#------------------------------------------------------------------------------
#$Date: 2016-03-24 02:15:46 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179565 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/34/4503452.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4503452
loop_
_publ_author_name
'Liu, Guang-Xiang'
'Huang, Yong-Qing'
'Chu, Qian'
'Okamura, Taka-aki'
'Sun, Wei-Yin'
'Liang, Hong'
'Ueyama, Norikazu'
_publ_section_title
;
 Effect ofN-Donor Ancillary Ligands on Supramolecular Architectures of a
 Series of Zinc(II) and Cadmium(II) Complexes with Flexible Tricarboxylate
;
_journal_issue                   9
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              3233
_journal_paper_doi               10.1021/cg701137d
_journal_volume                  8
_journal_year                    2008
_chemical_formula_moiety         'C48 H42 N4 O14 Zn3'
_chemical_formula_sum            'C48 H42 N4 O14 Zn3'
_chemical_formula_weight         1094.97
_chemical_name_systematic        ?
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                105.134(2)
_cell_angle_beta                 104.420(2)
_cell_angle_gamma                104.882(2)
_cell_formula_units_Z            1
_cell_length_a                   9.6558(12)
_cell_length_b                   9.8429(12)
_cell_length_c                   13.4437(16)
_cell_measurement_reflns_used    946
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      21.16
_cell_measurement_theta_min      2.31
_cell_volume                     1121.5(2)
_computing_cell_refinement       Saintplus(Bruker,2000)
_computing_data_collection       Smart(Bruker,2000)
_computing_data_reduction        Saintplus(Bruker,2000)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.982
_diffrn_measured_fraction_theta_max 0.982
_diffrn_measurement_device_type  'Bruker Smart Apex CCD'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0331
_diffrn_reflns_av_sigmaI/netI    0.0751
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       7
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            5637
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.67
_exptl_absorpt_coefficient_mu    1.667
_exptl_absorpt_correction_T_max  0.8251
_exptl_absorpt_correction_T_min  0.8125
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs(Bruker,2000)
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.621
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             560
_exptl_crystal_size_max          0.13
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.12
_refine_diff_density_max         0.816
_refine_diff_density_min         -0.359
_refine_diff_density_rms         0.104
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.089
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     313
_refine_ls_number_reflns         3883
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.089
_refine_ls_R_factor_all          0.1010
_refine_ls_R_factor_gt           0.0734
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0708P)²+1.2830P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1524
_refine_ls_wR_factor_ref         0.1657
_reflns_number_gt                2870
_reflns_number_total             3883
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg701137d-file002.cif
_cod_data_source_block           2
_cod_database_code               4503452
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Zn1 Zn 0.0000 0.0000 0.0000 0.0349(3) Uani 1 2 d S
Zn2 Zn -0.29012(8) -0.01132(9) -0.24528(6) 0.0367(3) Uani 1 1 d .
O1 O 0.0505(5) 0.1726(5) -0.0580(4) 0.0496(13) Uani 1 1 d .
O1W O -0.3068(8) 0.1870(9) -0.4724(6) 0.112(3) Uani 1 1 d .
O2 O -0.1190(5) 0.1800(6) -0.1987(4) 0.0526(13) Uani 1 1 d .
O3 O 0.5517(5) 0.0464(5) -0.3297(4) 0.0475(12) Uani 1 1 d .
O4 O 0.5467(7) 0.1405(6) -0.1650(4) 0.0675(16) Uani 1 1 d .
O5 O 0.5405(5) 0.7790(6) -0.2393(4) 0.0472(12) Uani 1 1 d .
O6 O 0.7559(4) 0.9233(5) -0.1103(3) 0.0358(10) Uani 1 1 d .
N1 N -0.2343(6) -0.1431(6) -0.3661(4) 0.0407(14) Uani 1 1 d .
N2 N -0.0439(6) -0.8570(6) -0.8759(4) 0.0377(13) Uani 1 1 d .
C1 C 0.2331(7) 0.4178(7) -0.1273(5) 0.0348(15) Uani 1 1 d .
C2 C 0.3434(7) 0.5572(7) -0.0877(5) 0.0330(15) Uani 1 1 d .
H2A H 0.3318 0.6357 -0.0383 0.040 Uiso 1 1 calc R
C3 C 0.4697(7) 0.5848(7) -0.1185(5) 0.0351(15) Uani 1 1 d .
C4 C 0.4858(7) 0.4650(8) -0.1913(5) 0.0387(16) Uani 1 1 d .
H4A H 0.5708 0.4816 -0.2132 0.046 Uiso 1 1 calc R
C5 C 0.3800(7) 0.3238(8) -0.2316(5) 0.0348(15) Uani 1 1 d .
C6 C 0.2530(7) 0.3017(7) -0.1993(5) 0.0366(15) Uani 1 1 d .
H6A H 0.1795 0.2066 -0.2266 0.044 Uiso 1 1 calc R
C7 C 0.0930(7) 0.3980(7) -0.0924(6) 0.0456(18) Uani 1 1 d .
H7A H 0.1254 0.4507 -0.0142 0.055 Uiso 1 1 calc R
H7B H 0.0288 0.4441 -0.1289 0.055 Uiso 1 1 calc R
C8 C 0.0005(7) 0.2381(7) -0.1172(6) 0.0353(15) Uani 1 1 d .
C9 C 0.5901(7) 0.7381(8) -0.0680(5) 0.0425(17) Uani 1 1 d .
H9A H 0.5569 0.8024 -0.0182 0.051 Uiso 1 1 calc R
H9B H 0.6824 0.7302 -0.0246 0.051 Uiso 1 1 calc R
C10 C 0.6286(7) 0.8133(7) -0.1461(6) 0.0365(16) Uani 1 1 d .
C11 C 0.3992(8) 0.1968(9) -0.3105(6) 0.0488(19) Uani 1 1 d .
H11A H 0.4345 0.2329 -0.3635 0.059 Uiso 1 1 calc R
H11B H 0.3000 0.1193 -0.3500 0.059 Uiso 1 1 calc R
C12 C 0.5069(8) 0.1268(7) -0.2613(6) 0.0420(17) Uani 1 1 d .
C13 C -0.1082(8) -0.0923(8) -0.3899(6) 0.0485(18) Uani 1 1 d .
H13A H -0.0496 0.0088 -0.3558 0.058 Uiso 1 1 calc R
C14 C -0.0613(8) -0.1788(8) -0.4602(6) 0.0494(18) Uani 1 1 d .
H14A H 0.0277 -0.1361 -0.4726 0.059 Uiso 1 1 calc R
C15 C -0.1423(7) -0.3278(8) -0.5136(5) 0.0404(17) Uani 1 1 d .
C16 C -0.2750(9) -0.3815(9) -0.4932(6) 0.063(2) Uani 1 1 d .
H16A H -0.3368 -0.4816 -0.5289 0.075 Uiso 1 1 calc R
C17 C -0.3162(8) -0.2878(9) -0.4202(7) 0.060(2) Uani 1 1 d .
H17A H -0.4062 -0.3273 -0.4078 0.072 Uiso 1 1 calc R
C18 C -0.0927(9) -0.4241(9) -0.5894(6) 0.057(2) Uani 1 1 d .
H18A H 0.0001 -0.3809 -0.5968 0.068 Uiso 1 1 calc R
C19 C -0.1673(9) -0.5652(10) -0.6473(7) 0.063(2) Uani 1 1 d .
H19A H -0.2614 -0.6072 -0.6412 0.075 Uiso 1 1 calc R
C20 C -0.1171(8) -0.6640(8) -0.7213(6) 0.0475(18) Uani 1 1 d .
C21 C 0.0152(8) -0.6171(8) -0.7435(6) 0.0467(18) Uani 1 1 d .
H21A H 0.0833 -0.5196 -0.7065 0.056 Uiso 1 1 calc R
C22 C 0.0451(8) -0.7149(8) -0.8201(6) 0.0459(18) Uani 1 1 d .
H22A H 0.1343 -0.6800 -0.8347 0.055 Uiso 1 1 calc R
C23 C -0.1708(7) -0.9022(8) -0.8514(6) 0.0449(18) Uani 1 1 d .
H23A H -0.2350 -1.0015 -0.8867 0.054 Uiso 1 1 calc R
C24 C -0.2101(8) -0.8090(9) -0.7768(6) 0.052(2) Uani 1 1 d .
H24A H -0.3006 -0.8450 -0.7641 0.062 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Zn1 O1 180.0(2) 2 . yes
O1 Zn1 N2 92.1(2) 2 1_566 yes
O1 Zn1 N2 87.9(2) . 1_566 yes
O1 Zn1 N2 87.9(2) 2 2_544 yes
O1 Zn1 N2 92.1(2) . 2_544 yes
N2 Zn1 N2 180.0(3) 1_566 2_544 yes
O1 Zn1 O6 90.93(16) 2 1_445 yes
O1 Zn1 O6 89.07(16) . 1_445 yes
N2 Zn1 O6 90.84(18) 1_566 1_445 yes
N2 Zn1 O6 89.16(18) 2_544 1_445 yes
O1 Zn1 O6 89.07(16) 2 2_665 yes
O1 Zn1 O6 90.93(16) . 2_665 yes
N2 Zn1 O6 89.16(18) 1_566 2_665 yes
N2 Zn1 O6 90.84(18) 2_544 2_665 yes
O6 Zn1 O6 180.0(2) 1_445 2_665 yes
O3 Zn2 O2 97.3(2) 1_455 . yes
O3 Zn2 O6 139.08(18) 1_455 1_445 yes
O2 Zn2 O6 102.49(18) . 1_445 yes
O3 Zn2 N1 103.0(2) 1_455 . yes
O2 Zn2 N1 99.6(2) . . yes
O6 Zn2 N1 108.49(19) 1_445 . yes
O3 Zn2 O5 94.95(19) 1_455 1_445 yes
O2 Zn2 O5 161.30(19) . 1_445 yes
O6 Zn2 O5 59.38(16) 1_445 1_445 yes
N1 Zn2 O5 91.4(2) . 1_445 yes
O3 Zn2 C10 117.3(2) 1_455 1_445 ?
O2 Zn2 C10 132.6(2) . 1_445 ?
O6 Zn2 C10 30.52(18) 1_445 1_445 ?
N1 Zn2 C10 102.6(2) . 1_445 ?
O5 Zn2 C10 28.94(18) 1_445 1_445 ?
C8 O1 Zn1 146.3(4) . . ?
C8 O2 Zn2 130.4(4) . . ?
C12 O3 Zn2 107.7(4) . 1_655 ?
C10 O5 Zn2 85.3(4) . 1_665 ?
C10 O6 Zn2 95.2(4) . 1_665 ?
C10 O6 Zn1 141.7(4) . 1_665 ?
Zn2 O6 Zn1 118.47(17) 1_665 1_665 ?
C17 N1 C13 115.2(6) . . ?
C17 N1 Zn2 121.9(5) . . ?
C13 N1 Zn2 122.7(5) . . ?
C22 N2 C23 115.3(6) . . ?
C22 N2 Zn1 123.5(4) . 1_544 ?
C23 N2 Zn1 121.2(5) . 1_544 ?
C2 C1 C6 118.2(6) . . ?
C2 C1 C7 119.1(6) . . ?
C6 C1 C7 122.7(6) . . ?
C3 C2 C1 122.4(6) . . ?
C3 C2 H2A 118.8 . . ?
C1 C2 H2A 118.8 . . ?
C2 C3 C4 117.8(6) . . ?
C2 C3 C9 119.7(6) . . ?
C4 C3 C9 122.4(6) . . ?
C5 C4 C3 121.9(6) . . ?
C5 C4 H4A 119.0 . . ?
C3 C4 H4A 119.0 . . ?
C4 C5 C6 118.2(6) . . ?
C4 C5 C11 121.0(6) . . ?
C6 C5 C11 120.8(6) . . ?
C1 C6 C5 121.5(6) . . ?
C1 C6 H6A 119.3 . . ?
C5 C6 H6A 119.3 . . ?
C8 C7 C1 114.2(5) . . ?
C8 C7 H7A 108.7 . . ?
C1 C7 H7A 108.7 . . ?
C8 C7 H7B 108.7 . . ?
C1 C7 H7B 108.7 . . ?
H7A C7 H7B 107.6 . . ?
O1 C8 O2 125.1(6) . . ?
O1 C8 C7 117.5(6) . . ?
O2 C8 C7 117.4(6) . . ?
C10 C9 C3 116.2(5) . . ?
C10 C9 H9A 108.2 . . ?
C3 C9 H9A 108.2 . . ?
C10 C9 H9B 108.2 . . ?
C3 C9 H9B 108.2 . . ?
H9A C9 H9B 107.4 . . ?
O5 C10 O6 119.8(6) . . ?
O5 C10 C9 122.4(6) . . ?
O6 C10 C9 117.6(6) . . ?
O5 C10 Zn2 65.7(4) . 1_665 ?
O6 C10 Zn2 54.3(3) . 1_665 ?
C9 C10 Zn2 168.4(5) . 1_665 ?
C5 C11 C12 116.1(6) . . ?
C5 C11 H11A 108.3 . . ?
C12 C11 H11A 108.3 . . ?
C5 C11 H11B 108.3 . . ?
C12 C11 H11B 108.3 . . ?
H11A C11 H11B 107.4 . . ?
O4 C12 O3 121.6(6) . . ?
O4 C12 C11 123.4(6) . . ?
O3 C12 C11 114.9(6) . . ?
N1 C13 C14 124.1(7) . . ?
N1 C13 H13A 118.0 . . ?
C14 C13 H13A 118.0 . . ?
C13 C14 C15 121.1(7) . . ?
C13 C14 H14A 119.5 . . ?
C15 C14 H14A 119.5 . . ?
C14 C15 C16 115.9(7) . . ?
C14 C15 C18 122.0(6) . . ?
C16 C15 C18 122.0(7) . . ?
C17 C16 C15 120.1(7) . . ?
C17 C16 H16A 119.9 . . ?
C15 C16 H16A 119.9 . . ?
N1 C17 C16 123.5(7) . . ?
N1 C17 H17A 118.2 . . ?
C16 C17 H17A 118.2 . . ?
C19 C18 C15 125.6(8) . . ?
C19 C18 H18A 117.2 . . ?
C15 C18 H18A 117.2 . . ?
C18 C19 C20 126.2(8) . . ?
C18 C19 H19A 116.9 . . ?
C20 C19 H19A 116.9 . . ?
C24 C20 C21 117.3(7) . . ?
C24 C20 C19 118.6(7) . . ?
C21 C20 C19 123.9(7) . . ?
C22 C21 C20 119.2(7) . . ?
C22 C21 H21A 120.4 . . ?
C20 C21 H21A 120.4 . . ?
N2 C22 C21 124.8(6) . . ?
N2 C22 H22A 117.6 . . ?
C21 C22 H22A 117.6 . . ?
N2 C23 C24 123.2(7) . . ?
N2 C23 H23A 118.4 . . ?
C24 C23 H23A 118.4 . . ?
C20 C24 C23 120.2(7) . . ?
C20 C24 H24A 119.9 . . ?
C23 C24 H24A 119.9 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Zn1 O1 2.047(4) 2 yes
Zn1 O1 2.047(4) . yes
Zn1 N2 2.092(5) 1_566 yes
Zn1 N2 2.092(5) 2_544 yes
Zn1 O6 2.255(4) 1_445 yes
Zn1 O6 2.255(4) 2_665 yes
Zn2 O3 1.965(4) 1_455 yes
Zn2 O2 1.984(5) . yes
Zn2 O6 2.064(4) 1_445 yes
Zn2 N1 2.075(5) . yes
Zn2 O5 2.315(5) 1_445 yes
Zn2 C10 2.530(6) 1_445 ?
O1 C8 1.232(7) . ?
O2 C8 1.250(8) . ?
O3 C12 1.285(8) . ?
O3 Zn2 1.965(4) 1_655 ?
O4 C12 1.216(8) . ?
O5 C10 1.229(8) . ?
O5 Zn2 2.315(5) 1_665 ?
O6 C10 1.290(7) . ?
O6 Zn2 2.064(4) 1_665 ?
O6 Zn1 2.255(4) 1_665 ?
N1 C17 1.333(9) . ?
N1 C13 1.342(8) . ?
N2 C22 1.331(8) . ?
N2 C23 1.344(8) . ?
N2 Zn1 2.092(5) 1_544 ?
C1 C2 1.374(8) . ?
C1 C6 1.381(9) . ?
C1 C7 1.522(8) . ?
C2 C3 1.368(8) . ?
C2 H2A 0.9300 . ?
C3 C4 1.392(9) . ?
C3 C9 1.504(9) . ?
C4 C5 1.368(9) . ?
C4 H4A 0.9300 . ?
C5 C6 1.385(8) . ?
C5 C11 1.499(9) . ?
C6 H6A 0.9300 . ?
C7 C8 1.497(8) . ?
C7 H7A 0.9700 . ?
C7 H7B 0.9700 . ?
C9 C10 1.499(9) . ?
C9 H9A 0.9700 . ?
C9 H9B 0.9700 . ?
C10 Zn2 2.530(6) 1_665 ?
C11 C12 1.502(9) . ?
C11 H11A 0.9700 . ?
C11 H11B 0.9700 . ?
C13 C14 1.346(9) . ?
C13 H13A 0.9300 . ?
C14 C15 1.364(10) . ?
C14 H14A 0.9300 . ?
C15 C16 1.379(10) . ?
C15 C18 1.462(10) . ?
C16 C17 1.372(10) . ?
C16 H16A 0.9300 . ?
C17 H17A 0.9300 . ?
C18 C19 1.302(11) . ?
C18 H18A 0.9300 . ?
C19 C20 1.465(10) . ?
C19 H19A 0.9300 . ?
C20 C24 1.361(10) . ?
C20 C21 1.376(10) . ?
C21 C22 1.358(9) . ?
C21 H21A 0.9300 . ?
C22 H22A 0.9300 . ?
C23 C24 1.370(9) . ?
C23 H23A 0.9300 . ?
C24 H24A 0.9300 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O1 Zn1 O1 C8 121(46) 2 .
N2 Zn1 O1 C8 -86.8(8) 1_566 .
N2 Zn1 O1 C8 93.2(8) 2_544 .
O6 Zn1 O1 C8 4.1(8) 1_445 .
O6 Zn1 O1 C8 -175.9(8) 2_665 .
O3 Zn2 O2 C8 154.2(6) 1_455 .
O6 Zn2 O2 C8 10.2(6) 1_445 .
N1 Zn2 O2 C8 -101.3(6) . .
O5 Zn2 O2 C8 23.7(10) 1_445 .
C10 Zn2 O2 C8 15.9(7) 1_445 .
O3 Zn2 N1 C17 -82.6(6) 1_455 .
O2 Zn2 N1 C17 177.5(6) . .
O6 Zn2 N1 C17 70.8(6) 1_445 .
O5 Zn2 N1 C17 12.8(6) 1_445 .
C10 Zn2 N1 C17 39.7(6) 1_445 .
O3 Zn2 N1 C13 102.2(6) 1_455 .
O2 Zn2 N1 C13 2.3(6) . .
O6 Zn2 N1 C13 -104.4(5) 1_445 .
O5 Zn2 N1 C13 -162.5(5) 1_445 .
C10 Zn2 N1 C13 -135.6(5) 1_445 .
C6 C1 C2 C3 1.1(9) . .
C7 C1 C2 C3 -177.6(6) . .
C1 C2 C3 C4 -1.0(9) . .
C1 C2 C3 C9 -177.0(6) . .
C2 C3 C4 C5 0.0(9) . .
C9 C3 C4 C5 175.9(6) . .
C3 C4 C5 C6 0.9(9) . .
C3 C4 C5 C11 179.6(6) . .
C2 C1 C6 C5 -0.1(9) . .
C7 C1 C6 C5 178.5(6) . .
C4 C5 C6 C1 -0.8(9) . .
C11 C5 C6 C1 -179.5(6) . .
C2 C1 C7 C8 -165.8(6) . .
C6 C1 C7 C8 15.6(10) . .
Zn1 O1 C8 O2 -25.4(12) . .
Zn1 O1 C8 C7 157.1(6) . .
Zn2 O2 C8 O1 14.5(10) . .
Zn2 O2 C8 C7 -167.9(4) . .
C1 C7 C8 O1 75.6(8) . .
C1 C7 C8 O2 -102.1(7) . .
C2 C3 C9 C10 -124.0(6) . .
C4 C3 C9 C10 60.2(8) . .
Zn2 O5 C10 O6 -5.4(5) 1_665 .
Zn2 O5 C10 C9 170.6(6) 1_665 .
Zn2 O6 C10 O5 6.1(6) 1_665 .
Zn1 O6 C10 O5 -146.4(5) 1_665 .
Zn2 O6 C10 C9 -170.1(5) 1_665 .
Zn1 O6 C10 C9 37.4(9) 1_665 .
Zn1 O6 C10 Zn2 -152.4(6) 1_665 1_665
C3 C9 C10 O5 22.2(9) . .
C3 C9 C10 O6 -161.7(5) . .
C3 C9 C10 Zn2 154.6(19) . 1_665
C4 C5 C11 C12 79.6(8) . .
C6 C5 C11 C12 -101.7(7) . .
Zn2 O3 C12 O4 -9.0(8) 1_655 .
Zn2 O3 C12 C11 172.9(5) 1_655 .
C5 C11 C12 O4 18.8(10) . .
C5 C11 C12 O3 -163.1(6) . .
C17 N1 C13 C14 -2.1(11) . .
Zn2 N1 C13 C14 173.4(6) . .
N1 C13 C14 C15 0.4(12) . .
C13 C14 C15 C16 1.8(11) . .
C13 C14 C15 C18 -179.3(7) . .
C14 C15 C16 C17 -2.1(11) . .
C18 C15 C16 C17 179.0(7) . .
C13 N1 C17 C16 1.8(11) . .
Zn2 N1 C17 C16 -173.8(6) . .
C15 C16 C17 N1 0.3(13) . .
C14 C15 C18 C19 -176.4(8) . .
C16 C15 C18 C19 2.5(13) . .
C15 C18 C19 C20 -178.2(7) . .
C18 C19 C20 C24 -179.4(8) . .
C18 C19 C20 C21 -3.5(13) . .
C24 C20 C21 C22 1.3(11) . .
C19 C20 C21 C22 -174.6(7) . .
C23 N2 C22 C21 -0.5(10) . .
Zn1 N2 C22 C21 176.2(5) 1_544 .
C20 C21 C22 N2 -1.2(11) . .
C22 N2 C23 C24 1.9(10) . .
Zn1 N2 C23 C24 -174.8(5) 1_544 .
C21 C20 C24 C23 0.1(11) . .
C19 C20 C24 C23 176.2(7) . .
N2 C23 C24 C20 -1.8(11) . .
