866 0.155 Uiso 0.709(10) 1 calc PR A 1
H26C H -0.0333 0.4755 0.1771 0.155 Uiso 0.709(10) 1 calc PR A 1
C26A C 0.154(3) 0.574(3) 0.1159(14) 0.086(6) Uani 0.291(10) 1 d PDU A 2
H26D H 0.1861 0.6719 0.1283 0.129 Uiso 0.291(10) 1 calc PR A 2
H26E H 0.0713 0.5655 0.073 0.129 Uiso 0.291(10) 1 calc PR A 2
H26F H 0.2369 0.5267 0.0953 0.129 Uiso 0.291(10) 1 calc PR A 2
P1 P 0.58061(15) 0.16190(15) 0.23360(13) 0.0738(5) Uani 1 1 d . . .
P2 P 0.26296(17) 0.50090(13) 0.27950(9) 0.0567(3) Uani 1 1 d D . .
Pt1 Pt 0.414412(17) 0.328202(15) 0.249857(10) 0.03866(6) Uani 1 1 d . A .
N1 N 0.9556(4) 0.9572(4) -0.0221(2) 0.0439(8) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.006 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
C2 C1 Pt1 177.3(4) .
C1 C2 C3 177.7(5) .
C4 C3 C2 120.1(4) .
C8 C3 C2 121.7(4) .
C8 C3 C4 118.2(4) .
C5 C4 C3 120.5(4) .
C4 C5 C6 120.4(4) .
C5 C6 N1 124.3(4) .
C7 C6 C5 119.2(4) .
C7 C6 N1 116.5(4) .
C8 C7 C6 120.7(4) .
C7 C8 C3 121.0(4) .
C10 C9 C14 114.6(4) .
C10 C9 Pt1 122.1(3) .
C14 C9 Pt1 123.3(3) .
C9 C10 C11 123.6(5) .
C12 C11 C10 120.0(5) .
C13 C12 C11 118.6(4) .
C12 C13 C14 121.1(5) .
C13 C14 C9 122.1(4) .
C16 C15 P1 114.8(6) .
C18 C17 P1 117.1(5) .
C20 C19 P1 114.3(7) .
C22 C21 P2 118.1(11) .
C22A C21A P2 120(3) .
C24 C23 P2 113.7(13) .
C24A C23A P2 111(3) .
C26 C25 P2 111.8(7) .
C26A C25A P2 112.9(14) .
C15 P1 C17 111.1(4) .
C15 P1 C19 99.6(4) .
C15 P1 Pt1 118.6(3) .
C17 P1 C19 95.7(5) .
C17 P1 Pt1 119.1(2) .
C19 P1 Pt1 107.8(3) .
C21 P2 C21A 15(2) .
C21 P2 C23 109.3(12) .
C21 P2 C23A 107(3) .
C21 P2 C25 106.6(7) .
C21 P2 C25A 83.4(9) .
C21 P2 Pt1 118.1(6) .
C21A P2 C23 99(2) .
C21A P2 C25 119.3(18) .
C21A P2 C25A 98(2) .
C21A P2 Pt1 114.6(15) .
C23 P2 C25 100.3(7) .
C23 P2 C25A 124.1(9) .
C23 P2 Pt1 108.2(8) .
C23A P2 C21A 100(3) .
C23A P2 C23 17.4(18) .
C23A P2 C25 84.5(16) .
C23A P2 C25A 106.9(17) .
C23A P2 Pt1 122(2) .
C25 P2 C25A 28.3(6) .
C25 P2 Pt1 112.8(3) .
C25A P2 Pt1 112.4(8) .
C1 Pt1 C9 178.69(17) .
C1 Pt1 P1 92.62(14) .
C1 Pt1 P2 87.55(14) .
C9 Pt1 P1 88.16(12) .
C9 Pt1 P2 91.56(12) .
P2 Pt1 P1 173.87(6) .
N1 N1 C6 114.1(4) 2_775
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 C2 1.207(6) .
C1 Pt1 2.018(4) .
C2 C3 1.441(6) .
C3 C4 1.410(6) .
C3 C8 1.389(6) .
C4 C5 1.381(5) .
C5 C6 1.395(6) .
C6 C7 1.383(6) .
C6 N1 1.428(5) .
C7 C8 1.381(6) .
C9 C10 1.384(6) .
C9 C14 1.402(6) .
C9 Pt1 2.062(4) .
C10 C11 1.389(7) .
C11 C12 1.368(8) .
C12 C13 1.367(8) .
C13 C14 1.388(6) .
C15 C16 1.511(11) .
C15 P1 1.791(7) .
C17 C18 1.474(11) .
C17 P1 1.798(7) .
C19 C20 1.378(16) .
C19 P1 1.955(10) .
C21 C22 1.528(11) .
C21 P2 1.817(9) .
C21A C22A 1.531(17) .
C21A P2 1.821(17) .
C23 C24 1.49(2) .
C23 P2 1.832(10) .
C23A C24A 1.53(2) .
C23A P2 1.818(17) .
C25 C26 1.499(16) .
C25 P2 1.856(9) .
C25A C26A 1.522(18) .
C25A P2 1.877(17) .
P1 Pt1 2.2938(14) .
P2 Pt1 2.2851(13) .
N1 N1 1.254(7) 2_775
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_4
C1 C2 C3 C4 -132(12) .
C1 C2 C3 C8 47(13) .
C2 C1 Pt1 C9 -8(14) .
C2 C1 Pt1 P1 -135(9) .
C2 C1 Pt1 P2 39(9) .
C2 C3 C4 C5 179.4(4) .
C2 C3 C8 C7 179.5(4) .
C3 C4 C5 C6 1.2(7) .
C4 C3 C8 C7 -0.9(7) .
C4 C5 C6 C7 -1.1(7) .
C4 C5 C6 N1 179.0(4) .
C5 C6 C7 C8 0.0(7) .
C5 C6 N1 N1 -5.2(7) 2_775
C6 C7 C8 C3 1.0(8) .
C7 C6 N1 N1 174.9(5) 2_775
C8 C3 C4 C5 -0.2(7) .
C9 C10 C11 C12 -0.3(10) .
C10 C9 C14 C13 -1.0(7) .
C10 C9 Pt1 C1 -42(7) .
C10 C9 Pt1 P1 84.1(4) .
C10 C9 Pt1 P2 -89.8(4) .
C10 C11 C12 C13 -0.3(10) .
C11 C12 C13 C14 0.3(9) .
C12 C13 C14 C9 0.4(8) .
C14 C9 C10 C11 1.0(8) .
C14 C9 Pt1 C1 137(7) .
C14 C9 Pt1 P1 -96.4(4) .
C14 C9 Pt1 P2 89.8(4) .
C15 P1 Pt1 C1 -2.5(4) .
C15 P1 Pt1 C9 178.5(4) .
C15 P1 Pt1 P2 -93.9(6) .
C16 C15 P1 C17 73.1(7) .
C16 C15 P1 C19 173.1(7) .
C16 C15 P1 Pt1 -70.5(7) .
C17 P1 Pt1 C1 -143.2(4) .
C17 P1 Pt1 C9 37.9(3) .
C17 P1 Pt1 P2 125.4(5) .
C18 C17 P1 C15 -79.1(7) .
C18 C17 P1 C19 178.4(7) .
C18 C17 P1 Pt1 64.3(7) .
C19 P1 Pt1 C1 109.4(4) .
C19 P1 Pt1 C9 -69.5(4) .
C19 P1 Pt1 P2 18.0(6) .
C20 C19 P1 C15 68.4(9) .
C20 C19 P1 C17 -179.1(9) .
C20 C19 P1 Pt1 -56.0(9) .
C21 P2 Pt1 C1 -175.1(8) .
C21 P2 Pt1 C9 3.9(8) .
C21 P2 Pt1 P1 -83.4(9) .
C21A P2 Pt1 C1 -159(2) .
C21A P2 Pt1 C9 20(2) .
C21A P2 Pt1 P1 -68(2) .
C22 C21 P2 C21A 101(9) .
C22 C21 P2 C23 56.5(15) .
C22 C21 P2 C23A 38(2) .
C22 C21 P2 C25 -51.1(14) .
C22 C21 P2 C25A -67.5(14) .
C22 C21 P2 Pt1 -179.3(10) .
C22A C21A P2 C21 -80(8) .
C22A C21A P2 C23 58(4) .
C22A C21A P2 C23A 40(5) .
C22A C21A P2 C25 -49(5) .
C22A C21A P2 C25A -69(4) .
C22A C21A P2 Pt1 172(3) .
C23 P2 Pt1 C1 -50.3(9) .
C23 P2 Pt1 C9 128.7(9) .
C23 P2 Pt1 P1 41.4(10) .
C23A P2 Pt1 C1 -38(2) .
C23A P2 Pt1 C9 141(2) .
C23A P2 Pt1 P1 53(2) .
C24 C23 P2 C21 74(2) .
C24 C23 P2 C21A 64(3) .
C24 C23 P2 C23A 160(13) .
C24 C23 P2 C25 -174(2) .
C24 C23 P2 C25A 169(2) .
C24 C23 P2 Pt1 -56(3) .
C24A C23A P2 C21 81(6) .
C24A C23A P2 C21A 67(6) .
C24A C23A P2 C23 -19(9) .
C24A C23A P2 C25 -174(6) .
C24A C23A P2 C25A 169(6) .
C24A C23A P2 Pt1 -60(7) .
C25 P2 Pt1 C1 59.7(4) .
C25 P2 Pt1 C9 -121.3(4) .
C25 P2 Pt1 P1 151.4(5) .
C25A P2 Pt1 C1 90.4(7) .
C25A P2 Pt1 C9 -90.6(7) .
C25A P2 Pt1 P1 -177.9(8) .
C26 C25 P2 C21 -55.1(11) .
C26 C25 P2 C21A -63(2) .
C26 C25 P2 C23 -169.0(12) .
C26 C25 P2 C23A -161(3) .
C26 C25 P2 C25A -18.9(18) .
C26 C25 P2 Pt1 76.1(8) .
C26A C25A P2 C21 166(2) .
C26A C25A P2 C21A 163(2) .
C26A C25A P2 C23 57(2) .
C26A C25A P2 C23A 60(3) .
C26A C25A P2 C25 20.8(14) .
C26A C25A P2 Pt1 -76.2(19) .
Pt1 C1 C2 C3 177(7) .
Pt1 C9 C10 C11 -179.4(5) .
Pt1 C9 C14 C13 179.4(4) .
N1 C6 C7 C8 179.9(4) .
