#------------------------------------------------------------------------------
#$Date: 2016-03-24 02:04:51 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179555 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/24/4502436.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4502436
loop_
_publ_author_name
'Li, Cheng-Peng'
'Chen, Jing'
'Yu, Qian'
'Du, Miao'
_publ_section_title
;
 Structural Modulation and Properties of Silver(I) Coordination Frameworks
 with Benzenedicarboxyl Tectons
 andtrans-1-(2-Pyridyl)-2-(4-pyridyl)ethylene Spacer
;
_journal_issue                   4
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              1623
_journal_paper_doi               10.1021/cg901188g
_journal_volume                  10
_journal_year                    2010
_chemical_formula_sum            'C64 H52 Ag6 Br2 N10 O17'
_chemical_formula_weight         2040.20
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                94.2270(10)
_cell_angle_beta                 97.3120(10)
_cell_angle_gamma                90.7090(10)
_cell_formula_units_Z            2
_cell_length_a                   10.6107(4)
_cell_length_b                   17.4900(6)
_cell_length_c                   18.1407(6)
_cell_measurement_reflns_used    5231
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      24.21
_cell_measurement_theta_min      2.28
_cell_volume                     3329.3(2)
_computing_cell_refinement       'Bruker APEX II'
_computing_data_collection       'Bruker APEX II'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'APEX II CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0225
_diffrn_reflns_av_sigmaI/netI    0.0481
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            17298
_diffrn_reflns_theta_full        25.03
_diffrn_reflns_theta_max         25.03
_diffrn_reflns_theta_min         1.13
_exptl_absorpt_coefficient_mu    3.008
_exptl_absorpt_correction_T_max  1.000000
_exptl_absorpt_correction_T_min  0.615603
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            COLORLESS
_exptl_crystal_density_diffrn    2.035
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       BLOCK
_exptl_crystal_F_000             1988
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.16
_refine_diff_density_max         1.065
_refine_diff_density_min         -0.775
_refine_diff_density_rms         0.097
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.049
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     892
_refine_ls_number_reflns         11727
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.049
_refine_ls_R_factor_all          0.0633
_refine_ls_R_factor_gt           0.0382
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0507P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0909
_refine_ls_wR_factor_ref         0.1033
_reflns_number_gt                8472
_reflns_number_total             11727
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg901188g_si_002.cif
_cod_data_source_block           5
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from
2011-04-26.

'_exptl_absorpt_correction_type' value 'MULTI-SCAN'
changed to 'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'NONE' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4502436
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 1.08950(4) 0.39709(3) 0.82617(3) 0.05470(14) Uani 1 1 d .
Ag2 Ag 1.09868(4) 0.20751(3) 0.84181(2) 0.05094(13) Uani 1 1 d .
Ag3 Ag 1.01735(4) 0.22563(2) 0.68578(2) 0.04523(12) Uani 1 1 d .
Ag4 Ag 0.76152(4) -0.25268(2) 0.46304(3) 0.04969(13) Uani 1 1 d .
Ag5 Ag 0.50146(5) -0.24453(3) 0.68210(3) 0.05785(14) Uani 1 1 d .
Ag6 Ag 0.48257(5) -0.13091(3) 0.93867(3) 0.05936(15) Uani 1 1 d .
Br1 Br 0.68574(6) 0.02368(3) 0.71893(4) 0.05539(17) Uani 1 1 d .
Br2 Br 1.44035(6) 0.14082(3) 0.79218(4) 0.05921(18) Uani 1 1 d .
O1 O 1.2455(3) 0.2963(2) 0.8067(2) 0.0476(10) Uani 1 1 d .
O2 O 1.2314(3) 0.2685(2) 0.6846(2) 0.0485(10) Uani 1 1 d .
O3 O 1.9017(4) 0.2701(3) 0.8065(4) 0.0924(18) Uani 1 1 d .
O4 O 1.8871(4) 0.3880(3) 0.7700(3) 0.0903(17) Uani 1 1 d .
O5 O 0.9642(5) 0.0997(2) 0.6872(2) 0.0667(13) Uani 1 1 d .
O6 O 1.0375(6) 0.0861(2) 0.8044(3) 0.0855(17) Uani 1 1 d .
O7 O 0.7324(4) -0.2822(2) 0.7083(2) 0.0493(10) Uani 1 1 d .
O8 O 0.9371(4) -0.3084(2) 0.7149(3) 0.0711(14) Uani 1 1 d .
O9 O 0.5017(4) -0.1430(3) 0.7929(2) 0.0656(12) Uani 1 1 d .
O10 O 0.3628(6) -0.1172(3) 0.7040(3) 0.104(2) Uani 1 1 d .
O11 O 0.3822(5) -0.0474(3) 0.8056(3) 0.0829(15) Uani 1 1 d .
O12 O 0.4787(5) -0.3299(3) 0.7729(3) 0.1012(19) Uani 1 1 d .
O13 O 0.3044(6) -0.3613(4) 0.7072(3) 0.108(2) Uani 1 1 d .
O14 O 0.3935(7) -0.4377(4) 0.7843(4) 0.129(3) Uani 1 1 d .
O15 O 1.1690(5) 0.4702(2) 0.7298(3) 0.0744(14) Uani 1 1 d .
H15A H 1.2288 0.5030 0.7434 0.112 Uiso 1 1 d R
H15B H 1.0951 0.4878 0.7192 0.112 Uiso 1 1 d R
O16 O 0.3006(5) 0.4301(3) 0.2433(3) 0.0903(17) Uani 1 1 d .
H16A H 0.2610 0.3874 0.2424 0.136 Uiso 1 1 d R
H16B H 0.3816 0.4280 0.2479 0.136 Uiso 1 1 d R
O17 O 0.0523(5) 0.4627(3) 0.3038(4) 0.110(2) Uani 1 1 d .
H17A H 0.0398 0.4446 0.2586 0.165 Uiso 1 1 d R
H17B H 0.1150 0.4938 0.3157 0.165 Uiso 1 1 d R
N1 N 0.6692(4) 0.2135(3) 1.0608(3) 0.0528(13) Uani 1 1 d .
N2 N 1.1801(4) 0.4514(3) 0.9369(3) 0.0463(12) Uani 1 1 d .
N3 N 1.1869(4) 0.2212(2) 0.9637(2) 0.0362(10) Uani 1 1 d .
N4 N 0.6355(5) -0.0486(3) 0.9719(3) 0.0473(12) Uani 1 1 d .
N5 N 0.9380(4) 0.2809(2) 0.5791(3) 0.0432(11) Uani 1 1 d .
N6 N 0.7928(4) -0.1319(2) 0.4631(3) 0.0394(11) Uani 1 1 d .
N7 N 0.4685(4) -0.2152(2) 0.5621(2) 0.0377(10) Uani 1 1 d .
N8 N 0.2769(4) -0.6317(2) 0.5169(3) 0.0423(11) Uani 1 1 d .
N9 N 0.4147(5) -0.1015(3) 0.7672(3) 0.0463(12) Uani 1 1 d .
N10 N 0.3923(6) -0.3771(3) 0.7550(4) 0.0660(16) Uani 1 1 d .
C1 C 0.8384(6) 0.2928(3) 1.1259(3) 0.0529(15) Uani 1 1 d .
H1 H 0.8822 0.3113 1.1715 0.063 Uiso 1 1 calc R
C2 C 0.7369(6) 0.2429(4) 1.1233(4) 0.0581(17) Uani 1 1 d .
H2 H 0.7141 0.2287 1.1683 0.070 Uiso 1 1 calc R
C3 C 0.7046(6) 0.2360(3) 0.9968(4) 0.0542(16) Uani 1 1 d .
H3 H 0.6579 0.2170 0.9522 0.065 Uiso 1 1 calc R
C4 C 0.8036(6) 0.2844(3) 0.9934(4) 0.0545(16) Uani 1 1 d .
H4 H 0.8245 0.2971 0.9475 0.065 Uiso 1 1 calc R
C5 C 0.8752(5) 0.3156(3) 1.0600(3) 0.0454(14) Uani 1 1 d .
C6 C 0.9848(6) 0.3682(3) 1.0623(4) 0.0517(15) Uani 1 1 d .
H6 H 1.0231 0.3878 1.1090 0.062 Uiso 1 1 calc R
C7 C 1.0334(5) 0.3899(3) 1.0032(3) 0.0444(14) Uani 1 1 d .
H7 H 0.9942 0.3703 0.9567 0.053 Uiso 1 1 calc R
C8 C 1.1423(5) 0.4415(3) 1.0040(3) 0.0435(14) Uani 1 1 d .
C9 C 1.2816(6) 0.4985(4) 0.9343(4) 0.0603(17) Uani 1 1 d .
H9 H 1.3083 0.5051 0.8882 0.072 Uiso 1 1 calc R
C10 C 1.3459(7) 0.5365(4) 0.9959(5) 0.072(2) Uani 1 1 d .
H10 H 1.4145 0.5688 0.9919 0.086 Uiso 1 1 calc R
C11 C 1.3079(7) 0.5266(4) 1.0645(4) 0.077(2) Uani 1 1 d .
H11 H 1.3508 0.5517 1.1076 0.092 Uiso 1 1 calc R
C12 C 1.2055(6) 0.4788(4) 1.0680(4) 0.0605(17) Uani 1 1 d .
H12 H 1.1785 0.4716 1.1138 0.073 Uiso 1 1 calc R
C13 C 1.2900(5) 0.2665(3) 0.9826(3) 0.0437(13) Uani 1 1 d .
H13 H 1.3264 0.2884 0.9449 0.052 Uiso 1 1 calc R
C14 C 1.3448(6) 0.2821(3) 1.0550(3) 0.0515(15) Uani 1 1 d .
H14 H 1.4171 0.3135 1.0659 0.062 Uiso 1 1 calc R
C15 C 1.2909(6) 0.2508(4) 1.1107(3) 0.0550(16) Uani 1 1 d .
H15 H 1.3256 0.2609 1.1602 0.066 Uiso 1 1 calc R
C16 C 1.1843(6) 0.2039(3) 1.0925(3) 0.0496(15) Uani 1 1 d .
H16 H 1.1467 0.1819 1.1297 0.059 Uiso 1 1 calc R
C17 C 1.1326(5) 0.1894(3) 1.0172(3) 0.0378(12) Uani 1 1 d .
C18 C 1.0217(5) 0.1396(3) 0.9940(3) 0.0427(13) Uani 1 1 d .
H18 H 0.9941 0.1338 0.9431 0.051 Uiso 1 1 calc R
C19 C 0.9558(5) 0.1018(3) 1.0373(3) 0.0457(14) Uani 1 1 d .
H19 H 0.9823 0.1077 1.0883 0.055 Uiso 1 1 calc R
C20 C 0.8452(5) 0.0514(3) 1.0126(3) 0.0388(12) Uani 1 1 d .
C21 C 0.7903(6) 0.0385(3) 0.9390(3) 0.0539(16) Uani 1 1 d .
H21 H 0.8232 0.0631 0.9016 0.065 Uiso 1 1 calc R
C22 C 0.6870(6) -0.0108(4) 0.9215(3) 0.0612(18) Uani 1 1 d .
H22 H 0.6511 -0.0181 0.8719 0.073 Uiso 1 1 calc R
C23 C 0.6874(6) -0.0361(3) 1.0424(3) 0.0522(16) Uani 1 1 d .
H23 H 0.6519 -0.0611 1.0786 0.063 Uiso 1 1 calc R
C24 C 0.7907(5) 0.0117(3) 1.0643(3) 0.0471(14) Uani 1 1 d .
H24 H 0.8246 0.0175 1.1143 0.056 Uiso 1 1 calc R
C25 C 0.8977(6) 0.2791(3) 0.4470(3) 0.0529(15) Uani 1 1 d .
H25 H 0.8741 0.2520 0.4012 0.063 Uiso 1 1 calc R
C26 C 0.9260(6) 0.3565(4) 0.4508(4) 0.0643(19) Uani 1 1 d .
H26 H 0.9257 0.3817 0.4074 0.077 Uiso 1 1 calc R
C27 C 0.9541(6) 0.3954(4) 0.5182(4) 0.0628(19) Uani 1 1 d .
H27 H 0.9686 0.4482 0.5216 0.075 Uiso 1 1 calc R
C28 C 0.9612(6) 0.3571(3) 0.5810(4) 0.0555(17) Uani 1 1 d .
H28 H 0.9828 0.3843 0.6269 0.067 Uiso 1 1 calc R
C29 C 0.9048(5) 0.2419(3) 0.5126(3) 0.0385(12) Uani 1 1 d .
C30 C 0.8788(5) 0.1596(3) 0.5142(3) 0.0385(13) Uani 1 1 d .
H30 H 0.8963 0.1396 0.5604 0.046 Uiso 1 1 calc R
C31 C 0.8339(5) 0.1106(3) 0.4585(3) 0.0384(12) Uani 1 1 d .
H31 H 0.8110 0.1303 0.4126 0.046 Uiso 1 1 calc R
C32 C 0.8165(5) 0.0280(3) 0.4619(3) 0.0365(12) Uani 1 1 d .
C33 C 0.8453(5) -0.0088(3) 0.5271(3) 0.0420(13) Uani 1 1 d .
H33 H 0.8729 0.0194 0.5718 0.050 Uiso 1 1 calc R
C34 C 0.8327(5) -0.0877(3) 0.5249(3) 0.0423(13) Uani 1 1 d .
H34 H 0.8532 -0.1112 0.5691 0.051 Uiso 1 1 calc R
C35 C 0.7633(5) -0.0967(3) 0.4003(3) 0.0470(14) Uani 1 1 d .
H35 H 0.7363 -0.1265 0.3564 0.056 Uiso 1 1 calc R
C36 C 0.7712(5) -0.0180(3) 0.3979(3) 0.0428(13) Uani 1 1 d .
H36 H 0.7463 0.0041 0.3534 0.051 Uiso 1 1 calc R
C37 C 0.4142(6) -0.2424(3) 0.4317(3) 0.0542(16) Uani 1 1 d .
H37 H 0.3860 -0.2773 0.3917 0.065 Uiso 1 1 calc R
C38 C 0.4418(7) -0.1677(3) 0.4199(4) 0.0628(19) Uani 1 1 d .
H38 H 0.4331 -0.1520 0.3717 0.075 Uiso 1 1 calc R
C39 C 0.4817(6) -0.1169(3) 0.4784(4) 0.0531(16) Uani 1 1 d .
H39 H 0.4992 -0.0660 0.4712 0.064 Uiso 1 1 calc R
C40 C 0.4953(6) -0.1425(3) 0.5480(4) 0.0503(15) Uani 1 1 d .
H40 H 0.5247 -0.1079 0.5881 0.060 Uiso 1 1 calc R
C41 C 0.4287(5) -0.2653(3) 0.5037(3) 0.0376(12) Uani 1 1 d .
C42 C 0.3985(5) -0.3433(3) 0.5219(3) 0.0408(13) Uani 1 1 d .
H42 H 0.3996 -0.3516 0.5720 0.049 Uiso 1 1 calc R
C43 C 0.3698(5) -0.4028(3) 0.4728(3) 0.0416(13) Uani 1 1 d .
H43 H 0.3690 -0.3942 0.4228 0.050 Uiso 1 1 calc R
C44 C 0.3392(5) -0.4810(3) 0.4900(3) 0.0385(12) Uani 1 1 d .
C45 C 0.3211(5) -0.5013(3) 0.5604(3) 0.0450(14) Uani 1 1 d .
H45 H 0.3307 -0.4645 0.6005 0.054 Uiso 1 1 calc R
C46 C 0.2889(5) -0.5755(3) 0.5709(3) 0.0462(14) Uani 1 1 d .
H46 H 0.2747 -0.5871 0.6184 0.055 Uiso 1 1 calc R
C47 C 0.2934(5) -0.6119(3) 0.4484(3) 0.0463(14) Uani 1 1 d .
H47 H 0.2840 -0.6499 0.4092 0.056 Uiso 1 1 calc R
C48 C 0.3230(5) -0.5394(3) 0.4336(3) 0.0447(14) Uani 1 1 d .
H48 H 0.3325 -0.5288 0.3851 0.054 Uiso 1 1 calc R
C49 C 1.2910(5) 0.2870(3) 0.7468(3) 0.0338(12) Uani 1 1 d .
C50 C 1.4336(5) 0.2967(3) 0.7530(3) 0.0345(12) Uani 1 1 d .
C51 C 1.5118(5) 0.2378(3) 0.7739(3) 0.0421(13) Uani 1 1 d .
C52 C 1.6438(5) 0.2458(3) 0.7825(3) 0.0430(13) Uani 1 1 d .
H52 H 1.6947 0.2051 0.7964 0.052 Uiso 1 1 calc R
C53 C 1.6977(5) 0.3151(3) 0.7699(3) 0.0419(13) Uani 1 1 d .
C54 C 1.8419(6) 0.3246(4) 0.7830(3) 0.0559(17) Uani 1 1 d .
C55 C 1.6206(5) 0.3751(3) 0.7491(3) 0.0469(14) Uani 1 1 d .
H55 H 1.6565 0.4219 0.7406 0.056 Uiso 1 1 calc R
C56 C 1.4898(5) 0.3653(3) 0.7408(3) 0.0413(13) Uani 1 1 d .
H56 H 1.4387 0.4059 0.7268 0.050 Uiso 1 1 calc R
C57 C 0.9848(5) 0.0632(3) 0.7416(3) 0.0406(13) Uani 1 1 d .
C58 C 0.9466(5) -0.0215(3) 0.7332(3) 0.0343(12) Uani 1 1 d .
C59 C 0.8219(5) -0.0471(3) 0.7228(3) 0.0341(12) Uani 1 1 d .
C60 C 0.7881(5) -0.1245(3) 0.7171(3) 0.0343(12) Uani 1 1 d .
H60 H 0.7031 -0.1401 0.7116 0.041 Uiso 1 1 calc R
C61 C 0.8831(5) -0.1780(3) 0.7197(3) 0.0350(12) Uani 1 1 d .
C62 C 0.8478(6) -0.2637(3) 0.7135(3) 0.0426(13) Uani 1 1 d .
C63 C 1.0076(5) -0.1538(3) 0.7278(3) 0.0371(12) Uani 1 1 d .
H63 H 1.0713 -0.1899 0.7280 0.045 Uiso 1 1 calc R
C64 C 1.0403(5) -0.0763(3) 0.7356(3) 0.0383(12) Uani 1 1 d .
H64 H 1.1255 -0.0610 0.7425 0.046 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N2 Ag1 O4 133.0(2) . 1_455
N2 Ag1 O15 106.54(17) . .
O4 Ag1 O15 95.07(18) 1_455 .
N2 Ag1 O1 99.16(15) . .
O4 Ag1 O1 122.31(18) 1_455 .
O15 Ag1 O1 90.35(14) . .
N2 Ag1 Ag2 105.67(12) . .
O4 Ag1 Ag2 91.63(15) 1_455 .
O15 Ag1 Ag2 127.97(11) . .
O1 Ag1 Ag2 44.79(8) . .
O6 Ag2 N3 112.62(16) . .
O6 Ag2 O1 135.23(18) . .
N3 Ag2 O1 92.17(15) . .
O6 Ag2 O3 99.14(19) . 1_455
N3 Ag2 O3 118.46(18) . 1_455
O1 Ag2 O3 100.60(16) . 1_455
O6 Ag2 Ag3 80.65(12) . .
N3 Ag2 Ag3 166.11(11) . .
O1 Ag2 Ag3 74.82(10) . .
O3 Ag2 Ag3 60.75(15) 1_455 .
O6 Ag2 Ag1 152.57(12) . .
N3 Ag2 Ag1 93.28(11) . .
O1 Ag2 Ag1 47.46(9) . .
O3 Ag2 Ag1 58.62(13) 1_455 .
Ag3 Ag2 Ag1 74.407(16) . .
O5 Ag3 N5 114.63(15) . .
O5 Ag3 O2 122.13(16) . .
N5 Ag3 O2 95.24(15) . .
O5 Ag3 Ag2 81.56(10) . .
N5 Ag3 Ag2 160.32(12) . .
O2 Ag3 Ag2 84.25(10) . .
N8 Ag4 N6 169.56(18) 2_646 .
N7 Ag5 O12 150.02(18) . .
N7 Ag5 O7 106.93(14) . .
O12 Ag5 O7 81.76(16) . .
N7 Ag5 O9 122.80(14) . .
O12 Ag5 O9 83.01(19) . .
O7 Ag5 O9 97.49(13) . .
N1 Ag6 N4 163.69(19) 2_657 .
C49 O1 Ag2 122.0(3) . .
C49 O1 Ag1 121.1(3) . .
Ag2 O1 Ag1 87.75(12) . .
C49 O2 Ag3 115.1(3) . .
C54 O3 Ag2 151.5(5) . 1_655
C54 O4 Ag1 107.7(4) . 1_655
C57 O5 Ag3 124.0(4) . .
C57 O6 Ag2 125.9(4) . .
C62 O7 Ag5 148.8(3) . .
N9 O9 Ag5 100.0(3) . .
N10 O12 Ag5 113.7(5) . .
Ag1 O15 H15A 118.1 . .
Ag1 O15 H15B 89.5 . .
H15A O15 H15B 116.5 . .
H16A O16 H16B 115.8 . .
H17A O17 H17B 116.6 . .
C2 N1 C3 116.1(5) . .
C2 N1 Ag6 122.0(4) . 2_657
C3 N1 Ag6 121.8(4) . 2_657
C8 N2 C9 118.4(5) . .
C8 N2 Ag1 126.2(4) . .
C9 N2 Ag1 115.4(4) . .
C13 N3 C17 119.4(4) . .
C13 N3 Ag2 118.9(4) . .
C17 N3 Ag2 121.6(3) . .
C23 N4 C22 116.9(5) . .
C23 N4 Ag6 121.9(4) . .
C22 N4 Ag6 121.0(4) . .
C29 N5 C28 118.6(5) . .
C29 N5 Ag3 124.3(3) . .
C28 N5 Ag3 114.4(4) . .
C34 N6 C35 117.1(5) . .
C34 N6 Ag4 122.7(4) . .
C35 N6 Ag4 119.9(4) . .
C41 N7 C40 117.9(5) . .
C41 N7 Ag5 124.9(3) . .
C40 N7 Ag5 117.2(4) . .
C46 N8 C47 116.4(5) . .
C46 N8 Ag4 122.3(4) . 2_646
C47 N8 Ag4 121.3(4) . 2_646
O11 N9 O10 121.5(6) . .
O11 N9 O9 119.7(5) . .
O10 N9 O9 118.8(5) . .
O14 N10 O12 120.2(7) . .
O14 N10 O13 121.6(7) . .
O12 N10 O13 118.2(7) . .
C2 C1 C5 119.6(6) . .
C2 C1 H1 120.2 . .
C5 C1 H1 120.2 . .
N1 C2 C1 124.2(6) . .
N1 C2 H2 117.9 . .
C1 C2 H2 117.9 . .
N1 C3 C4 124.1(6) . .
N1 C3 H3 118.0 . .
C4 C3 H3 118.0 . .
C3 C4 C5 119.6(6) . .
C3 C4 H4 120.2 . .
C5 C4 H4 120.2 . .
C1 C5 C4 116.3(5) . .
C1 C5 C6 119.8(6) . .
C4 C5 C6 123.9(5) . .
C7 C6 C5 125.1(6) . .
C7 C6 H6 117.5 . .
C5 C6 H6 117.5 . .
C6 C7 C8 126.2(6) . .
C6 C7 H7 116.9 . .
C8 C7 H7 116.9 . .
N2 C8 C12 120.5(5) . .
N2 C8 C7 115.7(5) . .
C12 C8 C7 123.8(6) . .
N2 C9 C10 122.8(6) . .
N2 C9 H9 118.6 . .
C10 C9 H9 118.6 . .
C9 C10 C11 119.1(7) . .
C9 C10 H10 120.5 . .
C11 C10 H10 120.5 . .
C12 C11 C10 118.7(7) . .
C12 C11 H11 120.7 . .
C10 C11 H11 120.7 . .
C11 C12 C8 120.5(6) . .
C11 C12 H12 119.7 . .
C8 C12 H12 119.7 . .
N3 C13 C14 123.0(5) . .
N3 C13 H13 118.5 . .
C14 C13 H13 118.5 . .
C15 C14 C13 118.8(6) . .
C15 C14 H14 120.6 . .
C13 C14 H14 120.6 . .
C14 C15 C16 119.1(6) . .
C14 C15 H15 120.4 . .
C16 C15 H15 120.4 . .
C15 C16 C17 119.6(6) . .
C15 C16 H16 120.2 . .
C17 C16 H16 120.2 . .
N3 C17 C16 120.1(5) . .
N3 C17 C18 117.5(5) . .
C16 C17 C18 122.4(5) . .
C19 C18 C17 127.2(5) . .
C19 C18 H18 116.4 . .
C17 C18 H18 116.4 . .
C18 C19 C20 126.2(5) . .
C18 C19 H19 116.9 . .
C20 C19 H19 116.9 . .
C24 C20 C21 116.1(5) . .
C24 C20 C19 119.5(5) . .
C21 C20 C19 124.4(5) . .
C22 C21 C20 119.7(5) . .
C22 C21 H21 120.1 . .
C20 C21 H21 120.1 . .
N4 C22 C21 123.5(6) . .
N4 C22 H22 118.3 . .
C21 C22 H22 118.3 . .
N4 C23 C24 123.2(5) . .
N4 C23 H23 118.4 . .
C24 C23 H23 118.4 . .
C23 C24 C20 120.6(5) . .
C23 C24 H24 119.7 . .
C20 C24 H24 119.7 . .
C26 C25 C29 119.2(6) . .
C26 C25 H25 120.4 . .
C29 C25 H25 120.4 . .
C27 C26 C25 119.3(6) . .
C27 C26 H26 120.3 . .
C25 C26 H26 120.3 . .
C26 C27 C28 119.7(6) . .
C26 C27 H27 120.2 . .
C28 C27 H27 120.2 . .
N5 C28 C27 122.4(6) . .
N5 C28 H28 118.8 . .
C27 C28 H28 118.8 . .
N5 C29 C25 120.6(5) . .
N5 C29 C30 116.2(5) . .
C25 C29 C30 123.2(5) . .
C31 C30 C29 128.1(5) . .
C31 C30 H30 115.9 . .
C29 C30 H30 115.9 . .
C30 C31 C32 126.1(5) . .
C30 C31 H31 116.9 . .
C32 C31 H31 116.9 . .
C33 C32 C36 116.7(5) . .
C33 C32 C31 123.0(5) . .
C36 C32 C31 120.3(5) . .
C34 C33 C32 119.5(5) . .
C34 C33 H33 120.2 . .
C32 C33 H33 120.2 . .
N6 C34 C33 123.6(5) . .
N6 C34 H34 118.2 . .
C33 C34 H34 118.2 . .
N6 C35 C36 122.9(5) . .
N6 C35 H35 118.6 . .
C36 C35 H35 118.6 . .
C35 C36 C32 120.0(5) . .
C35 C36 H36 120.0 . .
C32 C36 H36 120.0 . .
C38 C37 C41 119.5(6) . .
C38 C37 H37 120.3 . .
C41 C37 H37 120.3 . .
C39 C38 C37 120.1(6) . .
C39 C38 H38 120.0 . .
C37 C38 H38 120.0 . .
C38 C39 C40 118.2(5) . .
C38 C39 H39 120.9 . .
C40 C39 H39 120.9 . .
N7 C40 C39 123.6(6) . .
N7 C40 H40 118.2 . .
C39 C40 H40 118.2 . .
N7 C41 C37 120.8(5) . .
N7 C41 C42 115.8(5) . .
C37 C41 C42 123.3(5) . .
C43 C42 C41 125.4(5) . .
C43 C42 H42 117.3 . .
C41 C42 H42 117.3 . .
C42 C43 C44 126.0(5) . .
C42 C43 H43 117.0 . .
C44 C43 H43 117.0 . .
C45 C44 C48 116.1(5) . .
C45 C44 C43 124.1(5) . .
C48 C44 C43 119.8(5) . .
C46 C45 C44 120.1(5) . .
C46 C45 H45 119.9 . .
C44 C45 H45 119.9 . .
N8 C46 C45 123.5(5) . .
N8 C46 H46 118.2 . .
C45 C46 H46 118.2 . .
N8 C47 C48 123.3(5) . .
N8 C47 H47 118.4 . .
C48 C47 H47 118.4 . .
C47 C48 C44 120.6(5) . .
C47 C48 H48 119.7 . .
C44 C48 H48 119.7 . .
O2 C49 O1 126.4(5) . .
O2 C49 C50 118.4(4) . .
O1 C49 C50 115.2(5) . .
C51 C50 C56 117.8(5) . .
C51 C50 C49 120.8(4) . .
C56 C50 C49 121.4(5) . .
C50 C51 C52 122.1(5) . .
C50 C51 Br2 120.2(4) . .
C52 C51 Br2 117.7(4) . .
C53 C52 C51 118.9(5) . .
C53 C52 H52 120.5 . .
C51 C52 H52 120.5 . .
C52 C53 C55 119.8(5) . .
C52 C53 C54 118.6(5) . .
C55 C53 C54 121.6(5) . .
O3 C54 O4 126.6(6) . .
O3 C54 C53 116.8(6) . .
O4 C54 C53 116.6(6) . .
C53 C55 C56 119.9(5) . .
C53 C55 H55 120.1 . .
C56 C55 H55 120.1 . .
C50 C56 C55 121.5(5) . .
C50 C56 H56 119.3 . .
C55 C56 H56 119.3 . .
O5 C57 O6 127.5(5) . .
O5 C57 C58 117.9(5) . .
O6 C57 C58 114.6(5) . .
C59 C58 C64 117.6(5) . .
C59 C58 C57 123.0(5) . .
C64 C58 C57 119.4(5) . .
C58 C59 C60 122.5(5) . .
C58 C59 Br1 120.9(4) . .
C60 C59 Br1 116.6(4) . .
C61 C60 C59 118.9(5) . .
C61 C60 H60 120.6 . .
C59 C60 H60 120.6 . .
C63 C61 C60 119.5(5) . .
C63 C61 C62 120.8(5) . .
C60 C61 C62 119.7(5) . .
O8 C62 O7 125.9(5) . .
O8 C62 C61 116.3(5) . .
O7 C62 C61 117.7(5) . .
C61 C63 C64 121.1(5) . .
C61 C63 H63 119.5 . .
C64 C63 H63 119.5 . .
C63 C64 C58 120.4(5) . .
C63 C64 H64 119.8 . .
C58 C64 H64 119.8 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N2 2.251(5) .
Ag1 O4 2.256(5) 1_455
Ag1 O15 2.466(4) .
Ag1 O1 2.470(4) .
Ag1 Ag2 3.3501(7) .
Ag2 O6 2.244(4) .
Ag2 N3 2.284(4) .
Ag2 O1 2.362(4) .
Ag2 O3 2.408(5) 1_455
Ag2 Ag3 2.8938(6) .
Ag3 O5 2.270(4) .
Ag3 N5 2.296(4) .
Ag3 O2 2.386(4) .
Ag4 N8 2.124(4) 2_646
Ag4 N6 2.135(4) .
Ag5 N7 2.259(4) .
Ag5 O12 2.336(5) .
Ag5 O7 2.541(4) .
Ag5 O9 2.582(5) .
Ag6 N1 2.151(5) 2_657
Ag6 N4 2.153(5) .
Br1 C59 1.912(5) .
Br2 C51 1.918(6) .
O1 C49 1.245(6) .
O2 C49 1.239(6) .
O3 C54 1.224(8) .
O3 Ag2 2.408(5) 1_655
O4 C54 1.253(8) .
O4 Ag1 2.256(5) 1_655
O5 C57 1.214(6) .
O6 C57 1.239(7) .
O7 C62 1.252(7) .
O8 C62 1.236(7) .
O9 N9 1.246(6) .
O10 N9 1.216(7) .
O11 N9 1.214(6) .
O12 N10 1.223(7) .
O13 N10 1.240(8) .
O14 N10 1.220(7) .
O15 H15A 0.8500 .
O15 H15B 0.8500 .
O16 H16A 0.8513 .
O16 H16B 0.8536 .
O17 H17A 0.8499 .
O17 H17B 0.8491 .
N1 C2 1.328(8) .
N1 C3 1.349(7) .
N1 Ag6 2.151(5) 2_657
N2 C8 1.351(7) .
N2 C9 1.356(7) .
N3 C13 1.335(7) .
N3 C17 1.339(7) .
N4 C23 1.328(7) .
N4 C22 1.334(7) .
N5 C29 1.344(7) .
N5 C28 1.348(7) .
N6 C34 1.333(7) .
N6 C35 1.338(7) .
N7 C41 1.344(7) .
N7 C40 1.350(7) .
N8 C46 1.330(7) .
N8 C47 1.347(7) .
N8 Ag4 2.124(4) 2_646
C1 C2 1.372(8) .
C1 C5 1.388(8) .
C1 H1 0.9300 .
C2 H2 0.9300 .
C3 C4 1.352(8) .
C3 H3 0.9300 .
C4 C5 1.411(8) .
C4 H4 0.9300 .
C5 C6 1.468(8) .
C6 C7 1.327(8) .
C6 H6 0.9300 .
C7 C8 1.454(8) .
C7 H7 0.9300 .
C8 C12 1.379(8) .
C9 C10 1.357(9) .
C9 H9 0.9300 .
C10 C11 1.378(10) .
C10 H10 0.9300 .
C11 C12 1.373(9) .
C11 H11 0.9300 .
C12 H12 0.9300 .
C13 C14 1.374(8) .
C13 H13 0.9300 .
C14 C15 1.368(8) .
C14 H14 0.9300 .
C15 C16 1.379(8) .
C15 H15 0.9300 .
C16 C17 1.409(7) .
C16 H16 0.9300 .
C17 C18 1.454(7) .
C18 C19 1.323(7) .
C18 H18 0.9300 .
C19 C20 1.461(8) .
C19 H19 0.9300 .
C20 C24 1.386(7) .
C20 C21 1.389(8) .
C21 C22 1.376(8) .
C21 H21 0.9300 .
C22 H22 0.9300 .
C23 C24 1.370(8) .
C23 H23 0.9300 .
C24 H24 0.9300 .
C25 C26 1.378(8) .
C25 C29 1.391(8) .
C25 H25 0.9300 .
C26 C27 1.352(9) .
C26 H26 0.9300 .
C27 C28 1.357(9) .
C27 H27 0.9300 .
C28 H28 0.9300 .
C29 C30 1.466(7) .
C30 C31 1.311(7) .
C30 H30 0.9300 .
C31 C32 1.461(7) .
C31 H31 0.9300 .
C32 C33 1.390(7) .
C32 C36 1.392(7) .
C33 C34 1.381(7) .
C33 H33 0.9300 .
C34 H34 0.9300 .
C35 C36 1.381(7) .
C35 H35 0.9300 .
C36 H36 0.9300 .
C37 C38 1.373(8) .
C37 C41 1.385(8) .
C37 H37 0.9300 .
C38 C39 1.353(9) .
C38 H38 0.9300 .
C39 C40 1.362(8) .
C39 H39 0.9300 .
C40 H40 0.9300 .
C41 C42 1.468(7) .
C42 C43 1.325(7) .
C42 H42 0.9300 .
C43 C44 1.467(7) .
C43 H43 0.9300 .
C44 C45 1.385(7) .
C44 C48 1.385(7) .
C45 C46 1.371(7) .
C45 H45 0.9300 .
C46 H46 0.9300 .
C47 C48 1.357(7) .
C47 H47 0.9300 .
C48 H48 0.9300 .
C49 C50 1.510(7) .
C50 C51 1.375(7) .
C50 C56 1.378(7) .
C51 C52 1.393(7) .
C52 C53 1.381(8) .
C52 H52 0.9300 .
C53 C55 1.383(7) .
C53 C54 1.523(8) .
C55 C56 1.383(7) .
C55 H55 0.9300 .
C56 H56 0.9300 .
C57 C58 1.522(7) .
C58 C59 1.377(7) .
C58 C64 1.389(7) .
C59 C60 1.390(7) .
C60 C61 1.382(7) .
C60 H60 0.9300 .
C61 C63 1.369(7) .
C61 C62 1.533(7) .
C63 C64 1.387(7) .
C63 H63 0.9300 .
C64 H64 0.9300 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N2 Ag1 Ag2 O6 163.8(4) . .
O4 Ag1 Ag2 O6 28.0(4) 1_455 .
O15 Ag1 Ag2 O6 -69.7(4) . .
O1 Ag1 Ag2 O6 -108.9(4) . .
N2 Ag1 Ag2 N3 2.68(16) . .
O4 Ag1 Ag2 N3 -133.15(19) 1_455 .
O15 Ag1 Ag2 N3 129.13(19) . .
O1 Ag1 Ag2 N3 89.94(17) . .
N2 Ag1 Ag2 O1 -87.26(18) . .
O4 Ag1 Ag2 O1 136.9(2) 1_455 .
O15 Ag1 Ag2 O1 39.2(2) . .
N2 Ag1 Ag2 O3 124.3(2) . 1_455
O4 Ag1 Ag2 O3 -11.5(2) 1_455 1_455
O15 Ag1 Ag2 O3 -109.3(2) . 1_455
O1 Ag1 Ag2 O3 -148.4(2) . 1_455
N2 Ag1 Ag2 Ag3 -170.79(12) . .
O4 Ag1 Ag2 Ag3 53.38(15) 1_455 .
O15 Ag1 Ag2 Ag3 -44.34(15) . .
O1 Ag1 Ag2 Ag3 -83.53(13) . .
O6 Ag2 Ag3 O5 3.2(2) . .
N3 Ag2 Ag3 O5 166.5(5) . .
O1 Ag2 Ag3 O5 145.36(16) . .
O3 Ag2 Ag3 O5 -102.9(2) 1_455 .
Ag1 Ag2 Ag3 O5 -165.30(13) . .
O6 Ag2 Ag3 N5 149.9(4) . .
N3 Ag2 Ag3 N5 -46.8(6) . .
O1 Ag2 Ag3 N5 -67.9(3) . .
O3 Ag2 Ag3 N5 43.9(4) 1_455 .
Ag1 Ag2 Ag3 N5 -18.5(3) . .
O6 Ag2 Ag3 O2 -120.57(18) . .
N3 Ag2 Ag3 O2 42.7(4) . .
O1 Ag2 Ag3 O2 21.63(13) . .
O3 Ag2 Ag3 O2 133.37(18) 1_455 .
Ag1 Ag2 Ag3 O2 70.97(9) . .
O6 Ag2 O1 C49 16.0(5) . .
N3 Ag2 O1 C49 141.8(4) . .
O3 Ag2 O1 C49 -98.7(4) 1_455 .
Ag3 Ag2 O1 C49 -43.2(4) . .
Ag1 Ag2 O1 C49 -125.7(4) . .
O6 Ag2 O1 Ag1 141.76(19) . .
N3 Ag2 O1 Ag1 -92.46(14) . .
O3 Ag2 O1 Ag1 27.04(18) 1_455 .
Ag3 Ag2 O1 Ag1 82.58(9) . .
N2 Ag1 O1 C49 -130.4(4) . .
O4 Ag1 O1 C49 72.6(4) 1_455 .
O15 Ag1 O1 C49 -23.6(4) . .
Ag2 Ag1 O1 C49 126.5(4) . .
N2 Ag1 O1 Ag2 103.05(15) . .
O4 Ag1 O1 Ag2 -53.9(2) 1_455 .
O15 Ag1 O1 Ag2 -150.13(15) . .
O5 Ag3 O2 C49 -93.3(4) . .
N5 Ag3 O2 C49 143.2(4) . .
Ag2 Ag3 O2 C49 -17.1(3) . .
N5 Ag3 O5 C57 -171.2(5) . .
O2 Ag3 O5 C57 74.8(5) . .
Ag2 Ag3 O5 C57 -2.9(5) . .
N3 Ag2 O6 C57 178.5(5) . .
O1 Ag2 O6 C57 -62.9(7) . .
O3 Ag2 O6 C57 52.3(6) 1_455 .
Ag3 Ag2 O6 C57 -5.8(6) . .
Ag1 Ag2 O6 C57 18.9(8) . .
N7 Ag5 O7 C62 63.7(7) . .
O12 Ag5 O7 C62 -145.8(7) . .
O9 Ag5 O7 C62 -64.0(7) . .
N7 Ag5 O9 N9 37.8(4) . .
O12 Ag5 O9 N9 -125.8(4) . .
O7 Ag5 O9 N9 153.5(3) . .
N7 Ag5 O12 N10 -21.3(8) . .
O7 Ag5 O12 N10 -131.0(5) . .
O9 Ag5 O12 N10 130.3(5) . .
O4 Ag1 N2 C8 50.1(5) 1_455 .
O15 Ag1 N2 C8 163.9(4) . .
O1 Ag1 N2 C8 -103.0(4) . .
Ag2 Ag1 N2 C8 -57.6(5) . .
O4 Ag1 N2 C9 -129.6(4) 1_455 .
O15 Ag1 N2 C9 -15.8(5) . .
O1 Ag1 N2 C9 77.3(4) . .
Ag2 Ag1 N2 C9 122.8(4) . .
O6 Ag2 N3 C13 138.6(4) . .
O1 Ag2 N3 C13 -3.2(4) . .
O3 Ag2 N3 C13 -106.5(4) 1_455 .
Ag3 Ag2 N3 C13 -23.5(7) . .
Ag1 Ag2 N3 C13 -50.7(4) . .
O6 Ag2 N3 C17 -46.3(4) . .
O1 Ag2 N3 C17 172.0(4) . .
O3 Ag2 N3 C17 68.7(4) 1_455 .
Ag3 Ag2 N3 C17 151.6(3) . .
Ag1 Ag2 N3 C17 124.5(4) . .
N1 Ag6 N4 C23 9.2(9) 2_657 .
N1 Ag6 N4 C22 -174.5(6) 2_657 .
O5 Ag3 N5 C29 -23.9(5) . .
O2 Ag3 N5 C29 105.1(4) . .
Ag2 Ag3 N5 C29 -167.3(3) . .
O5 Ag3 N5 C28 174.9(4) . .
O2 Ag3 N5 C28 -56.1(4) . .
Ag2 Ag3 N5 C28 31.5(6) . .
N8 Ag4 N6 C34 28.5(12) 2_646 .
N8 Ag4 N6 C35 -146.5(9) 2_646 .
O12 Ag5 N7 C41 -12.4(6) . .
O7 Ag5 N7 C41 90.7(4) . .
O9 Ag5 N7 C41 -158.3(4) . .
O12 Ag5 N7 C40 170.0(4) . .
O7 Ag5 N7 C40 -86.8(4) . .
O9 Ag5 N7 C40 24.2(4) . .
Ag5 O9 N9 O11 177.0(4) . .
Ag5 O9 N9 O10 -1.9(6) . .
Ag5 O12 N10 O14 157.0(6) . .
Ag5 O12 N10 O13 -23.4(8) . .
C3 N1 C2 C1 -0.6(9) . .
Ag6 N1 C2 C1 176.7(5) 2_657 .
C5 C1 C2 N1 0.2(10) . .
C2 N1 C3 C4 1.1(9) . .
Ag6 N1 C3 C4 -176.2(5) 2_657 .
N1 C3 C4 C5 -1.2(10) . .
C2 C1 C5 C4 -0.2(9) . .
C2 C1 C5 C6 -179.2(6) . .
C3 C4 C5 C1 0.7(9) . .
C3 C4 C5 C6 179.6(6) . .
C1 C5 C6 C7 175.5(6) . .
C4 C5 C6 C7 -3.4(9) . .
C5 C6 C7 C8 -179.6(5) . .
C9 N2 C8 C12 0.3(8) . .
Ag1 N2 C8 C12 -179.4(4) . .
C9 N2 C8 C7 -179.6(5) . .
Ag1 N2 C8 C7 0.7(7) . .
C6 C7 C8 N2 175.8(5) . .
C6 C7 C8 C12 -4.1(9) . .
C8 N2 C9 C10 -0.6(9) . .
Ag1 N2 C9 C10 179.1(5) . .
N2 C9 C10 C11 0.7(11) . .
C9 C10 C11 C12 -0.5(11) . .
C10 C11 C12 C8 0.2(11) . .
N2 C8 C12 C11 -0.1(10) . .
C7 C8 C12 C11 179.8(6) . .
C17 N3 C13 C14 0.4(8) . .
Ag2 N3 C13 C14 175.7(4) . .
N3 C13 C14 C15 -0.7(9) . .
C13 C14 C15 C16 0.7(9) . .
C14 C15 C16 C17 -0.3(9) . .
C13 N3 C17 C16 0.0(8) . .
Ag2 N3 C17 C16 -175.1(4) . .
C13 N3 C17 C18 -179.1(5) . .
Ag2 N3 C17 C18 5.8(6) . .
C15 C16 C17 N3 0.0(8) . .
C15 C16 C17 C18 179.0(5) . .
N3 C17 C18 C19 178.7(5) . .
C16 C17 C18 C19 -0.4(9) . .
C17 C18 C19 C20 -179.4(5) . .
C18 C19 C20 C24 175.9(6) . .
C18 C19 C20 C21 -2.6(9) . .
C24 C20 C21 C22 0.7(9) . .
C19 C20 C21 C22 179.2(6) . .
C23 N4 C22 C21 1.0(10) . .
Ag6 N4 C22 C21 -175.5(5) . .
C20 C21 C22 N4 -0.7(10) . .
C22 N4 C23 C24 -1.4(9) . .
Ag6 N4 C23 C24 175.1(4) . .
N4 C23 C24 C20 1.4(9) . .
C21 C20 C24 C23 -1.0(8) . .
C19 C20 C24 C23 -179.7(5) . .
C29 C25 C26 C27 -3.1(10) . .
C25 C26 C27 C28 3.7(10) . .
C29 N5 C28 C27 -1.1(9) . .
Ag3 N5 C28 C27 161.2(5) . .
C26 C27 C28 N5 -1.7(10) . .
C28 N5 C29 C25 1.7(8) . .
Ag3 N5 C29 C25 -158.7(4) . .
C28 N5 C29 C30 -179.1(5) . .
Ag3 N5 C29 C30 20.5(6) . .
C26 C25 C29 N5 0.4(9) . .
C26 C25 C29 C30 -178.8(5) . .
N5 C29 C30 C31 173.1(5) . .
C25 C29 C30 C31 -7.6(9) . .
C29 C30 C31 C32 176.2(5) . .
C30 C31 C32 C33 0.8(9) . .
C30 C31 C32 C36 -178.0(5) . .
C36 C32 C33 C34 2.4(8) . .
C31 C32 C33 C34 -176.5(5) . .
C35 N6 C34 C33 -0.3(8) . .
Ag4 N6 C34 C33 -175.4(4) . .
C32 C33 C34 N6 -0.5(8) . .
C34 N6 C35 C36 -0.8(8) . .
Ag4 N6 C35 C36 174.5(4) . .
N6 C35 C36 C32 2.7(9) . .
C33 C32 C36 C35 -3.4(8) . .
C31 C32 C36 C35 175.5(5) . .
C41 C37 C38 C39 -0.6(10) . .
C37 C38 C39 C40 1.1(10) . .
C41 N7 C40 C39 1.4(8) . .
Ag5 N7 C40 C39 179.1(5) . .
C38 C39 C40 N7 -1.6(9) . .
C40 N7 C41 C37 -0.9(8) . .
Ag5 N7 C41 C37 -178.4(4) . .
C40 N7 C41 C42 -178.9(5) . .
Ag5 N7 C41 C42 3.6(6) . .
C38 C37 C41 N7 0.5(9) . .
C38 C37 C41 C42 178.4(6) . .
N7 C41 C42 C43 -173.1(5) . .
C37 C41 C42 C43 8.9(9) . .
C41 C42 C43 C44 -179.9(5) . .
C42 C43 C44 C45 8.2(9) . .
C42 C43 C44 C48 -173.8(6) . .
C48 C44 C45 C46 0.0(8) . .
C43 C44 C45 C46 178.0(5) . .
C47 N8 C46 C45 -2.5(8) . .
Ag4 N8 C46 C45 176.0(4) 2_646 .
C44 C45 C46 N8 2.0(9) . .
C46 N8 C47 C48 1.2(8) . .
Ag4 N8 C47 C48 -177.3(4) 2_646 .
N8 C47 C48 C44 0.7(9) . .
C45 C44 C48 C47 -1.2(8) . .
C43 C44 C48 C47 -179.3(5) . .
Ag3 O2 C49 O1 -11.6(7) . .
Ag3 O2 C49 C50 165.7(3) . .
Ag2 O1 C49 O2 46.1(7) . .
Ag1 O1 C49 O2 -62.7(6) . .
Ag2 O1 C49 C50 -131.3(4) . .
Ag1 O1 C49 C50 119.9(4) . .
O2 C49 C50 C51 -96.1(6) . .
O1 C49 C50 C51 81.5(6) . .
O2 C49 C50 C56 86.4(6) . .
O1 C49 C50 C56 -95.9(6) . .
C56 C50 C51 C52 -0.4(8) . .
C49 C50 C51 C52 -177.9(5) . .
C56 C50 C51 Br2 179.8(4) . .
C49 C50 C51 Br2 2.3(7) . .
C50 C51 C52 C53 0.3(8) . .
Br2 C51 C52 C53 -179.8(4) . .
C51 C52 C53 C55 -0.1(8) . .
C51 C52 C53 C54 177.1(5) . .
Ag2 O3 C54 O4 -6.6(16) 1_655 .
Ag2 O3 C54 C53 175.0(7) 1_655 .
Ag1 O4 C54 O3 -15.2(9) 1_655 .
Ag1 O4 C54 C53 163.2(4) 1_655 .
C52 C53 C54 O3 -2.3(8) . .
C55 C53 C54 O3 174.8(6) . .
C52 C53 C54 O4 179.1(6) . .
C55 C53 C54 O4 -3.7(9) . .
C52 C53 C55 C56 -0.1(8) . .
C54 C53 C55 C56 -177.2(5) . .
C51 C50 C56 C55 0.2(8) . .
C49 C50 C56 C55 177.7(5) . .
C53 C55 C56 C50 0.0(9) . .
Ag3 O5 C57 O6 -0.6(10) . .
Ag3 O5 C57 C58 -178.4(3) . .
Ag2 O6 C57 O5 5.7(10) . .
Ag2 O6 C57 C58 -176.5(4) . .
O5 C57 C58 C59 -69.9(7) . .
O6 C57 C58 C59 112.1(6) . .
O5 C57 C58 C64 109.9(6) . .
O6 C57 C58 C64 -68.2(7) . .
C64 C58 C59 C60 1.9(8) . .
C57 C58 C59 C60 -178.3(5) . .
C64 C58 C59 Br1 179.8(4) . .
C57 C58 C59 Br1 -0.4(7) . .
C58 C59 C60 C61 -1.9(8) . .
Br1 C59 C60 C61 -179.9(4) . .
C59 C60 C61 C63 0.0(8) . .
C59 C60 C61 C62 180.0(5) . .
Ag5 O7 C62 O8 -164.8(5) . .
Ag5 O7 C62 C61 15.9(10) . .
C63 C61 C62 O8 -1.3(8) . .
C60 C61 C62 O8 178.7(5) . .
C63 C61 C62 O7 178.1(5) . .
C60 C61 C62 O7 -1.9(8) . .
C60 C61 C63 C64 1.9(8) . .
C62 C61 C63 C64 -178.1(5) . .
C61 C63 C64 C58 -1.9(8) . .
C59 C58 C64 C63 0.0(7) . .
C57 C58 C64 C63 -179.8(5) . .
