#------------------------------------------------------------------------------
#$Date: 2016-03-24 01:36:23 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179538 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/07/4500793.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4500793
loop_
_publ_author_name
'Liu, Lei-Lei'
'Ren, Zhi-Gang'
'Zhu, Lian-Wen'
'Wang, Hui-Fang'
'Yan, Wen-Yan'
'Lang, Jian-Ping'
_publ_section_title
;
 Temperature-Driven Assembly of Ln(III) (Ln = Nd, Eu, Yb) Coordination
 Polymers of a Flexible Azo Calix[4]arene Polycarboxylate Ligand
;
_journal_issue                   8
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              3479
_journal_paper_doi               10.1021/cg200308k
_journal_volume                  11
_journal_year                    2011
_chemical_formula_moiety
'C56 H36.52 Eu N8 O13, C2 H3 N, 2(C1.50 H3.50 N0.50 O0.50), H0.5'
_chemical_formula_sum            'C61 H50 Eu N10 O16'
_chemical_formula_weight         1331.07
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           87
_symmetry_cell_setting           tetragonal
_symmetry_space_group_name_Hall  '-I 4'
_symmetry_space_group_name_H-M   'I 4/m'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.2815(16)
_cell_length_b                   11.2815(16)
_cell_length_c                   49.769(10)
_cell_measurement_reflns_used    7704
_cell_measurement_temperature    223(2)
_cell_measurement_theta_max      27.4160
_cell_measurement_theta_min      3.0334
_cell_volume                     6334.2(18)
_computing_cell_refinement       'CrystalClear, Ver. 1.30 (Rigaku/MSC, 2001)'
_computing_data_collection       'CrystalClear, Ver. 1.30 (Rigaku/MSC, 2001)'
_computing_data_reduction
'CrystalStructure, Ver. 3.60 (Rigaku/MSC, 2004)'
_computing_molecular_graphics    'SHELXL-97 (Sheldrick, 1997)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      223(2)
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'Rigaku Mercury'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0610
_diffrn_reflns_av_sigmaI/netI    0.0672
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       54
_diffrn_reflns_limit_l_min       -59
_diffrn_reflns_number            8244
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         3.27
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.064
_exptl_absorpt_correction_T_max  0.9011
_exptl_absorpt_correction_T_min  0.5677
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
'Jacobson, R. (1998) Private communication to Rigaku Corp.'
_exptl_crystal_colour            Orange
_exptl_crystal_density_diffrn    1.396
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             2708
_exptl_crystal_size_max          0.60
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.10
_refine_diff_density_max         3.069
_refine_diff_density_min         -0.867
_refine_diff_density_rms         0.125
_refine_ls_extinction_coef       0.0012(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.097
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     225
_refine_ls_number_reflns         2808
_refine_ls_number_restraints     104
_refine_ls_restrained_S_all      1.081
_refine_ls_R_factor_all          0.0978
_refine_ls_R_factor_gt           0.0791
_refine_ls_shift/su_max          0.010
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1122P)²+23.1645P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1966
_refine_ls_wR_factor_ref         0.2124
_reflns_number_gt                2293
_reflns_number_total             2808
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg200308k_si_002.cif
_cod_data_source_block           5
_cod_database_code               4500793
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z'
'-y, x, z'
'y, -x, z'
'x+1/2, y+1/2, z+1/2'
'-x+1/2, -y+1/2, z+1/2'
'-y+1/2, x+1/2, z+1/2'
'y+1/2, -x+1/2, z+1/2'
'-x, -y, -z'
'x, y, -z'
'y, -x, -z'
'-y, x, -z'
'-x+1/2, -y+1/2, -z+1/2'
'x+1/2, y+1/2, -z+1/2'
'y+1/2, -x+1/2, -z+1/2'
'-y+1/2, x+1/2, -z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 1.0000 0.0000 0.931700(13) 0.0510(4) Uani 1 4 d S
C1 C 0.8873(6) 0.7952(6) 0.77282(13) 0.0382(14) Uani 1 1 d .
C2 C 0.7770(6) 0.8189(6) 0.78422(13) 0.0409(15) Uani 1 1 d .
C3 C 0.7461(6) 0.7592(7) 0.80765(16) 0.0498(17) Uani 1 1 d .
H3 H 0.6722 0.7745 0.8157 0.060 Uiso 1 1 calc R
C4 C 0.8222(7) 0.6774(7) 0.81945(15) 0.0506(17) Uani 1 1 d .
C5 C 0.9333(6) 0.6552(6) 0.80762(14) 0.0445(16) Uani 1 1 d .
H5 H 0.9854 0.6005 0.8155 0.053 Uiso 1 1 calc R
C6 C 0.9654(6) 0.7130(6) 0.78463(13) 0.0414(15) Uani 1 1 d .
C7 C 0.8242(8) 0.4974(8) 0.87847(16) 0.059(2) Uani 1 1 d .
C8 C 0.7544(10) 0.5590(9) 0.89678(19) 0.079(3) Uani 1 1 d .
H8 H 0.7157 0.6293 0.8917 0.095 Uiso 1 1 calc R
C9 C 0.7428(11) 0.5142(10) 0.9229(2) 0.092(4) Uani 1 1 d .
H9 H 0.6998 0.5570 0.9359 0.111 Uiso 1 1 calc R
C10 C 0.7946(9) 0.4067(8) 0.92976(17) 0.068(2) Uani 1 1 d .
H10 H 0.7836 0.3751 0.9470 0.082 Uiso 1 1 calc R
C11 C 0.8639(8) 0.3451(7) 0.91070(16) 0.0570(19) Uani 1 1 d .
C12 C 0.8767(7) 0.3923(7) 0.88584(17) 0.0560(19) Uani 1 1 d .
H12 H 0.9233 0.3518 0.8732 0.067 Uiso 1 1 calc R
C13 C 0.9189(8) 0.2284(7) 0.91844(16) 0.0566(19) Uani 1 1 d .
C14 C 1.0890(6) 0.6921(6) 0.77281(14) 0.0412(15) Uani 1 1 d .
H14A H 1.1134 0.6104 0.7766 0.049 Uiso 1 1 calc R
H14B H 1.0855 0.7017 0.7533 0.049 Uiso 1 1 calc R
C15 C 1.0000 0.0000 0.6802(4) 0.086(5) Uani 1 4 d SDU
C16 C 1.0000 0.0000 0.6513(4) 0.091(6) Uani 1 4 d SDU
H16A H 0.9714 -0.0758 0.6448 0.137 Uiso 0.25 1 calc PR
H16B H 1.0800 0.0131 0.6448 0.137 Uiso 0.25 1 calc PR
H16C H 0.9487 0.0627 0.6448 0.137 Uiso 0.25 1 calc PR
N1 N 0.7862(6) 0.6271(6) 0.84459(13) 0.0601(17) Uani 1 1 d .
N2 N 0.8490(6) 0.5404(6) 0.85174(13) 0.0562(16) Uani 1 1 d .
N3 N 1.0000 0.0000 0.7030(4) 0.124(7) Uani 1 4 d SDU
O1 O 0.9233(4) 0.8494(5) 0.74973(10) 0.0516(13) Uani 1 1 d .
H1 H 0.8708 0.8953 0.7445 0.077 Uiso 1 1 calc R
O2 O 0.8982(6) 0.1862(5) 0.94174(11) 0.0660(16) Uani 1 1 d .
O3 O 0.9844(5) 0.1773(5) 0.90157(10) 0.0588(14) Uani 1 1 d .
O1W O 1.0000 0.0000 0.9787(2) 0.066(3) Uani 1 4 d SU
H1WA H 0.9376 -0.0114 0.9879 0.079 Uiso 0.13 1 d PR
O2W O 1.0000 1.0000 0.8591(2) 0.079(4) Uani 1 4 d SU
H2WA H 0.9571 0.9528 0.8500 0.095 Uiso 0.13 1 d PR
O3W O 1.357(5) 0.579(4) 1.0000 0.213(18) Uani 0.50 2 d SPU
H3WA H 1.4054 0.6367 1.0000 0.256 Uiso 0.50 2 d SPR
H3WB H 1.2823 0.5732 1.0000 0.256 Uiso 0.50 2 d SPR
H3WC H 1.4122 0.5277 1.0000 0.256 Uiso 0.50 2 d SPR
O4 O 0.817(5) 0.249(5) 1.0000 0.243(16) Uani 0.50 2 d SPDU
N4 N 1.027(6) 0.304(6) 1.0000 0.241(16) Uani 0.50 2 d SPDU
C17 C 0.900(5) 0.318(8) 1.0000 0.241(16) Uani 0.50 2 d SPDU
H17 H 0.8753 0.3981 1.0000 0.290 Uiso 0.50 2 calc SPR
C18 C 1.096(4) 0.328(5) 0.9759(9) 0.239(17) Uani 0.50 1 d PDU
H18A H 1.1796 0.3132 0.9796 0.359 Uiso 0.50 1 calc PR
H18B H 1.0859 0.4098 0.9706 0.359 Uiso 0.50 1 calc PR
H18C H 1.0703 0.2761 0.9615 0.359 Uiso 0.50 1 calc PR
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1W Eu1 O2 78.21(13) . 3_645
O1W Eu1 O2 78.21(13) . 4_665
O2 Eu1 O2 156.4(3) 3_645 4_665
O1W Eu1 O2 78.21(13) . .
O2 Eu1 O2 87.61(5) 3_645 .
O2 Eu1 O2 87.61(5) 4_665 .
O1W Eu1 O2 78.21(13) . 2_755
O2 Eu1 O2 87.61(5) 3_645 2_755
O2 Eu1 O2 87.61(5) 4_665 2_755
O2 Eu1 O2 156.4(3) . 2_755
O1W Eu1 O3 126.76(13) . 3_645
O2 Eu1 O3 53.40(18) 3_645 3_645
O2 Eu1 O3 147.21(19) 4_665 3_645
O2 Eu1 O3 78.9(2) . 3_645
O2 Eu1 O3 115.9(2) 2_755 3_645
O1W Eu1 O3 126.76(13) . 2_755
O2 Eu1 O3 78.9(2) 3_645 2_755
O2 Eu1 O3 115.9(2) 4_665 2_755
O2 Eu1 O3 147.21(19) . 2_755
O2 Eu1 O3 53.40(18) 2_755 2_755
O3 Eu1 O3 69.01(13) 3_645 2_755
O1W Eu1 O3 126.76(13) . 4_665
O2 Eu1 O3 147.21(19) 3_645 4_665
O2 Eu1 O3 53.40(18) 4_665 4_665
O2 Eu1 O3 115.9(2) . 4_665
O2 Eu1 O3 78.9(2) 2_755 4_665
O3 Eu1 O3 106.5(3) 3_645 4_665
O3 Eu1 O3 69.01(13) 2_755 4_665
O1W Eu1 O3 126.76(13) . .
O2 Eu1 O3 115.9(2) 3_645 .
O2 Eu1 O3 78.9(2) 4_665 .
O2 Eu1 O3 53.40(18) . .
O2 Eu1 O3 147.21(19) 2_755 .
O3 Eu1 O3 69.01(13) 3_645 .
O3 Eu1 O3 106.5(3) 2_755 .
O3 Eu1 O3 69.01(13) 4_665 .
O1W Eu1 C13 103.57(17) . 3_645
O2 Eu1 C13 26.9(2) 3_645 3_645
O2 Eu1 C13 170.9(2) 4_665 3_645
O2 Eu1 C13 84.1(2) . 3_645
O2 Eu1 C13 101.5(2) 2_755 3_645
O3 Eu1 C13 26.6(2) 3_645 3_645
O3 Eu1 C13 70.4(2) 2_755 3_645
O3 Eu1 C13 127.8(2) 4_665 3_645
O3 Eu1 C13 93.1(2) . 3_645
O1W Eu1 C13 103.57(17) . 4_665
O2 Eu1 C13 170.9(2) 3_645 4_665
O2 Eu1 C13 26.9(2) 4_665 4_665
O2 Eu1 C13 101.5(2) . 4_665
O2 Eu1 C13 84.1(2) 2_755 4_665
O3 Eu1 C13 127.8(2) 3_645 4_665
O3 Eu1 C13 93.1(2) 2_755 4_665
O3 Eu1 C13 26.6(2) 4_665 4_665
O3 Eu1 C13 70.4(2) . 4_665
C13 Eu1 C13 152.9(3) 3_645 4_665
O1W Eu1 C13 103.57(17) . 2_755
O2 Eu1 C13 84.1(2) 3_645 2_755
O2 Eu1 C13 101.5(2) 4_665 2_755
O2 Eu1 C13 170.9(2) . 2_755
O2 Eu1 C13 26.9(2) 2_755 2_755
O3 Eu1 C13 93.1(2) 3_645 2_755
O3 Eu1 C13 26.6(2) 2_755 2_755
O3 Eu1 C13 70.4(2) 4_665 2_755
O3 Eu1 C13 127.8(2) . 2_755
C13 Eu1 C13 86.85(8) 3_645 2_755
C13 Eu1 C13 86.85(8) 4_665 2_755
O1 C1 C2 121.5(6) . .
O1 C1 C6 117.4(6) . .
C2 C1 C6 121.0(6) . .
C3 C2 C1 118.2(6) . .
C3 C2 C14 119.0(6) . 4_575
C1 C2 C14 122.7(6) . 4_575
C2 C3 C4 121.4(7) . .
C2 C3 H3 119.3 . .
C4 C3 H3 119.3 . .
C3 C4 C5 119.4(7) . .
C3 C4 N1 117.2(7) . .
C5 C4 N1 123.2(7) . .
C6 C5 C4 120.1(7) . .
C6 C5 H5 119.9 . .
C4 C5 H5 119.9 . .
C5 C6 C1 119.8(6) . .
C5 C6 C14 119.3(6) . .
C1 C6 C14 120.8(6) . .
C12 C7 C8 120.0(8) . .
C12 C7 N2 116.9(8) . .
C8 C7 N2 123.1(8) . .
C7 C8 C9 118.7(9) . .
C7 C8 H8 120.6 . .
C9 C8 H8 120.6 . .
C10 C9 C8 120.2(9) . .
C10 C9 H9 119.9 . .
C8 C9 H9 119.9 . .
C9 C10 C11 119.9(8) . .
C9 C10 H10 120.0 . .
C11 C10 H10 120.0 . .
C12 C11 C10 118.6(8) . .
C12 C11 C13 122.3(8) . .
C10 C11 C13 119.1(7) . .
C11 C12 C7 122.5(8) . .
C11 C12 H12 118.8 . .
C7 C12 H12 118.8 . .
O3 C13 O2 122.9(7) . .
O3 C13 C11 118.1(7) . .
O2 C13 C11 118.9(7) . .
O3 C13 Eu1 63.0(4) . .
O2 C13 Eu1 60.3(4) . .
C11 C13 Eu1 174.4(6) . .
C2 C14 C6 112.4(5) 3_755 .
C2 C14 H14A 109.1 3_755 .
C6 C14 H14A 109.1 . .
C2 C14 H14B 109.1 3_755 .
C6 C14 H14B 109.1 . .
H14A C14 H14B 107.9 . .
N3 C15 C16 180.000(5) . .
N2 N1 C4 113.3(7) . .
N1 N2 C7 114.4(7) . .
C1 O1 H1 109.5 . .
C13 O2 Eu1 92.8(5) . .
C13 O3 Eu1 90.4(5) . .
Eu1 O1W H1WA 122.6 . .
H3WA O3W H3WB 134.2 . .
H3WA O3W H3WC 93.2 . .
H3WB O3W H3WC 132.6 . .
C17 N4 C18 121(2) . 10_557
C17 N4 C18 121(2) . .
C18 N4 C18 111(6) 10_557 .
O4 C17 N4 133(9) . .
O4 C17 H17 113.4 . .
N4 C17 H17 113.4 . .
N4 C18 H18A 109.5 . .
N4 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
N4 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O1W 2.337(10) .
Eu1 O2 2.446(6) 3_645
Eu1 O2 2.446(6) 4_665
Eu1 O2 2.446(6) .
Eu1 O2 2.446(6) 2_755
Eu1 O3 2.506(5) 3_645
Eu1 O3 2.506(5) 2_755
Eu1 O3 2.506(5) 4_665
Eu1 O3 2.506(5) .
Eu1 C13 2.813(8) 3_645
Eu1 C13 2.813(8) 4_665
Eu1 C13 2.813(8) 2_755
C1 O1 1.364(8) .
C1 C2 1.393(9) .
C1 C6 1.408(9) .
C2 C3 1.391(10) .
C2 C14 1.524(9) 4_575
C3 C4 1.391(11) .
C3 H3 0.9400 .
C4 C5 1.407(10) .
C4 N1 1.433(10) .
C5 C6 1.366(10) .
C5 H5 0.9400 .
C6 C14 1.531(9) .
C7 C12 1.375(12) .
C7 C8 1.390(13) .
C7 N2 1.443(10) .
C8 C9 1.402(13) .
C8 H8 0.9400 .
C9 C10 1.388(13) .
C9 H9 0.9400 .
C10 C11 1.412(12) .
C10 H10 0.9400 .
C11 C12 1.355(11) .
C11 C13 1.505(11) .
C12 H12 0.9400 .
C13 O3 1.259(10) .
C13 O2 1.275(10) .
C14 C2 1.524(9) 3_755
C14 H14A 0.9800 .
C14 H14B 0.9800 .
C15 N3 1.138(16) .
C15 C16 1.437(17) .
C16 H16A 0.9700 .
C16 H16B 0.9700 .
C16 H16C 0.9700 .
N1 N2 1.259(9) .
O1 H1 0.8300 .
O1W H1WA 0.8501 .
O2W H2WA 0.8501 .
O3W H3WA 0.8481 .
O3W H3WB 0.8479 .
O3W H3WC 0.8479 .
O4 C17 1.22(2) .
N4 C17 1.44(2) .
N4 C18 1.458(19) 10_557
N4 C18 1.458(19) .
C17 H17 0.9400 .
C18 H18A 0.9700 .
C18 H18B 0.9700 .
C18 H18C 0.9700 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O1 C1 C2 C3 179.4(6) . .
C6 C1 C2 C3 0.1(10) . .
O1 C1 C2 C14 -3.5(10) . 4_575
C6 C1 C2 C14 177.2(6) . 4_575
C1 C2 C3 C4 -0.4(11) . .
C14 C2 C3 C4 -177.6(7) 4_575 .
C2 C3 C4 C5 0.6(12) . .
C2 C3 C4 N1 175.5(7) . .
C3 C4 C5 C6 -0.5(11) . .
N1 C4 C5 C6 -175.1(7) . .
C4 C5 C6 C1 0.1(10) . .
C4 C5 C6 C14 177.1(6) . .
O1 C1 C6 C5 -179.3(6) . .
C2 C1 C6 C5 0.1(10) . .
O1 C1 C6 C14 3.8(9) . .
C2 C1 C6 C14 -176.9(6) . .
C12 C7 C8 C9 2.4(16) . .
N2 C7 C8 C9 -175.3(10) . .
C7 C8 C9 C10 -3.7(19) . .
C8 C9 C10 C11 3.0(19) . .
C9 C10 C11 C12 -0.9(15) . .
C9 C10 C11 C13 -179.7(10) . .
C10 C11 C12 C7 -0.5(14) . .
C13 C11 C12 C7 178.3(8) . .
C8 C7 C12 C11 -0.3(14) . .
N2 C7 C12 C11 177.5(8) . .
C12 C11 C13 O3 4.2(13) . .
C10 C11 C13 O3 -177.0(8) . .
C12 C11 C13 O2 -176.4(8) . .
C10 C11 C13 O2 2.3(13) . .
C12 C11 C13 Eu1 -96(6) . .
C10 C11 C13 Eu1 83(6) . .
O1W Eu1 C13 O3 153.3(4) . .
O2 Eu1 C13 O3 -126.2(5) 3_645 .
O2 Eu1 C13 O3 77.0(5) 4_665 .
O2 Eu1 C13 O3 173.4(8) . .
O2 Eu1 C13 O3 53.0(15) 2_755 .
O3 Eu1 C13 O3 -82.1(5) 3_645 .
O3 Eu1 C13 O3 -41.4(7) 2_755 .
O3 Eu1 C13 O3 24.3(5) 4_665 .
C13 Eu1 C13 O3 -103.5(4) 3_645 .
C13 Eu1 C13 O3 50.1(5) 4_665 .
C13 Eu1 C13 O3 -26.7(4) 2_755 .
O1W Eu1 C13 O2 -20.0(5) . .
O2 Eu1 C13 O2 60.4(4) 3_645 .
O2 Eu1 C13 O2 -96.4(5) 4_665 .
O2 Eu1 C13 O2 -120.3(13) 2_755 .
O3 Eu1 C13 O2 104.5(5) 3_645 .
O3 Eu1 C13 O2 145.2(5) 2_755 .
O3 Eu1 C13 O2 -149.1(5) 4_665 .
O3 Eu1 C13 O2 -173.4(8) . .
C13 Eu1 C13 O2 83.2(5) 3_645 .
C13 Eu1 C13 O2 -123.2(5) 4_665 .
C13 Eu1 C13 O2 160.0(5) 2_755 .
O1W Eu1 C13 C11 -104(6) . .
O2 Eu1 C13 C11 -23(6) 3_645 .
O2 Eu1 C13 C11 180(100) 4_665 .
O2 Eu1 C13 C11 -84(6) . .
O2 Eu1 C13 C11 156(5) 2_755 .
O3 Eu1 C13 C11 21(6) 3_645 .
O3 Eu1 C13 C11 62(6) 2_755 .
O3 Eu1 C13 C11 127(6) 4_665 .
O3 Eu1 C13 C11 103(6) . .
C13 Eu1 C13 C11 -1(6) 3_645 .
C13 Eu1 C13 C11 153(6) 4_665 .
C13 Eu1 C13 C11 76(6) 2_755 .
C5 C6 C14 C2 -88.8(8) . 3_755
C1 C6 C14 C2 88.2(7) . 3_755
C3 C4 N1 N2 168.9(7) . .
C5 C4 N1 N2 -16.4(11) . .
C4 N1 N2 C7 172.7(7) . .
C12 C7 N2 N1 170.3(7) . .
C8 C7 N2 N1 -11.9(13) . .
O3 C13 O2 Eu1 -7.1(8) . .
C11 C13 O2 Eu1 173.6(7) . .
O1W Eu1 O2 C13 160.1(5) . .
O2 Eu1 O2 C13 -121.4(5) 3_645 .
O2 Eu1 O2 C13 81.7(5) 4_665 .
O2 Eu1 O2 C13 160.1(5) 2_755 .
O3 Eu1 O2 C13 -68.3(5) 3_645 .
O3 Eu1 O2 C13 -56.3(6) 2_755 .
O3 Eu1 O2 C13 34.8(5) 4_665 .
O3 Eu1 O2 C13 3.7(5) . .
C13 Eu1 O2 C13 -94.7(5) 3_645 .
C13 Eu1 O2 C13 58.4(5) 4_665 .
C13 Eu1 O2 C13 -97.6(15) 2_755 .
O2 C13 O3 Eu1 6.9(8) . .
C11 C13 O3 Eu1 -173.8(7) . .
O1W Eu1 O3 C13 -33.0(5) . .
O2 Eu1 O3 C13 61.5(5) 3_645 .
O2 Eu1 O3 C13 -99.0(5) 4_665 .
O2 Eu1 O3 C13 -3.7(5) . .
O2 Eu1 O3 C13 -166.6(5) 2_755 .
O3 Eu1 O3 C13 87.9(6) 3_645 .
O3 Eu1 O3 C13 147.0(5) 2_755 .
O3 Eu1 O3 C13 -153.9(5) 4_665 .
C13 Eu1 O3 C13 76.5(4) 3_645 .
C13 Eu1 O3 C13 -125.6(5) 4_665 .
C13 Eu1 O3 C13 165.0(3) 2_755 .
C18 N4 C17 O4 -106(6) 10_557 .
C18 N4 C17 O4 106(6) . .
