#------------------------------------------------------------------------------
#$Date: 2016-02-14 06:40:26 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176432 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/07/4500715.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4500715
loop_
_publ_author_name
'Wang, Xinjiao'
'Vogel, Carola S.'
'Heinemann, Frank W.'
'Wasserscheid, Peter'
'Meyer, Karsten'
_publ_section_title
;
 Solid-State Structures of Double-Long-Chain Imidazolium Ionic Liquids:
 Influence of Anion Shape on Cation Geometry and Crystal Packing
;
_journal_issue                   5
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              1974
_journal_paper_doi               10.1021/cg200169u
_journal_volume                  11
_journal_year                    2011
_chemical_formula_moiety         'C27 H53 N2, F6 Sb'
_chemical_formula_sum            'C27 H53 F6 N2 Sb'
_chemical_formula_weight         641.46
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           13
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yc'
_symmetry_space_group_name_H-M   'P 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 100.628(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   13.909(2)
_cell_length_b                   6.3867(9)
_cell_length_c                   35.945(5)
_cell_measurement_reflns_used    9923
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      27.40
_cell_measurement_theta_min      2.99
_cell_volume                     3138.3(8)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'SHELXTL 6.12 (Bruker AXS, 2002)'
_computing_publication_material  'SHELXTL 6.12 (Bruker AXS, 2002)'
_computing_structure_refinement  'SHELXTL 6.12 (Bruker AXS, 2002)'
_computing_structure_solution    'SHELXTL 6.12 (Bruker AXS, 2002)'
_diffrn_ambient_temperature      150(2)
_diffrn_detector_area_resol_mean 83.33
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker Kappa APEX II CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  'Quazar focussing montel optics'
_diffrn_radiation_source         'ImuS micro-focus tube'
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0393
_diffrn_reflns_av_sigmaI/netI    0.0318
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_k_min       -8
_diffrn_reflns_limit_l_max       46
_diffrn_reflns_limit_l_min       -46
_diffrn_reflns_number            47493
_diffrn_reflns_theta_full        27.10
_diffrn_reflns_theta_max         27.10
_diffrn_reflns_theta_min         2.97
_exptl_absorpt_coefficient_mu    0.932
_exptl_absorpt_correction_T_max  0.746
_exptl_absorpt_correction_T_min  0.673
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS, Bruker-AXS, 2009'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.358
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1336
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.08
_refine_diff_density_max         1.023
_refine_diff_density_min         -1.227
_refine_diff_density_rms         0.074
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.070
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     356
_refine_ls_number_reflns         6891
_refine_ls_number_restraints     72
_refine_ls_restrained_S_all      1.141
_refine_ls_R_factor_all          0.0466
_refine_ls_R_factor_gt           0.0352
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0300P)²+3.5676P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0790
_refine_ls_wR_factor_ref         0.0836
_reflns_number_gt                5768
_reflns_number_total             6891
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg200169u_si_006.cif
_cod_data_source_block           xw1002
_cod_original_cell_volume        3138.2(8)
_cod_original_sg_symbol_Hall     -P2yc
_cod_original_sg_symbol_H-M      P2/c
_cod_database_code               4500715
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Sb1 Sb 0.0000 0.22887(4) 0.2500 0.02792(8) Uani 1 2 d SD . .
F11 F -0.01707(15) 0.0193(3) 0.21286(6) 0.0515(5) Uani 1 1 d D . .
F12 F -0.01650(14) 0.4324(3) 0.21224(5) 0.0451(5) Uani 1 1 d D . .
F13 F -0.13492(13) 0.2252(3) 0.24925(5) 0.0410(4) Uani 1 1 d D . .
Sb2 Sb 0.5000 1.00676(4) 0.2500 0.03452(9) Uani 1 2 d SD . .
F21 F 0.3854(5) 0.9467(11) 0.2179(2) 0.0924(19) Uani 0.50 1 d PDU A 1
F22 F 0.5683(5) 0.9058(11) 0.21339(16) 0.1000(17) Uani 0.50 1 d PDU A 1
F23 F 0.4949(4) 1.2605(7) 0.22445(15) 0.0706(13) Uani 0.50 1 d PDU A 1
F21A F 0.4909(4) 0.7553(7) 0.22416(15) 0.0747(14) Uani 0.50 1 d PDU A 2
F22A F 0.5624(5) 1.1144(11) 0.21443(16) 0.1011(17) Uani 0.50 1 d PDU A 2
F23A F 0.3773(5) 1.0672(11) 0.2236(2) 0.104(2) Uani 0.50 1 d PDU A 2
N1 N 0.72410(19) 0.5860(4) 0.21490(7) 0.0354(6) Uani 1 1 d . . .
N2 N 0.75144(19) 0.6092(4) 0.27566(7) 0.0345(6) Uani 1 1 d . . .
C1 C 0.6932(2) 0.5272(5) 0.24607(9) 0.0356(7) Uani 1 1 d . . .
H1A H 0.6382 0.4404 0.2470 0.043 Uiso 1 1 calc R . .
C2 C 0.8222(2) 0.7237(5) 0.26308(10) 0.0432(8) Uani 1 1 d . . .
H2A H 0.8738 0.7989 0.2784 0.052 Uiso 1 1 calc R . .
C3 C 0.8052(2) 0.7100(5) 0.22517(10) 0.0425(8) Uani 1 1 d . . .
H3A H 0.8423 0.7741 0.2086 0.051 Uiso 1 1 calc R . .
C4 C 0.6777(3) 0.5256(6) 0.17653(9) 0.0491(9) Uani 1 1 d . . .
H4A H 0.6894 0.6371 0.1588 0.059 Uiso 1 1 calc R . .
H4B H 0.6062 0.5152 0.1754 0.059 Uiso 1 1 calc R . .
C5 C 0.7146(2) 0.3195(5) 0.16369(8) 0.0379(7) Uani 1 1 d . . .
H5A H 0.7020 0.2060 0.1809 0.045 Uiso 1 1 calc R . .
H5B H 0.7860 0.3280 0.1646 0.045 Uiso 1 1 calc R . .
C6 C 0.6630(2) 0.2706(5) 0.12348(8) 0.0399(7) Uani 1 1 d . . .
H6A H 0.5916 0.2655 0.1230 0.048 Uiso 1 1 calc R . .
H6B H 0.6754 0.3866 0.1067 0.048 Uiso 1 1 calc R . .
C7 C 0.6940(2) 0.0669(5) 0.10758(8) 0.0398(7) Uani 1 1 d . . .
H7A H 0.6806 -0.0502 0.1240 0.048 Uiso 1 1 calc R . .
H7B H 0.7653 0.0707 0.1080 0.048 Uiso 1 1 calc R . .
C8 C 0.6410(2) 0.0260(5) 0.06719(8) 0.0371(7) Uani 1 1 d . . .
H8A H 0.5698 0.0211 0.0670 0.045 Uiso 1 1 calc R . .
H8B H 0.6533 0.1454 0.0511 0.045 Uiso 1 1 calc R . .
C9 C 0.6705(2) -0.1737(5) 0.04973(8) 0.0370(7) Uani 1 1 d . . .
H9A H 0.6601 -0.2932 0.0661 0.044 Uiso 1 1 calc R . .
H9B H 0.7412 -0.1672 0.0489 0.044 Uiso 1 1 calc R . .
C10 C 0.6138(2) -0.2130(5) 0.00983(8) 0.0365(7) Uani 1 1 d . . .
H10A H 0.5431 -0.2191 0.0107 0.044 Uiso 1 1 calc R . .
H10B H 0.6241 -0.0930 -0.0064 0.044 Uiso 1 1 calc R . .
C11 C 0.6422(2) -0.4127(5) -0.00831(8) 0.0373(7) Uani 1 1 d . . .
H11A H 0.6329 -0.5329 0.0081 0.045 Uiso 1 1 calc R . .
H11B H 0.7125 -0.4058 -0.0098 0.045 Uiso 1 1 calc R . .
C12 C 0.5832(2) -0.4509(5) -0.04793(8) 0.0364(7) Uani 1 1 d . . .
H12A H 0.5129 -0.4580 -0.0464 0.044 Uiso 1 1 calc R . .
H12B H 0.5923 -0.3303 -0.0642 0.044 Uiso 1 1 calc R . .
C13 C 0.6113(2) -0.6495(5) -0.06630(8) 0.0376(7) Uani 1 1 d . . .
H13A H 0.6032 -0.7699 -0.0498 0.045 Uiso 1 1 calc R . .
H13B H 0.6814 -0.6413 -0.0682 0.045 Uiso 1 1 calc R . .
C14 C 0.5514(2) -0.6893(5) -0.10568(8) 0.0402(8) Uani 1 1 d . . .
H14A H 0.4812 -0.6944 -0.1039 0.048 Uiso 1 1 calc R . .
H14B H 0.5607 -0.5707 -0.1224 0.048 Uiso 1 1 calc R . .
C15 C 0.5784(3) -0.8909(6) -0.12348(10) 0.0524(9) Uani 1 1 d . . .
H15A H 0.5349 -0.9117 -0.1479 0.079 Uiso 1 1 calc R . .
H15B H 0.5716 -1.0088 -0.1067 0.079 Uiso 1 1 calc R . .
H15C H 0.6463 -0.8825 -0.1273 0.079 Uiso 1 1 calc R . .
C16 C 0.7414(3) 0.5759(6) 0.31515(8) 0.0446(8) Uani 1 1 d . . .
H16A H 0.6713 0.5587 0.3163 0.054 Uiso 1 1 calc R . .
H16B H 0.7658 0.7010 0.3302 0.054 Uiso 1 1 calc R . .
C17 C 0.7972(2) 0.3849(5) 0.33228(8) 0.0357(7) Uani 1 1 d . . .
H17A H 0.8675 0.4022 0.3315 0.043 Uiso 1 1 calc R . .
H17B H 0.7732 0.2594 0.3172 0.043 Uiso 1 1 calc R . .
C18 C 0.7843(2) 0.3539(5) 0.37326(8) 0.0390(7) Uani 1 1 d . . .
H18A H 0.8085 0.4802 0.3881 0.047 Uiso 1 1 calc R . .
H18B H 0.7137 0.3397 0.3738 0.047 Uiso 1 1 calc R . .
C19 C 0.8378(2) 0.1633(5) 0.39206(8) 0.0354(7) Uani 1 1 d . . .
H19A H 0.9086 0.1788 0.3921 0.043 Uiso 1 1 calc R . .
H19B H 0.8146 0.0373 0.3770 0.043 Uiso 1 1 calc R . .
C20 C 0.8227(2) 0.1315(5) 0.43264(8) 0.0360(7) Uani 1 1 d . . .
H20A H 0.8478 0.2559 0.4478 0.043 Uiso 1 1 calc R . .
H20B H 0.7517 0.1208 0.4327 0.043 Uiso 1 1 calc R . .
C21 C 0.8731(2) -0.0621(5) 0.45137(8) 0.0341(7) Uani 1 1 d . . .
H21A H 0.9444 -0.0498 0.4521 0.041 Uiso 1 1 calc R . .
H21B H 0.8495 -0.1863 0.4359 0.041 Uiso 1 1 calc R . .
C22 C 0.8551(2) -0.0954(5) 0.49164(8) 0.0352(7) Uani 1 1 d . . .
H22A H 0.8792 0.0284 0.5072 0.042 Uiso 1 1 calc R . .
H22B H 0.7837 -0.1061 0.4909 0.042 Uiso 1 1 calc R . .
C23 C 0.9045(2) -0.2901(5) 0.51050(8) 0.0340(7) Uani 1 1 d . . .
H23A H 0.9758 -0.2797 0.5112 0.041 Uiso 1 1 calc R . .
H23B H 0.8802 -0.4141 0.4951 0.041 Uiso 1 1 calc R . .
C24 C 0.8865(2) -0.3226(5) 0.55093(8) 0.0358(7) Uani 1 1 d . . .
H24A H 0.9105 -0.1983 0.5663 0.043 Uiso 1 1 calc R . .
H24B H 0.8152 -0.3337 0.5502 0.043 Uiso 1 1 calc R . .
C25 C 0.9361(2) -0.5161(5) 0.56983(8) 0.0370(7) Uani 1 1 d . . .
H25A H 1.0073 -0.5054 0.5704 0.044 Uiso 1 1 calc R . .
H25B H 0.9117 -0.6404 0.5545 0.044 Uiso 1 1 calc R . .
C26 C 0.9187(3) -0.5478(6) 0.61026(8) 0.0419(8) Uani 1 1 d . . .
H26A H 0.9430 -0.4236 0.6256 0.050 Uiso 1 1 calc R . .
H26B H 0.8475 -0.5589 0.6098 0.050 Uiso 1 1 calc R . .
C27 C 0.9690(3) -0.7425(6) 0.62896(9) 0.0505(9) Uani 1 1 d . . .
H27A H 0.9579 -0.7520 0.6551 0.076 Uiso 1 1 calc R . .
H27B H 1.0393 -0.7338 0.6291 0.076 Uiso 1 1 calc R . .
H27C H 0.9420 -0.8669 0.6148 0.076 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
F12 Sb1 F12 91.51(12) . 2
F12 Sb1 F13 90.44(8) . 2
F12 Sb1 F13 90.57(8) 2 2
F12 Sb1 F13 90.56(8) . .
F12 Sb1 F13 90.44(8) 2 .
F13 Sb1 F13 178.56(11) 2 .
F12 Sb1 F11 178.62(9) . 2
F12 Sb1 F11 89.82(9) 2 2
F13 Sb1 F11 89.19(9) 2 2
F13 Sb1 F11 89.78(8) . 2
F12 Sb1 F11 89.82(9) . .
F12 Sb1 F11 178.62(9) 2 .
F13 Sb1 F11 89.79(8) 2 .
F13 Sb1 F11 89.18(9) . .
F11 Sb1 F11 88.85(14) 2 .
F22A Sb2 F22A 135.3(5) . 2_655
F22A Sb2 F21 92.8(3) . 2_655
F22A Sb2 F21 96.3(3) 2_655 2_655
F22A Sb2 F21 96.3(3) . .
F22A Sb2 F21 92.8(3) 2_655 .
F21 Sb2 F21 155.8(4) 2_655 .
F22A Sb2 F23A 76.3(3) . 2_655
F22A Sb2 F23A 94.4(4) 2_655 2_655
F21 Sb2 F23A 25.6(2) 2_655 2_655
F21 Sb2 F23A 172.1(4) . 2_655
F22A Sb2 F23A 94.4(4) . .
F22A Sb2 F23A 76.3(3) 2_655 .
F21 Sb2 F23A 172.1(4) 2_655 .
F21 Sb2 F23A 25.6(2) . .
F23A Sb2 F23A 155.7(4) 2_655 .
F22A Sb2 F21A 133.5(3) . 2_655
F22A Sb2 F21A 88.4(3) 2_655 2_655
F21 Sb2 F21A 61.9(3) 2_655 2_655
F21 Sb2 F21A 96.1(3) . 2_655
F23A Sb2 F21A 87.3(2) 2_655 2_655
F23A Sb2 F21A 114.5(3) . 2_655
F22A Sb2 F21A 88.4(3) . .
F22A Sb2 F21A 133.5(3) 2_655 .
F21 Sb2 F21A 96.1(3) 2_655 .
F21 Sb2 F21A 61.9(3) . .
F23A Sb2 F21A 114.5(3) 2_655 .
F23A Sb2 F21A 87.3(2) . .
F21A Sb2 F21A 59.3(4) 2_655 .
F22A Sb2 F23 45.4(3) . .
F22A Sb2 F23 92.2(3) 2_655 .
F21 Sb2 F23 116.4(3) 2_655 .
F21 Sb2 F23 85.5(3) . .
F23A Sb2 F23 91.1(2) 2_655 .
F23A Sb2 F23 67.3(3) . .
F21A Sb2 F23 178.2(2) 2_655 .
F21A Sb2 F23 121.1(3) . .
F22A Sb2 F23 92.2(3) . 2_655
F22A Sb2 F23 45.4(3) 2_655 2_655
F21 Sb2 F23 85.5(3) 2_655 2_655
F21 Sb2 F23 116.4(3) . 2_655
F23A Sb2 F23 67.3(3) 2_655 2_655
F23A Sb2 F23 91.1(2) . 2_655
F21A Sb2 F23 121.1(3) 2_655 2_655
F21A Sb2 F23 178.2(2) . 2_655
F23 Sb2 F23 58.5(4) . 2_655
F22A Sb2 F22 42.5(3) . .
F22A Sb2 F22 177.5(4) 2_655 .
F21 Sb2 F22 82.8(3) 2_655 .
F21 Sb2 F22 88.9(3) . .
F23A Sb2 F22 83.8(4) 2_655 .
F23A Sb2 F22 104.7(3) . .
F21A Sb2 F22 93.3(3) 2_655 .
F21A Sb2 F22 49.1(3) . .
F23 Sb2 F22 86.0(3) . .
F23 Sb2 F22 132.0(3) 2_655 .
F22A Sb2 F22 177.5(4) . 2_655
F22A Sb2 F22 42.5(3) 2_655 2_655
F21 Sb2 F22 88.9(3) 2_655 2_655
F21 Sb2 F22 82.8(3) . 2_655
F23A Sb2 F22 104.7(3) 2_655 2_655
F23A Sb2 F22 83.8(4) . 2_655
F21A Sb2 F22 49.1(3) 2_655 2_655
F21A Sb2 F22 93.3(3) . 2_655
F23 Sb2 F22 132.0(3) . 2_655
F23 Sb2 F22 86.0(3) 2_655 2_655
F22 Sb2 F22 139.7(5) . 2_655
C1 N1 C3 108.3(3) . .
C1 N1 C4 124.5(3) . .
C3 N1 C4 127.1(3) . .
C1 N2 C2 108.5(3) . .
C1 N2 C16 124.6(3) . .
C2 N2 C16 126.9(3) . .
N2 C1 N1 108.8(3) . .
N2 C1 H1A 125.6 . .
N1 C1 H1A 125.6 . .
C3 C2 N2 107.4(3) . .
C3 C2 H2A 126.3 . .
N2 C2 H2A 126.3 . .
C2 C3 N1 107.0(3) . .
C2 C3 H3A 126.5 . .
N1 C3 H3A 126.5 . .
N1 C4 C5 113.7(3) . .
N1 C4 H4A 108.8 . .
C5 C4 H4A 108.8 . .
N1 C4 H4B 108.8 . .
C5 C4 H4B 108.8 . .
H4A C4 H4B 107.7 . .
C4 C5 C6 109.9(3) . .
C4 C5 H5A 109.7 . .
C6 C5 H5A 109.7 . .
C4 C5 H5B 109.7 . .
C6 C5 H5B 109.7 . .
H5A C5 H5B 108.2 . .
C7 C6 C5 114.6(3) . .
C7 C6 H6A 108.6 . .
C5 C6 H6A 108.6 . .
C7 C6 H6B 108.6 . .
C5 C6 H6B 108.6 . .
H6A C6 H6B 107.6 . .
C6 C7 C8 112.6(3) . .
C6 C7 H7A 109.1 . .
C8 C7 H7A 109.1 . .
C6 C7 H7B 109.1 . .
C8 C7 H7B 109.1 . .
H7A C7 H7B 107.8 . .
C9 C8 C7 114.8(3) . .
C9 C8 H8A 108.6 . .
C7 C8 H8A 108.6 . .
C9 C8 H8B 108.6 . .
C7 C8 H8B 108.6 . .
H8A C8 H8B 107.5 . .
C8 C9 C10 113.3(3) . .
C8 C9 H9A 108.9 . .
C10 C9 H9A 108.9 . .
C8 C9 H9B 108.9 . .
C10 C9 H9B 108.9 . .
H9A C9 H9B 107.7 . .
C11 C10 C9 114.3(3) . .
C11 C10 H10A 108.7 . .
C9 C10 H10A 108.7 . .
C11 C10 H10B 108.7 . .
C9 C10 H10B 108.7 . .
H10A C10 H10B 107.6 . .
C10 C11 C12 113.4(3) . .
C10 C11 H11A 108.9 . .
C12 C11 H11A 108.9 . .
C10 C11 H11B 108.9 . .
C12 C11 H11B 108.9 . .
H11A C11 H11B 107.7 . .
C13 C12 C11 113.8(3) . .
C13 C12 H12A 108.8 . .
C11 C12 H12A 108.8 . .
C13 C12 H12B 108.8 . .
C11 C12 H12B 108.8 . .
H12A C12 H12B 107.7 . .
C12 C13 C14 113.8(3) . .
C12 C13 H13A 108.8 . .
C14 C13 H13A 108.8 . .
C12 C13 H13B 108.8 . .
C14 C13 H13B 108.8 . .
H13A C13 H13B 107.7 . .
C15 C14 C13 113.4(3) . .
C15 C14 H14A 108.9 . .
C13 C14 H14A 108.9 . .
C15 C14 H14B 108.9 . .
C13 C14 H14B 108.9 . .
H14A C14 H14B 107.7 . .
C14 C15 H15A 109.5 . .
C14 C15 H15B 109.5 . .
H15A C15 H15B 109.5 . .
C14 C15 H15C 109.5 . .
H15A C15 H15C 109.5 . .
H15B C15 H15C 109.5 . .
N2 C16 C17 112.1(3) . .
N2 C16 H16A 109.2 . .
C17 C16 H16A 109.2 . .
N2 C16 H16B 109.2 . .
C17 C16 H16B 109.2 . .
H16A C16 H16B 107.9 . .
C16 C17 C18 110.7(3) . .
C16 C17 H17A 109.5 . .
C18 C17 H17A 109.5 . .
C16 C17 H17B 109.5 . .
C18 C17 H17B 109.5 . .
H17A C17 H17B 108.1 . .
C19 C18 C17 113.4(3) . .
C19 C18 H18A 108.9 . .
C17 C18 H18A 108.9 . .
C19 C18 H18B 108.9 . .
C17 C18 H18B 108.9 . .
H18A C18 H18B 107.7 . .
C18 C19 C20 113.0(3) . .
C18 C19 H19A 109.0 . .
C20 C19 H19A 109.0 . .
C18 C19 H19B 109.0 . .
C20 C19 H19B 109.0 . .
H19A C19 H19B 107.8 . .
C21 C20 C19 113.6(2) . .
C21 C20 H20A 108.9 . .
C19 C20 H20A 108.9 . .
C21 C20 H20B 108.9 . .
C19 C20 H20B 108.9 . .
H20A C20 H20B 107.7 . .
C20 C21 C22 113.0(2) . .
C20 C21 H21A 109.0 . .
C22 C21 H21A 109.0 . .
C20 C21 H21B 109.0 . .
C22 C21 H21B 109.0 . .
H21A C21 H21B 107.8 . .
C23 C22 C21 113.3(2) . .
C23 C22 H22A 108.9 . .
C21 C22 H22A 108.9 . .
C23 C22 H22B 108.9 . .
C21 C22 H22B 108.9 . .
H22A C22 H22B 107.7 . .
C22 C23 C24 113.2(2) . .
C22 C23 H23A 108.9 . .
C24 C23 H23A 108.9 . .
C22 C23 H23B 108.9 . .
C24 C23 H23B 108.9 . .
H23A C23 H23B 107.8 . .
C25 C24 C23 113.3(3) . .
C25 C24 H24A 108.9 . .
C23 C24 H24A 108.9 . .
C25 C24 H24B 108.9 . .
C23 C24 H24B 108.9 . .
H24A C24 H24B 107.7 . .
C24 C25 C26 113.3(3) . .
C24 C25 H25A 108.9 . .
C26 C25 H25A 108.9 . .
C24 C25 H25B 108.9 . .
C26 C25 H25B 108.9 . .
H25A C25 H25B 107.7 . .
C27 C26 C25 112.8(3) . .
C27 C26 H26A 109.0 . .
C25 C26 H26A 109.0 . .
C27 C26 H26B 109.0 . .
C25 C26 H26B 109.0 . .
H26A C26 H26B 107.8 . .
C26 C27 H27A 109.5 . .
C26 C27 H27B 109.5 . .
H27A C27 H27B 109.5 . .
C26 C27 H27C 109.5 . .
H27A C27 H27C 109.5 . .
H27B C27 H27C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Sb1 F12 1.8626(17) .
Sb1 F12 1.8626(17) 2
Sb1 F13 1.8718(18) 2
Sb1 F13 1.8719(18) .
Sb1 F11 1.8745(18) 2
Sb1 F11 1.8745(18) .
Sb2 F22A 1.808(5) .
Sb2 F22A 1.808(5) 2_655
Sb2 F21 1.828(6) 2_655
Sb2 F21 1.828(6) .
Sb2 F23A 1.834(6) 2_655
Sb2 F23A 1.834(6) .
Sb2 F21A 1.848(4) 2_655
Sb2 F21A 1.848(4) .
Sb2 F23 1.858(4) .
Sb2 F23 1.858(4) 2_655
Sb2 F22 1.873(5) .
Sb2 F22 1.873(5) 2_655
N1 C1 1.326(4) .
N1 C3 1.372(4) .
N1 C4 1.462(4) .
N2 C1 1.321(4) .
N2 C2 1.368(4) .
N2 C16 1.467(4) .
C1 H1A 0.9500 .
C2 C3 1.342(5) .
C2 H2A 0.9500 .
C3 H3A 0.9500 .
C4 C5 1.515(5) .
C4 H4A 0.9900 .
C4 H4B 0.9900 .
C5 C6 1.523(4) .
C5 H5A 0.9900 .
C5 H5B 0.9900 .
C6 C7 1.515(5) .
C6 H6A 0.9900 .
C6 H6B 0.9900 .
C7 C8 1.525(4) .
C7 H7A 0.9900 .
C7 H7B 0.9900 .
C8 C9 1.512(5) .
C8 H8A 0.9900 .
C8 H8B 0.9900 .
C9 C10 1.525(4) .
C9 H9A 0.9900 .
C9 H9B 0.9900 .
C10 C11 1.517(4) .
C10 H10A 0.9900 .
C10 H10B 0.9900 .
C11 C12 1.526(4) .
C11 H11A 0.9900 .
C11 H11B 0.9900 .
C12 C13 1.514(5) .
C12 H12A 0.9900 .
C12 H12B 0.9900 .
C13 C14 1.526(4) .
C13 H13A 0.9900 .
C13 H13B 0.9900 .
C14 C15 1.516(5) .
C14 H14A 0.9900 .
C14 H14B 0.9900 .
C15 H15A 0.9800 .
C15 H15B 0.9800 .
C15 H15C 0.9800 .
C16 C17 1.514(4) .
C16 H16A 0.9900 .
C16 H16B 0.9900 .
C17 C18 1.529(4) .
C17 H17A 0.9900 .
C17 H17B 0.9900 .
C18 C19 1.519(4) .
C18 H18A 0.9900 .
C18 H18B 0.9900 .
C19 C20 1.525(4) .
C19 H19A 0.9900 .
C19 H19B 0.9900 .
C20 C21 1.516(4) .
C20 H20A 0.9900 .
C20 H20B 0.9900 .
C21 C22 1.529(4) .
C21 H21A 0.9900 .
C21 H21B 0.9900 .
C22 C23 1.519(4) .
C22 H22A 0.9900 .
C22 H22B 0.9900 .
C23 C24 1.534(4) .
C23 H23A 0.9900 .
C23 H23B 0.9900 .
C24 C25 1.514(4) .
C24 H24A 0.9900 .
C24 H24B 0.9900 .
C25 C26 1.530(4) .
C25 H25A 0.9900 .
C25 H25B 0.9900 .
C26 C27 1.521(5) .
C26 H26A 0.9900 .
C26 H26B 0.9900 .
C27 H27A 0.9800 .
C27 H27B 0.9800 .
C27 H27C 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C2 N2 C1 N1 -0.2(4)
C16 N2 C1 N1 -178.9(3)
C3 N1 C1 N2 0.1(3)
C4 N1 C1 N2 -180.0(3)
C1 N2 C2 C3 0.3(4)
C16 N2 C2 C3 178.9(3)
N2 C2 C3 N1 -0.3(4)
C1 N1 C3 C2 0.1(4)
C4 N1 C3 C2 -179.8(3)
C1 N1 C4 C5 -87.3(4)
C3 N1 C4 C5 92.6(4)
N1 C4 C5 C6 -179.5(3)
C4 C5 C6 C7 -179.9(3)
C5 C6 C7 C8 -179.4(3)
C6 C7 C8 C9 179.0(3)
C7 C8 C9 C10 178.1(3)
C8 C9 C10 C11 180.0(3)
C9 C10 C11 C12 179.0(3)
C10 C11 C12 C13 179.8(3)
C11 C12 C13 C14 179.1(3)
C12 C13 C14 C15 -178.7(3)
C1 N2 C16 C17 89.0(4)
C2 N2 C16 C17 -89.4(4)
N2 C16 C17 C18 -179.5(3)
C16 C17 C18 C19 179.4(3)
C17 C18 C19 C20 -178.8(3)
C18 C19 C20 C21 178.2(3)
C19 C20 C21 C22 -178.4(3)
C20 C21 C22 C23 179.5(3)
C21 C22 C23 C24 179.8(3)
C22 C23 C24 C25 -179.7(3)
C23 C24 C25 C26 179.6(3)
C24 C25 C26 C27 -179.9(3)
