#------------------------------------------------------------------------------
#$Date: 2016-03-24 02:09:31 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179559 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/28/4502897.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4502897
loop_
_publ_author_name
'Kole, Goutam Kumar'
'Tan, Geok Kheng'
'Vittal, Jagadese J.'
_publ_section_title
;
 Photoreactivity of Ag(I) Complexes and Coordination Polymers of Pyridyl
 Acrylic Acids
;
_journal_issue                   1
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              326
_journal_paper_doi               10.1021/cg201119c
_journal_volume                  12
_journal_year                    2012
_chemical_formula_sum            'C16 H16 Ag Cl N2 O9'
_chemical_formula_weight         523.63
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           11
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yb'
_symmetry_space_group_name_H-M   'P 1 21/m 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 109.452(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   16.3714(18)
_cell_length_b                   6.4132(7)
_cell_length_c                   18.820(2)
_cell_measurement_reflns_used    861
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      27.16
_cell_measurement_theta_min      2.86
_cell_volume                     1863.2(4)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0385
_diffrn_reflns_av_sigmaI/netI    0.0418
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       7
_diffrn_reflns_limit_k_min       -7
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            11159
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.15
_exptl_absorpt_coefficient_mu    1.280
_exptl_absorpt_correction_T_max  0.6468
_exptl_absorpt_correction_T_min  0.5279
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Sadabs, (Sheldrick 2001)'
_exptl_crystal_colour            Colourless
_exptl_crystal_density_diffrn    1.867
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Rod
_exptl_crystal_F_000             1048
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.06
_refine_diff_density_max         1.708
_refine_diff_density_min         -1.969
_refine_diff_density_rms         0.134
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.054
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     379
_refine_ls_number_reflns         3603
_refine_ls_number_restraints     56
_refine_ls_restrained_S_all      1.632
_refine_ls_R_factor_all          0.0817
_refine_ls_R_factor_gt           0.0654
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0635P)²+12.4960P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1534
_refine_ls_wR_factor_ref         0.1629
_reflns_number_gt                2853
_reflns_number_total             3603
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg201119c_si_002.cif
_cod_data_source_block           compound3
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'Multi-scan'
changed to 'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'Not Measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_sg_symbol_H-M      P2(1)/m
_cod_database_code               4502897
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'
'-x, -y, -z'
'x, -y-1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag -0.52638(7) 0.2500 0.48664(7) 0.0401(4) Uani 1 2 d S . .
Ag2 Ag 0.49852(9) 0.2500 0.03185(9) 0.0605(5) Uani 1 2 d S . .
Cl1 Cl 0.6202(2) 0.2500 0.68183(19) 0.0381(9) Uani 1 2 d S . .
O9 O 0.5626(8) 0.2500 0.7236(7) 0.096(6) Uani 1 2 d S . .
O10 O 0.7052(8) 0.2500 0.7347(6) 0.085(5) Uani 1 2 d S . .
O11 O 0.6085(9) 0.4271(15) 0.6363(5) 0.114(5) Uani 1 1 d . . .
Cl2 Cl 0.3606(2) 0.2500 0.82242(19) 0.0409(9) Uani 1 2 d SD . .
O12 O 0.3740(12) 0.342(3) 0.8912(8) 0.107(11) Uani 0.50 1 d PD . .
O13 O 0.4026(11) 0.049(2) 0.8367(10) 0.069(5) Uani 0.50 1 d PD . .
O14 O 0.2726(7) 0.216(6) 0.7830(8) 0.103(11) Uani 0.50 1 d PD . .
O15 O 0.3984(11) 0.359(3) 0.7777(10) 0.094(8) Uani 0.50 1 d PD . .
O1W O 0.1322(10) 0.2500 0.8408(9) 0.094(5) Uani 1 2 d SD . .
H1W H 0.119(2) 0.3404(3) 0.8081(9) 0.113 Uiso 1 1 d D . .
O2W O 0.8362(8) 0.2500 0.6667(8) 0.130(9) Uani 1 2 d SD . .
H2W H 0.836(3) 0.3404(3) 0.6975(12) 0.156 Uiso 1 1 d D . .
N1 N -0.4226(8) 0.2500 0.4418(7) 0.039(3) Uani 1 2 d S A .
N2 N -0.6449(7) 0.2500 0.5101(7) 0.033(3) Uani 1 2 d S . .
N3 N 0.3956(9) 0.2500 0.0776(9) 0.050(4) Uani 1 2 d S . .
N4 N 0.6126(7) 0.2500 0.0020(6) 0.032(3) Uani 1 2 d S A .
O3 O -1.0026(8) 0.2500 0.6718(6) 0.067(4) Uani 1 2 d S . .
H3 H -1.0545 0.2500 0.6702 0.101 Uiso 1 2 calc SR . .
O4 O -1.0633(7) 0.2500 0.5471(6) 0.061(3) Uani 1 2 d S . .
O5 O 0.0877(7) 0.2500 0.2727(7) 0.073(4) Uani 1 2 d S . .
H5X H 0.0441 0.2500 0.2868 0.109 Uiso 0.373(18) 2 calc SPR A 2
O6 O -0.0129(9) 0.2500 0.1624(7) 0.071(4) Uani 1 2 d S . .
H6O H -0.0444 0.2500 0.1897 0.107 Uiso 0.627(18) 2 calc SPR A 1
O7 O 1.0371(9) 0.2500 -0.0404(9) 0.098(6) Uani 1 2 d S A .
O8 O 0.9605(11) 0.2500 -0.1604(7) 0.080(4) Uani 1 2 d S A .
H8 H 1.0102 0.2500 -0.1641 0.119 Uiso 1 2 calc SR . .
C1 C -0.3389(9) 0.2500 0.4847(9) 0.035(3) Uani 1 2 d SD . .
H1 H -0.3237 0.2500 0.5381 0.042 Uiso 1 2 calc SR . .
C2 C -0.2744(10) 0.2500 0.4524(11) 0.048(4) Uani 1 2 d SD A .
H2 H -0.2155 0.2500 0.4840 0.058 Uiso 1 2 calc SR . .
C3 C -0.2937(13) 0.2500 0.3757(11) 0.056(5) Uani 1 2 d SD . .
C4 C -0.3816(11) 0.2500 0.3325(10) 0.059(5) Uani 1 2 d SD A .
H4 H -0.3990 0.2500 0.2790 0.071 Uiso 1 2 calc SR . .
C6 C -0.2380(11) 0.2500 0.3269(11) 0.039(6) Uani 0.627(18) 2 d SPD A 1
H6 H -0.2641 0.2500 0.2736 0.047 Uiso 0.627(18) 2 calc SPR A 1
C7 C -0.1545(11) 0.2500 0.3569(11) 0.034(6) Uani 0.627(18) 2 d SPD A 1
H7 H -0.1300 0.2500 0.4103 0.041 Uiso 0.627(18) 2 calc SPR A 1
C8 C -0.0957(15) 0.2500 0.3129(12) 0.046(7) Uani 0.627(18) 2 d SPD A 1
O1 O -0.1231(12) 0.2500 0.2444(12) 0.075(8) Uani 0.627(18) 2 d SPD A 1
O2 O -0.0150(13) 0.2500 0.3516(12) 0.059(6) Uani 0.627(18) 2 d SPD A 1
H2O H 0.0143 0.2500 0.3225 0.089 Uiso 0.627(18) 2 calc SPR A 1
C5 C -0.4419(11) 0.2500 0.3675(9) 0.051(4) Uani 1 2 d SD . .
H5 H -0.5013 0.2500 0.3371 0.062 Uiso 1 2 calc SR A .
C6X C -0.2053(15) 0.2500 0.3677(18) 0.034 Uiso 0.373(18) 2 d SPD A 2
H6X H -0.1534 0.2500 0.4099 0.040 Uiso 0.373(18) 2 calc SPR A 2
C7X C -0.205(2) 0.2500 0.2982(17) 0.031 Uiso 0.373(18) 2 d SPD A 2
H7X H -0.2590 0.2500 0.2581 0.037 Uiso 0.373(18) 2 calc SPR A 2
C8X C -0.125(3) 0.2500 0.281(2) 0.058 Uiso 0.373(18) 2 d SPD A 2
O1X O -0.135(3) 0.2500 0.210(2) 0.064 Uiso 0.373(18) 2 d SPD A 2
H1X H -0.0856 0.2500 0.2049 0.096 Uiso 0.373(18) 2 calc SPR A 2
O2X O -0.053(3) 0.2500 0.328(3) 0.064 Uiso 0.373(18) 2 d SPD A 2
C9 C -0.6488(9) 0.2500 0.5804(8) 0.033(3) Uani 1 2 d S . .
H9 H -0.5964 0.2500 0.6220 0.040 Uiso 1 2 calc SR . .
C10 C -0.7271(10) 0.2500 0.5941(9) 0.039(4) Uani 1 2 d S . .
H10 H -0.7283 0.2500 0.6442 0.047 Uiso 1 2 calc SR . .
C11 C -0.8048(9) 0.2500 0.5321(9) 0.043(4) Uani 1 2 d S . .
C12 C -0.7990(10) 0.2500 0.4614(9) 0.054(5) Uani 1 2 d S . .
H12 H -0.8499 0.2500 0.4182 0.064 Uiso 1 2 calc SR . .
C13 C -0.7192(10) 0.2500 0.4538(9) 0.047(4) Uani 1 2 d S . .
H13 H -0.7167 0.2500 0.4040 0.057 Uiso 1 2 calc SR . .
C14 C -0.8926(10) 0.2500 0.5388(9) 0.045(4) Uani 1 2 d S . .
H14 H -0.9405 0.2500 0.4933 0.055 Uiso 1 2 calc SR . .
C15 C -0.9099(10) 0.2500 0.6015(10) 0.047(4) Uani 1 2 d S . .
H15 H -0.8632 0.2500 0.6479 0.056 Uiso 1 2 calc SR . .
C16 C -0.9996(9) 0.2500 0.6031(8) 0.036(3) Uani 1 2 d S . .
C17 C 0.3127(11) 0.2500 0.0362(11) 0.050(4) Uani 1 2 d S . .
H17 H 0.2975 0.2500 -0.0172 0.060 Uiso 1 2 calc SR . .
C18 C 0.2464(11) 0.2500 0.0677(12) 0.055(5) Uani 1 2 d S . .
H18 H 0.1874 0.2500 0.0362 0.066 Uiso 1 2 calc SR . .
C19 C 0.2676(13) 0.2500 0.1454(12) 0.059(5) Uani 1 2 d S . .
C20 C 0.3527(13) 0.2500 0.1877(12) 0.071(6) Uani 1 2 d S . .
H20 H 0.3700 0.2500 0.2411 0.085 Uiso 1 2 calc SR . .
C21 C 0.4133(12) 0.2500 0.1524(12) 0.071(6) Uani 1 2 d S . .
H21 H 0.4725 0.2500 0.1832 0.085 Uiso 1 2 calc SR . .
C22 C 0.2038(12) 0.2500 0.1893(12) 0.059(5) Uani 1 2 d S . .
H22 H 0.2256 0.2500 0.2429 0.071 Uiso 1 2 calc SR . .
C23 C 0.1232(13) 0.2500 0.1562(12) 0.062(5) Uani 1 2 d S . .
H23 H 0.1000 0.2500 0.1027 0.075 Uiso 1 2 calc SR . .
C24 C 0.0638(13) 0.2500 0.2027(11) 0.049(4) Uani 1 2 d S . .
C25 C 0.6106(9) 0.2500 -0.0693(8) 0.034(3) Uani 1 2 d S . .
H25 H 0.5565 0.2500 -0.1089 0.041 Uiso 1 2 calc SR . .
C26 C 0.6871(11) 0.2500 -0.0862(10) 0.052(5) Uani 1 2 d SD A .
H26 H 0.6842 0.2500 -0.1375 0.063 Uiso 1 2 calc SR . .
C27 C 0.7661(10) 0.2500 -0.0308(14) 0.062(6) Uani 1 2 d SD . .
C28 C 0.7638(10) 0.2500 0.0394(12) 0.065(6) Uani 1 2 d SD A .
H28 H 0.8173 0.2500 0.0799 0.078 Uiso 1 2 calc SR . .
C29 C 0.6907(11) 0.2500 0.0561(8) 0.046(4) Uani 1 2 d S . .
H29 H 0.6939 0.2500 0.1075 0.055 Uiso 1 2 calc SR A .
C30 C 0.8589(10) 0.2500 -0.0271(10) 0.033(6) Uani 0.627(18) 2 d SPD A 1
H30 H 0.9033 0.2500 0.0207 0.040 Uiso 0.627(18) 2 calc SPR A 1
C31 C 0.8799(13) 0.2500 -0.0874(11) 0.031(5) Uani 0.627(18) 2 d SPD A 1
H31 H 0.8333 0.2500 -0.1338 0.038 Uiso 0.627(18) 2 calc SPR A 1
C30X C 0.8344(14) 0.2500 -0.0673(12) 0.057 Uiso 0.373(18) 2 d SPD A 2
H30X H 0.8109 0.2500 -0.1208 0.068 Uiso 0.373(18) 2 calc SPR A 2
C31X C 0.9173(16) 0.2500 -0.0432(17) 0.032 Uiso 0.373(18) 2 d SPD A 2
H31X H 0.9468 0.2500 0.0097 0.038 Uiso 0.373(18) 2 calc SPR A 2
C32 C 0.9667(8) 0.2500 -0.0925(8) 0.035(3) Uani 1 2 d SD . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N2 Ag1 N1 169.4(4) . .
N2 Ag1 Ag1 100.26(7) . 3_466
N1 Ag1 Ag1 81.86(8) . 3_466
N2 Ag1 Ag1 100.26(7) . 3_456
N1 Ag1 Ag1 81.86(8) . 3_456
Ag1 Ag1 Ag1 150.56(8) 3_466 3_456
N4 Ag2 N3 172.1(5) . .
O11 Cl1 O11 108.8(9) 4_565 .
O11 Cl1 O9 111.1(5) 4_565 .
O11 Cl1 O9 111.1(5) . .
O11 Cl1 O10 109.4(6) 4_565 .
O11 Cl1 O10 109.4(6) . .
O9 Cl1 O10 106.9(7) . .
O12 Cl2 O12 50.7(18) . 4_565
O12 Cl2 O15 113.2(12) . .
O12 Cl2 O15 145.6(11) 4_565 .
O12 Cl2 O15 145.6(11) . 4_565
O12 Cl2 O15 113.2(11) 4_565 4_565
O15 Cl2 O15 60.6(18) . 4_565
O12 Cl2 O14 112.2(11) . .
O12 Cl2 O14 104.2(13) 4_565 .
O15 Cl2 O14 110.2(11) . .
O15 Cl2 O14 100.8(13) 4_565 .
O12 Cl2 O14 104.2(13) . 4_565
O12 Cl2 O14 112.2(11) 4_565 4_565
O15 Cl2 O14 100.8(13) . 4_565
O15 Cl2 O14 110.2(11) 4_565 4_565
O14 Cl2 O14 18(3) . 4_565
O12 Cl2 O13 61.7(11) . 4_565
O12 Cl2 O13 106.9(11) 4_565 4_565
O15 Cl2 O13 51.8(10) . 4_565
O15 Cl2 O13 106.5(11) 4_565 4_565
O14 Cl2 O13 125.4(19) . 4_565
O14 Cl2 O13 107.5(15) 4_565 4_565
O12 Cl2 O13 106.9(11) . .
O12 Cl2 O13 61.7(11) 4_565 .
O15 Cl2 O13 106.5(11) . .
O15 Cl2 O13 51.8(10) 4_565 .
O14 Cl2 O13 107.5(15) . .
O14 Cl2 O13 125.4(19) 4_565 .
O13 Cl2 O13 126.7(15) 4_565 .
O12 O12 Cl2 64.7(9) 4_565 .
O12 O12 O13 119.2(9) 4_565 4_565
Cl2 O12 O13 61.7(7) . 4_565
O15 O13 Cl2 61.8(9) 4_565 .
O15 O13 O12 118.1(13) 4_565 4_565
Cl2 O13 O12 56.7(8) . 4_565
O14 O14 Cl2 81.0(15) 4_565 .
O13 O15 Cl2 66.4(8) 4_565 .
O13 O15 O15 118.4(11) 4_565 4_565
Cl2 O15 O15 59.7(9) . 4_565
C5 N1 C1 118.2(13) . .
C5 N1 Ag1 118.4(10) . .
C1 N1 Ag1 123.4(9) . .
C13 N2 C9 117.1(12) . .
C13 N2 Ag1 119.6(10) . .
C9 N2 Ag1 123.3(9) . .
C17 N3 C21 116.2(14) . .
C17 N3 Ag2 123.7(12) . .
C21 N3 Ag2 120.0(12) . .
C25 N4 C29 117.5(12) . .
C25 N4 Ag2 122.6(9) . .
C29 N4 Ag2 119.9(10) . .
N1 C1 C2 120.8(14) . .
C3 C2 C1 121.4(16) . .
C2 C3 C4 116.4(14) . .
C2 C3 C6 132.3(18) . .
C4 C3 C6 111.3(16) . .
C2 C3 C6X 102.3(19) . .
C4 C3 C6X 141.3(18) . .
C6 C3 C6X 30.0(13) . .
C5 C4 C3 119.5(16) . .
C7 C6 C3 120.3(18) . .
C6 C7 C8 123.5(19) . .
O1 C8 O2 123(2) . .
O1 C8 C7 121(2) . .
O2 C8 C7 115.2(17) . .
N1 C5 C4 123.7(16) . .
C7X C6X C3 115(2) . .
C6X C7X C8X 122(3) . .
O2X C8X O1X 120(5) . .
O2X C8X C7X 124(4) . .
O1X C8X C7X 115(4) . .
N2 C9 C10 122.1(13) . .
C9 C10 C11 118.7(14) . .
C12 C11 C10 118.0(13) . .
C12 C11 C14 117.8(14) . .
C10 C11 C14 124.2(15) . .
C13 C12 C11 118.9(14) . .
N2 C13 C12 125.1(15) . .
C15 C14 C11 125.9(15) . .
C14 C15 C16 122.4(15) . .
O4 C16 O3 123.7(14) . .
O4 C16 C15 123.7(14) . .
O3 C16 C15 112.6(13) . .
N3 C17 C18 122.5(18) . .
C19 C18 C17 119.3(17) . .
C20 C19 C18 117.8(16) . .
C20 C19 C22 115.9(18) . .
C18 C19 C22 126.3(18) . .
C19 C20 C21 119(2) . .
N3 C21 C20 125.0(19) . .
C23 C22 C19 122(2) . .
C22 C23 C24 119.0(19) . .
O6 C24 O5 123.2(15) . .
O6 C24 C23 111.4(16) . .
O5 C24 C23 125.3(18) . .
N4 C25 C26 120.6(14) . .
C27 C26 C25 121.4(15) . .
C28 C27 C26 115.1(14) . .
C28 C27 C30X 136.6(18) . .
C26 C27 C30X 108.2(18) . .
C28 C27 C30 108.4(17) . .
C26 C27 C30 136.4(18) . .
C30X C27 C30 28.2(6) . .
C27 C28 C29 123.8(17) . .
C28 C29 N4 121.5(15) . .
C31 C30 C27 121.4(15) . .
C30 C31 C32 127.6(18) . .
C31X C30X C27 134.7(19) . .
C30X C31X C32 122(2) . .
O7 C32 O8 123.2(16) . .
O7 C32 C31X 93.7(17) . .
O8 C32 C31X 143.1(18) . .
O7 C32 C31 128.2(16) . .
O8 C32 C31 108.6(15) . .
C31X C32 C31 34.5(13) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N2 2.128(11) .
Ag1 N1 2.134(11) .
Ag1 Ag1 3.3154(7) 3_466
Ag1 Ag1 3.3154(7) 3_456
Ag2 N4 2.122(11) .
Ag2 N3 2.133(12) .
Cl1 O11 1.397(9) 4_565
Cl1 O11 1.397(9) .
Cl1 O9 1.414(11) .
Cl1 O10 1.416(12) .
Cl2 O12 1.372(11) .
Cl2 O12 1.372(11) 4_565
Cl2 O15 1.390(11) .
Cl2 O15 1.390(11) 4_565
Cl2 O14 1.401(11) .
Cl2 O14 1.401(11) 4_565
Cl2 O13 1.445(12) 4_565
Cl2 O13 1.445(12) .
O12 O12 1.17(4) 4_565
O12 O13 1.45(2) 4_565
O13 O15 1.24(2) 4_565
O13 O12 1.45(2) 4_565
O14 O14 0.44(8) 4_565
O15 O13 1.24(2) 4_565
O15 O15 1.40(4) 4_565
N1 C5 1.33(2) .
N1 C1 1.338(18) .
N2 C13 1.320(18) .
N2 C9 1.346(18) .
N3 C17 1.32(2) .
N3 C21 1.34(2) .
N4 C25 1.331(17) .
N4 C29 1.343(19) .
O3 C16 1.309(18) .
O4 C16 1.210(17) .
O5 C24 1.24(2) .
O6 C24 1.23(2) .
O7 C32 1.239(18) .
O8 C32 1.248(18) .
C1 C2 1.384(17) .
C2 C3 1.37(2) .
C3 C4 1.40(3) .
C3 C6 1.494(17) .
C3 C6X 1.505(19) .
C4 C5 1.357(19) .
C6 C7 1.294(14) .
C7 C8 1.46(2) .
C8 O1 1.21(2) .
C8 O2 1.279(15) .
C6X C7X 1.308(16) .
C7X C8X 1.45(3) .
C8X O2X 1.22(3) .
C8X O1X 1.287(16) .
C9 C10 1.390(19) .
C10 C11 1.41(2) .
C11 C12 1.37(2) .
C11 C14 1.48(2) .
C12 C13 1.36(2) .
C14 C15 1.30(2) .
C15 C16 1.48(2) .
C17 C18 1.40(2) .
C18 C19 1.39(3) .
C19 C20 1.36(3) .
C19 C22 1.53(2) .
C20 C21 1.36(2) .
C22 C23 1.26(2) .
C23 C24 1.51(2) .
C25 C26 1.39(2) .
C26 C27 1.36(3) .
C27 C28 1.33(3) .
C27 C30X 1.495(19) .
C27 C30 1.498(17) .
C28 C29 1.34(2) .
C30 C31 1.290(14) .
C31 C32 1.46(2) .
C30X C31X 1.279(15) .
C31X C32 1.42(3) .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O3 H3 O2W 0.84 1.77 2.608(18) 180.0 1_355
O5 H5X O2X 0.84 1.99 2.83(6) 175.5 .
O6 H6O O1 0.84 1.90 2.74(3) 175.7 .
O8 H8 O1W 0.84 1.97 2.80(2) 173.0 1_654
O2 H2O O5 0.84 1.75 2.59(2) 172.2 .
O1X H1X O6 0.84 1.64 2.44(5) 159.0 .
