#------------------------------------------------------------------------------
#$Date: 2016-02-14 06:40:26 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176432 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/21/4502190.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4502190
loop_
_publ_author_name
'Li, Hao-Hong'
'Chen, Zhi-Rong'
'Sun, Ling-Guo'
'Lian, Zhao-Xun'
'Chen, Xiao-Bo'
'Li, Jun-Bo'
'Li, Jun-Qian'
_publ_section_title
;
 Two Iodoargentate Hybrid Coordination Polymers Induced by
 Transition-Metal Complexes: Structures and Properties
;
_journal_issue                   3
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              1068
_journal_paper_doi               10.1021/cg900476m
_journal_volume                  10
_journal_year                    2010
_chemical_formula_moiety         'C30 H24 Cu N6, Ag5 I7'
_chemical_formula_sum            'C30 H24 Ag5 Cu I7 N6'
_chemical_formula_weight         1959.75
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           19
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   13.681(3)
_cell_length_b                   14.016(3)
_cell_length_c                   23.383(5)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      18
_cell_measurement_theta_min      12
_cell_volume                     4483.8(17)
_computing_cell_refinement       'TEXRAY software'
_computing_data_collection
'TEXRAY software (Molecular Structure Corporation, 1999)'
_computing_data_reduction
'TEXSAN (Molecular Structure Corporation, 1999)'
_computing_molecular_graphics    'ORTEX (P.McArdle, 1995)'
_computing_publication_material  'SHELXL-97/2 (Sheldrick,1997)')'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean None
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Rigaku Weissenberg IP'
_diffrn_measurement_method       'scintillation counter'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'rotor target'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0000
_diffrn_reflns_av_sigmaI/netI    0.2755
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            5683
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         1.69
_diffrn_standards_decay_%        'not measured'
_diffrn_standards_interval_count 'not measured'
_diffrn_standards_interval_time  'not measured'
_diffrn_standards_number         None
_exptl_absorpt_coefficient_mu    7.455
_exptl_absorpt_correction_T_max  0.225
_exptl_absorpt_correction_T_min  0.152
_exptl_absorpt_correction_type   PSI-Scans
_exptl_absorpt_process_details
'TEXRAY software (Molecular Structure Corporation, 1999)'
_exptl_crystal_colour            Blue
_exptl_crystal_density_diffrn    2.903
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Parallelepiped
_exptl_crystal_F_000             3524
_exptl_crystal_size_max          0.50
_exptl_crystal_size_mid          0.40
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.459
_refine_diff_density_min         -1.873
_refine_diff_density_rms         0.653
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.49(11)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.719
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     280
_refine_ls_number_reflns         5683
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.719
_refine_ls_R_factor_all          0.1880
_refine_ls_R_factor_gt           0.0412
_refine_ls_shift/su_max          0.066
_refine_ls_shift/su_mean         0.005
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0764P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0848
_refine_ls_wR_factor_ref         0.1718
_reflns_number_gt                1688
_reflns_number_total             5683
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg900476m_si_002.cif
_cod_data_source_block           lihh
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_cell_volume        4483.9(17)
_cod_original_sg_symbol_Hall     P2ac2ab
_cod_original_sg_symbol_H-M      P212121
_cod_database_code               4502190
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
I1 I 1.0008(2) 0.26946(14) 0.25331(10) 0.0538(6) Uani 1 1 d .
I2 I 1.0137(2) 0.51744(16) 0.36734(9) 0.0619(7) Uani 1 1 d .
I3 I 0.80734(17) 0.52892(17) 0.20649(10) 0.0550(7) Uani 1 1 d .
I4 I 1.16863(18) 0.52622(19) 0.18941(10) 0.0599(7) Uani 1 1 d .
I5 I 1.2620(2) 0.22216(19) 0.12123(10) 0.0681(8) Uani 1 1 d .
I6 I 0.6965(2) 0.2190(2) 0.16628(12) 0.0778(8) Uani 1 1 d .
I7 I 0.96201(18) 0.36160(16) 0.06117(10) 0.0576(7) Uani 1 1 d .
Ag1 Ag 0.9930(2) 0.4781(2) 0.24443(14) 0.0671(8) Uani 1 1 d .
Ag2 Ag 0.8581(3) 0.3394(2) 0.16317(13) 0.0782(10) Uani 1 1 d .
Ag3 Ag 1.1257(3) 0.1364(3) 0.19153(15) 0.0861(11) Uani 1 1 d .
Ag4 Ag 0.8588(3) 0.1246(3) 0.20220(14) 0.0876(11) Uani 1 1 d .
Ag5 Ag 1.1068(3) 0.3468(3) 0.14329(14) 0.0898(12) Uani 1 1 d .
Cu1 Cu 0.5278(3) 0.1470(3) 0.41542(16) 0.0454(10) Uani 1 1 d .
N1 N 0.4588(16) 0.0335(17) 0.4456(11) 0.039(6) Uani 1 1 d .
N2 N 0.653(2) 0.0545(17) 0.4486(11) 0.045(7) Uani 1 1 d .
N3 N 0.619(2) 0.260(2) 0.3972(12) 0.066(9) Uani 1 1 d .
N4 N 0.5269(18) 0.2251(16) 0.4894(9) 0.038(7) Uani 1 1 d .
N5 N 0.5057(19) 0.1019(16) 0.3347(11) 0.046(7) Uani 1 1 d .
N6 N 0.395(2) 0.234(2) 0.3832(11) 0.062(9) Uani 1 1 d .
C1 C 0.367(3) 0.028(3) 0.4371(15) 0.065(4) Uani 1 1 d .
H1 H 0.3328 0.0778 0.4196 0.078 Uiso 1 1 calc R
C2 C 0.320(3) -0.054(2) 0.4551(14) 0.065(4) Uani 1 1 d .
H2 H 0.2523 -0.0561 0.4534 0.078 Uiso 1 1 calc R
C3 C 0.367(3) -0.130(3) 0.4748(13) 0.065(4) Uani 1 1 d .
H3 H 0.3328 -0.1857 0.4836 0.078 Uiso 1 1 calc R
C4 C 0.468(3) -0.126(2) 0.4820(14) 0.065(4) Uani 1 1 d .
H4 H 0.5045 -0.1767 0.4957 0.078 Uiso 1 1 calc R
C5 C 0.512(3) -0.034(2) 0.4664(15) 0.065(4) Uani 1 1 d .
C6 C 0.613(3) -0.024(3) 0.4734(15) 0.065(4) Uani 1 1 d .
C7 C 0.679(3) -0.083(3) 0.5038(15) 0.065(4) Uani 1 1 d .
H7 H 0.6586 -0.1400 0.5206 0.078 Uiso 1 1 calc R
C8 C 0.776(3) -0.054(2) 0.5078(15) 0.065(4) Uani 1 1 d .
H8 H 0.8191 -0.0924 0.5280 0.078 Uiso 1 1 calc R
C9 C 0.812(3) 0.026(3) 0.4846(14) 0.065(4) Uani 1 1 d .
H9 H 0.8770 0.0437 0.4886 0.078 Uiso 1 1 calc R
C10 C 0.746(3) 0.080(3) 0.4544(14) 0.065(4) Uani 1 1 d .
H10 H 0.7667 0.1370 0.4376 0.078 Uiso 1 1 calc R
C11 C 0.660(3) 0.264(3) 0.3501(16) 0.068(4) Uani 1 1 d .
H11 H 0.6517 0.2152 0.3238 0.081 Uiso 1 1 calc R
C12 C 0.716(3) 0.343(3) 0.3364(16) 0.068(4) Uani 1 1 d .
H12 H 0.7437 0.3493 0.3001 0.081 Uiso 1 1 calc R
C13 C 0.732(3) 0.411(3) 0.3784(15) 0.068(4) Uani 1 1 d .
H13 H 0.7760 0.4608 0.3729 0.081 Uiso 1 1 calc R
C14 C 0.681(3) 0.405(3) 0.4259(16) 0.068(4) Uani 1 1 d .
H14 H 0.6857 0.4529 0.4530 0.081 Uiso 1 1 calc R
C15 C 0.621(3) 0.325(3) 0.4368(17) 0.068(4) Uani 1 1 d .
C16 C 0.578(3) 0.303(3) 0.4861(17) 0.068(4) Uani 1 1 d .
C17 C 0.578(3) 0.355(3) 0.5343(14) 0.068(4) Uani 1 1 d .
H17 H 0.6168 0.4089 0.5347 0.081 Uiso 1 1 calc R
C18 C 0.527(3) 0.336(2) 0.5815(16) 0.068(4) Uani 1 1 d .
H18 H 0.5298 0.3772 0.6126 0.081 Uiso 1 1 calc R
C19 C 0.472(3) 0.255(2) 0.5835(15) 0.068(4) Uani 1 1 d .
H19 H 0.4371 0.2358 0.6156 0.081 Uiso 1 1 calc R
C20 C 0.474(3) 0.205(2) 0.5340(15) 0.068(4) Uani 1 1 d .
H20 H 0.4340 0.1514 0.5316 0.081 Uiso 1 1 calc R
C21 C 0.556(3) 0.035(3) 0.3187(17) 0.084(4) Uani 1 1 d .
H21 H 0.6015 0.0100 0.3441 0.101 Uiso 1 1 calc R
C22 C 0.548(3) -0.008(3) 0.2605(16) 0.084(4) Uani 1 1 d .
H22 H 0.5795 -0.0653 0.2511 0.101 Uiso 1 1 calc R
C23 C 0.493(3) 0.040(3) 0.2219(17) 0.084(4) Uani 1 1 d .
H23 H 0.4908 0.0234 0.1835 0.101 Uiso 1 1 calc R
C24 C 0.437(3) 0.120(3) 0.2439(16) 0.084(4) Uani 1 1 d .
H24 H 0.3958 0.1543 0.2200 0.101 Uiso 1 1 calc R
C25 C 0.447(3) 0.146(3) 0.3033(17) 0.084(4) Uani 1 1 d .
C26 C 0.383(3) 0.219(3) 0.3290(17) 0.084(4) Uani 1 1 d .
C27 C 0.315(3) 0.274(3) 0.2982(17) 0.084(4) Uani 1 1 d .
H27 H 0.3091 0.2644 0.2590 0.101 Uiso 1 1 calc R
C28 C 0.259(3) 0.340(3) 0.3242(16) 0.084(4) Uani 1 1 d .
H28 H 0.2182 0.3813 0.3042 0.101 Uiso 1 1 calc R
C29 C 0.268(3) 0.342(3) 0.3841(16) 0.084(4) Uani 1 1 d .
H29 H 0.2257 0.3788 0.4058 0.101 Uiso 1 1 calc R
C30 C 0.340(3) 0.290(3) 0.4105(18) 0.084(4) Uani 1 1 d .
H30 H 0.3490 0.2965 0.4498 0.101 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
I I -0.4742 1.8119 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ag3 I1 Ag1 128.65(13) . .
Ag3 I1 Ag2 103.87(12) . .
Ag1 I1 Ag2 66.76(10) . .
Ag3 I1 Ag4 75.70(10) . .
Ag1 I1 Ag4 127.73(13) . .
Ag2 I1 Ag4 62.22(11) . .
Ag3 I1 Ag5 62.91(11) . .
Ag1 I1 Ag5 67.39(10) . .
Ag2 I1 Ag5 67.51(10) . .
Ag4 I1 Ag5 101.67(11) . .
Ag4 I2 Ag3 79.96(11) 3_755 3_755
Ag4 I2 Ag1 66.14(10) 3_755 .
Ag3 I2 Ag1 65.02(10) 3_755 .
Ag1 I3 Ag2 70.23(11) . .
Ag1 I3 Ag3 65.90(11) . 3_755
Ag2 I3 Ag3 131.77(13) . 3_755
Ag1 I4 Ag5 73.09(11) . .
Ag1 I4 Ag4 66.68(11) . 3_755
Ag5 I4 Ag4 134.90(14) . 3_755
Ag3 I5 Ag5 69.49(13) . .
Ag4 I6 Ag2 69.79(13) . .
Ag5 I7 Ag2 76.33(12) . .
I3 Ag1 I4 125.01(13) . .
I3 Ag1 I1 108.11(13) . .
I4 Ag1 I1 103.91(13) . .
I3 Ag1 I2 110.60(13) . .
I4 Ag1 I2 108.68(13) . .
I1 Ag1 I2 96.54(11) . .
I3 Ag1 Ag3 59.86(10) . 3_755
I4 Ag1 Ag3 119.54(13) . 3_755
I1 Ag1 Ag3 133.74(14) . 3_755
I2 Ag1 Ag3 56.61(10) . 3_755
I3 Ag1 Ag4 123.25(13) . 3_755
I4 Ag1 Ag4 58.21(10) . 3_755
I1 Ag1 Ag4 126.81(14) . 3_755
I2 Ag1 Ag4 55.06(10) . 3_755
Ag3 Ag1 Ag4 71.45(11) 3_755 3_755
I3 Ag1 Ag2 56.94(10) . .
I4 Ag1 Ag2 110.96(12) . .
I1 Ag1 Ag2 58.10(10) . .
I2 Ag1 Ag2 136.92(13) . .
Ag3 Ag1 Ag2 113.87(14) 3_755 .
Ag4 Ag1 Ag2 168.03(14) 3_755 .
I3 Ag1 Ag5 109.70(12) . .
I4 Ag1 Ag5 54.22(10) . .
I1 Ag1 Ag5 59.29(10) . .
I2 Ag1 Ag5 137.90(13) . .
Ag3 Ag1 Ag5 163.82(14) 3_755 .
Ag4 Ag1 Ag5 109.66(13) 3_755 .
Ag2 Ag1 Ag5 62.07(10) . .
I6 Ag2 I7 119.62(14) . .
I6 Ag2 I3 110.68(14) . .
I7 Ag2 I3 108.37(12) . .
I6 Ag2 I1 107.27(12) . .
I7 Ag2 I1 107.53(13) . .
I3 Ag2 I1 101.85(12) . .
I6 Ag2 Ag4 54.16(10) . .
I7 Ag2 Ag4 110.63(14) . .
I3 Ag2 Ag4 140.27(13) . .
I1 Ag2 Ag4 59.16(10) . .
I6 Ag2 Ag1 142.19(14) . .
I7 Ag2 Ag1 98.16(12) . .
I3 Ag2 Ag1 52.83(9) . .
I1 Ag2 Ag1 55.14(9) . .
Ag4 Ag2 Ag1 113.37(12) . .
I5 Ag3 I2 114.47(14) . 3_745
I5 Ag3 I1 114.36(15) . .
I2 Ag3 I1 102.65(13) 3_745 .
I5 Ag3 I3 119.42(14) . 3_745
I2 Ag3 I3 107.14(13) 3_745 3_745
I1 Ag3 I3 96.18(12) . 3_745
I5 Ag3 Ag1 160.66(16) . 3_745
I2 Ag3 Ag1 58.37(10) 3_745 3_745
I1 Ag3 Ag1 84.97(11) . 3_745
I3 Ag3 Ag1 54.24(10) 3_745 3_745
I5 Ag3 Ag5 55.79(11) . .
I2 Ag3 Ag5 108.32(14) 3_745 .
I1 Ag3 Ag5 62.14(11) . .
I3 Ag3 Ag5 141.66(14) 3_745 .
Ag1 Ag3 Ag5 141.97(15) 3_745 .
I6 Ag4 I2 125.93(15) . 3_745
I6 Ag4 I4 113.23(14) . 3_745
I2 Ag4 I4 109.27(13) 3_745 3_745
I6 Ag4 I1 108.46(14) . .
I2 Ag4 I1 100.77(13) 3_745 .
I4 Ag4 I1 93.23(12) 3_745 .
I6 Ag4 Ag1 165.37(17) . 3_745
I2 Ag4 Ag1 58.80(10) 3_745 3_745
I4 Ag4 Ag1 55.11(10) 3_745 3_745
I1 Ag4 Ag1 82.45(11) . 3_745
I6 Ag4 Ag2 56.05(11) . .
I2 Ag4 Ag2 110.17(13) 3_745 .
I4 Ag4 Ag2 134.88(14) 3_745 .
I1 Ag4 Ag2 58.62(10) . .
Ag1 Ag4 Ag2 137.92(15) 3_745 .
I7 Ag5 I5 117.54(14) . .
I7 Ag5 I4 114.01(14) . .
I5 Ag5 I4 113.18(15) . .
I7 Ag5 I1 105.27(14) . .
I5 Ag5 I1 106.60(13) . .
I4 Ag5 I1 97.51(11) . .
I7 Ag5 Ag3 112.05(14) . .
I5 Ag5 Ag3 54.72(10) . .
I4 Ag5 Ag3 131.24(13) . .
I1 Ag5 Ag3 54.95(10) . .
I7 Ag5 Ag1 96.59(12) . .
I5 Ag5 Ag1 145.04(14) . .
I4 Ag5 Ag1 52.69(9) . .
I1 Ag5 Ag1 53.32(8) . .
Ag3 Ag5 Ag1 107.20(13) . .
N1 Cu1 N5 90.5(10) . .
N1 Cu1 N4 97.2(10) . .
N5 Cu1 N4 163.6(10) . .
N1 Cu1 N3 168.5(10) . .
N5 Cu1 N3 98.0(10) . .
N4 Cu1 N3 76.6(11) . .
N1 Cu1 N2 77.3(9) . .
N5 Cu1 N2 104.6(10) . .
N4 Cu1 N2 91.2(9) . .
N3 Cu1 N2 92.9(10) . .
N1 Cu1 N6 99.5(10) . .
N5 Cu1 N6 75.1(10) . .
N4 Cu1 N6 89.4(10) . .
N3 Cu1 N6 90.3(11) . .
N2 Cu1 N6 176.7(10) . .
C1 N1 C5 125(3) . .
C1 N1 Cu1 117(3) . .
C5 N1 Cu1 117(2) . .
C10 N2 C6 124(3) . .
C10 N2 Cu1 127(2) . .
C6 N2 Cu1 108(2) . .
C11 N3 C15 126(4) . .
C11 N3 Cu1 120(3) . .
C15 N3 Cu1 114(3) . .
C20 N4 C16 122(3) . .
C20 N4 Cu1 124(2) . .
C16 N4 Cu1 113(2) . .
C21 N5 C25 124(4) . .
C21 N5 Cu1 116(3) . .
C25 N5 Cu1 120(3) . .
C30 N6 C26 122(4) . .
C30 N6 Cu1 129(3) . .
C26 N6 Cu1 109(3) . .
N1 C1 C2 117(4) . .
N1 C1 H1 121.5 . .
C2 C1 H1 121.5 . .
C3 C2 C1 124(4) . .
C3 C2 H2 118.2 . .
C1 C2 H2 118.2 . .
C2 C3 C4 119(4) . .
C2 C3 H3 120.6 . .
C4 C3 H3 120.5 . .
C3 C4 C5 115(4) . .
C3 C4 H4 122.7 . .
C5 C4 H4 122.6 . .
N1 C5 C6 122(4) . .
N1 C5 C4 120(4) . .
C6 C5 C4 118(4) . .
N2 C6 C5 116(4) . .
N2 C6 C7 115(4) . .
C5 C6 C7 129(4) . .
C8 C7 C6 118(4) . .
C8 C7 H7 121.1 . .
C6 C7 H7 121.1 . .
C9 C8 C7 125(4) . .
C9 C8 H8 117.6 . .
C7 C8 H8 117.6 . .
C8 C9 C10 116(4) . .
C8 C9 H9 122.2 . .
C10 C9 H9 122.3 . .
N2 C10 C9 122(4) . .
N2 C10 H10 119.1 . .
C9 C10 H10 119.0 . .
N3 C11 C12 120(4) . .
N3 C11 H11 120.0 . .
C12 C11 H11 119.9 . .
C11 C12 C13 118(4) . .
C11 C12 H12 121.0 . .
C13 C12 H12 121.0 . .
C14 C13 C12 118(4) . .
C14 C13 H13 121.0 . .
C12 C13 H13 121.0 . .
C13 C14 C15 121(4) . .
C13 C14 H14 119.4 . .
C15 C14 H14 119.3 . .
N3 C15 C16 116(4) . .
N3 C15 C14 116(4) . .
C16 C15 C14 127(4) . .
N4 C16 C15 119(4) . .
N4 C16 C17 114(4) . .
C15 C16 C17 127(4) . .
C18 C17 C16 126(4) . .
C18 C17 H17 116.8 . .
C16 C17 H17 116.8 . .
C17 C18 C19 119(4) . .
C17 C18 H18 120.7 . .
C19 C18 H18 120.7 . .
C20 C19 C18 113(4) . .
C20 C19 H19 123.5 . .
C18 C19 H19 123.5 . .
N4 C20 C19 126(4) . .
N4 C20 H20 117.2 . .
C19 C20 H20 117.1 . .
N5 C21 C22 124(4) . .
N5 C21 H21 118.2 . .
C22 C21 H21 118.2 . .
C23 C22 C21 116(4) . .
C23 C22 H22 122.1 . .
C21 C22 H22 122.1 . .
C22 C23 C24 116(4) . .
C22 C23 H23 121.8 . .
C24 C23 H23 121.8 . .
C23 C24 C25 119(4) . .
C23 C24 H24 120.4 . .
C25 C24 H24 120.4 . .
N5 C25 C24 120(4) . .
N5 C25 C26 119(4) . .
C24 C25 C26 121(4) . .
N6 C26 C27 120(4) . .
N6 C26 C25 116(4) . .
C27 C26 C25 124(4) . .
C28 C27 C26 121(4) . .
C28 C27 H27 119.3 . .
C26 C27 H27 119.3 . .
C27 C28 C29 114(4) . .
C27 C28 H28 122.9 . .
C29 C28 H28 122.9 . .
C30 C29 C28 120(4) . .
C30 C29 H29 119.9 . .
C28 C29 H29 119.9 . .
N6 C30 C29 122(4) . .
N6 C30 H30 119.1 . .
C29 C30 H30 119.1 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
I1 Ag3 2.913(4) .
I1 Ag1 2.934(3) .
I1 Ag2 3.036(4) .
I1 Ag4 3.054(5) .
I1 Ag5 3.146(4) .
I2 Ag4 2.818(4) 3_755
I2 Ag3 2.883(4) 3_755
I2 Ag1 2.940(4) .
I3 Ag1 2.783(4) .
I3 Ag2 2.926(4) .
I3 Ag3 2.965(4) 3_755
I4 Ag1 2.808(4) .
I4 Ag5 2.864(4) .
I4 Ag4 2.910(4) 3_755
I5 Ag3 2.762(4) .
I5 Ag5 2.797(4) .
I6 Ag4 2.718(4) .
I6 Ag2 2.781(4) .
I7 Ag5 2.767(4) .
I7 Ag2 2.794(4) .
Ag1 Ag3 3.130(5) 3_755
Ag1 Ag4 3.143(5) 3_755
Ag1 Ag2 3.286(5) .
Ag1 Ag5 3.378(5) .
Ag2 Ag4 3.147(5) .
Ag3 I2 2.883(4) 3_745
Ag3 I3 2.965(4) 3_745
Ag3 Ag1 3.130(5) 3_745
Ag3 Ag5 3.168(5) .
Ag4 I2 2.818(4) 3_745
Ag4 I4 2.910(4) 3_745
Ag4 Ag1 3.143(5) 3_745
Cu1 N1 1.98(2) .
Cu1 N5 2.01(3) .
Cu1 N4 2.05(2) .
Cu1 N3 2.06(3) .
Cu1 N2 2.28(3) .
Cu1 N6 2.32(3) .
N1 C1 1.27(4) .
N1 C5 1.29(4) .
N2 C10 1.33(4) .
N2 C6 1.36(4) .
N3 C11 1.23(4) .
N3 C15 1.30(4) .
N4 C20 1.30(4) .
N4 C16 1.29(4) .
N5 C21 1.22(4) .
N5 C25 1.25(4) .
N6 C30 1.26(4) .
N6 C26 1.29(4) .
C1 C2 1.39(4) .
C1 H1 0.9300 .
C2 C3 1.33(5) .
C2 H2 0.9300 .
C3 C4 1.39(5) .
C3 H3 0.9300 .
C4 C5 1.46(4) .
C4 H4 0.9300 .
C5 C6 1.40(5) .
C6 C7 1.42(5) .
C7 C8 1.39(5) .
C7 H7 0.9300 .
C8 C9 1.33(4) .
C8 H8 0.9300 .
C9 C10 1.38(5) .
C9 H9 0.9300 .
C10 H10 0.9300 .
C11 C12 1.38(5) .
C11 H11 0.9300 .
C12 C13 1.39(5) .
C12 H12 0.9300 .
C13 C14 1.31(5) .
C13 H13 0.9300 .
C14 C15 1.41(5) .
C14 H14 0.9300 .
C15 C16 1.33(5) .
C16 C17 1.34(4) .
C17 C18 1.33(4) .
C17 H17 0.9300 .
C18 C19 1.37(5) .
C18 H18 0.9300 .
C19 C20 1.35(4) .
C19 H19 0.9300 .
C20 H20 0.9300 .
C21 C22 1.50(5) .
C21 H21 0.9300 .
C22 C23 1.36(5) .
C22 H22 0.9300 .
C23 C24 1.45(5) .
C23 H23 0.9300 .
C24 C25 1.44(5) .
C24 H24 0.9300 .
C25 C26 1.48(6) .
C26 C27 1.40(5) .
C27 C28 1.35(5) .
C27 H27 0.9300 .
C28 C29 1.41(5) .
C28 H28 0.9300 .
C29 C30 1.37(5) .
C29 H29 0.9300 .
C30 H30 0.9300 .
