#------------------------------------------------------------------------------
#$Date: 2016-03-24 02:15:46 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179565 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/34/4503413.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4503413
loop_
_publ_author_name
'Zhu, Xiandong'
'Lü, Jian'
'Li, Xiaoju'
'Gao, Shuiying'
'Li, Guoliang'
'Xiao, Fuxian'
'Cao, Rong'
_publ_section_title
;
 Syntheses, Structures, Near-Infrared, and Visible Luminescence of
 Lanthanide-Organic Frameworks with Flexible Macrocyclic Polyamine Ligands
;
_journal_issue                   6
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              1897
_journal_paper_doi               10.1021/cg701098t
_journal_volume                  8
_journal_year                    2008
_chemical_formula_sum            'C18 H34 Dy N5 O13'
_chemical_formula_weight         691.00
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                101.844(10)
_cell_angle_beta                 108.954(8)
_cell_angle_gamma                111.228(7)
_cell_formula_units_Z            2
_cell_length_a                   8.9432(12)
_cell_length_b                   12.114(2)
_cell_length_c                   13.550(2)
_cell_measurement_reflns_used    3782
_cell_measurement_temperature    294.1500
_cell_measurement_theta_max      27.4797
_cell_measurement_theta_min      2.4977
_cell_volume                     1204.3(4)
_computing_cell_refinement       'CrystalClear (Rigaku/MSC Inc., 2005)'
_computing_data_collection       'CrystalClear (Rigaku/MSC Inc., 2005)'
_computing_data_reduction        'CrystalClear (Rigaku/MSC Inc., 2005)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      294.1500
_diffrn_measured_fraction_theta_full 0.986
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measurement_device_type  'mercury CCD'
_diffrn_measurement_method       dtprofit.ref
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0194
_diffrn_reflns_av_sigmaI/netI    0.0324
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            9563
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         2.06
_exptl_absorpt_coefficient_mu    3.180
_exptl_absorpt_correction_T_max  0.015
_exptl_absorpt_correction_T_min  0.001
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    1.906
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Prism
_exptl_crystal_F_000             694
_exptl_crystal_size_max          0.3000
_exptl_crystal_size_mid          0.1200
_exptl_crystal_size_min          0.0600
_refine_diff_density_max         2.157
_refine_diff_density_min         -1.248
_refine_diff_density_rms         0.209
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.170
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     346
_refine_ls_number_reflns         5460
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.170
_refine_ls_R_factor_all          0.0354
_refine_ls_R_factor_gt           0.0320
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0471P)²+3.6632P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0872
_refine_ls_wR_factor_ref         0.0954
_reflns_number_gt                5031
_reflns_number_total             5460
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg701098t-file002.cif
_cod_data_source_block           CCDC_661346_Dy
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_cell_volume        1204.3(3)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4503413
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Dy1 Dy 1.24384(2) 0.501021(18) -0.009858(15) 0.01389(8) Uani 1 1 d .
O1 O 1.3748(4) 0.4074(3) 0.1122(3) 0.0195(6) Uani 1 1 d .
O2 O 1.6565(4) 0.4486(3) 0.1471(3) 0.0197(7) Uani 1 1 d .
O3 O 1.9988(4) 0.4534(3) 0.8252(3) 0.0214(7) Uani 1 1 d .
O4 O 1.7315(4) 0.4010(3) 0.8274(3) 0.0206(7) Uani 1 1 d .
O5 O 1.2717(4) 0.7140(3) 0.0108(3) 0.0203(7) Uani 1 1 d .
O6 O 0.9993(4) 0.6381(3) -0.0002(3) 0.0249(7) Uani 1 1 d .
O7 O 1.1716(4) 1.2973(3) -0.1384(3) 0.0217(7) Uani 1 1 d .
O8 O 1.4594(4) 1.3577(3) -0.0869(3) 0.0229(7) Uani 1 1 d .
O9 O 1.275(4) 0.080(2) 0.452(2) 0.332(15) Uani 1 1 d .
O10 O 1.3559(12) 0.2224(11) 0.3980(9) 0.145(4) Uani 1 1 d .
O11 O 1.1111(15) 0.1096(16) 0.3312(15) 0.256(9) Uani 1 1 d .
N1 N 1.7517(5) 0.5235(4) 0.3795(3) 0.0217(8) Uani 1 1 d .
N2 N 1.8611(6) 0.3811(4) 0.5990(3) 0.0199(8) Uani 1 1 d .
N3 N 1.3301(6) 0.9625(4) 0.1090(4) 0.0310(10) Uani 1 1 d .
N4 N 1.3739(6) 1.0957(4) -0.1637(4) 0.0325(10) Uani 1 1 d .
N5 N 1.2508(13) 0.1323(9) 0.3957(8) 0.076(2) Uani 1 1 d .
C1 C 1.5319(6) 0.4330(4) 0.1747(4) 0.0167(8) Uani 1 1 d .
C2 C 1.5672(7) 0.4380(6) 0.2938(4) 0.0266(11) Uani 1 1 d .
H2A H 1.4867 0.4651 0.3154 0.032 Uiso 1 1 calc R
H2B H 1.5359 0.3509 0.2942 0.032 Uiso 1 1 calc R
C3 C 1.7926(7) 0.6549(5) 0.3907(4) 0.0291(11) Uani 1 1 d .
H3A H 1.7254 0.6811 0.4275 0.035 Uiso 1 1 calc R
H3B H 1.7503 0.6585 0.3148 0.035 Uiso 1 1 calc R
C4 C 1.9901(7) 0.7500(5) 0.4575(4) 0.0292(11) Uani 1 1 d .
H4A H 2.0018 0.8368 0.4697 0.035 Uiso 1 1 calc R
H4B H 2.0325 0.7432 0.5321 0.035 Uiso 1 1 calc R
C5 C 1.7656(7) 0.5059(5) 0.4863(4) 0.0259(11) Uani 1 1 d .
H5A H 1.6594 0.5013 0.4970 0.031 Uiso 1 1 calc R
H5B H 1.8727 0.5791 0.5496 0.031 Uiso 1 1 calc R
C6 C 1.7784(7) 0.3825(5) 0.4838(4) 0.0252(10) Uani 1 1 d .
H6A H 1.6572 0.3094 0.4413 0.030 Uiso 1 1 calc R
H6B H 1.8503 0.3720 0.4439 0.030 Uiso 1 1 calc R
C7 C 1.8871(8) 0.2637(5) 0.5937(4) 0.0287(11) Uani 1 1 d .
H7A H 1.7689 0.1878 0.5499 0.034 Uiso 1 1 calc R
H7B H 1.9349 0.2642 0.6708 0.034 Uiso 1 1 calc R
C8 C 1.7448(7) 0.3864(6) 0.6564(4) 0.0272(11) Uani 1 1 d .
H8A H 1.6352 0.3037 0.6211 0.033 Uiso 1 1 calc R
H8B H 1.7086 0.4527 0.6449 0.033 Uiso 1 1 calc R
C9 C 1.8349(6) 0.4153(4) 0.7818(4) 0.0171(8) Uani 1 1 d .
C10 C 1.1498(6) 0.7277(5) 0.0322(4) 0.0226(10) Uani 1 1 d .
C11 C 1.1958(11) 0.8546(7) 0.1120(9) 0.074(3) Uani 1 1 d .
H11A H 1.0860 0.8645 0.0943 0.089 Uiso 1 1 calc R
H11B H 1.2376 0.8546 0.1892 0.089 Uiso 1 1 calc R
C12 C 1.4847(10) 1.0431(8) 0.2125(7) 0.057(2) Uani 1 1 d .
H12A H 1.4458 1.0673 0.2704 0.069 Uiso 1 1 calc R
H12B H 1.5543 1.1220 0.2036 0.069 Uiso 1 1 calc R
C13 C 1.2460(14) 1.0377(9) 0.0672(8) 0.071(3) Uani 1 1 d .
H13A H 1.1172 0.9794 0.0205 0.085 Uiso 1 1 calc R
H13B H 1.2567 1.0997 0.1327 0.085 Uiso 1 1 calc R
C14 C 1.3092(11) 1.1060(6) 0.0036(6) 0.0486(17) Uani 1 1 d .
H14A H 1.4338 1.1725 0.0521 0.058 Uiso 1 1 calc R
H14B H 1.2365 1.1493 -0.0201 0.058 Uiso 1 1 calc R
C15 C 1.3026(10) 1.0226(7) -0.0999(6) 0.0476(16) Uani 1 1 d .
H15A H 1.3724 0.9774 -0.0766 0.057 Uiso 1 1 calc R
H15B H 1.1775 0.9578 -0.1496 0.057 Uiso 1 1 calc R
C16 C 1.3938(10) 1.0138(7) -0.2544(5) 0.0486(17) Uani 1 1 d .
H16A H 1.2742 0.9438 -0.3086 0.058 Uiso 1 1 calc R
H16B H 1.4403 1.0660 -0.2951 0.058 Uiso 1 1 calc R
C17 C 1.2564(8) 1.1487(5) -0.2148(5) 0.0372(14) Uani 1 1 d .
H17A H 1.1313 1.0879 -0.2368 0.045 Uiso 1 1 calc R
H17B H 1.2664 1.1566 -0.2840 0.045 Uiso 1 1 calc R
C18 C 1.2979(6) 1.2774(4) -0.1391(4) 0.0165(8) Uani 1 1 d .
H1C H 1.163(9) 0.266(7) 0.242(6) 0.029(19) Uiso 1 1 d .
H2D H 0.916(9) 0.323(6) 0.234(5) 0.024(18) Uiso 1 1 d .
H2N H 1.957(8) 0.448(6) 0.637(5) 0.019(14) Uiso 1 1 d .
OW2 O 0.8632(6) 0.3298(5) 0.2601(4) 0.0410(11) Uani 1 1 d .
OW1 O 1.1136(8) 0.2805(7) 0.1991(6) 0.0705(19) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O6 Dy1 O8 145.36(13) 2_765 2_875
O6 Dy1 O3 74.84(12) 2_765 1_454
O8 Dy1 O3 138.60(12) 2_875 1_454
O6 Dy1 O2 140.06(12) 2_765 2_865
O8 Dy1 O2 73.65(11) 2_875 2_865
O3 Dy1 O2 70.25(11) 1_454 2_865
O6 Dy1 O4 74.37(12) 2_765 2_866
O8 Dy1 O4 77.77(12) 2_875 2_866
O3 Dy1 O4 121.41(11) 1_454 2_866
O2 Dy1 O4 141.67(11) 2_865 2_866
O6 Dy1 O1 78.20(12) 2_765 .
O8 Dy1 O1 74.27(12) 2_875 .
O3 Dy1 O1 143.40(12) 1_454 .
O2 Dy1 O1 121.36(11) 2_865 .
O4 Dy1 O1 73.05(11) 2_866 .
O6 Dy1 O7 76.92(12) 2_765 1_545
O8 Dy1 O7 115.62(12) 2_875 1_545
O3 Dy1 O7 73.76(11) 1_454 1_545
O2 Dy1 O7 75.24(12) 2_865 1_545
O4 Dy1 O7 141.48(12) 2_866 1_545
O1 Dy1 O7 76.39(11) . 1_545
O6 Dy1 O5 116.06(12) 2_765 .
O8 Dy1 O5 72.62(12) 2_875 .
O3 Dy1 O5 79.61(12) 1_454 .
O2 Dy1 O5 76.16(11) 2_865 .
O4 Dy1 O5 71.25(11) 2_866 .
O1 Dy1 O5 135.29(11) . .
O7 Dy1 O5 146.03(11) 1_545 .
C1 O1 Dy1 134.9(3) . .
C1 O2 Dy1 142.9(3) . 2_865
C9 O3 Dy1 143.9(3) . 1_656
C9 O4 Dy1 135.8(3) . 2_866
C10 O5 Dy1 111.8(3) . .
C10 O6 Dy1 158.8(3) . 2_765
C18 O7 Dy1 117.3(3) . 1_565
C18 O8 Dy1 178.1(3) . 2_875
C3 N1 C2 109.3(4) . .
C3 N1 C5 110.7(4) . .
C2 N1 C5 107.8(4) . .
C8 N2 C6 109.3(4) . .
C8 N2 C7 110.3(4) . .
C6 N2 C7 111.1(4) . .
C8 N2 H2N 105(4) . .
C6 N2 H2N 109(4) . .
C7 N2 H2N 112(4) . .
C12 N3 C11 116.2(7) . .
C12 N3 C13 109.2(6) . .
C11 N3 C13 107.7(6) . .
C17 N4 C15 110.6(5) . .
C17 N4 C16 109.6(5) . .
C15 N4 C16 111.4(5) . .
O9 N5 O10 125.5(19) . .
O9 N5 O11 124.8(19) . .
O10 N5 O11 109.4(14) . .
O2 C1 O1 126.7(4) . .
O2 C1 C2 117.8(4) . .
O1 C1 C2 115.4(4) . .
N1 C2 C1 115.4(4) . .
N1 C2 H2A 108.4 . .
C1 C2 H2A 108.4 . .
N1 C2 H2B 108.4 . .
C1 C2 H2B 108.4 . .
H2A C2 H2B 107.5 . .
N1 C3 C4 114.4(4) . .
N1 C3 H3A 108.7 . .
C4 C3 H3A 108.7 . .
N1 C3 H3B 108.7 . .
C4 C3 H3B 108.7 . .
H3A C3 H3B 107.6 . .
C7 C4 C3 116.7(4) 2_966 .
C7 C4 H4A 108.1 2_966 .
C3 C4 H4A 108.1 . .
C7 C4 H4B 108.1 2_966 .
C3 C4 H4B 108.1 . .
H4A C4 H4B 107.3 . .
N1 C5 C6 109.4(4) . .
N1 C5 H5A 109.8 . .
C6 C5 H5A 109.8 . .
N1 C5 H5B 109.8 . .
C6 C5 H5B 109.8 . .
H5A C5 H5B 108.2 . .
N2 C6 C5 112.7(4) . .
N2 C6 H6A 109.1 . .
C5 C6 H6A 109.1 . .
N2 C6 H6B 109.1 . .
C5 C6 H6B 109.1 . .
H6A C6 H6B 107.8 . .
N2 C7 C4 115.7(4) . 2_966
N2 C7 H7A 108.3 . .
C4 C7 H7A 108.3 2_966 .
N2 C7 H7B 108.3 . .
C4 C7 H7B 108.3 2_966 .
H7A C7 H7B 107.4 . .
N2 C8 C9 113.5(4) . .
N2 C8 H8A 108.9 . .
C9 C8 H8A 108.9 . .
N2 C8 H8B 108.9 . .
C9 C8 H8B 108.9 . .
H8A C8 H8B 107.7 . .
O3 C9 O4 129.1(4) . .
O3 C9 C8 116.9(4) . .
O4 C9 C8 114.0(4) . .
O6 C10 O5 123.1(4) . .
O6 C10 C11 117.8(5) . .
O5 C10 C11 118.6(5) . .
N3 C11 C10 114.6(6) . .
N3 C11 H11A 108.6 . .
C10 C11 H11A 108.6 . .
N3 C11 H11B 108.6 . .
C10 C11 H11B 108.6 . .
H11A C11 H11B 107.6 . .
N3 C12 C16 115.3(6) . 2_875
N3 C12 H12A 108.4 . .
C16 C12 H12A 108.4 2_875 .
N3 C12 H12B 108.4 . .
C16 C12 H12B 108.4 2_875 .
H12A C12 H12B 107.5 . .
C14 C13 N3 118.9(7) . .
C14 C13 H13A 107.6 . .
N3 C13 H13A 107.6 . .
C14 C13 H13B 107.6 . .
N3 C13 H13B 107.6 . .
H13A C13 H13B 107.0 . .
C13 C14 C15 113.6(6) . .
C13 C14 H14A 108.9 . .
C15 C14 H14A 108.9 . .
C13 C14 H14B 108.9 . .
C15 C14 H14B 108.9 . .
H14A C14 H14B 107.7 . .
N4 C15 C14 113.0(6) . .
N4 C15 H15A 109.0 . .
C14 C15 H15A 109.0 . .
N4 C15 H15B 109.0 . .
C14 C15 H15B 109.0 . .
H15A C15 H15B 107.8 . .
C12 C16 N4 114.7(6) 2_875 .
C12 C16 H16A 108.6 2_875 .
N4 C16 H16A 108.6 . .
C12 C16 H16B 108.6 2_875 .
N4 C16 H16B 108.6 . .
H16A C16 H16B 107.6 . .
N4 C17 C18 114.4(4) . .
N4 C17 H17A 108.7 . .
C18 C17 H17A 108.7 . .
N4 C17 H17B 108.7 . .
C18 C17 H17B 108.7 . .
H17A C17 H17B 107.6 . .
O7 C18 O8 125.5(4) . .
O7 C18 C17 118.4(4) . .
O8 C18 C17 116.1(4) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Dy1 O6 2.285(3) 2_765
Dy1 O8 2.285(3) 2_875
Dy1 O3 2.346(3) 1_454
Dy1 O2 2.404(3) 2_865
Dy1 O4 2.412(3) 2_866
Dy1 O1 2.422(3) .
Dy1 O7 2.427(3) 1_545
Dy1 O5 2.447(3) .
O1 C1 1.261(5) .
O2 C1 1.250(5) .
O2 Dy1 2.404(3) 2_865
O3 C9 1.244(5) .
O3 Dy1 2.346(3) 1_656
O4 C9 1.252(5) .
O4 Dy1 2.412(3) 2_866
O5 C10 1.271(6) .
O6 C10 1.243(6) .
O6 Dy1 2.285(3) 2_765
O7 C18 1.240(5) .
O7 Dy1 2.427(3) 1_565
O8 C18 1.253(5) .
O8 Dy1 2.285(3) 2_875
O9 N5 1.105(15) .
O10 N5 1.140(11) .
O11 N5 1.159(16) .
N1 C3 1.461(7) .
N1 C2 1.472(6) .
N1 C5 1.477(6) .
N2 C8 1.499(6) .
N2 C6 1.502(6) .
N2 C7 1.513(6) .
N2 H2N 0.84(6) .
N3 C12 1.426(9) .
N3 C11 1.438(8) .
N3 C13 1.466(8) .
N4 C17 1.481(7) .
N4 C15 1.484(8) .
N4 C16 1.514(7) .
C1 C2 1.525(6) .
C2 H2A 0.9900 .
C2 H2B 0.9900 .
C3 C4 1.525(8) .
C3 H3A 0.9900 .
C3 H3B 0.9900 .
C4 C7 1.515(8) 2_966
C4 H4A 0.9900 .
C4 H4B 0.9900 .
C5 C6 1.534(7) .
C5 H5A 0.9900 .
C5 H5B 0.9900 .
C6 H6A 0.9900 .
C6 H6B 0.9900 .
C7 C4 1.515(8) 2_966
C7 H7A 0.9900 .
C7 H7B 0.9900 .
C8 C9 1.523(6) .
C8 H8A 0.9900 .
C8 H8B 0.9900 .
C10 C11 1.507(8) .
C11 H11A 0.9900 .
C11 H11B 0.9900 .
C12 C16 1.510(10) 2_875
C12 H12A 0.9900 .
C12 H12B 0.9900 .
C13 C14 1.420(10) .
C13 H13A 0.9900 .
C13 H13B 0.9900 .
C14 C15 1.521(9) .
C14 H14A 0.9900 .
C14 H14B 0.9900 .
C15 H15A 0.9900 .
C15 H15B 0.9900 .
C16 C12 1.510(10) 2_875
C16 H16A 0.9900 .
C16 H16B 0.9900 .
C17 C18 1.516(7) .
C17 H17A 0.9900 .
C17 H17B 0.9900 .
OW2 H2D 0.69(6) .
OW1 H1C 0.70(7) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O6 Dy1 O1 C1 -168.1(4) 2_765 .
O8 Dy1 O1 C1 -9.3(4) 2_875 .
O3 Dy1 O1 C1 148.8(4) 1_454 .
O2 Dy1 O1 C1 49.7(4) 2_865 .
O4 Dy1 O1 C1 -91.0(4) 2_866 .
O7 Dy1 O1 C1 112.7(4) 1_545 .
O5 Dy1 O1 C1 -52.8(5) . .
O6 Dy1 O5 C10 4.0(3) 2_765 .
O8 Dy1 O5 C10 -139.8(3) 2_875 .
O3 Dy1 O5 C10 71.3(3) 1_454 .
O2 Dy1 O5 C10 143.3(3) 2_865 .
O4 Dy1 O5 C10 -57.2(3) 2_866 .
O1 Dy1 O5 C10 -95.9(3) . .
O7 Dy1 O5 C10 109.9(3) 1_545 .
Dy1 O2 C1 O1 20.9(8) 2_865 .
Dy1 O2 C1 C2 -162.6(4) 2_865 .
Dy1 O1 C1 O2 -53.1(7) . .
Dy1 O1 C1 C2 130.3(4) . .
C3 N1 C2 C1 65.6(5) . .
C5 N1 C2 C1 -174.0(4) . .
O2 C1 C2 N1 31.6(7) . .
O1 C1 C2 N1 -151.4(4) . .
C2 N1 C3 C4 -167.4(4) . .
C5 N1 C3 C4 74.0(5) . .
N1 C3 C4 C7 66.1(6) . 2_966
C3 N1 C5 C6 -163.0(4) . .
C2 N1 C5 C6 77.5(5) . .
C8 N2 C6 C5 63.3(6) . .
C7 N2 C6 C5 -174.8(4) . .
N1 C5 C6 N2 158.0(4) . .
C8 N2 C7 C4 -177.1(4) . 2_966
C6 N2 C7 C4 61.5(6) . 2_966
C6 N2 C8 C9 -167.0(4) . .
C7 N2 C8 C9 70.5(6) . .
Dy1 O3 C9 O4 11.2(9) 1_656 .
Dy1 O3 C9 C8 -171.5(4) 1_656 .
Dy1 O4 C9 O3 29.2(8) 2_866 .
Dy1 O4 C9 C8 -148.1(4) 2_866 .
N2 C8 C9 O3 12.7(7) . .
N2 C8 C9 O4 -169.7(4) . .
Dy1 O6 C10 O5 121.9(8) 2_765 .
Dy1 O6 C10 C11 -50.5(12) 2_765 .
Dy1 O5 C10 O6 -29.2(6) . .
Dy1 O5 C10 C11 143.2(6) . .
C12 N3 C11 C10 -122.6(8) . .
C13 N3 C11 C10 114.7(8) . .
O6 C10 C11 N3 -154.6(6) . .
O5 C10 C11 N3 32.7(11) . .
C11 N3 C12 C16 69.8(8) . 2_875
C13 N3 C12 C16 -168.2(7) . 2_875
C12 N3 C13 C14 84.7(9) . .
C11 N3 C13 C14 -148.3(9) . .
N3 C13 C14 C15 56.9(11) . .
C17 N4 C15 C14 -67.3(7) . .
C16 N4 C15 C14 170.6(6) . .
C13 C14 C15 N4 -178.3(7) . .
C17 N4 C16 C12 178.3(6) . 2_875
C15 N4 C16 C12 -58.9(8) . 2_875
C15 N4 C17 C18 87.1(6) . .
C16 N4 C17 C18 -149.6(6) . .
Dy1 O7 C18 O8 -7.1(6) 1_565 .
Dy1 O7 C18 C17 177.3(4) 1_565 .
Dy1 O8 C18 O7 138(10) 2_875 .
Dy1 O8 C18 C17 -46(10) 2_875 .
N4 C17 C18 O7 -139.0(5) . .
N4 C17 C18 O8 45.0(7) . .
